WO2008037374A2 - Verbesserung der biologischen wirkung von agrochemischen zusammensetzungen bei applikation in das kultursubstrat, geeignete formulierungen und ihre anwendung - Google Patents
Verbesserung der biologischen wirkung von agrochemischen zusammensetzungen bei applikation in das kultursubstrat, geeignete formulierungen und ihre anwendung Download PDFInfo
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- WO2008037374A2 WO2008037374A2 PCT/EP2007/008096 EP2007008096W WO2008037374A2 WO 2008037374 A2 WO2008037374 A2 WO 2008037374A2 EP 2007008096 W EP2007008096 W EP 2007008096W WO 2008037374 A2 WO2008037374 A2 WO 2008037374A2
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
- A01N37/30—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof containing the groups —CO—N< and, both being directly attached by their carbon atoms to the same carbon skeleton, e.g. H2N—NH—CO—C6H4—COOCH3; Thio-analogues thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/08—Oxygen or sulfur directly attached to an aromatic ring system
- A01N31/14—Ethers
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/12—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group, wherein Cn means a carbon skeleton not containing a ring; Thio analogues thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
- A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
- A01N41/10—Sulfones; Sulfoxides
Definitions
- the present invention relates to the improvement of the action of agrochemical compositions in soil application, the agrochemical compositions suitable for this application, and their use for control of noxious insects.
- Agrochemical active substances can be applied in different ways for controlling harmful organisms.
- a treatment of the culture substrate can also be carried out.
- This may be soil, but also special substrates u.a. based on peat moss, coconut fiber, rock wool, e.g. Grodan®, pumice, expanded clay, e.g. Lecaton® or Lecadan®, clay granules, e.g. Seramis®, foams, e.g. Baystrat®, vermiculite, perlite, man-made earth, e.g. Hygromull®, or combinations of these substrates. All of these culture substrates are referred to below as soil.
- both soil-borne pests are brought into contact with the active ingredient and the uptake of systemic agents by the roots is initiated.
- tools known to improve the effect of agrochemical drugs in foliar treatment include, for example, penetration enhancers which facilitate penetration of the active ingredients into the plant (e.g., WO 03/000053).
- Corresponding adjuvants have not yet been described for the soil applications of insecticides and fungicides.
- Soil Penetration Aids which accelerate the penetration of irrigation water into dry soils (e.g., Agri-Prep® CS from Northwest Agricultural Products).
- compositions of this invention contain an adjuvant.
- the adjuvant may either be already part of the concentrated formulation (in-can formulation) or added in the course of the preparation of the ready-to-use pesticide solution (tank mix application).
- the improved effect occurs both in the control of soil organisms and in the control of leaf pests or leaf diseases caused by the systemic Active ingredients are combated. """In this way, the application rate an improved effect can be achieved by the compositions of this invention can be reduced to active substance or the same application rate. In addition, the water consumption can be minimized.
- the subject of the present invention is therefore the use of adjuvants to improve the action of soil agrochemical compositions, e.g. by spraying on the floor, casting, side-dressing, shower-drenching, overhead drenching or application as part of an irrigation system (drip irrigation).
- adjuvants to improve the action of soil agrochemical compositions, e.g. by spraying on the floor, casting, side-dressing, shower-drenching, overhead drenching or application as part of an irrigation system (drip irrigation).
- the invention also relates to dilute, ready-to-use compositions.
- the invention furthermore relates to the use of these compositions for combating soil-borne harmful organisms and leaf pests.
- An adjuvant in the context of the present invention is a substance which causes an improvement in the biological activity in the test system described below:
- the same test is performed without the addition of a potential adjuvant.
- the adjuvant according to the invention shows in this test increased mortality compared to the control.
- the mortality is not necessarily increased at any time, it can also only an improvement of the initial effect or the
- compositions containing dioctyl sodium sulfosuccinate and sodium benzoate available commercially, e.g. in the Aerosol® product line; preferably that is
- compositions comprising corn syrup, methylated soybean oil and nonionic emulsifier, commercially available e.g. in the Süperb® product range.
- Phthalic diamides are known as compounds having insecticidal properties (cf., EP-A-0 919 542, EP-A-006 107, WO 01/00575, WO 01/00599, WO 01/46124, JP-A 2001-33 555 9, WO 01/02354, WO 01/21 576, WO 02/08 8074, WO 02/08 8075, WO 02/09 4765, WO 02/09 4766, WO 02/06 2807).
- Such phthalic diamides are described by the formula (II):
- X B is halogen, cyano, Q-Cg-alkyl, C r C 8 haloalkyl, C r C 8 -alkoxy or C r C 8 - haloalkoxy,
- R 1B , R 2B and R 3B are independently hydrogen, cyano, optionally substituted by
- M represents optionally substituted achiral Cj-Cn-alkylene, achiral C 3 -C 2 alkenylene or C 3 -C achiral is 2 alkynylene,
- Q B is hydrogen, halogen, cyano, nitro, C r C 8 haloalkyl, each optionally substituted C 3 -C 8 -Cyloalkyl, Ci-Cg--alkyl-carbonyl or Ci-Cg-alkoxy-carbonyl, 4B respectively T ⁇ _R optionally substituted phenyl, hetaryl or represents the group,
- T B is oxygen, -S (O) n , - or -N (R 5B > -,
- R 4B represents hydrogen, in each case optionally substituted d-Cu-alkyl, C 3 -C 2 -alkenyl, C 3 - C n -alkynyl, C 3 -C 8 cycloalkyl, C 3 -C 8 cycloalkyl-C, -C 6 -alkyl, C 1 -C 6 -alkoxy-C 1 -C 4 -alkyl, C 1 -C 4 -alkylcarbonyl, C 1 -C 8 -alkoxycarbonyl, phenyl, phenyl-C 1 -C 12 -alkyl, phenylC r C 4 -alkoxy, hetaryl, hetaryl-C r C 4 -alkyl,
- R 5B is hydrogen, each optionally substituted Q-Cg-alkyl-carbonyl, C] -C 8 -alkoxycarbonyl, phenyl-carbonyl] or phenyl-Cj-C 6 -alkoxycarbonyl, k is 1, 2, 3, or 4,
- n 0, 1 or 2
- R 1B and R 28 together form an optionally substituted 4- to 7-membered ring which may optionally be interrupted by heteroatoms,
- L 1B and L 3B are independently hydrogen, halogen, cyano or in each case optionally substituted C r C 8 alkyl, C, -C 8 alkoxy, Ci-C 6 alkyl -S (O) m -, phenyl, phenoxy or Hetaryloxy stand,
- L 28 is hydrogen, halogen, cyano, optionally substituted C r Ci 2 -alkyl, C 2 - C] 2 alkenyl, C2-Ci2 alkynyl, C r C] 2 haloalkyl, C 3 -C 8 - cycloalkyl, phenyl, hetaryl M2B_ R 6B or the group M is ⁇ ,
- M 2B is oxygen or -S (O) n , -,
- R 6B is in each case optionally substituted C 1 -C 8 -alkyl, C 2 -C 8 -alkenyl, C 3 -C 6 -alkynyl C 3 -C 9 -cycloalkyl, phenyl or hetaryl,
- L 1B and L 3B or L IB and L 2B each together form an optionally substituted 5- to 6-membered ring which may optionally be interrupted by heteroatoms,
- the phthalic diamides of the acaricidal and / or insecticidal agents are generally defined by the formula (II). Preferred substituents or ranges of the radicals listed in the formulas mentioned above and below are explained below:
- X B is preferably fluorine, chlorine, bromine, iodine, cyano, C r C 6 alkyl, C r C 6 haloalkyl, C 1 - C ⁇ -alkoxy or Ci-C 6 haloalkoxy.
