WO2007047527A2 - Direct melt processing of resins into animal chews - Google Patents

Direct melt processing of resins into animal chews Download PDF

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Publication number
WO2007047527A2
WO2007047527A2 PCT/US2006/040240 US2006040240W WO2007047527A2 WO 2007047527 A2 WO2007047527 A2 WO 2007047527A2 US 2006040240 W US2006040240 W US 2006040240W WO 2007047527 A2 WO2007047527 A2 WO 2007047527A2
Authority
WO
WIPO (PCT)
Prior art keywords
resin
injection molding
screw
flight
resin comprises
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2006/040240
Other languages
English (en)
French (fr)
Other versions
WO2007047527A3 (en
Inventor
Glen S. Axelrod
Ajay Gajria
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
TFH Publications Inc
Original Assignee
TFH Publications Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by TFH Publications Inc filed Critical TFH Publications Inc
Priority to CN2006800444453A priority Critical patent/CN101316523B/zh
Priority to JP2008535750A priority patent/JP5202321B2/ja
Priority to CA2625973A priority patent/CA2625973C/en
Priority to EP06816938.2A priority patent/EP1945050B1/en
Publication of WO2007047527A2 publication Critical patent/WO2007047527A2/en
Publication of WO2007047527A3 publication Critical patent/WO2007047527A3/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01KANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
    • A01K15/00Devices for taming animals, e.g. nose-rings or hobbles; Devices for overturning animals in general; Training or exercising equipment; Covering boxes
    • A01K15/02Training or exercising equipment, e.g. mazes or labyrinths for animals ; Electric shock devices; Toys specially adapted for animals
    • A01K15/025Toys specially adapted for animals
    • A01K15/026Chewable toys, e.g. for dental care of pets
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23KFODDER
    • A23K20/00Accessory food factors for animal feeding-stuffs
    • A23K20/10Organic substances
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23KFODDER
    • A23K20/00Accessory food factors for animal feeding-stuffs
    • A23K20/10Organic substances
    • A23K20/163Sugars; Polysaccharides
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23KFODDER
    • A23K40/00Shaping or working-up of animal feeding-stuffs
    • A23K40/20Shaping or working-up of animal feeding-stuffs by moulding, e.g. making cakes or briquettes
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23KFODDER
    • A23K50/00Feeding-stuffs specially adapted for particular animals
    • A23K50/40Feeding-stuffs specially adapted for particular animals for carnivorous animals, e.g. cats or dogs
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23KFODDER
    • A23K50/00Feeding-stuffs specially adapted for particular animals
    • A23K50/40Feeding-stuffs specially adapted for particular animals for carnivorous animals, e.g. cats or dogs
    • A23K50/42Dry feed
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23PSHAPING OR WORKING OF FOODSTUFFS, NOT FULLY COVERED BY A SINGLE OTHER SUBCLASS
    • A23P30/00Shaping or working of foodstuffs characterised by the process or apparatus
    • A23P30/10Moulding
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23PSHAPING OR WORKING OF FOODSTUFFS, NOT FULLY COVERED BY A SINGLE OTHER SUBCLASS
    • A23P30/00Shaping or working of foodstuffs characterised by the process or apparatus
    • A23P30/20Extruding
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S426/00Food or edible material: processes, compositions, and products
    • Y10S426/805Pet food for dog, cat, bird, or fish

