CN108753341B - Can realize junked tire complete schizolysis and quick refrigerated integrated device - Google Patents

Can realize junked tire complete schizolysis and quick refrigerated integrated device Download PDF

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Publication number
CN108753341B
CN108753341B CN201811009094.3A CN201811009094A CN108753341B CN 108753341 B CN108753341 B CN 108753341B CN 201811009094 A CN201811009094 A CN 201811009094A CN 108753341 B CN108753341 B CN 108753341B
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cooling
pyrolysis
carbon black
cracking
section
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CN201811009094.3A
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CN108753341A (en
Inventor
李志华
宋应帅
刘强彩
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Qingdao University of Science and Technology
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Qingdao University of Science and Technology
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/10Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal from rubber or rubber waste
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J6/00Heat treatments such as Calcining; Fusing ; Pyrolysis
    • B01J6/008Pyrolysis reactions
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J11/00Recovery or working-up of waste materials
    • C08J11/04Recovery or working-up of waste materials of polymers
    • C08J11/10Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation
    • C08J11/12Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by dry-heat treatment only
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/44Carbon
    • C09C1/48Carbon black
    • C09C1/482Preparation from used rubber products, e.g. tyres
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10Feedstock materials
    • C10G2300/1003Waste materials
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/62Plastics recycling; Rubber recycling

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Thermal Sciences (AREA)
  • Wood Science & Technology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Sustainable Development (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)

Abstract

The invention discloses an integrated device capable of realizing complete pyrolysis and rapid cooling of waste tires, which comprises a stirring driving part, a complementary pyrolysis part and a cooling part. The invention is supported and connected with the driven end of the cracking host in a sealing way, the carbon black cracked by the cracking host directly falls into the invention, the stirring blades in the barrel of the cracking section stir the loose carbon black and make the carbon black carry out the complementary cracking by utilizing the heat carried by the carbon black, meanwhile, the cracking gas overflows from the carbon black, the cooling blades in the barrel of the cooling section stir the carbon black to make the carbon black contact with the cooling pipe and the cooling jacket, so that the carbon black is cooled rapidly and discharged through the carbon black outlet at the bottom. The cracking section cylinder is positioned at the upper part of the cooling section cylinder and is connected with the cooling section cylinder through a flange. The invention utilizes the pyrolysis host to lead out the heat of the carbon black, achieves the purposes of complete pyrolysis and rapid cooling and discharge, improves the utilization rate of heat energy, ensures the quality of the pyrolysis carbon black, and increases the output of pyrolysis oil gas.

