WO2008018041A2 - Procédé de fabrication de capsules déformables contenant de l'eau - Google Patents

Procédé de fabrication de capsules déformables contenant de l'eau Download PDF

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Publication number
WO2008018041A2
WO2008018041A2 PCT/IB2007/053148 IB2007053148W WO2008018041A2 WO 2008018041 A2 WO2008018041 A2 WO 2008018041A2 IB 2007053148 W IB2007053148 W IB 2007053148W WO 2008018041 A2 WO2008018041 A2 WO 2008018041A2
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WO
WIPO (PCT)
Prior art keywords
phase
pigment
capsule
water
mixing
Prior art date
Application number
PCT/IB2007/053148
Other languages
English (en)
Other versions
WO2008018041A3 (fr
Inventor
Takashi Sako
Kojo Tanaka
Takahiro Nakajima
Original Assignee
The Procter & Gamble Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by The Procter & Gamble Company filed Critical The Procter & Gamble Company
Priority to CA002658990A priority Critical patent/CA2658990A1/fr
Priority to JP2009523434A priority patent/JP2010500339A/ja
Priority to CN2007800293890A priority patent/CN101500699B/zh
Priority to EP07826015A priority patent/EP2069064A2/fr
Priority to AU2007282910A priority patent/AU2007282910B2/en
Publication of WO2008018041A2 publication Critical patent/WO2008018041A2/fr
Publication of WO2008018041A3 publication Critical patent/WO2008018041A3/fr

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
    • B01J13/02—Making microcapsules or microballoons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
    • B01J13/02—Making microcapsules or microballoons
    • B01J13/04—Making microcapsules or microballoons by physical processes, e.g. drying, spraying
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0241—Containing particulates characterized by their shape and/or structure
    • A61K8/025—Explicitly spheroidal or spherical shape
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/11—Encapsulated compositions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/26—Aluminium; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/27—Zinc; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/29—Titanium; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/69—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing fluorine
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/732—Starch; Amylose; Amylopectin; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/88—Polyamides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/12—Face or body powders for grooming, adorning or absorbing
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/24—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
    • B01J8/40—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with fluidised bed subjected to vibrations or pulsations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/41—Particular ingredients further characterized by their size
    • A61K2800/412—Microsized, i.e. having sizes between 0.1 and 100 microns
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/42—Colour properties
    • A61K2800/43—Pigments; Dyes
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/60—Particulates further characterized by their structure or composition
    • A61K2800/61—Surface treated
    • A61K2800/62—Coated
    • A61K2800/622—Coated by organic compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/60—Particulates further characterized by their structure or composition
    • A61K2800/65—Characterized by the composition of the particulate/core
    • A61K2800/651—The particulate/core comprising inorganic material
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
    • Y10T428/2984—Microcapsule with fluid core [includes liposome]

Definitions

  • the present invention relates to a process for making a collapsible water-containing capsule having water encapsulated or dispersed in hydrophobic pigments.
  • the present invention further relates to capsules made by such process.
  • a foundation composition can be applied to the face and other parts of the body to even skin tone and texture and to hide pores, imperfections, fine lines and the like.
  • a foundation composition is also applied to moisturize the skin, to balance the oil level of the skin, and to provide protection against the adverse effects of sunlight, wind, and other environmental factors.
  • Foundation compositions are generally available in the form of liquid or cream suspensions, emulsions, gels, pressed powders, loose powders or anhydrous oil and wax compositions.
  • Emulsion-type foundations are suitable in that they provide moisturizing effects by the water and water-soluble skin treatment agents incorporated.
  • a larger amount and variation of powders and pigments can be formulated into pressed powders and loose powders.
  • the two step regimen typically contains application of a liquid or emulsion form foundation followed by a pressed or loose powder foundation. It is conceived by such demanding consumers that such two-step regimen provides best results, however, such regimen is also quite elaborate. There is a need for a foundation product which can provide both good feel and good appearance on the skin, and also being easy to apply on the skin.
  • collapsible water-containing capsules are known in the art, such as in WO 01/85138, Japanese Patent Publications 2001-131528A, 2000-247823A, 2000-309506A, 11- 130614A, 10-265367A, 5-65212A, 4-308520A, 2006-509732A, 2001-226230A, 2001-158716A, and 1-125314A.
  • Such capsules provide a unique feel or change of feel upon application and collapsing on the skin. Upon application to the skin, such capsules provide a moisturizing or fresh feeling.
  • Such capsules may also deliver water-soluble skin active agents such as vitamin C derivatives to the skin, in a more or less stable manner.
  • the collapsible water-containing capsules form may be adopted for foundations having such benefits.
  • the present invention is directed to a process for making a collapsible water-containing capsule having a water phase encapsulated or dispersed in a pigment phase, the pigment phase comprising at least a first pigment component having a particle size of less than l ⁇ m and a hydrophobic surface; wherein the water phase and the pigment phase is mixed by a mixing apparatus selected from the group consisting of external energy sourcing type and container shaking type.
  • the present invention is also directed to a process for making a collapsible water- containing capsule having a water phase encapsulated or dispersed in a pigment phase, the pigment phase comprising at least a first pigment component having a particle size of less than l ⁇ m and is surface coated with a lipophobic hydrophobic coating material; wherein the water phase and the pigment phase is mixed by a mixing apparatus selected from the group consisting of fluidizer type, mechanical mixing type and container rotating type.
