WO2008081490A1 - Dispositif d'accrochage et pinces de serrage avec double contact cathodique sur les deux côtés d'un substrat diélectrique à électrogalvaniser - Google Patents

Dispositif d'accrochage et pinces de serrage avec double contact cathodique sur les deux côtés d'un substrat diélectrique à électrogalvaniser Download PDF

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Publication number
WO2008081490A1
WO2008081490A1 PCT/IT2007/000087 IT2007000087W WO2008081490A1 WO 2008081490 A1 WO2008081490 A1 WO 2008081490A1 IT 2007000087 W IT2007000087 W IT 2007000087W WO 2008081490 A1 WO2008081490 A1 WO 2008081490A1
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WO
WIPO (PCT)
Prior art keywords
gripping device
substratum
gripping
insulating support
contact
Prior art date
Application number
PCT/IT2007/000087
Other languages
English (en)
Inventor
Francesco Occleppo
Original Assignee
Occleppo S.R.L.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Occleppo S.R.L. filed Critical Occleppo S.R.L.
Publication of WO2008081490A1 publication Critical patent/WO2008081490A1/fr

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Classifications

    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D17/00Constructional parts, or assemblies thereof, of cells for electrolytic coating
    • C25D17/005Contacting devices
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D17/00Constructional parts, or assemblies thereof, of cells for electrolytic coating
    • C25D17/06Suspending or supporting devices for articles to be coated
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K3/00Apparatus or processes for manufacturing printed circuits
    • H05K3/22Secondary treatment of printed circuits
    • H05K3/24Reinforcing the conductive pattern
    • H05K3/241Reinforcing the conductive pattern characterised by the electroplating method; means therefor, e.g. baths or apparatus

