Classifications

• • A—HUMAN NECESSITIES
  • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
  • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
  • A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
  • A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
  • A01N57/12—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing acyclic or cycloaliphatic radicals

Definitions

• the present invention relates to novel drug combinations containing as active ingredients Cadusafos and another active ingredient from the series of neonicotinoids and have very good insecticidal properties.
• mixtures comprising cadusafos and at least one compound from the series of the neonicotinoids mentioned below are synergistically active and are suitable for controlling animal pests. Because of this synergism, significantly lower levels of drug can be used, i. the effect of the mixture is greater than the effect of the individual components.
• Clothianidin has the formula
• Acetamiprid has the formula
• Nitenpyram has the formula
• Imidaclothiz has the formula
• Cadusafos has the formula shown at the beginning and is known from "The Pesticide Manual", 13 * Edition, 2003, published by the British Crop Protection Council, page 129.
• the ratio of the active ingredients used, as well as the total amount of the mixture to be used depends on the nature and the occurrence of the insects.
• the optimal ratios and total amounts can be determined in each application by test series.
• a particularly preferred mixture according to the invention comprises the active ingredients Cadusafos and Imidacloprid.
• the weight ratio of the respective active ingredients to each other is between 1000 to 1 and 1 to 125, preferably between 125 to 1 and 1 to 50 and particularly preferably between 25 to 1 and 1 to 5, here as in the following Cadusafos in the proportions first mentioned.
• Another particularly preferred mixture according to the invention comprises the active ingredients Cadusafos and acetamiprid.
• the weight ratio of both active ingredients is between 1000: 1 and 1: 125, preferably between 125: 1 and 1: 50, and more preferably between 25: 1 and 1: 5.
• Another particularly preferred mixture according to the invention comprises the active ingredients cadusafos and nitenpyram.
• the weight ratio of both active ingredients is between 1000: 1 and 1: 125, preferably between 125: 1 and 1: 50, and more preferably between 25: 1 and 1: 5.
• Another particularly preferred mixture according to the invention comprises the active ingredients cadusafos and dinotefuran.
• the weight ratio of both active ingredients is between 1000: 1 and 1: 125, preferably between 125: 1 and 1: 50, and more preferably between 25: 1 and 1: 5.
• Another particularly preferred mixture according to the invention comprises the active ingredients Cadusafos and Thiacloprid.
• the weight ratio of both active ingredients is between 1000: 1 and 1: 125, preferably between 125: 1 and 1: 50, and more preferably between 25: 1 and 1: 5.
• Another particularly preferred mixture according to the invention comprises the active ingredients Cadusafos and Imidaclothiz.
• the weight ratio of both active ingredients is between 1000: 1 and 1: 125, preferably between 125: 1 and 1: 50, and more preferably between 25: 1 and 1: 5.
• a particularly preferred mixture according to the invention comprises the active ingredients cadusafos and clothianidin.
• the weight ratio of the two active substances to one another is between 1000 to 1 and 1 to 125, preferably between 125 to 1 and 1 to 50 and particularly preferably between 25 to 1 and 1 to 5, wherein, as also above, Cadusafos in the ratios in each case first mentioned.
• the mixtures mentioned above as preferred contain no further insecticidally active ingredient.
• the active substance combinations are suitable with good plant tolerance and favorable warm-blood toxicity for combating animal pests, in particular insects, arachnids and nematodes, which occur in agriculture, in forests, in the protection of stored products and in the hygiene sector. They can preferably be used as crop protection agents in foliar and soil treatment.
• pests are effective against normally sensitive and resistant species as well as against all or individual stages of development.
• the above mentioned pests include:
• Isopoda for example, Oniscus asellus, Armadillidium vulgare, Porcellio scaber. From the order of Diplopoda eg Blaniulus guttulatus. From the order of Chilopoda eg Geophilus carpophagus, Scutigera spp. From the order of the Symphyla eg Scutigerella immaculata. From the order of Thysanura eg Lepisma saccharina. From the order of the Collembola eg Onychiurus armatus.
• Phthiraptera for example, Pediculus humanus corporis, Haematopinus spp., Linognathus spp., Trichodectes spp., Damalinia spp. From the order of Thysanoptera eg Hercinothrips femoralis, Thrips tabaci, Thrips palmi, Frankliniella occidentalis. From the order of Heteroptera eg Eurygaster spp., Dysdercus intermedius, Piesma quadrata, Cimex lectularius, Rhodnius prolixus, Triatoma spp.
