GB1044015A - Improved linear polyesters - Google Patents

Improved linear polyesters

Info

Publication number
GB1044015A
GB1044015A GB22696/63A GB2269663A GB1044015A GB 1044015 A GB1044015 A GB 1044015A GB 22696/63 A GB22696/63 A GB 22696/63A GB 2269663 A GB2269663 A GB 2269663A GB 1044015 A GB1044015 A GB 1044015A
Authority
GB
United Kingdom
Prior art keywords
cyclobutanediol
tetramethyl
dimethyl
dimethyl terephthalate
dialkyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB22696/63A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kodak Ltd
Original Assignee
Kodak Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US860375A external-priority patent/US3313777A/en
Priority claimed from FR847213A external-priority patent/FR1278284A/en
Application filed by Kodak Ltd filed Critical Kodak Ltd
Publication of GB1044015A publication Critical patent/GB1044015A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/44—Polyester-amides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16—Dicarboxylic acids and dihydroxy compounds
    • C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
    • C08G63/199—Acids or hydroxy compounds containing cycloaliphatic rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/60—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from the reaction of a mixture of hydroxy carboxylic acids, polycarboxylic acids and polyhydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
    • C08G64/02—Aliphatic polycarbonates
    • C08G64/0208—Aliphatic polycarbonates saturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyesters Or Polycarbonates (AREA)

Abstract

In the manufacture of linear polyesters by reacting a dialkyl ester of a dicarboxylic acid or carbonic acid with a 2:2:4:4-tetraalkyl-1:3-cyclobutanediol, there is used as catalyst an organo-tin compound or a stannous ester. Specified organic tin compounds are dialkyl tin oxides, dichlorides, dibromides, diiodides and dialkoxides; dialkyl dinonyl tins; and dialkyl tin esters of alkanoic and alkanedioic acids. Specified dicarboxylic acids are terephthalic, naphthalene dicarboxylic, 4:41-sulphonyldibenzoic, cyclo hexane-1:4-dicarboxylic and cycloic acid. In addition to the cyclobutanediol, other glycols may be used, e.g. ethylene glycol, 1:6-hexanediol, neopentylene glycol, quinitol, poly (oxyalkylene glycols) and poly (thioalkyleneglycols). After the ester-interchange reaction between the dihydroxy compound and the dialkyl ester, the product is either subject to a melt phase polymerization or is first subjected to a melt phase polymerization to produce a prepolymer which is then solidified and ground and subjected to a solid phase polymerization, possibly after crystallization by treatment with acetone. Examples describe the manufacture of polyesters by reacting (1) 2:2:4:4-tetramethyl - 1:3 - cyclobutanediol and dimethyl terephthalate; (2) 2:2:4:4 - tetramethyl - 1:3 - cyclobutanediol, dimethyl terephthalate and dimethyl azelate; (3) 2:2:4:4 - tetramethyl - 1:3 - cyclobutanediol and dimethyl azelate; (4) 2:2:4:4 - tetramethyl - 1:3-cyclobutanediol and dibutyl 4,41-sulphonyl dibenzoate; (5) 2:2:4:4 - tetramethyl - 1:3-cyclobutanediol and dimethyl trans-cyclohexane - 1:4 - dicarboxylate; (6) 2:4 - dimethyl-2:4 - diisopropyl - 1:3 - cyclobutanediol and dimethyl terephthalate; (7) 2:2:4:4 - tetramethyl - 1:3 - cyclobutanediol, 1:6 - hexanediol and dimethyl terephthalate; (8) 2:2:4:4-tetramethyl - 1:3 - cyclobutanediol, 1:4-cyclohexanedimethanol and dimethyl terephthalate; (9) 2:2:4:4 - tetramethyl - 1:3 - cyclobutanediol, polyoxytetramethylene glycol (M.W. 3100) and dimethyl terephthalate.
GB22696/63A 1959-12-18 1963-06-07 Improved linear polyesters Expired GB1044015A (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US860375A US3313777A (en) 1959-12-18 1959-12-18 Linear polyesters and polyester-amides from 2, 2, 4, 4-tetraalkyl-1, 3-cyclobutanediols
FR847213A FR1278284A (en) 1959-12-18 1960-12-16 New polymers derived from 2, 2, 4, 4-tetraalkyl-1, 3-cyclobutanediols and their industrial applications
US20067262A 1962-06-07 1962-06-07
FR937198A FR83790E (en) 1959-12-18 1963-06-06 New polymers derived from 2, 2, 4, 4-tetraalkyl-1, 3-cyclobutanediols and their industrial applications