- R IB , R 2B and R 3B independently of one another preferably represent hydrogen, cyano, for
- M 1B preferably represents achiral C r C 8 -alkylene, achiral C 3 -C 6 -alkenylene or achiral C 3 - C 6 -alkynylene.
- Q B preferably represents hydrogen, halogen, cyano, nitro, C r C 6 haloalkyl or optionally substituted by fluorine, chlorine, Ci-C 6 alkyl, or C) -C 6 -alkoxy-substituted C 3 -C 8 - cycloalkyl, in which optionally one or two not directly adjacent ring members are replaced by oxygen and / or sulfur or for each optionally substituted by halogen C r C 6 alkylcarbonyl or C r C 6 alkoxycarbonyl or in each case optionally by halogen, Ci-C 6 alkyl, C r C 6 -Haloalkyl, C r C 6 alkoxy, C r C 6 - haloalkoxy, cyano or nitro-substituted phenyl or hetaryl having 5 to 6 ring atoms (for example, furanyl, pyridyl, imidazolyl, triazolyl, pyrazo
- T B is preferably oxygen, -S (O) n , - or -N (R 5B > -.
- R 4B preferably represents hydrogen, in each case optionally fluorine- and / or chlorine-substituted C 1 -C 8 -alkyl, C 3 -C 8 -alkenyl, C 3 -C 8 -alkynyl, C 3 -C 8 -cycloalkyl, C 3 -C 8 - cycloalkyl-Ci-C 2 alkyl, QC ö alkyl-carbonyl, C] -C6 alkoxy-carbonyl, represents in each case optionally mono- to tetrasubstituted by halogen, C] -C6 alkyl, Ci C ⁇ alkoxy, C 1 -C 4 - haloalkyl, C
- R 5B preferably represents hydrogen, in each case optionally substituted by fluorine and / or chlorine Ci-C ⁇ -alkyl-carbonyl, Ci-C ⁇ -alkoxycarbonyl, in each case optionally monosubstituted to fourfold by halogen, C r C 6 alkyl, Ci -C 6 -alkoxy, C r C 4 -haloalkyl, C r
- k is preferably 1, 2 or 3.
- n is preferably 0, 1 or 2.
- R IB and R 2B together preferably form a 5- to 6-membered ring which may optionally be interrupted by an oxygen or sulfur atom.
- IB L and L 3B are each independently preferably represents hydrogen, cyano, fluorine, chlorine, bromine, iodine, C r C 6 alkyl, C r C 4 haloalkyl, C r C 6 alkoxy, C r C 4 haloalkoxy, C r C 4 - alkyl-S (O) m -, C 4 haloalkyl-S (O) m -, in each case optionally mono- to trisubstituted by fluorine, chlorine, bromine, C r C 6 alkyl, C -C 6 alkoxy, C, -C 4 haloalkyl, C 1 -C 4 - haloalkoxy, cyano or nitro-substituted phenyl, phenoxy, Pyrdinyloxy, thiazolyloxy or pyrimidinyloxy.
- L 2B preferably represents hydrogen, fluorine, chlorine, bromine, iodine, cyano, in each case optionally substituted by fluorine and / or chlorine-substituted Ci-Cio-alkyl, C 2 -C 10 alkenyl, C 2 -C 6 - alkynyl, for in each case optionally substituted by fluorine, chlorine-substituted C 3 -C 6 cycloalkyl, in each case optionally mono- to trisubstituted by fluorine, chlorine, bromine, Ci-C 6 alkyl, CpC 6 - alkoxy, C r C 4 haloalkyl, CpC 4 - Haloalkoxy, cyano or nitro substituted M?
- B_ R 6B preferably represents hydrogen, fluorine, chlorine, bromine, iodine, cyano, in each case optionally substituted by fluorine and / or chlorine-substituted Ci-Cio-alky
- M 2B is preferably oxygen or -S (O) n , -.
- R 6B preferably represents in each case optionally fluorine- and / or chlorine-substituted Cp
- L 1B and L 3B or L 1B and L 2B together preferably each form a 5- to 6-membered ring which is optionally substituted by fluorine and / or CpC 2 -alkyi and which may optionally be interrupted by one or two oxygen atoms.
- X B particularly preferably represents chlorine, bromine and iodine.
- R 1B , R 2B and R 3B independently of one another particularly preferably represent hydrogen or
- M 1B particularly preferably represents achiral CpCg-alkylene, achiral C 3 -C 6 -alkenylene or achiral C 3 -C 6 -alkynylene.
- Q B particularly preferably represents hydrogen, fluorine, chlorine, cyano, trifluoromethyl, C 3 -C 6 -
- T B particularly preferably represents oxygen or -S (O) n , -.
- R 4B particularly preferably represents hydrogen, in each case optionally mono- to trisubstituted by fluorine and / or chlorine, CpC 6 alkyl, C 3 -C 6 alkenyl, C 3 -C 6 alkynyl or
- k is particularly preferred for 1. 2 or 3.
