WO2007014489A1 - A pyrolysis method for treating waste rubber and plastics and materials containing resins - Google Patents

A pyrolysis method for treating waste rubber and plastics and materials containing resins Download PDF

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Publication number
WO2007014489A1
WO2007014489A1 PCT/CN2005/001181 CN2005001181W WO2007014489A1 WO 2007014489 A1 WO2007014489 A1 WO 2007014489A1 CN 2005001181 W CN2005001181 W CN 2005001181W WO 2007014489 A1 WO2007014489 A1 WO 2007014489A1
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WO
WIPO (PCT)
Prior art keywords
cracking
gas
slag
chamber
door
Prior art date
Application number
PCT/CN2005/001181
Other languages
French (fr)
Chinese (zh)
Inventor
Weitian Zhang
Original Assignee
Weitian Zhang
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Weitian Zhang filed Critical Weitian Zhang
Priority to PCT/CN2005/001181 priority Critical patent/WO2007014489A1/en
Publication of WO2007014489A1 publication Critical patent/WO2007014489A1/en

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/02Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment
    • F23G5/027Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment pyrolising or gasifying stage
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • C10B53/07Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of solid raw materials consisting of synthetic polymeric materials, e.g. tyres
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/10Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal from rubber or rubber waste
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/02Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment
    • F23G5/033Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment comminuting or crushing
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G7/00Incinerators or other apparatus for consuming industrial waste, e.g. chemicals
    • F23G7/12Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of plastics, e.g. rubber
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J15/00Arrangements of devices for treating smoke or fumes
    • F23J15/02Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2219/00Treatment devices
    • F23J2219/70Condensing contaminants with coolers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/141Feedstock
    • Y02P20/143Feedstock the feedstock being recycled material, e.g. plastics

Definitions

  • the invention relates to a waste rubber and plastic product and a cracking treatment method comprising the resin component product, which can completely crack the waste rubber product, the waste plastic product and the waste product containing the resin component, and carry out harmless treatment, and is beneficial. Conversion of raw materials.
  • 99212437. 9 discloses a dry distillation gasification incinerator, in particular, a dry distillation capable of completely burning high calorific wastes such as waste plastics and waste tires, and capable of effectively suppressing generation of harmful substances such as dioxins. Gasification incinerator.
  • the main technical feature is that the dry distillation gas discharge port of the primary combustion chamber is connected to the secondary combustion chamber through the gas introduction pipe, and the combustion air is mixed into the flowing dry distillation gas in the gas introduction pipe, and the combustion air mixing portion is flown upward.
  • this patent does not purify the dry distillation gas, and does not comprehensively utilize the residue generated after combustion, which wastes resources and pollutes the environment twice. Therefore, it is necessary to propose a new waste rubber and plastic product and a cracking treatment method containing the resin component product.
  • the object of the present invention is to provide a waste rubber and plastic product and a cracking treatment method comprising the resin component, which can disintegrate waste rubber products, waste plastic products, and waste products containing resin components in a cracking from the external environment.
  • the indoor is completely cracked, and the harmless treatment is carried out to carry out beneficial raw material conversion, and the energy consumption is small and the treatment amount is large.
  • a waste rubber and plastic product and a cracking treatment method comprising the resin component product, which is subjected to a cracking treatment using a cracking furnace, wherein the cracking furnace body is provided with a plurality of cracking chambers, Each of the cracking chambers is provided with a heating fire wall parallel thereto, and each of the heating fire walls is provided with a plurality of fire chamber type combustion chambers, and a plurality of regenerators are disposed at a lower portion of the cracking furnace body, and the regenerators are disposed
  • the top portion is in communication with the bottom of the fire tunnel type combustion chamber through a two-way air passage; the fire tunnel type bottom of the combustion chamber a gas injection port is arranged at the top; a charging port and a cracking gas collecting port are arranged at the top of the cracking chamber, a gas collecting device is arranged at an upper portion of the cracking gas collecting port, and a sealed furnace door is arranged at both ends of the cracking chamber;
  • the material port is simultaneously discharged to the cracking chamber on the cracking furnace body; the gas pipeline is mixed with gas and air to be combusted, and the hot air heated by the regenerator reaches the combustion chamber to be combusted with the gas, and the heat of combustion is transmitted to the cracking chamber through the heated fire wall,
  • the temperature of the cracking chamber is kept at 600 ° C - 140 (TC, the material inside is cracked; the air introducing system is started, the cracked gas after guiding cooling enters the oil and gas recovery and separation device, and the cracked gas is separated into fuel oil by the oil and gas recovery and separation device
  • combustible gas oil and gas separators, condensers, oil-water separators can be installed in the oil and gas recovery and separation device; the separated combustible gas can be connected to the natural gas cabinet, and then
  • the gas pipeline is supplied to the combustion chamber for use; the flue gas generated by the combustion passes through the ventilation controller and the branch flue to enter the chimney; after the cracking of the material in the crack
  • the invention has the following advantages:
  • the flue gas of the invention is stored in a regenerator for heat storage, has high heat utilization rate and low energy consumption.
  • the processing capacity of the invention is large, and the annual processing capacity ranges from 100,000 tons to 2 million tons, and the investment is small and the efficiency is high.
  • the waste treatment scope of the invention is large, and can treat waste plastics, waste rubber, waste engineering plastics, resin waste Japanese products and other organic substances.
  • the cracking furnace of the invention has good temperature adjustment, and the temperature range is 600 ° C - 1400 ° C, which can be conveniently adjusted with different cracking products.
  • the cracking furnace of the invention has a high recovery rate, and all the waste is recovered and converted into market shortage resources such as fuel oil, combustible gas, carbon black and scrap steel.
  • the cracking furnace of the invention can achieve zero discharge without environmental pollution.
  • the cracking gas of the present invention is cooled by ammonia water or cooled by water, and the cooling effect is good.
  • FIG. 2 is a schematic view showing the structure of the cracking furnace body of the present invention (Fig. 3E-E sectional view)
  • Figure 4 is a cross-sectional view of the regenerator of the present invention (Fig. 2B-B is a cross-sectional view)
  • Figure 5 is a cross-sectional view of the cracking furnace body of the present invention (Fig. 2C - C sectional view)
  • FIG. 9 Schematic diagram of the ventilation controller of the present invention
  • Figure 10 is a schematic view of the structure of the furnace door of the present invention.
  • Figure 11 is a cross-sectional view of the furnace door of the present invention (Figure 10H ⁇ -H sectional view)
  • Figure 12 is a schematic view of the slag-carrying vehicle structure of the present invention
  • Figure 13 is a schematic view showing the structure of the transport truck of the present invention.
  • FIG. 14 Schematic diagram of the structure of the slag pushing truck of the present invention
  • Figure 15 is a schematic view showing the structure of the hanging door device of the present invention
  • Figure 16 is a schematic view showing the structure of the loading vehicle of the present invention.
  • Figure 18 is a schematic view of another embodiment of the present invention.
  • the present invention uses a cracking furnace for cracking treatment, and uses a pulverizing device in the waste rubber and plastics workshop 1 to pulverize the scrap 2, magnetically select 3, and then feed it into the silo 4; magnetically selected scrap steel 14 is fed into the waste; in this embodiment, the waste can be directly sent to the silo without pulverization and magnetic separation.
  • the charging port 6 is used to open the charging port cover on the cracking furnace, and the plurality of charging ports are simultaneously distributed to the cracking chamber on the cracking furnace 5;
  • the gas pipe is connected to the gas (combustible gas) and mixed with the air to be heated, and the temperature is raised by the regenerator After the hot air reaches the combustion chamber and the gas is burned, the heat of combustion is transferred to the cracking chamber through the refractory material (heating the fire wall), and the temperature of the cracking chamber is maintained at 600 ° C - 1400 ° C (the temperature of the cracking chamber can be 600 ° C - Arbitrarily regulated in the range of 1400 °C), the material in the air is cracked; the induced draft fan 10 in the air intake system is started, and the cooled cracked gas is introduced into the oil and gas recovery and separation device, and the cracked gas is separated into fuel oil by the oil and gas recovery and separation device.
  • oil and gas recovery and separation device can be provided with oil and gas separator 7, condenser 8, oil water separator 12; the separated combustible gas can be connected to the natural gas cabinet 11, and a part of the gas is supplied to the combustion chamber through the gas pipeline. Another part of the gas supply.
  • the flue gas generated by the combustion enters the chimney 19 through the ventilating controller 90 and the branch flue 18; after the material in the cracking chamber is cracked, the slag pushing cart 40 and the slag guiding cart 20 start the door picking device to pick up the door, and the slag pushing device is Pushing the residue into the slag-carrying vehicle, the slag-carrying vehicle guides the residue to the slag-carrying vehicle 30, and the slag-carrying vehicle and the slag-carrying vehicle start the furnace door pick-up device to close the furnace door on both sides of the cracking chamber, and the slag-removing vehicle will have the residue It is sent to the carbon black workshop 15, and the carbon black 16 and the scrap steel 17 are separated to complete the whole process of cracking.
  • an oil and gas recovery and separation device is set in this embodiment.
  • the device is composed of an oil separator 7, a condenser 8, and a water separator 12 .
  • the cracking gas in the gas collecting device from the cracking furnace body contains oil and water (formed by spraying water or spray cooling ammonia water), and the cracking gas is cooled by the gas collecting device and then enters the oil separator from the gas inlet port to be separated.
  • the liquid flows into the oil water separator through the liquid discharge port, and the separated gas enters the condenser through the gas outlet.
  • the condenser is a box type condenser, and the oil water separator is provided with a scraper conveyor, an oil-water mixture inlet, a water outlet, an oil outlet, a residual liquid discharge outlet, and a slag discharge port.
  • the scraper conveyor is provided with a motor, a reducer and a chain.
  • a liquid buffer plate is arranged at the inlet of the oil-water mixture to reduce the liquid impact force.
  • a partition is provided in front of the water inlet.
  • the oil outlet is provided with an overflow tank.
  • a slow release agent is selected according to different physical properties and chemical properties of the waste material, and the sustained release agent is mixed.
  • the waste material enters the cracking furnace together, and the slow release agent is mainly used to reduce the cracking speed;
  • the sustained release agent may be made of coke powder, or may be pebbles or cobblestone slag, which is made of pebbles and has a particle size of 3 - 5 cm.
  • the weight ratio of the waste to the sustained release agent is 10 to 70: 90 to 30.
  • a form of charging on the side of the furnace body may be adopted, and an electric tape unloading trolley 70 is disposed on one side of the cracking furnace body, first used.
  • the charging guide device starts the door lifting device to pick up the door, and then uses the unloading trolley to fill the charging material into the charging guiding device 80, and the charging device feeds the charging material into the cracking chamber.
  • the door picking device on the charging guide device is the same as the door picking device on the slag pushing device. Since the electric tape unloading trolley is a conventional conveying device, it will not be described in detail herein. The specific structure is described in the "Code for Construction and Acceptance of Metallurgical Machinery Installation Engineering" published in 1998.
