WO2007126855A1 - Compositions de polyester lesquelles comprennent du cyclobutanediol et certains agents stabilisants thermiques et/ou des produits de réaction de ceux-ci - Google Patents

Compositions de polyester lesquelles comprennent du cyclobutanediol et certains agents stabilisants thermiques et/ou des produits de réaction de ceux-ci Download PDF

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Publication number
WO2007126855A1
WO2007126855A1 PCT/US2007/007632 US2007007632W WO2007126855A1 WO 2007126855 A1 WO2007126855 A1 WO 2007126855A1 US 2007007632 W US2007007632 W US 2007007632W WO 2007126855 A1 WO2007126855 A1 WO 2007126855A1
Authority
WO
WIPO (PCT)
Prior art keywords
mole
polyester
dicarboxylic acid
residues
phosphate esters
Prior art date
Application number
PCT/US2007/007632
Other languages
English (en)
Inventor
Ted Calvin Germroth
Gary Wayne Connell
Thomas Joseph Pecorini
Emmett Dudley Crawford
Douglas Stephens Mcwilliams
Benjamin Fredrick Barton
Damon Bryan Shackelford
Original Assignee
Eastman Chemical Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US11/390,812 external-priority patent/US7959836B2/en
Priority claimed from US11/390,846 external-priority patent/US7955674B2/en
Priority claimed from US11/391,659 external-priority patent/US20060287496A1/en
Priority claimed from US11/390,809 external-priority patent/US7959998B2/en
Priority claimed from US11/391,124 external-priority patent/US20060234073A1/en
Priority claimed from US11/390,908 external-priority patent/US7462684B2/en
Priority claimed from US11/439,340 external-priority patent/US20060270806A1/en
Priority claimed from US11/439,062 external-priority patent/US20060270773A1/en
Priority claimed from PCT/US2006/041917 external-priority patent/WO2007053434A1/fr
Priority claimed from US11/588,883 external-priority patent/US20070105993A1/en
Priority claimed from US11/588,906 external-priority patent/US8193302B2/en
Priority claimed from US11/588,554 external-priority patent/US20070100125A1/en
Priority claimed from US11/588,527 external-priority patent/US20100087574A1/en
Priority claimed from US11/588,907 external-priority patent/US20070106054A1/en
Priority claimed from PCT/US2006/042292 external-priority patent/WO2007053549A1/fr
Priority claimed from US11/588,524 external-priority patent/US20100096589A1/en
Priority claimed from US11/588,458 external-priority patent/US20070100122A1/en
Priority claimed from US11/635,434 external-priority patent/US7737246B2/en
Priority claimed from US11/635,433 external-priority patent/US20070142511A1/en
Priority claimed from US11/706,791 external-priority patent/US20070232779A1/en
Priority claimed from US11/706,476 external-priority patent/US20070232778A1/en
Application filed by Eastman Chemical Company filed Critical Eastman Chemical Company
Priority to US12/294,690 priority Critical patent/US20100184940A1/en
Priority to PCT/US2007/010551 priority patent/WO2007139653A1/fr
Priority to PCT/US2007/010590 priority patent/WO2007139655A1/fr
Priority to PCT/US2007/011150 priority patent/WO2007139663A1/fr
Priority to PCT/US2007/015702 priority patent/WO2008054559A1/fr
Priority to CA002666571A priority patent/CA2666571A1/fr
Priority to TW096125125A priority patent/TW200819497A/zh
Priority to MX2009003369A priority patent/MX2009003369A/es
Priority to KR1020097008484A priority patent/KR20090079212A/ko
Priority to PCT/US2007/015713 priority patent/WO2008054560A2/fr
Priority to JP2009534566A priority patent/JP2010507717A/ja
Priority to CA002666585A priority patent/CA2666585A1/fr
Priority to PCT/US2007/015704 priority patent/WO2008051321A1/fr
Priority to BRPI0717761-5A priority patent/BRPI0717761A2/pt
Priority to EP07836026A priority patent/EP2074174A1/fr
Priority to TW096125089A priority patent/TW200819496A/zh
Priority to BRPI0717755-0A priority patent/BRPI0717755A2/pt
Priority to KR1020097008483A priority patent/KR20090079211A/ko
Priority to PCT/US2007/015701 priority patent/WO2008051320A1/fr
Priority to JP2009534565A priority patent/JP2010507716A/ja
Priority to EP07836029A priority patent/EP2074158A1/fr
Priority to MX2009003375A priority patent/MX2009003375A/es
Publication of WO2007126855A1 publication Critical patent/WO2007126855A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/85—Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16—Dicarboxylic acids and dihydroxy compounds
    • C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
    • C08G63/199—Acids or hydroxy compounds containing cycloaliphatic rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds

