WO2008111638A1 - ブテン-エチレン共重合体の製造方法 - Google Patents

ブテン-エチレン共重合体の製造方法 Download PDF

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Publication number
WO2008111638A1
WO2008111638A1 PCT/JP2008/054600 JP2008054600W WO2008111638A1 WO 2008111638 A1 WO2008111638 A1 WO 2008111638A1 JP 2008054600 W JP2008054600 W JP 2008054600W WO 2008111638 A1 WO2008111638 A1 WO 2008111638A1
Authority
WO
WIPO (PCT)
Prior art keywords
butene
ethylene copolymer
producing
formula
ethylene
Prior art date
Application number
PCT/JP2008/054600
Other languages
English (en)
French (fr)
Inventor
Takahiro Hino
Hidenori Hanaoka
Taichi Senda
Original Assignee
Sumitomo Chemical Company, Limited
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Chemical Company, Limited filed Critical Sumitomo Chemical Company, Limited
Priority to US12/531,047 priority Critical patent/US20100093957A1/en
Priority to EP08722004A priority patent/EP2123685A1/en
Publication of WO2008111638A1 publication Critical patent/WO2008111638A1/ja

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/08—Butenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+

Abstract

　式（１）で示される遷移金属錯体を触媒成分として含むオレフィン重合用触媒の存在下、1-ブテンおよびエチレンを共重合することを含んでなる、1-ブテン含量が６０ｍｏｌ％以上、Ｍｗが２００，０００以上及びＭｗ／Ｍｎが３以下であるブテン-エチレン共重合体を得ることを特徴とするブテン-エチレン共重合体の製造方法： 式（１）（式中、Ｍ，Ａ，Ｂ，Ｆｌｕ，Ｘ１，Ｘ２，Ｒ１－Ｒ６の定義は明細書の記載を参照。）。 この製造方法によれば、高い1-ブテン含量の高分子量エチレン－ブテンを得ることができる。
PCT/JP2008/054600 2007-03-14 2008-03-13 ブテン-エチレン共重合体の製造方法 WO2008111638A1 (ja)

Priority Applications (2)

Application Number Priority Date Filing Date Title
US12/531,047 US20100093957A1 (en) 2007-03-14 2008-03-13 Method for producing butene-ethylene copolymer
EP08722004A EP2123685A1 (en) 2007-03-14 2008-03-13 Method for producing butene-ethylene copolymer

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007-064804 2007-03-14
JP2007064804A JP2008222898A (ja) 2007-03-14 2007-03-14 ブテンエチレン共重合体の製造方法

Publications (1)

Publication Number Publication Date
WO2008111638A1 true WO2008111638A1 (ja) 2008-09-18

Family

ID=39759569

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/054600 WO2008111638A1 (ja) 2007-03-14 2008-03-13 ブテン-エチレン共重合体の製造方法

Country Status (4)

Country Link
US (1) US20100093957A1 (ja)
EP (1) EP2123685A1 (ja)
JP (1) JP2008222898A (ja)
WO (1) WO2008111638A1 (ja)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010070758A (ja) * 2008-08-21 2010-04-02 Sumitomo Chemical Co Ltd 樹脂組成物
SG11201501899UA (en) 2012-09-14 2015-05-28 Mitsui Chemicals Inc 1-BUTENE • a-OLEFIN COPOLYMER COMPOSITION

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5819309A (ja) 1981-07-09 1983-02-04 ヘキスト・アクチエンゲゼルシヤフト ポリオレフインの製造法
JPH07501845A (ja) * 1991-12-13 1995-02-23 エクソン・ケミカル・パテンツ・インク エチレンとより長いアルファーオレフィンのコポリマー
JPH0987313A (ja) 1995-07-14 1997-03-31 Sumitomo Chem Co Ltd 遷移金属錯体、その製造方法、該遷移金属錯体を含有するオレフィン重合用触媒、およびオレフィン重合体の製造方法
JPH09183809A (ja) * 1995-10-30 1997-07-15 Sumitomo Chem Co Ltd オレフィン系重合体の製造方法
JP2003176295A (ja) * 1995-07-14 2003-06-24 Sumitomo Chem Co Ltd 遷移金属錯体およびその製造方法
JP2004224881A (ja) * 2003-01-22 2004-08-12 Sumitomo Chem Co Ltd 重合用触媒及びオレフィン系重合体の製造法
JP2006182851A (ja) * 2004-12-27 2006-07-13 Sumitomo Chemical Co Ltd 付加重合用触媒成分、付加重合用触媒ならびに付加重合体の製造方法
JP2006233116A (ja) * 2005-02-28 2006-09-07 Sumitomo Chemical Co Ltd 付加重合用触媒成分、付加重合用触媒ならびに付加重合体の製造方法
JP2007191534A (ja) * 2006-01-18 2007-08-02 Sumitomo Chemical Co Ltd オレフィン重合体の製造方法

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6329478B1 (en) * 1995-07-14 2001-12-11 Sumitmo Chemical Company, Limited Transition metal complex, process for producing the same, olefin polymerization catalyst containing the transition metal complex and process for producing olefin polymers
US6664208B1 (en) * 1999-09-07 2003-12-16 Sumitomo Chemical Company, Limited Modified aluminum oxy compound, polymerization catalyst and process for producing olefin polymer and alkenyl aromatic hydrocarbon polymer

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5819309A (ja) 1981-07-09 1983-02-04 ヘキスト・アクチエンゲゼルシヤフト ポリオレフインの製造法
JPH07501845A (ja) * 1991-12-13 1995-02-23 エクソン・ケミカル・パテンツ・インク エチレンとより長いアルファーオレフィンのコポリマー
JPH0987313A (ja) 1995-07-14 1997-03-31 Sumitomo Chem Co Ltd 遷移金属錯体、その製造方法、該遷移金属錯体を含有するオレフィン重合用触媒、およびオレフィン重合体の製造方法
JP2003176295A (ja) * 1995-07-14 2003-06-24 Sumitomo Chem Co Ltd 遷移金属錯体およびその製造方法
JPH09183809A (ja) * 1995-10-30 1997-07-15 Sumitomo Chem Co Ltd オレフィン系重合体の製造方法
JP2004224881A (ja) * 2003-01-22 2004-08-12 Sumitomo Chem Co Ltd 重合用触媒及びオレフィン系重合体の製造法
JP2006182851A (ja) * 2004-12-27 2006-07-13 Sumitomo Chemical Co Ltd 付加重合用触媒成分、付加重合用触媒ならびに付加重合体の製造方法
JP2006233116A (ja) * 2005-02-28 2006-09-07 Sumitomo Chemical Co Ltd 付加重合用触媒成分、付加重合用触媒ならびに付加重合体の製造方法
JP2007191534A (ja) * 2006-01-18 2007-08-02 Sumitomo Chemical Co Ltd オレフィン重合体の製造方法

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
"KOBUNSHI BUNSEKI HANDBOOK", KINOKUNIYA COMPANY LTD, article "the Japan Society for Analytical Chemistry, Research Committee of Polymer Analysis"
JMS-REV. MACROMOL. CHEM. PHYS., vol. C29, no. 2, 3, 1989, pages 201 - 317

Also Published As

Publication number Publication date
JP2008222898A (ja) 2008-09-25
EP2123685A1 (en) 2009-11-25
US20100093957A1 (en) 2010-04-15

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