WO2007124803A1 - Préparation pigmentaire à base aqueuse - Google Patents

Préparation pigmentaire à base aqueuse Download PDF

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Publication number
WO2007124803A1
WO2007124803A1 PCT/EP2007/001711 EP2007001711W WO2007124803A1 WO 2007124803 A1 WO2007124803 A1 WO 2007124803A1 EP 2007001711 W EP2007001711 W EP 2007001711W WO 2007124803 A1 WO2007124803 A1 WO 2007124803A1
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WO
WIPO (PCT)
Prior art keywords
pigment
component
weight
pigment preparation
water
Prior art date
Application number
PCT/EP2007/001711
Other languages
German (de)
English (en)
Inventor
Björn FECHNER
Uwe Bechtold
Andrea BÖHMER
Original Assignee
Clariant International Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Clariant International Ltd filed Critical Clariant International Ltd
Priority to CN2007800084838A priority Critical patent/CN101400749B/zh
Priority to BRPI0710901A priority patent/BRPI0710901B1/pt
Priority to DE502007002424T priority patent/DE502007002424D1/de
Priority to JP2009506926A priority patent/JP5008719B2/ja
Priority to US12/298,352 priority patent/US7938900B2/en
Priority to EP07722964A priority patent/EP2013299B1/fr
Publication of WO2007124803A1 publication Critical patent/WO2007124803A1/fr

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/45—Anti-settling agents
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
    • C09D11/037—Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/16—Writing inks
    • C09D11/18—Writing inks specially adapted for ball-point writing instruments
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/30—Inkjet printing inks
    • C09D11/32—Inkjet printing inks characterised by colouring agents
    • C09D11/322—Pigment inks
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/30—Inkjet printing inks
    • C09D11/34—Hot-melt inks
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/30—Inkjet printing inks
    • C09D11/36—Inkjet printing inks based on non-aqueous solvents
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D17/00—Pigment pastes, e.g. for mixing in paints
    • C09D17/003—Pigment pastes, e.g. for mixing in paints containing an organic pigment
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D17/00—Pigment pastes, e.g. for mixing in paints
    • C09D17/004—Pigment pastes, e.g. for mixing in paints containing an inorganic pigment
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D17/00—Pigment pastes, e.g. for mixing in paints
    • C09D17/004—Pigment pastes, e.g. for mixing in paints containing an inorganic pigment
    • C09D17/005—Carbon black
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/41—Organic pigments; Organic dyes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/65—Additives macromolecular
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G9/00—Developers
    • G03G9/08—Developers with toner particles
    • G03G9/0802—Preparation methods
    • G03G9/0812—Pretreatment of components
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G9/00—Developers
    • G03G9/08—Developers with toner particles
    • G03G9/09—Colouring agents for toner particles
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G9/00—Developers
    • G03G9/08—Developers with toner particles
    • G03G9/09—Colouring agents for toner particles
    • G03G9/0926—Colouring agents for toner particles characterised by physical or chemical properties
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L29/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
    • C08L71/02—Polyalkylene oxides

