WO2008000216A1 - Reformer für ein brennstoff zellensystem - Google Patents

Reformer für ein brennstoff zellensystem Download PDF

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Publication number
WO2008000216A1
WO2008000216A1 PCT/DE2007/001035 DE2007001035W WO2008000216A1 WO 2008000216 A1 WO2008000216 A1 WO 2008000216A1 DE 2007001035 W DE2007001035 W DE 2007001035W WO 2008000216 A1 WO2008000216 A1 WO 2008000216A1
Authority
WO
WIPO (PCT)
Prior art keywords
reformer
fuel
type
functional unit
fuel cell
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/DE2007/001035
Other languages
German (de)
English (en)
French (fr)
Inventor
Matthias Boltze
Michael Rozumek
Stefan Käding
Andreas Lindermeir
Norbert GÜNTHER
Jeremy Lawrence
Andreas Reinert
Marco Mühlner
Stefan Kah
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Webasto SE
Enerday GmbH
Original Assignee
Webasto SE
Enerday GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Webasto SE, Enerday GmbH filed Critical Webasto SE
Priority to BRPI0712859-2A priority Critical patent/BRPI0712859A2/pt
Priority to AU2007264245A priority patent/AU2007264245B2/en
Priority to US12/302,455 priority patent/US20090239110A1/en
Priority to AT07785536T priority patent/ATE444805T1/de
Priority to DK07785536.9T priority patent/DK2032249T3/da
Priority to PL07785536T priority patent/PL2032249T3/pl
Priority to EP07785536A priority patent/EP2032249B1/de
Priority to DE502007001698T priority patent/DE502007001698D1/de
Priority to CA002653441A priority patent/CA2653441A1/en
Priority to EA200870485A priority patent/EA200870485A1/ru
Priority to JP2009516876A priority patent/JP2009541951A/ja
Publication of WO2008000216A1 publication Critical patent/WO2008000216A1/de
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24Stationary reactors without moving elements inside
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/04Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
    • B01J8/0403Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the fluid flow within the beds being predominantly horizontal
    • B01J8/0423Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the fluid flow within the beds being predominantly horizontal through two or more otherwise shaped beds
    • B01J8/0438Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the fluid flow within the beds being predominantly horizontal through two or more otherwise shaped beds the beds being placed next to each other
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/04Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
    • B01J8/0403Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the fluid flow within the beds being predominantly horizontal
    • B01J8/0423Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the fluid flow within the beds being predominantly horizontal through two or more otherwise shaped beds
    • B01J8/0442Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the fluid flow within the beds being predominantly horizontal through two or more otherwise shaped beds the beds being placed in separate reactors
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60LPROPULSION OF ELECTRICALLY-PROPELLED VEHICLES; SUPPLYING ELECTRIC POWER FOR AUXILIARY EQUIPMENT OF ELECTRICALLY-PROPELLED VEHICLES; ELECTRODYNAMIC BRAKE SYSTEMS FOR VEHICLES IN GENERAL; MAGNETIC SUSPENSION OR LEVITATION FOR VEHICLES; MONITORING OPERATING VARIABLES OF ELECTRICALLY-PROPELLED VEHICLES; ELECTRIC SAFETY DEVICES FOR ELECTRICALLY-PROPELLED VEHICLES
    • B60L50/00Electric propulsion with power supplied within the vehicle
    • B60L50/50Electric propulsion with power supplied within the vehicle using propulsion power supplied by batteries or fuel cells
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/32Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
    • C01B3/34Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
    • C01B3/36Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using oxygen; using mixtures containing oxygen as gasifying agents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002Chemical plants
    • B01J2219/00018Construction aspects
    • B01J2219/0002Plants assembled from modules joined together
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/025Processes for making hydrogen or synthesis gas containing a partial oxidation step
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06Integration with other chemical processes
    • C01B2203/066Integration with other chemical processes with fuel cells
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1276Mixing of different feed components
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14Details of the flowsheet
    • C01B2203/148Details of the flowsheet involving a recycle stream to the feed of the process for making hydrogen or synthesis gas
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Definitions