Definitions

  • the present invention relates to electroplating -equipment for the production of printed circuit boards (PCB or PWB), the substrata to be plated being passed horizontally through rollers that have absorbed the plating solution in a wet bed unit, said substrata being taken up laterally during . transport by gripping devices . that comprise pincer-like means provided with a cathode contact insulated from the plating solution or, to state it more precisely, the invention relates to a gripping device having clamping pincers with a double cathode contact on both sides of a dielectric substratum to be subsequently electroplated.
  • PCB or PWB printed circuit boards
  • This method is known as direct metallization of the holes by chemical means; it can be done by using a conductive polymer, or graphite or other similar materials, even though these possess a specific resistance superior to that of the copper used in the plating process.
  • Direct metallization of the holes leads to imperfect electrical conductivity due both to the materials used arid to the layer applied being very thin. On account of this, and also because the gripping device ensures electrical contact on one side only, it generally happens that current is not evenly distributed on both faces of the substratum which therefore leads to uneven distribution of the plating material.
  • Figure 1 shows the position of the device on the chain conveyor-belt mechanism for transporting the substratum ( Figures 1, 2, 3 and 4 correspond, in the same order, to Figures 17, 7, 1OA and 1OC of the citation, reference numerals being maintained unaltered).
  • FIG. 1 shows a view from above of a drive unit 150 for conveying the substratum 217 during the plating process.
  • the drive unit 150 comprises the following parts: an actuator in the form of a chain 152 fitted with mounting means for the gripping devices 124 placed one next to another; a drive supporting frame 156, a motor with gear box 158 for driving the chain 152, and a tensioning gear 160 placed at one end where the chain 152 makes its rotating movement. Apart from these points of rotation, concentrated at its two ends, the chain 152 and the gripping devices 124 follow a substantially rectilinear path, as indicated by the arrow A, along the longest side of the frame 156.
  • the substratum 217 is gripped at the beginning of the straight length and is dropped just before the straight length terminates.
  • the cupric ion in a Cu ++ solution migrates from the electrified substratum to the cathode, by means of the pincer means on the gripping device, where it takes the form of a layer of metal copper evenly laid on the surface of the substratum as well as inside the holes.
  • the hydroxyl group OH becomes oxidised leaving the hydrogen ion H + in an aqueous solution which acidifies it and which must therefore be buffered.
  • FIG. 1 gives an axonometric ,view of a gripping device 124 in the electroplating device belonging to the previously known art, shown when open and without substratum 217 ( Figure 1).
  • the gripping device 124 comprises a non-metal housing 166 (of polypropylene or polyethylene), a metal component 168, a flat support 172 able to pivot, and a sealing device 176 consisting of an elastic cone-shaped packing.
  • the non-metal housing 166 comprises a T-shaped component 178 and a second component 180.
  • the plastic component 178 has a central body 182 and two arms 184 that extend perpendicular to the body.
  • the second component 180 also defines a passageway 170 ( Figure 3) that receives the central body 182 of the T-shaped component 178.
  • the second component 180 further contains a mounting part with a plurality of holes for screwing the mounting connection onto the drive- chain 152.
  • Springs are placed between the two arms 184 of the T-shaped component 178 and the second component 180 below, their purpose being to render elastic the sliding movement made by the central body 182 into the passageway 170 ( Figure 3).
  • the gripping device 124 is symmetrical to a plane that passes through the axis A-A. •
  • Figure 3 shows the section A-A in Figure 2, where it will be seen that the metal component 168 comprises the following conductors of electricity: a metal roller 206, a pin 208 for rotating said roller, a first contact 197 and a second contact 199, both of a substantially lengthened rectangular shape, a first spring 200 and a second spring 202, these being more rigid than the previous ones, a braided or plaited conductor 204 fixed by screws 218 to contacts 197 and 199.
  • the pin 208 is in contact both with the roller 206 and with the walls of a housing for the roller made in the upper part of the first contact 197 which also marks a lower opening 198 for the conductor 204.
  • the second contact 199 defines an opening 210 for the conductor 204 and presents an extension 212 which, when closed, crosses through an opening 214 in the lower wall of the central body 182 which is continuous with the cavity 186 (see Figure 4).
  • the first spring 200 is placed between the first contact 197 and the second contact 199.
  • the second spring 202 is situated between the second contact 199 and the base of the cavity 186. Beyond the edge of the opening 214, the base of the central body 182 presents a short narrow extension to permit application of the seal packing 176.
  • the flat support 172 is substantially L-shaped, the shorter arm of which is connected to the housing 166 by a pin 213 around which it can make a partial turn so forming, together with the other arm, a passageway 174 for the substratum 217 (see Figure 4).
  • the rectilinear movement of the gripping device 124 carries the roller 206 below a collector of anodic current in the form of a bar that slopes downward in the direction in which the initial stretch moves.
  • the T-shaped component 178 is pressed inside the cavity 170 until it comes in contact with the upper face- of the substratum 217 and engages the seal packing 176.
  • the extension 212 of the cathode contact 199 is kept insulated from the plating solution.
  • the springs possessing greater rigidity also become compressed by thrust from the roller 206 until the extension 212, penetrating inside the cavity 214, reaches the substratum to provide the cathode contact.