Definitions

  • the present invention relates to water-based
  • Pigment preparations or dispersions process for their preparation, their use for coloring natural and synthetic materials, in particular aqueous paints, dispersion and enamel paints of all kinds.
  • pigment preparations for coloring aqueous paints, dispersion and enamel paints. Examples thereof are contained in EP-A-0 735 109, WO 03/006 556 or EP-A-1 049 745 (US Pat. No. 6,478,866 B1).
  • anionic, cationic, amphoteric or nonionic dispersants with surfactant character optionally also in macromolecular form, are used in order to physically stabilize the pigment particles finely in an aqueous medium.
  • conventional pigment preparations generally also contain various additives in addition to the surfactants or dispersants, such as wetting agents, thickeners, preservatives, viscosity stabilizers, fillers and retention aids.
  • VOC-free pigment preparations contain high molecular weight non-volatile oligomers or polymers such as, for example, polyether polyols (polyglycols).
  • hygroscopic non-volatile oligomers and polymers remain in the application medium for a long time.
  • the retention of these substances has some disadvantages. For example, if an aqueous dispersion paint with a Pigment preparation is colored, containing such hygroscopic non-volatile compounds, the paint gets a slightly hygroscopic, sticky character. An increased water absorption is the result.
  • the present invention was therefore based on the object, aqueous
  • the present invention relates to aqueous pigment preparations containing
  • A at least one organic and / or inorganic pigment
  • B dispersants and / or surfactants
  • (C) a trihydric or higher alkoxylated alcohol which is preferably branched, in particular star-branched,
  • Preferred pigment preparations contain from 5 to 80% by weight, for example from 10 to 70% by weight, of component (A).
  • Preferred pigment preparations contain from 0.1 to 30% by weight, for example from 2 to 15% by weight, of component (B). Preferred pigment preparations contain from 0.1 to 30% by weight, for example from 3 to 15% by weight, of component (C).
  • Preferred pigment preparations contain from 0.1 to 20% by weight, for example from 1 to 10% by weight, of component (D).
  • Particularly preferred pigment preparations comprise component
  • the minimum concentration is independently of each other suitably at least 0.01 wt .-%, preferably at least 0.1 wt .-%, based on the Total weight of the pigment preparation.
  • the component (A) of the pigment preparation according to the invention is a finely divided organic or inorganic pigment or a mixture of various organic and / or inorganic pigments.
  • the component (A) may also be a dye which is insoluble in certain solvents and has this pigment character.
  • the pigments can be used both in the form of dry powder and as water-moist press cake.
  • Suitable organic pigments are monoazo, disazo, laked azo, ⁇ -naphthol, naphthol AS, benzimidazolone, disazo condensation, azo metal complex pigments and polycyclic pigments such as phthalocyanine, quinacridone, perylene, perinone , Thioindigo, anthanthrone, anthraquinone, flavanthrone, Indanthrone, isoviolanthrone, pyranthrone, dioxazine, quinophthalone, isoindolinone, isoindoline and diketopyrrolopyrrole pigments or carbon blacks.
  • the organic pigments those which are as finely divided as possible for the preparation of the preparations are particularly suitable, with preferably 95% and particularly preferably 99% of the pigment particles having a particle size ⁇ 500 nm.
  • the morphology of the pigment particles may differ greatly, and accordingly, the viscosity behavior of the pigment preparations may also vary greatly depending on the particle shape.
  • the particles should preferably have a spherical to cube-shaped (with flattened corners) shape.
  • carbon black pigments e.g. Gas or furnace carbon black
  • Monoazo and disazo pigments in particular the Color Index Pigments Pigment Yellow 1, Pigment Yellow 3, Pigment Yellow 12, Pigment Yellow 13, Pigment Yellow 14, Pigment Yellow 16, Pigment Yellow 17, Pigment Yellow 73, Pigment Yellow 74, Pigment Yellow 81, Pigment Yellow® 83, Pigment Yellow® 87, Pigment Yellow® 97, Pigment Yellow® 111, Pigment Yellow® 126, Pigment Yellow® 127, Pigment Yellow® 128, Pigment Yellow® 155, Pigment Yellow® 174, Pigment Yellow® 176, Pigment Yellow® 191, Pigment Yellow® 213, Pigment Yellow Pigment Red 219, Pigment Red 38, Red Pigment Red 144, Red Red Pigment 214, Pigment Red 242, Pigment Red 262, Pigment Red 266, Pigment Red 269, Pigment Red 274, Pigment Orange
  • Pigment Orange 34 or Pigment Brown 41 Pigment Orange 34 or Pigment Brown 41; ß-naphthol and naphthol AS pigments, in particular the Color Index pigments Pigment Red 2, Pigment Red
  • Pigment Red 53 1, Pigment Red 112, Pigment Red 146, Pigment Red 147, Pigment Red 170, Pigment Red 184, Pigment Red 187, Pigment Red 188, Pigment Red 210, Pigment Red 247, Pigment Red 253, Pigment Red 256, Pigment Orange 5, Pigment Orange 38 or Pigment Brown 1; laked azo and metal complex pigments, in particular the Color Index pigments Pigment Red 48: 2, Pigment Red 48: 3, Pigment Red 48: 4, Pigment Red 57: 1, Pigment Red 257, Pigment Orange 68 or Pigment Orange 70; Benzimidazolinpigmente, in particular the Color Index Pigments Pigment Yellow 120, Pigment Yellow 151, Pigment Yellow 154, Pigment Yellow 175, Pigment Yellow 180, Pigment Yellow 181, Pigment Yellow 194, Pigment Red 175, Pigment Red 176, Pigment Red 185, Pigment Red 208, Pigment Violet 32, Pigment Orange 36, Pigment Orange 62, Pigment Orange 72 or Pigment Brown 25; Isoindolinone