  • the present invention is also directed to products made by the processes above.
  • the present invention is also directed to a preparation-at-use product for providing a collapsible water-containing capsule.
  • the present invention relates to making a collapsible water-containing capsule which comprises, by weight of the capsule, at least about 60%, preferably from about 70% to about 92% of a water phase, the water phase being water and optional water-soluble solvents.
  • the capsule of the present invention comprises a pigment phase, the pigment phase comprising at least a first pigment component having a particle size of less than l ⁇ m and a hydrophobic surface, in which the water is encapsulated or dispersed.
  • the process preferably provides a capsule which is stable under normal storage conditions as well as normal mixing processes, however, collapses upon application.
  • such stability for the capsule is provided by further comprising, in the present capsule, a gelling agent, and a second pigment component in the pigment phase.
  • a gelling agent holds the water phase in a relatively rigid structure, while the first and second pigment components cover the water phase and thereby provide the stability and integrity of the capsule.
  • the first pigment component and optional second pigment components are collectively referred to as "the pigment phase”. Pigments and powders which do not meet the criteria for the first or second pigment component are not referred to as the pigment phase.
  • the capsule of the present invention is substantially free of surfactant.
  • surfactants may negatively affect the stability and shear stress tolerance of the present capsule by decreasing the surface tension difference between the water phase and the pigment phase.
  • surfactants include those which have detersive capability, as well as those which only act as emulsifiers for emulsifying water and oil phases.
  • the capsule of the present invention comprises less than 1% of porous pigments having a particle size of less than l ⁇ m.
  • porous pigments of small size may absorb sebum from the personal surface to such an extent that a dry negative feeling is provided to the personal surface.
  • porous pigments include silica, aluminum oxide, calcium carbonate, cellulose, and others that may have a porous structure when observed under magnification. It is noted that pigments made from the same chemical compound may take either a porous or non-porous structure, based on the process it is purified, processed, synthesized, or otherwise treated.
  • the capsule of the present invention provides unique benefits on the personal surface, such as skin, hair, or scalp, when collapsed on the surface. It provides a fresh or cooling feel to the surface, by releasing the abundant water. In preferred embodiments, the capsule provides an initially fresh, and then moisturizing feel to the surface. The preferred embodiment capsule further provides a good feel to the surface by the characteristic of the first and/or second pigment components. When the first and second pigment components are applied on the surface, the components provide the appearance benefits inherent of such pigment components.
  • the capsule of the present invention may, by itself, provide a product in the form of a loose powder product. The capsule of the present invention may also be mixed with other components to provide different product forms.
  • the capsule of the present invention is particularly useful for personal care compositions for delivering water, the pigments, and other components to the personal surface.
  • Personal care compositions herein include those for the purpose of skin care, make-up, extensive treatment, perfume, antiperspiration, deodorizing, hair coloring, hair treatment, hair styling, and others.
  • Personal care compositions herein can take the product form of powders, wax solidified solid forms, liquids, lotions, pastes, aerosols, and others.
  • One highly preferred product form embodiment is powder for use on the skin, such as foundation and skin care products.
  • the first pigment component and optional second pigment component are selected to provide the appropriate skin treatment and/or make-up benefits.
  • the capsule comprises by weight:
  • a second pigment component which has a particle size of l ⁇ m or more, is surface coated with a hydrophobic coating material; and is spherical in shape; wherein the total of the first pigment component and the second pigment component is at least about 8% of the capsule; and wherein the capsule comprises less than 1 % of a porous pigment having a particle size of less than l ⁇ m.
  • the capsule of the present invention comprises a water phase, the water phase comprising water, and optional water-soluble solvent detailed hereafter.
  • the present capsule comprises, by weight of the capsule, at least from about 60%, preferably from about 70% to about 92% of the water phase.
  • the water phase may be made only by water.
  • water is contained at from about 5% to about 91.9% of the capsule.
  • Deionized water is preferably used.
  • Water from natural sources including mineral cations can also be used, depending on the desired characteristic of the product.
  • water may be sourced from fermented biological cultures or its filtrates.
  • a highly preferred commercial source of this kind is Saccharomycopsis ferment filtrate by the tradename SK-II Pitera available from Kashiwayama.
  • the pH of the water phase is selected in view of the desired characteristic of the product, and particularly, when skin benefit agents are included, the activity and stability of the skin benefit agents. In one preferred embodiment the pH is adjusted from about 4 to about 8. Buffers and other pH adjusting agents can be included to achieve the desirable pH.
  • Water-Soluble Solvent
  • the water phase of the capsule of the present invention may further comprise a water- soluble solvent selected from lower alkyl alcohols and water-soluble humectants.
  • the water- soluble solvents are selected according to the desired skin feel to be delivered, and/or for delivering certain skin benefit agents.
  • Lower alkyl alcohols useful herein are monohydric alcohols having 1 to 6 carbons, more preferably ethanol and isopropanol.