Definitions

  • the present invention relates to the formation of an animal chew composition. More particularly, the present invention is directed at direct injection molding of resins as well as a modified screw design utilized in melt processing of resins suitable for forming an animal chew, such as an edible dog chew.
  • An aspect of the present invention relates to a method for direct injection molding an animal chew using a modified screw.
  • the invention relates to the introduction of resin into an injection molding machine including a modified screw, where the modified screw includes a transition zone having a first length Ll and a feed zone having a second length L2, wherein Ll > 0.5*L2 and forming the resin into an animal chew.
  • the modified screw and/or barrel of the injection molding machine may be coated, which may impart a surface finish value "Ra" greater than 5 micro-inches.
  • the modified screw may also include at least two flights on all or a portion of the screw.
  • Another aspect of the present invention relates to a method for direct injection molding an animal chew which has a particle size of less than about 2000 microns.
  • the particles may also exhibit a particle size distribution and have a bulk density of between 30- 50 lb/cubic foot.
  • the resin may have a moisture content of between 1-20% by weight.
  • FIG. 1 is an exemplary embodiment of an injection molding machine.
  • FIG. 2 is an exemplary embodiment of a screw.
  • FIG. 3 is an exemplary embodiment of a portion of a screw including an additional flight.
  • the present invention relates to a modified screw design that may be utilized for the direct injection molding of resins suitable for forming animal chews.
  • the modified screw design may be provided to increase shear and melt mixing of the resin.
  • the resin may be an edible resin, such as starch.
  • the resin may be of a controlled particle size, and may have a controlled level of moisture, so that the resin may be formed, upon exposure to one cycle of heat, into a desired shape.
  • the resin may have a particle size distribution wherein all or a portion of the particles are less than about 2.0 millimeters (mm), or 2000 microns, including all ranges of particle size that may be below 2000 microns.
  • the resin particle size may be less than about 500 microns and any value or range between 500 microns and 1 micron, including less than 250 microns, less than 149 microns, less than 44 microns, etc. In one embodiment, approximately greater than 95% of the particles are less than 149 microns and approximately greater than 60% of the particles are less than 44 microns. In another embodiment, approximately greater than 97% of the particles are less than 250 microns, and approximately greater than 75% of the particles are less than 149 microns.
  • the resin may also have a bulk density of between 30-50 lb/cubic foot, including all increments and ranges there between such as between 40-45 lb/cubic foot, 38-40 lb/cubic foot, 35-38 lb/cubic foot, etc.
  • the resin may include any starch or carbohydrate of natural or vegetable origin.
  • the starch may include amylose and/or amylopectin and may be extracted from plants, including but not limited to potatoes, rice, tapioca, corn and cereals such as rye, wheat, and oats.
  • the starch may also be extracted from fruits, nuts and rhizomes, or arrowroot, guar gum, locust bean, arracacha, buckwheat, banana, barley, cassava, konjac, kudzu, oca, sago, sorghum, sweet potato, taro, yams, fava beans, lentils and peas.
  • the starch may be present in the resin composition between about 30-99% including all increments and values therebetween such as levels above about 50%, 85%, etc.
  • the starch employed herein may be raw starch, which may be understood as starch that has not seen a prior thermal molding history, such as extrusion or other type of melt processing step where the resin is shaped in the presence of heat.
  • the raw starch itself may also be native, which may be understood as unmodified starch recovered in the original form by extraction and not physically or chemically modified.
  • the raw starch may also be in powder form of varying particle size, as described above, which may be understood as milled and/or pre-sifted. It should be understood that the raw starch may also have varying degrees of moisture present.
  • moisture may be present in the raw starch between 1-60%, including all increments and values therebetween such as 40%, 20%, 10%, etc.
  • direct as used herein with respect to injection molding refers to the molding of resin (e.g.starch) without exposing the resin to prior thermal molding histories before injection molding.
  • the resin e.g. starch
  • the resin herein may, e.g., be heated for drying purposes, which would not amount to a prior thermal molding history.
