WO2006135195A1 - Multipurpose ceramic composition and usage thereof - Google Patents

Multipurpose ceramic composition and usage thereof Download PDF

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Publication number
WO2006135195A1
WO2006135195A1 PCT/KR2006/002278 KR2006002278W WO2006135195A1 WO 2006135195 A1 WO2006135195 A1 WO 2006135195A1 KR 2006002278 W KR2006002278 W KR 2006002278W WO 2006135195 A1 WO2006135195 A1 WO 2006135195A1
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Prior art keywords
ceramic composition
ability
far infrared
present
filter
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PCT/KR2006/002278
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French (fr)
Inventor
Young-Moon Kim
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Young-Moon Kim
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Publication of WO2006135195A1 publication Critical patent/WO2006135195A1/en

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/515Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D39/00Filtering material for liquid or gaseous fluids
    • B01D39/02Loose filtering material, e.g. loose fibres
    • B01D39/06Inorganic material, e.g. asbestos fibres, glass beads or fibres
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • C02F1/003Processes for the treatment of water whereby the filtration technique is of importance using household-type filters for producing potable water, e.g. pitchers, bottles, faucet mounted devices
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/005Systems or processes based on supernatural or anthroposophic principles, cosmic or terrestrial radiation, geomancy or rhabdomancy
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04BGENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
    • E04B1/00Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
    • E04B1/62Insulation or other protection; Elements or use of specified material therefor
    • E04B1/74Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls
    • E04B1/76Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls specifically with respect to heat only
    • E04B1/78Heat insulating elements
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04CSTRUCTURAL ELEMENTS; BUILDING MATERIALS
    • E04C2/00Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels
    • E04C2/02Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials
    • E04C2/04Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials of concrete or other stone-like material; of asbestos cement; of cement and other mineral fibres
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/40Metallic constituents or additives not added as binding phase
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/40Metallic constituents or additives not added as binding phase
    • C04B2235/401Alkaline earth metals
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/42Non metallic elements added as constituents or additives, e.g. sulfur, phosphor, selenium or tellurium
    • C04B2235/428Silicon
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/72Products characterised by the absence or the low content of specific components, e.g. alkali metal free alumina ceramics
    • C04B2235/725Metal content
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/72Products characterised by the absence or the low content of specific components, e.g. alkali metal free alumina ceramics
    • C04B2235/728Silicon content
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/94Products characterised by their shape

