WO2007054505A2 - Process for the manufacture of dichloropropanol by chlorination of glycerol - Google Patents
Process for the manufacture of dichloropropanol by chlorination of glycerol Download PDFInfo
- Publication number
- WO2007054505A2 WO2007054505A2 PCT/EP2006/068208 EP2006068208W WO2007054505A2 WO 2007054505 A2 WO2007054505 A2 WO 2007054505A2 EP 2006068208 W EP2006068208 W EP 2006068208W WO 2007054505 A2 WO2007054505 A2 WO 2007054505A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- vessel
- liquid medium
- wall
- level
- liquid
- Prior art date
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C31/34—Halogenated alcohols
- C07C31/36—Halogenated alcohols the halogen not being fluorine
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/62—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by introduction of halogen; by substitution of halogen atoms by other halogen atoms
Definitions
- the present invention relates to a process for the manufacture of dichloropropanol in which glycerol and a chlorinating agent are reacted optionally in the presence of an organic acid, so as to obtain reaction products comprising dichloropropanol.
- the dichloropropanol can be separated from the other reaction products and can be subjected to a dehydrochlorination reaction, so as to manufacture epichlorohydrin.
- a preferred chlorinating agent is hydrogen chloride.
- the reaction between glycerol and the chlorinating agent is preferably carried out in a reactor and related ancilliary equipments made of or coated with materials resistant to chlorinating agents and in particular to hydrogen chloride under the reaction conditions.
- Enamelled (glass-lined) steel is a preferred vessel material. The applicant has found that such materials remain however unsatisfactory, i.e. they are corroded by liquid mixtures containing water, dichloropropanol and hydrogen chloride, resulting from the condensation of rich hydrogen chloride content vapours on the inner walls of the reactor and of related ancilliary equipments.
- This aim of this invention is to provide a process for manufacturing dichloropropanol which does not exhibit that problem.
- the invention therefore relates to a process for the manufacture of dichloropropanol in which glycerol is reacted with a chlorinating agent comprising hydrogen chloride, wherein, in a vessel, a liquid medium is in equilibrium with a vapour phase and wherein at least one part of the inner wall of the vessel which is above the level of the liquid medium in the vessel is maintained at a temperature lower than 120 0 C or at a temperature at least 1 0 C higher than the dew temperature of the vapour phase and/or is trickled with a liquid.
- the part of the inner wall of the vessel which is above the level of the liquid medium in the vessel is maintained at the required temperature continuously or intermittently.
- the temperature of 120 0 C is the temperature at which corrosion of enamelled steel at a rate of at least 0.01 mm/year is observed in the presence of hydrogen chloride/water liquid mixtures containing at least 4 % by weight of hydrogen chloride.
- the vessel can be any vessel of the process for manufacturing the dichloropropanol where the temperature of the liquid phase is higher than 120 0 C, like for instance a reactor, a distillation column, a stripping column or a decantor.
- the hydrogen chloride content is generally higher than or equal to 1 % by weight of the mixture, frequently higher than or equal to 3 % and often greater than or equal to 5 %.
- the hydrogen chloride content is generally lower than or equal to 80 % by weight of the mixture, frequently lower than or equal to 60 % and often lower than or equal to 50 %.
- the water content is generally higher than or equal to 4 % by weight of the mixture, frequently higher than or equal to 5 % and often greater than or equal to 10 %.
- the water content is generally lower than or equal to 80 % by weight of the mixture, frequently lower than or equal to 70 % and often lower than or equal to 60 %.
- the dichloropropanol content is generally higher than or equal to 4 % by weight of the mixture, frequently higher than or equal to 5 % and often greater than or equal to 10 %.
- the dichloropropanol content is generally lower than or equal to 80 % by weight of the mixture, frequently lower than or equal to 70 % and often lower than or equal to 60 %.
- the level of the liquid medium in the vessel is defined as the level of the liquid when the vessel is operating in stationary regime.
- the inner wall of the vessel which is above the level of the liquid medium in the vessel generally extends above the level of the liquid medium in the vessel to the top of the vessel.
- the temperature of the inner wall of the vessel which is above the level of the liquid medium in the vessel is at a temperature lower than 120 0 C, preferably lower than or equal to 110 0 C, more preferably lower than or equal to 100 0 C and most preferably lower than or equal to 90 0 C.
- the internal wall of the vessel which is above the level of the liquid medium in the vessel is cooled down by means of an external cooling system.
