WO2008064463A1 - Filtre de cigarette avec particules aromatisées - Google Patents

Filtre de cigarette avec particules aromatisées Download PDF

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Publication number
WO2008064463A1
WO2008064463A1 PCT/CA2007/002066 CA2007002066W WO2008064463A1 WO 2008064463 A1 WO2008064463 A1 WO 2008064463A1 CA 2007002066 W CA2007002066 W CA 2007002066W WO 2008064463 A1 WO2008064463 A1 WO 2008064463A1
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WO
WIPO (PCT)
Prior art keywords
filter
smoke
particles
enhancing
segments
Prior art date
Application number
PCT/CA2007/002066
Other languages
English (en)
Other versions
WO2008064463A8 (fr
Inventor
France Cote
Jacinthe Larochelle
Original Assignee
Imperial Tobacco Canada Limited
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Tobacco Canada Limited filed Critical Imperial Tobacco Canada Limited
Priority to EP07845536.7A priority Critical patent/EP2088877B1/fr
Priority to CA2667633A priority patent/CA2667633C/fr
Priority to PL07845536T priority patent/PL2088877T3/pl
Priority to BRPI0719373-4A priority patent/BRPI0719373B1/pt
Priority to JP2009538558A priority patent/JP2010510780A/ja
Priority to KR1020097013602A priority patent/KR101552736B1/ko
Publication of WO2008064463A1 publication Critical patent/WO2008064463A1/fr
Priority to ZA2009/02917A priority patent/ZA200902917B/en
Publication of WO2008064463A8 publication Critical patent/WO2008064463A8/fr

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Classifications

    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/04Tobacco smoke filters characterised by their shape or structure
    • A24D3/048Tobacco smoke filters characterised by their shape or structure containing additives
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/02Manufacture of tobacco smoke filters
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/02Manufacture of tobacco smoke filters
    • A24D3/0204Preliminary operations before the filter rod forming process, e.g. crimping, blooming
    • A24D3/0212Applying additives to filter materials
    • A24D3/0225Applying additives to filter materials with solid additives, e.g. incorporation of a granular product
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/02Manufacture of tobacco smoke filters
    • A24D3/0229Filter rod forming processes
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/06Use of materials for tobacco smoke filters
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/06Use of materials for tobacco smoke filters
    • A24D3/14Use of materials for tobacco smoke filters of organic materials as additive