Definitions

  • the present invention generally relates to polyester compositions made from terephthalic acid, or an ester thereof, and mixtures thereof, 2,2,4,4- tetramethyl-1,3-cyclobutanediol, and cyclohexanedimethanol, and at least one phosphate ester, reaction products thereof, and mixtures thereof, having a certain combination of two or more of high impact strengths, high glass transition temperature (T 9 ), toughness, certain inherent viscosities, low ductile-to-brittle transition temperatures, good color and clarity, low densities, chemical resistance, hydrolytic stability, and long crystallization half-times, which allow them to be easily formed into articles.
  • the present invention also generally relates to processes for making the polyesters/polyester compositions of the invention.
  • PCT PoIy(1 ,4-cyclohexylenedimethylene) terephthalate
  • a polyester based solely on terephthalic acid or an ester thereof and cyclohexanedimethanol is known in the art and is commercially available.
  • This polyester crystallizes rapidly upon cooling from the melt, making it very difficult to form amorphous articles by methods known in the art such as extrusion, injection molding, and the like.
  • copolyesters can be prepared containing additional dicarboxylic acids or glycols such as isophthalic acid or ethylene glycol residues.
  • ethylene glycol residues- or isophthalic acid-modified PCTs are also known in the art and are commercially available.
  • One common copolyester used to produce films, sheeting, and molded articles is made from terephthalic acid, 1 ⁇ -cyclohexanedimethanol, and ethylene glycol residues. While these copolyesters are useful in many end-use applications, they exhibit deficiencies in properties such as glass transition temperature and impact strength when sufficient modifying ethylene glycol residues is included in the formulation to provide for long crystallization half- times.
  • copolyesters made from terephthalic acid, 1 ,4- cyclohexanedimethanol, and ethylene glycol residues with sufficiently long crystallization half-times can provide amorphous products that exhibit what is believed to be undesirably higher ductile-to-brittle transition temperatures and lower glass transition temperatures than the compositions revealed herein.
  • the polycarbonate of 4,4'-isopropylidenediphenol bisphenol A polycarbonate
  • Bisphenol A polycarbonate is a clear, high-performance plastic having good physical properties such as dimensional stability, high heat resistance, and good impact strength.
  • polyester compositions formed from terephthalic acid, an ester thereof, and/or mixtures thereof, cyclohexanedimethanol, and 2,2,4,4-tetramethyl-i ,3-cyclobutanediol comprising certain thermal stabilizers, reaction products thereof, and mixtures thereof, are superior to polyesters known in the art and to polycarbonate with respect to one or more of high impact strengths, hydrolytic stability, toughness, chemical resistance, good color and clarity, long crystallization half-times, low ductile to brittle transition temperatures, lower specific gravity, and thermoformability.
  • These compositions are believed to be similar to polycarbonate in heat resistance and are more processable on the standard industry equipment.
  • these polyesters have enhanced thermal stability allowing for easier manufacture and enhanced downstream material processing.
  • the polyesters can be more easily produced without at least one of the following occurring: bubbling, splay formation, color formation, foaming, off- gassing, and erratic melt levels, i.e., pulsating of the polyester or the polyesters production and processing systems.
  • at least one process of the invention provides a means to more easily produce the polyesters useful in the invention in large quantities (for example, pilot run scale and/or commercial production) without at least one of the aforesaid difficulties occurring.
  • large quantities includes quantities of polyester(s) useful in the invention which are produced in quantities larger than 100 pounds. In one embodiment, the term “large quantities, as used herein, includes quantities of polyester(s) useful in the invention which are produced in quantities larger than 1000 pounds.
  • the processes of making the polyesters useful in the invention can comprise a batch or continuous process. [0013J In one aspect, the processes of making the polyesters useful in the invention comprise a continuous process.
  • the invention relates to a polyester composition
  • a polyester composition comprising:
  • At least one thermal stabilizer chosen from at least one of alkyl phosphate esters, aryl phosphate esters, mixed alkyl aryl phosphate esters, reaction products thereof, and mixtures thereof.
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • the invention relates to a polyester composition comprising:
  • At least one thermal stabilizer chosen from at least one of alkyl phosphate esters, aryl phosphate esters, mixed alkyl aryl phosphate esters, reaction products thereof, and mixtures thereof; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and the total mole % of the glycol component is 100 mole %; and wherein the inherent viscosity of the polyester is 0.35 to 1.2 dL/g as determined in 60/40 (wt/wt) phenol/ tetrachloroethane at a concentration of 0.25 g/50 ml at
  • polyester has a Tg from 85°C to 200 0 C.
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • At least one thermal stabilizer chosen from at least one of alkyl phosphate esters, aryl phosphate esters, mixed alkyl aryl phosphate esters, reaction products thereof, and mixtures thereof; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and the total mole % of the glycol component is 100 mole %; and wherein the inherent viscosity of the polyester is from 0.35 to 1.2 dL/g as determined in60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.25 g/50 ml at 25°C; wherein the polyester has a Tg from 85 to 200 0 C.
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising
  • At least one thermal stabilizer chosen from at least one of alkyl phosphate esters, aryl phosphate esters, mixed alkyl aryl phosphate esters, reaction products thereof, and mixtures thereof; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and the total mole % of the glycol component is 100 mole %; and wherein the inherent viscosity of the polyester is from 0.35 to 0 75 dL/g as determined in 60/40 (wt/wt) phenol/ tetrachloroethane at a concentration of 0.25 g/50 ml at 25°C; wherein the polyester has a Tg from 110 to 200 0 C.
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • At least one thermal stabilizer chosen from at least one of alkyl phosphate esters, aryl phosphate esters, mixed alkyl aryl phosphate esters, reaction products thereof, and mixtures thereof; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and the total mole % of the glycol component is 100 mole %; and wherein the inherent viscosity of the polyester is from 0.35 to 1.2 dl_/g as determined in 60/40 (wt/wt) phenol/ tetrachloroethane at a concentration of 0.25 g/50 ml at 25 0 C; and wherein the polyester has a Tg from 120 to 135°C.
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • At least one thermal stabilizer chosen from at least one of alkyl phosphate esters, aryl phosphate esters, mixed alkyl aryl phosphate esters, reaction products thereof, and mixtures thereof; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and the total mole % of the glycol component is 100 mole %; and wherein the inherent viscosity of the polyester is from 0.35 to 0.70 dL/g as determined in 60/40 (wt/wt) phenol/ tetrachloroethane at a concentration of 0.25 g/50 ml at 25°C; and wherein the polyester has a Tg from 130 to 145°C.
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • At least one thermal stabilizer chosen from at least one of alkyl phosphate esters, aryl phosphate esters, mixed alkyl aryl phosphate esters, reaction products thereof, and mixtures thereof; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and the total mole % of the glycol component is 100 mole %; and wherein the inherent viscosity of the polyester is from 0.58 to 0.72 dL/g as determined in 60/40 (wt/wt) phenol/ tetrachloroethane at a concentration of 0.25 g/50 ml at 25 0 C; and wherein the polyester has a Tg from 130 to 145°C.
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • thermo stabilizer chosen from at least one of alkyl phosphate esters, aryl phosphate esters, mixed alkyl aryl phosphate esters, reaction products thereof, and mixtures thereof; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and the total mole % of the glycol component is 100 mole %; and wherein the inherent viscosity of the polyester is from 0.6 to 1 dL/g as determined in 60/40 (wt/wt) phenol/ tetrachloroethane at a concentration of 0.25 g/50 ml at 25 0 C; and wherein the polyester has a Tg from 130 to 145°C.
  • this invention relates to a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • At least one thermal stabilizer chosen from at least one of alkyl phosphate esters, aryl phosphate esters, mixed alkyl aryl phosphate esters, reaction products thereof, and mixtures thereof; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and the total mole % of the glycol component is 100 mole %; and wherein the inherent viscosity of the polyester is from 0.6 to 0.72 ⁇ Jg as determined in 60/40 (wt/wt) phenol/ tetrachloroethane at a concentration of 0.25 g/50 ml at 25 0 C; and wherein the polyester has a Tg from 130 to 145°C.
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • a tricarboxylic acid component comprising:
  • At least one thermal stabilizer chosen from at least one of alkyl phosphate esters, aryl phosphate esters, mixed alkyl aryl phosphate esters, reaction products thereof, and mixtures thereof; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and the total mole % of the glycol component is 100 mole %; and wherein the inherent viscosity of the polyester is 0.35 to 1.2 dL/g as determined in 60/40 (wt/wt) phenol/ tetrachloroethane at a concentration of 0.25 g/50 ml at
  • polyester has a Tg from greater than 148°C up to 200 0 C.