  • Figure 4 shows how the end section of the gripping device would appear when closed, with both the seal packing 176 and the extension 212 of contact 199 pressed against the substratum 217 in order to ensure a mechanical grip and supply a cathode contact, insulated from the electrolytic solution, when current passes through it.
  • the main drawback to the gripping device just described is that it does not ensure an uniform distribution of the plating material on both sides of the substratum through the holes, this because cathode contact is present on one side only of the substratum.
  • Purpose of the present invention is to overcome the drawbacks explained above and suggest how to provide a gripping device with an improved cathode contact able to ensure that said device can be more satisfactorily used in an electroplating apparatus such as that described for the production of printed circuit boards (PCB or PWB). .
  • subject of the present invention is a gripping device with cathode electrification of a dielectric substratum for printed circuit boards guided through means for electrolytic application- of a plating solution on both faces, said device being connected to means of conveyance, adjacent to the means of application, for translation along a path in contact with fixed external collectors of cathode current, preferably in the form of a bar and having a least one end inclined towards the substratum in the direction of translation, comprising: a first insulating support rigidly connected to said means of conveyance; a second insulating means slidingly connected to the . first support;
  • first means of compression placed between said first and second insulating support; - means for supplying an electric contact to said external collectors of current during translation; . second means of compression emerging from the second insulating support to connect with means for supplying an electric contact during translation; - first means of electrification with the substratum rigidly connected to the second insulating support and electrically connected to means for supplying an electric contact during translation;
  • the gripping device includes a third means of compression emerging from the second insulating support to make contact with the external current collector means.
  • the second and third means of compression are so arranged as to make the pressure exerted by the feed bar on the sliding electric contact independent of pressure exerted by said bar on both faces of the substratum to be plated.
  • the second and third means of compression comprise helical springs parallel to one another, placed in blind holes made in the second insulating support; these consist of two helical springs included in the second means of compression that engage the sliding contact and keep it pressed against the feed bar, and a central spring, included in the third means of compression, that transfers to the mobile insulating support the thrust exerted by the external feed bar on a presser means separate from the sliding contact.
  • said first and second means of electrification and grip are coated with a layer of electrically insulating material resistant to acids, except for the surfaces in contact with the substratum to be plated, the dimensions of which are those strictly necessary for satisfactory operation.
  • This serves to prevent any metal being deposited directly on the cathode electrodes immersed in the plating solution and helps to prolong their life.
  • the seal packing, used in the gripping device made according to the prior art, is thus no longer essential.
  • the electric conductor means, that connect the sliding contact to the first and second means used for electrification and for gripping the substratum comprise flexible wires placed externally in relation to said insulating supports. The advantage of this is to be able to use strong wires of suitable length and easily connectable to the clamps, unlike the flexible wire placed inside the insulating support used in the gripping, device made in accordance with the prior art mentioned above.
  • the first and second means used for electrification and for gripping the substratum are electrodes in the form of L-shaped bars whose shorter arms are superimposed one over another when required to grip, and the respective ends opposite one another similar to a pair of pincers (here called pincer- electrodes).
  • pincer- electrodes a pair of pincers
  • the means for supplying an electric contact during movement consist of a small metal bar shaped like a bridge with a flat area in the centre and with the flat ends free for connection, each to its respective contact block, to one end of the flexible conductors.
  • the bridge is laid'orthogonally to the external feed bar like a sliding block.
  • Figure 1 already described, shows a drive unit seen from above, constructed in accordance with the prior art, for conveying a substratum to be electroplated, and including a plurality of gripping devices;
  • Figure 2 already described, shows an axonometric view of the gripping device made in accordance with the prior art;
  • Figure 3 already described , shows a cross-section through the axis A-A seen in Figure 2;
  • Figure 4 already described, gives a detail of the gripping device in Figure
  • Figures 5 to 8 show views of the gripping device made according to the present invention, respectively seen from above, from the side and from the back and front;
  • Figures 9 and 10 show perspective views of the upper and lower pincer- electrodes, more correctly described as forming the electrified pincers of the gripping device in Figure 6;
  • Figure 11 shows a perspective view of the insulating support to which the number 1 is given in Figure 6;
  • Figures 12 and 12A show a side view and a front view of the upper pincer- electrode in Figure 6.
  • Figures 13 and 13A a show side view and a front view of the lower pincer- electrode seen in Figure 6;
  • FIG 14 a cross-section is shown of the chain conveyor for moving the gripping device made according to the invention, laying emphasis on a first gripping device seen holding the substratum to be electroplated, and a second gripping device shown when idle on the other side of the chain.