  • the resin compositions herein may be sourced from Manildra Group USA, under the following tradenames: "GEMSTAR 100" which is a refined food grade wheat starch; “GEMSTARl 00+” which is a refined food grade wheat starch; “GEM OF THE WEST VITAL WHEAT GLUTEN” which is a powder product by low temperature drying of gluten extracted from wheat flour; “ORGANIC GEM OF THE WEST VITAL WHEAT GLUTEN” which is a powder product by low temperature drying of gluten extracted from organic wheat flour; “ORGANIC GEMSTAR 100” which is a wheat starch extracted from organic what flour; and/or “ORGANIC GEMGEL 100” which is a pregelatinized organic wheat starch
  • the resin composition may be sourced from ADM under the tradename "EDIGEL 100” which is a wheat resin composition; "AYTEX P” which is a unmodified food grade wheat starch.
  • the resin may be a thermoplastic or rubber material, such as nylon, polyurethane, polyesteramide, natural rubber, isoprene, neoprene, thermoplastic elastomers, etc.
  • Other resin materials may be contemplated that may be derived from animal sources such as casein, denatured or hydrolyzed casein, collagen, denatured or hydrolyzed collagen, rawhide, gelatin, other animal protein products, such as animal meal.
  • the resin material may also be derived from plant matter such as gluten, vegetable matter, nuts, such as nut flour, paste or bits, fruit matter, etc.
  • the resin may include cellulose.
  • the cellulose may be, for example, a long-chain polymer of polysaccharide carbohydrate.
  • the cellulose may also be derived or extracted from plants.
  • the cellulose may be incorporated into the resin composition between about 1-
  • Emulsifiers or surfactants may also be incorporated into the resin composition.
  • the emulsifier may be present between about 1-10% by weight of the resin composition and all increments or values therebetween including 3%, 4%, etc.
  • the emulsifier may include, for example, lecithin, which may be extracted or derived from, for example, egg yolk or soy beans.
  • the resin composition may also include a plasticizer.
  • the plasticizer may include for example, glycerin.
  • the plasticizer may be incorporated between about 15-30%, including all increments and values therebetween such as levels greater than 15%, 21%, 27% etc.
  • a humectant may also be incorporated into the resin composition.
  • the humectant may include, for example, oat fiber.
  • the humectant may be incorporated between about 0.1-
  • a humectant may be understood to be any additive that may absorb water in the material.
  • the resin composition may also include water.
  • the water may be introduced into the composition between about 1-40% by weight of the resin composition and any increment or value therebetween, including 4%, 20-40%, 10-20%, etc. After the product has been formed, the water may be present between 1-20% by weight of the resin composition including all increments or values therebetween, such as, below 20%, 4%, 5-10%, etc.
  • the resin composition may include a nutraceutical.
  • the nutraceutical may be ' fermented soya. Fermented soya nutraceuticals are available from Bio Food, Ltd., Pine Brook, NJ. and sold under the general trademark Soynatto®. The fermented soya is present between about 1-40% by weight of the resin composition, including all increments and values therebetween, including 10%, 20%, etc.
  • Soynatto® product is more specifically described to contain the following as compared to other available compositions:
  • the Soynatto® product may provide proteins, minerals, and vitamins, in a fermented soy form.
  • the fermentation process may infuse the product with saccharomyces cerevisiae, commonly known as "bakers yeast” or “brewers yeast.” Saccharomyces cerevisiae is more traditionally known to ferment sugars present in flour or dough, yielding carbon dioxide and alcohol. Accordingly, it should be appreciated that a protein, one or more of a mineral, and one or more of a vitamin, along with saccharomyces cerevisiae may be present in the resin composition.
  • the fermented soy product herein may include increased concentrations of glycitein, daidzein and genistein, reportedly present at several hundred percent more than other more common soyfood sources.
  • Glycitein, daidzein and genistein belong to the isoflavone class of flavanoids and may be classified as phytoestrogen, since they are plant derived nonsteriodal compounds that contain estrogen-like biological activity.
  • the direct injection molding of the fermented soy product may offer advantages with respect to the activity of the soy product in a final molded shape. Specifically, the direct injection molding provides that the fermented soy product is not substantially degraded and the nutritional value of the fermented soy product remains substantially unchanged.
  • the resin composition may also include enzymes and/or co-enzymes which are similarly available through Bio Foods, Ltd., Pine Brook, NJ. and sold under the trademark of BT-CoQl 0®. This reportedly is a biologically transformed (fermented) cell mitochondrial coenzyme and contains Coenzyme QlO, antioxidants, phytonetrients and cofactor mineral nutrients and other cell constituents.
  • the enzymes and/or co-enzymes may be present between 0.1-10% by weight of the resin composition, including all increments and values therebetween such as 1%, 5%, etc.
  • the coenzyme QlO is a fat-soluble compound primarily synthesized by the body and also consumed in the diet and is required for mitochondrial ATP synthesis.