  • a belt scraper conveyor is disposed on the side of the cracking furnace, and when the material in the cracking chamber is cracked, the pusher and the slag-starting vehicle are started.
  • the door picking device picks up the door, and the residue is introduced into the belt scraper conveyor by the slag pushing device, and the residue is transported to the carbon black workshop by the belt scraper conveyor. Since the belt scraper conveyor is a conventional conveying device, it will not be described in detail herein.
  • the belt scraper conveyor is a conventional conveying device, it will not be described in detail herein.
  • the cracking furnace used in the present invention will be described in more detail below, see Fig. 1, Fig. 2, Fig. 3, Fig. 4, Fig. 5, wherein Fig. 1 is a longitudinal section of the present invention, and Fig. 2 is a section rotated 90° clockwise.
  • Fig. 1 The cracking furnace of the present invention has a cracking furnace body 5, and a plurality of cracking chambers 501 are disposed in the upper portion of the cracking furnace body, Fig. 1 shows the length direction of the cracking chamber, and Fig. 2 shows a sectional structure of the cracking furnace body, and the cracking chamber It is composed of refractory brick masonry and has excellent sealing performance.
  • Each of the cracking chambers is provided with heating fire walls 502 parallel thereto, and each of the heating fire walls is provided with a plurality of fire tunnel type combustion chambers 505.
  • a plurality of regenerators 503 are disposed in the lower portion of the pyrolysis furnace body, and the top of the regenerator chamber is connected to the bottom of the flue-type combustion chamber through a bidirectional air passage 504; the bottom of the flue-type combustion chamber is provided with a gas nozzle;
  • the top of the cracking chamber is provided with a charging port 508 and a cracking gas collecting port 509.
  • a gas collecting device 513 is disposed at an upper portion of the cracking gas collecting port, and a sealing furnace door is disposed at both ends of the cracking chamber; a dual-purpose air collecting channel 507 is disposed at a lower portion of the heat accumulating chamber, and a gas inlet and outlet end of the dual-purpose air collecting channel is A dual-purpose manifold of a ventilating controller 90 is connected to the branching duct 18 of the venting controller.
  • the cracking chamber 501 is a place for cracking of rubber and plastic waste such as waste tires and waste plastics, and the cracking chamber is completely sealed from the external environment and sealed.
  • An extremely rigid rectangular closed chamber, the wall of the two side walls of the cracking chamber is formed by using a special-shaped refractory brick with a convex groove and a groove, and in order to facilitate the slag discharge in the cracking chamber, the cracking chamber has a one end ratio
  • the slag has a wide end and a taper of about 0° - 10°.
  • the height and length of the cracking chamber may be different depending on the ability to dispose of the waste.
  • the height of the cracking chamber may be designed to be about 2-8 meters. Can be designed to be around 13-18 meters.
  • a plurality of charging ports 508 are provided at the top of the cracking chamber.
  • the cracking chamber is provided with one or more cracking gas collecting ports 509, and the cracking gas collecting port is provided with a gas collecting device 513, which is composed of an ammonia water nozzle, a water seal, a water seal flap, and a gas pipeline.
  • the gas collecting device is connected to an oil and gas recovery and separation device through a gas pipeline, and the gas output end of the oil and gas recovery and separation device is connected to the gas nozzle at the bottom of the fire tunnel type combustion chamber through the gas pipe 506.
  • the cracked gas is cooled to within 100 ° C by spraying with ammonia, and the gas collecting means can also be cooled by water, and thus the conventional structure will not be described in detail. '
  • each of the cracking chambers is provided with a heating fire wall 502 parallel thereto, the length of the heating fire wall is the same as that of the cracking chamber, and the taper is opposite to the cracking chamber.
  • Each of the heated fire walls is provided with a plurality of fire-type combustion chambers 505, which are places where gas and hot air are mixed for combustion, and the combustion chamber is composed of two parallel vertical fire passages, two The partition wall between the tops of the vertical fire passages is provided with a spanning hole 516, and the partition wall between the bottoms of the two vertical fire passages is provided with an exhaust gas circulation hole 517, which is located at both ends of the cracking furnace body to prevent short circuit of the gas.
  • a burner is provided at the bottom of the combustion chamber, the burner includes a gas nozzle and a hot air nozzle, the gas nozzle is an outlet end of the gas pipe 506, and the hot air nozzle is an outlet end of the two-way air passage 504.
  • a gas nozzle 5061 and two hot air nozzles 5041 are provided at the bottom of each fire chamber.
  • a plurality of fire sights 512 are disposed at the top of the fire chamber type combustion chamber, and the fire sights are disposed corresponding to the gas nozzles, and the fire hole is mounted with a fire hole seat and a fire hole cover, and the inside of the combustion chamber needs to be observed. When burning, open the fire hole cover and seal the fire hole cover when you do not need to observe it.
  • a plurality of regenerators 503 are disposed in a lower portion of the pyrolysis furnace body, and the top of the regenerator chamber and the bottom of the flue-type combustion chamber are bidirectionally transferred.
  • the air passage 504 is correspondingly connected.
  • the lower portion of the regenerator is provided with a dual-purpose air collection passage 507 with a tamper brick 510.
  • the upper part of the raft brick ie, the middle portion of the regenerator
  • the heat-transmission lattice brick 511 The heat exchange area is divided into six holes and nine holes.
  • the gas passing through the regenerator is time-varying and passes during the first working period.
  • the gas in the regenerator is the combustion exhaust gas, and the gas flows from the top to the bottom.
  • the exhaust gas in the flue-type combustion chamber enters the regenerator through the bidirectional air passage at the bottom thereof, and the exhaust gas carrying the heat flows through the heat exchange grid.
  • the brick enters the dual-purpose air collection channel, and at the same time, the lattice brick is heated to store heat in the heat exchange lattice brick; in the second working period, the gas passing through the regenerator is fresh air, and the gas is from bottom to top. Flowing, fresh air enters the regenerator from the dual-purpose air collection channel.
  • the combustion chamber in the heating wall on the left side of the first cracking chamber from the left in Figure 5 is the first column, and is sorted from top to bottom;
  • the combustion chamber in the heating wall on the right side of the cracking chamber is the second column, also Sorted from top to bottom;
  • the flue gas in the combustion chamber in the first column flows in a clockwise direction
  • the flue gas in the combustion chamber in the second column flows in a counterclockwise direction.
  • the first burner in the first column of combustion chambers in Figure 5 is combusted (top-down ordering), the first gas vent 5061 operates, and the first set of hot air vents 5041 to the combustion chamber Providing fresh air, the second burner is not working, the second gas nozzle is closed, the second group of hot air nozzles are used to suck and exhaust the burned exhaust gas; the second burner in the second column is combusted (from above Down sorting), the second gas nozzle works, the second group of hot air nozzles supplies fresh air to the combustion chamber, the first burner does not work, the first gas nozzle is closed, and the first group of hot air nozzles are used for suction and exhaust Referring to Fig.
  • the first and second regenerators from the left are connected to the first group of hot air nozzles of the first row through the two-way air passage, and the regenerator flows from bottom to top.
  • Fresh air, the third from the left, four regenerators are connected to the first group of hot air nozzles in the second row through the two-way air passage, and the exhaust gas flows from top to bottom in the regenerator.
  • the third and fourth regenerators from the left are connected to the second group of hot air nozzles of the first row through the two-way air passage, and the exhaust gas flows from top to bottom in the regenerator;
  • the fifth and sixth regenerators are connected to the second group of hot air nozzles through the two-way air passage, and the fresh air is flowing from bottom to top in the regenerator;
  • the flow direction of the above gas is simultaneously changed, and this timing change is controlled by a ventilation controller 90.
  • a plurality of gas pipes 506 extend from bottom to top through a wall of the regenerator to a gas nozzle at the bottom of the vertical fire channel, and the gas pipe is divided into a single channel and Double channels, and respectively connected to a single vertical fire channel and a double vertical fire channel.
  • the gas passing through the single channel and the double channel is controlled by a hydraulic switch 5062 to realize timing exchange, and turns on to provide gas to the combustion chamber, that is, respectively supplying gas to a single vertical fire channel or to a plurality of vertical fire channels. .
  • the singular channel is turned on, the dual channel is turned off. Conversely, when the singular channel is turned off, the dual channel is turned on.
  • a partition wall 520 is provided.
  • the dice brick and the lattice brick for heat exchange are common refractory materials.
  • a plurality of regenerators are disposed in a lower portion of the cracking furnace body, and the regenerators are arranged at equal intervals in rows and columns, and the lower portion of the regenerators in each row at the same place.
  • the dual-purpose air collection passage 507 can form a complete flue gas passage, and the direction of each column corresponds to the length direction of the cracking chamber.
  • FIG. 2 shows a total of 10 regenerators.
  • a central partition wall is arranged in the middle of each row of flue gas passages (the central partition wall is consistent with the middle partition wall 520 shown in FIG. 4), and ventilation is provided at both ends of the flue gas passage.
  • Controller 90 Referring to FIG. 9, the upper part of the ventilation controller is provided with a dual-purpose air collection tube 906.
  • the dual-purpose air collection tube is provided with an air valve 901, and the dual-purpose air collection tube is connected with the dual-purpose air collection duct, and the middle of the ventilation controller
  • a valve chamber 904 is provided, which is provided with an exhaust gas hopper 902 and an exhaust gas exhausting rod 903.
  • the lower portion of the gas exchange controller is provided with a cigarette dividing pipe 905, and the branching tobacco pipe is in communication with the branching flue 18.
  • the ventilation controller is driven by a hydraulic exchange device (produced by Dalian Metallurgical Heavy Machinery Factory), and the ventilation controller renews the fresh air and the combustion exhaust gas every 10-20 minutes.
  • the air valve is closed, the exhaust gas is snoring, and the combustion exhaust gas enters the branch flue 18 through the dual-purpose air collection passage, the dual-purpose air collection tube, the valve chamber, and the cigarette separation tube.
  • the air valve is opened, the exhaust gas is closed, the fresh air enters the regenerator through the dual-purpose collector and the dual-purpose air collection passage, and the heated fresh air enters the combustion chamber through the two-way air passage to assist combustion.
  • a sealing furnace door 514 and a furnace door frame 518 are disposed at both ends of the cracking chamber, and the sealing furnace door is provided by the outer casing 101,
  • the brick groove 102, the blade edge 103, the transverse iron 107, the cross-iron bolt 106, the knife edge clamp 105, the clamp bolt 104, and the furnace door insulator 109 have a unique sealing function.
  • a charging cart 6 is arranged above the cracking furnace body, and a slag pushing truck 40 is arranged on the right side of the cracking furnace body, and a slag guiding vehicle 20 is arranged on the left side of the cracking furnace body. And transport truck 30.
  • the slag pushing vehicle is provided with a sluice door device 401, a slag smashing device, a power distribution room, a cab 403, and a running mechanism 404.
  • the pick-up door device, the slag-crushing device, the power distribution room, and the driver's cab are mounted on a traveling frame.
  • the slag pushing device is provided with a slag head 402 and a slag rod 405.