  • Water soluble humectants useful herein include polyhydric alcohols such as butylene glycol (1,3-butanediol), pentylene glycol (1,2-pentanediol), glycerin, sorbitol, propylene glycol, hexylene glycol, ethoxylated glucose, 1,2-hexane diol, 1,2-pentane diol, hexanetriol, dipropylene glycol, erythritol, trehalose, diglycerin, xylitol, maltitol, maltose, glucose, fructose; and other water-soluble compounds such as urea, sodium chondroitin sulfate, sodium hyaluronate, sodium adenosin phosphate, sodium lactate, pyrrolidone carbonate, glucosamine, cyclodextrin, and mixtures thereof.
  • polyhydric alcohols such as butylene glyco
  • water soluble alkoxylated nonionic polymers such as polyethylene glycols and polypropylene glycols having a molecular weight of up to about 1000 such as those with CTFA names PEG-200, PEG-400, PEG-600, PEG-1000, and mixtures thereof.
  • the present capsule comprises from about 1% to about 30% of a water-soluble humectant. In one highly preferred embodiment wherein the capsule is used as a foundation, the capsule comprises from about 3% to about 30% of a water-soluble humectant.
  • humectants herein include: butylene glycol with tradename 1,3- Butylene Glycol available from Celanese, pentylene glycol with tradename HYDROLITE-5 available from Dragoco, glycerin with tradenames STAR and SUPEROL available from The Procter & Gamble Company, CRODEROL GA7000 available from Croda Universal Ltd., PRECERIN series available from Unichema, and a same tradename as the chemical name available from NOF; propylene glycol with tradename LEXOL PG-865/855 available from Inolex, 1 ,2-PROPYLENE GLYCOL USP available from BASF; sorbitol with tradenames LIPONIC series available from Lipo, SORBO, ALEX, A-625, and A-641 available from ICI, and UNISWEET 70, UNISWEET CONC available from UPI; dipropylene glycol with the same tradename available from BASF; diglycerin with tradename DIGLYCEROL available from
  • the collapsible water-containing capsule of the present composition may further comprise, by weight of the capsule, from about 0.1% to about 20%, preferably from about 0.1% to about 5%, of a gelling agent which, when mixed with the water phase, provides an aqueous composition having a viscosity of from about lOmPas to about l,000,000mPas, preferably from about lOmPas to about 100,000mPas.
  • a gelling agent which, when mixed with the water phase, provides an aqueous composition having a viscosity of from about lOmPas to about l,000,000mPas, preferably from about lOmPas to about 100,000mPas.
  • Incorporation of a gelling agent is advantageous, in that the gelling agent holds the water phase in a relatively rigid structure, and thereby believed to provide improved stability and integrity of the capsule.
  • the polymers useful as the gelling agent herein are water soluble or water miscible polymers.
  • the term "water soluble or water miscible" with regard to the gelling agents herein, relate to compounds that are dissolved to make a transparent solution when dissolved in ample amount of water with or without the aid of elevated temperature and/or mixing.
  • starch derivative polymers such as carboxymethyl starch, and methylhydroxypropyl starch.
  • Commercially available compounds that are highly useful herein include sodium carboxymethyl starch with tradename COVAGEL available from LCW.
  • Cellulose derivative polymers useful herein include methylcellulose, ethylcellulose, hydroxyethylcellulose, hydroxyethyl ethylcellulose, hydroxypropyl methyl cellulose, nitrocellulose, sodium cellulose sulfate, sodium carboxymethylcellulose, crystalline cellulose, cellulose powder, and mixtures thereof.
  • starch derivative polymers such as carboxymethyl starch, and methylhydroxypropyl starch.
  • Commercially available compounds that are highly useful herein include hydroxyethylcellulose with tradename Natrosol Hydroxyethylcellulose, and carboxymethylcellulose with tradename Aqualon Cellulose Gum, both available from Aqualon.
  • carboxylic acid/carboxylate copolymers Useful herein are carboxylic acid/carboxylate copolymers.
  • Commercially available carboxylic acid/carboxylate copolymers useful herein include: CTFA name Acrylates/C 10-30 Alkyl Acrylate Crosspolymer having tradenames Pemulen TR-I, Pemulen TR-2, Carbopol 1342, Carbopol 1382, and Carbopol ETD 2020, all available from B. F. Goodrich Company.
  • Neutralizing agents may be included to neutralize the carboxylic acid/carboxylate copolymers herein.
  • neutralizing agents include sodium hydroxide, potassium hydroxide, ammonium hydroxide, monoethanolamine, diethanolamine, triethanolamine, diisopropanolamine, aminomethylpropanol, tromethamine, tetrahydroxypropyl ethylenediamine, and mixtures thereof.
  • Polyalkylene glycols having a molecular weight of more than about 1000 are useful herein. Useful are those having the following general formula:
  • R 95 is selected from the group consisting of H, methyl, and mixtures thereof.
  • these materials are polymers of ethylene oxide, which are also known as polyethylene oxides, poly oxy ethylenes, and polyethylene glycols.
  • R 95 is methyl these materials are polymers of propylene oxide, which are also known as polypropylene oxides, polyoxypropylenes, and polypropylene glycols.
  • R 95 is methyl it is also understood that various positional isomers of the resulting polymers can exist.
  • x3 has an average value of from about 1500 to about 25,000, preferably from about 2500 to about 20,000, and more preferably from about 3500 to about 15,000.