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • a modifying glycol chosen from at least one of the following: ethylene glycol residues, propylene glycol, butanediol, and mixtures thereof; and (II) at least one thermal stabilizer chosen from at least one of alkyl phosphate esters, aryl phosphate esters, mixed alkyl aryl phosphate esters, reaction products thereof, and mixtures thereof; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and the total mole % of the glycol component is 100 mole %; and wherein the inherent viscosity of the polyester is from 0.35 to 1.2 d ⁇ Jg as determined in 60/40 (wt/wt) phenol/ tetrachloroethane at a concentration of 0.25 g/50 ml at 25 0 C; wherein the polyester has a Tg from 85 to 200 0 C.
  • At least one thermal stabilizer chosen from at least one of alkyl phosphate esters, aryl phosphate esters, mixed alkyl aryl phosphate esters, reaction products thereof, and mixtures thereof; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and the total mole % of the glycol component is 100 mole %; and wherein the inherent viscosity of the polyester is 0.35 to 1.2 dL/g as determined in 60/40 (wt/wt) phenol/ tetrachloroethane at a concentration of 0.25 g/50 ml at
  • polyester has a Tg from 85 to 200 0 C and optionally, wherein one or more branching agents is added prior to or during the polymerization of the polymer.
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • a modifying glycol chosen from at least one of the following: ethylene glycol residues, propylene glycol, butanediol, and mixtures thereof; and (II) at least one thermal stabilizer chosen from at least one of alkyl phosphate esters, aryl phosphate esters, mixed alkyl aryl phosphate esters, reaction products thereof, and mixtures thereof; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and the total mole % of the glycol component is 100 mole %; and wherein the inherent viscosity of the polyester is from 0.35 to 0.75 dL/g or less as determined in 60/40 (wt/wt) phenol/ tetrachloroethane at a concentration of 0.25 g/50 ml at 25 0 C; wherein the polyester has a Tg from 110 to 200 0 C.
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • At least one thermal stabilizer chosen from at least one of alkyl phosphate esters, aryl phosphate esters, mixed alkyl aryl phosphate esters, reaction products thereof, and mixtures thereof; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and the total mole % of the glycol component is 100 mole %; and wherein the inherent viscosity of the polyester is 0.35 to 0.75 dl_/g as determined in 60/40 (wt/wt) phenol/ tetrachloroethane at a concentration of 0.25 g/50 ml at 25°C; wherein the polyester has a Tg from 110 to 200 0 C; and optionally, wherein one or more branching agents is added prior to or during the polymerization of the polymer.
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • a modifying glycol chosen from at least one of the following: ethylene glycol residues, propylene glycol, butanediol, and mixtures thereof; and (II) at least one thermal stabilizer chosen from at least one of alkyl phosphate esters, aryl phosphate esters, mixed alkyl aryl phosphate esters, reaction products thereof, and mixtures thereof; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and the total mole % of the glycol component is 100 mole %; and wherein the inherent viscosity of the polyester is from 0.35 to 0.75 dL/g or less as determined in 60/40 (wt/wt) phenol/ tetrachloroethane at a concentration of 0.25 g/50 ml at 25°C; wherein the polyester has a Tg from 110 to 200 0 C.
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • At least one thermal stabilizer chosen from at least one of alkyl phosphate esters, aryl phosphate esters, mixed alkyl aryl phosphate esters, reaction products thereof, and mixtures thereof; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and the total mole % of the glycol component is 100 mole %; and wherein the inherent viscosity of the polyester is 0.35 to 1.2 dUg as determined in 60/40 (wt/wt) phenol/ tetrachloroethane at a concentration of 0.25 g/50 ml at
  • polyester has a Tg from 110 to 200 0 C and optionally, wherein one or more branching agents is added prior to or during the polymerization of the polymer.
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • At least one thermal stabilizer chosen from at least one of alkyl phosphate esters, aryl phosphate esters, mixed alkyl aryl phosphate esters, reaction products thereof, and mixtures thereof; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and the total mole % of the glycol component is 100 mole %; and wherein the inherent viscosity of the polyester is from 0.10 to 1.2 dL/g as determined in 60/40 (wt/wt) phenol/ tetrachloroethane at a concentration of 0.25 g/50 ml at 25°C; wherein the polyester has a Tg from 85 to 200 0 C; wherein if ethylene glycol residues is present in the glycol component, it is present in the polyester at less than 15 mole %.
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • At least one thermal stabilizer chosen from at least one of alkyl phosphate esters, aryl phosphate esters, mixed alkyl aryl phosphate esters, reaction products thereof, and mixtures thereof; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and the total mole % of the glycol component is 100 mole %; and wherein the amorphous polyester has a glass transition temperature (T 9 ) of greater than
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • At least one thermal stabilizer chosen from at least one of alkyl phosphate esters, aryl phosphate esters, mixed alkyl aryl phosphate esters, reaction products thereof, and mixtures thereof; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and the total mole % of the glycol component is 100 mole %; and wherein the inherent viscosity of the polyester is 0.10 to less than 1 dL/g as determined in 60/40 (wt/wt) phenol/ tetrachloroethane at a concentration of 0.25 g/50 ml at 25 0 C; and wherein the polyester has a Tg from 85 to 125°C.
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • a dicarboxylic acid component comprising: (i) 70 to 100 mole % of terephthalic acid residues; (ii) 0 to 30 mole % of aromatic dicarboxylic acid residues having up to 20 carbon atoms; and
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • At least one thermal stabilizer chosen from at least one of alkyl phosphate esters, aryl phosphate esters, mixed alkyl aryl phosphate esters, reaction products thereof, and mixtures thereof; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and the total mole % of the glycol component is 100 mole %; and wherein the inherent viscosity of the polyester is 0.5 to 1.2 dL/g as determined in
  • polyester has a Tg from 85 to 120 0 C.
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • At least one thermal stabilizer chosen from at least one of alkyl phosphate esters, aryl phosphate esters, mixed alkyl aryl phosphate esters, reaction products thereof, and mixtures thereof; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and the total mole % of the glycol component is 100 mole %; and wherein the inherent viscosity of the polyester is 0.35 to 1.2 dUg as determined in 60/40 (wt/wt) phenol/ tetrachloroethane at a concentration of 0.25 g/50 ml at
  • polyester has a Tg from 85 to 120 0 C.
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • At least one thermal stabilizer chosen from at least one of alkyl phosphate esters, aryl phosphate esters, mixed alkyl aryl phosphate esters, reaction products thereof, and mixtures thereof; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and the total mole % of the glycol component is 100 mole %; and wherein the inherent viscosity of the polyester is from 0.50 to 1.2 dL/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.25 g/50 ml at 25°C; and wherein the polyester has a Tg from 85 to 120 0 C.
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • At least one thermal stabilizer chosen from at least one of alkyl phosphate esters, aryl phosphate esters, mixed alkyl aryl phosphate esters, reaction products thereof, and mixtures thereof; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and the total mole % of the glycol component is 100 mole %; and wherein the inherent viscosity of the polyester is from 0.50 to 1.2 dL7g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.25 g/50 ml at 25°C; and wherein the polyester has a Tg from 85 to 120 0 C. In one embodiment, the Tg of the polyester is from 100 to 120 0 C.
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • At least one thermal stabilizer chosen from at least one of alkyl phosphate esters, aryl phosphate esters, mixed alkyl aryl phosphate esters, reaction products thereof, and mixtures thereof; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and the total mole % of the glycol component is 100 mole %; and wherein the inherent viscosity is from 0.50 to 0.8 dL/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.25 g/50 ml at 25°C; and wherein the polyester has a Tg from 85 to 120 0 C. In one embodiment, the Tg of the polyester is from 100 to 120 0 C.
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • At least one thermal stabilizer chosen from at least one of alkyl phosphate esters, aryl phosphate esters, mixed alkyl aryl phosphate esters, reaction products thereof, and mixtures thereof; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and the total mole % of the glycol component is 100 mole %; and wherein the inherent viscosity is from 0.50 to 0.75 dL/g as determined in 60/40
  • the polyester has a Tg from 85 to 120 0 C.
  • the Tg of the polyester is from 100 to 120" C.
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • the polyester has a Tg from 100 to 120 0 C. In one embodiment, the Tg of the polyester is from 100 to 120°C.
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • At least one thermal stabilizer chosen from at least one of alkyl phosphate esters, aryl phosphate esters, mixed alkyl aryl phosphate esters, reaction products thereof, and mixtures thereof; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and the total mole % of the glycol component is 100 mole %; and wherein the inherent viscosity of the polyester is from 0.50 to 1.2 dL/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.25 g/50 ml at 25 0 C; and wherein the polyester has a Tg from 95 to 115°C.
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • At least one thermal stabilizer chosen from at least one of alkyl phosphate esters, aryl phosphate esters, mixed alkyl aryl phosphate esters, reaction products thereof, and mixtures thereof; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and the total mole % of the glycol component is 100 mole %; and wherein the inherent viscosity of the polyester is from 0.60 to 0.75 dL/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.25 g/50 ml at 25°C; and wherein the polyester has a Tg from 85 to 120 0 C.