  • the slag-pumping vehicle picks up the sealed furnace door by using the sluice gate device, and aligns the slag-removing device with the cracking chamber to push the slag, and at the same time, closes the furnace door by using the sluice gate device, and pushes the slag to guide the slag truck.
  • the slag-driving vehicle is provided with a closing device 202, a sluice door device 203, a driving device 201, a power distribution room and a driver's cab.
  • the device, the hanging door device, the power distribution room and the driver's cab are fixed on the driving device.
  • the lower part of the closing device is provided with a slag discharging chute and a translation locking device 204.
  • the shovel door device is provided with a set of screwing mechanism, a door lifting mechanism and a door absorbing mechanism.
  • the slag-carrying vehicle After the cracking of the waste in the cracking chamber is completed, the slag-carrying vehicle is started, the sealing furnace door is removed by using the sluice gate device, and the closing device is aligned with the cracking chamber, and the translational locking device acts to close the cracking chamber to the cracking chamber.
  • the lower part of the closing device is connected to the inlet water seal of the screw conveyor, and the slag pushing vehicle passes through the slag guiding vehicle.
  • the closing device pushes all the residues into the screw conveyor, the slag-carrying vehicle closes the furnace door by using the hanging door device, and the slag is completed.
  • the slag-driving vehicle passes through the closing device to guide the residue to the screw conveyor on the slag-carrying vehicle, cools and stirs evenly, and then sends it to the slag-carrying vehicle 30.
  • the figure shows a sluice door device.
  • the sluice door device is provided with a set of screwing mechanism, a door lifting mechanism, and a door plucking mechanism.
  • a motor 173, a speed reducer 172 and a wire cutter 171 are provided, the speed of which is set by the speed reducer.
  • the door lift mechanism is provided with a motor, a reducer, a link 176 and a door lifter 174.
  • the door taking mechanism is composed of a motor, a reducer, and a door 175.
  • the wire cutter unscrews the horizontal iron bolt 106 on the door rail 107, and the door lifter 174 is connected with the door hook 110 and lifts the horizontal movement of the door, and the door lifting mechanism is removed.
  • the furnace door the door taking mechanism removes the furnace door and completes the door opening action.
  • the door-lifting mechanism sends the furnace door into the door frame, the door-lifting mechanism picks up the door, the door iron rotates, the wire cutter tightens the thread, the door-lift mechanism releases the door, and the door-lift mechanism retreats to complete the hanging door. action.
  • the sluice door device on the slag pushing cart is the same as the shovel door device on the slag guiding cart.
  • the oven door refers to a sealed oven door at both ends of the cracking chamber.
  • the bottom of the transport truck is provided with a driving device 310.
  • the transport truck is provided with a water tank 301, a slag bucket 302, and a screw conveyor 303.
  • the conveyor is provided with a water adding device, a steam exhausting port 305, a water seal and a lifting device.
  • the screw conveyor is provided with one end of the water seal and the slag discharging chute on the slag guiding vehicle, and the other end is docked with the slag bucket.
  • the water tank is provided with a water supply device 306 and a water supply pipe 315. The slag truck is towed by the locomotive 304, and the residue is transported to the carbon black workshop by the slag truck.
  • the charging cart 6 is provided with a nitrogen device, a cab 605, a power distribution chamber, a pneumatic device 610, and a charging device 602.
  • the nitrogen device, the charging device, the cab, the distribution room, and the pneumatic device are mounted on the traveling vehicle 606.
  • the pneumatic device is provided with an air compressor, a gas storage tank, a cylinder, a pipeline, and a pneumatic component.
  • the lifting guide device and the closing hopper gate device are completed by operating a pneumatic device through a solenoid valve.
  • the capping device is provided with an electromagnet and a cylinder.
  • the body of the charging device is a hyperbolic hopper, the top of the charging device is provided with a sealing cover 604, and the lower part is provided with a guiding device, a hopper gate device and a capping device.
  • loading first uncover the uncovering device to the loading port of the cracking chamber, uncover the charging port cover, lower the guide bushing device, open the hopper gate device, start loading, start the nitrogen filling device, and charge the nitrogen at the same time.
  • the pipe shields the filling port.

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Abstract

The invention relates to a pyrolysis method for treating waste rubbers and plastics and materials containing resins. It includes using a pyrolyzer, breaking the waste with crusher in waste rubber and plastic shop and loading them into feed bin, simultaneously feeding the charge into the cracker in the pyrolyzer with charging lorry. The burning gas from the gas pipeline mixes with the hot air elevated by the heat accumulating chamber and burns with it, the burning heat produced transfers to the cracker and causes the feed to pyrolyze. Starting up the induced draft system, the pyrolysis gas is induced to oil and gas recovery and separation equipment through which the pyrolysis gas is separated into fuel oil and combustible gas. The oil and gas recovery and separation equipment is provided with oil and gas separator, condenser, and oil and water separator. The residue is conveyed to black carbon shop after the feed is pyrolyzed completely in the cracker, and the black carbon and waste steel are separated and the whole pyrolysis process is completed.

Description

一种废旧橡塑制品及含有树脂成分制品的裂解处理方法 技术领域  Waste rubber and plastic product and cracking treatment method containing resin component product
本发明涉及一种废旧橡塑制品及含有树脂成分制品的裂解处理方法, 该裂 解处理方法可将废旧橡胶制品、 废旧塑料制品、 含有树脂成分的废旧制品完全 裂解, 进行无害化处理, 进行有益的原料转化。  The invention relates to a waste rubber and plastic product and a cracking treatment method comprising the resin component product, which can completely crack the waste rubber product, the waste plastic product and the waste product containing the resin component, and carry out harmless treatment, and is beneficial. Conversion of raw materials.
背景技术 Background technique
日益增加的废旧轮胎、废旧塑料制品、 含有树脂成分的废旧制品已成为全 球性的环境保护问题。 这些废旧物品堆积占用土地, 污染环境, 且易引起火灾 成为公害。 传统的处理方法, 如焚烧和填埋法已被禁止使用。 废旧轮胎再生处 理的仅占 50%左右, 而含有树脂成分的废旧制品几乎不能再生。 将废旧轮胎裂 解制取燃料油和炭黑是最有效最彻底的处理方法之一。废轮胎的裂解处理没有 污染物排放, 而且还可以回收燃料油、 燃气、 废钢和碳黑, 有利于环保及资源 回收利用。 有较高的经济价值被认为是当今处理废旧轮胎的最佳途径之一。 废 旧橡胶的处理还处在再生利用阶段, 热处理方法研究刚刚起步。 中国专利 99212437. 9公开了一种干馏式气体化焚烧炉, 尤其是一种能使废塑料、废轮胎 等的高发热量废弃物完全燃烧, 且能有效抑制二垩英类等有害物质产生的干馏 式气体化焚烧炉。其主要技术特征是把一次燃烧室的干馏气体排出口通过气体 导入管与二次燃烧室连通连接, 在气体导入管内, 在流动的干馏气体中混合入 燃烧用空气, 燃烧用空气混合部的上流方和下流方之间空出一定间隔, 且至少 是 2段以上的设计。 但是, 该专利没有将干馏气体进行净化, 并且没有将燃烧 后产生的剩余物进行综合利用, 既浪费了资源又二次污染了环境。 因此, 需要 提出一种新的废旧橡塑制品及含有树脂成分制品的裂解处理方法。  Increasingly, used tires, used plastic products, and waste products containing resin components have become global environmental issues. These waste materials pile up to occupy land, pollute the environment, and easily cause fires to become public hazards. Traditional treatment methods such as incineration and landfill have been banned. Recycling of used tires accounts for only about 50%, and waste products containing resin components can hardly be regenerated. Decomposing used tires to produce fuel oil and carbon black is one of the most effective and thorough treatments. The cracking of waste tires has no pollutants, and it can also recover fuel oil, gas, scrap and carbon black, which is beneficial to environmental protection and resource recycling. The high economic value is considered to be one of the best ways to deal with used tires today. The disposal of waste rubber is still in the stage of recycling, and the research on heat treatment methods has just started. Chinese Patent No. 99212437. 9 discloses a dry distillation gasification incinerator, in particular, a dry distillation capable of completely burning high calorific wastes such as waste plastics and waste tires, and capable of effectively suppressing generation of harmful substances such as dioxins. Gasification incinerator. The main technical feature is that the dry distillation gas discharge port of the primary combustion chamber is connected to the secondary combustion chamber through the gas introduction pipe, and the combustion air is mixed into the flowing dry distillation gas in the gas introduction pipe, and the combustion air mixing portion is flown upward. There is a certain interval between the square and the downstream, and at least two or more designs. However, this patent does not purify the dry distillation gas, and does not comprehensively utilize the residue generated after combustion, which wastes resources and pollutes the environment twice. Therefore, it is necessary to propose a new waste rubber and plastic product and a cracking treatment method containing the resin component product.
发明内容 Summary of the invention
本发明的目的在于提供一种废旧橡塑制品及含有树脂成分制品的裂解处 理方法, 该裂解处理方法可将废旧橡胶制品、 废旧塑料制品、 含有树脂成分的 废旧制品在一个与外界环境隔绝的裂解室内完全裂解, 进行无害化处理, 进行 有益的原料转化, 其能耗小、 处理量大。  The object of the present invention is to provide a waste rubber and plastic product and a cracking treatment method comprising the resin component, which can disintegrate waste rubber products, waste plastic products, and waste products containing resin components in a cracking from the external environment. The indoor is completely cracked, and the harmless treatment is carried out to carry out beneficial raw material conversion, and the energy consumption is small and the treatment amount is large.