• From the order of Homoptera for example, Aleurodes brassicae, Bemisia tabaci, Trialeurodes vaporariorum, Aphis gossypii, Brevicoryne brassicae, Cryptomyzus ribis, Aphis fabae, Aphis pomi, Eriosoma lanigerum, Hyalopterus arundinis, Phylloxera vastatrix, Pemphigus spp., Macrosiphum avenae, Myzus spp.
• Sitophilus spp. Sitophilus spp., Otiorrhynchus sulcatus, Cosmopolites sordidus, Ceuthorrhynchus assimilis, Hypera postica, Dermestes spp., Trogoderma spp., Anthrenus spp., Attagenus spp., Lyctus spp., Meligethes aeneus, Ptinus spp., Niptus hololeucus, Gibbium psylloides, Tribolium spp., Tenebrio molitor, Agriotes spp., Conoderus spp., Melolontha melolontha, Amphimallon solstitialis, Costelytra zealandica, Lissorhoptrus oryzophilus.
• Hymenoptera eg Diprion spp. From the order of Hymenoptera eg Diprion spp., Hoplocampa spp., Lasius spp., Monomorium pharaonis, Vespa spp.
• Diptera eg Aedes spp., Anopheles spp., Culex spp., Drosophila melanogaster, Musca spp., Fannia spp., Calliphora erythrocephala, Lucilia spp., Chrysomyia spp., Cuterebra spp., Gastrophilus spp., Hyppobosca spp , Stomoxys spp., Oestrus spp., Hypoderma spp., Tabanus spp., Tannia spp., Bibio hortulanus, Oscinella trit, Phorbia spp., Pegomyia hyoscyami
• Psoroptes spp. Chorioptes spp., Sarcoptes spp., Tarsonemus spp., Bryobia praetiosa, Panonychus spp., Tetranychus spp., Hemitarsonemus spp., Brevipalpus spp.
• the plant parasitic nematodes include e.g. Pratylenchus spp., Radopholus similis, Ditylenchus dipsaci, Tylenchulus semipenetrans, Heterodera spp., Globodera spp., Meloidogyne spp., Aphelenchoides spp., Longidorus spp., Xiphinema spp., Trichodorus spp., Bursaphelenchus spp.
• the active ingredient combinations are particularly suitable for controlling nematodes and insects.
• plants and parts of plants can be treated.
• plants are understood as meaning all plants and plant populations, such as desired and undesired wild plants or crop plants (including naturally occurring cultivated plants).
• Crop plants can be plants which can be obtained by conventional breeding and optimization methods or by biotechnological and genetic engineering methods or combinations of these methods, including the transgenic plants and including the plant varieties which can or can not be protected by plant breeders' rights.
• Plant parts are to be understood as meaning all aboveground and subterranean parts and organs of the plants, such as shoot, leaf, flower and root, examples of which include leaves, needles, stems, stems, flowers, fruiting bodies, fruits and seeds, and roots, tubers and rhizomes.
• the plant parts also include crops and vegetative and generative propagation material, such as cuttings, tubers, rhizomes, offshoots and seeds.
• the treatment according to the invention of the plants and plant parts with the active compound combinations takes place directly or by acting on their environment, habitat or storage space according to the usual treatment methods, e.g. by dipping, spraying, evaporating, nebulizing, spreading, brushing and propagating material, in particular in seeds, further by single or multi-layer coating.
• the mixtures according to the invention in particular the combination of the active ingredients imidacloprid and cadusafos and also clothianidin and cadusafos, are suitable for the treatment of seed. This is how much of the damage caused by pests is created
• the present invention therefore also relates, in particular, to a method of protecting seeds and germinating plants from attack by pests, by adding a seed to a seed
• the active ingredient combination according to the invention is treated.
• the method according to the invention for the protection of seeds and germinating plants from attack by pests comprises a method in which the seed is treated at the same time with an active compound of the formula I and thiamethoxam. It also includes a method in which the seed is treated at different times with an active ingredient of formula I and thiamethoxam.
• the invention also relates to the use of the active ingredient combinations according to the invention for the treatment of seed for the protection of the seed and the resulting plant from pests.
• the invention relates to seed which has been treated for protection against pests with a combination of active substances according to the invention.
• the invention also relates to seed treated at the same time with an active ingredient of formula I and thiamethoxam.
• the invention further relates to seed which has been treated at different times with an active compound of the formula I and thiamethoxam.
• the individual active compounds of the agent according to the invention may be present in different layers on the seed.