- That system can be for instance a cooling fluid circulating between the inner and outer wall of the part of the vessel (double-walled conventional jacket) which is above the level of the liquid medium in the vessel or a cooling fluid circulating in a serpentine welded on the vessel wall or connected by a thermally conductive cement or located within the protective layer (for instance serpentine flooded in the protective layer or channel drilled in the bulk of the protective layer) or a semi-shell tube (half -pipe jacket) in contact with the outer wall of the vessel which is above the level of the liquid medium in the vessel or by flushing a cooling fluid on the outer wall of the vessel which is above the level of the liquid medium in the vessel.
- the cooling fluid can be a gas or a liquid. It is preferred to use a gaseous fluid when flushing the outer wall.
- the gas can be for example dry air or nitrogen.
- a liquid fluid when circulating in double- walled envelope and serpentines.
- the liquid can be an organic liquid, an inorganic liquid or a mixture thereof. It is preferred to use an inorganic liquid, more preferably water.
- the inner wall of the vessel which is above the level of the liquid medium in the vessel is cooled down by flushing a cooling fluid on the inner wall.
- the fluid can be a gas or a liquid.
- the gas can for instance be hydrogen chloride or steam.
- the temperature of the gas is lower than the temperature of the liquid medium.
- the fluid is preferably a liquid.
- the liquid can be selected from a cold condensate arising from the treatment of the vapour phase in equilibrium with the liquid medium in a distillation, evaporation or stripping column, or selected from glycerol, water, an aqueous solution of hydrogen chloride, dichloropropanol, monochloropropanediol and mixtures thereof.
- cold condensate one intends to denote a condensate which temperature is lower than the temperature of the vapour phase in equilibrium with the liquid medium.
- the temperature of the cooling fluid is adjusted to obtain the inner wall temperature mentioned above.
- the temperature of the inner wall of the vessel which is above the level of the liquid medium in the vessel is at a temperature at least 1 0 C higher than the dew temperature of the vapour above the liquid medium, preferably at least 3 0 C higher, more preferably at least 5 0 C higher and most preferably at least 10 0 C higher.
- the inner wall of the vessel which is above the level of the liquid medium in the vessel is heated up by means of an external heating system.
- That system can be for instance a heating fluid circulating between the inner and outer wall (double- walled conventional jacket) of the part of the vessel which is above the level of the liquid medium in the vessel or a heating fluid circulating in a serpentine welded to the vessel wall or connected by a thermally conductive cement or in a semi- shell tube (half-pipe jacket) in contact with the outer wall of the vessel which is above the level of the liquid medium in the vessel or by flushing a heating fluid on the outer wall of the vessel which is above the level of the liquid medium in the vessel.
- the heating of the part of the vessel which is above the level of the liquid medium in the vessel can also be carried out by using electric tracing or by radiation, such as electro-magnetic radiations like for instance Infra Red radiations.
- a heating fluid When a heating fluid is used, it can be a gas or a liquid.
- a double- walled envelope or a serpentine or a semi-shell system is used for the external heating, it is preferred to use a liquid.
- the liquid can be an organic, an inorganic liquid or a mixture thereof. An inorganic liquid is preferred, pressurized water being most preferred.
- the heating is carried out by flushing a heating fluid, the fluid is preferably a hot gas.
- hot gas one intends to denote a gas with a temperature is higher than the temperature of the liquid medium.
- the gas can be nitrogen, air or steam. Steam is more preferred. Steam with a pressure lower than 10 absolute bar is the most preferred.
- the internal wall of the vessel which is above the level of the liquid medium in the vessel is heated up by means of an internal heating system and a thermally insulating device can optionally be placed on the external wall of the vessel which is above the level of the liquid medium.
- the internal heating is carried out by flushing a heating fluid on the inner wall.
- heating fluid By heating fluid, one intends to denote a fluid with a temperature higher than the temperature of the liquid medium.
- the fluid can for instance be nitrogen, steam, hydrogen chloride or low boiling compounds produced by the reaction between glycerol and hydrogen chloride like for instance dichloropropanol, or mixture thereof.
- the gas can be introduced in the vessel by any suitable way, like for instance above the level of the liquid medium in the vessel in such a way that a helicoidal stream of gas is produced above that level.
- the temperature of the heating fluid is adjusted to obtain the inner wall temperature mentioned above.
- Insulating material can be made of inorganic material like perlite, of organic material or mixture thereof.
- the inner wall of the vessel which is above the level of the liquid medium in the vessel is trickled with a liquid.
- the liquid can be selected from a cold condensate arising from the treatment of the vapour phase in equilibrium with the liquid medium in a distillation, evaporation or stripping column, or selected from glycerol, water, an aqueous solution of hydrogen chloride, dichloropropanol and monochloropropanediol, and mixtures thereof.
- cold condensate one intends to denote a condensate which temperature is lower than the temperature of the vapour phase in equilibrium with the liquid medium.
- the liquid can be selected from another part of the process with a low concentration of hydrogen chloride.