Definitions

  • the present invention relates to a novel smoke-enhancing filter rod; a smoking article comprising said smoke-enhancing filter rod; a method for the preparation of said smoke-enhancing filter rod and of said smoking article thereof.
  • a filter cartridge is integrated to a cigarette holder.
  • Two barrels are aligned and of their ends of similar diameter, one is connected to the cigarette to be smoked, and the other to a short length of cigarette acting as a tip.
  • the filter cartridge can be impregnated with a volatile oil such as menthol or mint in order to flavor smoke, and the two barrels act as air chambers to cool it.
  • menthol and volatile oils present an unpleasant aftertaste to certain groups of customers.
  • United States patent no. 4,889,144 entitled “Filter for tobacco smoking” is based on the conception of a flavored cigarette filter.
  • the filter tip comprises a space in its middle filled with flavored-sealed particles.
  • Those flavored- sealing particles are made of a natural polysaccharide, a diluent agent as well as one or more flavor materials selected from a variety of powdered and oil-soluble flavors: some of the most popular ones are licorice, clove, cinnamon powder and vanilla, lemon, Japanese mint oil. Such encapsulation provides protection of the flavors against volatilization and deterioration.
  • the capsules In order to release the flavor, the capsules have to be broken by the smoker by the application of a force on the outer surfaces of the filter that is greater than the one normally applied when smoking, such as twisting or pressing the filter.
  • Destruction-accelerator particles which are particles such as crystalline sugars and table salt with a greater hardness than the one of the flavor particles, can be added to increase speed of the flavor particle destruction.
  • such product gives the smoker the ability to enjoy either a flavored cigarette or an original one by not breaking the flavor particles.
  • This invention can be seen as a breakthrough in the cigarette flavoring industry: however, the main problem with a filter tip comprising a cavity in its center filled with flavor particles is that very often, those particles tend to compact and that the draw resistance increases. Thus, those cigarettes tend to be difficult to smoke and customers disinterest themselves from such product.
  • Method and apparatus for incorporating objects into cigarette filters relates to the conception of a new method for mechanically incorporating individual objects in cigarette filters.
  • the resulting filter rods have objects imbedded in the web filter such as flavorant containing capsules.
  • the smoke- enhancing filter rods of the present invention are made of a filtering-zone, in which smoke-enhancing plant flavour particles are present.
  • Smoke-enhancing plant flavour particles may be embedded or inserted in a cavity in the filter.
  • the filtering zone is made of a material chosen from cellulose acetate tow, cellulose acetate web and paper. Such filter material can be dyed to conform to the color of the smoke-enhancing plant flavour particles.
  • the smoke-enhancing plant flavour particles may be flavorant plant particles chopped to a size suitable to be embedded or inserted in a cavity in said filtering zone and chosen from mint, vanilla, peppermint, anise, basil, bay leaves, cardamom, cinnamon, coriander, cumin, ginger, nutmeg, oregano, paprika, rosemary, saffron, sage, thyme, vanilla, lavender, licorice, coffee, tea, eucalyptus, clove, wintergreen, beefsteak plant, curcuma, turmeric, sandalwood, cilantro, rose, bergamot and orange blossom.
  • the mint particles may be chosen from the following mint varieties: Mentha Arventis, Mentha c.v.
  • the smoke-enhancing plant flavour particles may also be a combination of natural flavorant plant particles blended with menthol and/or essential oils and/or one or more of their constituents.
  • the smoke-enhancing plant flavour particles are prepared by finely chopping dry plant parts such as leaves and/or stems to a size of 10 to 80 meshes.
  • the smoke-enhancing filter-rod is prepared in one preferred embodiment by uniformly sprinkling a suitable amount of smoke-enhancing plant flavour particles on a tow traveling laterally on a mechanical support.
  • the tow used for the preparation of such filter is a laterally widened tow and sprinkling of the smoke-enhancing plant flavour particles is effected through passage of said tow at a certain speed under an apparatus distributing said particles.
  • the sprinkled tow is then formed into a thin rod-shaped bundle, coated with lapping paper [plugwrap] and cut into rods of predetermined size in order to produce the smoke-enhancing filter rods.
  • the resulting filter rod can either be prepared using a single segment of smoke-enhancing plant flavour particles embedded in the filter material or a combination of segments of regular filter material continuously linked with segments of smoke-enhancing embedded filter material.
  • the smoke-enhancing filter rod is also prepared, in a second preferred embodiment, by filling a cavity between two segments of regular filter material with smoke-enhancing plant flavour particles.
  • filter rod can include multiple segments some of which may contain other particles embedded therein, such as charcoal and resin among others.
  • the filter is continuously connected to a tobacco rod, a cylindrical rod of smokable filler material, by wrapping the two axially aligned parts in an end-to-end relationship with tipping material.
  • the terms 'smoking material rod' or 'smoking material' are merely intended to mean that part of the smoking article which is contained within the substantially non-combustible wrapper and should not have imported therein any association as to the combustibility or otherwise of individual components of the rod of the smoking material.
  • carbonaceous includes material which has been pyrolysed, which material preferably contains carbon, although some incomplete combustion products may still be present.
  • Ready pyrolysed coconut fibre may, for example, be the carbonaceous material from which carbon is derived.
  • the term 'smoking material means any material which can be used in a smoking article. It does not necessarily mean that the material itself will necessarily sustain combustion.
  • the smoking material is usually produced as a sheet, then cut.
  • the smoking material may then be blended with other materials to produce a smokable filler material.
  • the term "smoke-enhancing" is referring to an ability to provide improved features to the smoke of a smoking article. Such features are the result of the presence of specific particles in the filter of a smoking-device: depending on the type of particles, as smoke passes through the filter, it can be flavored, improve aftertaste's quality and/or add a refreshing taste.
  • smoke-enhancing plant flavour particles is referring to natural flavorant plant particles and to a combination of natural flavorant plant particles blended with menthol and/or essential oils.
  • flavourant is referring to the ability of smoke- enhancing plant flavour particles to flavor the smoke produced by a smoking-device as it drawn through the filter in which they are embedded which releases, produces, neutralises, masks or alters odours, for example a perfume or deodorant.
  • smoking article is referring to an apparatus for smoking tobacco comprising a rod of smokable material, such as tobacco, enclosed in a circumscribing material connected to a filter by wrapping material. Such smoking article, when lit, produces the smoke that will be drawn through the filter.
  • smoking articles include cigarettes, cigars and cigarillos.
  • Other smokable materials include reconstituted tobacco, and tobacco substitutes, and alternative smoking products in which the material is not smoked/burned as such.
  • natural flavorant plant particles is referring to particles of any plant parts having flavorant properties, which can be used in order to flavor the smoke of a smoking article.
  • Those flavoring plant parts comprise, but are not limited to, flowers, beans, fruits, leaves, stems and roots.
