WO2007102701A1 - Photolysis and photocatalaysis air pollution treatment system using electrodeless uv lamp - Google Patents
Photolysis and photocatalaysis air pollution treatment system using electrodeless uv lamp Download PDFInfo
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- WO2007102701A1 WO2007102701A1 PCT/KR2007/001124 KR2007001124W WO2007102701A1 WO 2007102701 A1 WO2007102701 A1 WO 2007102701A1 KR 2007001124 W KR2007001124 W KR 2007001124W WO 2007102701 A1 WO2007102701 A1 WO 2007102701A1
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- 238000006303 photolysis reaction Methods 0.000 title claims abstract description 19
- 230000015843 photosynthesis, light reaction Effects 0.000 title claims abstract description 17
- 238000003915 air pollution Methods 0.000 title claims description 25
- 239000011941 photocatalyst Substances 0.000 claims abstract description 56
- 239000000428 dust Substances 0.000 claims abstract description 22
- 239000003595 mist Substances 0.000 claims abstract description 19
- 239000007921 spray Substances 0.000 claims abstract description 19
- 239000002253 acid Substances 0.000 claims abstract description 13
- 238000006552 photochemical reaction Methods 0.000 claims abstract description 13
- 230000007423 decrease Effects 0.000 claims abstract description 10
- 230000000694 effects Effects 0.000 claims abstract description 10
- 238000004140 cleaning Methods 0.000 claims abstract description 9
- 238000001816 cooling Methods 0.000 claims abstract description 9
- 239000002904 solvent Substances 0.000 claims abstract description 5
- 239000012855 volatile organic compound Substances 0.000 claims description 9
- 230000001699 photocatalysis Effects 0.000 claims description 7
- 238000007146 photocatalysis Methods 0.000 claims description 7
- 229910052782 aluminium Inorganic materials 0.000 claims description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 5
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims description 5
- 229910052753 mercury Inorganic materials 0.000 claims description 5
- 230000005540 biological transmission Effects 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 2
- 229910052802 copper Inorganic materials 0.000 claims description 2
- 239000010949 copper Substances 0.000 claims description 2
- 230000010355 oscillation Effects 0.000 claims description 2
- 239000010453 quartz Substances 0.000 claims description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 2
- 239000007789 gas Substances 0.000 description 60
- 238000000034 method Methods 0.000 description 17
- 230000003287 optical effect Effects 0.000 description 15
- 241000264877 Hippospongia communis Species 0.000 description 12
- 238000012545 processing Methods 0.000 description 12
- 230000008569 process Effects 0.000 description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 10
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 10
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 9
- 230000005684 electric field Effects 0.000 description 8
- 238000007254 oxidation reaction Methods 0.000 description 7
- 241000894006 Bacteria Species 0.000 description 6
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 6
- 239000000460 chlorine Substances 0.000 description 6
- 229910052801 chlorine Inorganic materials 0.000 description 6
- 230000001590 oxidative effect Effects 0.000 description 6
- 239000011593 sulfur Substances 0.000 description 6
- 229910052717 sulfur Inorganic materials 0.000 description 6
- 238000010586 diagram Methods 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 239000004020 conductor Substances 0.000 description 4
- 238000000354 decomposition reaction Methods 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 4
- KVGZZAHHUNAVKZ-UHFFFAOYSA-N 1,4-Dioxin Chemical compound O1C=COC=C1 KVGZZAHHUNAVKZ-UHFFFAOYSA-N 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 230000003247 decreasing effect Effects 0.000 description 3
- 230000000593 degrading effect Effects 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- -1 hydrogen sulfide Chemical compound 0.000 description 3
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 3
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000004065 semiconductor Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 241000700605 Viruses Species 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical compound ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 238000010494 dissociation reaction Methods 0.000 description 2
- 230000005593 dissociations Effects 0.000 description 2
- 238000010410 dusting Methods 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 239000003344 environmental pollutant Substances 0.000 description 2
- 230000005284 excitation Effects 0.000 description 2
- 239000003574 free electron Substances 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 238000012423 maintenance Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 231100000719 pollutant Toxicity 0.000 description 2
