WO2007117168A1

WO2007117168A1 - Fire-extinguishing gas-dispersed composition, a fire-fighting method and a device for carrying out said method

Info

Publication number: WO2007117168A1
Application number: PCT/RU2006/000167
Authority: WO
Inventors: Vladimir Ivanovich Seliverstov; Vladimir Ilyich Stenkovoy; Pavel Gennadievich Veretinsky; Vladimir Petrovich Ivashkov; Nikolay Arsentievich Kuskov; Lev Vladislavovich Rzhavsky; Galina Vladimirovna Trubnikova
Original assignee: Vladimir Ivanovich Seliverstov; Vladimir Ilyich Stenkovoy; Pavel Gennadievich Veretinsky; Vladimir Petrovich Ivashkov; Nikolay Arsentievich Kuskov; Lev Vladislavovich Rzhavsky; Galina Vladimirovna Trubnikova
Priority date: 2006-04-07
Filing date: 2006-04-07
Publication date: 2007-10-18

Abstract

The invention relates to fire-fighting engineering. The inventive fire-fighting device comprises a container-shaped gas supply which contains a phlegmatising agent or the mixture thereof with a liquid inhibitor and is provided with a sealed lid, a siphon tube and with a closing-and-triggering device. The siphon tube is connected, via a junction line, to a mixing prechamber containing a fire extinguishing powder based on powdered fire retarder, highly dispersed additive, target fluidity additive and organosilicon water repellent. A variable cross-section aerator is placed inside the prechamber. Said prechamber is connected, via an exhaust valve actuatable at a pressure equal to or higher than 0.9 MPa, to a tubular evaporation chamber whose diameter/length ration ranged from 20 to 1000. Said tubular evaporation chamber is fastened, via an exhaust valve actuatable at a pressure equal to or higher than 0.5 MPa, to a nozzle unit which is provided with a supersonic confuser and whose nozzle length/diameter ratio ensures a pressure 0.11MPa and an outflow velocity ranging from 100 to 240 m/s at a temperature ranging from -50°C to +50°C. The mass relation between gas-liquid and solid-state components ranges within the limits of 7.5-80:19.9- 92.5. Said invention makes it possible to obtain the maximum powder release, to reduce a fire-fighting time and to increase the three-dimensional firefighting.

Description

Fire extinguishing gas dispersed composition, fire extinguishing method and device for its implementation

Technical field

The invention relates to the field of fire fighting equipment, namely:

-to extinguishing gas dispersed compositions (GDS); - fire extinguishing methods; -modular device for its implementation.

Using the proposed extinguishing gas dispersed composition, a method of extinguishing a fire using modular plants and systems based on them, this invention can be successfully used to combat fires, including for their prevention, in almost all industries: chemical, petrochemical, oil refining , woodworking, etc.

State of the art

A known fire extinguishing composition in which the mixing of homogeneous and heterogeneous inhibitors is carried out mechanically using an ejector device [USSR Author Certificate Zh715092 of 08/11/1978].

The disadvantage is the inability to use the resulting fire extinguishing composition for volumetric fire extinguishing and its short duration of storage. Combination homogeneous (chladone) and heterogeneous (powder) inhibitors using an ejector is recommended only for manual fire extinguishing, and it cannot be used at negative temperatures up to -50 ⁰ C. In the invention [RF Patent JY ° 2225735 of 04/10/2001] provides for the creation of one solution freon (for example, a compound such as perfluorocyclobutane C ₄ F ₈ , perfluorobutane C ₄ Fi ₀₁ heptafluoropropane C ₃ F ₇ H, dibromotetrafluoroethane C ₂ F ₄ Br ₂ ) and potassium iodide. To do this, it is proposed to first obtain a saturated solution of potassium iodide in ethanol, after which this solution is mixed with liquid freon in a weight ratio of May 70-80. % Freon and May 20-30. % saturated solution of potassium iodide in ethanol. The content of potassium iodide in ethanol in this case is up to 5 wt.%. The disadvantages of the composition is the high cost of protection lm ³ due to the expensive freons included in the formulation and the impossibility of its use at t ° to - 50 ⁰ C.