  • the invention relates to a reformer for a fuel cell system for generating a reformate, comprising a plurality of functional units for treating the fuel, wherein at least one functional unit is tuned to a first type of fuel.
  • the invention relates to a functional unit for such a reformer, a fuel cell system with such a reformer and a motor vehicle with such a fuel cell system.
  • Fuel cell systems are used in a well-known manner, the conversion of chemical energy into electrical energy. Fuel cell systems must be able to handle common fuels in the field. Since hydrogen and oxygen are converted in a fuel cell, the fuel used must be processed so that the gas supplied to the anode of the fuel cell stack has the highest possible proportion of hydrogen. On the cathode side, in most cases, atmospheric oxygen is supplied to the fuel cell stack. For this purpose, fuel and an oxidizing agent, preferably air, are fed to a reformer. In the reformer, the reaction of the fuel with the oxygen then takes place, wherein preferably the process of partial oxidation is carried out. A conventionally constructed reformer is described for example in DE 101 20 375 A1. The reformate thus produced is then supplied to the fuel cell or a fuel cell stack, wherein electrical energy is released by the controlled conversion of hydrogen, as part of the reformate, and oxygen.
  • Fuel type tuned functional unit can be coupled as a detachable module by means of an interface with the reformer, which is also designed to couple a replacement function unit instead of the matched to the first fuel type functional unit with the reformer, where wherein the replacement function unit is tuned to a second type of fuel that differs from the first type of fuel.
  • Such a construction makes it possible to reuse essential functional units of the reformer when operating with different fuel types. This allows for a very cost effective and easy way to adapt the reformer to different requirements of different fuel types. It is therefore possible to optimally adapt a complete fuel cell system to another kind of fuel by simply exchanging a functional unit of the reformer.
  • the functional unit matched to the first fuel type and the replacement functional unit is a gas mixture-forming unit.
  • the gas mixture formation unit is an evaporator.
  • the functional unit tuned to the first fuel type and the replacement functional unit is a reaction unit.
  • reaction unit is a reformer burner.
  • the reformer according to the invention can be further developed in that the interface is a quick connection.
  • the interface is a bayonet connection.
  • a functional unit for a reformer having an interface adapted for coupling to such a reformer.
  • the invention provides a fuel cell system with such a reformer and a motor vehicle with such a fuel cell system, which provide the above advantages in a transferred manner.
  • Figure 1 is a schematic representation of the fuel cell system according to the invention.
  • FIG. 1 shows a schematic representation of the fuel cell system according to the invention.
  • the fuel cell system 10 includes a reformer 12 to which fuel is supplied from a fuel pump 14.
  • fuel types are diesel, gasoline, biogas, natural gas, and other known from the prior art types of fuel in question.
  • the reformer 12 is supplied with oxidizing agent which, in the illustrated case, is composed of air conveyed by a fan 16 and anode exhaust gas 18 introduced therein.
  • the anode exhaust gas 18 is generated by a fuel cell 20, which is associated with a fuel cell blower 22 and fed to the reformate 12 generated by the reformer becomes.
  • the reformate is a hydrogen-containing gas which is converted into electricity and heat in the fuel cell 20 by means of cathode air conveyed through the fuel cell fan 22.
  • the non-recirculated portion of the anode exhaust gas 18 is supplied to an afterburner 24, which is associated with a Nachbrennerbläse 26.
  • the depleted reformate is reacted with air conveyed through the afterburner fan 26 to form a combustion exhaust gas which contains virtually no pollutants.
  • the reformer 12 comprises a gas mixture formation unit 28 and a reaction unit 30.
  • a gaseous mixture is formed from the fuel and an oxidant, preferably air, preferably with evaporation of the fuel.
  • This gaseous mixture reacts in the reaction unit 30 to reformate, preferably by partial oxidation.
  • the gas mixture formation unit 28 is preferably an evaporator and the reaction unit 30 is preferably a reformer burner.
  • the gas mixture formation unit 28 as well as the reaction unit 30 are connected by means of interfaces 32, which are preferably designed as Sehne11Veritatien, such as a bayonet connection, a screw connection or a snap-in connector, with the
  • Reformer or coupled with the other functional units of the reformer Under quick connection is to be understood as a mechanical, releasable and positive or non-positive connection with which the coupling is preferably carried out without additional tools.
  • the reformer is divided into detachable modules, which are easy and user-friendly if necessary interchangeable.
  • the reformer and thus the entire fuel cell system is tuned in this configuration to a particular type of fuel. Should a conversion to another type of fuel be required? become, so can the functional units of the reformer, which are tuned to a particular type of fuel, exchanged for other functional units, which preferably perform the same function, but are tuned to a different type of fuel.
  • the interfaces of the functional units that are tuned to different types of fuel and should be interchangeable, preferably equipped with identical interfaces, so that all interchangeable functional units in terms of dimensions and connections optimally in or on the reformer or the rest Function units fit.
  • the reformer may be composed of a plurality of functional units coupled in series one behind the other so that an interface of a terminal functional unit forms the input of the reformer.
  • the other interface of this terminal functional unit is coupled to a subsequent functional unit.
  • This functional unit can in turn be coupled to a functional unit until the interface of the last functional unit forms an output of the reformer.
  • a reformer housing is provided which has respective housing-side interfaces to which the functional units are coupled by means of their interfaces. For the connection of the functional units in the operating case to each other in this embodiment, the housing-side interfaces should be connected within the reformer housing.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Fluid Mechanics (AREA)
  • Physics & Mathematics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Energy (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Sustainable Development (AREA)
  • Manufacturing & Machinery (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Power Engineering (AREA)
  • Transportation (AREA)
  • Mechanical Engineering (AREA)
  • Fuel Cell (AREA)
  • Hydrogen, Water And Hydrids (AREA)
PCT/DE2007/001035 2006-06-29 2007-06-12 Reformer für ein brennstoff zellensystem Ceased WO2008000216A1 (de)