- 238000007781 pre-processing Methods 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 230000001172 regenerating effect Effects 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical class [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 230000005679 Peltier effect Effects 0.000 description 1
- 229910002370 SrTiO3 Inorganic materials 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229940069428 antacid Drugs 0.000 description 1
- 239000003159 antacid agent Substances 0.000 description 1
- 230000001458 anti-acid effect Effects 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- NEHMKBQYUWJMIP-NJFSPNSNSA-N chloro(114C)methane Chemical compound [14CH3]Cl NEHMKBQYUWJMIP-NJFSPNSNSA-N 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 229910052976 metal sulfide Inorganic materials 0.000 description 1
- 229940050176 methyl chloride Drugs 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000007539 photo-oxidation reaction Methods 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 1
- 229910052815 sulfur oxide Inorganic materials 0.000 description 1
- 239000002470 thermal conductor Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 238000002211 ultraviolet spectrum Methods 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 229910000859 α-Fe Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/75—Multi-step processes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/16—Disinfection, sterilisation or deodorisation of air using physical phenomena
- A61L9/18—Radiation
- A61L9/20—Ultraviolet radiation
- A61L9/205—Ultraviolet radiation using a photocatalyst or photosensitiser
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/32—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by electrical effects other than those provided for in group B01D61/00
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/80—Type of catalytic reaction
- B01D2255/802—Photocatalytic
Definitions
- the present invention relates generally to an air pollution treatment system and, more particularly, to a photolysis and photocatalysis air pollution treatment system using electrodeless UV lamp which treats a various types of air pollution using the high photochemical characteristics of electrodeless short wavelength ultraviolet light.
- Pure gas includes oxygen, nitrogen, a small amount of hydrogen, argon or the like and moisture and a small amount of carbon dioxide, and a harmful compound into which several molecules are combined does not exist.
- micro dust and volatile organic material generated from population explosion and industrialization, and NO , SO generated upon combustion of fossil fuel, as well as bad smell generated from several processes not only injure people's health but also cause global warming and disruption of the ozone layer, thereby damage due to air pollution getting serious.
- a porous filter such as activated carbon, for adsorbing harmful gas molecules, a bio-filter for decomposing them through the metabolism of bacteria, or a method of decomposing and oxidizing gas through low-temperature plasma is conventionally used in order to remove bad smell among air pollution generated.
- a Regenerative Thermal Oxidizer of directly oxidizing them through a separate heat source, or a Regenerative Catalytic Oxidizer (ROC) of removing them using catalyzer at low-temperature is used.
- a scrubber for removing micro dust and water-soluble gas contained in air using liquid may be used.
- ROT which is a process of collecting and oxidizing oxidizable material
- RCO uses platinum, tungsten, or vanadium as a catalyzer, so that fuel cost decreases, but cost for exchange of catalyzer is expensive, thereby falling generality because of the burden of operation.
- harmful gases that pollutes atmosphere are almost compounds generated by combining several elements and having inherent characteristics. Such characteristics are maintained as long as the bound molecular structure is not broken.
- the binding energy between respective elements constituting a molecule differs depending on the kind of elements and binding types. At this time, when external energy that is higher than the binding energy is applied to a molecule, the molecule is dissociated into respective elements (in this case, required energy is dissociation energy).
- photochemical energy irradiated through light among Thermal, Electrical, Chemical, photochemical energy that dissociates molecular combination, harmful gas compound can be decomposed.
- a principle of generating ultraviolet using a discharge lamp is to fill a lamp body with gas having a ultraviolet spectrum and flow discharge current through electrodes, thereby an outer electron of a mercury atom being excited.
- the outer excited electrons are transited from a high energy orbital to a low energy orbital to emit optical energy to the amount of orbital changes.
- a life of a discharge electrode decreases abruptly and thus an ultraviolet lamp with high power becomes less practical.