- L 1B and L 3B independently of one another particularly preferably represent hydrogen, fluorine, chlorine,
- L 2B particularly preferably represents hydrogen, fluorine, chlorine, bromine, iodine, cyano, in each case optionally monosubstituted to trisubstituted by fluorine and / or chlorine, C 1 -C 6 -MB R 6B
- Alkyl C 2 -C 6 -alkenyl, C 2 -C 6 -alkynyl, C 3 -C 6 -cycloalkyl or for the group M ⁇ .
- M 2B is particularly preferably oxygen or -S (O) n , -.
- R 6B particularly preferably represents in each case optionally monosubstituted to trisubstituted by fluorine and / or chlorine QC ö alkyl, C 2 -C 6 alkenyl, C 2 -C ⁇ alkynyl or C 3 -C 6 - cycloalkyl, in each case optionally mono- to disubstituted by fluorine, chlorine, bromine, Q C 4 alkyl, C r C 4 alkoxy, trifluoromethyl, difluoromethoxy, trifluoromethoxy, cyano or nitro-substituted phenyl or pyridyl.
- X B is most preferably iodine.
- R 1B and R 2B are very particularly preferably hydrogen.
- R 3B most preferably represents the group.
- M ' B is very particularly preferably -C (CH 3 ) 2 CH 2 - or -C (C 2 Hj) 2 CH 2 -
- Q B is very particularly preferably hydrogen, fluorine, chlorine, cyano, trifluoromethyl, C 3 - TB_ R 4B C 6 -cycloalkyl or the group ' ⁇ .
- T B is very particularly preferably -S-, -SO- or -SO 2 -.
- R 4B very particularly preferably represents in each case optionally mono- to trisubstituted by fluorine and / or chlorine, methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, sec-butyl or tert-butyl, allyl, Butenyl or isoprenyl.
- L 1 B and L 3B very particularly preferably represent hydrogen, fluorine, chlorine, bromine, iodine, cyano, methyl, ethyl, n-propyl, isopropyl, tert-butyl, methoxy, ethoxy, trifluoromethyl, difluoromethoxy or trifluoromethoxy
- L stands g anz particularly Favor g t represents hydrogen, fluorine, chlorine, bromine, iodine, cyano, represents in each case optionally substituted once to nine times by fluorine and / or chlorine-substituted methyl, ethyl, n-propyl, iso-propyl, n-butyl, iso-butyl, sec-butyl, tert-butyl, AHyI, M2B "6B
- Butenyl or isoprenyl or for the group m butenyl or isoprenyl or for the group m .
- M is most preferably oxygen or sulfur.
- R 6B very particularly preferably stands for in each case optionally up to nine times
- compositions according to the invention may preferably also contain further formulation auxiliaries:
- At least one nonionic surfactant and / or at least one anionic surfactant one or more additives from the groups of antifreezes, antifoaming agents, preservatives, antioxidants, spreading agents, dyes and / or thickeners.
- Suitable nonionic surfactants are all substances of this type conventionally usable in agrochemical compositions.
- Polyethylene oxide-polypropylene oxide block copolymers polyethylene glycol ethers of linear alcohols, reaction products of fatty acids with ethylene oxide and / or propylene oxide, polyvinyl alcohol, polyvinylpyrrolidone, copolymers of polyvinyl alcohol and polyvinylpyrrolidone, copolymers of polyvinyl acetate and polyvinylpyrrolidone and copolymers of (meth) acrylic acid and (meth ) acrylic acid esters, furthermore alkyl ethoxylates and alkylaryl ethoxylates, which may optionally be phosphated and optionally neutralized with bases, polyoxyamine derivatives and nonylphenol ethoxylates.
- Suitable anionic surfactants are all substances of this type conventionally usable in agrochemical compositions. Preference is given to alkali metal and alkaline earth metal salts of alkylsulfonic acids or alkylarylsulfonic acids.
- anionic surfactants or dispersants are salts of polystyrenesulfonic acids, salts of polyvinylsulfonic acids, salts of naphthalenesulfonic acid-formaldehyde condensation products, salts of condensation products of naphthalenesulfonic acid, phenolsulfonic acid and formaldehyde and salts of lignosulfonic acid.
- Suitable foam-inhibiting substances are all substances customarily usable for this purpose in agrochemical compositions.
- Preferred are silicone oils and magnesium stearate.
- Suitable preservatives are all substances customarily usable for this purpose in agrochemical compositions of this type. Examples which may be mentioned are Preventol® (Bayer AG) and Proxel®.
- antioxidants are all commonly used for this purpose in agrochemical agents substances into consideration.
- BHT butylhydroxytoluene (2,6-di-t-butyl-4-methyl-phenol
- Suitable spreading agents are all substances customarily usable for this purpose in agrochemical compositions. Preference is given to polyether- or organo-modified polysiloxanes.
- Suitable dyes are all substances customarily usable for this purpose in agrochemical compositions. Examples include titanium dioxide, carbon black, zinc oxide and blue pigments as well as permanent red FGR.
- Suitable thickeners are all substances of this type conventionally usable in agrochemical compositions. Preference is given to silicates (such as, for example, Atagel® 50 from Engelhard) or xanthan gum (such as, for example, Kelzan® S from Kelko).
- silicates such as, for example, Atagel® 50 from Engelhard
- xanthan gum such as, for example, Kelzan® S from Kelko
- the preparation of the concentrated formulations according to the invention takes place in such a way that the components are mixed together in the respectively desired ratios.
- the order in which the ingredients are mixed together is arbitrary. Conveniently, one uses the solid components in a finely ground state. However, it is also possible first to subject the suspension formed after mixing the constituents to a coarse and then to a fine grinding so that the mean particle size is less than 20 ⁇ m. Preference is given to suspension concentrates in which the solid particles have an average particle size of between 1 and 10 ⁇ m.
- the temperatures can be varied in carrying out the method according to the invention in a certain range. It generally works at temperatures between 10 0 C and 60 0 C, preferably between 15 0 C and 40 0 C.
- customary mixing and grinding devices which are used for the production of agrochemical formulations are suitable.
- compositions according to the invention are formulations which remain stable even after prolonged storage at elevated temperatures or in the cold, since no crystal growth is observed. They can be converted by dilution with water into homogeneous spray liquids.
- the application rate of the compositions according to the invention can be varied within a relatively wide range. It depends on the particular agrochemical active ingredients and their content in the compositions.