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • At least one thermal stabilizer chosen from at least one of alkyl phosphate esters, aryl phosphate esters, mixed alkyl aryl phosphate esters, reaction products thereof, and mixtures thereof; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and the total mole % of the glycol component is 100 mole %; and wherein the inherent viscosity of the polyester is from 0.5 to 0.8 dL/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.25 g/50 ml at 25°C; and wherein the polyester has a Tg from 85 to 120 0 C. In one embodiment, the Tg of the polyester is from 100 to 120 0 C.
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • At least one thermal stabilizer chosen from at least one of alkyl phosphate esters, aryl phosphate esters, mixed alkyl aryl phosphate esters, reaction products thereof, and mixtures thereof; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and the total mole % of the glycol component is 100 mole %; and wherein the inherent viscosity of the polyester is from 0.6 to 0.8 dl_/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.25 g/50 ml at 25°C; and wherein the polyester has a Tg from 85 to 120 0 C. In one embodiment, the Tg of the polyester is from 100 to 120 0 C.
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • a dicarboxylic acid component comprising: (i) 70 to 100 mole % of terephthalic acid residues; (ii) 0 to 30 mole % of aromatic dicarboxylic acid residues having up to 20 carbon atoms; and
  • thermo stabilizer chosen from at least one of alkyl phosphate esters, aryl phosphate esters, mixed alkyl aryl phosphate esters, reaction products thereof, and mixtures thereof; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and the total mole % of the glycol component is 100 mole %; and wherein the inherent viscosity of the polyester is from 0.50 to 0.75 dL/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.25 g/50 ml at 25°C; and wherein the polyester has a Tg from 85 to 120 0 C. In one embodiment, the Tg of the polyester is from 100 to 120 0 C. [0092] In one aspect, this invention relates to a polyester composition comprising:
  • thermo stabilizer chosen from at least one of alkyl phosphate esters, aryl phosphate esters, mixed alkyl aryl phosphate esters, reaction products thereof, and mixtures thereof; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and the total mole % of the glycol component is 100 mole %; and wherein the inherent viscosity of the polyester is from 0.50 to 0.75 dL/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.25 g/50 ml at 25 0 C; and wherein the polyester has a Tg from 85 to 120 0 C. In one embodiment, the Tg of the polyester is from 100 to 120 0 C. [0093] In one aspect, this invention relates to a polyester composition comprising:
  • thermo stabilizer chosen from at least one of alkyl phosphate esters, aryl phosphate esters, mixed alkyl aryl phosphate esters, reaction products thereof, and mixtures thereof; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and. the total mole % of the glycol component is 100 mole %; and wherein the inherent viscosity of the polyester is from 0.65 to 0.75 dL/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.25 g/50 ml at 25 0 C; and wherein the polyester has a Tg from 85 to 120 0 C. In one embodiment, the Tg of the polyester is from 100 to 120 0 C. [0094] In one aspect, this invention relates to a polyester composition comprising:
  • At least one thermal stabilizer chosen from at least one of alky) phosphate esters, aryl phosphate esters, mixed alkyl aryl phosphate esters, reaction products thereof, and mixtures thereof; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and the total mole % of the glycol component is 100 mole %; and wherein the inherent viscosity of the polyester is from 0.65 to 0.75 dL/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.25 g/50 ml at 25 0 C; and wherein the polyester has a Tg from 100 to 120 0 C.
  • the Tg of the polyester is from 100 to 120 0 C.
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • thermo stabilizer chosen from at least one of alkyl phosphate esters, aryl phosphate esters, mixed alkyl aryl phosphate esters, reaction products thereof, and mixtures thereof; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and the total mole % of the glycol component is 100 mole %; and wherein the inherent viscosity of the polyester is from 0.7 to 0.8 dL/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.25 g/50 ml at 25°C; and wherein the polyester has a Tg from 85 to 120 0 C. In one embodiment, the Tg of the polyester is from 100 to 120 0 C. [0096J In one aspect, this invention relates to a polyester composition comprising:
  • a glycol component comprising: (i) 17 to 28 mole % of 2,2,4,4-tetramethyl-i ,3- cyclobutanediol residues;
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • At least one thermal stabilizer chosen from at least one of alkyl phosphate esters, aryl phosphate esters, mixed alkyl aryl phosphate esters, reaction products thereof, and mixtures thereof; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and the total mole % of the glycol component is 100 mole %; and wherein the inherent viscosity of the polyester is from 0.65 to 0.75 dl_/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.25 g/50 ml at 25 0 C; and wherein the polyester has a Tg from 100 to 115 ⁇ C.
  • the Tg of the polyester is from 100 to 120 0 C.
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • At least one thermal stabilizer chosen from at least one of alkyl phosphate esters, aryl phosphate esters, mixed alkyl aryl phosphate esters, reaction products thereof, and mixtures thereof; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and the total mole % of the glycol component is 100 mole %; and wherein the inherent viscosity of the polyester is from 0.50 to 0.75 dL/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.25 g/50 ml at 25 0 C; and wherein the polyester has a Tg from 95 to 115°C.
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • At least one thermal stabilizer chosen from at least one of alkyl phosphate esters, aryl phosphate esters, mixed alkyl aryl phosphate esters, reaction products thereof, and mixtures thereof; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and the total mole % of the glycol component is 100 mole %; and wherein the inherent viscosity of the polyester is from 0.35 to 1.2 dL/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.25 g/50 ml at 25°C; and wherein the polyester has a Tg from 60 to 110 0 C.
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • At least one thermal stabilizer chosen from at least one of alkyl phosphate esters, aryl phosphate esters, mixed alkyl aryl phosphate esters, reaction products thereof, and mixtures thereof; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and the total mole % of the glycol component is 100 mole %; and wherein the inherent viscosity of the polyester is from 0.35 to 1.2 dL/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.25 g/50 ml at 25 0 C; and wherein the polyester has a Tg from 60 to 110 0 C.
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • At least one thermal stabilizer chosen from at least one of alkyl phosphate esters, aryl phosphate esters, mixed alkyf aryl phosphate esters, reaction products thereof, and mixtures thereof; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and the total mole % of the glycol component is 100 mole %; and wherein the inherent viscosity of the polyester is from 0.35 to 1.2 dl_/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.25 g/50 ml at 25 0 C; and wherein the polyester has a Tg from 60 to 110 0 C.
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • At least one thermal stabilizer chosen from at least one of alkyl phosphate esters, aryl phosphate esters, mixed alkyl aryl phosphate esters, reaction products thereof, and mixtures thereof; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and the total mole % of the glycol component is 100 mole %; and wherein the inherent viscosity of the polyester is from 0.35 to 1.2 dUg as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.25 g/50 ml at 25°C; and wherein the polyester has a Tg from 60 to 110 0 C.
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • At least one thermal stabilizer chosen from at least one of alkyl phosphate esters, aryl phosphate esters, mixed alkyl aryl phosphate esters, reaction products thereof, and mixtures thereof; and wherein the total mole % of the dicarboxylic acid component is 100 mole %, and the total mole % of the glycol component is 100 mole %; and wherein the inherent viscosity of the polyester is from 0.35 to 1.2 dL/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.25 g/50 ml at 25°C; and wherein the polyester has a Tg from 60 to 110 0 C.
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • At least one thermal stabilizer chosen from at least one of alkyl phosphate esters, aryl phosphate esters, mixed alkyl aryl phosphate esters, reaction products thereof, and mixtures thereof; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and the total mole % of the glycol component is 100 mole %; and wherein the inherent viscosity of the polyester is from 0.35 to 1.2 dl_/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.25 g/50 ml at 25 0 C; and wherein the polyester has a Tg from 60 to 110 0 C.
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • At least one thermal stabilizer chosen from at least one of alkyl phosphate esters, aryl phosphate esters, mixed alkyl aryl phosphate esters, reaction products thereof, and mixtures thereof; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and the total mole % of the glycol component is 100 mole %; and wherein the inherent viscosity of the polyester is from 0.35 to 1.2 dl_/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.25 g/50 ml at 25°C; and wherein the polyester has a Tg from 60 to 110 0 C.
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • a dicarboxylic acid component comprising: (i) 70 to 100 mole % of terephthalic acid residues; (ii) 0 to 30 mole % of aromatic dicarboxylic acid residues having up to 20 carbon atoms; and
  • this invention relates to a polyester composition
  • a polyester composition comprising:
  • this invention relates to a polyester composition
  • a polyester composition comprising:

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyesters Or Polycarbonates (AREA)

Abstract

L'invention concerne dans un aspect des compositions de polyester contenant : (I) au moins un polyester qui comprend : (a) un composant acide dicarboxylique comprenant : (i) 70 à 100 mol% de résidus d'acide téréphtalique ; (ii) 0 à 30 mol% de résidus d'acide dicarboxylique aromatique ayant jusqu'à 20 atomes de carbone ; et (iii) 0 à 10 mol% de résidus d'acide dicarboxylique aliphatique ayant jusqu'à 16 atomes de carbone ; et (b) un composant glycol comprenant : (i) 1 à 99 mol% de résidus de 2,2,4,4-tétraméthyl-1,3-cyclobutanediol ; et (ii) 1 à 99 mol% de résidus de cyclohexanediméthanol ; et (II) au moins un agent stabilisant thermique choisi parmi au moins l'un parmi des esters de phosphate d'alkyle, des esters de phosphate d'aryle, des esters mélangés de phosphate d'alkyle et de phosphate d'aryle, des produits de réaction de ceux-ci et des mélanges de ceux-ci ; le % en mole total du composant acide dicarboxylique étant de 100 mol% et le % en mole total du composant glycol étant de 100 mol%.
PCT/US2007/007632 2005-03-02 2007-03-27 Compositions de polyester lesquelles comprennent du cyclobutanediol et certains agents stabilisants thermiques et/ou des produits de réaction de ceux-ci WO2007126855A1 (fr)

Priority Applications (22)

Application Number Priority Date Filing Date Title
US12/294,690 US20100184940A1 (en) 2005-03-02 2007-03-27 Polyester Compositions Which Comprise Cyclobutanediol and Certain Thermal Stabilizers, and/or Reaction Products Thereof
PCT/US2007/010590 WO2007139655A1 (fr) 2006-05-23 2007-05-02 Compositions de polyester comprenant un cyclobutanediol et un certain nombre de stabilisants thermiques et/ou des produits de réaction de ceux-ci
PCT/US2007/010551 WO2007139653A1 (fr) 2006-05-23 2007-05-02 Films de lcd ou feuilles comprenant des films comprenant des compositions polyester formées de 2,2,4,4,-tétraméthyl-1,3-cyclobutanediol et de 1,4-cyclohexanediméthanol
PCT/US2007/011150 WO2007139663A1 (fr) 2006-05-23 2007-05-09 Compositions de polyester comprenant du cyclobutanediol et certains stabilisants vis-à-vis de la chaleur et/ou des produits de réaction de ceux-ci
BRPI0717761-5A BRPI0717761A2 (pt) 2006-10-27 2007-07-10 composiÇço de poliÉster, mistura de polÍmero, e, artigo de manufatura
MX2009003375A MX2009003375A (es) 2006-10-27 2007-07-10 Composiones de poliester que comprenden tetrametilciclobutanodiol, ciclohexanodimetanol y etilenglicol, y procesos de manufctura para las mismas.
EP07836029A EP2074158A1 (fr) 2006-10-27 2007-07-10 Compositions de polyester de couleur améliorée comprenant cyclobutanediol, éthylèneglycol, titane et phosphore, et méthodes de production desdites compositions
JP2009534565A JP2010507716A (ja) 2006-10-27 2007-07-10 テトラメチルシクロブタンジオール、シクロヘキサンジメタノール及びエチレングリコールを含むポリエステル組成物並びにその製造方法
PCT/US2007/015701 WO2008051320A1 (fr) 2006-10-27 2007-07-10 Compositions de polyester comprenant tétraméthylcyclobutanediol, cyclohexanediméthanol et éthylèneglycol, et méthodes de production desdites compositions
KR1020097008483A KR20090079211A (ko) 2006-10-27 2007-07-10 테트라메틸사이클로뷰테인다이올, 사이클로헥세인다이메탄올, 및 에틸렌 글라이콜을 포함하는 폴리에스터 조성물, 및 이의 제조 방법
PCT/US2007/015702 WO2008054559A1 (fr) 2006-10-27 2007-07-10 Certaines compositions de polyester qui comprennent du tétraméthylcyclobutanediol, du cyclohexanediméthanol et un acide trans-cyclohexanedicarboxylique supérieur
BRPI0717755-0A BRPI0717755A2 (pt) 2006-10-27 2007-07-10 composiÇço de poliÉster, mistura, e, artigo de manufatura
TW096125089A TW200819496A (en) 2006-10-27 2007-07-10 Polyester compositions which comprise cyclobutanediol, ethylene glycol, titanium, and phosphorus with improved color and manufacturing processes therefor
EP07836026A EP2074174A1 (fr) 2006-10-27 2007-07-10 Compositions de polyester comprenant tétraméthylcyclobutanediol, cyclohexanediméthanol et éthylèneglycol, et méthodes de production desdites compositions
CA002666571A CA2666571A1 (fr) 2006-10-27 2007-07-10 Compositions de polyester comprenant tetramethylcyclobutanediol, cyclohexanedimethanol et ethyleneglycol, et methodes de production desdites compositions
PCT/US2007/015704 WO2008051321A1 (fr) 2006-10-27 2007-07-10 Compositions de polyester de couleur améliorée comprenant cyclobutanediol, éthylèneglycol, titane et phosphore, et méthodes de production desdites compositions
CA002666585A CA2666585A1 (fr) 2006-10-27 2007-07-10 Compositions de polyester
JP2009534566A JP2010507717A (ja) 2006-10-27 2007-07-10 ポリエステル組成物
PCT/US2007/015713 WO2008054560A2 (fr) 2006-10-27 2007-07-10 Certaines compositions de polyester qui comprennent du cyclobutanediol, du cyclohexanediméthanol, et de l'acide trans-cyclohexanedicarboxylique supérieur
KR1020097008484A KR20090079212A (ko) 2006-10-27 2007-07-10 사이클로뷰테인다이올, 에틸렌 글라이콜, 티타늄 및 인을 포함하는 개선된 색상의 폴리에스터 조성물 및 이의 제조방법
MX2009003369A MX2009003369A (es) 2006-10-27 2007-07-10 Composiciones de poliester.
TW096125125A TW200819497A (en) 2006-10-27 2007-07-10 Polyester compositions which comprise cyclobutanediol, cyclohexanedimethanol, and ethylene glycol and manufacturing processes therefor