- the photochemical reaction on gas is determined depending on the wavel ength, exposure time and the amount of light of ultraviolet irradiated for each unit area, so that a function to irradiate enough amount of light to an irradiation area of a special purpose is required, and several parameters, such as the shape and resonance efficiency of a microwave resonant cavity, the electron field density distribution value of resonated electric field pattern must be applied, and therefore, the structure design of a resonance cavity is very difficult.
- the components of polluted air includes components including sulfur such as hydrogen sulfide, disulfide methyl or the like, components including nitrogen such as amine, and components including chlorine such as dioxin or the like, besides hydrocarbon, aldehyde composed of carbon, hydrogen and oxide.
- the former polluted gas is to be harmless just through decomposition; however, the later polluted gas is not perfectly to be harmless just through decomposition, so that an apparatus for stabilizing the gas in a state of acid, such as nitric acid, hydrochloric acid, sulfuric acid, or the like, and preventing it from being exited to the exterior is required.
- an object of the present invention is to provide an apparatus for processing various air pollutions using photolysis reaction promoted by an electrodeless ultraviolet lamp and photochemical reaction promoted by pho- tocatalyst which processes a various types of air pollution using the high photochemical characteristics of electrodeless short wavelength ultraviolet light.
- Another object of the present invention is to an apparatus for processing air pollution which stably and perfectly processes all air pollution components, can be small-sized and lighten, is applied to from indoor environment to large-scaled industries in places of a conventional bio-filter for removal of bad smell, is used for all air pollution, such as bad smell, NOx, Sox volatile organic compound and the like, requires low maintenance and management expenses, and provides large contribution to atmosphere environment management field.
- Still another object of the present invention is to provide an apparatus for processing air pollution which uses an electrodeless lamp, thereby eliminating cause of decreasing life thereof due to degradation of electrodes to allow permanent usage, decreases mercury pollution due to disuse of a lamp, thereby providing large environmental effect.
- Still another object of the present invention is to provide an apparatus for processing air pollution which resolves the treatment of fluent gas, such as dioxin, and biological pollution which have been difficult problems.
- the present invention provides photolysis and photocatalysis air pollution treatment system using electrodeless UV lamp, comprising a spray humidifying unit for solving water-soluble gas in a solvent and collecting the gas; a first chevron filter unit for collecting and exhausting mist in which the water-soluble gas is dissolved through the spray humidifying unit to decrease load; a dehumidifying unit having a cooling element coupled thereto to adjust temperature to a dew point; an electrostatic filer unit having a minus (-) electrode for electrically charging micro dust of inflow air to remove micro dust using an electrostatic effect; an air-transmissive plate-type ultraviolet lamp for exhausting electrodeless ultraviolet using magnetron; a photolysis unit for making inflow gas dissociated according to a photochemical reaction; a honeycomb-shaped photocatalyst filter unit arranged adjacent to the plate-type ultraviolet lamp; a spay nozzle mounted in the photolysis unit for cleaning acid adhered to a surface of a photocatalyst; and a second
- FIG. 1 is a schematic perspective view showing an photolysis and photocatalysis air pollution treatment system using electrodeless UV lamp according to the present invention.
- FIG. 2 is a plan view of electrodeless ultraviolet lamp structure illustrated in FIG. 1.
- FIG. 3 is a diagram exemplarily showing the distribution of electric field in a resonator constituting the present invention.
- FIG. 4 is a perspective view schematically showing a 2-step distribution-type electrodeless apparatus for generating ultraviolet according to an embodiment of the present invention.
- FIG. 5 is an exploded perspective view of a magnetron launcher having a 2-branch slot constituting the present invention.
- FIG. 6 is a perspective view of a dehumidifying unit using a chevron filter constituting the present invention.
- FIG. 7 is a perspective view of a dehumidifying unit using a chevron filter another embodiment a screen unit constituting the present invention.
- FIG. 8 is a diagram showing the flow of air within the chevron filter constituting the present invention.
- FIGS 9 and 10 are diagrams showing carriers for oxidation treatment promoted by photocatalyst according to the present invention.