  • the length of the smoking material rod is advantageously at least 60 mm and the rod should preferably yield not less than six puffs, and more preferably not less than seven puffs when smoked under standard machine smoking conditions.
  • the rod is preferably of uniform cross-sectional shape and dimensions throughout the length of the rod.
  • the smoking article incorporates a filter element which may be conventional fibrous cellulose acetate, polypropylene or polyethylene material or gathered paper material. Multiple filter elements may also be utilised. Filter elements having particular pressure drop characteristics, such as the filter sold by Filtrona and known as The Ratio Filter, may also be utilised. Disposed upon or within the material of the filter element may be further flavouring materials, as described above, which are released or eluted from the filter element by the aerosol generated by the heated or burnt aerosol generation means.
  • a filter element which may be conventional fibrous cellulose acetate, polypropylene or polyethylene material or gathered paper material. Multiple filter elements may also be utilised. Filter elements having particular pressure drop characteristics, such as the filter sold by Filtrona and known as The Ratio Filter, may also be utilised. Disposed upon or within the material of the filter element may be further flavouring materials, as described above, which are released or eluted from the filter element by the aerosol generated by the heated or burnt aerosol
  • the filter element may further contain particulate material, such as granular carbon, which may suitably be activated carbon.
  • the activated carbon is activated coconut carbon.
  • the filter containing particulate material may be a dual filter comprising, for example, a cellulose acetate mouth section and a dalmatian rod at the tobacco end of the filter. A paper section may also form part of a multiple filter.
  • the filter may be the filter manufactured in accordance with the structural design of the filter known as the Active Patch filter (manufactured by Filtrona International) as described in UK Patent Specification No. 2249936.
  • the filter element may be cavity filter comprising two end sections with a central cavity containing granular material.
  • the filter element may alternatively be a selective reduction filter as described in co-pending US Provisional Patent Applications Serial Nos. 60/309,388 and 60/309,435 both filed on 1 st August 2001.
  • the mouth end located filter plug may be made from a variety of material, for example, cellulose acetate tow, cellulose, paper, cotton, polypropylene web, polypropylene tow, polyester web, polyester tow or combinations thereof.
  • the pressure drop and/or mechanical filtration efficiency of the filter plug sections can be selected to achieve the desired smoking mechanics and filtration characteristics as may be required with the specific product design desired.
  • a further filter construction that may be useful in the present invention is that described in our co-pending International Patent Application No. PCT/GB02/005603.
  • the grooved arrangement of the filter described therein provides for ventilating air to enter grooves extending towards the tobacco end and then be re-directed towards the mouth end. The result is a decrease in the CO/tar ratio.
  • particulate additives that selectively reduce vapour phases a significant reduction in vapour phase constituents can be achieved.
  • a first portion of the tobacco smoke filter comprises an adsorbent material.
  • the adsorbent material is a general adsorbent.
  • the general adsorbent material is preferably selected from a group of relatively high surface area materials, such as activated charcoal, which are capable of adsorbing a range of chemical compounds without a high degree of specificity.
  • the second portion of the smoke filter of the present invention comprises a conventional smoke filtration material.
  • Suitable conventional materials include cellulose acetate, paper, polypropylene and other materials that will be well known to persons skilled in the art and capable of retaining at least a portion of the particulate phase of smoke.
  • the first and second portions of the smoke filter of the present invention are arranged in co-axial alignment.
  • the wrapper enwrapping the smoking article may comprise a burn additive, such as sodium and/or potassium citrate, for example.
  • a burn additive such as sodium and/or potassium citrate
  • suitable burn additives such as sodium or potassium salts, such as acetate and tartrate; mono- ammonium phosphate, and di-sodium hydrogen phosphate, for example, will be known to the skilled man.
  • the burn additive is present in the range of 0.5-2.5% by weight of the wrapper.
  • the wrapper may also have a basis weight in the range of 20-40g/m 2 .
  • the wrapper of the smoking article may alternatively or in addition be a non-paper wrapper, such as the wrappers described in International Patent Applications, Publications Nos. WO 96/07336 and WO 01/41590.
  • Such wrappers assist in the reduction of sidestream smoke components, but still provide a smoking article which has burning and ashing characteristics similar to conventional products, i.e. the wrappers allow the smoking article to burn down and ash in a similar way to conventional products.
  • the wrapper may suitably be a paper wrapper or a substantially non-combustible wrapper, such as that described in WO 96/07336.
  • the subject matter of that application as it relates to the substantially non-combustible wrapper is incorporated herein by reference.
  • the wrapper thereof advantageously contains at least 65% inorganic particulate filler material, such as those inorganic materials described above.
  • a conventional cellulose pulp paper wrapper may have a permeability in the range 2-300 CU and preferably less than 100 CU. Such a wrapper may also be a low total filler paper such as disclosed in European Patent Application No. 0 404 580 and comprising less than 14% magnesium oxide or hydroxide, for example.
  • Smokable Material may have a permeability in the range 2-300 CU and preferably less than 100 CU. Such a wrapper may also be a low total filler paper such as disclosed in European Patent Application No. 0 404 580 and comprising less than 14% magnesium oxide or hydroxide, for example.
  • the smokable material is a tobacco material.
  • the tobacco material comprises one or more of stem, lamina, tobacco dust. It is preferred that the tobacco material comprises one or more of the following types: Virginia or flue-cured tobacco, Burley tobacco, Oriental tobacco, reconstituted tobacco. It is much by preference that the smokable material comprises a blend of tobacco material.
  • the smokable material comprises 10-80% Virginia tobacco, 10-60% Burley tobacco, 0-20% Oriental tobacco, 0-120% reconstituted tobacco and 0-30% expanded tobacco.
  • the smoking material of smoking articles according to the subject invention preferably comprises or consists of cut tobacco, a proportion of which tobacco may be expanded tobacco.
  • the smoking material may comprise reconstituted tobacco or tobacco substitute material.
  • the smokable filler material may also comprise a burn additive to enhance the smoking properties of the filler material.
  • the burn additive is either a burn promoter or a burn retardant.
  • Suitable burn additives may be selected from one or more of salts of Group I or Il metals such as acetates, citrates and other burn promoters known to the skilled man.
  • Suitable burn retardants include magnesium hydroxide, mono-ammonium phosphate or magnesium chloride, for example.
  • the smokable filler material may also comprise an ash improver, which is advantageously present in the filler in the range of 0-5%.
  • ash improvers include one or more of mica, perlite, clays, such as, for example, vermiculite, kaolinites, talcs, saponites, bentonites, as well as ash improvers such as disodium hydrogen orthophosphate, sodium carbonate or diammonium phosphate, for example.
  • the inorganic filler material is one or more of perlite, alumina, diatomaceous earth, calcium carbonate (chalk), vermiculite, magnesium oxide, magnesium sulphate, zinc oxide, calcium sulphate (gypsum), ferric oxide, pumice, titanium dioxide, calcium aluminate or other insoluble aluminates, or other inorganic filler materials.