  • Isoindoline pigments in particular the Color Index pigments Pigment Yellow 139 or Pigment Yellow 173; Phthalocyanine pigments, in particular the Color Index pigments Pigment Blue 15, Pigment Blue 15: 1, Pigment Blue 15: 2, Pigment Blue 15: 3, Pigment Blue 15: 4, Pigment Blue 15: 6, Pigment Blue 16, Pigment Green 7 or Pigment Green 36; Anthanthrone, anthraquinone, quinacridone, dioxazine, indanthrone, perylene, perinone and thioindigo pigments, in particular the Color Index Pigments Pigment Yellow 196, Pigment Red 122, Pigment Red 149, Pigment Red 168, Pigment Red 177, Pigment Red 179, Pigment Red 181, Pigment Red 207, Pigment Red 209, Pigment Red 263, Pigment Blue 60, Pigment Violet 19, Pigment Violet 23 or Pigment Orange 43; Triarylcarboniumpigmente, in particular the Color Index pigments Pigment Red 169, Pigment Blue 56 or Pigment Blue
  • the organic pigment is preferably combined with carbon black and / or titanium dioxide.
  • laked dyes such as Ca, Mg, Al lacquers of dyes containing sulfonic acid and / or carboxylic acid groups.
  • suitable inorganic pigments are titanium dioxides, zinc sulfides, zinc oxides, iron oxides, magnetites, manganese iron oxides, chromium oxides, ultramarine, nickel or chromium antimony titanium oxides, manganese titanium rutiles, cobalt oxides, mixed oxides of cobalt and aluminum, rutile mixed phase pigments, rare earth sulfides, spinels of cobalt with nickel and zinc , Spinels based on iron and chromium with copper zinc as well as manganese, bismuth vanadate and extender pigments.
  • the Color Index pigments Pigment Yellow 184 pigment Yellow Yellow, Pigment Yellow Brown, Pigment Yellow Brown, Pigment Red Brown, Pigment Blue, Pigment Blue, Pigment Green, Pigment Green, Pigment Black, Pigment Black, and Pigment White. Preference is also often given to using mixtures of inorganic pigments. Mixtures of organic and inorganic pigments are also commonly used.
  • pigment dispersions can also be prepared dispersions containing as solids, for example, natural finely divided ores, minerals, difficult or insoluble salts, wax or plastic particles, dyes, crop protection and pest control, UV absorbers, optical brighteners and polymerization stabilizers.
  • Component (B) of the pigment preparations of the invention are customary dispersants suitable for the preparation of aqueous pigment dispersions and surfactants or mixtures of such substances.
  • anionic, cationic, amphoteric or nonionic surfactant compounds are used therefor.
  • Dispersing agents which have one or more medium- or long-chain hydrocarbon chains and, in some cases, those which have aromatic ring groups have proved particularly suitable. Of the large number of compounds, only a selection should be mentioned at this point, but without restricting the applicability of the compounds according to the invention to these examples.
  • alkyl sulfates such as lauryl sulfate, stearyl sulfate or octadecyl sulfate, primary alkyl sulfonates such as dodecyl sulfonate, and secondary alkyl sulfonates, especially the C 3 -C 17 alkanesulfonate sodium salt, alkyl phosphates, alkylbenzenesulfonates such as dodecylbenzenesulfonic acid, as well as all salts of these compounds.
  • soya lecithin is suitable or condensation products of fatty acid and taurine or hydroxyethanesulfonic acid are used, as are alkoxylation products of alkylphenols,
  • Castor oil rosin esters, fatty alcohols, fatty amines, fatty acids and fatty acid amides, these alkoxylation products may likewise be endowed with ionic end groups, for example as sulfosuccinic acid half esters or as sulfonic acid, sulfuric and phosphoric acid esters, and their salts, the sulfonates, sulfates or phosphates.
  • ionic end groups for example as sulfosuccinic acid half esters or as sulfonic acid, sulfuric and phosphoric acid esters, and their salts, the sulfonates, sulfates or phosphates.
  • oxalkylated addition compounds which are obtained by reacting polyepoxides with amines or bisphenol A or bisphenol A derivatives with amines, likewise urea derivatives in a similar manner.
  • reaction products of substituted and unsubstituted relatively long- and shorter-chain alkylphenols and their polymeric derivatives such as formaldehyde condensation products, the novolaks.
  • Mention may also nonionic alkoxylated styrene-phenol condensates, which are obtained by addition of optionally substituted styrenes to optionally substituted phenols and reaction with ethylene oxide and / or propylene oxide, as well as their ionically modified derivatives, for example as sulfonic acid, sulfuric acid and phosphoric acid esters, and their salts, sulfonates, sulfates or phosphates.
  • component (B) Also suitable as surface-active compounds of component (B) are lignosulfonates and polycondensates of naphthalenesulfonic acid and formaldehyde or of alkylarylsulfonic acids, haloarylsulfonic acid, sulfonated phenols or sulfonated naphthols with formaldehyde.
  • polymeric dispersants for example aqueous, preferably from 5 to 40 percent by weight, of acrylate resin solutions of dissolved polyacrylates which have been brought into solution by means of bases by neutralization of the vinylic acid components are also suitable.
  • the polyacrylates used for this purpose are frequently copolymers which consist essentially of 30 to 80 mol% of monoalkylene aromatics and 20 to 70 mol% of acrylic and / or methacrylic acids and / or esters of acrylic and / or methacrylic acid.
  • the polyacrylates used generally have number-average molar masses M n of between 1000 and 100 000 g / mol, preferably 2000 to 50 000 g / mol.
  • Suitable components (C) are polyalkylene glycols of at least trivalent, for example tri-, tetra-, penta- or hexa-hydric, alcohols which are preferably branched and more preferably branched in a star shape. Star-branched compounds are understood to mean those having at least one quaternary aliphatic carbon atom. Examples of suitable alcohols are Glycerol, diglycerol, triglycerol, oligoglycerols, trimethylolethane, trimethylolpropane, 1, 2,3-hexanetriol, sorbitol, mannitol, pentaerythritol and dipentaerythritol.
  • the alcohols mentioned are alkoxylated per mole with up to 1000 moles of alkylene oxide, preferably 4 to 200 moles, of alkylene oxide, such as ethylene oxide, propylene oxide, n-butylene oxide, isobutylene oxide, styrene oxide or a mixture thereof.