- UV lamp according to a preferred embodiment of the present invention is described below in detail with reference to the accompanying drawings.
- FIG. 1 is a schematic perspective view showing a system for treating a pollutant in a gas state according to a first embodiment of the present invention.
- photolysis and photocatalysis air pollution treatment system using electrodeless UV lamp includes, a spray humidifying unit for making water-soluble gas to be dissolved in a solvent and collecting the gas, a first chevron filter unit for collecting and exhausting mist in which the water-soluble gas is dissolved through the spray humidifying unit to decrease load, a dehumidifying unit having a cooling element coupled thereto to adjust temperature to a dew point, an electrostatic filer unit having a minus (-) electrode 31 for electrically charging micro dust of inflow air to remove micro dust using an electrostatic effect, an air-transmissive plate-type ultraviolet lamp for exhausting electrodeless type ultraviolet using magnetron, a photolysis unit for making inflow gas dissociated according to a photochemical reaction, a honeycomb- shaped photocatalyst filter unit arranged adjacent to the plate-type ultraviolet lamp, a spay nozzle mounted in the photolysis unit for cleaning acid adhered to a surface of a photocat
- bad-smelling polluted air among which dust particles having large diameters are filled out by passing through a free filter 10, flows into an air blower 11 which is composed of both inhalation sirocco fans.
- the sirocco fan is capable of exhausting air with relatively high wind pressure, and thus can prevent the reduction of the amount of wind due to the loss of the wind pressure to be occurred in a subsequent stage.
- the present invention relates to an apparatus for processing harmful gas based on a photochemical method, but a pre-processing apparatus to be described below may be attached thereto in order to improve efficiency and reliability in the main functions thereof.
- the spray-type humidifying unit is constructed in a water cleaning (scrubber) way to reduce the concentration thereof using a relatively simple method.
- the spray-type humidifying unit is composed of a mist spray nozzle 20, it's support bracket 21, and a hose 23 and a pump 24 for supplying water, which minutely vaporizes water in the inlet of harmful gas and sprays them. Then, water-soluble gas molecules are dissolved in minute water particles when being mixed within and exhausted from the air blower 11. The separation and exhaustion of the mist, in which water-soluble gas are dissolved, are performed by the first chevron filter unit composed of the chevron filter 30, thereby reducing the load of a main apparatus.
- the chevron filter 30 commonly used in the pre-processing steps is made of metal plate material, a thermal conductivity of which is good, having a structure similar to that of D shaped character, thereby having a bent structure in order to guide collision with inflow air, and the structure and operational principle thereof are described below.
- FIGS. 6 to 8 are diagrams showing the chevron filter 30 used for a de-dusting, a de- humidifying, and an antacid operations.
- FIG. 6 is a perspective view of a dehu- midifying unit using a chevron filter constituting the present invention
- FIG. 7 is a perspective view of a de-dusting unit using a chevron filter according to another embodiment constituting the present invention
- FIG. 8 is a diagram showing the flow of air within the chevron filter constituting the present invention.
- the chevron filters 30 are arranged to be parallel to each other for air to pass through gaps therebetween, so that the air continuously collides with bent surfaces, thereby causing a vortex around the air pocket 36.
- a portion into which air flows is separated from the exterior with a plate member 33 as shown in FIG. 7, but an air pocket 36 portion is exposed to have pressure difference from the exterior.
- thermoelectric elements 40, 42 which are respectively heating and cooling elements based on Peltier effect in which a heating phenomenon occurs in one surface and a heat absorption phenomenon occurs in the other surface when current flow therethrough, are arranged in another end of the chevron filter 30.
- thermoelectric elements 40 and 42 shown in FIG. 6 a cooling phenomenon due to the heat absorption occurs in a front surface and a heating phenomenon occurs to emit the heat in a rear surface when a current flows therethrough. Therefore, when the heat collected in the rear surface is transferred to another place to emit the heat, a cooling is continuously carried out in the cooled surface.