  • Figure 5 gives a plan view .of a gripping device comprising a . first insulating support 1 and a second insulating support 2, both of plastic material.
  • Support 1 is rigidly fixed to an anchoring plate 3 by screws 3 a and 3b; said plate also presents holes 3c and 3d for screwing the plate onto the conveyor chain (not seen).
  • a metal contact 4 is visible between the plastic supports 1 and 2, said contact being of a substantially , rectangular shape, extending over the whole width of the gripping device and having a central semicircular recess around a hole 5 in the upper part of the plastic support 2.
  • Contact 4 is screwed at its two ends onto two contact blocks (not shown) by screws, 7a and 8a respectively.
  • the leads 9 and 10 converge towards a plate 12, inside a centrally placed hole 11, to which they are fixed by a round-headed screw 17.
  • the plate 12 is also mechanically and electrically connected to a metal rod 19a that extends as far as a jaw 19b, both forming part of a lower pincer- electrode.
  • the contact blocks also carry two flexible leads 13 and 14 respectively fixed by screws 13a and 14a onto the face opposite to the screws 9a and 10a. At the other end the leads 13 and 14 are fixed by screws 13b and 14b to contacts inside the plastic support 2 and extend as far as an electrode 18b superimposed over the electrode 19b.
  • Figure 6 shows a side view of the gripping device in which one end of the sliding contact 4 is screwed by a screw 8a onto the contact block 8.
  • a presser 6 can be seen in the form of a small plastic cylinder.
  • An external lateral spring 15a is situated between the plastic supports 1 and 2.
  • the pincer-electrodes 18 and 19 can be seen respectively connected to the plastic supports 2 and 1.
  • the pincer- electrode 18 comprises an arm 18a that extends downwards from the top of the plastic support 2 and beyond the lower end where it makes a 90° bend and continues outwards for a suitable length 18b, finally terminating in a further short downward 90° bend.
  • the arm 18a is rigidly joined to the plastic support 2 by a screw (not shown) and electrically connected to the terminal blocks 7 and 8 by an upper metal component (visible in Figure 9) orthogonal to the arm 18a to which it is firmly fixed, said arm presenting lateral expansions that follow the outline of the sides of the plastic support 2 connecting up to contacts 13b and 14b of the flexible electric leads 13 and 14.
  • the pincer-electrode 19 is substantially L-shaped and consists of one longer arm 19a and one shorter arm 19b.
  • the L-shaped electrode can pivot around a pin 16a that crosses a point where the inner sides widen out close to the angle, and is sustained by two small parts 16 close to the lower end of the plastic support 1.
  • the terminal section of the arm 19b is enlarged and flat, and is situated opposite the inward curve of the arm 18b so as to ensure mechanical engagement and, simultaneously, an electric contact when the two arms are pressed together.
  • Figure 7 shows a rear view of the gripping device, this being the view seen from the side opposite to the substratum.
  • the figure shows that the upper contact 4 is bridge-shaped with a substantially flat central part and the two ends screwed to the contact blocks.7 and 8.
  • the presser 6 projects from the upper part of support 2 at the centre of the sliding conductor 4; joints can be seen at the sides of the presser 6 and these will be described in greater detail in the next Figure.
  • the insulating support 2 is substantially T-shaped, its shank translating vertically in relation to the insulating support 1 which, in turn, is fixed to the conveyor means. Below the arms of the T. are two springs, 15a and 15b, that rest on the upper face of the insulating support 1.
  • Figure .8 shows a view of the gripping device from the front, this being the side where the substratum (not shown) is gripped and slides along.
  • the device is symmetrical to a vertical axis, drawn in the figure, that intercepts the horizontal feed bar 37 designed by a broken line.
  • a groove having a rectangular cross section (seen in
  • Figure 11 passes through the front of the insulating support for its entire height. This groove is partially open at the front; inside it is the insulating
  • the insulating support 2 comprises three blind holes in its upper part, the central one, 5, being wider and situated on the axis of symmetry coinciding with the centre line of the view seen in this figure, while the two shallower and narrower holes lie one on each side of the central hole 5.
  • Inside hole 5 is a spring 6a on which rests the base of the presser component 6.
  • two compensation springs 24 and 27 on which rest the shanks 23 and 26 of two operative components connected to the sliding contact 4 on the opposite side.
  • One of these components is a support that engages the spring 24 and comprises the parts marked 20, 22 and 23.
  • the other component is a joint that engages the spring 27 and comprises the parts marked 21, 25 and 26.
  • part 20 is a tongue bent downward from the edge of the sliding contact 4.
  • Lower down on the tongue 20 is a small projecting part that, with the aid of a tongue placed opposite, sustains the head 22 of a small piston 23 that tests on the spring 24!
  • the circular head 22 makes contact against the under surface of the sliding contact 4 to give it better support.
  • the part marked 21 is a tongue bent downward from the edge of sliding contact 4.
  • a pin 25 is inserted in a hole in the tongue 21, said pin also passing through the hole in a tongue placed opposite.
  • FIG. 9 shows the upper pincer-electrode 18, also substantially L-shaped, consisting of one longer arm 18a, and one shorter arm 18b, ending in a downward curve at 90°.
  • This pineer-electrode 18 also comprises an upper component 18c consisting of a metal bar of the same width and thickness, placed orthogonally to the longer arm 18a, to which arm said orthogonal bar 18c is joined by a screw 18f screwed into a hole in its centre.