本发明的目的是由下述技术方案实现的: 一种废旧橡塑制品及含有树脂成 分制品的裂解处理方法, 使用一个裂解炉进行裂解处理, 该裂解炉体上部设有 多个裂解室, 所述每个裂解室两侧设有与其平行的加热火墙, 每个所述的加热 火墙内设有多个火道式燃烧室, 所述裂解炉体下部设置多个蓄热室, 该蓄热室 顶部与所述火道式燃烧室底部通过双向输气道对应连通; 所述火道式燃烧室底 部设有燃气喷口; 所述裂解室顶部设有装料口及裂解气收集口, 所述裂解气收 集口上部设置集气装置, 所述裂解室两端设有密封炉门; 所述蓄热室下部设有 两用集气道; 在废旧橡塑车间内使用粉碎设备将废料进行粉碎、 磁选、 然后送 入料仓; 使用装料车打开裂解炉上的装料口盖, 多个装料口同时向裂解炉体上 的裂解室布料; 燃气管道通入燃气与空气混合燃烧, 通过蓄热室升温后的热空 气到达燃烧室与燃气燃烧, 燃烧热量通过加热火墙传递到裂解室, 将裂解室的 温度保持在 600°C - 140(TC, 使其内的物料裂解; 启动引风系统, 引导冷却后的 裂解气进入油气回收分离装置, 通过油气回收分离装置将裂解气分离为燃料油 和可燃气; 油气回收分离装置中可以设置油气分离器、 冷凝器、 油水分离器; 分离出来的可燃气可以接入天然气柜, 然后通过燃气管道提供给燃烧室使用; 燃烧产生的烟气经过换气控制器、 分烟道进入烟囱; 裂解室内的物料裂解完毕 后,推渣车和导渣车启动炉门摘挂装置摘门,由推渣装置将残渣推入导渣车中, 该导渣车引导残渣到运渣车上, 推渣车和导猹车启动炉门摘挂装置封闭裂解室 两侧炉门, 所述运渣车将残渣输送至炭黑车间, 分离出炭黑及废钢, 完成裂解 的全过程。 The object of the present invention is achieved by the following technical solutions: a waste rubber and plastic product and a cracking treatment method comprising the resin component product, which is subjected to a cracking treatment using a cracking furnace, wherein the cracking furnace body is provided with a plurality of cracking chambers, Each of the cracking chambers is provided with a heating fire wall parallel thereto, and each of the heating fire walls is provided with a plurality of fire chamber type combustion chambers, and a plurality of regenerators are disposed at a lower portion of the cracking furnace body, and the regenerators are disposed The top portion is in communication with the bottom of the fire tunnel type combustion chamber through a two-way air passage; the fire tunnel type bottom of the combustion chamber a gas injection port is arranged at the top; a charging port and a cracking gas collecting port are arranged at the top of the cracking chamber, a gas collecting device is arranged at an upper portion of the cracking gas collecting port, and a sealed furnace door is arranged at both ends of the cracking chamber; There is a dual-purpose air collection channel in the lower part of the room; the waste material is crushed, magnetically selected, and then sent to the silo in the waste rubber and plastic workshop; the loading port cover on the cracking furnace is opened by the loading vehicle, and multiple loadings are installed. The material port is simultaneously discharged to the cracking chamber on the cracking furnace body; the gas pipeline is mixed with gas and air to be combusted, and the hot air heated by the regenerator reaches the combustion chamber to be combusted with the gas, and the heat of combustion is transmitted to the cracking chamber through the heated fire wall, The temperature of the cracking chamber is kept at 600 ° C - 140 (TC, the material inside is cracked; the air introducing system is started, the cracked gas after guiding cooling enters the oil and gas recovery and separation device, and the cracked gas is separated into fuel oil by the oil and gas recovery and separation device And combustible gas; oil and gas separators, condensers, oil-water separators can be installed in the oil and gas recovery and separation device; the separated combustible gas can be connected to the natural gas cabinet, and then The gas pipeline is supplied to the combustion chamber for use; the flue gas generated by the combustion passes through the ventilation controller and the branch flue to enter the chimney; after the cracking of the material in the cracking chamber is completed, the push slag truck and the slag guiding vehicle start the furnace door picking device to pick up the door, The slag pushing device pushes the residue into the slag-carrying vehicle, and the slag guiding vehicle guides the residue to the slag-carrying vehicle, and the slag-pumping vehicle and the guiding smashing vehicle start the furnace door lifting device to close the furnace door on both sides of the cracking chamber, and the slag-loading vehicle The residue is transferred to the carbon black workshop to separate the carbon black and the scrap steel, and the entire process of cracking is completed.
本发明与已有技术相比具有如下优点:  Compared with the prior art, the invention has the following advantages:
1、 本发明的烟气通过蓄热室进行蓄热, 热量利用率高, 能耗小。  1. The flue gas of the invention is stored in a regenerator for heat storage, has high heat utilization rate and low energy consumption.
2、 本发明的处理能力调整量大, 年处理量 10万吨〜 200万吨不等, 投资 小, 效率高。  2. The processing capacity of the invention is large, and the annual processing capacity ranges from 100,000 tons to 2 million tons, and the investment is small and the efficiency is high.
3、 本发明的废料处理范围大, 可处理废塑料、 废旧橡胶、 废旧工程塑料、 树脂类的废 I日制品及其它有机物质。  3. The waste treatment scope of the invention is large, and can treat waste plastics, waste rubber, waste engineering plastics, resin waste Japanese products and other organic substances.
4、 本发明的裂解炉处理温度可调性好, 温度范围 600°C - 1400°C , 随裂解 产品不同可方便的进行调整。  4. The cracking furnace of the invention has good temperature adjustment, and the temperature range is 600 ° C - 1400 ° C, which can be conveniently adjusted with different cracking products.
5、 本发明的裂解炉最终回收率高, 将废物全部回收, 并转化成燃料油、 可燃气、 炭黑、 废钢等市场紧缺资源。  5. The cracking furnace of the invention has a high recovery rate, and all the waste is recovered and converted into market shortage resources such as fuel oil, combustible gas, carbon black and scrap steel.
6、 本发明的裂解炉可实现零排放, 无环境污染。  6. The cracking furnace of the invention can achieve zero discharge without environmental pollution.
7、 本发明的裂解气釆用氨水冷却或者水冷却, 冷却效果好。  7. The cracking gas of the present invention is cooled by ammonia water or cooled by water, and the cooling effect is good.
附图说明 DRAWINGS
以下结合附图及实施例对本发明作进一步说明- 图 1、 本发明的裂解炉总体结构示意图 (图 2A- A剖视图)  The present invention will be further described below with reference to the accompanying drawings and embodiments - Fig. 1. Schematic diagram of the overall structure of the cracking furnace of the present invention (Fig. 2A-A cross-sectional view)
图 2、 本发明的裂解炉体结构示意图 (图 3E- E剖视图)  Figure 2 is a schematic view showing the structure of the cracking furnace body of the present invention (Fig. 3E-E sectional view)
图 3、 本发明的裂解炉总体结构俯视图  Figure 3. Top view of the overall structure of the cracking furnace of the present invention
图 4、 本发明的蓄热室剖视图 (图 2B— B剖视图) 图 5、 本发明的裂解炉体剖面图 (图 2C— C剖视图) Figure 4 is a cross-sectional view of the regenerator of the present invention (Fig. 2B-B is a cross-sectional view) Figure 5 is a cross-sectional view of the cracking furnace body of the present invention (Fig. 2C - C sectional view)
图 6、 本发明的加热火墙剖面图 (图 2D— ■D剖面图)  Figure 6. Sectional view of the heated fire wall of the present invention (Fig. 2D - ■ D sectional view)
图 7、 本发明裂解炉体的双向输气道分布图 (图 5F— -F剖视图)  Figure 7. Bidirectional airway distribution map of the cracking furnace body of the present invention (Fig. 5F--F cross-sectional view)
图 8、 本发明裂解炉体的双向输气道分布图 (图 5G— -G剖视图)  Figure 8. Bidirectional airway distribution map of the cracking furnace body of the present invention (Fig. 5G--G sectional view)
图 9、 本发明的换气控制器结构示意图  Figure 9. Schematic diagram of the ventilation controller of the present invention
图 10、 本发明的炉门结构示意图  Figure 10 is a schematic view of the structure of the furnace door of the present invention
图 11、 本发明的炉门横断面视图 (图 10H ί一 H剖视图) 图 12、 本发明的导渣车结构示意图  Figure 11 is a cross-sectional view of the furnace door of the present invention (Figure 10H ί-H sectional view) Figure 12 is a schematic view of the slag-carrying vehicle structure of the present invention
图 13、 本发明的运渣车结构示意图  Figure 13 is a schematic view showing the structure of the transport truck of the present invention
图 14、 本发明的推渣车结构示意图  Figure 14. Schematic diagram of the structure of the slag pushing truck of the present invention
图 15、 本发明的摘挂炉门装置结构示意图  Figure 15 is a schematic view showing the structure of the hanging door device of the present invention
图 16、 本发明的装料车结构示意图  Figure 16 is a schematic view showing the structure of the loading vehicle of the present invention
图 17、 本发明的的工艺流程框图  Figure 17. Process flow diagram of the present invention
图 18、 本发明的另一个实施例示意图  Figure 18 is a schematic view of another embodiment of the present invention
具体实施方式 detailed description
参见图 1、 图 17, 本发明使用一个裂解炉进行裂解处理, 在废旧橡塑车间 1内使用粉碎设备将废料进行粉碎 2、 磁选 3、 然后送入料仓 4; 磁选出的废钢 铁 14送入废料处; 在本实施例中也可以不进行粉碎和磁选直接将废料送入料 仓。 使用装料车 6打开裂解炉上的装料口盖, 多个装料口同时向裂解炉 5上的 裂解室布料; 燃气管道通入燃气 (可燃气) 与空气混合燃烧, 通过蓄热室升温 后的热空气到达燃烧室与燃气燃烧, 燃烧热量通过耐火材料 (加热火墙) 传递 到裂解室, 将裂解室的温度保持在 600 °C - 1400 °C (裂解室的温度可以在 600°C - 1400°C范围内任意调控) , 使其内的物料裂解; 启动引风系统中的引风机 10, 引导冷却后的裂解气进入油气回收分离装置, 通过油气回收分离装置将裂解气 分离为燃料油 13和可燃气 9 ; 油气回收分离装置中可以设置油气分离器 7、 冷 凝器 8、 油水分离器 12 ; 分离出来的可燃气可以接入天然气柜 11, 一部分燃气 通过燃气管道提供给燃烧室使用, 另一部分燃气外供。 燃烧产生的烟气经过换 气控制器 90、 分烟道 18进入烟囱 19 ; 裂解室内的物料裂解完毕后, 推渣车 40 和导渣车 20启动炉门摘挂装置摘门, 由推渣装置将残渣推入导渣车中, 该导 渣车引导残渣到运渣车 30上, 推渣车和导渣车启动炉门摘挂装置封闭裂解室 两侧炉门, 所述运渣车将残渣输送至炭黑车间 15, 分离出炭黑 16及废钢 17, 完成裂解的全过程。  Referring to Fig. 1, Fig. 17, the present invention uses a cracking furnace for cracking treatment, and uses a pulverizing device in the waste rubber and plastics workshop 1 to pulverize the scrap 2, magnetically select 3, and then feed it into the silo 4; magnetically selected scrap steel 14 is fed into the waste; in this embodiment, the waste can be directly sent to the silo without pulverization and magnetic separation. The charging port 6 is used to open the charging port cover on the cracking furnace, and the plurality of charging ports are simultaneously distributed to the cracking chamber on the cracking furnace 5; the gas pipe is connected to the gas (combustible gas) and mixed with the air to be heated, and the temperature is raised by the regenerator After the hot air reaches the combustion chamber and the gas is burned, the heat of combustion is transferred to the cracking chamber through the refractory material (heating the fire wall), and the temperature of the cracking chamber is maintained at 600 ° C - 1400 ° C (the temperature of the cracking chamber can be 600 ° C - Arbitrarily regulated in the range of 1400 °C), the material in the air is cracked; the induced draft fan 10 in the air intake system is started, and the cooled cracked gas is introduced into the oil and gas recovery and separation device, and the cracked gas is separated into fuel oil by the oil and gas recovery and separation device. 13 and combustible gas 9; oil and gas recovery and separation device can be provided with oil and gas separator 7, condenser 8, oil water separator 12; the separated combustible gas can be connected to the natural gas cabinet 11, and a part of the gas is supplied to the combustion chamber through the gas pipeline. Another part of the gas supply. The flue gas generated by the combustion enters the chimney 19 through the ventilating controller 90 and the branch flue 18; after the material in the cracking chamber is cracked, the slag pushing cart 40 and the slag guiding cart 20 start the door picking device to pick up the door, and the slag pushing device is Pushing the residue into the slag-carrying vehicle, the slag-carrying vehicle guides the residue to the slag-carrying vehicle 30, and the slag-carrying vehicle and the slag-carrying vehicle start the furnace door pick-up device to close the furnace door on both sides of the cracking chamber, and the slag-removing vehicle will have the residue It is sent to the carbon black workshop 15, and the carbon black 16 and the scrap steel 17 are separated to complete the whole process of cracking.