Publications (1)

Publication Number Publication Date
GB1044015A true GB1044015A (en) 1966-09-28

Family

ID=27445255

Family Applications (1)

Application Number Title Priority Date Filing Date
GB22696/63A Expired GB1044015A (en) 1959-12-18 1963-06-07 Improved linear polyesters

Country Status (2)

Country Link
FR (1) FR83790E (en)
GB (1) GB1044015A (en)

Cited By (44)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4014858A (en) 1975-05-12 1977-03-29 Standard Oil Company Polybutylene terephthalate
US4049631A (en) * 1975-12-22 1977-09-20 Owens-Illinois, Inc. Isophthalic acid/p,p-sulfonyldibenzoic acid/ethylene glycol/neopentyl glycol polyester compositions and containers made therefrom
US4076693A (en) * 1975-12-22 1978-02-28 Owens-Illinois, Inc. Terephthalic acid/p,p-sulfonyldibenzoic acid/ethylene glycol/neopentyl glycol polyester compositions and containers made therefrom
US4777282A (en) * 1985-08-27 1988-10-11 Raychem Limited Preparation of monomers
US4845179A (en) * 1984-02-27 1989-07-04 Raychem Limited Preparation of organic polymers using organometallic capped monomers to produce metal free polymers
US5104942A (en) * 1985-08-27 1992-04-14 Towle Ian H Preparation of side-chain polymers
US5705575A (en) * 1995-05-31 1998-01-06 Shell Oil Company Copolyester composition
WO2006137954A1 (en) * 2005-06-17 2006-12-28 Eastman Chemical Company Polyester compositions containing low amounts of cyclobutanediol and articles made therefrom
WO2007050118A1 (en) * 2005-10-28 2007-05-03 Eastman Chemical Company Restaurant smallware comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
WO2007053434A1 (en) * 2005-10-28 2007-05-10 Eastman Chemical Company Polyester compositions which comprise cyclobutanediol and certain thermal stabilizers, and/or reaction products thereof
WO2007053549A1 (en) * 2005-10-28 2007-05-10 Eastman Chemical Company Polyester compositions containing cyclobutanediol having a certain combination of inherent viscosity and moderate glass transition temperature and articles made therefrom
WO2007123631A1 (en) * 2006-03-28 2007-11-01 Eastman Chemical Company Polyester compositions which comprise cyclobutanediol and at least one phosphorus compound
US7704605B2 (en) 2006-03-28 2010-04-27 Eastman Chemical Company Thermoplastic articles comprising cyclobutanediol having a decorative material embedded therein
US7737246B2 (en) 2005-12-15 2010-06-15 Eastman Chemical Company Polyester compositions which comprise cyclobutanediol, cyclohexanedimethanol, and ethylene glycol and manufacturing processes therefor
WO2010114508A1 (en) * 2009-04-01 2010-10-07 Eastman Chemical Company Improved process for the production of polyesters
US8163850B2 (en) 2009-02-06 2012-04-24 Eastman Chemical Company Thermosetting polyester coating compositions containing tetramethyl cyclobutanediol
US8168721B2 (en) 2009-02-06 2012-05-01 Eastman Chemical Company Coating compositions containing tetramethyl cyclobutanediol
US8193302B2 (en) 2005-10-28 2012-06-05 Eastman Chemical Company Polyester compositions which comprise cyclobutanediol and certain phosphate thermal stabilizers, and/or reaction products thereof
US8198371B2 (en) 2008-06-27 2012-06-12 Eastman Chemical Company Blends of polyesters and ABS copolymers
CN101193932B (en) * 2005-06-17 2012-08-08 伊士曼化工公司 Polyester compositions which comprise cyclobutanediol and have a certain combination of inherent viscosity and moderate glass transition temperature and articles made therefrom
US8287970B2 (en) 2007-11-21 2012-10-16 Eastman Chemical Company Plastic baby bottles, other blow molded articles, and processes for their manufacture