  • the density range of the materials is suitably in the range of 0.1-5.7 g/cm 3 .
  • the inorganic filler material has a density that is less than 3 g/cm 3 , and preferably less than 2.5 g/cm 3 , more preferably less than 2.0 g/cm 3 and even more preferably less than 1.5 g/cm 3 .
  • An inorganic filler having a density of less than 1 g/cm 3 is desirable.
  • a lower density inorganic filler reduces the density of the product, thus improving the ash characteristics.
  • the smokable filler material may also comprise an organic filler.
  • the organic filler material is inert or relatively inert when alone i.e. will not readily maintain burning, but in a mixture may become more combustible, i.e. will maintain burning.
  • Suitable organic fillers include insoluble alginates, such as calcium or magnesium alginate, calcium pectinate or alginic acid, as well as non- modified cellulose, such as treated or non-treated wood pulp or alpha cellulose, for example. Mixtures of inert organic fillers and inorganic fillers may also be used.
  • the aerosol generating source preferably comprises aerosol forming means, such as glycerol and/or other aerosol forming compounds illustrated in our co-pending PCT Application No. WO 96/07336. These include polyhydric alcohols, propylene glycol and triethylene glycol, esters such as triethyl citrate, triacetin or triethylene glycol diacetate (TEGDA), or high boiling point hydrocarbons. Other suitable aerosol forming means will be known to those skilled in the art.
  • the binder is a mixture of alginate and non-alginate binders
  • the binder is comprised of at least 50% alginate, preferably at least 60% alginate and even more preferably at least 70% alginate.
  • the amount of combined binder required may suitably decrease when a non-alginate binder is utilised.
  • the amount of alginate in a binder combination advantageously increases as the amount of combined binder decreases.
  • Suitable alginic binders include soluble alginates, such as ammonium alginate, sodium alginate, sodium calcium alginate, calcium ammonium alginate, potassium alginate, magnesium alginate, triethanol-amine alginate and propylene glycol alginate.
  • Suitable cellulosic binders include cellulose and cellulose derivatives, such as sodium carboxymethylcellulose, methyl cellulose, hydroxypropyl cellulose, hydroxyethyl cellulose ethers.
  • Suitable gums include gum arabic, gum ghatti, gum tragacanth, Karaya, locust bean, acacia, guar, quince seed or xanthan gums.
  • Suitable gels include agar, agarose, carrageenans, furoidan and furcellaran. Starches can also be used as organic binders.
  • Other suitable gums can be selected by reference to handbooks, such as Industrial Gums, E. Whistler (Academic Press).
  • Colouring means such as food grade dyes, for example, or colourants such as liquorice, caramel or malt, or extracts thereof, may be used to darken the colour of the filler material.
  • colourants such as liquorice, caramel or malt, or extracts thereof.
  • vermiculite or other inorganic material such as iron oxide, may also give a darker colour to the filler material of the smoking article.
  • Suitable colourant materials include cocoa, liquorice, caramel, chocolate or toffee, for example. Finely ground, granulated or homogenised tobacco may also be used. Industry approved food colourants may also be used, such as E150a (caramel), E151 (brilliant black BN), E153 (vegetable carbon) or E155 (brown HT). Other casing materials may also be suitable. In the alternative, the presence of vermiculite or other inorganic filler materials may give a darker colour to the smoking material.
  • the colourant is present from 0-10% and may be as much as 5-7% by weight of the final smoking material.
  • the colourant is less than 7% preferably less than 6% and more preferably less than 5% of the final smoking material.
  • Much preferred is use of colourant at less than 4%, less than 3% and less than 2%.
  • Cocoa may suitably be present in a range of 0-5% and liquorice may be present in a range of 0-4%, by weight of the final smoking material.
  • the colourant is cocoa or liquorice, for example, the minimum amount of cocoa to obtain the desired sheet colour is about 3% and for liquorice is about 2%, by weight of the final smoking material.
  • caramel may suitably be present in a range of 0-5%, preferably less than about 2% by weight of the final smoking material, and more preferably about 1.5%.
  • suitable colourants include molasses, malt extract, coffee extract, tea resinoids, St. John's Bread, prune extract or tobacco extract. Mixtures of colourants may also be used.
  • smoke-enhancing plant flavour particles embedded or inserted in a cavity, such as mint particles, in the filter [this could be clearer, perhaps by referring simply to the particles being in the filter, with further additional possibility that they may be embedded in the filter material itself or may be provided in a cavity of the filter] providing a minty flavor and a refreshing taste and aftertaste to the smoke as it passes through it, comparatively with the overly intense taste and cooling aftertaste of the mentholated product.
  • a smoke- enhancing filter rod for use in a smoking article through connection to a tobacco rod.
  • Such smoke-enhancing filter rod comprises smoke-enhancing plant flavour particles embedded or inserted in a cavity in a filtering zone, wherein said smoke- enhancing plant flavour particles are flavorant plant particles and or a blend of flavorant plant particles with menthol and/or essential oils and/or one or more of their constituents incorporated in the filter.
  • the dried particles to be embedded in the filtering zone of the smoke-enhancing filter are chopped to a predetermined size and chosen from any mint varieties.
  • Known mint varieties include Mentha Arventis, Mentha c.v., Mentha niliaca, Mentha piperita, Mentha piperita citrata c.v., Mentha piperita c.v, Mentha spicata crispa, Mentha cardifolia, Mentha Iongifolia, Mentha suaveolens vahegata, Mentha pulegium, Mentha spicata c.v. and Mentha suaveolens.
  • the preferred mint variety used in accordance with the present invention is Mentha Arventis.
  • the type of material used for the filtering zone of the smoke-enhancing filter is chosen from any cellulose acetate tow, cellulose acetate web and paper.
  • the preferred material used in the present invention is cellulose acetate.
  • the filtering material is usually in the form of a fibrous tow, but may also be in other physical forms such as crimped sheet in the case of paper.
  • the type of smoking article to be attached to the smoke-enhancing filter can be chosen from cigarette, cigars and cigarillos.
  • the smoke-enhancing plant flavour particles consist of flavorant plant particles or flavorant plant particles blended with menthol and/or essential oils and/or one or more of their constituents.
  • the main aim associated with the use of plant particles in the smoke-enhancing filter rods instead of artificial purified agents is to provide the consumers with natural flavorant agents, in combination or not with menthol and/or essential oils and/or one or more of their constituents, and thus a product with a refreshing taste and improved aftertaste.
  • the plant particles comprise every usable part of a chosen plant such as the roots, leaves, flowers, stems or buds. They are collected, dried and mechanically chopped to a suitable size to be embedded in the filter rod.
  • the preferred humidity percentage of the particles to be incorporated being from 10 % to 20 %, whereas the normal degree of humidity of a cigarette being from 10 to 14 % obtained by either drying or not.
  • natural mint particles are being used for flavoring the smoke.
  • Various studies comparing the use of natural mint particles in a filter of a smoking-device were conducted to compare the smoking article with a commercially available menthol cigarette. First, studies on loading, flavor retention and overall taste in a prolonged amount of time of natural greenhouse and field mint particles when incorporated in a filter were conducted. Those tests demonstrated that natural mint particles presented different flavoring properties than the already marketed flavoring products.