Priority Applications (11)

Application Number Priority Date Filing Date Title
BRPI0712859-2A BRPI0712859A2 (pt) 2006-06-29 2007-06-12 reformador para um sistema de cÉlula de combustÍvel
AU2007264245A AU2007264245B2 (en) 2006-06-29 2007-06-12 Reformer for a fuel cell system
US12/302,455 US20090239110A1 (en) 2006-06-29 2007-06-12 Reformer for a fuel cell system
AT07785536T ATE444805T1 (de) 2006-06-29 2007-06-12 Reformer für ein brennstoff zellensystem
DK07785536.9T DK2032249T3 (da) 2006-06-29 2007-06-12 Reformer til et brændstofcellesystem
PL07785536T PL2032249T3 (pl) 2006-06-29 2007-06-12 Reformer do systemu ogniwa paliwowego
EP07785536A EP2032249B1 (de) 2006-06-29 2007-06-12 Reformer für ein brennstoff zellensystem
DE502007001698T DE502007001698D1 (https=) 2006-06-29 2007-06-12
CA002653441A CA2653441A1 (en) 2006-06-29 2007-06-12 Reformer for a fuel cell system
EA200870485A EA200870485A1 (ru) 2006-06-29 2007-06-12 Риформер для системы топливных элементов
JP2009516876A JP2009541951A (ja) 2006-06-29 2007-06-12 燃料電池システム用の改質器

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102006029917A DE102006029917A1 (de) 2006-06-29 2006-06-29 Reformer für ein Brennstoffzellensystem
DE102006029917.5 2006-06-29

Publications (1)