• the layers containing an active ingredient of the formula I and thiamethoxam may optionally be separated by an intermediate layer.
• the invention also relates to seed in which an active substance of the formula I and thiamethoxam are applied as a constituent of a coating or as a further layer or further layers in addition to a coating.
• One of the advantages of the present invention is that because of the particular systemic properties of the compositions of the invention, treatment of the seed with these agents not only protects the seed itself, but also the resulting plants after emergence from pests. In this way, the immediate treatment of the culture at the time of sowing or shortly afterwards can be omitted.
• a further advantage consists in the synergistic increase in the insecticidal activity of the agents according to the invention over the respective individual active ingredient, which goes beyond the sum of the efficacy of the two individually applied active ingredients. This allows optimization of the amount of active ingredient used.
• the mixtures according to the invention can also be used in particular in the case of transgenic seed, wherein the plants resulting from this seed are capable of expressing a protein directed against pests.
• certain pests can already be controlled by the expression of the insecticidal protein, for example, and, in addition, surprisingly, to a synergistic action supplement with the invention. appropriate means comes, what the effectiveness of the protection against pest infestation once again improved.
• compositions according to the invention are suitable for the protection of seed of any plant variety as already mentioned above, which is used in agriculture, in the greenhouse, in forests or in horticulture.
• these are maize, peanut, canola, rapeseed, poppy, soybean, cotton, turnip (e.g., sugar beet and fodder beet), rice, millet, wheat, barley, oats, rye, sunflower or tobacco seeds.
• the compositions according to the invention are likewise suitable for the treatment of the seed of fruit plants and vegetables as already mentioned above.
• the mixture according to the invention comprising the active ingredients cadusafos and imidacloprid or clothianidin and cadusafos in particular for the treatment of the seed of maize, the seed of cotton and beets.
• transgenic seed with a composition according to the invention is of particular importance.
• the heterologous genes in transgenic seed can come from microorganisms such as Bacillus, Rhizobium, Pseudomonas, Serratia, Trichoderma, Clavibacter, Glomus or Gliocladium.
• the present invention is particularly useful for the treatment of transgenic seed containing at least one heterologous gene derived from Bacillus sp. and whose gene product shows activity against corn borer and / or corn rootworm. Most preferably, this is a heterologous gene derived from Bacillus thuringiensis.
• the combination of the invention are particularly suitable for the seed of corn.
• the agent according to the invention is applied to the seed alone or in a suitable formulation.
• the seed is treated in a condition that is so stable that no damage occurs during the treatment.
• the treatment of the seed can be done at any time between harvesting and sowing.
• seed is used which is separate from the plant and from
• the agents according to the invention can be applied directly, ie without containing further components and without being diluted.
• suitable formulations and methods for seed treatment are known to those skilled in the art and are described e.g. in the following documents: US 4,272,417 A, US 4,245,432 A, US 4,808,430 A, US 5,876,739 A, US 2003/0176428 A1, WO 2002/080675 A1, WO 2002/028186 A2.
• the active compound combinations can be converted into the customary formulations, such as solutions, emulsions, wettable powders, suspensions, powders, dusts, pastes, soluble powders, granules, suspension-emulsion concentrates, active substance-impregnated natural and synthetic substances and superfine encapsulations in polymers substances.
• formulations are prepared in a known manner, e.g. by mixing the active compounds with extenders, ie liquid solvents and / or solid carriers, if appropriate using surface-active agents, ie emulsifiers and / or dispersants and / or foam-forming agents.
• Suitable liquid solvents are essentially: aromatics, such as xylene, toluene, or alkylnaphthalenes, chlorinated aromatics and chlorinated aliphatic hydrocarbons, such as chlorobenzenes, chloroethylenes or methylene chloride, aliphatic hydrocarbons, such as cyclohexane or paraffins, e.g.
• Petroleum fractions mineral and vegetable oils, alcohols such as butanol or glycol and their ethers and esters, ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents such as dimethylformamide and dimethyl sulfoxide, and water.
• alcohols such as butanol or glycol and their ethers and esters
• ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone
• strongly polar solvents such as dimethylformamide and dimethyl sulfoxide, and water.
• Suitable solid carriers are:
• ammonium salts and ground natural minerals such as kaolins, clays, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth and synthetic minerals, such as highly silicic acid, aluminum nitrate and silicates, as solid Shinstcffe for granules come in.