  • smoke tests established that the characteristic taste and aftertaste of natural mint, which is the result of a combination of a multitude of components is providing a refreshing taste and improved aftertaste compared to a strong cooling effect of a current menthol product.
  • Flavorant particles can be incorporated in a filter rod through various techniques: the particles can be contained within a cavity in the filter rod or applied on and/or in the filter material.
  • "Dalmatian-filters” may be made according to known techniques.
  • “Dalmatian-filters” consist of filtering material through which smoke- enhancing plant flavour particles have been sprinkled before it has been folded and wrapped in wrapping material.
  • Various steps are needed to lead to the conception of such filter: first, the filter material is wound in a roll from which it is continuously drawn. The laterally widened, flat material is brought to a smoke-enhancing particle dispersing section by a mechanical support.
  • a hopper is provided above the rotary dispersion roller and a guide case is provided in front of it.
  • the smoke-enhancing plant flavour particles fed in the hopper are uniformly applied to the filter material that is being continuously fed below the rotary dispersion roller.
  • the filter material on which smoke-enhancing plant flavour particles are sprinkled can be dyed for aesthetic reasons.
  • the filter material is brought to a second section wherein the folding operation is effected.
  • a filter material folding section is used to fold the filter material.
  • a retainer plate projecting from the machine body is provided horizontally through a gap corresponding to a thickness of the filter material above another upper surface of a receiving plate projecting from the same machine body.
  • a pair of curved rods obliquely closed to each other on the front side of the retainer space are provided on a mount rod projecting from the machine body.
  • a curved portion of each rod is provided in order to depress downwardly both edge portions of the filter material.
  • a pair of clamping thin plates are provided on both sides on the upper surface of the retainer plate for clamping, folding and gathering at the center the edge portions, downwardly depressed and inwardly pressed by the curved portions of the curved rods.
  • the clamping thin plates are arranged so as to intersect with each other, the distance between the clamping plates and the retainer plate is increased toward the rear side and the opposite edge portions are drawn inwardly to each other by the feed of the material.
  • the edge portions are overlapped to form the overlapping portion which is fed in this state. Accordingly, the opposite edge portions of the filter material lap the smoke-enhancing plant flavour particles, which is led to the sleeve portion of the forming section.
  • the filter material After introduction of the filter material into the sleeve portion, it is gathered into a thin rod shaped-bundle containing the embedded particles and subsequently coated with a lapping paper (plug wrap), porous or non-porous. Thereafter, the filter is cut into rods of predetermined length in the cutter section.
  • a lapping paper plug wrap
  • Filters can also be configured as a combination of segments of various filter materials, physical forms and/or composition wherein smoke- enhancing plant flavour particles are present in different locations along the length of the rod.
  • Such construction can provide various advantages compared to the regular "dalmatian filter” in terms of general appearance, resistance to draw.
  • These particular filter rods are made of two types of segments present in alternation in the rod and maintained together by lapping paper. Indeed, a combination of two to five segments of either filter material embedded with flavorant particles or regular filter material are continuously connected in the rod and, depending on the total number of segments, are known as “dual-dalmatian filter", “triple-dalmatian filter”, “quadruple-dalmatian filter” and “quintuple-dalmatian filter”.
  • the filters may be symmetrical, when the segments are all of the same size, or asymmetrical, when two or more of the segments are of different lengths.
  • the first type of segmented filter rods is the "dual-dalmatian filter” comprising a segment of smoke-enhancing plant flavour particles embedded filter material as well as a segment of regular filter material.
  • the segment of the filter located adjacent to tobacco rod is the segment comprising embedded smoke- enhancing plant flavour particles in order to flavor the smoke being drawn through, whereas the segment located at mouth end is made of regular filter material, produced exactly as the "dalmatian-filter” but without the step consisting of sprinkling smoke-enhancing plant flavour particles.
  • regular filter material produced exactly as the "dalmatian-filter” but without the step consisting of sprinkling smoke-enhancing plant flavour particles.
  • a second configuration of segmented filter rods consists of "triple- dalmatian filter rods".
  • This type of filter comprising two or three different segments, one configuration option is as follows: the segments adjacent to the tobacco rod and to the mouth end are both made of regular filter material whereas the segment located between the later two is made of filter material embedded with smoke- enhancing plant flavour particles. Therefore, the smoke is flavored as it passes through the filter and the appearance of the product is the same as the one of regular cigarettes.
  • Another filter configuration is a triple-dalmatian filter where the mouth end segment is a regular filter, the middle segment is embedded with mint particles and the tobacco rod segment is embedded with charcoal and/or resin particles among others.
  • the "cavity filter” constitutes an alternative for the flavoring of the smoke as it is conceived as a filter rod comprising 2 segments separated by a cavity containing smoke-enhancing plant flavour particles. Therefore, instead of two regular segments separated by a particles embedded segment, the segments are separated by pure free smoke-enhancing plant flavour particles inserted in a cavity in the filter. Such construction is again appealing for consumers because the product has the same appearance as regular cigarettes and has interesting flavoring properties.
  • “Quadruple-dalmatian filter” and “quintuple-dalmatian filter” are filter rods having a configuration option in accordance with one embodiment of the present invention consisting of an alternation of four or five segments of regular filter material and of filter material embedded with smoke-enhancing plant flavour particles.
  • the various segments are disposed in the filter rod in such an order that a segment of regular filter material is present at the mouth end.
  • the presence of a multitude of segments in the filter rod makes it possible to present consumers with a variety of products.
  • the various segments embedded with smoke-enhancing plant flavour particles can be prepared using either a variety or identical smoke- enhancing plant flavour particles and/or charcoal and resin, among others. Therefore, the resulting product can present a smoke that is more concentrated in flavor or a smoke characterized by a blend of flavors, thus permitting better modulation of its taste and aftertaste.
  • the smoking article is prepared by filling a cylindrical open-ended rod with smokable filler material.
  • smokable filler material normally consists of a blend of shredded tobacco which composition can vary, the existing varieties being flue-cured, burley, Oriental, Maryland, dark, dark- fired and Rustica tobaccos as well as rare and specialty tobacco.
  • the circumscribing wrapping material of the tobacco rod can vary in composition and properties.
  • One end of the tobacco rod is the lighting end whereas the other one is adapted to be linked to the filter.
  • the filter and the tobacco rod are prepared with similar diameter and are axially aligned in an end-to-end relationship before being attached to one another by tipping material. Filter ventilation can be done through preperforated tipping or laser perforation on line.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Cigarettes, Filters, And Manufacturing Of Filters (AREA)
  • Manufacturing Of Cigar And Cigarette Tobacco (AREA)