- compositions of the invention contain
- compositions according to the invention contain:
- At least one active ingredient selected from (II-1), (II-2) and (II-3) selected from (II-1), (II-2) and (II-3)
- compositions according to the invention comprise:
- compositions of the invention contain - when it comes to concentrated formulations
- agrochemically active compounds which can be used according to the invention, preferably 5 to 50% by weight and particularly preferably 10 to 30% by weight
- nonionic surfactants and / or anionic surfactants generally between 1 and 20% by weight of nonionic surfactants and / or anionic surfactants, preferably between 2.5 and 10% by weight,
- antifreeze generally between 1 and 20% by weight of antifreeze, preferably between 5 and 15% by weight
- additives between 0.1 and 20 wt .-%, preferably between
- compositions according to the invention generally contain between 0.05 and 10 g / l of adjuvant, preferably 0.1 to 8 g / l and more preferably 0.1 to 5 g / l, in the case of ready-to-use formulations (priming solutions).
- compositions according to the invention are suitable with good plant tolerance, favorable toxicity to warm-blooded animals and good environmental compatibility for the protection of plants and plant organs, for increasing crop yields, improving the quality of the crop and for controlling animal pests, in particular insects, arachnids, helminths, nematodes and mollusks in agriculture, horticulture, livestock, forests, gardens and recreational facilities, in the protection of materials and materials and in the hygiene sector. They can preferably be used as crop protection agents. They are effective against normally sensitive and resistant species as well as against all or individual stages of development.
- the above mentioned pests include:
- Anoplura e.g. Damalinia spp., Haematopinus spp., Linognathus spp., Pediculus spp., Trichodectes spp.
- arachnids e.g. Acarus siro, Aceria sheldoni, Aculops spp., Aculus spp., Amblyomma spp., Argas spp., Boophilus spp., Brevipalpus spp., Bryobia praetiosa, Chorioptes spp., Dermanyssus gallinae, Eotetranychus spp., Epitrimerus pyri, Eutetranychus spp.
- Eriophyes spp. Hemitarsonemus spp., Hyalomma spp., Ixodes spp., Latrodectus mactans, Metatetranychus spp., Oligonychus spp., Ornithodoros spp., Panonychus spp., Phyllocoptruta oleivora, Polyphagotarsonemus latus, Psoroptes spp., Rhipicephalus spp. Rhizoglyphus spp., Sarcoptes spp., Scorpio maurus, Stenotarsonemus spp., Tarsonemus spp., Tetranychus spp., Vasates lycopersici.
- Gastropoda e.g. Arion spp., Biomphalaria spp., Bulinus spp., Deroceras spp., Galba spp., Lymnaea spp., Oncomelania spp., Succinea spp.
- helminths e.g. Ancylostoma duodenale, Ancylostoma ceylanicum, Acylostoma braziliensis, Ancylostoma spp., Ascaris lubricoides, Ascaris spp., Brugia malayi, Brugia timori, Bunostomum spp., Chabertia spp., Clonorchis spp., Cooperia spp., Dicrocoelium spp, Dictyocaulus filaria, Diphyllobothrium latum , Dracunculus medinensis, Echinococcus granulosus, Echinococcus multilocularis, Enterobius vermicularis, Faciola spp., Haemonchus spp., Heterakis spp., Hymenolepis nana, Hyostrongulus spp., Loa Loa, Ne
- protozoa such as Eimeria
- Eimeria protozoa
- Psylla spp. Pteromalus spp., Pyrilla spp., Quadraspidiotus spp., Quesada gigas, Rastrococcus spp., Rhopalosiphum spp., Saissetia spp., Scaphoides titanus, Schizaphis graminum, Selenaspidus articulatus, Sogata spp., Sogatella furcifera, Sogatodes spp , Stictocephala festina, Tenalaphara malayensis, Tinocallis caryaefoliae, Tomaspis spp., Toxoptera spp., Tri- aleurodes vaporariorum, Trioza spp., Typhlocyba spp., Unaspis spp., Viteus vitifolii.
- Hymenoptera e.g. Diprion spp., Hoplocampa spp., Lasius spp., Monomorium pharaonis, Vespa spp.
- Lepidoptera From the order of Lepidoptera, for example, Acronicta major, Aedia leucomelas, Agrotis spp., Alabama argillacea, Anticarsia spp., Barathra brassicae, Bucculatrix thurberiella, Bupalus piniarius, Cacoecia podana, Capua reticulana, Carpocapsa pomonella, Cheimatobia brumata, Chilo spp., Choristoneura fumiferana , Clysia ambiguella, Cnaphalocerus spp., Earias insulana, Ephestia kuehniella, Euproctis chrysorrhoea, Euxoa spp., Feltia spp., Galleria mellonella, Helicove ⁇ a spp., Heliothis spp., Hofinannophila pseudospretella,
- Orthoptera e.g. Acheta domesticus, Blatta orientalis, Blattella germanica, Gryllotaipa spp., Leucophaea maderae, Locusta spp., Melanoplus spp., Periplaneta americana, Schistocerca gregaria.
- siphonaptera e.g. Ceratophyllus spp., Xenopsylla cheopis.
- Symphyla e.g. Scutigerella immaculata.
- Thysanoptera e.g. Basothrips biformis, Enneothrips flavens, Frankliniella spp., Heliothrips spp., Hercinothrips femoralis, Kakothrips spp., Rhipiphorothrips cruentatus, Scirtothrips spp., Taeniothrips cardamoni, Thrips spp.
- Thysanura e.g. Lepisma saccharina.
- the plant parasitic nematodes include e.g. Anguina spp., Aphelenchoides spp., Belonoaimus spp., Bursaphelenchus spp., Ditylenchus dipsaci, Globodera spp., Heliocotylenchus spp., Heterodera spp., Longidorus spp., Meloidogyne spp., Pratylenchus spp., Radopholus similis, Rotylenchus spp. Trichodorus spp., Tylenchorhynchus spp., Tylenchulus spp., Tylenchulus semipenetrans, Xiphinema spp.
- Anguina spp. Aphelenchoides spp., Belonoaimus spp., Bursaphelenchus spp., Ditylenchus dipsaci, Globodera
- compositions according to the invention may optionally also be used in certain concentrations or application rates as herbicides, safeners, growth regulators or agents for improving plant properties, or as microbicides, for example as fungicides, antimycotics, bactericides, viricides (including anti-viral agents) or as anti-MLO agents ( Mycoplasma-like-organism) and RLO (Rickettsia-like-organism).
- compositions according to the invention may contain other active ingredients such as insecticides, attractants, sterilants, bactericides, acaricides, nematicides, fungicides, growth-regulating substances, herbicides, safeners, fertilizers or semiochemicals as mixing partners.