Description

Can realize junked tire complete schizolysis and quick refrigerated integrated device
Technical Field
The invention relates to the technical field of waste tire cracking, in particular to an integrated device capable of realizing complete waste tire cracking and rapid cooling.
Background
The cracking of junked tires is one of the effective methods for solving the environmental pollution caused by junked tires. The waste tires are cracked in a cracking host, the obtained cracking products are carbon black and combustible gas, the carbon black is cooled and then subjected to subsequent treatment to obtain high-value activated carbon, and the combustible gas is cooled and then subjected to subsequent treatment to obtain various oil products and non-condensable gases. The cracking technology is already applied to the field of recycling of junked tires, and the related tire cracking technology is also continuously improved at present.
The invention CN104031672A provides a continuous thermal cracking method and device for junked tires, wherein the method comprises the following steps: (1) Preheating (15-25) the waste tire materials at 230-250 ℃ for a period of time, and vacuumizing to remove gas generated in the preheating process; (2) Heating the material obtained in the step (1) to 340-360 ℃, and cracking (8-12) for a minute at 340-360 ℃ to crack the natural rubber, and pumping out gas generated in the cracking process under vacuum; (3) Heating the material obtained in the step (2) to 440-460 ℃, and cracking (8-12) for a minute at 440-460 ℃ to crack butadiene rubber and styrene butadiene rubber, and pumping out gas generated in the cracking process under vacuum; (4) Heating the material obtained in the step (3) to 540-560 ℃, and cracking (8-12) for a minute at 540-560 ℃ to crack carbonaceous deposits on the surface of the carbon black, and pumping out gas generated in the cracking process under vacuum. The method and the device can effectively remove the sediment on the surface of the carbon black, improve the activity and the quality of the carbon black, and realize the continuous production of cracking the waste tires with low energy consumption.
The invention CN108018062A provides a waste rubber cracking method and a system, which are characterized in that waste rubber is sequentially sent into a low-temperature thermal cracking chamber, a high-temperature thermal cracking chamber and a microwave cracking chamber which are in an anaerobic or oxygen-deficient environment; wherein, waste rubber is thermally cracked in a low-temperature thermal cracking chamber at 200-400 ℃, is thermally cracked in a high-temperature thermal cracking chamber at 500-800 ℃, and is thermally cracked in a microwave cracking chamber at 500-800 ℃; the pyrolysis oil gas generated in the pyrolysis process is continuously discharged out of the low-temperature pyrolysis chamber, the high-temperature pyrolysis chamber and the microwave pyrolysis chamber; recovering the solids produced during the pyrolysis. The invention can effectively reduce the energy consumption in the cracking process and improve the waste tire cracking efficiency and the quality of the cracked carbon black.
The existing patent is greatly improved in the waste tire cracking method and the waste tire cracking equipment, so that the waste tire cracking efficiency is improved, and the energy consumption during cracking is reduced. However, the conventional continuous waste tire cracking equipment still has a plurality of technical problems, and the problem that the carbon black produced by the waste tires after being cracked by a cracking host is not completely cracked easily occurs because the carbon black which is one of important products of the cracking is treated by a treatment method of directly cooling by a post-treatment device and then immediately discharging the carbon black out of the cracking device. In addition, the incompletely cracked carbon black is rapidly cooled in the post-treatment device, and the heat loss caused by direct cooling of the high-temperature carbon black and the problem that condensed oil is attached to carbon black particles during cooling are caused. Although the prior patent can improve the yield of carbon black, the correct treatment and recovery of the cracking products are ignored, and the problems cannot be solved, so that the quality of the cracking carbon black is influenced, the yield of cracking oil gas is reduced, and the energy waste is caused by heat loss.
SUMMARY OF THE PATENT FOR INVENTION
The invention aims to overcome the defects of the prior art, and provides an integrated device capable of realizing complete pyrolysis and rapid cooling of waste tires, which is directly connected with the output end of a pyrolysis host, and further realizes complete pyrolysis by utilizing heat carried by pyrolysis carbon black, and rapidly cools down. The problems of incomplete carbon black cracking and cooling carbon black attached oil after the waste tires are cracked by the cracking main machine can be effectively solved, the heat energy utilization rate is improved, the quality of the cracked carbon black is ensured, and the output of the cracked oil gas is increased.
In order to achieve the purpose, the invention adopts the following technical scheme: the utility model provides an integrated device that can realize junked tire complete pyrolysis and quick cooling, includes stirring drive part, supplements pyrolysis part, cooling down part, its characterized in that: the upper end of the stirring shaft of the stirring driving part is connected with a driving motor through a driving end bearing seat, the lower end of the stirring shaft penetrates through the bottom of the cooling section cylinder body to be connected with a driven end bearing seat, an insulating layer is arranged outside the cracking section cylinder body of the supplementary cracking part, a high material level gauge, a low material level gauge, an insulating section thermocouple and a support are arranged outside the cracking section cylinder body, a cooling section thermocouple and a cracking carbon black outlet pipe are arranged at the bottom of the cooling section cylinder body of the cooling part, and a cooling jacket and two rows of cooling pipes are arranged at the circumference and the bottom of the cooling section cylinder body.
Further, four stirring blades of the stirring driving part are uniformly distributed and welded on the stirring shaft and are positioned in the cracking section cylinder, the plane of each stirring blade forms an included angle of 45 degrees with the axis of the stirring shaft, two upper cooling blades, two lower cooling blades of the stirring driving part are respectively welded on the stirring shaft at an included angle of 180 degrees, and the planes of the upper cooling blades, the cooling blades and the lower cooling blades form an included angle of 0 degrees with the axis of the stirring shaft and are respectively positioned at the upper part, the middle part and the lower part of the two rows of cooling pipes.
Further, the output end of the cracking host penetrates through the cracking section cylinder, the cracking carbon black outlet of the cracking host is positioned in the cracking section cylinder, the cracking section cylinder is in supporting and sealing connection with the output end of the cracking host, and a cracking gas outlet pipe is arranged at the top of the cracking section cylinder.