• emulsifiers and / or foam formers are: for example nonionic and anionic emulsifiers, such as polyoxyethylene fatty acid esters, polyoxyethylene fatty alcohol Ethers, for example alkylaryl polyglycol ethers, alkylsulfonates, alkyl sulfates, arylsulfonates and protein hydrolysates; suitable dispersants are: for example, lignin-sulphite liquors and methylcellulose.
• Adhesives such as carboxymethylcellulose, natural and synthetic powders, granules or latexes such as gum arabic, polyvinyl alcohol, polyvinyl acetate and natural phospholipids such as cephalins and lecithins and synthetic phospholipids may be used in the formulations.
• Other additives may be mineral and vegetable oils.
• Dyes such as inorganic pigments, e.g. Iron oxide, titanium oxide, ferrocyan blue and organic dyes such as alizarin, azo and metal phthalocyanine dyes and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc.
• inorganic pigments e.g. Iron oxide, titanium oxide, ferrocyan blue and organic dyes such as alizarin, azo and metal phthalocyanine dyes and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc.
• the formulations generally contain between 0.1 and 95% by weight of active compound, preferably between 0.5 and 90%.
• the active compound combinations according to the invention preferably contain, in addition Cadusafos and said neonicotinoids no further active ingredients.
• the active compound combinations according to the invention may optionally be present in commercially available formulations and in the forms of use prepared from these formulations in admixture with still other active ingredients such as insecticides, attractants, sterilants, bactericides, acaricides, nematicides, fungicides, growth-regulating substances or herbicides.
• active ingredients such as insecticides, attractants, sterilants, bactericides, acaricides, nematicides, fungicides, growth-regulating substances or herbicides.
• the insecticides include, for example, phosphoric acid esters, carbamates, carboxylic esters, chlorinated hydrocarbons, phenylureas, microorganism-produced substances and the like.
• Particularly favorable mixing partners are e.g. the following:
• the active compound combinations according to the invention may also be present when used as insecticides in their commercial formulations as well as in the formulations prepared from these formulations in admixture with synergists.
• Synergists are compounds that increase the effect of the active ingredients without the added synergist itself having to be active.
• the active substance content of the application forms prepared from the commercial formulations can vary within wide ranges.
• the active ingredient concentration of the use forms may be from 0.0000001 to 95% by weight of active ingredient, preferably between 0.0001 and 1% by weight.
• the application is done in a custom forms adapted to the application forms.
• the active substance combinations When used against hygiene and storage pests, the active substance combinations are distinguished by an excellent residual action on wood and clay and by a good alkali stability on limed substrates.
• the active compound combinations according to the invention not only act against plant, hygiene and storage damage, but also on your vctEnnärrncdiZinischcr; Sector includes animal parasites (ectoparasites) such as ticks, leather ticks, mange mites, running mites, flies (stinging and licking), parasitic fly larvae, lice, hair pieces, featherlings and fleas.
• animal parasites ectoparasites
• ectoparasites such as ticks, leather ticks, mange mites, running mites, flies (stinging and licking), parasitic fly larvae, lice, hair pieces, featherlings and fleas.
• the active compound combinations according to the invention are also suitable for controlling arthropods, the livestock, such as cattle, sheep, goats, horses, pigs, donkeys, Camels, buffaloes, rabbits, chickens, turkeys, ducks, geese, bees, other pets such as dogs, cats, caged birds, aquarium fish and so-called experimental animals, such as hamsters, guinea pigs, rats and mice infested.
• livestock such as cattle, sheep, goats, horses, pigs, donkeys, Camels, buffaloes, rabbits, chickens, turkeys, ducks, geese, bees, other pets such as dogs, cats, caged birds, aquarium fish and so-called experimental animals, such as hamsters, guinea pigs, rats and mice infested.
• enteral administration in the form of, for example, tablets, capsules, infusions, Drenchen, granules, pastes, BoIi, the feed-through process, suppositories
• parenteral administration such as by Injections (intramuscular, sub
• the active ingredients can be used as formulations (for example, powders, emulsions, flowable agents) containing the active ingredients in an amount of 1 to 80% by weight, directly or after 100 to 10,000 dilution or use as a chemical bath.
• formulations for example, powders, emulsions, flowable agents
• the active compound combinations according to the invention have a high insecticidal activity against insects which destroy industrial materials.
• Non-living materials such as preferably plastics, adhesives, glues, papers and cardboard, leather, wood, wood processing products and paints.
• the material to be protected from insect attack is wood and woodworking products.