- the inner wall of the vessel which is above the level of the liquid medium in the vessel can be heated and trickled with a liquid.
- the lower part generally extends from the level of the liquid medium in the vessel to 0.1 m above that level.
- the upper part generally extends from 0.5 m above the level of the liquid medium to the top of the vessel.
- the inner wall of the vessel which is above the level of the liquid medium in the vessel can be cooled and trickled with a liquid.
- Example 1 (not according to the invention)
- Example 2 When contacted with a water-hydrogen chloride liquid mixture containing 20 % by weight of hydrogen chloride at 12O 0 C, an enamelled-lined steel sample exhibits a corrosion rate of 0.035 mm/year.
- Example 2 (according to the invention)
- an enamelled-lined steel sample When contacted with a water-hydrogen chloride liquid mixture containing 20 % by weight of hydrogen chloride at 5O 0 C, an enamelled-lined steel sample exhibits a corrosion rate of less than 0.010 mm/year.
Abstract
Description
Claims
Priority Applications (10)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020087010970A KR101434680B1 (en) | 2005-11-08 | 2006-11-08 | Process for the manufacture of dichloropropanol by chlorination of glycerol |
EA200801285A EA200801285A1 (en) | 2005-11-08 | 2006-11-08 | METHOD OF MANUFACTURE OF DICHLORPROPANOL BY CHLORINATING GLYCERIN |
MX2008005827A MX2008005827A (en) | 2005-11-08 | 2006-11-08 | Process for the manufacture of dichloropropanol by chlorination of glycerol. |
CN2006800006745A CN101068761B (en) | 2005-11-08 | 2006-11-08 | Process for the manufacture of dichloropropanol by chlorination of glycerol |
JP2008539426A JP5576045B2 (en) | 2005-11-08 | 2006-11-08 | Process for producing dichloropropanol by chlorination of glycerol |
CA002628684A CA2628684A1 (en) | 2005-11-08 | 2006-11-08 | Process for the manufacture of dichloropropanol by chlorination of glycerol |
EP06829952A EP1948583A2 (en) | 2005-11-08 | 2006-11-08 | Process for the manufacture of dichloropropanol by chlorination of glycerol |
US12/092,178 US7939696B2 (en) | 2005-11-08 | 2006-11-08 | Process for the manufacture of dichloropropanol by chlorination of glycerol |
BRPI0618325-5A BRPI0618325A2 (en) | 2005-11-08 | 2006-11-08 | process stop dichloropropanol production |
US13/051,007 US8106246B2 (en) | 2005-11-08 | 2011-03-18 | Process for the manufacture of dichloropropanol by chlorination of glycerol |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US73463705P | 2005-11-08 | 2005-11-08 | |
US60/734,637 | 2005-11-08 |
Related Child Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US12/092,178 A-371-Of-International US7939696B2 (en) | 2005-11-08 | 2006-11-08 | Process for the manufacture of dichloropropanol by chlorination of glycerol |
US13/051,007 Continuation US8106246B2 (en) | 2005-11-08 | 2011-03-18 | Process for the manufacture of dichloropropanol by chlorination of glycerol |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2007054505A2 true WO2007054505A2 (en) | 2007-05-18 |
WO2007054505A3 WO2007054505A3 (en) | 2007-07-26 |
Family
ID=37998379
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2006/068208 WO2007054505A2 (en) | 2005-11-08 | 2006-11-08 | Process for the manufacture of dichloropropanol by chlorination of glycerol |
Country Status (13)
Country | Link |
---|---|
US (2) | US7939696B2 (en) |
EP (1) | EP1948583A2 (en) |
JP (1) | JP5576045B2 (en) |
KR (1) | KR101434680B1 (en) |
CN (4) | CN102219644B (en) |
AR (1) | AR057255A1 (en) |
BR (1) | BRPI0618325A2 (en) |
CA (1) | CA2628684A1 (en) |
EA (1) | EA200801285A1 (en) |
MX (1) | MX2008005827A (en) |
TW (1) | TWI318622B (en) |
WO (1) | WO2007054505A2 (en) |
ZA (1) | ZA200803774B (en) |
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WO2008128011A2 (en) * | 2007-04-12 | 2008-10-23 | Dow Global Technologies Inc. | Conversion of a multihydroxylated-aliphatic hydrocarbon or ester thereof to a chlorohydrin |
WO2009075402A1 (en) * | 2007-12-12 | 2009-06-18 | Samsung Fine Chemicals Co., Ltd. | Method of preparing dichloropropanol from glycerol using heteropolyacid catalysts |