  • component (C) are compounds of the formula (1),
  • R 1, R 2, R 3 are independently hydrogen, a branched or unbranched C- ⁇ -C2 0 alkyl or C3-C2o-cycloalkyl, branched or unbranched C2-C2o-alkenyl or C 3 -C 2 0 -
  • Cycloalkenyl radical a benzyl radical or a phenyl radical, preferably H,
  • m is, on average, a number from 0 to 100, preferably from 1 to 60, particularly preferably 4 to 25, n averaging a number from 0 to 100, preferably from 0 to 60, particularly preferably 0 to 10, p is, on average, a number from 0 to 100, preferably from 0 to 60, particularly preferably 0 to 10, wherein the sum m + n + p is at least 1, preferably at least 4 and particularly preferably 15 to 30.
  • the compound of the formula (1) is prepared by alkoxylation of pentaerythritol with at least four times the molar amount of alkoxide. Thereby arise naturally mixtures with different long alkoxide chains, so that for the numbers m, n and p only average values can be given.
  • the polyglycol alkyl ether corresponding to the component (D) is preferably a compound of the formula (2)
  • R 4 is a substituted or unsubstituted, unbranched or preferably branched C 2 -C 20 -alkyl or C 3 -C 20 -cycloalkyl radical or a substituted or unsubstituted, branched or unbranched
  • R 5 is H, XM or a substituted or unsubstituted, unbranched or, preferably, branched C 2 -C 2 o alkyl or C 3 -C 2 o-cycloalkyl radical or a substituted or unsubstituted, branched or unbranched C 2 -C2o-alkenyl or C 3 -C 2 o-Cycloalkenylrest, wherein the substituents 1, 2, 3 or 4 radicals from the group
  • Halogen aryl, aryl (C 1 -C 20) alkyl, C 5 -C 6 -cycloalkyl, hetaryl, hetaryl (C 1 -C 20) -alkyl or C 1 -C 20 -alkoxy, where X is SO 3 " , SO 2 " , CH 2 COO, PO 3 2 " or PO 3 M " , and
  • MH a monovalent metal cation, a divalent metal cation, NH4 + , a secondary, tertiary or quaternary ammonium ion, or a
  • hydrotropic retention agents are used. Suitable compounds are those which optionally also serve as solvents, or are of oligomeric or polymeric nature, for example formamide, urea, tetramethylurea, ⁇ -caprolactam, ethylene glycol, propylene glycol, Diethylene glycol, triethylene glycol, polyethylene glycol, ⁇ -methyl- ⁇ -hydroxy polyethylene glycol, dimethyl polyethylene glycol, dipropylene glycol, polypropylene glycol, Dimethylpolypropylenglykolether, copolymers of ethylene and propylene glycol, butyl glycol, methyl cellulose, glycerol, diglycerol, polyglycerol, N-methylpyrrolidone, 1, 3-diethyl -2-imidazolidinone, thiodiglycol, sodium benzenesulfonate, sodium xylenesulfonate, sodium toluenesulfonate, sodium cumene sulfonate, sodium
  • Polymers with vinyl acetate can be subjected to saponification to vinyl alcohol.
  • Component (F) corresponds to fats and oils of vegetable and animal origin, for example beef tallow, palm kernel fat, coconut oil, rapeseed oil, sunflower oil, linseed oil, palm oil, soybean oil, peanut oil and whale oil, cottonseed oil, corn oil, poppy oil, olive oil, castor oil, rapeseed oil, safflower oil, soybean oil , Thistle oil, sunflower oil, herring oil, sardine oil.
  • the saturated and unsaturated higher fatty acids are common additives, e.g.
  • component (G) for example, cationic, anionic, amphoteric or nonionic compounds are used which promote pigment wetting (wetting agent). Thickeners, preservatives, viscosity stabilizers, grinding aids and fillers are also used. Further customary additives may be antisettling agents, light stabilizers, antioxidants, degasifiers / defoamers, foam-reducing agents, anti-caking agents and additives which favorably influence viscosity and rheology. As a viscosity modifier, for example, polyvinyl alcohol and cellulose derivatives are suitable. Water-soluble natural or synthetic resins and polymers as film formers or binders for increasing adhesion and abrasion resistance as well.
  • organic or inorganic bases and acids are used as pH regulators.
  • Preferred organic bases are amines, such as ethanolamine, diethanolamine, triethanolamine, N, N-dimethylethanolamine, diisopropylamine, aminomethylpropanol or dimethylaminomethylpropanol.
  • Preferred inorganic bases are sodium, potassium, lithium hydroxide or ammonia.
  • Water used to prepare the pigment preparations, component (H), is preferably used in the form of desalted or distilled water. Also drinking water (tap water) and / or water of natural origin can be used.
  • the present invention also provides a process for the preparation of the pigment preparations according to the invention, which comprises reacting component (A) in the form of powder, granules or aqueous presscake in the presence of water (H) and components (B), (C). and (D) dispersed, then optionally water (H), and optionally admixing one or more of components (E), (F) and (G) and optionally adjusting the resulting aqueous pigment dispersion with water (H) to the desired concentration.
  • component (A) in the form of powder, granules or aqueous presscake in the presence of water (H) and components (B), (C). and (D) dispersed, then optionally water (H), and optionally admixing one or more of components (E), (F) and (G) and optionally adjusting the resulting aqueous pigment dispersion with water (H) to the desired concentration.
  • the components (B), (C) and (D) and optionally one or more of the components (E), (F) and (G) are first mixed and homogenized, then the component (A) is stirred into the initially introduced mixture, wherein the pigment is pasted and predispersed. Depending on the grain hardness of the pigments used, it is then optionally finely dispersed or finely divided with cooling with the aid of a grinding or dispersing unit.
  • agitators dissolvers (sawtooth), rotor-stator mills, ball mills, stirred ball mills such as sand and bead mills, high-speed mixers, kneaders, roller mills or high performance bead mills can be used.
  • the fine dispersion or grinding of the pigments is carried out to the desired particle size distribution and can be carried out at temperatures ranging from 0 to 100 0 C, preferably at a temperature between 10 and 7O 0 C, preferably at 20 to 60 0 C.