Abstract

L'invention concerne une tige de filtre améliorant la fumée qui comprend : (1) une zone de filtrage ; et (2) des particules d'arôme de plante améliorant la fumée présentes dans ladite zone de filtrage.
PCT/CA2007/002066 2006-11-29 2007-11-16 Filtre de cigarette avec particules aromatisées WO2008064463A1 (fr)

Priority Applications (7)

Application Number Priority Date Filing Date Title
EP07845536.7A EP2088877B1 (fr) 2006-11-29 2007-11-16 Filtre de cigarette avec particules aromatisées
CA2667633A CA2667633C (fr) 2006-11-29 2007-11-16 Filtre de cigarette avec particules aromatisees
PL07845536T PL2088877T3 (pl) 2006-11-29 2007-11-16 Filtr papierosowy z aromatyzowanymi cząstkami
BRPI0719373-4A BRPI0719373B1 (pt) 2006-11-29 2007-11-16 Haste de filtro melhoradora de fumaça, artigo para fumar, e, método para produzir hastes de filtro melhoradoras de fumaça
JP2009538558A JP2010510780A (ja) 2006-11-29 2007-11-16 風味が付与された粒子を有する紙巻きタバコ用フィルター
KR1020097013602A KR101552736B1 (ko) 2006-11-29 2007-11-16 향미 입자를 보유한 궐련 필터
ZA2009/02917A ZA200902917B (en) 2006-11-29 2009-04-28 Cigarette filter with flavored particles

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US86765206P 2006-11-29 2006-11-29
US60/867,652 2006-11-29

Publications (2)

Publication Number Publication Date
WO2008064463A1 true WO2008064463A1 (fr) 2008-06-05
WO2008064463A8 WO2008064463A8 (fr) 2009-07-16

Family

ID=39467378

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CA2007/002066 WO2008064463A1 (fr) 2006-11-29 2007-11-16 Filtre de cigarette avec particules aromatisées

Country Status (13)

Country Link
EP (1) EP2088877B1 (fr)
JP (3) JP2010510780A (fr)
KR (1) KR101552736B1 (fr)
AR (1) AR064042A1 (fr)
BR (1) BRPI0719373B1 (fr)
CA (1) CA2667633C (fr)
CO (1) CO6210714A2 (fr)
MY (1) MY160632A (fr)
PL (1) PL2088877T3 (fr)
RU (1) RU2462964C2 (fr)
TR (1) TR201815890T4 (fr)
WO (1) WO2008064463A1 (fr)
ZA (1) ZA200902917B (fr)