US8324316B2 (en) 2009-02-06 2012-12-04 Eastman Chemical Company Unsaturated polyester resin compositions containing 2,2,2,4-tetramethyl-1,3-cyclobutanediol and articles made therefrom
WO2013012556A1 (en) * 2011-07-21 2013-01-24 Eastman Chemical Company Sulfopolyester polymer compositions with improved water dispersibility
US8394997B2 (en) 2010-12-09 2013-03-12 Eastman Chemical Company Process for the isomerization of 2,2,4,4-tetraalkylcyclobutane-1,3-diols
US8420869B2 (en) 2010-12-09 2013-04-16 Eastman Chemical Company Process for the preparation of 2,2,4,4-tetraalkylcyclobutane-1,3-diols
US8420868B2 (en) 2010-12-09 2013-04-16 Eastman Chemical Company Process for the preparation of 2,2,4,4-tetraalkylcyclobutane-1,3-diols
US8501287B2 (en) 2007-11-21 2013-08-06 Eastman Chemical Company Plastic baby bottles, other blow molded articles, and processes for their manufacture
US8586701B2 (en) 2005-10-28 2013-11-19 Eastman Chemical Company Process for the preparation of copolyesters based on 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
WO2014066296A1 (en) * 2012-10-23 2014-05-01 Eastman Chemical Company Copolyesters containing neopentyl glycol and 2,2,4,4-tetraalkyl-1,3-cyclobutanediol
US8895654B2 (en) 2008-12-18 2014-11-25 Eastman Chemical Company Polyester compositions which comprise spiro-glycol, cyclohexanedimethanol, and terephthalic acid
US9029461B2 (en) 2009-02-06 2015-05-12 Eastman Chemical Company Aliphatic polyester coating compositions containing tetramethyl cyclobutanediol
US9029460B2 (en) 2009-02-06 2015-05-12 Stacey James Marsh Coating compositions containing acrylic and aliphatic polyester blends
US9127122B2 (en) 2012-10-23 2015-09-08 Eastman Chemical Company Copolyesters containing neopentyl glycol and 2,2,4,4-tetraalkyl 1,3-cyclobutanediol
US9169388B2 (en) 2006-03-28 2015-10-27 Eastman Chemical Company Polyester compositions which comprise cyclobutanediol and certain thermal stabilizers, and/or reaction products thereof
US9487619B2 (en) 2014-10-27 2016-11-08 Eastman Chemical Company Carboxyl functional curable polyesters containing tetra-alkyl cyclobutanediol
US9598533B2 (en) 2005-11-22 2017-03-21 Eastman Chemical Company Polyester compositions containing cyclobutanediol having a certain combination of inherent viscosity and moderate glass transition temperature and articles made therefrom
US9598602B2 (en) 2014-11-13 2017-03-21 Eastman Chemical Company Thermosetting compositions based on phenolic resins and curable poleyester resins made with diketene or beta-ketoacetate containing compounds
US9650539B2 (en) 2014-10-27 2017-05-16 Eastman Chemical Company Thermosetting compositions based on unsaturated polyesters and phenolic resins
US9982125B2 (en) 2012-02-16 2018-05-29 Eastman Chemical Company Clear semi-crystalline articles with improved heat resistance
US9988553B2 (en) 2016-02-22 2018-06-05 Eastman Chemical Company Thermosetting coating compositions
US10011737B2 (en) 2016-03-23 2018-07-03 Eastman Chemical Company Curable polyester polyols and their use in thermosetting soft feel coating formulations
US10526444B2 (en) 2015-09-25 2020-01-07 Eastman Chemical Company Polymers containing cyclobutanediol and 2,2-bis(hydroxymethyl)alkylcarboxylic acid
CN111087586A (en) * 2019-12-18 2020-05-01 浙江恒澜科技有限公司 2,2,4, 4-tetramethyl-1, 3-cyclobutanediol modified high-heat-resistance biodegradable polyester
US10676565B2 (en) 2015-05-19 2020-06-09 Eastman Chemical Company Aliphatic polyester coating compositions containing tetramethyl cyclobutanediol

