WO2008138836A3 - Verfahren zur herstellung von polyisobutylbernsteinsäureanhydriden - Google Patents

Verfahren zur herstellung von polyisobutylbernsteinsäureanhydriden Download PDF

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Publication number
WO2008138836A3
WO2008138836A3 PCT/EP2008/055640 EP2008055640W WO2008138836A3 WO 2008138836 A3 WO2008138836 A3 WO 2008138836A3 EP 2008055640 W EP2008055640 W EP 2008055640W WO 2008138836 A3 WO2008138836 A3 WO 2008138836A3
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WO
WIPO (PCT)
Prior art keywords
polyisobutyl
production
anhydrides
succinate
molar ratio
Prior art date
Application number
PCT/EP2008/055640
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English (en)
French (fr)
Other versions
WO2008138836A2 (de
Inventor
Phillip Hanefeld
Hans-Michael Walter
Ulrich Eichenauer
Helmut Mach
Original Assignee
Basf Se
Phillip Hanefeld
Hans-Michael Walter
Ulrich Eichenauer
Helmut Mach
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se, Phillip Hanefeld, Hans-Michael Walter, Ulrich Eichenauer, Helmut Mach filed Critical Basf Se
Publication of WO2008138836A2 publication Critical patent/WO2008138836A2/de
Publication of WO2008138836A3 publication Critical patent/WO2008138836A3/de

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
    • C08F8/32—Introducing nitrogen atoms or nitrogen-containing groups by reaction with amines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/08—Butenes
    • C08F10/10—Isobutene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/26—Removing halogen atoms or halogen-containing groups from the molecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/46—Reaction with unsaturated dicarboxylic acids or anhydrides thereof, e.g. maleinisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/48—Isomerisation; Cyclisation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/192—Macromolecular compounds
    • C10L1/198—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/234—Macromolecular compounds
    • C10L1/238—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
    • C10L1/2383—Polyamines or polyimines, or derivatives thereof (poly)amines and imines; derivatives thereof (substituted by a macromolecular group containing 30C)
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00—Use of additives to fuels or fires for particular purposes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00—Use of additives to fuels or fires for particular purposes
    • C10L10/04—Use of additives to fuels or fires for particular purposes for minimising corrosion or incrustation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00—Use of additives to fuels or fires for particular purposes
    • C10L10/18—Use of additives to fuels or fires for particular purposes use of detergents or dispersants for purposes not provided for in groups C10L10/02 - C10L10/16
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
    • C10M129/86—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of 30 or more atoms
    • C10M129/92—Carboxylic acids
    • C10M129/93—Carboxylic acids having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M133/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
    • C10M133/52—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of 30 or more atoms
    • C10M133/56—Amides; Imides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2810/00—Chemical modification of a polymer
    • C08F2810/30—Chemical modification of a polymer leading to the formation or introduction of aliphatic or alicyclic unsaturated groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2810/00—Chemical modification of a polymer
    • C08F2810/40—Chemical modification of a polymer taking place solely at one end or both ends of the polymer backbone, i.e. not in the side or lateral chains
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/129—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/28—Amides; Imides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/04—Detergent property or dispersant property

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Combustion & Propulsion (AREA)
  • Emergency Medicine (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Herstellung von Polyisobutylbernsteinsäureanhydriden mit einem durchschnittlichen molaren Verhältnis von Bernsteinsäureanhydrid-Gruppen zu Polyisobutyl-Gruppen von 1,0 : 1 bis 1,3 : 1 durch thermische Umsetzung von hochreaktiven Polyisobutenen mit einem zahlenmittleren Molekulargewicht Mn von 350 bis 50.000 und mit einem Gehalt an terminalen Vinyliden-Doppelbindungen von mehr als 90 Mol-% mit Maleinsäure oder Maleinsäureanhydrid im Mol-Verhältnis von 1 : 3 bis 1 : 0,95. Die so erhaltenen Polyisobutylbernsteinsäureanhydride dienen zur Herstellung von als Additive in Kraft- und Schmierstoffzusammensetzungen geeigneten Polyisobutylbernsteinsäure-Derivaten, welche wenigstens eine primäre oder sekundäre Aminogruppe, eine Iminogruppe und/oder eine Hydroxylgruppe aufweisen.
PCT/EP2008/055640 2007-05-11 2008-05-07 Verfahren zur herstellung von polyisobutylbernsteinsäureanhydriden WO2008138836A2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP07108029.5 2007-05-11
EP07108029 2007-05-11

Publications (2)

Publication Number Publication Date
WO2008138836A2 WO2008138836A2 (de) 2008-11-20
WO2008138836A3 true WO2008138836A3 (de) 2009-02-26