  • Polyethylene glycol polymers useful herein are PEG- 2M wherein R 95 equals H and x3 has an average value of about 2,000 (PEG-2M is also known as Polyox WSR ® N-10, which is available from Union Carbide and as PEG-2,000); PEG-5M wherein R 95 equals H and x3 has an average value of about 5,000 (PEG- 5 M is also known as Polyox WSR ® N-35 and Polyox WSR ® N-80, both available from Union Carbide and as PEG- 5,000 and Polyethylene Glycol 300,000); PEG-7M wherein R 95 equals H and x3 has an average value of about 7,000 (PEG-7M is also known as Polyox WSR ® N-750 available from Union Carbide); PEG-9M wherein R 95 equals H and x
  • vinyl polymers such as cross linked acrylic acid polymers with the CTFA name Carbomer, pullulan, mannan, scleroglucans, polyvinylpyrrolidone, polyvinyl alcohol, guar gum, hydroxypropyl guar gum, xanthan gum, acacia gum, arabia gum, tragacanth, galactan, carob gum, karaya gum, locust bean gum, carrageenin, pectin, amylopectin, agar, quince seed (Cydonia oblonga Mill), starch (rice, corn, potato, wheat), algae colloids (algae extract), microbiological polymers such as dextran, succinoglucan, starch-based polymers such as carboxymethyl starch, methylhydroxypropyl starch, alginic acid-based polymers such as sodium alginate, alginic acid propylene glycol esters, acrylate polymers such as sodium polyacrylate, polyacrylamide,
  • gelling agents useful herein include xanthan gum with tradename KELTROL series available from Kelco, Carbomers with tradenames CARBOPOL 934, CARBOPOL 940, CARBOPOL 950, CARBOPOL 980, and CARBOPOL 981, all available from B. F.
  • amphoteric polymers such as Polyquaternium 22 with tradenames MERQUAT 280, MERQUAT 295, Polyquaternium 39 with tradenames MERQUAT PLUS 3330, MERQUAT PLUS 3331, and Polyquaternium 47 with tradenames MERQUAT 2001, MERQUAT 200 IN, all available from Calgon Corporation.
  • Other useful amphoteric polymers include octylacrylamine/acrylates/ butylaminoethyl methacrylate copolymers with the tradenames AMPHOMER, AMPHOMER SH701, AMPHOMER 28-4910, AMPHOMER LV71, and AMPHOMER LV47 supplied by National Starch & Chemical.
  • the collapsible water-containing capsule of the present composition comprises a pigment phase comprising at least a first pigment component having a particle size of less than l ⁇ m, preferably from about 5nm to about 600nm, more preferably from about IOnm to about 500nm.
  • the first pigment component has a hydrophobic surface, meaning the first pigment component is inherently hydrophobic, or hydrophobic ally surface coated, preferably surface coated with a lipophobic hydrophobic coating material.
  • the first pigment component is comprised, by weight of the capsule, from about 1% to about 29.9%, more preferably from about 6% to about 27%, of the capsule.
  • the first pigment component is surface coated with a lipophobic hydrophobic coating material.
  • a lipophobic hydrophobic coating material it is believed that, by the surface tension of the lipophobic hydrophobic surface of the first pigment component, the first pigment component aligns at the phase boundary of the water phase, while the particles of the first pigment component bind with each other via van-der- Waals binding. Hence, the first pigment component covers the water phase. It is further believed that the overall structure due to the lipophobic hydrophobic surface, combined with the relatively small particle size of the first pigment component, contributes to the suitable shear stress tolerance of the collapsible water-containing capsule of the present composition.
  • the base pigments of the first pigment component useful herein include those that provide color or change tone, and also those that provide a certain skin feel.
  • Useful pigments herein include clay mineral powders such as talc, magnesium silicate, synthetic fluorphlogopite, calcium silicate, aluminum silicate, silicate, bentonite and montomorilonite.
  • the coloring powders useful herein include pearl pigments such as alumina, barium sulfate, calcium secondary phosphate, zirconium oxide, zinc oxide, hydroxy apatite, iron oxide, iron titate, ultramarine blue, Prussian blue, chromium oxide, chromium hydroxide, cobalt oxide, cobalt titanate, titanium oxide coated mica; organic powders such as polyester, polyethylene, polypropylene, polystyrene, methyl metharylate copolymer, cross-linked polymethyl methacrylate, 12-nylon, 6-nylon, polystyrene, styrene- acrylic acid copolymers, vinyl chloride polymer, vinyl acetates, tetrafluoroethylene polymer, polyorganosilsesquioxane resins, solid silicone elastomers, boron nitride, fish scale guanine, laked tar color dyes, and laked natural color dyes.
  • the surface is coated with materials having hydrophobic characteristics.
  • Useful hydrophobic coating materials herein include organic silicone compounds, metal soap, oils, and material having both lipophobic and hydrophobic characteristics, such as fluorine compounds.
  • Particularly suitable fluorine compounds herein are selected from the group consisting of perfluorooctyl triethoxylsilane, perfluoroalkylphosphoric acids, their salts, and mixtures thereof.