  • the pigment preparation can be further diluted with water (H), preferably deionized or distilled water.
  • the pigment preparations according to the invention are suitable for pigmenting and dyeing natural and synthetic materials of all kinds, in particular aqueous paints, dispersion and enamel paints (dispersion paints). Furthermore, the pigment preparations according to the invention are suitable for coloring macromolecular materials of all kinds, e.g. of natural and synthetic fiber materials, preferably cellulose fibers, also for paper pulp dyeing as well as for laminate dyeing. Other applications include the production of
  • Printing inks in this case for example textile printing, flexoprinting, decorative printing or gravure printing inks, wallpaper paints, water-dilutable paints, wood protection systems, viscose spin dyes, paints, sausage casings, seeds, fertilizers, glass, in particular glass bottles, and for mass coloration of roof tiles, for coloring for plasters, Concrete, wood stains, crayon mines,
  • High molecular weight organic materials are, for example, cellulose ethers and esters, such as ethylcellulose , Nitrocellulose, cellulose acetate or cellulose butyrate, natural resins or synthetic resins, such as polymerization or condensation resins, eg Aminoplasts, in particular urea- and melamine-formaldehyde resins, alkyd resins, acrylic resins, phenoplasts, polycarbonates, polyolefins, such as polystyrene, polyvinyl chloride, polyethylene, polypropylene, polyacrylonitrile, polyacrylic acid esters, polyamides, polyurethanes or polyesters, rubber, casein, latices, silicone, silicone resins, individually or in Mixture.
  • cellulose ethers and esters such as ethylcellulose , Nitrocellulose, cellulose acetate or cellulose butyrate, natural resins or synthetic resins, such as polymerization or condensation resins, eg Aminoplasts,
  • the pigment preparations according to the invention are suitable for the production of printing inks for use in all conventional ink-jet printers, in particular for those based on the bubble jet or piezo process. These printing inks can be used to print on paper, as well as natural or synthetic fiber materials, films and plastics.
  • the pigment preparations according to the invention can be used for printing various types of coated or uncoated substrate materials, for example for printing on board, cardboard, wood and wood-based materials, metallic materials, semiconductor materials, ceramic materials, glasses, glass and ceramic fibers, inorganic materials, concrete, leather, foods, cosmetics, skin and hair ,
  • the substrate material may be two-dimensional flat or spatially extended, ie be designed in three dimensions and both completely or only partially printed or coated.
  • the pigment preparations of the present invention are also useful as colorants in electrophotographic toners and developers, e.g. One- or two-component powder toners (also called one- or two-component developer), magnetic toner, liquid toner, latextoner, polymerization toner and special toner.
  • Typical toner binders here are polymerization, polyaddition and polycondensation resins, such as styrene, styrene acrylate, styrene butadiene, acrylate, polyester, phenolic epoxy resins, polysulfones,
  • Polyurethanes individually or in combination, as well as polyethylene and polypropylene, which may contain other ingredients such as charge control agents, waxes or flow aids, or be modified afterwards with these additives.
  • the pigment preparations according to the invention are suitable as colorants for powders and powder coatings, in particular for triboelectrically or electrokinetically sprayable powder coatings, which are used for surface coating of objects made of, for example, metal, wood, plastic, glass, ceramic, concrete, textile material, paper or rubber.
  • the pigment preparations of the present invention are colorants in inks, preferably ink-jet inks, such as aqueous or non-aqueous (solvent based), microemulsion inks, UV curable inks, and inks that function by the hot-melt process , suitable.
  • Ink-jet inks generally contain a total of 0.5 to 15 wt .-%, preferably 1, 5 to 8 wt .-%, (calculated dry) of the pigment preparation according to the invention.
  • Microemulsion inks are based on organic solvents, water and possibly an additional hydrotropic substance (interface mediator).
  • Microemulsion inks contain 0.5 to 15 wt .-%, preferably 1, 5 to 8 wt .-%, of the pigment preparation according to the invention, 5 to 99 wt .-% water and 0.5 to 94.5 wt .-% organic solvent and / or hydrotrope compound.
  • "Solvent-based" ink-jet inks preferably contain 0.5 to 15% by weight of the pigment preparation according to the invention, 85 to 99.5% by weight of organic solvent and / or hydrotropic compounds.
  • UV-curable inks contain substantially 0.5 to 30 wt .-% of the pigment preparation according to the invention, 0.5 to 95 wt .-% water, 0.5 to 95 wt .-% of an organic solvent or solvent mixture, 0.5 to 50 wt .-% of a radiation-curable binder and optionally 0 to 10 wt .-% of a photoinitiator.
  • Hot-melt inks are usually based on waxes, fatty acids, fatty alcohols or sulfonamides, which are solid at room temperature and liquid when heated, the preferred melting range between about 6O 0 C and 140 0 C is about.
  • hot-melt ink-jet inks consist essentially of 20 to 90% by weight of wax and 1 to 10% by weight of the pigment preparation of the invention. Furthermore, 0 to 20 wt .-% of an additional polymer (as a "dye remover"), 0 to 5 wt .-% dispersing aid, 0 to 20 wt .-% viscosity modifier, 0 to 20 wt .-% plasticizer, 0 to 10 wt % Of tackiness additive, 0 to 10% by weight of transparency stabilizer (prevents, for example, crystallization of the waxes) and 0 to 2% by weight of antioxidant.
  • an additional polymer as a "dye remover”
  • dispersing aid 0 to 20 wt .-% viscosity modifier