为了达到资源利用最大化的目的, 在本实施例中设置一个油气回收分离装 置, 该装置由一个油气分离器 7、 一个冷凝器 8和一个油水分离器 12构成。 来 自裂解炉体上的集气装置中的裂解气中含有油和水(由喷却水或者喷冷却氨水 形成) , 该裂解气经过集气装置冷却后从气体输入口进入油气分离器,分离出 的液体经液体排出口流入油水分离器,分离出的燃气经气体导出口进入冷凝 器。 所述冷凝器是一种箱式冷凝器, 所述油水分离器设有刮板输送机,油水混 合物入口,水出口,油出口, 残液排出口,出渣口。 所述刮板输送机设有电机,减 速机,链条。 所述油水混合物入口处设有液体缓冲板,减轻液体冲击力。 所述水 入口前设有隔板。 所述油出口设有溢流槽。 In order to achieve the purpose of maximizing resource utilization, an oil and gas recovery and separation device is set in this embodiment. The device is composed of an oil separator 7, a condenser 8, and a water separator 12 . The cracking gas in the gas collecting device from the cracking furnace body contains oil and water (formed by spraying water or spray cooling ammonia water), and the cracking gas is cooled by the gas collecting device and then enters the oil separator from the gas inlet port to be separated. The liquid flows into the oil water separator through the liquid discharge port, and the separated gas enters the condenser through the gas outlet. The condenser is a box type condenser, and the oil water separator is provided with a scraper conveyor, an oil-water mixture inlet, a water outlet, an oil outlet, a residual liquid discharge outlet, and a slag discharge port. The scraper conveyor is provided with a motor, a reducer and a chain. A liquid buffer plate is arranged at the inlet of the oil-water mixture to reduce the liquid impact force. A partition is provided in front of the water inlet. The oil outlet is provided with an overflow tank.
不同的废料其物理性质有所不同, 例如熔点温度、 气化温度等, 在本发明 的实施例中, 根据所述废料不同的物理性质、 化学性质选择配置缓释剂, 将缓 释剂混合在废料中一起进入裂解炉, 缓释剂主要用于降低裂解速度; 所述缓释 剂可以采用焦炭粉, 也可以采用鹅卵石或鹅卵石渣, 该鹅卵石渣由鹅卵石破碎 制成, 其粒径为 3— 5厘米。所述废料与缓释剂的重量比例为 10〜70: 90〜30。  Different waste materials have different physical properties, such as melting point temperature, vaporization temperature, etc. In the embodiment of the present invention, a slow release agent is selected according to different physical properties and chemical properties of the waste material, and the sustained release agent is mixed. The waste material enters the cracking furnace together, and the slow release agent is mainly used to reduce the cracking speed; the sustained release agent may be made of coke powder, or may be pebbles or cobblestone slag, which is made of pebbles and has a particle size of 3 - 5 cm. The weight ratio of the waste to the sustained release agent is 10 to 70: 90 to 30.
参见图 18, 在本发明的另一个实施例中, 为了便于加快添加炉料, 可以采 用在炉体侧面装料的形式, 所述的裂解炉体一侧设置一个电动胶带卸料小车 70, 先使用装料导料装置启动炉门摘挂装置摘门, 然后使用卸料小车向装料导 料装置 80内填置炉料, 由推渣装置将炉料送入裂解室中。 参见图 15, 在本实 施例中,装料导料装置上的炉门摘挂装置与所述推渣装置上的炉门摘挂装置相 同。 由于电动胶带卸料小车是常规的输送设备, 在此不详细描述。 其具体结构 参见 1998年出版的 《冶金机械设备安装工程施工及验收规范》 。  Referring to FIG. 18, in another embodiment of the present invention, in order to facilitate the quick addition of the charge, a form of charging on the side of the furnace body may be adopted, and an electric tape unloading trolley 70 is disposed on one side of the cracking furnace body, first used. The charging guide device starts the door lifting device to pick up the door, and then uses the unloading trolley to fill the charging material into the charging guiding device 80, and the charging device feeds the charging material into the cracking chamber. Referring to Fig. 15, in the present embodiment, the door picking device on the charging guide device is the same as the door picking device on the slag pushing device. Since the electric tape unloading trolley is a conventional conveying device, it will not be described in detail herein. The specific structure is described in the "Code for Construction and Acceptance of Metallurgical Machinery Installation Engineering" published in 1998.
在本发明的一个实施例中, 为了便于处理裂解的炉渣, 所述裂解炉出渣一侧设 置一个带式刮板输送机, 当裂解室内的物料裂解完毕后, 推渣车和导渣车启动炉门 摘挂装置摘门, 由推渣装置将残渣经导渣车导入带式刮板输送机, 由带式刮板输送 机将残渣运送到炭黑车间。 由于带式刮板输送机是常规的输送设备, 在此不详细描 述。 其具体结构参见 1998年出版的 《冶金机械设备安装工程施工及验收规范》。  In an embodiment of the present invention, in order to facilitate the treatment of the cracked slag, a belt scraper conveyor is disposed on the side of the cracking furnace, and when the material in the cracking chamber is cracked, the pusher and the slag-starting vehicle are started. The door picking device picks up the door, and the residue is introduced into the belt scraper conveyor by the slag pushing device, and the residue is transported to the carbon black workshop by the belt scraper conveyor. Since the belt scraper conveyor is a conventional conveying device, it will not be described in detail herein. For the specific structure, please refer to the “Code for Construction and Acceptance of Metallurgical Machinery Equipment Installation Engineering” published in 1998.
以下对本发明中使用的裂解炉进行较详细说明, 参见图 1、 图 2、 图 3、 图 4、 图 5, (其中图 1是本发明的纵剖面, 图 2是顺时针旋转 90° 的剖面图) 本发明的 裂解炉有一个裂解炉体 5, 所述裂解炉体上部设有多个裂解室 501, 图 1显示了裂 解室长度方向, 图 2显示了裂解炉体截面结构, 该裂解室由耐火砖砌筑构成, 具有 极好的密封性, 所述每个裂解室两侧设有与其平行的加热火墙 502, 每个所述的加 热火墙内设有多个火道式燃烧室 505 , 所述裂解炉体下部设置多个蓄热室 503, 该 蓄热室顶部与所述火道式燃烧室底部通过双向输气道 504对应连通;所述火道式燃 烧室底部设有燃气喷口; 所述裂解室顶部设有装料口 508及裂解气收集口 509, 所 述裂解气收集口上部设置集气装置 513, 所述裂解室两端设有密封炉门; 所述蓄热 室下部设有两用集气道 507, 该两用集气道的气体出入口端与一个换气控制器 90 的两用集气管连接, 该换气控制器的分烟管与一个分烟道 18连接。 The cracking furnace used in the present invention will be described in more detail below, see Fig. 1, Fig. 2, Fig. 3, Fig. 4, Fig. 5, wherein Fig. 1 is a longitudinal section of the present invention, and Fig. 2 is a section rotated 90° clockwise. Fig. 1) The cracking furnace of the present invention has a cracking furnace body 5, and a plurality of cracking chambers 501 are disposed in the upper portion of the cracking furnace body, Fig. 1 shows the length direction of the cracking chamber, and Fig. 2 shows a sectional structure of the cracking furnace body, and the cracking chamber It is composed of refractory brick masonry and has excellent sealing performance. Each of the cracking chambers is provided with heating fire walls 502 parallel thereto, and each of the heating fire walls is provided with a plurality of fire tunnel type combustion chambers 505. a plurality of regenerators 503 are disposed in the lower portion of the pyrolysis furnace body, and the top of the regenerator chamber is connected to the bottom of the flue-type combustion chamber through a bidirectional air passage 504; the bottom of the flue-type combustion chamber is provided with a gas nozzle; The top of the cracking chamber is provided with a charging port 508 and a cracking gas collecting port 509. A gas collecting device 513 is disposed at an upper portion of the cracking gas collecting port, and a sealing furnace door is disposed at both ends of the cracking chamber; a dual-purpose air collecting channel 507 is disposed at a lower portion of the heat accumulating chamber, and a gas inlet and outlet end of the dual-purpose air collecting channel is A dual-purpose manifold of a ventilating controller 90 is connected to the branching duct 18 of the venting controller.