Known combined fire extinguishing composition [RF Patent N ° 2156630 from 02/08/1999], which contains a diluent-fluorine-containing saturated hydrocarbon and a combustion-inhibiting substance-iodine-containing saturated hydrocarbon in the ratio of components, mass. %: fluorine-containing hydrocarbons 70-95, iodine-containing hydrocarbons 5-30. The application [RF Application M> 2000114329 dated 06/05/2000] proposes a volume quenching composition containing air-diluting fluorocarbon and inhibiting the combustion process components, moreover, an iodine-containing hydrocarbon with one or two iodine atoms in which all other hydrogen atoms are used as a combustion inhibitor are replaced by fluorine atoms. The ratio of the components in the proposed composition next May. %: diluent - 40-98%, inhibitor-2-60%. Known extinguishing powder composition [RF Patent

N22143297 dated 12/16/1997], including, mass%: highly dispersed additive, mainly aerosil, 0.8-3.5; target additive for fluidity, mainly nepheline concentrate, 8.0-35.0; hydrophobizing organosilicon liquid 0.008-0.28; main component

- the rest. As a main component, the composition contains at least one compound from the series: potassium chloride, sodium chloride, ammophos, sylvinite, sulfate, alkaline or alkaline earth metal phosphate, sodium bicarbonate, monoammonium phosphate, diammonium phosphate, ammonium sulfate.

There is also known a method of extinguishing a fire in a tank and a device for its implementation [RF Patent N ° 2258549 of 03.02.2004], according to which a fire extinguishing mixture is supplied from a device floating in the center of the tank, and a gas-dispersed fire extinguishing mixture is formed in the above device by supplying under pressure at least 1 MPa a gaseous and / or liquefied phlegmatizer and / or gaseous and / or liquefied homogeneous combustion inhibitor into a container with a powder or liquid heterogeneous combustion inhibitor having a bursting membrane or valve, providing, when the pressure exceeds 1 MPa, a gas-dispersed discharge mixtures through the outlet pipe and the circular nozzle atomizer in compact jets with a divergence angle of 5-15 ° in the plane of a parallel liquid with a flow rate of at least 10 kg / s with an outflow rate at a nozzle exit not less than 70 m / s, while the jets are fed with a sweep of 360 ° so that they do not intersect in the radial direction inside the tank, creating a vacuum in the discontinuity of the extinguishing medium that provides suction into the rarefaction zone of the combustion products from the upper zone fire, thereby forming a continuous circular fire extinguishing zone with a ratio of fire extinguishing areas formed by gas-dispersed jets and products of combustion of a burning liquid in the range from 1: 1 to 10: 1, and the mass ratio between gas and the phases of the fire extinguishing mixture are in the range from 0.2: 1 dol5: l. As gaseous and / or liquefied phlegmatizer, carbon dioxide, and / or nitrogen, and / or argon, or a mixture thereof is used. As a gaseous and / or liquefied homogeneous combustion inhibitor, halogenated hydrocarbons are used, and as heterogeneous combustion inhibitor use a fire extinguishing powder composition based on carbonates and / or chlorides and / or phosphates of an alkali and / or alkaline earth metal and / or ammonium, or a fog-forming solution of phosphoric acid.

There is also known a method [US Patent N.> 6988558 B2 dated 01.24.2006] to extinguish a fire using gas, according to which a fire is extinguished by the eruption of at least one gaseous extinguishing agent selected from the group formed by argon, nitrogen and dioxide carbon, with foam, powder or water being used as their carriers.

The disadvantages of these extinguishing compositions is the high cost of protection lm ³ due to the costly freons included in the formulation and the impossibility of their use at t ° to -

50 ⁰ C.