Cited By (134)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4014858A (en) 1975-05-12 1977-03-29 Standard Oil Company Polybutylene terephthalate
US4049631A (en) * 1975-12-22 1977-09-20 Owens-Illinois, Inc. Isophthalic acid/p,p-sulfonyldibenzoic acid/ethylene glycol/neopentyl glycol polyester compositions and containers made therefrom
US4076693A (en) * 1975-12-22 1978-02-28 Owens-Illinois, Inc. Terephthalic acid/p,p-sulfonyldibenzoic acid/ethylene glycol/neopentyl glycol polyester compositions and containers made therefrom
US4845179A (en) * 1984-02-27 1989-07-04 Raychem Limited Preparation of organic polymers using organometallic capped monomers to produce metal free polymers
US4960835A (en) * 1984-02-27 1990-10-02 Raychem Limited Preparation of organic polymers using organometallic terminated blocks to produce metal free block copolymers
US4777282A (en) * 1985-08-27 1988-10-11 Raychem Limited Preparation of monomers
US4841094A (en) * 1985-08-27 1989-06-20 Raychem Limited Preparation of monomers
US5041611A (en) * 1985-08-27 1991-08-20 Raychem Limited Preparation of monomers
US5104942A (en) * 1985-08-27 1992-04-14 Towle Ian H Preparation of side-chain polymers
US5705575A (en) * 1995-05-31 1998-01-06 Shell Oil Company Copolyester composition
EP2138523A1 (en) * 2005-06-17 2009-12-30 Eastman Chemical Company Blood therapy containers comprising polyester compositions formed from 2,2,4,4-tetramethyl-1-3-cyclobutanediol and 1,4-cyclohexanedimethanol
US7803440B2 (en) 2005-06-17 2010-09-28 Eastman Chemical Company Bottles comprising polyester compositions which comprise cyclobutanediol
WO2007001547A1 (en) * 2005-06-17 2007-01-04 Eastman Chemical Company Polyester compositions which comprise cyclobutanediol having certain cis/trans ratios
WO2007001555A1 (en) * 2005-06-17 2007-01-04 Eastman Chemical Company Lcd films or sheets comprising polyester compositions formed from 2,2,4,4,-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
WO2007001557A1 (en) * 2005-06-17 2007-01-04 Eastman Chemical Company Polyester compositions containing cyclobutanediol having a certain combination of inherent viscosity and high glass transition temperature and articles made therefrom
WO2007001548A1 (en) * 2005-06-17 2007-01-04 Eastman Chemical Company Intravenous components comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
WO2007001566A1 (en) * 2005-06-17 2007-01-04 Eastman Chemical Company Point of purchase displays comprising polyester compositions
WO2007001537A1 (en) * 2005-06-17 2007-01-04 Eastman Chemical Company Greenhouses comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
WO2007001553A1 (en) * 2005-06-17 2007-01-04 Eastman Chemical Company Polyester compositions containing cyclobutanediol and articles made therefrom
WO2007001573A1 (en) * 2005-06-17 2007-01-04 Eastman Chemical Company Containers comprising polyester compositions which comprise cyclobutanediol
WO2007001533A1 (en) * 2005-06-17 2007-01-04 Eastman Chemical Company Vending machines comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
WO2007001569A1 (en) * 2005-06-17 2007-01-04 Eastman Chemical Company Polyester compositions containing high amounts of cyclobutanediol and articles made therefrom
WO2007001559A1 (en) * 2005-06-17 2007-01-04 Eastman Chemical Company Food storage containers comprising polyester compositions formed from 2,2,4,4-tetramethyl-1, 3-cyclobutanediol and 1, 4-cyclohexanedimethanol
WO2007001528A1 (en) * 2005-06-17 2007-01-04 Eastman Chemical Company Retort containers comprising polyester compositions formed from 2,2,4,4- tetramethyl-1,3,-cyclobutanediol and 1,4-cyclohexanedimethanol
WO2007001563A1 (en) * 2005-06-17 2007-01-04 Eastman Chemical Company Bottles comprising polyester compositions which comprise cyclobutanediol