参见图 1、 图 2、 图 4, 在本实施例中, 所述裂解室 501是废旧轮胎、 废塑料 等橡塑废品裂解的地方, 所述裂解室是一个可以与外界环境完全隔绝的、密封性极 好的矩形封闭腔室,该裂解室两侧壁的墙体使用带凸槽和凹槽的异型耐火砖砌筑构 成, 为了便于该裂解室排渣, 该裂解室推渣的一端比导渣的一端宽, 其锥度为 0° - 10° 左右, 根据处理废料的能力不同, 所述裂解室高度和长度也可以不同, 该裂 解室高度可设计成 2-8米左右, 该裂解室长度可设计成 13- 18米左右。所述裂解室 顶部设有多个装料口 508。 所述裂解室顶部设有一个或多个裂解气收集口 509, 该 裂解气收集口上安装有集气装置 513 , 该集气装置由氨水喷嘴、 水封、 水封翻板, 输气管道组成, 所述集气装置通过输气管道与一个油气回收分离装置连通, 该油气 回收分离装置的燃气输出端通过燃气管道 506 与火道式燃烧室底部的燃气喷口连 通。 裂解气经氨水喷淋冷却至 100°C以内, 该集气装置也可以使用水方式冷却, 由 于是常规结构, 在此不进行详细描述。 '  Referring to FIG. 1 , FIG. 2 and FIG. 4 , in the embodiment, the cracking chamber 501 is a place for cracking of rubber and plastic waste such as waste tires and waste plastics, and the cracking chamber is completely sealed from the external environment and sealed. An extremely rigid rectangular closed chamber, the wall of the two side walls of the cracking chamber is formed by using a special-shaped refractory brick with a convex groove and a groove, and in order to facilitate the slag discharge in the cracking chamber, the cracking chamber has a one end ratio The slag has a wide end and a taper of about 0° - 10°. The height and length of the cracking chamber may be different depending on the ability to dispose of the waste. The height of the cracking chamber may be designed to be about 2-8 meters. Can be designed to be around 13-18 meters. A plurality of charging ports 508 are provided at the top of the cracking chamber. The cracking chamber is provided with one or more cracking gas collecting ports 509, and the cracking gas collecting port is provided with a gas collecting device 513, which is composed of an ammonia water nozzle, a water seal, a water seal flap, and a gas pipeline. The gas collecting device is connected to an oil and gas recovery and separation device through a gas pipeline, and the gas output end of the oil and gas recovery and separation device is connected to the gas nozzle at the bottom of the fire tunnel type combustion chamber through the gas pipe 506. The cracked gas is cooled to within 100 ° C by spraying with ammonia, and the gas collecting means can also be cooled by water, and thus the conventional structure will not be described in detail. '
参见图 2、 图 5、 图 6, 在本实施例中, 所述每个裂解室两侧设有与其平行的 加热火墙 502, 该加热火墙长度与裂解室相同, 锥度与裂解室大小相同方向相反。 每个所述的加热火墙内设有多个火道式燃烧室 505, 该燃烧室是燃气与热空气混合 进行燃烧的地方,所述燃烧室由两个并列的竖直火道组成, 两个竖直火道顶端之间 的隔墙上都开设有跨越孔 516, 两个竖直火道底部之间的隔墙上都设废气循环孔 517, 为防止燃气短路, 位于裂解炉体两端头部位的竖直火道间不设废气循环孔。 所述燃烧室底部设有燃烧器, 该燃烧器包括燃气喷口和热空气喷口, 燃气喷口是燃 气管道 506的出口端, 热空气喷口是所述双向输气道 504的出口端。每个竖直火道 底部都设有一个燃气喷口 5061和两个热空气喷口 5041, 即每个火道式燃烧室底部 都设有两个燃气喷口和两对热空气喷口。 所述火道式燃烧室顶部设置多个看火孔 512, 该看火孔与燃气喷口相对应设置, 所述看火孔上安装有看火孔座和看火孔盖, 需要观察燃烧室内的燃烧情况时, 打开看火孔盖, 不需观察时, 将该看火孔盖密封 闭合。  Referring to FIG. 2, FIG. 5 and FIG. 6, in this embodiment, each of the cracking chambers is provided with a heating fire wall 502 parallel thereto, the length of the heating fire wall is the same as that of the cracking chamber, and the taper is opposite to the cracking chamber. . Each of the heated fire walls is provided with a plurality of fire-type combustion chambers 505, which are places where gas and hot air are mixed for combustion, and the combustion chamber is composed of two parallel vertical fire passages, two The partition wall between the tops of the vertical fire passages is provided with a spanning hole 516, and the partition wall between the bottoms of the two vertical fire passages is provided with an exhaust gas circulation hole 517, which is located at both ends of the cracking furnace body to prevent short circuit of the gas. There is no exhaust gas circulation hole between the vertical fire passages of the part. A burner is provided at the bottom of the combustion chamber, the burner includes a gas nozzle and a hot air nozzle, the gas nozzle is an outlet end of the gas pipe 506, and the hot air nozzle is an outlet end of the two-way air passage 504. At the bottom of each vertical fire channel is provided a gas nozzle 5061 and two hot air nozzles 5041, that is, two gas nozzles and two pairs of hot air nozzles are arranged at the bottom of each fire chamber. A plurality of fire sights 512 are disposed at the top of the fire chamber type combustion chamber, and the fire sights are disposed corresponding to the gas nozzles, and the fire hole is mounted with a fire hole seat and a fire hole cover, and the inside of the combustion chamber needs to be observed. When burning, open the fire hole cover and seal the fire hole cover when you do not need to observe it.
参见图 1、 图 2、 图 4、 图 5, 在本实施例中, 所述裂解炉体下部设置多个蓄热 室 503, 该蓄热室顶部与所述火道式燃烧室底部通过双向输气道 504对应连通, 该 蓄热室下部设置带篦子砖 510的两用集气道 507,所述箅子砖上面(即蓄热室中部) 放置换热用格子砖 511, 所述格子砖依据换热面积不同分六孔砖和九孔砖。 对于一 个特定的蓄热室, 通过蓄热室内的气体是定时变换的, 在第一个工作时段内, 通过 蓄热室的气体是燃烧废气, 该气体自上向下流动, 火道式燃烧室内燃烧后的废气经 其底部的双向输气道进入蓄热室,携带着热量的废气流经换热用格子砖进入两用集 气道, 并同时将该格子砖加热, 将热量储存在换热用格子砖内; 在第二个工作时段 内, 通过蓄热室的气体是新鲜空气, 该气体自下向上流动, 新鲜空气从两用集气道 进入蓄热室内, 新鲜空气流经带有热量的换热用格子砖时, 被换热用格子砖加热, 加热后的气体通过双向输气道进入燃烧室助燃。这种定时的气体的流动变换由一个 换气控制器 90进行控制。 Referring to FIG. 1 , FIG. 2 , FIG. 4 , FIG. 5 , in the embodiment, a plurality of regenerators 503 are disposed in a lower portion of the pyrolysis furnace body, and the top of the regenerator chamber and the bottom of the flue-type combustion chamber are bidirectionally transferred. The air passage 504 is correspondingly connected. The lower portion of the regenerator is provided with a dual-purpose air collection passage 507 with a tamper brick 510. The upper part of the raft brick (ie, the middle portion of the regenerator) is placed with a heat-transmission lattice brick 511. The heat exchange area is divided into six holes and nine holes. For a particular regenerator, the gas passing through the regenerator is time-varying and passes during the first working period. The gas in the regenerator is the combustion exhaust gas, and the gas flows from the top to the bottom. The exhaust gas in the flue-type combustion chamber enters the regenerator through the bidirectional air passage at the bottom thereof, and the exhaust gas carrying the heat flows through the heat exchange grid. The brick enters the dual-purpose air collection channel, and at the same time, the lattice brick is heated to store heat in the heat exchange lattice brick; in the second working period, the gas passing through the regenerator is fresh air, and the gas is from bottom to top. Flowing, fresh air enters the regenerator from the dual-purpose air collection channel. When the fresh air flows through the heat-transferring lattice brick with heat, it is heated by the heat-transmission lattice brick, and the heated gas enters the combustion chamber through the two-way air passage. Combustion. This timing flow of gas is controlled by a venting controller 90.
参见图 5、 图 6、 图 7、 图 8, 为了便于理解本发明, 简明的叙述一下蓄热室与 燃烧室中的气体流通关系。图 5中左起第一个裂解室左侧的加热火墙内的燃烧室为 第一列, 并且按自上而下排序; 该裂解室右侧的加热火墙内的燃烧室为第二列, 也 按自上而下排序; 参见图 6, 如果第一列中燃烧室中的烟气按顺时针方向流动, 则 第二列中燃烧室中的烟气按反时针方向流动。在第一个工作时段内, 图 5中第一列 燃烧室中的第一个燃烧器燃烧(自上而下排序), 第一个燃气喷口 5061工作, 第一 组热空气喷口 5041 向燃烧室提供新鲜空气, 第二个燃烧器不工作, 第二个燃气喷 口关闭, 第二组热空气喷口用于吸排燃烧后的废气; 第二列燃烧室中的第二个燃烧 器燃烧 (自上而下排序), 第二个燃气喷口工作, 第二组热空气喷口向燃烧室提供 新鲜空气, 第一个燃烧器不工作, 第一个燃气喷口关闭, 第一组热空气喷口用于吸 排燃烧后的废气; 参见图 7, 与之相对应, 左起第一、 二个蓄热室通过双向输气道 与第一列的第一组热空气喷口连通, 该蓄热室中自下而上流动的是新鲜空气, 左起 第三、 四个蓄热室通过双向输气道与第二列的第一组热空气喷口连通, 该蓄热室中 自上而下流动的是燃烧后的废气, 以下类推。 参见图 8, 左起第三、 四个蓄热室通 过双向输气道与第一列的第二组热空气喷口连通,该蓄热室中自上而下流动的是燃 烧后的废气; 左起第五、六个蓄热室通过双向输气道与第二列的第二组热空气喷口 连通, 该蓄热室中自下而上流动的是新鲜空气; 以后类推。 在第二个工作时段内, 上述气体的流动方向同时变换, 这种定时的变换由一个换气控制器 90进行控制。  Referring to Figures 5, 6, 7, and 8, in order to facilitate the understanding of the present invention, the relationship between the regenerator and the gas flow in the combustion chamber will be briefly described. The combustion chamber in the heating wall on the left side of the first cracking chamber from the left in Figure 5 is the first column, and is sorted from top to bottom; the combustion chamber in the heating wall on the right side of the cracking chamber is the second column, also Sorted from top to bottom; Referring to Figure 6, if the flue gas in the combustion chamber in the first column flows in a clockwise direction, the flue gas in the combustion chamber in the second column flows in a counterclockwise direction. During the first working period, the first burner in the first column of combustion chambers in Figure 5 is combusted (top-down ordering), the first gas vent 5061 operates, and the first set of hot air vents 5041 to the combustion chamber Providing fresh air, the second burner is not working, the second gas nozzle is closed, the second group of hot air nozzles are used to suck and exhaust the burned exhaust gas; the second burner in the second column is combusted (from above Down sorting), the second gas nozzle works, the second group of hot air nozzles supplies fresh air to the combustion chamber, the first burner does not work, the first gas nozzle is closed, and the first group of hot air nozzles are used for suction and exhaust Referring to Fig. 7, correspondingly, the first and second regenerators from the left are connected to the first group of hot air nozzles of the first row through the two-way air passage, and the regenerator flows from bottom to top. Fresh air, the third from the left, four regenerators are connected to the first group of hot air nozzles in the second row through the two-way air passage, and the exhaust gas flows from top to bottom in the regenerator. The following analogy. Referring to FIG. 8, the third and fourth regenerators from the left are connected to the second group of hot air nozzles of the first row through the two-way air passage, and the exhaust gas flows from top to bottom in the regenerator; The fifth and sixth regenerators are connected to the second group of hot air nozzles through the two-way air passage, and the fresh air is flowing from bottom to top in the regenerator; During the second working period, the flow direction of the above gas is simultaneously changed, and this timing change is controlled by a ventilation controller 90.