• wood and woodworking products which can be gesumlzl by the composition according to the invention or mixtures thereof, is to be understood by way of example:
• the active compound combinations can be used as such, in the form of concentrates or generally customary formulations such as powders, granules, solutions, suspensions, emulsions or pastes.
• the formulations mentioned can be prepared in a manner known per se, e.g. by mixing the active compounds with at least one solvent or diluent, emulsifier, dispersing and / or binding or fixing agent, water repellent, optionally siccatives and UV stabilizers and optionally dyes and pigments, and further processing aids.
• the insecticidal agents or concentrates used for the protection of wood and wood-based materials contain the active ingredient according to the invention in a concentration of 0.0001 to 95 wt .-%, in particular 0.001 to 60 wt .-%.
• the amount of agents or concentrates used depends on the nature and occurrence of the insects and on the medium.
• the optimal amount used can be determined in each case by test series. In general, however, it is sufficient to use 0.0001 to 20% by weight, preferably 0.001 to 10% by weight, of the active ingredient, based on the material to be protected.
• the solvent and / or diluent used is an organic-chemical solvent or solvent mixture and / or an oily or oily medium organic-chemical solvent or solvent mixture and / or a polar organic-chemical solvent or solvent mixture and / or water and optionally one Emulsifier and / or wetting agent.
• organic-chemical solvents are preferably oily or oily solvents having an evaporation number above 35 and a flash point above 30 0 C, preferably above 45 ° C used.
• water-insoluble, oily and oily solvents corresponding mineral oils or their aromatic fractions or mineral oil-containing solvent mixtures, preferably white spirit, petroleum and / or alkylbenzene are used.
• liquid aliphatic hydrocarbons having a boiling range of 180 to 210 0 C or high-boiling mixtures of aromatic and aliphatic Hydrocarbons having a boiling range of 180 to 220 0 C and / or lock oil and / or monochloronaphthalene, preferably ⁇ -Monochlornaphthalin used.
• the organic non-volatile oily or oily solvents having an evaporation number above 35 and a flash point above 30 0 C, preferably above 45 ° C, can be partially replaced by light or medium volatile organic chemical solvents, with the proviso that the solvent mixture also has an evaporation number 35 and above 45 ° C, has a flashpoint above 3O 0 C, preferably and that the insecticide-fungicide mixture is soluble or emulsifiable in this solvent mixture.
• a portion of the organic chemical solvent or solvent mixture is replaced by an aliphatic polar organic chemical solvent or solvent mixture.
• aliphatic organic chemical solvents containing hydroxyl and / or ester and / or ether groups are used, for example glycol ethers, esters or the like.
• organic-chemical binders are the water-dilutable and / or soluble or dispersible or emulsifiable synthetic resins and / or binding drying oils used in the organic-chemical solvents used, in particular binders consisting of or containing an acrylate resin, a vinyl resin, eg Polyvinyl acetate, polyester resin, polycondensation or polyaddition resin, polyurethane resin, alkyd resin or modified alkyd resin, phenolic resin, hydrocarbon resin such as indene coumarone resin, silicone resin, drying vegetable and / or drying oils and / or physically drying binders based on a natural and / or or synthetic resin used.
• binders consisting of or containing an acrylate resin, a vinyl resin, eg Polyvinyl acetate, polyester resin, polycondensation or polyaddition resin, polyurethane resin, alkyd resin or modified alkyd resin, phenolic resin, hydrocarbon resin such as indene coumarone resin
• the synthetic resin used as the binder may be used in the form of an emulsion, dispersion or solution. Bitumen or bituminous substances up to 10% by weight can also be used as binders. In addition, known dyes, pigments, water repellents, odor correctors and inhibitors or corrosion inhibitors and the like can be used.
• At least one alkyd resin or modified alkyd resin and / or a drying vegetable oil is preferably present as the organic-chemical binder in the middle or in the concentrate.
• Alkyd resins with an oil content of more than 45% by weight, preferably 50 to 68% by weight, are preferably used according to the invention.
• the mentioned binder can be completely or partially replaced by a fixing agent (mixture) or a plasticizer (mixture). These additives are intended to volatilize the active ingredients and prevent crystallization or precipitation. Preferably, they replace 0.01 to 30% of the binder (based on 100% of the binder used).
• the plasticizers are derived from the chemical classes of phthalic acid esters such as dibutyl, dioctyl or benzyl butyl phthalate, phosphoric esters such as tributyl phosphate, adipic acid esters such as di (2-ethylhexyl) adipate, stearates such as butyl stearate or amyl stearate, oleates such as butyl oleate, glycerol ethers or higher molecular weight glycol ethers, glycerol esters and p-toluenesulfonic acid ester.