- active ingredients such as insecticides, attractants, sterilants, bactericides, acaricides, nematicides, fungicides, growth-regulating substances, herbicides, safeners, fertilizers or semiochemicals.
- Particularly favorable mixing partners are, for example, the following:
- Azoxystrobin Cyazofamide, Dimoxystrobin, Enestrobin, Famoxadone, Fenamidon, Fluoxastrobin, Kresoximmethyl, Metominostrobin, Orysastrobin, Pyraclostrobin, Picoxystrobin, Trifloxystrobin
- Prothioconazole pyrifenox, simeconazole, tebuconazole, tetraconazole, triadimefon, triadimenol, triflumizole triforin, triticonazole, uniconazole, voriconazole, viniconazole,
- Inhibitors of cell wall synthesis Benthiavalicarb, Bialaphos, Dimethomorph, Flumo ⁇ h, Iprovalicarb, Mandipropamide, Polyoxins, Polyoxorim, Validamycin A
- Carbamates for example Alanycarb, Aldicarb, Aldoxycarb, Allyxycarb, Aminocarb, Bendiocarb, Benfuracarb, Bufencarb, Butacarb, Butocarboxim, Butoxycarboxim, Carbaryl, Carbofuran,
- Organophosphates for example, acephates, azamethiphos, azinphos (-methyl, -ethyl), bromophos-ethyl, bromfenvinfos (-methyl), butathiofos, cadusafos, carbophenothione, chloroethoxyfos, chlorfenvinphos, chlormephos, chlorpyrifos
- Dichlorvos / DDVP Dicrotophos, Dimethoates, Dimethylvinphos, Dioxabenzofos, Disulfoton, EPN, Ethion, Ethoprophos, Etrimfos, Famphur, Fenamiphos, Fenitrothion, Fensulfothion, Fenthion, Flupyrazofos, Fonofos, Formothion, Fosmethilane, Fosthiazate, Heptenophos, Iodofenphos, Iprobenfos, Isazofos, Isofenphos, isopropyl-o-salicylate, isoxathione, malathion, mecarbam, methacrifos, methamidophos, methidathione,
- Mevinphos Monocrotophos, Naled, Omethoate, Oxydemeton-methyl, Parathion (-methyl / -ethyl), Phenthoate, Phorate, Phosalone, Phosmet, Phosphamidon, Phosphocarb, Phoxim, Pirimiphos (-methylAethyl), Profenofos, Propaphos, Propetamphos, Prothiofos, Prothoate , Pyraclofos, Pyridaphenthion, Pyridathion, Quinalphos, Sebufos, Sulfotep, Sulprofos, Tebupirimfos, Temephos, Terbufos, Tetrachlorvinphos, Thiometon, Triazophos,
- Pyrethroids for example acrinathrin, allethrin (d-cis-trans, d-trans), beta-cyfluthrin, bifenthrin, bioallethrin, bioallethrin-S-cyclopentyl isomer, bioethanomethrin, biopermethrin,
- Oxadiazines for example Indoxacarb
- Chloronicotinyls for example acetamipride, clothianidin, dinotefuran, imidacloprid, nitenpyram, nithiazines, thiacloprid, thiamethoxam
- Acetylcholine receptor modulators are Acetylcholine receptor modulators
- Organochlorines for example, camphechlor, chlordane, endosulfan, gamma-HCH, HCH, heptachlor,
- Fiproles for example, acetoprole, ethiprole, fipronil, pyrafluprole, pyriprole, vaniliprole
- Chloride channel activators Mectins for example Abamectin, Emamectin, Emamectin benzoate, Ivermectin, Lepimectin,
- Juvenile hormone mimetics for example, diofenolan, epofenonans, fenoxycarb, hydroprene, kinoprene,
- Diacylhydrazines for example chromafenozide, Halofenozide, Methoxyfenozide, Tebufenozide
- Benzoylureas for example bistrifluron, chlorofluazuron, diflubenzuron, fluazuron, flucycloxuron, fenphenoxuron, hexaflumuron, lufenuron, novaluron, noviflumuron, penfluron, teflubenzuron, triflumuron
- Organotin compounds for example azocyclotin, cyhexatin, fenbutatin oxides
- Dinitrophenols for example binapacyrl, dinobutone, dinocap, DNOC, meptyldinocap
- METI's Site I electron transport inhibitors METI's, for example fenazaquin, fenpyroximate, pyrimidifen, pyridaben, tebufenpyrad,
- spirodiclofen for example spirodiclofen, spiromesifen,
- rynaxypyr (3-bromo-N- ⁇ 4-chloro-2-methyl-6-
- Fumigants for example aluminum phosphides, methyl bromides, sulfuryl fluorides
- Food inhibitors for example Cryolite, Flonicamid, Pymetrozine
- Mite growth inhibitors for example clofentezine, etoxazole, hexythiazox
- Cyflumetofen Dicyclanil, Fenoxacrim, Fentrifanil, Flubenzimine, Flufenerim, Flutenzine, Gossyplure, Hydramethylnone, Japonilure, Metoxadiazone, Petroleum, Piperonylbutoxide, Potassium oleate, Pyralidyl, Sulfluramid, Tetradifon, Tetrasul, Tri- arathene, Verbutin
- compositions according to the invention may furthermore be present in insecticides in their commercial formulations and in the formulations prepared from these formulations in admixture with synergists.
- Synergists are compounds by which the effect of the active ingredients contained in the compositions according to the invention is increased without the added synergist itself having to be actively active.
- compositions according to the invention may furthermore, when used as insecticides in their commercial formulations and in the forms of use prepared from these formulations, be present in mixtures with inhibitors which inhibit the degradation of the agrochemical active ingredient used in the environment of the plant, on the surface of parts of plants or in plants Reduce tissue.
- the active substance content of the application forms prepared from the commercial formulations can vary within wide ranges.
- the active ingredient concentration of the use forms may be from 0.00000001 up to 95% by weight of active compound, preferably between 0.00001 and 1% by weight.
- the application is done in a custom forms adapted to the application.
- plants and parts of plants can be treated.
- plants are understood as meaning all plants and plant populations, such as desired and undesired wild plants or crop plants (including naturally occurring crop plants).
- Crop plants can be plants which can be obtained by conventional breeding and optimization methods or by biotechnological and genetic engineering methods or combinations of these methods, including the transgenic plants and including the plant varieties which can or can not be protected by plant breeders' rights.