  • the ends of the upper bar 18c are bent to form a wide U so as to fit onto the sides of the mobile insulating support 2.
  • the two ends 18d and 18e of part 18c are bent inwards and each contain a hole in its front surface into which the flexible electric leads 13 and 14 are screwed.
  • Figure 10 shows the lower pincer-electrode 19 where a hole for insertion of the pin 16a; fixed to the insulating support 1, is seen in the solid part 19c at the angle between the two arms 19a and 19b. In this way the pincer- electrode 19 can pivot around the pin 16a.
  • Figure 11 shows the fixed insulating support 1 consisting of a plastic body shaped so as to comprise a front bevelled section, and a thinner rear section separated by a projection underneath that extends along the entire length.
  • a slot open at the front communicating with a longer cavity Id, both cavities having a rectangular section throughout.
  • the slot and cavity Id together form an opening shaped like a short T to receive the translating shank of the. plastic support 2 that holds the upper pincef -electrode 18 in position.
  • the upper face of the plastic support 1 is flat and presents a long hole 1 1 in which to insert the electronic arm 19a, two housings Ie and If for receiving one end of each of the springs 15a and 15b, and two holes 3c and"3 J d for two screws to fix the whole to the conveying means.
  • Figures 12 and 12A show the electrically insulating and anticorrosive coating applied to the surface of the upper pincer-electrode 18. It will be seen from the figures that the surface of the electrode is evenly coated with a thick layer of insulating material 1 SR, except the face at the end of the final curved section of the arm 18b where electric contact will be made and except for the upper part left free so that it can be screwed in place.
  • Figures 13 and 13 A show the electrically insulating and anticorrosive coating applied to the surface of the lower pincer-electrode 19. It will be seen from the figures that the surface of the electrode is evenly coated with a thick layer of insulating material 19R except for the flat face at the end of the arm 19b where electric contact will be made and except for the upper part where it is screwed to the contact plate 12.
  • Figure 14 shows how the gripping device and cathode electrification is connected to a conveying means 34, 32, 33 adjacent to a double set of rollers 35 whose function is to apply an electrolytic plating solution to the two faces of a substratum 36.
  • a conveying means 34, 32, 33 adjacent to a double set of rollers 35 whose function is to apply an electrolytic plating solution to the two faces of a substratum 36.
  • a chain 34, . together with its rotating supports 32 and 33 form part of the chain conveyor 34.
  • the figure does not show the electric motors and all other parts needed to move the chain, but shows a cross section along the path of translation well beyond the initial stage where the gripping device intercepts the substratum.
  • Two gripping devices are represented inside two ellipses GPl and GP2; one device in the GPl ellipse is-in 1 operation with the substratum 36 held between arms 18b and 19b of the pincer-electrodes 18 and 19; these receive current from the sliding contact 4 compressed by a heavy copper bar 37 that lies parallel to the .chain 34 for the whole of its length.
  • the lower pincer-electrode 19b rests on" a metal support 38 into which fit the shafts of the application rollers 35.
  • the distance between the bar 37 and the support 38 is less than the height of the gripping device in its idle position, visible on the other side of the chain inside the ellipse GP2; when in that position, all the springs present are compressed to ensure proper gripping strength and stability of the electrical contacts both above and below.
  • this configuration is reached after an initial stage in which the substratum is fitted in between the two arms 18b and 19b (which might be considered equivalent to the two jaws of. a pair of cathode pincers) and following gradual application of compression to the springs possessing different degrees of elasticity.
  • This position is reached by a gradual inclination both of the copper bar 37 and of the lower support 38 when these are converging towards the operating position.
  • the insulating support 1 is made of poly ethyl ene-terephthalate (PET)
  • the insulating support 2 is made of polyethylene (PE).
  • the presser 6 is made of PET.
  • the sliding contact 4, the feed bar, the terminal blocks 7 and 8 and the contact plate 12 are all of copper.
  • the pincer-electrodes, 18, 18c and 19 and their connecting parts, as well as those for fixing the sliding contact 4 to contact blocks 7, 8 and 12, (namely screws, nuts, washers, etc.), are all of titanium.
  • the shaft 26, with its pin 25, of the joint fixed to the sliding contact 4 are of titanium.
  • the insulating coating 18R and 19R on the pincer-electrodes 18 and 19, is of polyethylene 0.5 mm thick.
  • Dimensions of the springs 15a and 15b ( Figure 7), of AISI 316 stainless steel, are 1.20 x 9.80 x 44.00 mm elasticity being constant at 2.20 N/mm.
  • Dimensions of the spring 6a ( Figure 8), of AISI 316 stainless steel, are 1.20 x 9.00 x 19.00 mm, elasticity being constant at 7.50 N/mm.
  • Dimensions of the springs 24 and 27. ( Figure 8), of AISI 316 stainless steel are 0.80 x 6.10 s 10.20 mm, elasticity being constant at 6.60 N/mm.
  • the downward movement continues until the internal spring 6a also begins to shorten immediately followed by the two internal lateral springs 24 and 27 which then press the sliding contact 4 against the feed bar 37, but with slightly less force than that exerted on the pincer-electrodes 18 and 19.
  • the spring 6a possessing a greater degree of constant elasticity, applies the correct amount of pressure to the jaws 18b and 19b sufficient to ensure their ability to grip the substratum 36.
  • the two internal lateral springs 24 and 27 ensure that the sliding contact 4' maintains its contact with the feed bar 37, the degree of pressure exerted there being determined independently from that applied to the pincet-electrodes.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Electroplating Methods And Accessories (AREA)