WO2007001542A1 (en) * 2005-06-17 2007-01-04 Eastman Chemical Company Tough amorphous polyester compositions
WO2007001531A1 (en) * 2005-06-17 2007-01-04 Eastman Chemical Company Blood therapy containers comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
WO2007001567A1 (en) * 2005-06-17 2007-01-04 Eastman Chemical Company Outdoor signs comprising polyester compositions formed from 2,2,4,4,-tetramethyl-1, 3-cyclobutanediol and 1,4- cyclohexanedimethanol
WO2007001552A1 (en) * 2005-06-17 2007-01-04 Eastman Chemical Company Polyester compositions containing cyclobutanediol having a certain combination of inherent viscosity and moderate glass transition temperature and articles made therefrom
WO2007001556A1 (en) * 2005-06-17 2007-01-04 Eastman Chemical Company Infant care sterilization containers comprising polyester compositions formed fr0m 2,2,4,4-tetramethyl-1, 3-cyclobutanediol and 1,4-cylohexanedimethanol
WO2007001550A1 (en) * 2005-06-17 2007-01-04 Eastman Chemical Company Skylights comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
WO2007001549A1 (en) * 2005-06-17 2007-01-04 Eastman Chemical Company Pacifiers comprising polyester compositions formed from 2,2,4,4,-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
WO2007001554A1 (en) * 2005-06-17 2007-01-04 Eastman Chemical Company Optical media comprising polyester compositions formed from 2,2,4,4,-tetramethyl-1,3-cyclobutanediol and 1,4,-cyclohexanedimethanol
WO2006137954A1 (en) * 2005-06-17 2006-12-28 Eastman Chemical Company Polyester compositions containing low amounts of cyclobutanediol and articles made therefrom
US9765181B2 (en) 2005-06-17 2017-09-19 Eastman Chemical Company Polyester compositions containing cyclobutanediol having a certain combination of inherent viscosity and high glass transition temperature and articles made therefrom
US9534079B2 (en) 2005-06-17 2017-01-03 Eastman Chemical Company Containers comprising polyester compositions which comprise cyclobutanediol
US9181388B2 (en) 2005-06-17 2015-11-10 Eastman Chemical Company Polyester compositions containing cyclobutanediol having a certain combination of inherent viscosity and high glass transition temperature and articles made therefrom
US9181387B2 (en) 2005-06-17 2015-11-10 Eastman Chemical Company Polyester compositions which comprise cyclobutanediol having certain cis/trans ratios
US9175134B2 (en) 2005-06-17 2015-11-03 Eastman Chemical Company Containers comprising polyester compositions which comprise cyclobutanediol
EP2138524A1 (en) * 2005-06-17 2009-12-30 Eastman Chemical Company Food storage containers comprising polyester compositions formed from 2,2,4,4-Tetramethyl-1, 3-cyclobutanediol and 1,4-cyclohexanedimethanol
CN101193932B (en) * 2005-06-17 2012-08-08 伊士曼化工公司 Polyester compositions which comprise cyclobutanediol and have a certain combination of inherent viscosity and moderate glass transition temperature and articles made therefrom
US9169348B2 (en) 2005-06-17 2015-10-27 Eastman Chemical Company Baby bottles comprising polyester compositions which comprise cyclobutanediol
EP2907640A1 (en) * 2005-06-17 2015-08-19 Eastman Chemical Company Polyester compositions which comprise cyclobutanediol having certain cis/trans ratios
US7740941B2 (en) 2005-06-17 2010-06-22 Eastman Chemical Company Thermoplastic articles comprising cyclobutanediol having a decorative material embedded therein
US8507638B2 (en) 2005-06-17 2013-08-13 Eastman Chemical Company Polyester compositions containing cyclobutanediol having a certain combination of inherent viscosity and moderate glass transition temperature and articles made therefrom