- Plant parts are to be understood as meaning all aboveground and underground parts and organs of the plants, such as shoot, leaf, flower and root, by way of example leaves, needles, stems, stems, flowers, fruiting bodies, fruits and seeds and roots, tubers and rhizomes.
- the plant parts also include crops and vegetative and generative propagation material, such as cuttings, tubers, rhizomes, offshoots and seeds.
- the treatment according to the invention of the plants and plant parts with the compositions is carried out by soil treatment.
- plants and their parts can be treated.
- wild or obtained by conventional biological breeding methods such as crossing or protoplast fusion Plant species and plant varieties and their parts treated.
- transgenic plants and plant cultivars obtained by genetic engineering if appropriate in combination with conventional methods (Genetically Modified Organisms), and parts thereof are treated.
- the terms "parts” or “parts of plants” or “plant parts” have been explained above.
- Plant varieties are understood as meaning plants having new traits which have been bred by conventional breeding, by mutagenesis or by recombinant DNA techniques. These can be varieties, biotypes and genotypes.
- the treatment according to the invention may also give rise to superadditive ("synergistic") effects.
- superadditive for example, reduced application rates and / or extensions of the spectrum of action and / or an increase in the effect of the substances and agents usable in the invention, better plant growth, increased tolerance to high or low temperatures, increased tolerance to drought or to water or soil salt content, increased flowering power facilitated harvest, acceleration of ripeness, higher crop yields, higher quality and / or higher nutritional value of the harvested products, higher shelf life and / or machinability of the harvested products, which exceed the actual expected effects.
- the preferred plants or plant varieties to be treated according to the invention to be treated include all plants which, as a result of the genetic engineering modification, obtained genetic material which gives these plants particularly advantageous valuable properties ("traits").
- traits are better plant growth, increased tolerance to high or low temperatures, increased tolerance to dryness or to bottoms salt, increased flowering, easier harvesting, acceleration of ripeness, higher crop yields, higher quality and / or higher nutritional value of the harvested products , higher shelf life and / or workability of the harvested products.
- Further and particularly emphasized examples of such properties are an increased defense of the plants against animal and microbial pests, as against insects, mites, phytopathogenic fungi, bacteria and / or viruses as well as an increased tolerance of the plants to certain herbicidal active substances.
- transgenic plants are the important crops such as cereals (wheat, rice), corn, soybean, potato, sugar beets, tomatoes, peas and other vegetables, cotton, tobacco, rape, and fruit plants (with the fruits apples, pears, citrus fruits and grapes), with special emphasis on maize, soya, potato, cotton, tobacco and oilseed rape.
- Traits that are particularly emphasized are the increased defense of the plants against insects, arachnids, nematodes and snails by toxins produced in the plants, in particular those which are produced by the genetic material from Bacillus thuringiensis (eg by the genes Cry ⁇ A (a) , Cry ⁇ A (b), Cry ⁇ A (c), CrylLA, CrylllA, CryIIIB2, Cry9c Cry2Ab, Cry3Bb and CrylF, and combinations thereof) in the plants (hereinafter "Bt plants”). Traits also highlight the increased resistance of plants to fungi, bacteria and viruses by systemic acquired resistance (SAR), systemin, phytoalexins, elicitors and resistance genes and correspondingly expressed proteins and toxins.
- SAR systemic acquired resistance
- Traits which are furthermore particularly emphasized are the increased tolerance of the plants to certain herbicidally active compounds, for example imidazolinones, sulfonylureas, glyphosate or phosphinotricin (eg "PAT" gene).
- the genes which confer the desired properties (“traits") can also occur in combinations with one another in the transgenic plants.
- Examples of “Bt plants” are maize varieties, cotton varieties, soybean varieties and potato varieties which are sold under the trade names YIELD GARD® (eg corn, cotton, soya), KnockOut® (eg maize), StarLink® (eg maize), Bollgard® ( Cotton), Nucotn® (cotton) and NewLeaf® (potato).
- herbicide-tolerant plants are maize varieties, cotton varieties and soybean varieties, which are sold under the trade names Roundup Ready® (tolerance to glyphosate eg corn, cotton, soy), Liberty Link® (tolerance to phosphinotricin, eg rapeseed), IMI® (tolerance against imidazolinone) and STS® (tolerance to sulfonylureas eg corn).
- Roundup Ready® tolerance to glyphosate eg corn, cotton, soy
- Liberty Link® tolerance to phosphinotricin, eg rapeseed
- IMI® tolerance against imidazolinone
- STS® tolerance to sulfonylureas eg corn
- Clearfield® varieties eg corn
- compositions according to the invention can be treated particularly advantageously according to the invention with the compositions according to the invention.
- the preferred ranges given above for the compositions also apply to the treatment of these plants.
- Particularly emphasized is the plant treatment with the compositions specifically listed in the present text.
- compositions of the invention not only work against plant, hygiene and
- animal parasites ecto- and endoparasites
- ticks such as ticks, leather ticks, mange mites, mites, flies (stinging and licking), parasitizing fly larvae, lice, hair pieces, featherlings and fleas.
- endoparasites such as ticks, leather ticks, mange mites, mites, flies (stinging and licking), parasitizing fly larvae, lice, hair pieces, featherlings and fleas.
- Anoplurida e.g. Haematopinus spp., Linognathus spp., Pediculus spp., Phtirus spp., Solenopotes spp.
- Trimenopon spp. Menopon spp., Trinoton spp., Bovicola spp., Werneckiella spp., Lepikentron spp., Damalina spp., Trichodectes spp., Felicola spp.
- Nematocerina and Brachycerina e.g. Aedes spp K, Anopheles spp., Culex spp., Simulium spp., Eusimulium spp., Phlebotomus spp., Lutzomyia spp., Culicoides spp., Chrysops spp., Hybomitra spp., Atylotus spp., Tabanus spp., Haematopota Spp., Philipomyia spp., Braula spp., Musca spp., Hydrotaea spp., Stomoxys spp., Haematobia spp., Murnrellellia sspppp., Fannia spp., Glossina spp., Calliphora spp., Glossina spp., Chry
- siphonaptrida e.g. Pulex spp., Ctenocephalides spp., Xenopsylla spp., Ceratophyllus spp.
- heteropterid e.g. Cimex spp., Triatoma spp., Rhodnius spp., Panstrongylus spp.
