WO2008078406A1 - Flame-retardant thermoplastic resin composition - Google Patents

Flame-retardant thermoplastic resin composition Download PDF

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Publication number
WO2008078406A1
WO2008078406A1 PCT/JP2007/001422 JP2007001422W WO2008078406A1 WO 2008078406 A1 WO2008078406 A1 WO 2008078406A1 JP 2007001422 W JP2007001422 W JP 2007001422W WO 2008078406 A1 WO2008078406 A1 WO 2008078406A1
Authority
WO
WIPO (PCT)
Prior art keywords
weight
thermoplastic resin
resin composition
flame
retardant thermoplastic
Prior art date
Application number
PCT/JP2007/001422
Other languages
French (fr)
Japanese (ja)
Inventor
Hisao Shinto
Keisuke Yagi
Original Assignee
Mitsubishi Chemical Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Chemical Corporation filed Critical Mitsubishi Chemical Corporation
Priority to JP2008550960A priority Critical patent/JPWO2008078406A1/en
Publication of WO2008078406A1 publication Critical patent/WO2008078406A1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H01B3/442—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from aromatic vinyl compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
    • C08L23/0853—Vinylacetate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02—Homopolymers or copolymers of hydrocarbons
    • C08L25/04—Homopolymers or copolymers of styrene
    • C08L25/06—Polystyrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00—Insulated conductors or cables characterised by their form
    • H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/29—Protection against damage caused by extremes of temperature or by flame
    • H01B7/295—Protection against damage caused by extremes of temperature or by flame using material resistant to flame

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Insulated Conductors (AREA)
  • Inorganic Insulating Materials (AREA)
  • Organic Insulating Materials (AREA)

Abstract

Disclosed is a flame-retardant thermoplastic resin composition which maintains high flame retardancy without containing a halogen, and is free from problems of conventional non-halogen flame-retardant thermoplastic resin compositions. This flame-retardant thermoplastic resin composition is flexible and highly heat-resistant, while having good terminal workability, scratch whitening resistance, mechanical strength, moldability and excellent discoloration resistance. Specifically disclosed is a flame-retardant thermoplastic resin composition which is obtained by blending 50-300 parts by weight of a metal hydroxide (Y) per 100 parts by weight of a thermoplastic resin composition (X) containing 25-90% by weight of a polyethylene resin (a), 1-20% by weight of a polypropylene resin (b), 5-39% by weight of a styrene thermoplastic elastomer (c) and 4-40% by weight of a mineral oil-based rubber softener (d). This flame-retardant thermoplastic resin composition is characterized in that at least a part of the polyethylene resin (a) is composed of an ethylene-vinyl acetate copolymer (EVA), and the ethylene-vinyl acetate copolymer content is 40-80% by weight relative to 100% by weight of the thermoplastic resin composition (X).
PCT/JP2007/001422 2006-12-22 2007-12-18 Flame-retardant thermoplastic resin composition WO2008078406A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2008550960A JPWO2008078406A1 (en) 2006-12-22 2007-12-18 Flame retardant thermoplastic resin composition

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2006-345609 2006-12-22
JP2006345609 2006-12-22

Publications (1)

Publication Number Publication Date
WO2008078406A1 true WO2008078406A1 (en) 2008-07-03

Family

ID=39562203

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2007/001422 WO2008078406A1 (en) 2006-12-22 2007-12-18 Flame-retardant thermoplastic resin composition

Country Status (4)

Country Link
JP (1) JPWO2008078406A1 (en)
KR (1) KR20090089839A (en)
CN (1) CN101522780A (en)
WO (1) WO2008078406A1 (en)