  • the fermented coenzyme also reportedly belongs to the family of compounds known as ubiquinones, which are either of two isomeric cyclic crystalline compounds C 6 H 4 O 2 that are di-keto derivatives of dihydro-benzene. It may also function as an antioxidant in cell membranes and lipoproteins.
  • additives may be introduced into the composition as well. These additives may include vegetable matter, fruit matter, rawhide, nuts, nut bits or nut flour such as peanut flour, and animal or fish products, by-products, meal or digests, etc.
  • Glutens may also be incorporated into the resin composition. Gluten may be understood as water-insoluble protein complex extracted from cereal grains such as maize or corn and wheat. These additives may be present individually or cumulatively between about 0.1-50% by weight of the resin composition and all increments and values therebetween including 0.1-5.0%, 15%,
  • Yeast products may include nutritional yeast or brewers yeast such as saccharomyces cerevisiae, dairy yeast such as kluyveromyce marxianus or wine yeast such as saccharomyces fermentati.
  • the soy products may include fermented soy or other soy products, as listed in the table above.
  • Attractants may include compounds listed herein, such as the animal or fish digests, or other compounds that may increase an animal's interest in the resin composition.
  • additives may be present individually or cumulatively between about 0.01-25% by weight of the resin composition and any increment or value therebetween including 0.01- 0.5%, 10%, 20%, etc.
  • the composition may also include calcium carbonate.
  • the calcium carbonate may be present between about 5-10%.
  • the additives of the resin composition may be introduced directly into the barrel of an injection molding machine 100, illustrated in FIG. 1, through a hopper or other feeding device 102.
  • Various feeding devices for introducing the additives into the injection molding barrel may be contemplated including loss-in weight gravimetric blenders/feeders, auger feeders, venturi loaders, etc.
  • an injection molding machine 100 typically contains a barrel 104 including a feed section 106, a screw 108 and an output nozzle 110.
  • the barrel 104 may include a plurality of temperature control zones 112, 114, 116, 118 in the barrel extending from the feed section 106 section to the nozzle 110.
  • the injection molding machine may include a mold 120 having one or more cavities 122.
  • the molding machine may also be vented, including a vented barrel and/or a vented mold.
  • the molding machine barrel may include 4 zones, zone 1 112 being the closest to the feed section 106 and zone 4 118 being the closest to the nozzle 110.
  • Zone 1 112 may be set to less than about 150 degrees F, including any increment or value between about 35 to 150 degrees F including between about 46 to 150 degrees F, 46 to 70 degrees F, etc.
  • zone 2 114 may be set between about 70 to 150 degrees F including any increment or value therebetween, zone 3 116 between about 50 to 300 degrees F including any increment or value therebetween, and zone 4 118 between about 200 to 375 degrees F including any increment or value therebetween.
  • the nozzle 110 may be set between about 250 to 390 degrees F including any increment or value therebetween.
  • the bushing 124 inside of the mold 120 may be set between about 250 to 425 degrees F including any increment or value therebetween and the mold 120 may also be set between about 35 to 65 degrees F including any increment or value therebetween.
  • the resin and additives may be blended as the screw 108 conveys the material towards the mold 120 where the resin composition may be formed.
  • the mold 120 may cool the resin composition.
  • the resin composition may include water between about 1- 20% by weight of the resin composition, including all increments and values therebetween such as 10%, 15%, etc.
  • the resin composition may be molded into any form capable of being produced in an injection molding cavity.
  • the design of the screw 108 may also be varied to provide greater thermal and/or mechanical interaction with the resin composition.
  • the screw may impart increased shear stress on the material.
  • the screw 108 may include a number of zones which extend along the length L of the screw.
  • the screw may include a feed zone 210, a transition zone 212 and a metering zone 214.
  • the feed zone 210 may be proximate to the hopper or other feeding device 102 in the barrel 104 and the metering zone may be proximate to the nozzle 110.
  • the feed zone therefore may function to convey solid material away from the feed section 106.
  • the length of the feed zone 210, the transition zone 212 and the metering zone 214 may be adjusted while maintaining the overall length L of the screw at the same size.
  • the length of the feed zone 210 maybe decreased and the length of the transition zone and/or the metering zone 212, 214 may be increased.
  • the screw therefore may include a transition zone having a first length Ll and a feed zone having a second length L2, wherein Ll > f*L2.