- Actinedida Prostigmata
- Acaridida e.g. Acarapis spp., Cheyletiella spp., Ornitrocheyletia spp., Myobia spp., Psorergates spp., Demodex spp., Trombicula spp., Listrophorus spp., Acarus spp., Tyrophagus spp., Caloglyphus spp., Hypodectes spp., Pterolichus spp , Psoroptes spp., Chorioptes spp., Otodectes spp., Sarcoptes spp., Notoedres spp., Knemidocoptes spp., Cytodites spp., Laminosioptes spp.
- compositions according to the invention are also suitable for controlling arthropods, livestock, such as cattle, sheep, goats, horses, pigs, donkeys, Camels, buffaloes, rabbits, chickens, turkeys, ducks, geese, bees, other pets such as dogs, cats, caged birds, aquarium fish and so-called experimental animals, such as hamsters, guinea pigs, rats and mice infested.
- livestock such as cattle, sheep, goats, horses, pigs, donkeys, Camels, buffaloes, rabbits, chickens, turkeys, ducks, geese, bees, other pets such as dogs, cats, caged birds, aquarium fish and so-called experimental animals, such as hamsters, guinea pigs, rats and mice infested.
- the control of these arthropods is intended to reduce deaths and reductions in performance (in the case of meat, milk, wool, hides, eggs, honey, etc.), so that a more economical and simpler animal husband
- compositions according to the invention is carried out in the veterinary sector and in animal husbandry in a known manner by enteral administration in the form of, for example, tablets, capsules, infusions, drenches, granules, pastes, boilies, feed-through, suppositories, by parenteral administration, as by injections (intramuscular, subcutaneous, intravenous, intraperitoneal, etc.), implants, by nasal application, by dermal application in the form of, for example, diving or bathing (dipping), spraying, pouring (pour-on and spot-on ), washing, powdering and with the aid of active substance-containing moldings, such as collars, ear tags, tail marks, limb bands, holsters, marking devices, etc.
- enteral administration in the form of, for example, tablets, capsules, infusions, drenches, granules, pastes, boilies, feed-through, suppositories
- parenteral administration as by injections (intramuscular, subcutaneous,
- compositions may be formulated (for example, powders, emulsions, flowables) containing the active ingredients in an amount of 1 to 80% by weight, directly or after 100 to 10,000 dilution or use as a chemical bath.
- compositions according to the invention have a high insecticidal activity against insects which destroy industrial materials.
- insects By way of example and preferably without limiting however, the following insects are mentioned:
- Skin fins such as Sirex juvencus, Urocerus gigas, Urocerus gigas taignus, Urocerus augur;
- Termites such as Kalotermes flavicollis, Cryptotermes brevis, Heterotermes indicola, Reticulitermes flavipes, Reticulitermes santonensis, Reticulitermes lucifugus, Mastotermes darwiniensis, Zootermopsis nevadensis, Coptotermes formosanus; Bristle tails like Lepisma saccharina.
- Non-living materials such as preferably plastics, adhesives, glues, papers and cardboard, leather, wood, wood processing products and paints.
- the ready-to-use agents may optionally contain further insecticides and optionally one or more fungicides.
- compositions according to the invention can be used to protect against the growth of objects, in particular hulls, sieves, nets, structures, quay systems and signal systems, which come into contact with seawater or brackish water.
- compositions according to the invention can be used alone or in combinations with other active substances as antifouling agents.
- compositions are also suitable for controlling animal pests in household, hygiene and storage protection, in particular insects, arachnids and mites, which are used in enclosed spaces, such as, for example, apartments, factory halls, offices,
- Acarina e.g. Argas persicus, Argas reflexus, Bryobia ssp., Dermanyssus gallinae, Glyciphagus domesticus, Ornithodorus moubat, Rhipicephalus sanguineus, Trombicula alfreddugesi, Neutrombicula autumnalis, Dermatophagoides pteronissimus, Dermatophagoides forinae.
- Opiliones e.g. Pseudoscorpiones chelifer, Pseudoscorpiones cheiridium, Opiliones phalangium.
- Zygentoma e.g. Ctenolepisma spp., Lepisma saccharina, Lepismodes inquilinus.
- Diptera e.g. Aedes aegypti, Aedes albopictus, Aedes taeniorhynchus, Anopheles spp., Calliphora erythrocephala, Chrysozona pluvialis, Culex quinquefasciatus, Culex pipiens, Culex tarsalis, Drosophila spp., Fannia canicularis, Musca domestica, Phlebotomus spp., Sarcophaga carnaria, Simulium spp., Stomoxys Calcitrans, Tipula paludosa.
- Lepidoptera e.g. Achroia grisella, Galleria mellonella, Plodia interpunctella, Tinea cloacella, Tinea pellionella, Tineola bisselliella.
- Ctenocephalides canis Ctenocephalides felis, Pulex irritans, Tunga penetrans, Xenopsylla cheopis.
- Hymenoptera e.g. Camponotus herculeanus, Lasius fuliginosus, Lasius niger, Lasius umbratus, Monomorium pharaonis, Paravespula spp., Tetramorium caespitum.
- X means the degree of killing, expressed in% of the untreated control, when using the active substance A at a rate of m g / ha or in a concentration of m ppm,
- Y means the degree of killing, expressed in% of the untreated control, when using the active ingredient B in an application rate of n g / ha or in a concentration of n ppm
- Active substances A and B in amounts of m and n g / ha or in a concentration of m and n ppm,
- the combination is over-additive in its kill, ie there is a synergistic effect.
- the actually observed kill rate must be greater than the expected kill rate (E) value calculated from the above formula.
- a suitable product solution 1 part by weight of formulated product is mixed with water to the desired concentration.
- the desired adjuvant is added in a defined amount and mixed well.
- Corn plants (Zea mays) are infused with the product solution of the desired concentration and infected with larvae of the armyworm ⁇ Spodoptera frugiperda).
- the kill is determined in%. 100% means that all caterpillars have been killed; 0% means that no caterpillars have been killed.
- the determined kill values are calculated according to the Colby formula (see page 1).