  • plasticizer 0 to 20 wt .-% plasticizer
  • 0 to 10 wt % Of tackiness additive 0 to 10% by weight of transparency stabilizer (prevents
  • pigment preparations according to the invention are also suitable as colorants for "color filter” for "Fiat panel displays”, both for additive and for the subtractive color generation, also for “photo-resists”, as well as colorants for electronic inks (" Electronic Inks “or” e-inks ”) or electronic paper (“ Electronic Paper “or” e-paper “).
  • the color strength and hue were determined according to DIN 55986.
  • the emulsion paint or the paint was mixed with the pigment dispersion applied to a paint card. Subsequently, rubbed with the finger on the lower part of the paint card. Incompatibility was when the rubbed area was then stained more vividly or lighter than the adjacent untreated area (the rub-out test is described in DE-A-2 638 946.)
  • the coloristic data and compatibilities with the The media to be dyed were determined on the basis of up to eight different commercial white dispersions and up to two different commercially available paints
  • the evaluation of the resistance to drying was carried out by filling the pigment preparation in a well of a spot plate
  • the viscosity was measured directly after production of the preparation and also after four weeks of storage at 5O 0 C and after storage in a climate chamber with ⁇ O 0 C.
  • a dissolver eg from VMA Getzmann GmbH, type AE3-M1
  • a dissolver eg from VMA Getzmann GmbH, type AE3-M1
  • Another suitable apparatus homogenized and predisp
  • the pigment preparations described in the following examples were prepared by the method described above, wherein the constituents in the stated amounts were used so that 100 parts of the respective pigment preparation are formed. In the following examples, parts are parts by weight.
  • Example 1 48 parts Component (A), Cl. Pigment Yellow 74
  • component (B) ionically modified tristyrylphenyloxyethylate
  • R 3 CH 3 ,
  • the pigment preparation has a high color strength and is particularly flocculation-stable. In six different commercially available white dispersions it can be incorporated very easily with easy dispersibility. In all cases, the rub-out test shows no color intensity differences in comparison between the rubbed area and the untreated area. Thus, the preparation is very well tolerated to the tested dispersions.
  • Pigment preparation has excellent rheological properties, proves to be well flowable and storage stable.
  • the viscosity after preparation is 0.58 Pa s.
  • the preparation has a good resistance to drying, since it begins to dry only after 24 hours.
  • the pigment preparation has a coloration corresponding to the standard dispersion and is particularly flocculation-stable. In six different white dispersions it can be incorporated very easily with easy dispersibility. In all cases, the rub-out test shows no color intensity differences in comparison between the rubbed area and the untreated area. Thus, the preparation is very well tolerated to the tested dispersions.
  • the pigment preparation has excellent theological properties for inorganic pigment pastes and has good flowability and storage stability. The viscosity after preparation is 2.3 Pa s. Furthermore, the preparation has a good resistance to drying, since it begins to dry only after 24 hours.
  • component (B) 3 parts of component (B), ionically modified tristyrylphenyloxyethylate 10 parts of component (E), triethylene glycol
  • Residual component (H) water.
  • Component (B) fatty acid oxyethylate, ionically modified
  • the pigment preparation has a coloration corresponding to the standard dispersion and is particularly flocculation-stable. In six different white dispersions it can be incorporated very easily with easy dispersibility. In all cases, the rub-out test shows no color intensity differences in comparison between the rubbed area and the untreated area. Thus, the preparation is very well tolerated to the tested dispersions.
  • the pigment preparation has excellent theological properties for inorganic pigment pastes and proves to be readily flowable and storage-stable.
  • the viscosity after preparation is 1.9 Pa s.
  • the preparation has a good resistance to drying, since it begins to dry only after 24 hours.
  • component (E) polyvinylpyrrolidone 1 part of component (G) Rheology additive
  • the pigment preparation has a color matching the standard. In six different white dispersions it can be incorporated very easily with easy dispersibility. In all cases, the rub-out test shows no color intensity differences in comparison between the rubbed area and the untreated area, so that no flocculation phenomena occur can be detected. Thus, the preparation is universally compatible with the tested dispersions.
  • the pigment preparation has excellent rheological properties, proves to be readily flowable and is storage-stable.
  • the viscosity after preparation is 2.0 Pa s. Furthermore, the preparation has a good resistance to drying since it begins to dry after 24 hours.
  • Component (B) fatty acid oxyethylate, ionically modified
  • the pigment preparation has a coloration corresponding to the standard dispersion and is particularly flocculation-stable. In six different white dispersions it can be incorporated very easily with easy dispersibility. In all cases, the rub-out test shows no color intensity differences in comparison between the rubbed area and the untreated area. Thus, the preparation is very well tolerated to the tested dispersions.
  • Pigment preparation has excellent theological properties for inorganic pigment pastes and proves to be readily flowable and storage-stable.
  • the viscosity after preparation is 1.9 Pa s.
  • the preparation has a good resistance to drying, since it begins to dry only after 24 hours.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Paints Or Removers (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Medicinal Preparation (AREA)