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ID=39800656

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PCT/EP2008/055640 WO2008138836A2 (de) 2007-05-11 2008-05-07 Verfahren zur herstellung von polyisobutylbernsteinsäureanhydriden

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Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20090258803A1 (en) * 2008-04-14 2009-10-15 Harrison James J Copolymers made with quasi-living polyolefins and unsaturated acidic reagents, dispersants using same, and methods of making same
WO2009135877A1 (de) * 2008-05-07 2009-11-12 Basf Se Diblockcopolymer-substituierte bernsteinsäurederivate
CA2804322C (en) 2010-07-06 2020-02-11 Basf Se Acid-free quaternised nitrogen compounds and use thereof as additives in fuels and lubricants
EP2540808A1 (de) 2011-06-28 2013-01-02 Basf Se Quaternisierte Stickstoffverbindungen und deren Verwendung als Additive in Kraft- und Schmierstoffen
US20130133243A1 (en) 2011-06-28 2013-05-30 Basf Se Quaternized nitrogen compounds and use thereof as additives in fuels and lubricants
MY186439A (en) 2013-06-07 2021-07-22 Basf Se Use of nitrogen compounds quaternised with alkylene oxide and hydrocarbyl-substituted polycarboxylic acid as additives in fuels and lubricants
ES2728113T3 (es) 2013-09-20 2019-10-22 Basf Se Uso de derivados especiales de compuestos cuaternizados de nitrógeno, como aditivos en combustibles
US11168273B2 (en) 2014-01-29 2021-11-09 Basf Se Polycarboxylic acid-based additives for fuels and lubricants
EP3257874A1 (de) * 2016-06-15 2017-12-20 Basf Se Alkenylbernsteinsäurederivate und verfahren zu deren herstellung
US11078418B2 (en) 2016-07-05 2021-08-03 Basf Se Corrosion inhibitors for fuels and lubricants
US10844308B2 (en) 2016-07-05 2020-11-24 Basf Se Corrosion inhibitors for fuels and lubricants
JP7069117B2 (ja) * 2017-03-16 2022-05-17 株式会社カネカ ビニル系櫛型共重合体

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0016312A1 (de) * 1979-02-05 1980-10-01 BASF Aktiengesellschaft Verfahren zur Herstellung von Polyisobutenen und Verwendung derselben zur Herstellung von Mineralölhilfsmitteln
US5068490A (en) * 1989-08-18 1991-11-26 Amoco Corporation BF3-tertiary etherate complexes for isobutylene polymerization
EP0587381A1 (de) * 1992-09-09 1994-03-16 BP Chemicals Limited Poly(iso)butylenderivate
EP0632061A1 (de) * 1993-06-14 1995-01-04 BASF Aktiengesellschaft Verfahren zur Herstellung von Polyisobutylbernsteinsäureanhydriden
EP1344785A1 (de) * 2002-03-15 2003-09-17 Bayer Ag Verfahren zur Herstellung hochreaktiver Polyisobutene
WO2007057404A1 (de) * 2005-11-21 2007-05-24 Basf Se Verfahren zur herstellung von hochreaktiven isobutenhomo- oder -copolymeren mittels borhaltiger katalysatorkomplexe
WO2007057406A1 (de) * 2005-11-21 2007-05-24 Basf Se Verfahren zur herstellung von hochreaktiven isobutenhomo- oder -copolymeren aus technischen c4-kohlenwasserstoffströmen mittels protonensaurer katalysatorkomplexe

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0016312A1 (de) * 1979-02-05 1980-10-01 BASF Aktiengesellschaft Verfahren zur Herstellung von Polyisobutenen und Verwendung derselben zur Herstellung von Mineralölhilfsmitteln
US5068490A (en) * 1989-08-18 1991-11-26 Amoco Corporation BF3-tertiary etherate complexes for isobutylene polymerization
EP0587381A1 (de) * 1992-09-09 1994-03-16 BP Chemicals Limited Poly(iso)butylenderivate
EP0632061A1 (de) * 1993-06-14 1995-01-04 BASF Aktiengesellschaft Verfahren zur Herstellung von Polyisobutylbernsteinsäureanhydriden
EP1344785A1 (de) * 2002-03-15 2003-09-17 Bayer Ag Verfahren zur Herstellung hochreaktiver Polyisobutene
WO2007057404A1 (de) * 2005-11-21 2007-05-24 Basf Se Verfahren zur herstellung von hochreaktiven isobutenhomo- oder -copolymeren mittels borhaltiger katalysatorkomplexe
WO2007057406A1 (de) * 2005-11-21 2007-05-24 Basf Se Verfahren zur herstellung von hochreaktiven isobutenhomo- oder -copolymeren aus technischen c4-kohlenwasserstoffströmen mittels protonensaurer katalysatorkomplexe

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