- thermoelectric elements 40 and 42 A thermal conductor 41 is attached to the cooled surface of each of the thermoelectric elements 40 and 42, thereby be coupling to the chevron filter 30, so that the temperature of the cooled surface is transferred to the chevron filter 30.
- Such elements constitute the dehumidifying unit.
- chevron filters 30 In the chevron filters 30 according to the present invention, concave inverse- projections are mounted on respective bent portions, thereby collecting mist and micro dust.
- the angle of bent portions falls within 130 to 165 degrees.
- the angle of gas flow can be controlled, and preferably is made of copper or aluminum having a low thermal resistance.
- an air-transmissive plate type ultraviolet lamp unit for decomposing pre-processed polluted air or gas to be processed, having the decreased concentration of water-soluble gas, is arranged.
- pollution gas including bad smell is a great quantity of low-concentration gas continuously generated, so that a continuous processing is preferred.
- an ultraviolet optical source used as a resonator in which a ultraviolet lamp is mounted, has a flat hexahedron structure and resonates in TE055 mode, both sides of which is made of metal lattice net such that electromagnetic waves is shielded and resonates within the lattice net, ultraviolet is irradiated through the lattice, and gas freely passes therethrough.
- a plurality of electrodeless lamp is arranged in a resonance cavity while their resonance patterns are identical to electronic resonance patterns, thereby improving the efficiency of optical transformation.
- Such lamp bodies are stacked in multi-stages, and a honeycomb coated with pho- tocatalyst is inserted into every stacked surfaces, so that it is preferred to cause photochemical reaction and oxidization reaction due to photocatalyst, thereby decomposing molecules and stably oxidizing the decomposed elements
- FIGS. 2 to 5 are views showing the constructions of a microwave electrodeless ultraviolet lamp unit embodied to the present invention.
- the microwave electrodeless ultraviolet lamp unit includes a magnetron 103 that is a microwave generator, and a magnetron launcher 105 configured to resonate electromagnetic waves oscillated by the magnetron.
- the magnetron launcher 105 branches the electromagnetic waves through respective wave node points 110 and 111 and respectively supplies the branches to upper and lower resonators 100 and 150 respectively housed a lamp.
- a photochemical reaction chamber 50 to which high density ultraviolet that is generated by the electrodeless ultraviolet lamp is irradiated, is formed.
- the upper and lower resonators 100 and 150 in which lamps are respectively received, are divided by electro magnetic shielding walls 104, and there is a opening on the wall, through which the ultraviolet lamp 106 passes, so that one lamp is commonly used by two resonators.
- a magnetron power supply adopts half- wave voltage doubling scheme, and is operated only for (+) or (-) of one period when using a conventional 60Hz power supply.
- two magnetrons 103 are operated in inverse-phase with respect to each other, thereby reducing blank time through mutual complementation.
- the reason for this is that the ultraviolet lamps are received in the resonators 101 and 102 through the wall 104, and the loss of electromagnetic waves occurs through the openings of the walls 104.
- the ultraviolet lamp received within the resonator starts to discharge, the interior of a tube represents the characteristics of a conductor due to free electrons, thereby intercepting the transmission path of electromagnetic wave, so that it is difficult to transfer the energy of electromagnetic waves to several lamps uniformly. Therefore, according to the present invention, propagation paths 107 and 108 are provided within the resonator as illustrated in FIG. 2, thereby making the distribution of electric field uniform within the resonator.
- the length of the wavelength of electromagnetic waves within free space is 12.2 cm in the resonance pattern of a case where the resonators 101 and 102 resonate in TE055 mode, but the length ⁇ g of one wavelength within a space surrounded by a specific conductor, such as a wave guide, is longer than it.
- the magnetron launcher 105 embodied to the present invention uses a wave guide having a width of 82.5 mm, so that ⁇ g is 268mm, and the interval between slots 110, 111 respectively formed in the wave node points of electromagnetic waves is to be 134mm.
- the resonator having a thickness of 35mm is located in the interval and a honeycomb photocatalyst having a thickness of 90 mm is inserted thereinto.