The closest in components and purpose is a fire extinguishing composition [RF Patent JVs2240848 from 08/07/2003], which is selected as a prototype. This fire extinguishing composition includes a finely dispersed additive, hydrophobizing organosilicon liquid, the main powder component, liquefied and / or gaseous phlegmatizer and / or liquefied and / or gaseous combustion inhibitor in the form of an azeotropic mixture of trifluoromethane and carbon dioxide in a ratio by weight (30-43): (33-43): (24-37), or a mixture carbon dioxide with nitrogen and argon in a ratio of 8:52:40 or a mixture of argon and nitrogen in a ratio of 50:50, or liquefied and / or gaseous halogenated hydrocarbon, and / or carbon dioxide, or nitrogen, and it contains ion-grating as a target additive for flowability mineral with complex anionic groups gross formula:

[Al ₂ 0 ₃ ] (o.5-7.5) • [SiO ₂ ] ₍ 40-50) • [Na ₂ O * K ₂ O] ₍₄ .5 -p.4) • [P2O5V5 -i.5) • [CaO] ₍ 5-9 .i) '[Fe ₂ O ₃ ] ₍ i _2-20 ) •' [FeO] (SI ₂ ) • [TiO ₂ ] ₍₇ .c) and / or phosphate rock with true densities of at least 2.8 g / cm ³ , as a hydrophobizing modifier fluid, it contains methyl hydride siloxane with an active hydrogen content of 1.6-1.7% by weight. or a mixture of methyl hydride siloxane as the basis of a hydrophobizing agent and an aminopropyltrimethoxysilane curing catalyst in the ratio (5-70): 1, while the modifier is an organosilicon hydrophobizing liquid taken in the form of a 10-70% solution in an organochlorine solvent in the following ratio of components, mass. %: highly dispersed additive 0.5-2.8 target additive for fluidity 4.6-25.0 hydrophobic organosilicon liquid 0.1-0.5 main component 15-70 phlegmatizer and / or combustion inhibitor else. The main disadvantage of this composition is the small temperature range of application (-20 ° C) ÷ (+ 50 ° C).

A known method of extinguishing a fire in tanks with flammable (LVH) and combustible liquids (GF) according to the patent [RF Patent No2241508 of 12/17/2002], which is the closest analogue of the method.

Extinguishing in this method is carried out by supplying a fire extinguishing gas dispersed mixture (GDS) into the combustion zone from the bottom up, and a fire extinguishing GDS is formed by applying at least 2 MPa of a gaseous and / or liquefied gas phlegmatizer and / or a gaseous and / or liquefied homogeneous combustion inhibitor and / or or a hydrocarbon-like surfactant in a container with a powdered or liquid heterogeneous combustion inhibitor, having a valve that allows the discharge of gas discharge when the pressure in the tank reaches at least 0.42 kPa a re-perforated atomizer or through several atomizers providing a 180 ° dispersion of GDS with a flow rate of at least 1 kg / s in a direction parallel to the surface of the burning liquid and into the upper hemisphere above the surface of the above liquid with an intensity that ensures the creation of a concentration of GDS in the center of the flame volume above the mirror burning surface of at least 0.09 kg / m ³ , moreover, the mass ratio between the gas and dispersed phases of the extinguishing mixture is in the range from 0.2: 1 to 15: 1. In an inert gas (for example, CO ₂ , N ₂ , Ar, or a mixture thereof) and / or an ozone-depleting halogen hydrocarbon, for example, 125XP freon, is used as the gas component, and a fire extinguishing powder composition based on carbonates and / or chlorides is used as a heterogeneous combustion inhibitor and / or phosphates of an alkali and / or alkaline earth metal and / or ammonium or a fog-forming phosphoric acid solution.

GDS is supplied simultaneously from generators floating on the surface of the liquid located in the tank and located both around the perimeter of the tank and in its center, with the resulting horizontal spray vector of the peripheral generators directed toward the center and the central ones towards the periphery, the resulting spray vector peripheral generators in the upper hemisphere is directed to the center of the flame volume, centrally located generators - from the center of the mirror of the burning surface to the periphery at an angle of 90 ° to the above vector.

Known powder fire extinguisher [RF Patent JN ° 2193427 from 11/28/2001], representing a module of gas dispersed extinguishing, which is selected as an analog device. The disadvantage of this device is the impossibility of its operation at ambient temperature (-20 ° C) ÷ (-50 ° C), long fire extinguishing time of 233V 8-Jus at t ^o = (- 2O ° C) ÷ (+ 5O ° C) . Disclosure of invention

The objective of the invention is to provide a composition that expands the temperature range of the composition from (-50 ⁰ C) to (+ 50 ⁰ C) without reducing the volume of fire extinguishing ability (0.1-0.2) kg / m ³ , as well as reducing the time to extinguish a fire without increasing fire extinguishing effectiveness.