Abstract

L'invention concerne une préparation pigmentaire aqueuse contenant (A) au moins un pigment organique et/ou inorganique, (B) des agents dispersants et/ou tensio-actifs, (C) un alcool alcoxylé trivalent ou supérieur, (D) un alkyléther de polyglycol, (E) le cas échéant des oligomères et/ou polymères hydrotropes, (F) le cas échéant des graisses, des huiles ou des acides gras, (G) le cas échéant d'autres additifs usuels pour la préparation de dispersions aqueuses de pigments, et (H) de l'eau.
PCT/EP2007/001711 2006-04-27 2007-02-28 Préparation pigmentaire à base aqueuse WO2007124803A1 (fr)

Priority Applications (6)

Application Number Priority Date Filing Date Title
CN2007800084838A CN101400749B (zh) 2006-04-27 2007-02-28 水基颜料制剂
BRPI0710901A BRPI0710901B1 (pt) 2006-04-27 2007-02-28 preparação de pigmento baseada em água contendo um álcool etoxilado e um poliglicol alquil éter; seu preparo e uso
DE502007002424T DE502007002424D1 (de) 2006-04-27 2007-02-28 Wasserbasierende pigmentpräparation
JP2009506926A JP5008719B2 (ja) 2006-04-27 2007-02-28 水性顔料調合物
US12/298,352 US7938900B2 (en) 2006-04-27 2007-02-28 Water-based pigment preparation
EP07722964A EP2013299B1 (fr) 2006-04-27 2007-02-28 Préparation pigmentaire à base aqueuse

Applications Claiming Priority (2)

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DE102006019553A DE102006019553A1 (de) 2006-04-27 2006-04-27 Wasserbasierende Pigmentpräparation
DE102006019553.1 2006-04-27

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WO2007124803A1 true WO2007124803A1 (fr) 2007-11-08

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US (1) US7938900B2 (fr)
EP (1) EP2013299B1 (fr)
JP (1) JP5008719B2 (fr)
CN (1) CN101400749B (fr)
AR (1) AR060821A1 (fr)
BR (1) BRPI0710901B1 (fr)
DE (2) DE102006019553A1 (fr)
ES (1) ES2335547T3 (fr)
WO (1) WO2007124803A1 (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
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CN102159653A (zh) * 2008-10-08 2011-08-17 理想科学工业株式会社 水性喷墨墨
WO2012123082A1 (fr) * 2011-03-16 2012-09-20 Clariant International Ltd Polyalkylèneglycoléthers ramifiés en tant qu'agents mouillants et dispersants de désaération pour des peintures en dispersion aqueuse

Families Citing this family (38)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2630503A1 (fr) * 2007-05-03 2008-11-03 Rust-Oleum Corporation Teinture pour substrats en bois decoratifs d'interieur et d'exterieur
DE102007021867A1 (de) 2007-05-10 2008-11-20 Clariant International Limited Pigmentpräparationen auf Wasserbasis
DE102007021869A1 (de) * 2007-05-10 2008-11-13 Clariant International Limited Anionische wasserlösliche Additive
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ES2412356T3 (es) * 2008-03-28 2013-07-11 Clariant Finance (Bvi) Limited Influencia sobre la reflectancia en el infrarrojo cercano de materiales textiles teñidos
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DE102008038070A1 (de) 2008-08-16 2010-02-18 Clariant International Ltd. Trockene Pigmentpräparationen mit nichtionischen Additiven
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WO2011115614A1 (fr) * 2010-03-15 2011-09-22 Hewlett-Packard Development Company, L.P. Encre pour impression à jet d'encre contenant un pigment auto-dispersant
CN101885930B (zh) * 2010-05-06 2013-10-09 成都松齐明科技有限公司 多功能水溶性粉笔及其制造方法
JP5241810B2 (ja) * 2010-12-03 2013-07-17 富士フイルム株式会社 インク組成物、インクセットおよび画像形成方法
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WO2012170035A1 (fr) 2011-06-10 2012-12-13 Hewlett-Packard Development Company, L.P. Agents tensio-actifs comprenant une amine tertiaire terminale substituée par dialkyle ou cycloalkyle et encres les contenant
EP2825604B1 (fr) * 2012-03-14 2016-02-24 BASF Coatings GmbH Pâtes pigmentaires contenant des pigments métalliques, en milieu solvant, et leur utilisation pour la production de substances de revêtement à effet en milieu solvant
RU2537490C2 (ru) * 2013-03-18 2015-01-10 Общество с ограниченной ответственностью "Поликол Инвест" Диспергирующий агент для получения водных пигментных паст
US9163154B2 (en) * 2013-07-26 2015-10-20 Hewlett-Packard Development Company, L.P. Inkjet printing fluids
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CA3202399A1 (fr) * 2020-12-03 2022-06-09 Sun Chemical B.V. Composition de surface pour graine comprenant un pigment dpp et une graine traitee avec ladite composition
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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0801120A1 (fr) * 1996-04-09 1997-10-15 Sakata Inx Corporation Composition d'encre pour enregistrement par jet d'encre
US6143807A (en) * 1995-06-07 2000-11-07 Xerox Corporation Pigment ink jet ink compositions for high resolution printing
US6332943B1 (en) * 1997-06-30 2001-12-25 Basf Aktiengesellschaft Method of ink-jet printing with pigment preparations having a dispersant
US20050182154A1 (en) * 2004-01-21 2005-08-18 Berge Charles T. Inkjet inks containing crosslinked polyurethanes
US20060014856A1 (en) * 2004-07-14 2006-01-19 Mcgorrin Marlene A Pigmented ink-jet inks with improved print quality and reliability
EP1650272A2 (fr) * 2004-10-20 2006-04-26 Hewlett-Packard Development Company, L.P. Mélanges de pigment auto-dispersible pour l'impression par jet d'encre