  • the metering zone may similarly have a length L3 wherein L3> f*L2.
  • the value of "f ' may be 0.5 and greater, such 0.6, 0.7 up to 10.0, including all incremental values therebetween.
  • Solids conveying in the screw may be improved by increasing the surface roughness of the internal barrel surface or the root surface of the screw.
  • the increased roughness may cause an increase in the coefficient of friction between the resin composition and the barrel wall.
  • Increasing the roughness may be accomplished by coating the surface of the screw and/or barrel wall.
  • the surface roughness may have an Ra value of greater than about 5 micro-inches, including all ranges and increments above such as 9, 30, 42 etc.
  • the variable "Ra" is an arithmetic mean and represents the average of all peaks and valleys. Lower numbers indicate a smoother finish.
  • the screw 108 may also include one or more flights 216 wrapping helically around the axis ⁇ of the screw (shown in phantom) extending from the feed zone 210 to the metering zone 214.
  • the flight 216 may define a plurality of channels 218.
  • the screw 108 includes an outer diameter OD, defined by the surface of the flight and a root diameter RD defined by the channels forming the root of the screw.
  • the channel depth CD is the distance between the top of a flight to the screw root.
  • Either the outer diameter or the inner diameter may vary along the length of the screw. Stated another way, there may be a consistent reduction or increase in either the outer diameter OD or the root diameter RD of the screw.
  • the screw may have a flighted length to diameter ratio of between 10:1 to 40:1.
  • the flighted length of the screw FL is a general reference to the length of the screw incorporating a flight (or flights), illustrated in FIG. 2a.
  • the diameter refers to the outer diameter of the screw OD (referring back to FIG. 2b).
  • the flight may also have a helix angle ⁇ of approximately 15.0 - 20.0 degrees, illustrated in FIG. 2b.
  • the compression ratio of the screw may also be increased.
  • the compression ratio is a reference to the difference in channel depth between the feed zone and metering zone of the screw.
  • the compression ratio may be greater than about 2:1, including all increments and values above such as 3.5:1, 4:1 etc.
  • the screw may include barrier flights and other mixing heads or flights.
  • a barrier zone 310 is a reference herein to a portion of the screw having more than one flight, such as a main flight 312 and a barrier flight 314, as illustrated in FIG. 3.
  • the main flight and the barrier flight may wrap around the screw concurrently.
  • the barrier flight may have a varying pitch P or the pitch may be similar to the main flight.
  • Pitch P is a general reference to the axial distance between two points on the flight separated by a full turn of the screw.
  • the pitch Pb of the barrier flight may be greater than the pitch of the main flight Pm, wherein Pb > d*Pm, where d is greater than or about 1.01, including any increment or value above, such as 1.1, 1.5 etc.
  • the barrier flight may be undercut and have a smaller outer diameter OD b than the main flight allowing polymer melt to pass from one channel to the other. The solids may not pass over the flight until they are small enough or have been completely melted.
  • the barrier flight ODb may be less than the diameter of the main flight OD. Accordingly, the ODb may be equal to x*OD wherein x is 0.5 - 0.99. Furthermore, the ODb may be equal to the OD of the main flight.
  • the channel depth CD of the barrier flight may also be the same as the main flight or may differ from the main flight. For example, the channel depth of the barrier flight may be greater than the channel depth of the main flight or the channel depth may increase or decrease along the length of the screw.
  • the barrier zone may extend the entire flighted length (FL illustrated in FIG. 2) of the screw or may extend along a portion of the screw, such as along the length of one or two of the zones, or along only a portion of a single zone.
  • Mixing heads, zones or flights may include dispersive mixing elements and distributive mixing elements.
  • Dispersive mixing elements may be used to decrease agglomerates or gels.
  • the mixing element may be fluted or splined.
  • the splines or flutes may be arranged parallel, perpendicular or at an angle to the longitudinal screw axis ⁇ .
  • the element may also be in the form of a blister ring.
  • Distributive mixing elements may be used to disrupt the velocity profiles of the material in the barrel. Pins of various sizes and geometries or small lands may be arranged radially about the axis of the screw including pin mixing sections or pineapple mixing sections. Slotted channels or narrow channels may also be employed or a cavity transfer mixing section. These elements may be used alone or in combination to provide adequate mixing of the polymer composition prior to exiting the barrel and entering the mold. The foregoing description is provided to illustrate and explain the present invention.