The problem is achieved in that in a fire extinguishing gas-dispersed composition, including a highly dispersed additive, the target additive for fluidity, an organosilicon water-repellent agent, a basic powder inhibitor of combustion, a gaseous and / or liquefied phlegmatizer, or a mixture of a phlegmatizer and inhibitor, use a gaseous and / or liquefied phlegmatizer nitrogen or a mixture of carbon dioxide and nitrogen or air in a ratio of from 95: 5 to 75:25 or a mixture of carbon dioxide with methyl, ethyl or propyl carbinol in a ratio of 99: 1 to 90: 10 or a mixture of carbon dioxide, nitrogen and one of the above alkylcarbinols in the ratio of carbon dioxide: nitrogen: alkylcarbinol as 80-100: 5-20: 0.5-5, and 5% iodine solution is used as a liquid combustion inhibitor or 5-20% solution of a mixture of iodine with alkali metal or ammonium iodide in one of the above alkylcarbinols, moreover, the ratio in the mixture is: phlegmatizer: liquid inhibitor is in the range from 100: 1 to 100: 30 with the following ratios of components, wt.%: highly dispersed additive - 0.2-2.8 target additive for fluidity - 4.6-25.0 organosilicon hydrophobisate - 0.1-0.7 main powder component - 15-85 phlegmatizer or mixture phlegmatizer and liquid inhibitor - the rest.

In addition, according to the claimed method, a fire extinguishing of flammable and combustible materials is carried out by supplying a fire extinguishing gas dispersed composition from a fire extinguishing modular device or a unit of devices installed outside or inside the fire zone, so that the fire extinguishing gas dispersed composition is formed in three stages: the first from the source tank gas with a siphon tube with a means of its supply and a locking-starting device, filled under pressure 4 MPa with a gas and / or liquefied phlegmatizer and / or a mixture of liquid the inhibitor and phlegmatizer under a pressure of at least 2.4 MPa, at the signal of the fire detector, at least 0.2 parts of the gas or gas-liquid mixture is fed into the mixing chamber, containing at the atmospheric pressure the main powdery combustion inhibitor, a highly dispersed additive, the target additive for fluidity, and an organosilicon hydrophobizing agent, moreover, as gaseous and / or liquefied phlegmatizer use nitrogen or a mixture of carbon dioxide and nitrogen or air in a ratio of 95: 5 to 75:25 or a mixture of carbon dioxide with methyl, ethyl, or propyl carbinol in a ratio of 99: 1 to 90: 10 or a mixture of carbon dioxide, nitrogen or air and alkylcarbinol in a ratio of 80-100: 5-20: 0.5-5, and as a liquid inhibitor use a 5% solution of iodine and a 5-20% solution of a mixture of iodine with alkali metal or ammonium iodide in one of these alkylcarbinols in a ratio of phlegmatizer: liquid inhibitor is in the range from 100: 1 to 100: 30, and the above mixture t in the pre-chamber of mixing from the gas source through a siphon tube and a connecting tube passing inside the sealed cover of the pre-chamber to a perforated tube aerator with a variable cross-section, while the total area of perforations does not exceed the end area of the siphon tube and, thus, form the primary solid in the pre-chamber - liquid-gas-phase mixture, the second - the primary solid-liquid-gas-phase mixture formed in the prechamber when the pressure reaches at least 0.9 MPa through the outlet valve is passed into a tubular evaporative amer, where at a pressure of at least

0.5MPa form a gas-dispersed stream; the third formed gas-dispersed stream from the tubular evaporation chamber through the exhaust valve during areal and / or space-local quenching is directed to the nozzle block with nozzles with a supersonic confuser with a length ratio nozzle to its diameter, providing O. PMP pressure and flow rate into the fire zone of a fire extinguishing gas-dispersed composition from 100 to 240 m / s at ambient temperature from (-50 ⁰ C) to (+ 50 ⁰ C), and during volume quenching - through one or more volumetric spray guns providing a flow rate of extinguishing gas dispersed composition of at least 70 m / s.