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2638946C3 (de) 1976-08-28 1983-06-16 Hoechst Ag, 6230 Frankfurt Pigmentdispersionen für den Einsatz in hydrophilen und hydrophoben Medien
US5180425A (en) * 1991-11-05 1993-01-19 E. I. Du Pont De Nemours And Company Aqueous ink jet inks containing polyol/alkylene oxide condensates as cosolvents
US5340394A (en) 1992-07-23 1994-08-23 The Glidden Company Zero voc tinting concentrates for decorative paints
DE19511624A1 (de) * 1995-03-30 1996-10-02 Bayer Ag Wäßrige Pigmentpräparationen
DE19801759A1 (de) 1998-01-20 1999-07-22 Bayer Ag Wäßrige Pigmentpräparationen
JPH11343258A (ja) * 1998-05-29 1999-12-14 Asahi Denka Kogyo Kk ポリエーテルポリオールの製造方法
DE19931322A1 (de) * 1999-07-07 2001-01-11 Clariant Gmbh Verfahren zur Herstellung hochkonzentrierter Pigmentpreßkuchen
US6676736B2 (en) * 2000-05-23 2004-01-13 Kao Corporation Water-based ink composition
JP4374760B2 (ja) * 2000-10-19 2009-12-02 Ｄｉｃ株式会社 インク組成物
DE10133641A1 (de) 2001-07-11 2003-01-30 Clariant Gmbh Wasserbasierende Pigmentdispersionen, ihre Herstellung und Verwendung
DE10135140A1 (de) * 2001-07-19 2003-01-30 Clariant Gmbh Wasserbasierende Pigmentdispersionen auf Acrylatbasis
DE10207370A1 (de) * 2002-02-22 2003-09-04 Clariant Gmbh Feuchtgranulate organischer Pigmente, Verfahren zu ihrer Herstellung und ihre Verwendung
DE10350556A1 (de) * 2003-10-29 2005-06-02 Clariant Gmbh Wasserbasierende Pigmentpräparationen
DE102004051455A1 (de) * 2004-10-22 2006-04-27 Clariant Gmbh Wasserbasierende Pigmentpräparationen auf Oligoesterbasis, ihre Herstellung und Verwendung
DE102005019747B3 (de) * 2005-04-28 2006-06-01 Clariant Gmbh Wasserbasierende Pigmentpräparationen
US7442245B2 (en) * 2007-03-23 2008-10-28 Eastman Kodak Company Glycerol derivatives for inkjet inks

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6143807A (en) * 1995-06-07 2000-11-07 Xerox Corporation Pigment ink jet ink compositions for high resolution printing
EP0801120A1 (fr) * 1996-04-09 1997-10-15 Sakata Inx Corporation Composition d'encre pour enregistrement par jet d'encre
US6332943B1 (en) * 1997-06-30 2001-12-25 Basf Aktiengesellschaft Method of ink-jet printing with pigment preparations having a dispersant
US20050182154A1 (en) * 2004-01-21 2005-08-18 Berge Charles T. Inkjet inks containing crosslinked polyurethanes
US20060014856A1 (en) * 2004-07-14 2006-01-19 Mcgorrin Marlene A Pigmented ink-jet inks with improved print quality and reliability
EP1650272A2 (fr) * 2004-10-20 2006-04-26 Hewlett-Packard Development Company, L.P. Mélanges de pigment auto-dispersible pour l'impression par jet d'encre

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20100121482A (ko) * 2008-02-04 2010-11-17 비와이케이-케미 게엠베하 습윤 및 분산제
US8097076B2 (en) * 2008-02-04 2012-01-17 Byk-Chemie Gmbh Wetting and dispersing agent
KR101631330B1 (ko) 2008-02-04 2016-06-16 비와이케이-케미 게엠베하 습윤 및 분산제
CN102159653A (zh) * 2008-10-08 2011-08-17 理想科学工业株式会社 水性喷墨墨
WO2012123082A1 (fr) * 2011-03-16 2012-09-20 Clariant International Ltd Polyalkylèneglycoléthers ramifiés en tant qu'agents mouillants et dispersants de désaération pour des peintures en dispersion aqueuse

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EP2013299B1 (fr) 2009-12-23
DE102006019553A1 (de) 2007-10-31
JP2009534506A (ja) 2009-09-24
ES2335547T3 (es) 2010-03-29
US20090095202A1 (en) 2009-04-16
CN101400749A (zh) 2009-04-01
JP5008719B2 (ja) 2012-08-22
BRPI0710901B1 (pt) 2017-04-11
AR060821A1 (es) 2008-07-16
CN101400749B (zh) 2012-09-26
DE502007002424D1 (de) 2010-02-04
US7938900B2 (en) 2011-05-10
BRPI0710901A2 (pt) 2012-01-10
EP2013299A1 (fr) 2009-01-14

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