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Zoology (AREA)
  • Animal Husbandry (AREA)
  • Health & Medical Sciences (AREA)
  • Birds (AREA)
  • Environmental Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Physical Education & Sports Medicine (AREA)
  • Animal Behavior & Ethology (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Injection Moulding Of Plastics Or The Like (AREA)
  • Biological Depolymerization Polymers (AREA)
PCT/US2006/040240 2005-10-14 2006-10-12 Direct melt processing of resins into animal chews Ceased WO2007047527A2 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
CN2006800444453A CN101316523B (zh) 2005-10-14 2006-10-12 树脂直接熔体加工成动物咀嚼物
JP2008535750A JP5202321B2 (ja) 2005-10-14 2006-10-12 樹脂の直接溶融方法
CA2625973A CA2625973C (en) 2005-10-14 2006-10-12 Direct melt processing of resins
EP06816938.2A EP1945050B1 (en) 2005-10-14 2006-10-12 Direct melt processing of resins for animal chews

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11/251,261 2005-10-14
US11/251,261 US8227007B2 (en) 2005-08-05 2005-10-14 Direct melt processing of resins

Publications (2)

Publication Number Publication Date
WO2007047527A2 true WO2007047527A2 (en) 2007-04-26
WO2007047527A3 WO2007047527A3 (en) 2007-06-21

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2006/040240 Ceased WO2007047527A2 (en) 2005-10-14 2006-10-12 Direct melt processing of resins into animal chews

Country Status (6)

Country Link
US (1) US8227007B2 (enExample)
EP (1) EP1945050B1 (enExample)
JP (1) JP5202321B2 (enExample)
CN (1) CN101316523B (enExample)
CA (1) CA2625973C (enExample)
WO (1) WO2007047527A2 (enExample)

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US20080206405A1 (en) * 2007-02-22 2008-08-28 T.F.H. Publications, Inc. Pet Treat Containing Organic Nutrients
US8257775B2 (en) * 2007-03-20 2012-09-04 T.F.H. Publications, Inc. Molded products based upon textured vegetable protein
US20090151649A1 (en) * 2007-12-14 2009-06-18 Summit Applied Technologies, Inc. Chewable animal toy
EP3081265A1 (en) 2012-04-17 2016-10-19 Big Heart Pet Brands Appetizing and dentally efficacious animal chews
US20160236385A1 (en) * 2015-02-12 2016-08-18 T.F.H Publications, Inc. Injection molded pet chew article
BR112018007861B1 (pt) * 2015-10-28 2022-11-01 Intercontinental Great Brands Llc Método para preparar uma composição encapsulada para uso em uma composição comestível
AU2019337661B2 (en) * 2018-09-14 2022-10-20 T.F.H. Publications, Inc. Composition and method for forming multilayer edible pet product

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JP2009511065A (ja) 2009-03-19
JP5202321B2 (ja) 2013-06-05
EP1945050B1 (en) 2017-01-04
CN101316523B (zh) 2013-05-15
CA2625973A1 (en) 2007-04-26
EP1945050A4 (en) 2013-11-06
US20070031556A1 (en) 2007-02-08
CA2625973C (en) 2013-12-17
EP1945050A2 (en) 2008-07-23
CN101316523A (zh) 2008-12-03
WO2007047527A3 (en) 2007-06-21

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