The invention is as follows. The mixing of the powder components and the preparation of the product is carried out on equipment and according to the technology adopted in the production of fire extinguishing powders.

The obtained product is equipped with a PSM type powder charging station in the mixing chamber of the proposed device, and the gaseous and liquefied part of the phlegmatizer and liquid inhibitor of the proposed composition is equipped with a 3CA charging station in the gas source container of the proposed modular device. When the proposed modular device of the fire extinguisher is mixed, both components of the fire extinguishing composition are mixed and the composition according to the invention is fed into the fire zone.

Tables 1-9 provide examples of the performance of the inventive fire extinguishing gas dispersed composition, the composition of the prototype and the values of some characteristics of the compositions (temperature range, application conditions, and fire extinguishing ability) for fire classes A, B, and C. As can be seen from the table. JSfel-9 data, the proposed composition compares favorably with the analogue composition in the range of application at (-30 ⁰ C).

The extinguishing time of a fire of a model center of class 233B according to Hi Ib 67-98 (S = 7.32 m ² ) using the proposed method was 2-3 s, for comparison, the extinguishing of the same center from a module by an analogous method was 8-10 s at t ° air

(-20 ° C) ÷ (+ 50 ° C).

In the proposed fire extinguisher, a gas source containing a mixture of carbon dioxide and ethanol and / or an aqueous-alcoholic solution of potassium and / or sodium compounds is connected to the powder fire extinguisher cavity through a siphon tube with a flow area of 0.05-0.2 of the flow area the outlet nozzle and fixed in the baffle cover, the lower end of the siphon tube located at a distance from the bottom of the housing of not more than 1/10 and not less than 1/50 of the height of the powder extinguishing powder, and the outlet nozzles are made in e perforated tube with a cap, sealingly closing the perforation, wherein the perforation area ratio and the flow section of the outlet nozzle is 0.3-0.8.

This design provides a 100% powder discharge and increases the volume quenching efficiency due to the increased consumption of the gas-powder mixture at the initial moment after the cap is broken. At the same time in the front sprayed gas-powder mixture forms a “jump” of compaction, which, spreading from top to bottom with a hemisphere, produces a flame failure, and subsequent portions of the extinguishing mixture do not allow the fire to reignite. The absolute powder utilization rate is explained by the fact that in this design a mixture of liquefied gas and ethanol and / or an aqueous-alcoholic solution of potassium and / or sodium compounds is fed through the siphon tube from top to bottom, while the mixture jet hits the bottom of the powder body and spreads over the entire area bottom and, evaporating, fluidizes the powder, throwing it through the hole in the jack cap in the exhaust nozzles.

Elimination of the disadvantages of the analog device in the proposed modular device is achieved provided that the modular device for extinguishing flammable liquids and combustible materials contains a gas source container with a siphon tube and a locking-starting device (ZPU) connected by a connecting pipe to a mixing chamber containing fire extinguishing powder based on a dispersed chemical inhibitor, and in a sealed cover of the mixing chamber before mixing, the connecting tube passes into a perforated tubular with a variable the cross section of the aerator located inside the chamber, while the cross-sectional area of the aerator perforations does not exceed the end area of the siphon tube, and the ratio of the end areas of the aerator relates as 2-5: 1-1.5, the lower end of the siphon tube is located at a distance within 1 / 80-1 / 100 of the height of the tube from the bottom of the gas source, the lower end of the aerator is located at a distance of 1/30 to 1/40 of the height of the aerator from the bottom of the mixing chamber, connected through an exhaust valve operating at a pressure of at least 0.9 MPa, with a tubular evaporation chamber having a diameter: length ratio of 20 ÷ 1000, and a tubular evaporation chamber through an exhaust valve operating at a pressure of at least 0.5 MPa, fastened with a nozzle block with a supersonic confuser with ratio of length to diameter of the nozzle, providing O.PMPa pressure and exhaust velocity of from 100 to 240 m / s at a temperature of (-50 ^ϋ C) - (+ 50 ° C), wherein the total mass ratio between the gas and solid components of the installation equipment It ranges from 7.5-80.1: 19.9-92.5.

In the proposed modular device, the locking and starting device is made with automatic, autonomous and manual start in the usual or explosion-proof version.