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2299854A1 (fr) * 2008-04-15 2011-03-30 Pt Hanjaya Mandala Sampoerna Tbk. Filtre pour article à fumer
CN102448334A (zh) * 2009-05-26 2012-05-09 菲尔特隆纳过滤产品开发私人有限公司 烟草烟雾过滤嘴
CN103622157A (zh) * 2012-12-29 2014-03-12 广东中烟工业有限责任公司 一种复合草本植物的三元烟草纤维纸质滤棒及其制备方法
CN103841844A (zh) * 2011-10-07 2014-06-04 菲利普莫里斯生产公司 多段式发烟制品
CN103841845A (zh) * 2011-10-07 2014-06-04 菲利普莫里斯生产公司 多段式发烟制品
CN104388192A (zh) * 2014-12-03 2015-03-04 湖北中烟工业有限责任公司 用于女士烟的玫瑰型香精及其应用
US9282766B2 (en) 2010-12-13 2016-03-15 Philip Morris Products S.A. Smoking article including flavour granules
EP2967131A4 (fr) * 2013-03-14 2016-11-09 Celanese Acetate Llc Appareils, systèmes et procédés associés pour former des masses poreuses organiques pour des filtres à fumée aromatisés
US9833021B2 (en) 2014-10-02 2017-12-05 Digirettes, Inc. Disposable tank electronic cigarette, method of manufacture and method of use
CN107568787A (zh) * 2017-09-04 2018-01-12 云南中烟工业有限责任公司 一种增香降温基棒
RU2665672C2 (ru) * 2012-12-13 2018-09-03 Джапан Тобакко Инк. Сигарета
CN110982625A (zh) * 2019-12-29 2020-04-10 亿利耐雀生物科技有限公司 一种香烟滤嘴用甘草味干珠及其制备方法
CN113338079A (zh) * 2021-06-16 2021-09-03 云南中烟工业有限责任公司 一种分段赋色加香纸、其制备方法和用于卷烟纸的用途
CN114403499A (zh) * 2021-12-13 2022-04-29 江苏大亚滤嘴材料有限公司 一种风味香精及其应用于空管滤棒加香

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0820229D0 (en) * 2008-11-05 2008-12-10 British American Tobacco Co Filter for a smoking article
EP2401929A1 (fr) * 2010-06-30 2012-01-04 Philip Morris Products S.A. Filtre pour article à fumer
CN102423133A (zh) * 2011-08-28 2012-04-25 云南烟草科学研究院 薄荷叶在二元复合滤嘴中的应用
CN102302221A (zh) * 2011-08-28 2012-01-04 云南烟草科学研究院 玫瑰花和薄荷叶在二元复合滤嘴中的应用
WO2016151681A1 (fr) * 2015-03-20 2016-09-29 日本たばこ産業株式会社 Filtre de cigarette et cigarette
JP2017136084A (ja) * 2017-04-05 2017-08-10 日本たばこ産業株式会社 シガレット
GB201805949D0 (en) 2018-04-10 2018-05-23 British American Tobacco Investments Ltd Smoking article
US11432581B2 (en) 2018-09-07 2022-09-06 Altria Client Services Llc Capsule containing a matrix, device with the matrix, and method of forming the matrix
CN108991596B (zh) * 2018-10-11 2020-07-28 玉溪开元金蓝生物科技有限责任公司 复方滇橄榄添加料、制备方法及其在香烟滤嘴棒上的应用
KR102445558B1 (ko) * 2020-07-06 2022-09-20 주식회사 케이티앤지 고체풍미제를 포함하는 흡연물품용 필터 및 그의 제조 방법

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3771534A (en) 1971-09-30 1973-11-13 O Kuehne Combination filter and cigarette holder
US3972335A (en) 1972-09-20 1976-08-03 Calgon Corporation Mentholated cigarette filter
EP0058463A1 (fr) * 1981-02-18 1982-08-25 Gist-Brocades N.V. Filtre pour la fumée de tabac
US4889144A (en) * 1987-05-29 1989-12-26 Japan Tobacco Inc. Filter for tobacco smoking
US20060213533A1 (en) * 1997-12-24 2006-09-28 Imam Emami Use of polyphenol compounds or derivatives thereof as free-radical scavengers in cigarette filters

Family Cites Families (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3319630A (en) * 1964-06-29 1967-05-16 Norman B Orrmins Tobacco smoke filter
US3603319A (en) * 1968-12-13 1971-09-07 Philip Morris Inc Flavor-releasing smoking article and method of making the same
GB2020158B (en) * 1978-04-21 1982-11-24 Cigarette Components Ltd Production of tobacco smoke filters
DE3114542A1 (de) * 1981-04-10 1982-12-30 Günter 2211 Wrist Pruss Stimulans - rauchtabakfilter
JPS58205490A (ja) * 1982-05-26 1983-11-30 小林 幸三 お茶いりタバコフイルタ−
JPS5911171A (ja) * 1982-07-08 1984-01-20 菅間 厚 タバコに風味を持たせるフイルタ−
JPS62162995U (fr) * 1986-04-07 1987-10-16
US5360023A (en) * 1988-05-16 1994-11-01 R. J. Reynolds Tobacco Company Cigarette filter
JPH02127194U (fr) * 1989-03-29 1990-10-19
JP2946236B2 (ja) * 1990-10-24 1999-09-06 株式会社三條機械製作所 タバコフィルターロッドの製造法及びその製造装置
JPH08266261A (ja) * 1995-03-30 1996-10-15 Hideki Kamiya 紙巻きタバコ
DE19524197C2 (de) * 1995-07-03 1997-09-04 Johann Fertl Verfahren zur Herstellung von Zigaretten
JP3802960B2 (ja) * 1997-02-10 2006-08-02 ダイセル化学工業株式会社 タバコフィルターおよびその製造方法
US5996589A (en) * 1998-03-03 1999-12-07 Brown & Williamson Tobacco Corporation Aerosol-delivery smoking article
EP1442667A4 (fr) * 2001-10-30 2005-11-02 Japan Tobacco Inc Filtre pour cigarette et cigarette avec filtre
JP3974898B2 (ja) * 2001-12-28 2007-09-12 日本たばこ産業株式会社 喫煙物品
CN1451326A (zh) * 2002-04-13 2003-10-29 梁永林 一种卷烟滤嘴棒
WO2004074449A2 (fr) 2003-02-18 2004-09-02 Filligent Limited Filtre contenant une phtalocyanine metallique et un polymere polycationique
TWI279195B (en) * 2004-03-16 2007-04-21 Japan Tobacco Inc Filter rod making machine
ITBO20040202A1 (it) * 2004-04-08 2004-07-08 Gd Spa Metodo e macchina per il confezionamento di filtri per articoli da fumo
US20070000505A1 (en) * 2005-02-24 2007-01-04 Philip Morris Usa Inc. Smoking article with tobacco beads