Further, the cracking section cylinder body and the cooling section cylinder body are arranged in a line, and the cracking section cylinder body is positioned on the cooling section cylinder body and is connected with the cooling section cylinder body in a sealing way through an upper flange and a lower flange.
Further, the output end of the pyrolysis host machine, the driving end of the stirring driving part, the driven end and the cooling section cylinder of the cooling part are respectively provided with a cooling water pipeline.
After the technical scheme of the invention is adopted, the following beneficial effects are brought:
the device is directly connected with the output end of the cracking host, and further realizes complete cracking by utilizing heat carried by the cracking carbon black, and rapidly cools down. The cracking host is meshed double-screw electromagnetic heating continuous cracking equipment, and the output end of the cracking host directly extends into the device and is supported and connected by the device. The cracked carbon black is pushed by the meshed double screws and falls into the device directly. With rotation of the stirring shaft. Under the effect of each blade, firstly, partial incompletely cracked carbon black is promoted to be completely cracked by utilizing the self heat of the carbon black at the upper part of the device, the generated cracking gas is timely discharged through the upper exhaust port, and then, the carbon black is cooled down through the cooling jacket and the cooling pipe at the lower part of the device, so that the heat energy utilization rate is improved, the quality of the cracked carbon black is ensured, and the output of cracked oil gas is increased.
Drawings
Fig. 1: the structure diagram of the patent of the invention;
fig. 2: FIG. 1 is a side view;
fig. 3: fig. 1 is a top cross-sectional view.
Wherein: 1. the device comprises a driving motor 2, a motor support 3, a driving end bearing seat 4, a driving end cooling water pipeline 5, a driving end shaft seal 6, a stirring blade 7, a stirring shaft 8, an upper cooling blade 9, a cooling blade 10, a lower cooling blade 11, a driven end cooling water pipeline 12, a driven end shaft seal 13, a driven end bearing seat 14, a high level gauge 15, a low level gauge 16, an upper flange 17, a pyrolysis gas outlet pipe 18, a pyrolysis host output end support 19, a pyrolysis host output end cooling water pipeline 20, a heat preservation section thermocouple 21, a heat preservation layer 22, a support 23, a pyrolysis section cylinder 24, a lower flange 25, a cooling section cylinder 26, a cooling jacket 27, a cooling water pipe 28, a cooling section thermocouple 29, a cooling water pipeline 30 and a pyrolysis carbon black outlet pipe.
Detailed Description
The following describes the embodiments of the present invention in further detail with reference to the accompanying drawings.
With reference to fig. 1 and 2, an integrated device capable of realizing complete cracking and rapid cooling of junked tires comprises a driving stirring part, a complementary cracking part and a cooling part. The stirring driving part mainly comprises a driving motor 1, a motor support 2, a driving end bearing seat 3, a driving end cooling water pipeline 4, a driving end shaft seal 5, stirring blades 6, a stirring shaft 7, an upper cooling blade 8, a cooling blade 9, a lower cooling blade 10, a driven end cooling water pipeline 11, a driven end shaft seal 12, a driven end bearing seat 13 and the like. The supplementary pyrolysis part mainly comprises a high level gauge 14, a low level gauge 15, an upper flange 16, a pyrolysis gas outlet pipe 17, a pyrolysis host output end support 18, a pyrolysis host output end cooling water pipeline 19, a heat preservation section thermocouple 20, a heat preservation layer 21, a support 22, a pyrolysis section cylinder 23 and the like. The cooling part mainly comprises a lower flange 24, a cooling section cylinder 25, a cooling jacket 26, a cooling pipe 27, a cooling section thermocouple 28, a cooling water pipeline 29, a pyrolysis carbon black outlet pipe 30 and the like. The cracking host is meshed double-screw electromagnetic heating continuous cracking equipment, and the output end of the cracking host directly extends into the device and is supported and connected by the device. Waste tires enter a cracking host machine to start working, and cracked carbon black is pushed by a meshed double screw rod and directly falls into the device. The device and the pyrolysis host synchronously work, the driving motor 1 drives the stirring shaft 7 to perform rotary motion, the stirring blade 6 on the stirring shaft 7 stirs the carbon black, the carbon black is acted by the stirring blade 6 and has upward acting force, the heat insulation layer 21 is arranged outside the pyrolysis section cylinder 23, so that the carbon black in the region is loosened, the heat carried by the carbon black from the pyrolysis host can be used for continuous supplementary pyrolysis, the generated pyrolysis gas rises to the pyrolysis gas outlet 17 in time through a loose carbon black gap and is discharged, the temperature of the carbon black is measured in real time according to the heat insulation section thermocouple 20 so as to adjust the pyrolysis temperature of the pyrolysis host and the rotational speed of the meshed double screw, and the high level gauge 14 and the low level gauge 15 feed back the position of the carbon black in real time, when the carbon black is at a low level, the rotational speed of the driving motor 1 is reduced; when the carbon black is at a high level, the rotational speed of the drive motor 1 is increased, and the carbon black level in the device is kept between the high and low levels. The cracking section cylinder 23 and the cooling section cylinder 25 are arranged up and down in a line, and are connected in a sealing way through the upper flange 16 and the lower flange 24, part of heat is consumed by carbon black in the cracking section cylinder 23, the cracking is completed, the temperature is reduced, and then the carbon black enters the cooling section cylinder 25 for cooling, and the cooling jacket 26 and the cooling pipe 27 are cooled through the cooling water pipeline 29. The upper cooling blade 8, the cooling blade 9 and the lower cooling blade 10 which rotate along with the stirring shaft 7 continuously stir and change the position of the carbon black, so that the carbon black is fully contacted with the cooling jacket 26 and the cooling pipe 27 for heat exchange, and the temperature of the carbon black is rapidly reduced. The cooling section thermocouple 28 measures the carbon black temperature in real time, and increases the cooling water flow rate when the carbon black temperature is higher than the discharge temperature; when the temperature is lower than the discharge temperature, the flow rate of the cooling water is reduced, and the carbon black temperature is kept within the set discharge temperature range. The lower cooling blades 10 also serve to push the lower soot out of the cracked soot exit tube 30.
The foregoing is merely illustrative of the preferred embodiments of this invention, and it will be appreciated by those skilled in the art that variations and modifications may be made without departing from the principles of this invention, which is also intended to be considered as within the scope of this invention.