  • first pigment components highly useful herein include Titanium Dioxide coated with C9-15 fluoroalcohol phosphates (0.25 ⁇ m) with tradename PF-5 TiO2 CR- 50, Titanium Dioxide coated with perfluorooctyl triethoxysilane (0.021 ⁇ m) with tradename FHS - 12 TiO2 P-25, Zinc Oxide coated with C9-15 fluoroalcohol phosphates (0.020 ⁇ m) with tradename PF-7 ZnO-350, Yellow Iron Oxide coated with C9-15 fluoroalcohol phosphates (0.435 ⁇ m) with tradename PF-5 YELLOW LL-100PD, Red Iron Oxide coated with C9-15 fluoroalcohol phosphates (0.44 ⁇ m) with tradename PF-5 RED R-516PD, and Black Iron Oxide coated with C9-15 fluoroalcohol phosphates (0.4 ⁇ m) with tradename PF-5 BLACK
  • the pigment phase further comprises, by weight of the capsule, from about 0.1% to about 29%, preferably from about 1% to about 10%, of a second pigment component.
  • the second pigment component herein has a particle size of l ⁇ m or more, preferably from about l ⁇ m to about 25 ⁇ m, more preferably from about 4 ⁇ m to about 15 ⁇ m, and is surface coated with a hydrophobic coating material.
  • the second pigment component has a more or less spherical shape. Without being bound by theory, it is believed that, by the larger size of the second pigment component, the second pigment component aligns at the phase boundary of the first pigment component. It is believed that the dual covered structure provided by the first and second pigment components provide the suitable shear stress tolerance of the collapsible water-containing capsule of the present composition. It is believed that pigments having spherical shape are advantageous.
  • the total of the first pigment component and the second pigment component is at least about 8% of the capsule, preferably from about 8% to about 26% of the capsule.
  • the second pigment component also provides a unique appearance effect or skin feel that is not easily delivered by the first pigment component.
  • the first pigment components alone may provide an overly matte finish and emphasize, rather than hide, skin unevenness such as pores.
  • a spherical and translucent second pigment component can improve the natural appearance by light diffusion effect due to its shape and translucency.
  • the first pigment components alone may provide a squeaky feel on the skin due to their small size.
  • a soft spherical second pigment component may alleviate such negative skin feel and provide good smooth feel.
  • the base pigments of the second pigment component useful herein include; polyacrylates, silicates, sulfates, alumina, metal dioxides, carbonates, celluloses, polyalkylenes, vinyl acetates, polystyrenes, polyamides, acrylic acid ethers, silicones, mica, and mixtures and complexes thereof.
  • materials useful herein include polyacrylates such as methyl methacrylate copolymer and nylon, cross linked polymethyl methacrylate; silicates such as calcium silicate, magnesium silicate, barium silicate, aluminium silicate and silica beads; alumina; metal dioxides such as titanium dioxide and aluminium hydroxide; carbonates such as calcium carbonate, magnesium carbonate; celluloses; polyalkylenes such as polyethylene, and polypropylene; vinyl acetates; polystyrenes; polyamides; acrylic acid ethers such as acrylic acid methyl ether and acrylic acid ethyl ether; polyvinyl pyrrolidones; and silicones such as polyorganosilsesquioxane resin and solid silicone elastomers.
  • Highly preferred materials are polymethyl methacylate.
  • polyorganosilsesquioxane resin and solid silicone elastomers may be used for enhancing the effect of hiding skin pores.
  • the second pigment component herein is surface coated with a coating material having hydrophobic characteristics, whereby lipophobic hydrophobic coating materials are preferred.
  • Useful hydrophobic coating materials herein include methyl polysiloxane, methyl hydrogen polysiloxane, methyl phenyl polysilxoane, n-octyl triethoxy silane, methyl- alpha- styrene polysiloxane, acryl silicone copolymer, and mixtures thereof.
  • Preferred lipophobic hydrophobic coating materials are the same coating material as aforementioned for the first pigment component.
  • second pigment components highly useful herein include mica (lO ⁇ m) with tradename SERICITE FSE available from Sanshin Kohkoh.
  • commercially available spherical second pigment components highly useful herein include methyl methacylate copolymer with tradename GANZ PEARL series available from Ganz Chemical Co., Ltd., and SYLYSIA series available from Fuji Sylysia Chemical, Nylon- 12 with tradename NYLON POWDER series available from Toray Dow Corning, Nylon-12 coated with C9-15 fluoroalcohol phosphates (5 ⁇ m) with tradename PF-5 NYLON SP 500 available from Daito Kasei, polymethyl silsesquioxane coated with with C9-15 fluoroalcohol phosphates with tradename PF-5 TOSPEARL 145 available from Daito Kasei, vinyl dimethicone/methicone silsesquioxane crosspolymer with tradenames KSP series available from ShinEtsu Chemical Co., Ltd., Tokyo
  • the present invention relates to suitable processes for making the collapsible water- containing capsules as described above in an effective manner, while the physical structures of the capsules are maintained.
  • the process relates to mixing the water phase and the pigment phase, the pigment phase comprising at least a first pigment component having a particle size of less than l ⁇ m and a hydrophobic surface.
  • main mixing the mixing of the water phase and the pigment phase for forming the capsule
  • premixing mixing of certain compositional components prior to the main mixing
  • the first pigment component aligns at the phase boundary of the water phase, while the particles of the first pigment component bind with each other via van-der-Waals binding.
  • the suitable processes herein are those which provide enough energy to micronize the water phase or maintain the size of the micronized water phase, to allow the first pigment components to align at the phase boundary and form a stable capsule, yet do not provide the shear stress that would immediately destroy the physical structure of the capsule.
  • Preferably avoided are means that apply high shear stress to the capsules, such as high speed agitation, and mechanical mixing means that provide crushing or kneading.