Publication Number Publication Date
WO2008000216A1 true WO2008000216A1 (de) 2008-01-03

Family

ID=38477135

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/DE2007/001035 Ceased WO2008000216A1 (de) 2006-06-29 2007-06-12 Reformer für ein brennstoff zellensystem

Country Status (15)

Country Link
US (1) US20090239110A1 (https=)
EP (1) EP2032249B1 (https=)
JP (1) JP2009541951A (https=)
KR (1) KR101009426B1 (https=)
CN (1) CN101479033A (https=)
AT (1) ATE444805T1 (https=)
AU (1) AU2007264245B2 (https=)
BR (1) BRPI0712859A2 (https=)
CA (1) CA2653441A1 (https=)
DE (2) DE102006029917A1 (https=)
DK (1) DK2032249T3 (https=)
EA (1) EA200870485A1 (https=)
ES (1) ES2333485T3 (https=)
PL (1) PL2032249T3 (https=)
WO (1) WO2008000216A1 (https=)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9190693B2 (en) 2006-01-23 2015-11-17 Bloom Energy Corporation Modular fuel cell system
US8852820B2 (en) 2007-08-15 2014-10-07 Bloom Energy Corporation Fuel cell stack module shell with integrated heat exchanger
US8535836B2 (en) 2009-07-08 2013-09-17 Bloom Energy Corporation Method of operating a fuel cell system with bypass ports in a fuel processing assembly
EP3092476A4 (en) 2014-01-06 2017-07-19 Bloom Energy Corporation Structure and method for indicating undesirable constituents in a fuel cell system
JP2015072930A (ja) * 2015-01-19 2015-04-16 株式会社東芝 燃料電池システムおよびその運転方法
US10320017B2 (en) 2015-10-06 2019-06-11 Bloom Energy Corporation Sorbent bed assembly and fuel cell system including same

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1471590A1 (en) * 2001-12-07 2004-10-27 Canon Kabushiki Kaisha Fuel battery and electric device
US20060029856A1 (en) * 2004-08-05 2006-02-09 Vail Timothy E Modular electrochemical power system

Family Cites Families (4)

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Publication number Priority date Publication date Assignee Title
US20020131919A1 (en) * 2001-03-15 2002-09-19 Debellis Crispin L. Modular fuel processing system for plate reforming type units
US20040253498A1 (en) * 2003-04-15 2004-12-16 Nuvera Fuel Cells, Inc. Modular fuel reformer with removable carrier
US20040265656A1 (en) * 2003-06-30 2004-12-30 Nokia Corporation Electricity generation system comprising a fuel cell
US7811341B2 (en) * 2005-12-28 2010-10-12 Casio Computer Co., Ltd. Reaction device, heat-insulating container, fuel cell device, and electronic apparatus

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1471590A1 (en) * 2001-12-07 2004-10-27 Canon Kabushiki Kaisha Fuel battery and electric device
US20060029856A1 (en) * 2004-08-05 2006-02-09 Vail Timothy E Modular electrochemical power system

Also Published As

Publication number Publication date
JP2009541951A (ja) 2009-11-26
US20090239110A1 (en) 2009-09-24
DE102006029917A1 (de) 2008-01-03
AU2007264245B2 (en) 2010-03-25
KR20090005232A (ko) 2009-01-12
AU2007264245A1 (en) 2008-01-03
KR101009426B1 (ko) 2011-01-19
ES2333485T3 (es) 2010-02-22
DK2032249T3 (da) 2010-01-18
CN101479033A (zh) 2009-07-08
CA2653441A1 (en) 2008-01-03
EA200870485A1 (ru) 2009-04-28
EP2032249B1 (de) 2009-10-07
PL2032249T3 (pl) 2010-04-30
DE502007001698D1 (https=) 2009-11-19
ATE444805T1 (de) 2009-10-15
EP2032249A1 (de) 2009-03-11
BRPI0712859A2 (pt) 2012-07-31

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