US7781562B2 (en) 2005-06-17 2010-08-24 Eastman Chemical Company Polyester compositions containing cyclobutanediol having a certain combination of inherent viscosity and moderate glass transition temperature and articles made therefrom
US7803439B2 (en) 2005-06-17 2010-09-28 Eastman Chemical Company Blood therapy containers comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
WO2007001532A1 (en) * 2005-06-17 2007-01-04 Eastman Chemical Company Outdoor shelters comprising polyester compositions formed from 2,2,4,4- tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US7803441B2 (en) 2005-06-17 2010-09-28 Eastman Chemical Company Intravenous components comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US7807775B2 (en) 2005-06-17 2010-10-05 Eastman Chemical Company Point of purchase displays comprising polyester compositions formed from 2,2,4,4-tetramethyl-1, 3,-cyclobutanediol and 1,4-cyclohexanedimethanol
US7807774B2 (en) 2005-06-17 2010-10-05 Eastman Chemical Company Vending machines comprising polyester compositions formed from 2,2,4,4,-tetramethyl-1,3,-cyclobutanediol and 1,4-cyclohexanedimethanol
US8415450B2 (en) 2005-06-17 2013-04-09 Eastman Chemical Company Polyester compositions containing cyclobutanediol having a certain combination of inherent viscosity and high glass transition temperature and articles made therefrom
US7812112B2 (en) 2005-06-17 2010-10-12 Eastman Chemical Company Outdoor signs comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US7812111B2 (en) 2005-06-17 2010-10-12 Eastman Chemical Company LCD films comprising polyester compositions formed from 2,2,4,4-tetramethy1-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US7834129B2 (en) 2005-06-17 2010-11-16 Eastman Chemical Company Restaurant smallware comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US7838620B2 (en) 2005-06-17 2010-11-23 Eastman Chemical Company Thermoformed sheet(s) comprising polyester compositions which comprise cyclobutanediol
US7842776B2 (en) 2005-06-17 2010-11-30 Eastman Chemical Company Appliance parts comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US7855267B2 (en) 2005-06-17 2010-12-21 Eastman Chemical Company Film(s) and/or sheet(s) comprising polyester compositions which comprise cyclobutanediol and have a certain combination of inherent viscosity and moderate glass transition temperature
US7868128B2 (en) 2005-06-17 2011-01-11 Eastman Chemical Company Skylights and windows comprising polyester compositions formed from 2,2,4,4,-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US7893187B2 (en) 2005-06-17 2011-02-22 Eastman Chemical Company Glass laminates comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US7893188B2 (en) 2005-06-17 2011-02-22 Eastman Chemical Company Baby bottles comprising polyester compositions which comprise cyclobutanediol
EP2159029A3 (en) * 2005-06-17 2011-03-02 Eastman Chemical Company Optical media comprising polyester compositions formed from 2,2,4,4,-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
EP2272888A3 (en) * 2005-06-17 2011-03-02 Eastman Chemical Company Bottles comprising polyester compositions which comprise cyclobutanediol
US7902320B2 (en) 2005-06-17 2011-03-08 Eastman Chemical Company Graphic art films comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US7906610B2 (en) 2005-06-17 2011-03-15 Eastman Chemical Company Food service products comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US7906211B2 (en) 2005-06-17 2011-03-15 Eastman Chemical Company Thermoplastic articles comprising cyclobutanediol having a decorative material embedded therein
US7906212B2 (en) 2005-06-17 2011-03-15 Eastman Chemical Company Thermoplastic articles comprising cyclobutanediol having a decorative material embedded therein
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