- An example of the combination of the slots 110 and 111 and the resonators 100 and 150 is illustrated in FIG. 4.
- the electrodeless ultraviolet lamp is driven by a super-high frequency oscillation magnetron.
- High frequency is provided to a plate-type resonator in a TEOnm mode through slots formed on each 1/2 wavelength-wave node point of the magnetron launcher (In this case, n and m are integers of 3 to 12), the transmission path of electromagnetic waves is provided within the resonator.
- n and m are integers within a range of 3 to 12).
- the plate-type ultraviolet lamps are arranged to be stacked and honeycomb-shaped photocatalysts are stacked and inserted therebetween.
- a cell diameter of the photocatalyst falls within a range of 2 to 5 mm
- a thickness of the photocatalyst is falls within a range of 20 to 100 mm.
- the ultraviolet lamp is made of Quartz material having characteristics of cutting off short- wavelength around 200 nm, and is a low-pressure ultraviolet lamp that is filled with 0.5-2 mg mercury for each volume of 1 cm , and has a caliber of 12-22 mm and an entire length falling within 400-1200 mm.
- a honeycomb-shaped photocatalyst filter unit is located adjacent to the ultraviolet lamps constructed as described above and a spray nozzle is mounted on the front of the photocatalyst in order to wash acid attached on the surface of the photocatalyst, and a second chevron filter unit for collecting scattered mist is provided, which are described in detail below.
- harmful gas is decomposed into carbon and hydrogen such as alcohol, hydrocarbon, or the like through optical dissociation by passing through the ultraviolet lamps, there is no problem.
- sulfur or chlorine such as hydrogen sulfide and methyl chloride is contained therein, but there is substance that should not be exhausted in being decomposed.
- a photocatalyst filter unit 60 in order to oxidize the substance using OH radicals to be stabilized to acid, such as a hydrochloric acid, sulfuric acid, or the like, and collect them, thereby not being exhausted toward the atmosphere, and separately clans generated acid.
- Photocatalyst is a kind of a semiconductor, and emits electrons and holes due to the photoelectric effect when optical energy that is higher than band gap energy of the semiconductor is provided thereto.
- the electrons and holes act on water molecules to generate OH radicals.
- the generated OH radicals oxidize most of organic and inorganic molecules.
- Metal-oxide photocatalyst includes TiO 2 (3.2eV), WO 3 (2.8eV), SrTiO 3 (3.2eV), ⁇ -Fe
- Metal sulfide photocatalyst includes ZnS(3.6eV) or the like.
- the photooxidation reaction activity of an oxide semiconductor represents the order of TiO (anatase)> TiO (rutile) > ZnO > ZrO > SnO > V O and TiO represents the highest activity, which is biologically and chemically inert, is resistant to optical corrosion and chemical corrosion, and is most inexpensive.
- the band gap energy of TiO is 3.2eV, and starts to be activated in an ultraviolet region shorter than 370nm. As the wavelength is shorter, optical activation increases. That is, in a photocatalyst oxidization process, a short-wavelength excitation optical source is essential.
- aluminum honeycombs 6163 on which photocatalyst are coated are mounted on both surfaces of the electrodeless ultraviolet lamp body having a plan structure, as shown in FIGS. 9 and 10, thereby constructing a photocatalyst filter unit 60.
- ultraviolet is irradiated to the interior of the cell of each honeycomb and, at the same time, gas to be processed passes through the cell, thereby solving this problem.
- the surface area thereof increases, so that contact efficiency with gas increases.
- photocatalyst is coated on the aluminum honeycombs 6163 having a cell size of 1/16-1/8 inch, thereby achieving this object.
- FIG. 9 shows the structure of a honeycomb on which photocatalyst is coated.
- the photocatalyst when ultraviolet is irradiated on the photocatalyst, the photocatalyst emits electrons and holes, and the electrons and holes act on water molecules to generate OH radicals.
- FIG. 10 shows that the interval of cells decreases when honeycombs are stacked, in which 3 honeycombs 61, 62 and 63 are stacked to decrease the size of existing cells to one sixth, thereby increasing contact efficiency with air.