参见图 1、 图 4, 在本实施例中, 多条燃气管道 506自下而上穿过蓄热室的墙 体延伸到竖直火道底部的燃气喷口处, 该燃气管道分为单数通道和双数通道, 并且 分别与单数的竖直火道和双数的竖直火道对应连接。所述单数通道和双数通道内通 过的燃气由一个液压交换机 5062控制实现定时交换,轮流开启向燃烧室提供燃气, 即分别向单数的竖直火道或向双数的竖直火道提供燃气。当单数通道开启时双数通 道关闭, 反之, 单数通道关闭时双数通道开启。 为了便于换气控制器的布置和安装 多个蓄热室中间设有隔墙 520。 在本实施例中, 所述的箅子砖及换热用格子砖都是 常用的耐火材料。 参见图 1、 图 2、 图 9, 在本实施例中, 所述裂解炉体下部设置多个蓄热室, 该蓄热室按行和列等间距布置,同处每一列的蓄热室下部的两用集气道 507可形成 一条完整的烟气通道, 每一列的走向与裂解室的长度方向对应, 图 2共显示了 10 列蓄热室。为了便于换气控制器的布置和安装, 每一列烟气通道中部设有中心隔墙 (该中心隔墙与图 4中显示的中间隔墙 520相一致), 该烟气通道两端设置换气控 制器 90。 参见图 9, 所述换气控制器上部设有两用集气管 906, 该两用集气管上设 有一个空气阀 901, 该两用集气管与两用集气道连通, 换气控制器中部设有阀室 904, 其内设有一个废气砣 902、 废气砣提升杆 903, 换气控制器下部设有分烟管 905, 该分烟管与分烟道 18连通。 所述换气控制器由液压交换装置驱动(该液压交 换装置为大连冶金重型机械厂生产),换气控制器每隔 10— 20分钟实现新鲜空气与 燃烧废气换向一次。 在第一个工作时段内, 空气阀关闭, 废气坨打幵, 燃烧废气经 过两用集气道、 两用集气管、 阀室、 分烟管进入分烟道 18。 在第二个工作时段内, 空气阀打开, 废气砣关闭, 新鲜空气通过两用集气管、 两用集气道进入蓄热室, 被 加热的新鲜空气通过双向输气道进入燃烧室助燃。 Referring to FIG. 1 and FIG. 4, in the embodiment, a plurality of gas pipes 506 extend from bottom to top through a wall of the regenerator to a gas nozzle at the bottom of the vertical fire channel, and the gas pipe is divided into a single channel and Double channels, and respectively connected to a single vertical fire channel and a double vertical fire channel. The gas passing through the single channel and the double channel is controlled by a hydraulic switch 5062 to realize timing exchange, and turns on to provide gas to the combustion chamber, that is, respectively supplying gas to a single vertical fire channel or to a plurality of vertical fire channels. . When the singular channel is turned on, the dual channel is turned off. Conversely, when the singular channel is turned off, the dual channel is turned on. In order to facilitate the arrangement of the ventilation controller and the installation of a plurality of regenerators, a partition wall 520 is provided. In this embodiment, the dice brick and the lattice brick for heat exchange are common refractory materials. Referring to FIG. 1 , FIG. 2 and FIG. 9 , in the embodiment, a plurality of regenerators are disposed in a lower portion of the cracking furnace body, and the regenerators are arranged at equal intervals in rows and columns, and the lower portion of the regenerators in each row at the same place. The dual-purpose air collection passage 507 can form a complete flue gas passage, and the direction of each column corresponds to the length direction of the cracking chamber. FIG. 2 shows a total of 10 regenerators. In order to facilitate the arrangement and installation of the ventilation controller, a central partition wall is arranged in the middle of each row of flue gas passages (the central partition wall is consistent with the middle partition wall 520 shown in FIG. 4), and ventilation is provided at both ends of the flue gas passage. Controller 90. Referring to FIG. 9, the upper part of the ventilation controller is provided with a dual-purpose air collection tube 906. The dual-purpose air collection tube is provided with an air valve 901, and the dual-purpose air collection tube is connected with the dual-purpose air collection duct, and the middle of the ventilation controller A valve chamber 904 is provided, which is provided with an exhaust gas hopper 902 and an exhaust gas exhausting rod 903. The lower portion of the gas exchange controller is provided with a cigarette dividing pipe 905, and the branching tobacco pipe is in communication with the branching flue 18. The ventilation controller is driven by a hydraulic exchange device (produced by Dalian Metallurgical Heavy Machinery Factory), and the ventilation controller renews the fresh air and the combustion exhaust gas every 10-20 minutes. During the first working period, the air valve is closed, the exhaust gas is snoring, and the combustion exhaust gas enters the branch flue 18 through the dual-purpose air collection passage, the dual-purpose air collection tube, the valve chamber, and the cigarette separation tube. During the second working period, the air valve is opened, the exhaust gas is closed, the fresh air enters the regenerator through the dual-purpose collector and the dual-purpose air collection passage, and the heated fresh air enters the combustion chamber through the two-way air passage to assist combustion.
参见图 5、 图 10、 图 11, 在本实施例中, 为了保证裂解室的密封性, 所述 裂解室两端设有密封炉门 514和炉门框 518, 所述密封炉门由外壳 101、 砖槽 102、 刀边 103 、 横铁 107、 横铁螺栓 106、 刀边压块 105, 压块螺栓 104、 炉 门隔热体 109构成, 该刀边具有独特的密封作用。  Referring to FIG. 5, FIG. 10, FIG. 11, in the embodiment, in order to ensure the sealing property of the cracking chamber, a sealing furnace door 514 and a furnace door frame 518 are disposed at both ends of the cracking chamber, and the sealing furnace door is provided by the outer casing 101, The brick groove 102, the blade edge 103, the transverse iron 107, the cross-iron bolt 106, the knife edge clamp 105, the clamp bolt 104, and the furnace door insulator 109 have a unique sealing function.
为了便于裂解室装料和卸料, 所述裂解炉体上方设有装料车 6, 所述裂解炉体 右侧设有推渣车 40, 所述裂解炉体左侧设有导渣车 20和运渣车 30。  In order to facilitate the charging and unloading of the cracking chamber, a charging cart 6 is arranged above the cracking furnace body, and a slag pushing truck 40 is arranged on the right side of the cracking furnace body, and a slag guiding vehicle 20 is arranged on the left side of the cracking furnace body. And transport truck 30.
当裂解室的废料裂解完成后,推渣车启动, 其推渣头伸入到裂解室将其内的残 渣推向导渣车。 参见图 1、 图 14, 在本实施例中, 所述推渣车上设有一个摘挂炉门 装置 401、 一个推渣装置、 一个配电室、 一个司机室 403、 一个行走机构 404。 所 述摘挂炉门装置、 推渣装置、 配电室、 司机室安装在一行走车架上。 所述推渣装置 设有推渣头 402、 推渣杆 405。 推渣车利用摘挂炉门装置摘下所述密封炉门, 将推 渣装置对准裂解室进行推渣,同时利用摘挂炉门装置封闭炉门,将炉渣推向导渣车。  When the cracking of the waste in the cracking chamber is completed, the slag pushing truck is started, and the slag head is inserted into the cracking chamber to push the residue therein to the slag truck. Referring to Fig. 1 and Fig. 14, in the embodiment, the slag pushing vehicle is provided with a sluice door device 401, a slag smashing device, a power distribution room, a cab 403, and a running mechanism 404. The pick-up door device, the slag-crushing device, the power distribution room, and the driver's cab are mounted on a traveling frame. The slag pushing device is provided with a slag head 402 and a slag rod 405. The slag-pumping vehicle picks up the sealed furnace door by using the sluice gate device, and aligns the slag-removing device with the cracking chamber to push the slag, and at the same time, closes the furnace door by using the sluice gate device, and pushes the slag to guide the slag truck.
参见图 1、 图 12, 在本实施例中, 所述导渣车上设有一个封闭装置 202、 一个 摘挂炉门装置 203、 一个行车装置 201、 一个配电室和司机室, 所述封闭装置、 摘 挂炉门装置、配电室和司机室固定在行车装置上。所述封闭装置下部设有一个排渣 溜槽、 一个平移闭锁装置 204, 所述摘挂炉门装置设有一套拧螺紋机构、 一个提门 机构、一个取门机构。 当裂解室的废料裂解完成后, 导渣车启动, 利用摘挂炉门装 置将所述密封炉门摘下, 将封闭装置对准裂解室,所述平移闭锁装置动作使封闭装 置贴紧裂解室, 所述封闭装置下部连接螺旋输送机入口水封, 推渣车通过导渣车的 封闭装置,将残渣全部推入螺旋输送机后,所述导渣车利用摘挂炉门装置关闭炉门, 导渣完毕。 导渣车通过封闭装置, 引导残渣至运渣车上的螺旋输送机, 冷却且搅拌 均匀后送到运渣车 30上。 Referring to FIG. 1 and FIG. 12, in the embodiment, the slag-driving vehicle is provided with a closing device 202, a sluice door device 203, a driving device 201, a power distribution room and a driver's cab. The device, the hanging door device, the power distribution room and the driver's cab are fixed on the driving device. The lower part of the closing device is provided with a slag discharging chute and a translation locking device 204. The shovel door device is provided with a set of screwing mechanism, a door lifting mechanism and a door absorbing mechanism. After the cracking of the waste in the cracking chamber is completed, the slag-carrying vehicle is started, the sealing furnace door is removed by using the sluice gate device, and the closing device is aligned with the cracking chamber, and the translational locking device acts to close the cracking chamber to the cracking chamber. The lower part of the closing device is connected to the inlet water seal of the screw conveyor, and the slag pushing vehicle passes through the slag guiding vehicle. After the closing device pushes all the residues into the screw conveyor, the slag-carrying vehicle closes the furnace door by using the hanging door device, and the slag is completed. The slag-driving vehicle passes through the closing device to guide the residue to the screw conveyor on the slag-carrying vehicle, cools and stirs evenly, and then sends it to the slag-carrying vehicle 30.
参见图 15, 该图显示了一个摘挂炉门装置, 在本实施例中, 所述摘挂炉门装 置设有一套拧螺紋机构、一个提门机构、一个取门机构, 所述拧螺紋机构设有电机 173、 减速机 172和一个拧丝器 171, 该拧丝器转速由减速机设定。 所述提门机构 设有电机、 减速机、 连杆 176和提门器 174。 所述取门机构由电机、 减速机、 取门 机 175组成。 首先, 取门机构到达炉门后拧丝器拧开炉门横铁 107上的横铁螺栓 106, 同时提门器 174与炉门钩 110连接并且提升炉门横铁移动, 提门机构取下炉 门, 取门机构将炉门取走, 完成摘门动作。 反之, 取门机构将炉门送进炉门框, 提 门机构提门对位, 炉门横铁转动, 拧丝器拧紧螺纹, 提门机构松开炉门, 取门机构 后退, 完成挂炉门动作。所述推渣车上的摘挂炉门装置与导渣车上的摘挂炉门装置 相同。 所述炉门是指裂解室两端的密封炉门。  Referring to Figure 15, the figure shows a sluice door device. In this embodiment, the sluice door device is provided with a set of screwing mechanism, a door lifting mechanism, and a door plucking mechanism. A motor 173, a speed reducer 172 and a wire cutter 171 are provided, the speed of which is set by the speed reducer. The door lift mechanism is provided with a motor, a reducer, a link 176 and a door lifter 174. The door taking mechanism is composed of a motor, a reducer, and a door 175. First, after the door taking mechanism reaches the furnace door, the wire cutter unscrews the horizontal iron bolt 106 on the door rail 107, and the door lifter 174 is connected with the door hook 110 and lifts the horizontal movement of the door, and the door lifting mechanism is removed. The furnace door, the door taking mechanism removes the furnace door and completes the door opening action. Conversely, the door-lifting mechanism sends the furnace door into the door frame, the door-lifting mechanism picks up the door, the door iron rotates, the wire cutter tightens the thread, the door-lift mechanism releases the door, and the door-lift mechanism retreats to complete the hanging door. action. The sluice door device on the slag pushing cart is the same as the shovel door device on the slag guiding cart. The oven door refers to a sealed oven door at both ends of the cracking chamber.