WO2009151175A1 (en) * | 2008-06-11 | 2009-12-17 | Samsung Fine Chemicals Co., Ltd. | Method of preparing dichloropropanol from glycerol in the presence of heteropolyacid catalyst and/or absorbent under solvent-free conditions |
JP2010529301A (en) * | 2007-06-12 | 2010-08-26 | ソルヴェイ(ソシエテ アノニム) | Aqueous composition containing salt, process and use |
WO2010102368A1 (en) * | 2009-03-11 | 2010-09-16 | Ima Quimica S.A. | Method for preparing dichloropropanols |
JP2011502032A (en) * | 2007-10-02 | 2011-01-20 | ソルヴェイ(ソシエテ アノニム) | Use of silicon-containing compositions to improve the corrosion resistance of containers |
US7939696B2 (en) | 2005-11-08 | 2011-05-10 | Solvay Societe Anonyme | Process for the manufacture of dichloropropanol by chlorination of glycerol |
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WO2012016872A1 (en) | 2010-08-02 | 2012-02-09 | Solvay Sa | Electrolysis process |
US8124814B2 (en) | 2006-06-14 | 2012-02-28 | Solvay (Societe Anonyme) | Crude glycerol-based product, process for its purification and its use in the manufacture of dichloropropanol |
WO2012025468A1 (en) | 2010-08-27 | 2012-03-01 | Solvay Sa | Brine purification process |
WO2012041816A1 (en) | 2010-09-30 | 2012-04-05 | Solvay Sa | Derivative of epichlorohydrin of natural origin |
WO2012056005A1 (en) | 2010-10-29 | 2012-05-03 | Solvay Sa | Process for manufacturing epichlorohydrin |
US8258350B2 (en) | 2007-03-07 | 2012-09-04 | Solvay (Societe Anonyme) | Process for the manufacture of dichloropropanol |
US8273923B2 (en) | 2007-06-01 | 2012-09-25 | Solvay (Societe Anonyme) | Process for manufacturing a chlorohydrin |
US8314205B2 (en) | 2007-12-17 | 2012-11-20 | Solvay (Societe Anonyme) | Glycerol-based product, process for obtaining same and use thereof in the manufacturing of dichloropropanol |
US8378130B2 (en) | 2007-06-12 | 2013-02-19 | Solvay (Societe Anonyme) | Product containing epichlorohydrin, its preparation and its use in various applications |
US8415509B2 (en) | 2003-11-20 | 2013-04-09 | Solvay (Societe Anonyme) | Process for producing dichloropropanol from glycerol, the glycerol coming eventually from the conversion of animal fats in the manufacture of biodiesel |
US8471074B2 (en) | 2007-03-14 | 2013-06-25 | Solvay (Societe Anonyme) | Process for the manufacture of dichloropropanol |
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US8507643B2 (en) | 2008-04-03 | 2013-08-13 | Solvay S.A. | Composition comprising glycerol, process for obtaining same and use thereof in the manufacture of dichloropropanol |
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US8795536B2 (en) | 2008-01-31 | 2014-08-05 | Solvay (Societe Anonyme) | Process for degrading organic substances in an aqueous composition |
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US9850190B2 (en) | 2015-12-18 | 2017-12-26 | Chang Chun Plastics Co., Ltd. | Process for preparing dichloropropanol |
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TWI321129B (en) * | 2005-05-20 | 2010-03-01 | Solvay | Process for preparing a chlorohydrin |
KR20080036555A (en) * | 2005-05-20 | 2008-04-28 | 솔베이(소시에떼아노님) | Method for making an epoxy starting from a chlorhydrine |
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KR101434680B1 (en) | 2014-08-26 |
CN101068761B (en) | 2011-11-23 |
CN102219644B (en) | 2013-11-06 |
CN102219644A (en) | 2011-10-19 |
US20110172449A1 (en) | 2011-07-14 |
US20080281132A1 (en) | 2008-11-13 |
ZA200803774B (en) | 2009-09-30 |
US7939696B2 (en) | 2011-05-10 |
CA2628684A1 (en) | 2007-05-18 |
BRPI0618325A2 (en) | 2011-08-23 |
EP1948583A2 (en) | 2008-07-30 |
TWI318622B (en) | 2009-12-21 |
CN102249858A (en) | 2011-11-23 |
MX2008005827A (en) | 2009-03-02 |
US8106246B2 (en) | 2012-01-31 |
JP5576045B2 (en) | 2014-08-20 |
TW200714577A (en) | 2007-04-16 |
CN102249859A (en) | 2011-11-23 |
JP2009514934A (en) | 2009-04-09 |
WO2007054505A3 (en) | 2007-07-26 |
CN101068761A (en) | 2007-11-07 |
AR057255A1 (en) | 2007-11-28 |
KR20080066777A (en) | 2008-07-16 |
EA200801285A1 (en) | 2009-02-27 |
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