Applications Claiming Priority (136)

Application Number Priority Date Filing Date Title
US39077306A 2006-03-28 2006-03-28
US78657206P 2006-03-28 2006-03-28
US78659606P 2006-03-28 2006-03-28
US78654706P 2006-03-28 2006-03-28
US78657106P 2006-03-28 2006-03-28
US78659806P 2006-03-28 2006-03-28
US11/390,826 2006-03-28
US11/391,659 US20060287496A1 (en) 2005-06-17 2006-03-28 Polyester compositions comprising minimal amounts of cyclobutanediol
US11/390,883 US7834129B2 (en) 2005-06-17 2006-03-28 Restaurant smallware comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/391,565 US7781562B2 (en) 2005-06-17 2006-03-28 Polyester compositions containing cyclobutanediol having a certain combination of inherent viscosity and moderate glass transition temperature and articles made therefrom
US11/391,565 2006-03-28
US11/390,883 2006-03-28
US11/390,722 2006-03-28
US11/390,671 US8063172B2 (en) 2005-06-17 2006-03-28 Film(s) and/or sheet(s) made using polyester compositions containing low amounts of cyclobutanediol
US11/390,858 2006-03-28
US11/390,858 US7951900B2 (en) 2005-06-17 2006-03-28 Dialysis filter housings comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/391,063 2006-03-28
US11/390,882 US20060287486A1 (en) 2005-06-17 2006-03-28 Optical media comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/391,495 US7807775B2 (en) 2005-06-17 2006-03-28 Point of purchase displays comprising polyester compositions formed from 2,2,4,4-tetramethyl-1, 3,-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/390,853 US20070270569A1 (en) 2005-06-17 2006-03-28 Film(s) and/or sheet(s) made from polyester compositions containing cyclobutanediol and articles made therefrom
US11/390,655 US8067525B2 (en) 2005-06-17 2006-03-28 Film(s) and/or sheet(s) comprising polyester compositions which comprise cyclobutanediol and have a certain combination of inherent viscosity and high glass transition temperature
US11/391,125 US20070010650A1 (en) 2005-06-17 2006-03-28 Tough amorphous polyester compositions
US11/391,485 2006-03-28
US11/390,750 2006-03-28
US11/390,794 2006-03-28
US11/390,563 US7902320B2 (en) 2005-06-17 2006-03-28 Graphic art films comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/390,853 2006-03-28
US11/390,814 US20060286327A1 (en) 2005-06-17 2006-03-28 Retort containers comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/390,846 2006-03-28
US11/390,751 2006-03-28
US11/391,125 2006-03-28
US11/390,814 2006-03-28
US11/390,882 2006-03-28
US11/390,812 2006-03-28
US11/391,576 US7803441B2 (en) 2005-06-17 2006-03-28 Intravenous components comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/391,571 US20060287494A1 (en) 2005-06-17 2006-03-28 Polyester compositions containing high amounts of cyclobutanediol and articles made therefrom
US11/390,629 US7803439B2 (en) 2005-06-17 2006-03-28 Blood therapy containers comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/390,827 2006-03-28
US11/390,631 US7855267B2 (en) 2005-06-17 2006-03-28 Film(s) and/or sheet(s) comprising polyester compositions which comprise cyclobutanediol and have a certain combination of inherent viscosity and moderate glass transition temperature
US11/391,156 2006-03-28
US60/786,598 2006-03-28
US11/390,836 US20060286330A1 (en) 2005-06-17 2006-03-28 Sterilization containers comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/391,156 US7812112B2 (en) 2005-06-17 2006-03-28 Outdoor signs comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/390,846 US7955674B2 (en) 2005-03-02 2006-03-28 Transparent polymer blends containing polyesters comprising a cyclobutanediol and articles prepared therefrom
US11/390,847 2006-03-28
US11/391,063 US7576171B2 (en) 2005-06-17 2006-03-28 Pacifiers comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/390,812 US7959836B2 (en) 2005-03-02 2006-03-28 Process for the preparation of transparent, shaped articles containing polyesters comprising a cyclobutanediol
US11/391,505 2006-03-28
US11/391,571 2006-03-28
US11/390,811 2006-03-28
US60/786,547 2006-03-28
US11/390,793 US20060286389A1 (en) 2005-06-17 2006-03-28 Protein-resistant articles comprising cyclobutanediol
US11/390,836 2006-03-28
US11/390,865 US20060287485A1 (en) 2005-06-17 2006-03-28 Sound barriers comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/390,794 US8119761B2 (en) 2005-06-17 2006-03-28 Polyester compositions containing cyclobutanediol having a certain combination of inherent viscosity and high glass transition temperature and articles made therefrom
US60/786,571 2006-03-28
US11/391,137 US7985827B2 (en) 2005-06-17 2006-03-28 Polyester compositions which comprise cyclobutanediol having certain cis/trans ratios
US11/390,809 2006-03-28
US11/391,495 2006-03-28
US11/390,655 2006-03-28
US11/390,630 US7807774B2 (en) 2005-06-17 2006-03-28 Vending machines comprising polyester compositions formed from 2,2,4,4,-tetramethyl-1,3,-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/390,773 2006-03-28
US11/390,752 US8063173B2 (en) 2005-06-17 2006-03-28 Polyester compositions containing low amounts of cyclobutanediol and articles made therefrom
US11/390,629 2006-03-28
US11/391,137 2006-03-28
US11/390,671 2006-03-28
US11/391,659 2006-03-28
US11/390,864 2006-03-28
US11/390,654 2006-03-28
US11/390,955 US7915376B2 (en) 2005-06-17 2006-03-28 Containers comprising polyester compositions which comprise cyclobutanediol
US11/391,485 US7842776B2 (en) 2005-06-17 2006-03-28 Appliance parts comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/391,576 2006-03-28
US11/390,630 2006-03-28
US11/390,847 US20060287484A1 (en) 2005-06-17 2006-03-28 Opththalmic devices comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/390,809 US7959998B2 (en) 2005-03-02 2006-03-28 Transparent, oxygen-scavenging compositions containing polyesters comprising a cyclobutanediol and articles prepared therefrom