  • the water phase and the pigment phase are separately prepared prior to main mixing.
  • the pigment phase may be pulverized to fragmentate any agglomeration which may interfere with the following capsule making process.
  • the gelling agent may be premixed with either the water phase or the pigment phase, depending on the physical properties of the compositional components, and the components of the mixing apparatus.
  • the water phase may be sprayed as is, or premixed with the gelling agent prior to main mixing. The flow rate of atomizing is adjusted to provide the desired size of the capsule.
  • the inner wall of the vessel for main mixing is hydrophobically coated with, for example, silicone or Teflon, to lower the surface energy of the inner wall, and thereby provide the capsule making in an efficient manner.
  • the inner wall of the final primary package should have a surface energy of 50dyne/cm or less, preferably 40dyne/cm or less.
  • Suitable mixing apparatus herein are the external energy sourcing type or container shaking type. These apparatus are those which do not have a mixing blade or the like within the vessel in which the capsule is made. These apparatus are advantageous in that there is hardly any, or only a controllable amount of shear stress provided during the making process. These apparatus are also advantageous in that the making process is done in a relatively short length of time.
  • Mixing apparatus of the external energy sourcing type include, but are not limited to, vibratory mixer, and resonant frequency mixer.
  • Vibratory mixers are those that provide convection mixing by impact of vertical shaking motion, gyrostopic oscillating or vibration frequency.
  • Resonant frequency mixers are those that use an oscillator to excite the material for mixing by high efficient energy transfer.
  • Mixing apparatus of the container shaking type are those that provide movement by alternative acceleration and retardation, rather than a rotating movement.
  • these external energy sourcing type or container shaking type apparatus the compositional components for making the capsule are simply filled in the mixing vessel together, and mixed.
  • the mixing vessel is not inverted, and there is no need to supply the water phase via spray or atomization.
  • these apparatus may be used for providing a process wherein the capsule is directly made in a final primary packaging for consumer use, sometimes called the "make-in-pack" process.
  • the present process relates to the use of a mixing apparatus of the external energy sourcing type or container shaking type, wherein the capsule is to be provided in a final primary packaging for consumer use, wherein the process comprises the steps of: i) directly supplying the water phase and the pigment phase in the final primary packaging; and ii) mounting the product of step i) onto the mixing apparatus for making the capsule.
  • the final primary packaging means the primary packaging in which the user receives the product, rather than an interim vessel or package which is only used for delivering or filling the product into a final primary package.
  • Vibratory Mixer and Vibratory Mixer Type 1 available from Tsukishima Techno Machinery Co., Ltd.
  • resonant frequency mixers highly preferred herein include Resodyn Acoustic Mixers available from Resodyn Corporation.
  • Container shaking type mixers that do not provide rotating movement are those that provide convection mixing by impact of alternative acceleration or retardation of gyroscopic shaking motion.
  • shaker mixers highly preferred herein include TURBULA Shaker Mixer (T2F) and Dyna Mix available from Willy A. Bachofen AG, and COROB M300/CORB and VIBRO available from CPS Color.
  • Suitable mixing apparatus herein are the fluidizer type, mechanical mixing type and container rotating type.
  • Mixing apparatus of the fluidizer type are those wherein air is delivered for mixing.
  • Fluidizer mixers are advantageous in providing homogenous particles size.
  • Mechanical mixing mixers are those that have some kind of revolving shaft, ribbon, screw, paddle, or combination thereof.
  • Mixing apparatus of the mechanical mixing type are those which provide low shear mixing including, but not limited to, ribbon blender, screw blender, and paddle mixer.
  • Container rotating mixers are those which provide convention mixing by sliding and falling down impact, shear compaction and revolvement, caused by the rotating movement of the container itself.
  • Mixing apparatus of the container rotating type include but are not limited to, V-mixer, and double conical mixer.
  • the water phase is delivered via an atomizing system.
  • the atomizing system can be a sprayer or a misting device, depending on the type of the mixing apparatus.
  • V- blender and Double-conical mixer available from Tokuju Corporation.
  • fluidizer mixers highly preferred herein include MULTIPLEX Type MP-Ol available from Powrex, and Fluid Bed Granulator available from Glatt.
  • mechanical mixing mixers highly preferred herein include Granurex available from Powrex Freund, Ribbon Blender available from Dalton Corporation, Ribbon Blender RB-8.5-05S available from Toyo Hi- Tech Co. Ltd., and paddle mixer Bella Fluidized Zone Mixer available from DYNAMIX AIR Inc.
  • the present capsule is provided to the end user as a preparation- at-use product for providing a collapsible water-containing capsule comprising:
  • a pigment phase comprising at least a first pigment component having a particle size of less than l ⁇ m and a hydrophobic surface
  • step i) a final primary packaging having an inner wall having a surface tension of 50dyne/cm or less; wherein the water phase and the pigment phase are separately packaged prior to use, and wherein the capsule is made by the steps of; i) filling the water phase and the pigment phase into the final primary packaging; and ii) manually shaking the product of step i) until the water phase is encapsulated in the pigment phase.
  • the capsule making process happens at use by manual shaking of the user.
  • preparation-at-use product provides the user of the feeling that the product is freshly made upon use, and/or the amusement of making the product.