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3771534A (en) 1971-09-30 1973-11-13 O Kuehne Combination filter and cigarette holder
US3972335A (en) 1972-09-20 1976-08-03 Calgon Corporation Mentholated cigarette filter
EP0058463A1 (fr) * 1981-02-18 1982-08-25 Gist-Brocades N.V. Filtre pour la fumée de tabac
US4889144A (en) * 1987-05-29 1989-12-26 Japan Tobacco Inc. Filter for tobacco smoking
US20060213533A1 (en) * 1997-12-24 2006-09-28 Imam Emami Use of polyphenol compounds or derivatives thereof as free-radical scavengers in cigarette filters

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP2088877A4

Cited By (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2299854A1 (fr) * 2008-04-15 2011-03-30 Pt Hanjaya Mandala Sampoerna Tbk. Filtre pour article à fumer
CN102448334A (zh) * 2009-05-26 2012-05-09 菲尔特隆纳过滤产品开发私人有限公司 烟草烟雾过滤嘴
US9282766B2 (en) 2010-12-13 2016-03-15 Philip Morris Products S.A. Smoking article including flavour granules
CN103841844A (zh) * 2011-10-07 2014-06-04 菲利普莫里斯生产公司 多段式发烟制品
CN103841845A (zh) * 2011-10-07 2014-06-04 菲利普莫里斯生产公司 多段式发烟制品
US10226068B2 (en) 2011-10-07 2019-03-12 Philip Morris Products S.A. Multi-segment smoking article
TWI551225B (zh) * 2011-10-07 2016-10-01 菲利浦莫里斯製品股份有限公司 多段煙品以及製造可吸材料之多段煙草桿之方法
TWI562736B (en) * 2011-10-07 2016-12-21 Philip Morris Products Sa Multi-segment smoking article and method for producing a multi-segmented tobacco rod of smokable material
RU2665672C2 (ru) * 2012-12-13 2018-09-03 Джапан Тобакко Инк. Сигарета
CN103622157A (zh) * 2012-12-29 2014-03-12 广东中烟工业有限责任公司 一种复合草本植物的三元烟草纤维纸质滤棒及其制备方法
CN103622157B (zh) * 2012-12-29 2015-03-18 广东中烟工业有限责任公司 一种复合草本植物的三元烟草纤维纸质滤棒及其制备方法
EP2967131A4 (fr) * 2013-03-14 2016-11-09 Celanese Acetate Llc Appareils, systèmes et procédés associés pour former des masses poreuses organiques pour des filtres à fumée aromatisés
USD805687S1 (en) 2014-10-02 2017-12-19 Digirettes, Inc. Vaping device tank
USD805686S1 (en) 2014-10-02 2017-12-19 Digirettes, Inc. Vaping device
US9833021B2 (en) 2014-10-02 2017-12-05 Digirettes, Inc. Disposable tank electronic cigarette, method of manufacture and method of use
US10278428B2 (en) 2014-10-02 2019-05-07 Digirettes, Inc. Disposable tank electronic cigarette, method of manufacture and method of use
US10299513B2 (en) 2014-10-02 2019-05-28 Digirettes, Inc. Disposable tank electronic cigarette, method of manufacture and method of use
USD857985S1 (en) 2014-10-02 2019-08-27 Digirettes, Inc. Vaping device
USD863676S1 (en) 2014-10-02 2019-10-15 Digirettes, Inc. Vaping device tank
CN104388192A (zh) * 2014-12-03 2015-03-04 湖北中烟工业有限责任公司 用于女士烟的玫瑰型香精及其应用
CN107568787A (zh) * 2017-09-04 2018-01-12 云南中烟工业有限责任公司 一种增香降温基棒
CN110982625A (zh) * 2019-12-29 2020-04-10 亿利耐雀生物科技有限公司 一种香烟滤嘴用甘草味干珠及其制备方法
CN113338079A (zh) * 2021-06-16 2021-09-03 云南中烟工业有限责任公司 一种分段赋色加香纸、其制备方法和用于卷烟纸的用途
CN114403499A (zh) * 2021-12-13 2022-04-29 江苏大亚滤嘴材料有限公司 一种风味香精及其应用于空管滤棒加香

Also Published As

Publication number Publication date
EP2088877B1 (fr) 2018-08-01
ZA200902917B (en) 2010-02-24
RU2009124595A (ru) 2011-01-10
CA2667633A1 (fr) 2008-06-05
JP2013226156A (ja) 2013-11-07
JP2015142576A (ja) 2015-08-06
MY160632A (en) 2017-03-15
JP2010510780A (ja) 2010-04-08
EP2088877A1 (fr) 2009-08-19
TR201815890T4 (tr) 2018-11-21
AR064042A1 (es) 2009-03-11
BRPI0719373A2 (pt) 2014-06-03
PL2088877T3 (pl) 2019-02-28
CO6210714A2 (es) 2010-10-20
KR20090112642A (ko) 2009-10-28
BRPI0719373B1 (pt) 2022-05-10
WO2008064463A8 (fr) 2009-07-16
RU2462964C2 (ru) 2012-10-10
EP2088877A4 (fr) 2013-08-21
KR101552736B1 (ko) 2015-09-11
CA2667633C (fr) 2013-01-08

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