US11/390,811 US7868128B2 (en) 2005-06-17 2006-03-28 Skylights and windows comprising polyester compositions formed from 2,2,4,4,-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/391,124 US20060234073A1 (en) 2005-03-02 2006-03-28 Multilayered, transparent articles containing polyesters comprising a cyclobutanediol and a process for their preparation
US11/391,642 US7510768B2 (en) 2005-06-17 2006-03-28 Thermoplastic articles comprising cyclobutanediol having a decorative material embedded therein
US11/390,631 2006-03-28
US11/390,672 US20060287479A1 (en) 2005-06-17 2006-03-28 Polyester compositions containing cyclobutanediol and articles made therefrom
US11/390,750 US20060287480A1 (en) 2005-06-17 2006-03-28 Outdoor shelters comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/390,722 US7893187B2 (en) 2005-06-17 2006-03-28 Glass laminates comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US60/786,572 2006-03-28
US11/390,864 US7812111B2 (en) 2005-06-17 2006-03-28 LCD films comprising polyester compositions formed from 2,2,4,4-tetramethy1-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/390,827 US7893188B2 (en) 2005-06-17 2006-03-28 Baby bottles comprising polyester compositions which comprise cyclobutanediol
US11/391,124 2006-03-28
US11/390,908 2006-03-28
US11/390,908 US7462684B2 (en) 2005-03-02 2006-03-28 Preparation of transparent, multilayered articles containing polyesters comprising a cyclobutanediol and homogeneous polyamide blends
US11/390,752 2006-03-28
US11/390,955 2006-03-28
US60/786,596 2006-03-28
US11/390,672 2006-03-28
US11/391,642 2006-03-28
US11/391,505 US7838620B2 (en) 2005-06-17 2006-03-28 Thermoformed sheet(s) comprising polyester compositions which comprise cyclobutanediol
US11/390,751 US7803440B2 (en) 2005-06-17 2006-03-28 Bottles comprising polyester compositions which comprise cyclobutanediol
US11/390,563 2006-03-28
US11/390,826 US7906610B2 (en) 2005-06-17 2006-03-28 Food service products comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/390,865 2006-03-28
US11/390,793 2006-03-28
US11/390,654 US20060287477A1 (en) 2005-06-17 2006-03-28 Greenhouses comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4- cyclohexanedimethanol
US11/439,062 2006-05-23
US11/439,340 2006-05-23
US11/439,340 US20060270806A1 (en) 2005-05-26 2006-05-23 Miscible high Tg polyester/polymer blend compositions and films formed therefrom
US11/439,062 US20060270773A1 (en) 2005-05-26 2006-05-23 Polyester-polycarbonate blends for diffuser sheets with improved luminance
USPCT/US2006/042292 2006-10-27
PCT/US2006/041917 WO2007053434A1 (fr) 2005-10-28 2006-10-27 Compositions de polyester comprenant du cyclobutanediol et certains stabilisants thermiques et/ou des produits de reaction de ceux-ci
US11/588,458 2006-10-27
US11/588,883 US20070105993A1 (en) 2005-10-28 2006-10-27 Polyester compositions which comprise cyclobutanediol and at least one phosphorus compound
PCT/US2006/042293 WO2007053550A1 (fr) 2005-10-28 2006-10-27 Compositions de polyester contenant du cyclobutanediol qui presente une temperature de transition vitreuse elevee et articles fabriques a partir de celles-ci
US11/588,458 US20070100122A1 (en) 2005-10-28 2006-10-27 Polyester compositions containing cyclobutanediol and articles made therefrom
US11/588,527 2006-10-27
US11/588,524 US20100096589A1 (en) 2005-10-28 2006-10-27 Polyester compositions containing low amounts of cyclobutanediol and articles made therefrom
US11/588,554 2006-10-27
PCT/US2006/042292 WO2007053549A1 (fr) 2005-10-28 2006-10-27 Compositions de polyester contenant du cyclobutanediol qui presente une certaine combinaison d'indice logarithmique de viscosite et de temperature de transition vitreuse moderee et articles fabriques a partir de celles-ci
USPCT/US2006/041917 2006-10-27
USPCT/US2006/042069 2006-10-27
PCT/US2006/042291 WO2007053548A2 (fr) 2005-10-28 2006-10-27 Compositions de polyester comprenant des quantites minimales de cyclobutanediol
US11/588,906 2006-10-27
US11/588,907 US20070106054A1 (en) 2005-10-28 2006-10-27 Polyester compositions containing cyclobutanediol having a certain combination of inherent viscosity and high glass transition temperature and articles made therefrom
US11/588,527 US20100087574A1 (en) 2005-10-28 2006-10-27 Polyester compositions containing cyclobutanediol having a certain combination of inherent viscosity and moderate glass transition temperature and articles made therefrom
US11/588,906 US8193302B2 (en) 2005-10-28 2006-10-27 Polyester compositions which comprise cyclobutanediol and certain phosphate thermal stabilizers, and/or reaction products thereof
US11/588,883 2006-10-27
US11/588,524 2006-10-27
USPCT/US2006/042293 2006-10-27
US11/588,907 2006-10-27
USPCT/US2006/042291 2006-10-27
US11/588,554 US20070100125A1 (en) 2005-10-28 2006-10-27 Polyester compositions comprising minimal amounts of cyclobutanediol
PCT/US2006/042069 WO2007053460A1 (fr) 2005-10-28 2006-10-27 Compositions de polyester comprenant du cyclobutanediol et au moins un compose phosphoreux
US11/635,434 US7737246B2 (en) 2005-12-15 2006-12-07 Polyester compositions which comprise cyclobutanediol, cyclohexanedimethanol, and ethylene glycol and manufacturing processes therefor
US11/635,434 2006-12-07
US11/635,433 US20070142511A1 (en) 2005-12-15 2006-12-07 Polyester compositions which comprise cyclobutanediol ethylene glycol, titanium, and phosphorus with improved color and manufacturing processes therefor
US11/635,433 2006-12-07
US11/706,791 2007-02-14
US11/706,476 2007-02-14
US11/706,791 US20070232779A1 (en) 2006-03-28 2007-02-14 Certain polyester compositions which comprise cyclohexanedimethanol, moderate cyclobutanediol, cyclohexanedimethanol, and high trans cyclohexanedicarboxylic acid
US11/706,476 US20070232778A1 (en) 2006-03-28 2007-02-14 Certain polyester compositions which comprise cyclobutanediol, cyclohexanedimethanol, and high trans-cyclohexanedicarboxylic acid