  • preparation- at-use action may be used as an effective demonstration of making the product for market promotion or otherwise.
  • the capsules hereof may further contain additional components such as are conventionally used in topical products, e.g., for providing aesthetic or functional benefit to the composition or personal surface, such as sensory benefits relating to appearance, smell, or feel, therapeutic benefits, or prophylactic benefits (it is to be understood that the above-described required materials may themselves provide such benefits).
  • the capsule of the present invention may comprise various skin benefit agents and perfumes in a dissolved or dispersed form in the water phase or attracted within the pigment phase. It is advantageous to deliver such skin benefit agents, and perfumes encompassed in the present collapsible water-containing capsule, for one or more reasons. For those components that are heat sensitive, the present capsule prevents or delays evaporation prior to use.
  • the present capsules act as a barrier.
  • Other components may provide a certain sensation upon application and collapsing of the present capsule.
  • the total amount of additional components are kept to no more than about 10% by weight of the capsule.
  • Powders and pigments that do not meet the definition of the first and second pigment components described above may be included as additional components. Namely, powders and pigments that do not have a hydrophobic surface, and powders and pigments having a particle size of l ⁇ m or more that have a non-spherical shape such as platelet and needle shape. Such additional powders are preferably not mixed with the pigment phase in the process, but are added after the water phase and pigment phase are mixed to make the capsule. Without being bound by theory, it is believed that separating the additional powders from the initial capsule making process step provides a more stable capsule.
  • compositions of the present capsule and suitable processes for making such capsules.
  • Table 1 Composition Examples 1-4 in weight percentage
  • Titanium Dioxide (0.040 ⁇ m): Titanium Dioxide TTO-55 available from Ishihara.
  • *18 Polyoxyethylene Methylpolysiloxane Copolymer KF-6018 from ShinEtsu Chemical.
  • D-delta-tocopherol D-DELTA-TOCOPHEROL available from EISAI CO., LTD.
  • Mulberry Root Extract Mulberry BG, available from Maruzen Pharmaceuticals.
  • Components (l)-(8) and (12)-(13) make the pigment phase.
  • the pigment phase components are mixed using a high speed fluidizing mixer or ribbon blender and further pulverized using a pulvelizer. A de- agglomerated fine powder mixture of the pigment phase is obtained.
  • Components (21)-(33) are the water phase components and other hydrophilic components. For purposes of explanation of the process embodiments below, components (21)- (33) will be collectively referred to as the water phase.
  • the water phase components are mixed using an agitator in the container.
  • Components (9)-(ll) make the gelling agent.
  • Components (14)-(20) and (34) are additional powders other hydrophobic components, and perfume.
  • the additional powders may be premixed in the same manner as the pigment phase.
  • components (14)-(20) and (34) will be collectively referred to as additional powders.
  • the capsule of any composition of Example 1-4 can be made by Vibratory Mixer Type 1 from TSUKISHIMA TECHNO-MACHINERY CO., Ltd. as follows:
  • the loading amount of each component is adjusted to make a 10kg batch size.
  • the pigment phase is transferred to a vibratory mixer vessel (VF-IM, 28L) at amplitude of vibration (5-50mm) and oscillation frequency (200-1000rpm). Under the same mixing condition, the water phase and gelling agent are added into the vessel until formation of capsule. Under the same mixing condition, the additional powders, if any, are added.
  • VF-IM vibratory mixer vessel
  • Process Example 2 Acoustic Resonance Frequency mixer
  • Example 1-4 The capsule of any composition of Example 1-4 can be made by LabRAM from Resodyn Corporation as follows:
  • the loading amount of each component is adjusted to make a 30Og batch size.
  • the pigment phase, water phase, and gelling agent are transferred to a mixing container (50OmL) and mixed at 5-80G acceleration until the formation of capsule. Under the same mixing condition, the additional powders, if any, are added.
  • Process Example 3. Shaker Mixer
  • Example 1-4 The loading amount of each component is adjusted to make a 42Og batch size.
  • the capsule of any composition of Example 1-4 can be made by TURBULA-Shaker from Willy A. Bachofen AG as follows:
  • Example 1-4 The capsule of any composition of Example 1-4 can be made by MULTIPLEX Type MP-Ol from POWREX as follows:
  • the loading amount of each component is adjusted to make a 75Og batch size.
  • the pigment phase and gelling agent are transferred to the fluidizer system.
  • the water phase is fed into the atomizer, and the atomizer is mounted onto the mixing apparatus.
  • the water phase is fed into the atomizer, and the atomizer is mounted onto the mixing apparatus.
  • the water phase is atomized at 10-80NL/min in an amount of 20-7Og of water phase/min, while air flow rate of 5-20m 3 /min is provided in the fluidizing bed until the formation of capsule. Under the same mixing condition, the additional powders, if any, are added.
  • Process Example 5 Mechanical Mixer
  • the capsule of any composition of Example 1-4 can be made by Ribbon Blender, RB- 8.5-05S from Toyo Hi-Tech Co. Ltd. as follows:
  • the loading amount of each component is adjusted to make a 1500g batch size.
  • the pigment phase and gelling agent are transferred to the ribbon blender mixer.
  • the water phase is fed into the atomizer, and the atomizer is mounted onto the mixing apparatus.
  • the water phase is atomized into the ribbon blender at 10-80NL/min in an amount of 20-7Og of water phase/min, and mixed until the formation of capsule. Under the same mixing condition, the additional powders, if any, are added.