Abstract

La présente invention concerne un dispositif d'accrochage et d'électrification cathodique d'un substrat diélectrique pour fabriquer des cartes de circuits imprimés, de nombreux dispositifs d'accrochage étant montés sur un convoyeur à chaîne qui guide le substrat, soutenu par lesdits dispositifs d'accrochage, à l'aide de deux séries de rouleaux opposés qui appliquent une solution de galvanisation par électrolyse. Le dispositif d'accrochage comprend un support isolant fixe à l'intérieur duquel coulisse un autre support, les deux supports étant séparés par des ressorts. Ces supports transportent chacun des électrodes de type pinces en forme de L pour s'accrocher au substrat, les bras les plus courts se superposant pendant l'action d'accrochage et les pointes respectives s'étendant à l'opposé l'une de l'autre à l'image d'une paire de pinces. Les électrodes en titane en forme de L sont plaquées avec un matériau isolant à l'exception des pointes. Le dispositif d'accrochage comprend également un contact en cuivre de la forme d'un coulisseau qui repose sur les ressorts à l'intérieur du support isolant coulissant. Pendant la translation du dispositif d'accrochage, le coulisseau coulisse contre une barre en cuivre située au-dessus de celui-ci qui fournit le courant de la cathode. Une extrémité de la barre est inclinée vers le substrat dans la direction de translation. Des branches flexibles externes relient le coulisseau aux électrodes-pinces. Un bouton-poussoir, détaché du coulisseau, est pressé contre la barre externe par un ressort central solide placé à l'intérieur du support isolant coulissant.
PCT/IT2007/000087 2007-01-03 2007-02-09 Dispositif d'accrochage et pinces de serrage avec double contact cathodique sur les deux côtés d'un substrat diélectrique à électrogalvaniser WO2008081490A1 (fr)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102766895A (zh) * 2011-05-05 2012-11-07 Lpkf激光和电子股份公司 在塑料部件上制造金属化结构的方法
CN107475766A (zh) * 2017-08-17 2017-12-15 奥士康科技股份有限公司 一种飞钯防腐蚀延长使用寿命保护方法
CN115573019A (zh) * 2022-12-09 2023-01-06 宁波德洲精密电子有限公司 一种引线框架电镀柜

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0254962A1 (fr) * 1986-07-28 1988-02-03 Siemens Aktiengesellschaft Dispositif pour l'électroplacage des articles en forme de plaques, en particulier des plaques de circuits imprimés
DE4324330A1 (de) * 1992-08-01 1994-02-03 Atotech Deutschland Gmbh Verfahren zum elektrolytischen Behandeln von insbesondere flachem Behandlungsgut, sowie Anordnung, insbesondere zur Durchführung des Verfahrens
WO2000011679A2 (fr) * 1998-08-19 2000-03-02 Atotech Deutschland Gmbh Element de contact
WO2001029288A2 (fr) * 1999-10-21 2001-04-26 Teledyne Technologies Incorporated Dispositif de galvanoplastie a convoyeur

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0254962A1 (fr) * 1986-07-28 1988-02-03 Siemens Aktiengesellschaft Dispositif pour l'électroplacage des articles en forme de plaques, en particulier des plaques de circuits imprimés
DE4324330A1 (de) * 1992-08-01 1994-02-03 Atotech Deutschland Gmbh Verfahren zum elektrolytischen Behandeln von insbesondere flachem Behandlungsgut, sowie Anordnung, insbesondere zur Durchführung des Verfahrens
WO2000011679A2 (fr) * 1998-08-19 2000-03-02 Atotech Deutschland Gmbh Element de contact
WO2001029288A2 (fr) * 1999-10-21 2001-04-26 Teledyne Technologies Incorporated Dispositif de galvanoplastie a convoyeur

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102766895A (zh) * 2011-05-05 2012-11-07 Lpkf激光和电子股份公司 在塑料部件上制造金属化结构的方法
EP2546390A1 (fr) * 2011-05-05 2013-01-16 LPKF Laser & Electronics AG Procédé de fabrication de métallisations sur des objets en plastique
CN107475766A (zh) * 2017-08-17 2017-12-15 奥士康科技股份有限公司 一种飞钯防腐蚀延长使用寿命保护方法
CN115573019A (zh) * 2022-12-09 2023-01-06 宁波德洲精密电子有限公司 一种引线框架电镀柜
CN115573019B (zh) * 2022-12-09 2023-02-17 宁波德洲精密电子有限公司 一种引线框架电镀柜

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