Related Parent Applications (38)

Application Number Title Priority Date Filing Date
US11/390,814 Continuation-In-Part US20060286327A1 (en) 2005-03-02 2006-03-28 Retort containers comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/391,576 Continuation-In-Part US7803441B2 (en) 2005-03-02 2006-03-28 Intravenous components comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/390,793 Continuation-In-Part US20060286389A1 (en) 2005-03-02 2006-03-28 Protein-resistant articles comprising cyclobutanediol
US11/391,485 Continuation-In-Part US7842776B2 (en) 2005-03-02 2006-03-28 Appliance parts comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/390,955 Continuation-In-Part US7915376B2 (en) 2005-03-02 2006-03-28 Containers comprising polyester compositions which comprise cyclobutanediol
US11/390,812 Continuation-In-Part US7959836B2 (en) 2005-03-02 2006-03-28 Process for the preparation of transparent, shaped articles containing polyesters comprising a cyclobutanediol
US11/390,846 Continuation-In-Part US7955674B2 (en) 2005-03-02 2006-03-28 Transparent polymer blends containing polyesters comprising a cyclobutanediol and articles prepared therefrom
US11/391,137 Continuation-In-Part US7985827B2 (en) 2005-03-02 2006-03-28 Polyester compositions which comprise cyclobutanediol having certain cis/trans ratios
US11/390,630 Continuation-In-Part US7807774B2 (en) 2005-03-02 2006-03-28 Vending machines comprising polyester compositions formed from 2,2,4,4,-tetramethyl-1,3,-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/390,654 Continuation-In-Part US20060287477A1 (en) 2005-03-02 2006-03-28 Greenhouses comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4- cyclohexanedimethanol
US11/390,722 Continuation-In-Part US7893187B2 (en) 2005-03-02 2006-03-28 Glass laminates comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/390,655 Continuation-In-Part US8067525B2 (en) 2005-03-02 2006-03-28 Film(s) and/or sheet(s) comprising polyester compositions which comprise cyclobutanediol and have a certain combination of inherent viscosity and high glass transition temperature
US11/390,836 Continuation-In-Part US20060286330A1 (en) 2005-03-02 2006-03-28 Sterilization containers comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/390,809 Continuation-In-Part US7959998B2 (en) 2005-03-02 2006-03-28 Transparent, oxygen-scavenging compositions containing polyesters comprising a cyclobutanediol and articles prepared therefrom
US39077306A Continuation-In-Part 2005-03-02 2006-03-28
US11/391,659 Continuation-In-Part US20060287496A1 (en) 2005-03-02 2006-03-28 Polyester compositions comprising minimal amounts of cyclobutanediol
US11/390,827 Continuation-In-Part US7893188B2 (en) 2005-03-02 2006-03-28 Baby bottles comprising polyester compositions which comprise cyclobutanediol
US11/391,565 Continuation-In-Part US7781562B2 (en) 2005-03-02 2006-03-28 Polyester compositions containing cyclobutanediol having a certain combination of inherent viscosity and moderate glass transition temperature and articles made therefrom
US11/390,631 Continuation-In-Part US7855267B2 (en) 2005-03-02 2006-03-28 Film(s) and/or sheet(s) comprising polyester compositions which comprise cyclobutanediol and have a certain combination of inherent viscosity and moderate glass transition temperature
US11/391,495 Continuation-In-Part US7807775B2 (en) 2005-03-02 2006-03-28 Point of purchase displays comprising polyester compositions formed from 2,2,4,4-tetramethyl-1, 3,-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/391,642 Continuation-In-Part US7510768B2 (en) 2005-03-02 2006-03-28 Thermoplastic articles comprising cyclobutanediol having a decorative material embedded therein
US11/390,752 Continuation-In-Part US8063173B2 (en) 2005-03-02 2006-03-28 Polyester compositions containing low amounts of cyclobutanediol and articles made therefrom
US11/391,063 Continuation-In-Part US7576171B2 (en) 2005-03-02 2006-03-28 Pacifiers comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/390,751 Continuation-In-Part US7803440B2 (en) 2005-03-02 2006-03-28 Bottles comprising polyester compositions which comprise cyclobutanediol
US11/391,505 Continuation-In-Part US7838620B2 (en) 2005-03-02 2006-03-28 Thermoformed sheet(s) comprising polyester compositions which comprise cyclobutanediol
US11/391,156 Continuation-In-Part US7812112B2 (en) 2005-03-02 2006-03-28 Outdoor signs comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/390,858 Continuation-In-Part US7951900B2 (en) 2005-03-02 2006-03-28 Dialysis filter housings comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/391,125 Continuation-In-Part US20070010650A1 (en) 2005-03-02 2006-03-28 Tough amorphous polyester compositions
US11/390,794 Continuation-In-Part US8119761B2 (en) 2005-03-02 2006-03-28 Polyester compositions containing cyclobutanediol having a certain combination of inherent viscosity and high glass transition temperature and articles made therefrom
US11/390,750 Continuation-In-Part US20060287480A1 (en) 2005-03-02 2006-03-28 Outdoor shelters comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/391,124 Continuation-In-Part US20060234073A1 (en) 2005-03-02 2006-03-28 Multilayered, transparent articles containing polyesters comprising a cyclobutanediol and a process for their preparation
US11/390,563 Continuation-In-Part US7902320B2 (en) 2005-03-02 2006-03-28 Graphic art films comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/390,826 Continuation-In-Part US7906610B2 (en) 2005-03-02 2006-03-28 Food service products comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/390,629 Continuation-In-Part US7803439B2 (en) 2005-03-02 2006-03-28 Blood therapy containers comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US11/391,571 Continuation-In-Part US20060287494A1 (en) 2005-03-02 2006-03-28 Polyester compositions containing high amounts of cyclobutanediol and articles made therefrom
US11/390,671 Continuation-In-Part US8063172B2 (en) 2005-03-02 2006-03-28 Film(s) and/or sheet(s) made using polyester compositions containing low amounts of cyclobutanediol
US11/390,908 Continuation-In-Part US7462684B2 (en) 2005-03-02 2006-03-28 Preparation of transparent, multilayered articles containing polyesters comprising a cyclobutanediol and homogeneous polyamide blends
US11/390,811 Continuation-In-Part US7868128B2 (en) 2005-03-02 2006-03-28 Skylights and windows comprising polyester compositions formed from 2,2,4,4,-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol

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PCT/US2007/007632 WO2007126855A1 (fr) 2005-03-02 2007-03-27 Compositions de polyester lesquelles comprennent du cyclobutanediol et certains agents stabilisants thermiques et/ou des produits de réaction de ceux-ci
PCT/US2007/007532 WO2007123631A1 (fr) 2005-06-17 2007-03-27 Compositions polyester comprenant du cyclobutanediol et au moins un compose phosphore

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Application Number Title Priority Date Filing Date
PCT/US2007/007532 WO2007123631A1 (fr) 2005-06-17 2007-03-27 Compositions polyester comprenant du cyclobutanediol et au moins un compose phosphore

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