  • Process Example 6 Mechanical Mixer
  • the capsule of any composition of Example 1-4 can be made by paddle mixer, Bella Fluidized Zone Mixer available from DYNAMIX AIR Inc as follows: The loading amount of each component is adjusted to make a 360Og batch size. The pigment phase and gelling agent are transferred to the paddle mixer. The water phase is fed into the atomizer, and the atomizer is mounted onto the mixing apparatus. The water phase is atomized into the paddle mixer at 10-80NL/min in an amount of 100-500g of water phase/min, and mixed until the formation of capsule. Under the same mixing condition, the additional powders, if any, are added. Process Example 7. Acoustic Resonance Frequency mixer
  • the capsule of Example 1 can be made by make-in-pack method using LabRAM from Resodyn Corporation as follows:
  • the loading amount of each component is adjusted to make a 1Og batch size.
  • the pigment phase, water phase, and gelling agent are transferred to a final primary packaging made of polyethylene terephthalate (30g, surface tension of inner wall less than 40dyne/cm), mounted onto the mixing apparatus, and mixed at 5-80G acceleration until the formation of capsule.
  • Process Example 8. Shaker Mixer
  • Example 1 The capsule of Example 1 can be made by make-in-pack method using TURBULA- Shaker from Willy A. Bachofen AG as follows:
  • the loading amount of each component is adjusted to make a 1Og batch size.
  • the pigment phase, water phase, and gelling agent are transferred to a final primary packaging made of polyethylene terephthalate (30g, surface tension of inner wall less than 40dyne/cm), mounted onto the mixing apparatus, and mixed at 49-101rpm until the formation of capsule.
  • the capsules of Composition Examples 1 and 4 made by any of the Process Examples 1- 6 above are stable under normal storage conditions as well as normal mixing processes, however, collapses upon application.
  • the capsules of Composition Example 1 made by any of the Process Examples 7-8 are also stable under normal storage conditions as well as normal mixing processes, however, collapses upon application.
  • Products of Example 1 made by any of the Process Examples 1-8 above and Example 4 made by any of the Process Examples 1-6 above are useful as foundation products.
  • Products of Example 2 made by any of the Process Examples 1-6 above are useful as whitening powders.
  • Products of Example 3 made by any of the Process Examples 1-6 above are useful as point make-up products. These products, when applied to the skin, provide good fit on the skin, favorable moisturizing and cooling sensation, even coverage, and long wear on the skin.
  • the dimensions and values disclosed herein are not to be understood as being strictly limited to the exact numerical values recited. Instead, unless otherwise specified, each such dimension is intended to mean both the recited value and a functionally equivalent range surrounding that value. For example, a dimension disclosed as "40 mm” is intended to mean “about 40 mm.”

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Abstract

L'invention concerne des procédés de fabrication d'une capsule déformable contenant de l'eau renfermant une phase aqueuse encapsulée ou dispersée dans une phase pigmentaire, la phase pigmentaire comprenant au moins un premier constituant pigmentaire ayant une taille de particules de moins de 1 µm et une surface hydrophobe ; dans lesquels la phase aqueuse et la phase pigmentaire sont mélangées par un appareil de mélangeage tel qu'un appareil du type source d'énergie externe et du type récipient vibrant, du type fluidiseur, du type appareil de mélangeage mécanique et du type appareil à récipient rotatif. L'invention décrit également des produits fabriqués par les procédés précédents. Elle décrit en outre les produits destinés à une préparation presque prête à l'emploi pour fournir une capsule déformable contenant de l'eau.
PCT/IB2007/053148 2006-08-08 2007-08-08 Procédé de fabrication de capsules déformables contenant de l'eau WO2008018041A2 (fr)

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CA002658990A CA2658990A1 (fr) 2006-08-08 2007-08-08 Procede de fabrication de capsules deformables contenant de l'eau
JP2009523434A JP2010500339A (ja) 2006-08-08 2007-08-08 崩壊性含水カプセルを製造するためのプロセス
CN2007800293890A CN101500699B (zh) 2006-08-08 2007-08-08 制备可崩解含水胶囊的方法
EP07826015A EP2069064A2 (fr) 2006-08-08 2007-08-08 Procédé de fabrication de capsules déformables contenant de l'eau
AU2007282910A AU2007282910B2 (en) 2006-08-08 2007-08-08 Process for making collapsible water-containing capsules

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JP2012517431A (ja) * 2009-02-06 2012-08-02 ザ プロクター アンド ギャンブル カンパニー 崩壊性水含有カプセル
JP2012519154A (ja) * 2009-02-06 2012-08-23 ザ プロクター アンド ギャンブル カンパニー 崩壊性水含有カプセル

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US20080038302A1 (en) 2008-02-14
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WO2008018041A3 (fr) 2008-06-19
CN101500528A (zh) 2009-08-05
CA2658990A1 (fr) 2008-02-14
CN101500699B (zh) 2013-08-21
EP2051801A2 (fr) 2009-04-29
CN101500699A (zh) 2009-08-05
EP2069064A2 (fr) 2009-06-17
AU2007282910A1 (en) 2008-02-14
US20080038557A1 (en) 2008-02-14
KR20090031932A (ko) 2009-03-30

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