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2012087238A (en) * 2010-10-21 2012-05-10 Furukawa Electric Co Ltd:The Insulated wire and method for production the same
WO2012127785A1 (en) * 2011-03-22 2012-09-27 Yazaki Corporation Electric cable
WO2013108329A1 (en) * 2012-01-19 2013-07-25 昭和電線ケーブルシステム株式会社 Flame-retardant electric wire/cable
WO2013140692A1 (en) * 2012-03-22 2013-09-26 住友電気工業株式会社 Non-halogen flame retardant resin composition, and electric wire and cable using same
JP2013245335A (en) * 2012-05-29 2013-12-09 Hitachi Cable Ltd Flame retardant non-crosslinked resin composition and electric wire and cable using the same
WO2014010500A1 (en) * 2012-07-09 2014-01-16 古河電気工業株式会社 Non-halogen flame-retardant resin composition and insulated wire/cable having non-halogen flame-retardant resin composition
EP2784144A1 (en) * 2013-03-29 2014-10-01 Hitachi Metals, Ltd. Halogen- and phosphorus-free flame-retardant insulated wire and halogen- and phosphorus-free flame-retardant insulated cable
CN105367972A (en) * 2015-11-18 2016-03-02 安徽雄亚塑胶科技有限公司 TPE composition and halogen-free flame retardant plug protective jacket prepared from TPE composition
WO2016074172A1 (en) * 2014-11-12 2016-05-19 Abb Technology Ltd Electrical insulating material and method for preparing insulating material element
US9447252B2 (en) 2014-07-07 2016-09-20 Hyundai Motor Company Polypropylene-based resin composition and method for manufacturing polypropylene composite material
WO2016152432A1 (en) * 2015-03-24 2016-09-29 株式会社オートネットワーク技術研究所 Electrical-wire covering material composition, insulated electrical wire, and wire harness
CN112961417A (en) * 2021-01-16 2021-06-15 江西江缆科技有限公司 High-flexibility fireproof cable and preparation method thereof
EP4024413A4 (en) * 2019-08-30 2022-10-19 Sumitomo Electric Industries, Ltd. Electrically insulated cable and sensor-integrated harness
CN115910456A (en) * 2022-11-07 2023-04-04 河南华东电缆股份有限公司 High-temperature-resistant fireproof cable and preparation method thereof

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102391637B (en) * 2011-09-14 2013-05-08 上海锦湖日丽塑料有限公司 Polyphenyl ether elastomer composition
CN103772834B (en) * 2014-01-25 2016-01-13 盛嘉伦橡塑(深圳）股份有限公司 Plastic water pipe material and preparation method thereof
US9156978B1 (en) * 2014-06-06 2015-10-13 Teknor Apex Company Low softener halogen free flame retardant styrenic block copolymer-based thermoplastic elastomer compositions
KR101866426B1 (en) 2017-03-20 2018-06-12 한국건설기술연구원 Aluminum Composite Panel Using Incombustible Plastic And Method for Manufacturing the Same
KR101893066B1 (en) 2017-03-20 2018-08-29 한국건설기술연구원 Gangway Bellows for Railway Vehicles Using Incombustible Plastic, And Method for Manufacturing the Same
KR101893089B1 (en) 2017-03-20 2018-08-29 한국건설기술연구원 Seat for Railway Vehicles Using Incombustible Plastic, And Method for Manufacturing the Same
KR101893069B1 (en) 2017-03-20 2018-08-29 한국건설기술연구원 Interior Member for Railway Vehicles Using Incombustible Plastic Panel, And Method for Manufacturing the Same
KR101938725B1 (en) 2017-03-23 2019-01-16 한국건설기술연구원 Extrusion Mould for Extruding Incombustible Plastic Panel And Method for Manufacturing Incombustible Plastic Panel Using the Same
EP3666823B1 (en) * 2017-08-08 2023-10-25 Riken Technos Corporation Thermoplastic resin composition for wire-coating and heat resistant wire
KR101981698B1 (en) 2018-11-28 2019-05-24 한국건설기술연구원 System for Manufacturing Incombustible Composite Panel And Method for Manufacturing Incombustible Composite Panel Using the Same
KR101988597B1 (en) 2018-11-28 2019-06-13 한국건설기술연구원 Laminating Apparatus for Manufacturing Incombustible Composite Panel And Method for Manufacturing Incombustible Composite Panel Using the Same
CN109401044A (en) * 2018-12-17 2019-03-01 上海至正道化高分子材料股份有限公司 A kind of low-smoke halogen-free polyolefin cable material and preparation method thereof
CN111961273A (en) * 2020-07-14 2020-11-20 江苏神达管阀件有限公司 Conductive plastic inflammable and explosive tail gas absorption tube

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3047911B1 (en) * 1999-05-28 2000-06-05 住友電気工業株式会社 Non-halogen flame-retardant resin composition and its applied products
JP2002226641A (en) * 2001-01-31 2002-08-14 Sumitomo Bakelite Co Ltd Flexible flame-retardant resin composition of non- halogen type and its application product
JP2006182875A (en) * 2004-12-27 2006-07-13 Advanced Plastics Compounds Co Flame-retardant thermoplastic resin composition

