WO2007085062A1 - Production of perforated aluminium (in the form of sheet or foil) hard- or soft-rolled - Google Patents
Production of perforated aluminium (in the form of sheet or foil) hard- or soft-rolled Download PDFInfo
- Publication number
- WO2007085062A1 WO2007085062A1 PCT/BA2007/000002 BA2007000002W WO2007085062A1 WO 2007085062 A1 WO2007085062 A1 WO 2007085062A1 BA 2007000002 W BA2007000002 W BA 2007000002W WO 2007085062 A1 WO2007085062 A1 WO 2007085062A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- foil
- sheet
- aluminium
- perforated
- production
- Prior art date
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25F—PROCESSES FOR THE ELECTROLYTIC REMOVAL OF MATERIALS FROM OBJECTS; APPARATUS THEREFOR
- C25F3/00—Electrolytic etching or polishing
- C25F3/02—Etching
- C25F3/04—Etching of light metals
Definitions
- the invention refers to aluminium foils or sheets that are perforated and can be classified as aluminium foil or sheet.
- the technological problem arises as to how to perforate a finished aluminium foil or sheet, i.e. which procedure to use in order to perform the perforation in order to obtain a product that could be used in e.g. food industry for packaging.
- the cathode is made of chrome steel net.
- Figure 1 Represents the technological scheme of aluminium foil perforation, with the following characteristics or elements:
- Figure 2 - Represents the technological scheme of aluminium sheet production in a tub with electrodes.
- the perforation process is continuous, as shown on Figure 1.
- the cathode consists of a 24m x Im chrome steel net, with 0.6mm x 0.6mm holes. Energy consumption: 5KW/hour for 36 foils.
- the perforated aluminium sheet (2m x Im) production requires a tub with dimensions 2.5m x 1.4m x 0.5m.
- the tub contains the already described electrolyte, where an aluminium bar as anode and a 2m x Im chrome steel net are vertically soaked.
- the distance between the electrodes is 15mm.
- the perforation of lmm thick sheet requires a 13.5 hour-long electrochemical process, with permanent electrolyte dozing and maintaining the required pH.
- the sheet is then rinsed with softened water and taken out of the tub.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electrolytic Production Of Metals (AREA)
Abstract
Perforated aluminium foil or sheet is produced electrochemically, so that the size of pores can be controlled by applying specific voltage on electrodes. In the presented technological process, the pore size ranges from 0.3 to 1.5 µ with stochastic distribution. The essence of the invention lies in the composition of electrolyte (HNO3 in pH=3-4 concentration) and in maintaining the concentration and voltage (12-13V) throughout the process. The anode is aluminium and cathode a chrome steel net. Perforated foil can be used in food industry for packaging.
Description
Zijad Cehic
Trnovska 7, 71000 Sarajevo, Bosna i Hercegovina
Production of perforated aluminium (in the form of sheet or foil) hard- or soft-rolled
Field of technology the invention refers to
The invention refers to aluminium foils or sheets that are perforated and can be classified as aluminium foil or sheet.
Technical problem
The technological problem arises as to how to perforate a finished aluminium foil or sheet, i.e. which procedure to use in order to perform the perforation in order to obtain a product that could be used in e.g. food industry for packaging.
State of art
The inventor is not aware of any technological solutions for the problem of foil or sheet perforation that are similar to the invention presented here.
Presentation of the essence of the invention
The production is based on electrochemical procedure, whereby micro-holes are being generate on the anode, which consists of aluminium, in the electrolyte (HNO3 solution inpH=3-4 concentration), with the 12V-13V direct current voltage. The cathode is made of chrome steel net.
Short description of drawings
The accompanying drawings, i.e. pictures included in the description, which make up part of the inovation description, ilustrated the best way of invention execution presently discussed, and help to explain the basic principles of the invention.
Figure 1 - Represents the technological scheme of aluminium foil perforation, with the following characteristics or elements:
1. imperforated aluminium roll, 2. tub with electrodes and electrolyte, where teh perforation is performed, 3. tub for neutralization, 4. rinsing tub, 5. perforated aluminium roll.
Figure 2 - Represents the technological scheme of aluminium sheet production in a tub with electrodes.
Detailed description of the invention AI-foil perforation
Rolled Al-foil, 20 μ (μ = 0,001mm) thick and 1000mm wide is bought from a foil manufacturer (roll weight depends on the length).
From the roll, Al-foil is drawn into the tub, with the known electrolyte, beneath the cathode, over the isolator distancer (the distance between anode and cathode is 15- 20mm), and with the known direct current voltage is kept for 15 minutes. It is then drawn into the second tub, where it is neutralized in NaOH solution with pH=8. Thus neutralized perforated aluminium foil is taken out of the second tub and placed into the third tub, where it is rinsed with 0.2-0.5 D0 water. The wet perforated aluminium foil, that has passed through these three tubs, is rolled. The current circle is then stopped and the roll is dried, i.e. it is unrolled and passed through a tunnel heated to 200 C, after which it is packed.
The perforation process is continuous, as shown on Figure 1.