Claims (2)

1. The utility model provides an integrated device that can realize junked tire complete pyrolysis and quick cooling, includes stirring drive part, supplements pyrolysis part, cooling down part, its characterized in that: the utility model provides a stirring drive part's (7) upper end links to each other with driving motor (1) through drive end bearing frame (3), and the lower extreme passes cooling section barrel (25) bottom and links to each other with driven end bearing frame (13), the outside of replenishing pyrolysis section barrel (23) of pyrolysis part is equipped with heat preservation (21) to be equipped with high charge level indicator (14), low charge level indicator (15) and heat preservation section thermocouple (20) and support (22), cooling section barrel (25) of cooling part is equipped with cooling section thermocouple (28), bottom and establishes pyrolysis carbon black exit tube (30), and establishes cooling jacket (26) at circumference and bottom and the inside two rows of cooling tubes (27) of establishing simultaneously, stirring drive part's stirring vane (6) total four, evenly distributed welding is on stirring shaft (7), lies in pyrolysis section barrel (23) the plane and the axis of stirring shaft (7) 45 contained angle, cooling vane (8), cooling vane (9) and cooling vane (10) down in stirring drive part, respectively have two, 180 on stirring shaft (7), cooling vane (7) are located cooling axis (7) and cooling tube (27) are located respectively on the cooling axis (7) contained angle The middle part and the lower part, the output of pyrolysis host computer pass pyrolysis section barrel (23), and the pyrolysis carbon black export of pyrolysis host computer is located pyrolysis section barrel (23), pyrolysis section barrel (23) and pyrolysis host computer output support (18) sealing connection, the top of pyrolysis section barrel (23) is equipped with pyrolysis gas exit tube (17).
2. The integrated device capable of realizing complete cracking and rapid cooling of junked tires according to claim 1, wherein the integrated device is characterized in that: the cracking section cylinder (23) and the cooling section cylinder (25) are arranged in a line, the cracking section cylinder (23) is positioned on the cooling section cylinder (25), and the cracking section cylinder and the cooling section cylinder are connected in a sealing manner through an upper flange (16) and a lower flange (24).
CN201811009094.3A 2018-08-31 2018-08-31 Can realize junked tire complete schizolysis and quick refrigerated integrated device Active CN108753341B (en)

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CN108753341B true CN108753341B (en) 2023-07-18

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007014489A1 (en) * 2005-08-03 2007-02-08 Weitian Zhang A pyrolysis method for treating waste rubber and plastics and materials containing resins
WO2014067246A1 (en) * 2012-10-31 2014-05-08 Niu Bin Continuous waste-rubber cracking process and equipment therefor
CN104560101A (en) * 2014-12-31 2015-04-29 青岛东方循环能源有限公司 Continuous rubber powder cracking device and method
WO2015085661A1 (en) * 2013-12-13 2015-06-18 牛晓璐 Process and apparatus for scrap tire pyrolysis and material discharging
CN204417393U (en) * 2014-12-31 2015-06-24 青岛东方循环能源有限公司 A kind of device making cracking black carbon fast cooling

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007014489A1 (en) * 2005-08-03 2007-02-08 Weitian Zhang A pyrolysis method for treating waste rubber and plastics and materials containing resins
WO2014067246A1 (en) * 2012-10-31 2014-05-08 Niu Bin Continuous waste-rubber cracking process and equipment therefor
WO2015085661A1 (en) * 2013-12-13 2015-06-18 牛晓璐 Process and apparatus for scrap tire pyrolysis and material discharging
CN104560101A (en) * 2014-12-31 2015-04-29 青岛东方循环能源有限公司 Continuous rubber powder cracking device and method
CN204417393U (en) * 2014-12-31 2015-06-24 青岛东方循环能源有限公司 A kind of device making cracking black carbon fast cooling

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