- the photochemical reaction of ultraviolet has the effect of killing virus or bacteria, and can be described as a photolysis appearance on hydrogen atoms which couple chains in DNA double stranded chain.
- the photochemical reaction has the effect on killing virus or bacteria as well as the effect on a harmful gas, so that the apparatus of processing pollution gas proposed in the present invention has an excellent advantage in a clean room such as where environmental hygiene is required.
- Such oxidation treatment is performed in the surface of the photocatalyst, so that sulfur or chlorine components are stabilized to sulfuric acid or hydrochloric acid, causing to be adhered to the surface of the photocatalyst and thus they become the cause of gradually degrading the function thereof.
- the spray nozzle is provided to periodically spray cleaning solution to wash the photocatalyst.
- the cleaning solution resulting from the washing of the photocatalyst is scattered and exhausted along with treated air
- the cleaning solution passes through a chevron filter 80 for collecting acid which constitutes the second chevron filter unit, so that mist is collected and only air components are exhausted to the exterior.
- the apparatus for dissolving and collecting water-soluble gas acts as an apparatus for condensing and collecting the volatile organic compound.
- the dust, moisture and mist collected by a filter are caused to be exhausted towards the exterior using pressure difference.
- the polluted air having passed through the air blower 11, passes through the charged electrodes 31 constituting an electrostatic filter unit, so that solid components, such as micro dust, contained in the inflow air, are charged negative (-).
- the air also passes through the chevron filters 30, where the chevron filters 30 are charged positive (+) to absorb micro dust having static electricity.
- Gas to be processed in which the concentration of polluted air or water-soluble gas has been reduced in the pre-processed state, flows into the photochemical reaction chamber 50 to which ultraviolet is irradiated, so that optical energy of about 20mW/cm /sec irradiated from the ultraviolet lamp decomposes the pollution components of the inflow air.
- the primary wavelength of the ultraviolet lamp which is 254nm, causes molecules, the binding energy of molecules of which is lower than 460KU/mole, to be dissociated, thereby decomposing most of bad smell and the volatile organic compound, nitrogen oxides and sulfur oxides which are air pollution components.
- the short- wavelength excitation optical source is essentially required.
- aluminum honeycombs 6163, on which photocatalyst are coated are mounted on both surfaces of the electrodeless ultraviolet lamp body having a plan structure, so that ultraviolet is irradiated to the interior of each cell of the honeycomb and, at the same time, gas to be processed passes through the cell, thereby solving this problem.
- a spray nozzle (not shown) is provided to periodically wash the surface of the photocatalyst in order to preventing the case in which sulfur or chlorine components are stabilized to sulfuric acid or hydrochloric acid, being caused to be adhered to the surface of the pho- tocatalyst, and then gradually degrading the function thereof.
- the cleaning solution resulting from the washing of the photocatalyst is scattered and exhausted along with treated air, it passes through the second chevron filter unit consisting of a chevron filter 80 for collecting acid, so that mist is collected and only air components are exhausted to the exterior.
- Electromagnetic waves generally having a frequency of 2450 MHz ⁇ 20MHz which is oscillated by the magnetron 103, which is means for generating micro wave, resonates through the magnetron launcher 105 in TEO 12 mode as shown in FIG. 5, is divided into two through respective wave node points 110 and 111 and flows into upper and lower resonators 100 and 150 in which lamps are respectively received.
- the ultraviolet lamp arranged within each of the resonators starts to discharge, the interior of a tube represents the characteristics of a conductor due to free electrons, thereby intercepting the transmission path of electromagnetic wave, so that it is difficult to transfer the energy of electromagnetic waves to several lamps uniformly. Therefore, in the present invention, propagation paths 107 and 108 are provided within the resonator as illustrated in FIG. 2, thereby making the distribution of electric field uniform within the resonator.
- micro dust are collected to concave air pocket 36 in which air speed is low, and again exhausted toward the direction 39 of the exterior in which pressure is low to be collected in and exhausted from an collector. Air is exhausted to the inverse direction of an inflow side, and, therefore, minute solid components and gas components are separated from each other.