Electrolyte concentration must be continually monitored, and the pH=3-4 value maintained by dozing the fresh electrolyte.
Following tub dimensions are needed for the production of 36 pieces of perforated foil (dimensions 8m x 0.33m):
-tub with electrodes and electrolyte: 28m x 1.4m x 0.80m,
-tub for neutralization: 5m x 1.4m x 0.80m,
-tub for rinsing: 3m x 1.4m x 0.80m.
The cathode consists of a 24m x Im chrome steel net, with 0.6mm x 0.6mm holes. Energy consumption: 5KW/hour for 36 foils.
Chemicals consumption: 20 litres OfHNO3 in 62% concentration for electrolyte
5 litres NaOH 45% for neutralization 2000 litres softened water/hour for rinsing.
Following storage tanks are needed for hourly production of 36 pieces of perforated foil:
- for HNO3 of 62% concentration cca 5m3,
- for NaON of 45% concentration cca 2m3,
- for electrolyte preparation, two 30m3 tanks,
- for NaOH preparation two 20m3 tanks,
- for waste water treatment, three pools with dimensions 10m x 7m x 2.5m.
Aluminium sheet perforation
The perforated aluminium sheet (2m x Im) production requires a tub with dimensions 2.5m x 1.4m x 0.5m.
The tub contains the already described electrolyte, where an aluminium bar as anode and a 2m x Im chrome steel net are vertically soaked. The distance between the electrodes is 15mm.
The perforation of lmm thick sheet requires a 13.5 hour-long electrochemical process, with permanent electrolyte dozing and maintaining the required pH. The
current is then turned off, and the neutralization with ph=8 NaOH is done. The sheet is then rinsed with softened water and taken out of the tub.
The process is discontinued, as presented in the scheme no.2.
Energy consumption per a sheet bar with dimensions 2m x Im x lmm is 5.2KW.
Chemicals consumption: for electrolyte, 15 litres OfHNO3 62% for neutralization, 2 litres of NaOH 45% for rinsing, 3m3 softened water.
Claims
1. This invention claims protection of the sequence of technological operations for production of perforated aluminium (in the form of sheet or foil) hard- or soft-rolled, characterized by the composition of electrolytes (HNO3 in pH=3-4 concentration), by defined voltage (12V — 13 V of direct current) and cathode type (chrome steel net).
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BABAP062327A | 2006-01-27 | ||
BA062327 | 2006-01-27 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2007085062A1 true WO2007085062A1 (en) | 2007-08-02 |
Family
ID=37912416
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/BA2007/000002 WO2007085062A1 (en) | 2006-01-27 | 2007-01-25 | Production of perforated aluminium (in the form of sheet or foil) hard- or soft-rolled |
Country Status (1)
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WO (1) | WO2007085062A1 (en) |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3193485A (en) * | 1960-09-20 | 1965-07-06 | Plessey Co Ltd | Electrolytic treatment of aluminium for increasing the effective surface |
US3477929A (en) * | 1966-04-18 | 1969-11-11 | Fujitsu Ltd | Method of etching aluminum foil in the manufacturing of aluminum electrolytic condensers |
FR2043765A1 (en) * | 1969-05-29 | 1971-02-19 | Vaw Ver Aluminium Werke Ag | Electrolytic polishing of aluminium strip - and sheer |
US3779877A (en) * | 1972-02-22 | 1973-12-18 | Sprague Electric Co | Electrolytic etching of aluminum foil |
JPS527834A (en) * | 1975-07-09 | 1977-01-21 | Fujitsu Ltd | Method of producing porous anodic elements of aluminum |
GB1524985A (en) * | 1975-08-26 | 1978-09-13 | Inco Europ Ltd | Electrolytic production of perforated metal foil |
US20040040416A1 (en) * | 2002-08-27 | 2004-03-04 | Jonah Erlebacher | Method of forming nanoporous membranes |
-
2007
- 2007-01-25 WO PCT/BA2007/000002 patent/WO2007085062A1/en active Application Filing
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3193485A (en) * | 1960-09-20 | 1965-07-06 | Plessey Co Ltd | Electrolytic treatment of aluminium for increasing the effective surface |
US3477929A (en) * | 1966-04-18 | 1969-11-11 | Fujitsu Ltd | Method of etching aluminum foil in the manufacturing of aluminum electrolytic condensers |
FR2043765A1 (en) * | 1969-05-29 | 1971-02-19 | Vaw Ver Aluminium Werke Ag | Electrolytic polishing of aluminium strip - and sheer |
US3779877A (en) * | 1972-02-22 | 1973-12-18 | Sprague Electric Co | Electrolytic etching of aluminum foil |
JPS527834A (en) * | 1975-07-09 | 1977-01-21 | Fujitsu Ltd | Method of producing porous anodic elements of aluminum |
GB1524985A (en) * | 1975-08-26 | 1978-09-13 | Inco Europ Ltd | Electrolytic production of perforated metal foil |
US20040040416A1 (en) * | 2002-08-27 | 2004-03-04 | Jonah Erlebacher | Method of forming nanoporous membranes |
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