• phthalic acid esters such as dibutyl, dioctyl or benzyl butyl phthalate
• phosphoric esters such as tributyl phosphate
• adipic acid esters such as di (2-ethylhexyl) adipate
• stearates such as butyl
• Fixing agents are chemically based on polyvinyl alkyl ethers such as e.g. Polyvinyl methyl ether or ketones such as benzophenone, ethylene benzophenone.
• Particularly suitable solvents or diluents are also water, optionally in admixture with one or more of the abovementioned organochemical solvents or diluents, emulsifiers and dispersants.
• wood protection is provided by large scale impregnation methods, e.g. Vacuum, double vacuum or printing process achieved.
• the ready-to-use agents may optionally contain further insecticides and, if appropriate, one or more fungicides.
• the active compound combinations according to the invention can be used to protect against fouling of objects, in particular of hulls, screens, nets, structures, quays and signal systems, which come into contact with seawater or brackish water.
• the active compound combinations according to the invention are also suitable for controlling animal
• Pests in particular of insects, arachnids and mites, which occur in confined spaces, such as homes, factories, offices, vehicle cabs, etc. You can fight these pests alone or in combination with other active and Excipients used in household insecticide products. They are effective against sensitive and resistant species and against all stages of development.
• the application in the field of household insecticides can also be carried out in combination with other suitable active ingredients such as phosphoric acid esters, carbamates, pyrethroids, growth regulators or active compounds from other known classes of insecticides.
• suitable active ingredients such as phosphoric acid esters, carbamates, pyrethroids, growth regulators or active compounds from other known classes of insecticides.
• Application is in aerosols, non-pressurized sprays, e.g. Pump and atomizer sprays, fog machines, foggers, foams, gels, evaporator products with evaporator plates of cellulose or plastic, liquid evaporators, gel and membrane evaporators, propeller driven evaporators, energyless or passive evaporation systems, moth papers, moth cakes and moth gels as granules or dusts, in litter or bait stations.
• Pump and atomizer sprays e.g. Pump and atomizer sprays, fog machines, foggers, foams, gels, evaporator products with evaporator plates of cellulose or plastic, liquid evaporators, gel and membrane evaporators, propeller driven evaporators, energyless or passive evaporation systems, moth papers, moth cakes and moth gels as granules or dusts, in litter or bait stations.
• the application rates can be varied within a substantial range, depending on the mode of administration.
• the application rates of active ingredient combination are generally between 0.1 and 10,000 g / ha, preferably between 10 and 1,000 g / ha.
• X means the degree of killing or efficiency, expressed in% of the untreated control, when using the active substance A in an application rate of m ppm or g / ha,
• Y means the degree of killing or efficiency, expressed in% of the untreated control, when using the active ingredient B in an application rate of nppm or g / ha, and
• E is the degree of kill or efficiency expressed as% of untreated control
• the degree of kill or efficiency is determined in%. It means O% a degree of kill or efficiency equal to that of the control, while a kill rate of 100% means that all animals are dead and an efficiency of 100% means that no infestation is observed.
• the combination is over-additive in its effect, ie there is a synergistic effect.
• the actual observed efficiency must be greater than the expected efficiency value (E) calculated from the above formula.
• Emulsifier 2 parts by weight of alkylaryl polyglycol ether
• active compound 1 part by weight of active compound is mixed with the indicated amounts of solvent and emulsifier, and the concentrate is diluted with water to the desired concentration.
• Vessels are filled with sand, drug solution, Meloidogyne mcogmta egg larvae suspension and lettuce seeds.
• the lettuce seeds germinate and the plantlets develop.
• the galls develop at the roots.
• the nematicidal activity is determined by means of bile formation in%. 100% means that no bile was found; 0% means that the number of bile on the treated plants corresponds to that of the untreated control.
• Plant damaging nematodes Meloidogyne incognita - test

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• 2006
  • 2006-07-22 DE DE200610033993 patent/DE102006033993A1/de not_active Withdrawn
• 2007
  • 2007-07-12 WO PCT/EP2007/006175 patent/WO2008011990A2/de active Application Filing
  • 2007-07-20 AR ARP070103253 patent/AR062016A1/es unknown
  • 2007-07-20 CL CL2007002129A patent/CL2007002129A1/es unknown

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