- the apparatus for processing air pollution having the above-described construction stably and perfectly processes all air pollution components, can be small-sized and lighten, is applied to from indoor environment to large-scaled industries in places of a conventional bio-filter for removal of bad smell, is used for all air pollution, such as bad smell, NO , SO volatile organic compound and the like, requires low maintenance and management expenses, and provides large contribution to atmosphere environment management field.
- the apparatus for generating electrodeless ultraviolet according to the present invention uses an electrodeless lamp, thereby eliminating cause of decreasing life thereof due to degradation of electrodes to allow permanent usage, decreases mercury pollution due to disuse of a lamp, thereby providing large environmental effect.
- the present invention resolves the treatment of fluent gas, such as dioxin, and biological pollution which have been difficult problems.
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KR1020060021354A KR100671232B1 (ko) | 2006-03-07 | 2006-03-07 | 무전극 자외선램프에 의한 광분해 반응과 광촉매에 의한광화학 반응을 이용한 기체 오염처리장치 |
KR10-2006-0021354 | 2006-03-07 |
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PCT/KR2007/001124 WO2007102701A1 (en) | 2006-03-07 | 2007-03-07 | Photolysis and photocatalaysis air pollution treatment system using electrodeless uv lamp |
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Cited By (8)
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CN104147916A (zh) * | 2014-07-31 | 2014-11-19 | 浙江天蓝环保技术股份有限公司 | 基于fluent设置循环流化床锅炉的SNCR喷枪方法 |
WO2016137550A1 (en) * | 2015-02-27 | 2016-09-01 | Mazra Incorporated | Air treatment system |
US20170341489A1 (en) * | 2015-02-17 | 2017-11-30 | Hanon Systems | Electrification apparatus for electrostatic dust collector |
US10300454B2 (en) | 2017-04-18 | 2019-05-28 | Breakthrough Technologies, Llc. | Sulfur production |
CN109925862A (zh) * | 2018-12-25 | 2019-06-25 | 四川大学 | 一种voc废气处理系统及其处理方法 |
CN112090222A (zh) * | 2020-09-23 | 2020-12-18 | 四川科伦药业股份有限公司 | 一种用于制药企业实验动物房废气治理的处理方法 |
CN112604494A (zh) * | 2020-11-27 | 2021-04-06 | 盐城中创环保科技有限公司 | 一种有机废气光催化设备 |
CN115121095A (zh) * | 2021-03-24 | 2022-09-30 | 湖北湛澜环保科技有限公司 | 一种MRTO磁控中温等离子VOCs消解装置、系统及工艺 |
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KR100832398B1 (ko) | 2007-07-20 | 2008-05-26 | 남승엽 | 무전극 지르코늄 자외선램프와 이를 이용한 액상 살균장치 |
KR100874130B1 (ko) | 2008-01-30 | 2008-12-15 | (주)동남이엔지 | 광촉매를 이용한 정화 장치 |
KR101113309B1 (ko) | 2010-02-03 | 2012-03-13 | 순천대학교 산학협력단 | 마이크로파로 구동되는 무전극 자외선 램프를 이용한 프레온 가스의 분해방법 및 이를 위한 분해장치 |
KR101253340B1 (ko) | 2012-12-13 | 2013-04-10 | 주식회사 한주나노 | 탈취장치 |
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CN112090222A (zh) * | 2020-09-23 | 2020-12-18 | 四川科伦药业股份有限公司 | 一种用于制药企业实验动物房废气治理的处理方法 |
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CN115121095A (zh) * | 2021-03-24 | 2022-09-30 | 湖北湛澜环保科技有限公司 | 一种MRTO磁控中温等离子VOCs消解装置、系统及工艺 |
CN115121095B (zh) * | 2021-03-24 | 2023-04-25 | 湖北湛澜环保科技有限公司 | 一种MRTO磁控中温等离子VOCs消解装置、系统及工艺 |
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