Brief Description of the Drawings

In the drawings of FIG. l, FIG. 2 and FIG. 3 show embodiments of modular devices where capacity 1 is indicated — gas source, siphon tube 2, ZPU 3, connecting tube

4, mixing chamber 5, aerator 6, sealed cover 7, exhaust valve 8, tubular evaporation chamber 9, exhaust valve 10, atomizer 11 - block with supersonic nozzles, mounting plate 12, powder 13.

BEST MODE FOR CARRYING OUT THE INVENTION A modular device for extinguishing flammable and combustible materials works as follows.

In the event of a fire, the signal from the fire alarm sensor enters the fire control system’s starting and starting device, from where it is supplied with an electric current with a certain current strength to the igniter located in the locking and starting device 3, which is installed on the source tank 1 with gaseous and / or a liquefied phlegmatizer or a mixture of a phlegmatizer and a liquid inhibitor, after the pyro cartridge is triggered, the membrane is opened at the neck of the source container and then gaseous and / or liquefied phlegm an atomizer or a mixture of a phlegmatizer and a liquid inhibitor through a siphon tube 2 and through a connecting tube 4, which in the distribution cover 7 passes into the tubular aerator 6, enters the mixing chamber 5 through the aerator 5. The mixing chamber contains a fire extinguishing powder based on a dispersed combustion inhibitor with a finely dispersed additive, target additive for fluidity and water repellent. In the mixing chamber, a fire extinguishing mixture forms, consisting of a fire extinguishing powder and a phlegmatizer or a mixture of a phlegmatizer and a liquid inhibitor. When the pressure in the prechamber of mixing 0.9 MPa or more, the exhaust valve 8 is activated, through which the extinguishing mixture enters the tubular evaporation 9, when the pressure in which 0.5 MPa or more is reached, the exhaust valve 10 is activated, through which the extinguishing mixture enters the nozzle block 11 and from it to the source of ignition.

Industrial applicability

As can be seen from the above data, the invention in comparison with the prototype compares favorably:

- expanding the operating range of the composition by -30 ⁰ C;

-reducing the fire fighting time in 2.6-3. Zraza due to an increase in the rate of expiration of the gas-dispersed flow without reducing the volume of fire extinguishing ability

(0.1-0.2) kg / m ³ when the cost of the composition and installation is reduced due to the exclusion of expensive freon from the formulation.

Table N≤l

Table Ns2

Yu

Table N ° 3

about

Table Na4

Bj

Table Jf ° 5

Table .Ns 6.

-y-

Table N ° 7

Table N ° 8

Table N ° 9

[O o

Claims

Claim

1. Fire extinguishing gas dispersion composition, including a fine dispersion additive, a target additive for fluidity, an organosilicon water-repellent agent, a basic powder inhibitor of combustion, a gaseous and / or liquefied phlegmatizer, or a mixture of a phlegmatizer and a liquid inhibitor, characterized in that a phlegmatized and / or liquefied nitrogen is used or a mixture of carbon dioxide and nitrogen or air in a ratio of from 95: 5 to 75: 25 or a mixture of carbon dioxide with methyl, ethyl or propylcarbinol in a ratio of from 99: 1 to 90: 10 silt and a mixture of carbon dioxide, nitrogen and one of the above alkylcarbinols in the ratio: carbon dioxide: nitrogen: alkylcarbinol as (80-100) :( 5-20) :( 0.5-5), and 5% iodine solution is used as a liquid combustion inhibitor or a 5-20% solution of a mixture of iodine with alkali metal or ammonium iodide in one of the above alkyl carbinols, the ratio in the mixture of the phlegmatizer liquid inhibitor being in the range from 100: 1 to 100: 30 with the following ratios of components, masses, highly dispersed additive - 0.2 -2.8; target additive for fluidity - 4.6-25; organosilicon water-repellent-0.1-0.7; the main powdery combustion inhibitor is 15-85; a phlegmatizer or a mixture of a phlegmatizer and a liquid inhibitor - the rest.