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
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Abstract
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
MX2009003071A MX2009003071A (es) | 2006-09-30 | 2007-09-18 | Mejora del efecto biologico de composiciones agroquimicas en la aplicacion al sustrato de cultivo, formulaciones adecuadas y su uso. |
US12/443,263 US20100087542A1 (en) | 2006-09-30 | 2007-09-18 | Improvement of the biological action of agrochemical compositions when applied to the cultivation substrate, suitable formulations and use thereof |
BRPI0717153-6A BRPI0717153A2 (pt) | 2006-09-30 | 2007-09-18 | Aperfeiçoamento da ação biológica de composições agroquímicas sobre a aplicação ao substrato de culturas, formulações adequadas e sua aplicação |
EP07818202A EP2101573A2 (de) | 2006-09-30 | 2007-09-18 | Verbesserung der biologischen wirkung von agrochemischen zusammensetzungen bei applikation in das kultursubstrat, geeignete formulierungen und ihre anwendung |
JP2009529574A JP2010505752A (ja) | 2006-09-30 | 2007-09-18 | 栽培基質に施用されたときの農薬組成物の生物学的効果の改善、適切な製剤及びその使用 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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EP06020678 | 2006-09-30 | ||
EP06020678.6 | 2006-09-30 |
Publications (3)
Publication Number | Publication Date |
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WO2008037374A2 true WO2008037374A2 (de) | 2008-04-03 |
WO2008037374A3 WO2008037374A3 (de) | 2009-02-12 |
WO2008037374A8 WO2008037374A8 (de) | 2009-05-22 |
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ID=38960806
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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PCT/EP2007/008096 WO2008037374A2 (de) | 2006-09-30 | 2007-09-18 | Verbesserung der biologischen wirkung von agrochemischen zusammensetzungen bei applikation in das kultursubstrat, geeignete formulierungen und ihre anwendung |
Country Status (13)
Country | Link |
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US (1) | US20100087542A1 (de) |
EP (1) | EP2101573A2 (de) |
JP (1) | JP2010505752A (de) |
KR (1) | KR20090060446A (de) |
CN (1) | CN101522024A (de) |
AR (1) | AR063055A1 (de) |
BR (1) | BRPI0717153A2 (de) |
CL (1) | CL2007002822A1 (de) |
CO (1) | CO6160262A2 (de) |
MX (1) | MX2009003071A (de) |
TW (1) | TW200822864A (de) |
WO (1) | WO2008037374A2 (de) |
ZA (1) | ZA200902118B (de) |
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EP2179650A1 (de) * | 2008-10-27 | 2010-04-28 | Evonik Goldschmidt GmbH | Nicht schäumende organische Tenside als Additive für Tankmischungszubereitungen im Pflanzenschutz |
WO2010139408A3 (de) * | 2009-06-03 | 2011-06-16 | Bayer Cropscience Ag | Flubendiamide-nützlings-kombinationen |
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AR084149A1 (es) * | 2010-12-13 | 2013-04-24 | Akzo Nobel Chemicals Int Bv | Composicion de adyuvantes para insecticidas y proceso para controlar poblaciones de insectos de cultivos |
JPWO2012115070A1 (ja) * | 2011-02-25 | 2014-07-07 | 株式会社クレハ | 農業用薬剤およびその製造方法 |
BR112013028998A2 (pt) * | 2011-06-06 | 2016-08-09 | Nihon Nohyaku Co Ltd | regulador de crescimento vegetal, método para usar o mesmo e método para aumentar o rendimento e para promover o crescimento de lavouras alvo |
WO2014187847A1 (en) * | 2013-05-23 | 2014-11-27 | Syngenta Participations Ag | Tank-mix formulations |
CN107056447B (zh) * | 2017-04-17 | 2020-12-08 | 南陵县生产力促进中心 | 一种根系促生园林绿化育苗基质 |
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-
2007
- 2007-09-18 EP EP07818202A patent/EP2101573A2/de not_active Withdrawn
- 2007-09-18 CN CNA2007800362975A patent/CN101522024A/zh active Pending
- 2007-09-18 KR KR1020097008033A patent/KR20090060446A/ko not_active Application Discontinuation
- 2007-09-18 JP JP2009529574A patent/JP2010505752A/ja not_active Withdrawn
- 2007-09-18 BR BRPI0717153-6A patent/BRPI0717153A2/pt not_active IP Right Cessation
- 2007-09-18 WO PCT/EP2007/008096 patent/WO2008037374A2/de active Application Filing
- 2007-09-18 US US12/443,263 patent/US20100087542A1/en not_active Abandoned
- 2007-09-18 MX MX2009003071A patent/MX2009003071A/es not_active Application Discontinuation
- 2007-09-28 TW TW096136088A patent/TW200822864A/zh unknown
- 2007-09-28 CL CL200702822A patent/CL2007002822A1/es unknown
- 2007-09-28 AR ARP070104314A patent/AR063055A1/es not_active Application Discontinuation
-
2009
- 2009-03-19 CO CO09028702A patent/CO6160262A2/es unknown
- 2009-03-26 ZA ZA200902118A patent/ZA200902118B/xx unknown
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EP1006107A2 (de) * | 1998-11-30 | 2000-06-07 | Nihon Nohyaku Co., Ltd. | Phthalamidderivate oder Salz davon, land- und gartenbauwirtschaftliche Insektizide sowie Verfahren zu ihrer Verwendung |
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Cited By (4)
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EP2179650A1 (de) * | 2008-10-27 | 2010-04-28 | Evonik Goldschmidt GmbH | Nicht schäumende organische Tenside als Additive für Tankmischungszubereitungen im Pflanzenschutz |
US8163673B2 (en) | 2008-10-27 | 2012-04-24 | Evonik Goldschmidt Gmbh | Non-foaming organic surfactants as additives for tank mixture preparations in crop protection |
WO2010139408A3 (de) * | 2009-06-03 | 2011-06-16 | Bayer Cropscience Ag | Flubendiamide-nützlings-kombinationen |
CN102480946A (zh) * | 2009-06-03 | 2012-05-30 | 拜尔农作物科学股份公司 | 氟虫双酰胺和有益生物的结合物 |
Also Published As
Publication number | Publication date |
---|---|
EP2101573A2 (de) | 2009-09-23 |
CN101522024A (zh) | 2009-09-02 |
TW200822864A (en) | 2008-06-01 |
MX2009003071A (es) | 2009-04-02 |
JP2010505752A (ja) | 2010-02-25 |
CO6160262A2 (es) | 2010-05-20 |
US20100087542A1 (en) | 2010-04-08 |
WO2008037374A8 (de) | 2009-05-22 |
CL2007002822A1 (es) | 2008-04-18 |
AR063055A1 (es) | 2008-12-23 |
WO2008037374A3 (de) | 2009-02-12 |
ZA200902118B (en) | 2010-06-30 |
BRPI0717153A2 (pt) | 2013-10-15 |
KR20090060446A (ko) | 2009-06-12 |
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