参见图 1、 图 13, 在本实施例中, 所述运渣车底部设有一个行车装置 310, 运 渣车上设有一个水箱 301、 一个渣斗 302、 一个螺旋输送机 303, 所述螺旋输送机 上设有一个加水器、 排蒸汽口 305、 一个水封、 一个升降装置, 该螺旋输送机设有 水封的一端与导渣车上的排渣溜槽对接, 另一端与渣斗对接, 所述水箱设有给水装 置 306, 给水管道 315。运渣车由机车 304牵引, 由运渣车将残渣输送到炭黑车间。  Referring to FIG. 1 and FIG. 13, in the embodiment, the bottom of the transport truck is provided with a driving device 310. The transport truck is provided with a water tank 301, a slag bucket 302, and a screw conveyor 303. The conveyor is provided with a water adding device, a steam exhausting port 305, a water seal and a lifting device. The screw conveyor is provided with one end of the water seal and the slag discharging chute on the slag guiding vehicle, and the other end is docked with the slag bucket. The water tank is provided with a water supply device 306 and a water supply pipe 315. The slag truck is towed by the locomotive 304, and the residue is transported to the carbon black workshop by the slag truck.
参见图 1、 图 16, 在本实施例中, 所述装料车 6上设有氮气装置、 司机室 605、 配电室、 气动装置 610、 一装料装置 602。 所述氮气装置、 装料装置、 司机室、 配 电室、 气动装置安装在行走车 606上。 所述气动装置设有空压机、 储气罐、 气缸、 管路和气动元件。 通过电磁阀操作气动装置完成升降导套装置和起闭料斗闸板装 置。所述取盖装置设有电磁铁和气缸。所述装料装置的本体是一个双曲线料斗, 该 装料装置顶部设有密封盖 604, 下部设有导套装置、 料斗闸板装置、 取盖装置。 装 料时先将揭盖装置对准裂解室的装料口, 揭开装料口盖, 放下导套装置, 打开料斗 闸板装置, 开始装料, 同时启动充氮装置, 装料同时氮气通过管道屏蔽装料口, 装 料完毕后, 关闭料斗闸板装置, 收起导套装置, 关闭装料口盖, 装料完成。  Referring to Fig. 1 and Fig. 16, in the embodiment, the charging cart 6 is provided with a nitrogen device, a cab 605, a power distribution chamber, a pneumatic device 610, and a charging device 602. The nitrogen device, the charging device, the cab, the distribution room, and the pneumatic device are mounted on the traveling vehicle 606. The pneumatic device is provided with an air compressor, a gas storage tank, a cylinder, a pipeline, and a pneumatic component. The lifting guide device and the closing hopper gate device are completed by operating a pneumatic device through a solenoid valve. The capping device is provided with an electromagnet and a cylinder. The body of the charging device is a hyperbolic hopper, the top of the charging device is provided with a sealing cover 604, and the lower part is provided with a guiding device, a hopper gate device and a capping device. When loading, first uncover the uncovering device to the loading port of the cracking chamber, uncover the charging port cover, lower the guide bushing device, open the hopper gate device, start loading, start the nitrogen filling device, and charge the nitrogen at the same time. The pipe shields the filling port. After the filling is completed, close the hopper gate device, close the guide bushing device, close the loading port cover, and complete the filling.

Claims

权 利 要 求 书 Claim
1、 一种废旧橡塑制品及含有树脂成分制品的裂解处理方法, 使用一个裂 解炉进行裂解处理, 其特征在于: 所述裂解炉体上部设有多个裂解室, 所述每 个裂解室两侧设有与其平行的加热火墙, 每个所述的加热火墙内设有多个火道 式燃烧室, 所述裂解炉体下部设置多个蓄热室, 该蓄热室顶部与所述火道式燃 烧室底部通过双向输气道对应连通; 所述火道式燃烧室底部设有燃气喷口; 所 述裂解室顶部设有装料口及裂解气收集口, 所述裂解气收集口上部设置集气装 置, 所述裂解室两端设有密封炉门; 所述蓄热室下部设有两用集气道; 在废旧 橡塑车间内使用粉碎设备将废料进行粉碎、 磁选、 然后送入料仓; 使用装料车 打开裂解炉上的装料口盖, 多个装料口同时向裂解炉体上的裂解室布料; 燃气 管道通入燃气与空气混合燃烧, 通过蓄热室升温后的热空气到达燃烧室与燃气 燃烧, 燃烧热量通过加热火墙传递到裂解室, 将裂解室的温度保持在 600 -1400°C , 使其内的物料裂解; 启动引风系统, 引导冷却后的裂解气进入油气 回收分离装置, 通过油气回收分离装置将裂解气分离为燃料油和可燃气; 油气 回收分离装置中可以设置油气分离器、 冷凝器、 油水分离器; 分离出来的可燃 气可以接入天然气柜, 然后通过燃气管道提供给燃烧室使用; 燃烧产生的烟气 经过换气控制器、 分烟道进入烟囱; 裂解室内的物料裂解完毕后, 推渣车和导 渣车启动炉门摘挂装置摘门, 由推渣装置将残渣推入导渣车中, 该导渣车引导 残渣到运渣车上, 推渣车和导渣车启动炉门摘挂装置封闭裂解室两侧炉门, 所 述运渣车将残渣输送至炭黑车间, 分离出炭黑及废钢, 完成裂解的全过程。 1. A waste rubber and plastic product and a cracking treatment method comprising the resin component product, wherein the cracking treatment is performed by using a cracking furnace, wherein: the cracking furnace body is provided with a plurality of cracking chambers, and each of the cracking chambers is The side is provided with a heating fire wall parallel thereto, and each of the heating fire walls is provided with a plurality of fire chamber type combustion chambers, and a plurality of regenerators are disposed at a lower portion of the cracking furnace body, and the top of the regenerator chamber and the fire channel The bottom of the combustion chamber is connected by a two-way air passage; the bottom of the fire chamber is provided with a gas nozzle; the top of the cracking chamber is provided with a charging port and a cracking gas collecting port, and the upper part of the cracking gas collecting port is set a gas device, a sealing furnace door is arranged at two ends of the cracking chamber; a dual-purpose gas collecting channel is arranged at a lower portion of the regenerator; a scraping device is used in the waste rubber and plastic workshop to pulverize, magnetically select and then feed the scrap The warehouse is used to open the charging port cover on the cracking furnace, and the plurality of charging ports are simultaneously distributed to the cracking chamber on the cracking furnace body; the gas pipe is mixed with gas and air to be combusted, and is passed through the regenerator. After the hot air reaches the combustion chamber and the gas is burned, the heat of combustion is transferred to the cracking chamber through the heated fire wall, and the temperature of the cracking chamber is maintained at 600-1400 ° C to crack the material therein; the air introducing system is started, and the cooling system is guided. The cracked gas enters the oil and gas recovery and separation device, and the cracked gas is separated into fuel oil and combustible gas through the oil and gas recovery and separation device; the oil and gas separator, the condenser and the oil water separator may be disposed in the oil and gas recovery and separation device; the separated combustible gas can be accessed The natural gas cabinet is then supplied to the combustion chamber through the gas pipeline; the flue gas generated by the combustion enters the chimney through the ventilation controller and the branch flue; after the material in the cracking chamber is cracked, the push slag truck and the slag-starting vehicle start the furnace door to be hanged The device picks up the door, and the residue is pushed into the slag-carrying vehicle by the slag-carrying device, and the slag-carrying vehicle guides the residue to the slag-carrying vehicle, and the slag-carrying vehicle and the slag-carrying vehicle start the furnace door lifting device to close the furnace door on both sides of the cracking chamber. The slag truck transports the residue to the carbon black workshop, separates the carbon black and the scrap steel, and completes the whole process of cracking.
2、 根据权利要求 1 所述的裂解处理方法, 其特征在于: 根据所述废料的 物理性质、 化学性质选择配置缓释剂, 用于降低裂解速度, 所述缓释剂是焦炭 粉或是鹅卵石渣, 所述废料与缓释剂的重量比例为 10〜70: 90〜30。  2. The cracking treatment method according to claim 1, wherein: a sustained release agent is selected according to physical properties and chemical properties of the waste material for reducing cracking speed, and the sustained release agent is coke powder or pebbles. The slag, the weight ratio of the waste to the sustained release agent is 10 to 70: 90 to 30.
3、 根据权利要求 1 所述的裂解处理方法, 其特征在于: 所述的裂解炉体 一侧设置一个电动胶带卸料小车, 使用装料导料装置启动炉门摘挂装置摘门, 然后使用卸料小车向装料导料装置内填置炉料, 由推渣装置将炉料送入裂解室 中。  3. The cracking treatment method according to claim 1, wherein: an electric tape unloading trolley is disposed on one side of the cracking furnace body, and the charging device is used to start the furnace door picking device to pick up the door, and then use The unloading trolley fills the charging material into the charging guide device, and the charging material is sent into the cracking chamber by the slag pushing device.
4、 根据权利要求 1 所述的裂解处理方法, 其特征在于: 所述裂解炉体出 渣一侧设置一个带式刮板输送机, 当裂解室内的物料裂解完毕后, 推渣车和导 渣车启动炉门摘挂装置摘门, 由推渣装置将残渣经导渣车封闭装置导入带式刮 板输送机, 由带式刮板输送机将残渣运送到炭黑车间。  4. The cracking treatment method according to claim 1, wherein: a belt scraper conveyor is arranged on the side of the cracking furnace body, and when the material in the cracking chamber is cracked, the slag pushing truck and the slag guiding device are pushed. The car starts the door picking device to pick up the door, and the residue is introduced into the belt scraper conveyor through the slag guiding device by the slag pushing device, and the residue is transported to the carbon black workshop by the belt scraper conveyor.
PCT/CN2005/001181 2005-08-03 2005-08-03 A pyrolysis method for treating waste rubber and plastics and materials containing resins WO2007014489A1 (en)

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CN106753505A (en) * 2017-01-18 2017-05-31 武汉大学 A kind of tilting biomass through pyrolysis reaction unit
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CN110066674A (en) * 2019-05-28 2019-07-30 青岛伊克斯达智能装备有限公司 A kind of tire pyrolysis breeze and gas and oil separating plant
CN110066674B (en) * 2019-05-28 2024-04-05 青岛伊克斯达智能装备有限公司 Tire schizolysis carbon residue and oil gas separation device
CN112662409A (en) * 2020-12-22 2021-04-16 浙江圣沐新能源有限公司 Cracking conversion device for producing carbon and processing technology thereof
CN112662409B (en) * 2020-12-22 2021-11-12 浙江圣沐新能源有限公司 Cracking conversion device for producing carbon and processing technology thereof
CN113403094A (en) * 2021-06-18 2021-09-17 唐山市嘉恒实业有限公司 Thermal cracking treatment method and equipment for hazardous waste and solid waste
US11999920B2 (en) 2021-09-10 2024-06-04 Ecolab Usa Inc. Cold flow additives for plastic-derived synthetic feedstock

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