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3047911B1 (en) * 1999-05-28 2000-06-05 住友電気工業株式会社 Non-halogen flame-retardant resin composition and its applied products
JP2002226641A (en) * 2001-01-31 2002-08-14 Sumitomo Bakelite Co Ltd Flexible flame-retardant resin composition of non- halogen type and its application product
JP2006182875A (en) * 2004-12-27 2006-07-13 Advanced Plastics Compounds Co Flame-retardant thermoplastic resin composition

Cited By (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2012087238A (en) * 2010-10-21 2012-05-10 Furukawa Electric Co Ltd:The Insulated wire and method for production the same
WO2012127785A1 (en) * 2011-03-22 2012-09-27 Yazaki Corporation Electric cable
US9236165B2 (en) 2011-03-22 2016-01-12 Yazaki Corporation Electric cable
WO2013108329A1 (en) * 2012-01-19 2013-07-25 昭和電線ケーブルシステム株式会社 Flame-retardant electric wire/cable
JP2013149472A (en) * 2012-01-19 2013-08-01 Swcc Showa Cable Systems Co Ltd Fire-retardant wire cable
WO2013140692A1 (en) * 2012-03-22 2013-09-26 住友電気工業株式会社 Non-halogen flame retardant resin composition, and electric wire and cable using same
JP2013245335A (en) * 2012-05-29 2013-12-09 Hitachi Cable Ltd Flame retardant non-crosslinked resin composition and electric wire and cable using the same
JPWO2014010500A1 (en) * 2012-07-09 2016-06-23 古河電気工業株式会社 Non-halogen flame retardant resin composition and insulated wire / cable having the resin composition
WO2014010500A1 (en) * 2012-07-09 2014-01-16 古河電気工業株式会社 Non-halogen flame-retardant resin composition and insulated wire/cable having non-halogen flame-retardant resin composition
EP2784144A1 (en) * 2013-03-29 2014-10-01 Hitachi Metals, Ltd. Halogen- and phosphorus-free flame-retardant insulated wire and halogen- and phosphorus-free flame-retardant insulated cable
US9447252B2 (en) 2014-07-07 2016-09-20 Hyundai Motor Company Polypropylene-based resin composition and method for manufacturing polypropylene composite material
CN107001765A (en) * 2014-11-12 2017-08-01 Abb瑞士股份有限公司 Electrically insulating material and the method for preparing insulating material component
WO2016074172A1 (en) * 2014-11-12 2016-05-19 Abb Technology Ltd Electrical insulating material and method for preparing insulating material element
US9951242B1 (en) 2015-03-24 2018-04-24 Autonetworks Technologies, Ltd. Electric wire coating material composition, insulated electric wire, and wire harness
JP2016181413A (en) * 2015-03-24 2016-10-13 株式会社オートネットワーク技術研究所 Composition for electric wire-coating material, insulated wire, and wire harness
WO2016152432A1 (en) * 2015-03-24 2016-09-29 株式会社オートネットワーク技術研究所 Electrical-wire covering material composition, insulated electrical wire, and wire harness
CN107406659A (en) * 2015-03-24 2017-11-28 株式会社自动网络技术研究所 Wire covering materials composition, insulated electric conductor and wire harness
CN107406659B (en) * 2015-03-24 2019-12-10 株式会社自动网络技术研究所 Wire coating material composition, insulated wire, and wire harness
CN105367972A (en) * 2015-11-18 2016-03-02 安徽雄亚塑胶科技有限公司 TPE composition and halogen-free flame retardant plug protective jacket prepared from TPE composition
EP4024413A4 (en) * 2019-08-30 2022-10-19 Sumitomo Electric Industries, Ltd. Electrically insulated cable and sensor-integrated harness
US11763964B2 (en) 2019-08-30 2023-09-19 Sumitomo Electric Industries, Ltd. Electrically insulated cable and harness integrated with sensor
CN112961417A (en) * 2021-01-16 2021-06-15 江西江缆科技有限公司 High-flexibility fireproof cable and preparation method thereof
CN115910456A (en) * 2022-11-07 2023-04-04 河南华东电缆股份有限公司 High-temperature-resistant fireproof cable and preparation method thereof
CN115910456B (en) * 2022-11-07 2023-11-14 河南华东电缆股份有限公司 High-temperature-resistant fireproof cable and preparation method thereof

Also Published As

Publication number Publication date
JPWO2008078406A1 (en) 2010-04-15
KR20090089839A (en) 2009-08-24
CN101522780A (en) 2009-09-02

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