2. A method of extinguishing a fire of flammable and combustible materials by supplying a fire extinguishing gas dispersed composition from a fire extinguishing modular device or a unit of devices installed outside or inside the fire zone, characterized in that the fire extinguishing gas dispersed composition is formed in three stages: the first is from a gas source container with a siphon a tube and a locking and starting device filled with a pressure of at least 4 MPa with a gas and / or liquefied phlegmatizer and / or a mixture of a liquid inhibitor and a phlegmatizer with a pressure of at least 2.4 MPa at the signal of the fire detector, at least 0.2 parts of a gas or gas-liquid mixture is fed into a mixing chamber containing at atmospheric pressure a basic powdery combustion inhibitor, a finely dispersed additive, a targeted fluidity additive and an organosilicon water-repellent agent, using nitrogen or a mixture as a gaseous and / or liquefied phlegmatizer carbon dioxide and nitrogen or air in a ratio of from 95: 5 to 75:25 or a mixture of carbon dioxide with methyl, ethyl, or propylcarbinol in a ratio of from 99: 1 to

90: 10 or a mixture of carbon dioxide, nitrogen or air and alkylcarbinol in a ratio of 80-100: 5-20: 0.5-5, and as a liquid inhibitor use a 5% solution of iodine and a 5-20% solution of a mixture of iodine with alkali metal iodide or ammonium in one of the named alkylcarbinols in the ratio: phlegmatizer: liquid inhibitor is in the range from 100: 1 to 100: 30, and the above mixture is fed to the mixing chamber from the gas source via a siphon tube and a connecting pipe passing inside the sealed chamber cover into a perforated tube aerator with a variable cross-section, while the total perforation area does not exceed the end area of the siphon tubes and, thus, in the prechamber form the primary solid-liquid-gas phase mixture; the second - the primary solid-liquid-gas-phase mixture formed in the prechamber when the pressure reaches at least 0.9 MPa through the exhaust valve is passed into the tubular evaporation chamber, where at a pressure of at least 0.5 MPa a gas-dispersed stream is formed; the third - the formed gas-dispersed flow from the tubular evaporation chamber through the exhaust valve with areal and / or volume-local quenching is sent to the nozzle block with nozzles with a supersonic confuser with a ratio of the nozzle length to its diameter, providing pressure O. PMP and flow rate to the fire zone extinguishing gas-dispersed composition from 100 to 240 m / s at an ambient temperature of (-50 ⁰ C) to (50 ⁰ C), but putting out a volume via one or more nozzles providing exhaust velocity of the extinguishing of gas-dispersed composition of not less than 70m / s.

3. A modular device for extinguishing flammable liquids and combustible materials, containing a gas source container with a phlegmatizer or 00167

32 with a mixture of a phlegmatizer and a liquid inhibitor with a sealed lid with a siphon tube, with its feeding means and a locking and starting device, connected by a connecting tube, equivalent in diameter to the siphon tube, with a mixing chamber containing a fire extinguishing powder based on a dispersed combustion inhibitor with a finely dispersed additive, target additive for fluidity and water repellent, and in a sealed cover of the mixing chamber before mixing, the connecting tube passes into a perforated tubular with a variable cross-section an aerator located inside the chamber, while the cross-sectional area of the aerator perforations does not exceed the end area of the connecting tube, and the ratio of the end areas of the aerator is 1.6-5: 1-1.5, the lower end of the siphon tube is located at a distance of 1 / 80-1 / 100 of the height of the tube from the bottom of the gas source, the lower end of the aerator is located at a distance of 1/30 to 1/40 of the height of the aerator from the bottom of the mixing chamber, connected through an exhaust valve operating at a pressure of at least 0.9 MPa, with a tubular evaporation chamber having the ratio diameter: length within 20 ÷ 1000, and a tubular evaporation chamber through an exhaust valve operating at a pressure of at least 0.5 MPa, is fastened to a nozzle block with a supersonic confuser with a ratio of the length of the nozzle to its diameter, providing pressure O. NMP and the flow rate from 100 up to 240 m / s at a temperature of (-50 ° C) - (+ 50 ° C), the mass ratio between the gas-liquid and solid components of the equipment of the installation is in the range from 7.5-80.1: 19.9-92.5.

4. The device according to claim 3, characterized in that the starting and closing device is made with automatic, autonomous and manual start in the usual or explosion-proof version.