Definitions

  • the present invention relates to multipurpose ceramic composition and the use thereof, more specifically to the composition comprising silicone, germanium and magnesium in the regular ratio and the use thereof as far infrared dispenser, the filter for water purifier and the lagging material for oven, heater and heating apparatus.
  • Ceramic is named as fine ceramics or new ceramics, which is also known as ceramics produced by the extruding method and the firing method which can be highly controlled the chemical composition minutely composed with an artificial material or a carefully selected material, unlike the conventional ceramics such as ceramic ware. Fine ceramics can be used in many purposes because it is more efficient than the conventional ceramics and has a new ability hitherto unknown to the art.
  • Fine ceramics can be divided into oxide based ceramics and non-oxide based ceramics, in which oxide based ceramics comprise alumina(Al 2 O 3 ), ferrite(Fe 2 O 3 ), zirconia(ZrO 2 ) and titania(TiO 2 ) etc., and non-oxide based ceramics comprise silicon carbide(SiC), silicon nitride(Si 3 N 4 ) etc.
  • oxide based ceramics comprise alumina(Al 2 O 3 ), ferrite(Fe 2 O 3 ), zirconia(ZrO 2 ) and titania(TiO 2 ) etc.
  • non-oxide based ceramics comprise silicon carbide(SiC), silicon nitride(Si 3 N 4 ) etc.
  • unearth abilities of the fine ceramics such as thermal ability, mechanical ability, biological and chemical ability, electric and electronic ability and optical ability have been found.
  • far infrared is a radiation having 4 to 400 ⁇ m of wavelength
  • far infrared has a characteristic of interfering in all organic material to change its molecular motion besides general characteristics as a radiation.
  • far infrared having 8 to 20 ⁇ m of wavelength have good permeability and act on organic materials to activate it.
  • the efficiency of far infrared like this have been discovered gradually and hereupon various products utilizing far infrared have been forwarded.
  • ceramic sources are used as far infrared radiating structures, in which ceramic sources and natural mineral sources are used as materials for synthesizing ceramic.
  • ceramic sources include materials on the basis of alumina, silicone, zirconia, titania etc.
  • Natural mineral sources include clay, mica, petalite, cordierite, mullite or sphene etc. and it used in synthesizing of far infrared radiating ceramic materials.
  • Such far infrared radiating ceramics are classified in accordance with its constituents, such as 1. alumina silicone series, 2. zircon series, 3. cordierite series and 4. synthetic product of other ceramic radiating materials.
  • Far infrared radiating structures of alumina silicone series are made of kaolinite, clay and talcum obtained in nature as main ingredient and it formed into the crystal by firing rather than non-firing in order to increase far infrared radiating efficiency. Also, far infrared radiating structures are constructed by mixing proper materials with proper amount according to the use. Also, far infrared radiating structures of zircon series are made of zircon sand obtained in nature as main ingredient, and it constructed by adding small amount of transition element such as Fe 2 O 3 and MnO 2 , and used as a raw material of tube type far infrared radiating structures and coating type far infrared radiating structures.
  • the far infrared radiating structures of cordierite series are made of kaolinite, clay and talcum obtained in nature as main ingredient and it used as a raw material of honeycomb type far infrared heating element which is prepared by press molding because it has high resistance to the heat-shock and very low thermal expansion coefficient due to the addition of MgO.
  • far infrared radiating structures synthesized by other ceramic radiating materials include one of adding Si 3 N 4 , SiC etc. to increase mechanical strength of ceramics.
  • Other natural materials radiating the far infrared include silicone, ferric oxide, titanium oxide, alumina calcium oxide, magnesium oxide, sodium oxide, potassium oxide.
  • ceramics having high far infrared radiating efficiency natural mineral material or ceramic materials are mixed according to its use, and then the mixture are sintered and processed.
  • mixing materials and mixing ratios can be varied.
  • the present inventor accomplish the present invention by establishing the fact that the ceramic composition having specific constitution is superior in far infrared radiating ability, excellent in water purification as well as have good emission ability of radiation energy to provide the use for the lagging material for oven, heater and heating apparatus.
  • the object of the present invention is to present the ceramic composition having superior far infrared radiating ability, excellent in water purification ability and heat energy radiating ability.
  • Another object of the present invention is to present the use of the ceramic composition.
  • the ceramic composition of the present invention is consist of 90 to 110 mg of Si, 20 to 40 mg of Mg and 0.5 to 1 mg of Ge per 1 kg of the ceramic composition.
  • the filter for water purification of the present invention is characterized in that the ceramic composition is formed into the sphere shape particle having diameter of below 10 mm and filled the tube for filter of the water purifier with the particle.
  • the size of the particle can be made vary from 3 to 10 mm according to the size of the water purifier.
  • the lagging material for heating of the present invention is characterized in that the ceramic composition is formed into the sphere shape particle having below 10 mm, preferably below 5 mm of diameter and made it into the board type.
  • the reason for forming the ceramic composition into the sphere shape of below specific size is to maximize its surface area.
  • the shape of the particle is not limited as long as it does not affect to surface area of the particle.
  • the ceramic composition of the present, invention can be applied to the oven, heater and confectionary/bakery by using its radiation energy radiating ability for the purpose of heating by the method known to the ordinary person.
  • Figure 1 is a graph showing an radiating ratio resulted by testing the negative ion radiation ability of the ceramic composition of the present invention
  • Figure 2 is a graph comparing radiation energy of the present invention and that of a black structures
  • Figure 3 is a perspective view showing a cutting plane of center part of the filter for water purification filled with the ball which is prepared with the ceramic composition of the present invention.
  • T the tube for the filter of purifier
  • Figure 3 is a perspective view showing a cutting plane of center part of the filter for water purification filled with the ball which is prepared with the ceramic composition of the present invention.
  • the ball which is filled into the filter for water purification of the present invention is prepared by forming the ceramic composition of the present invention into sphere shape ball having diameter of 5 mm and filling it into filter tube (T) of water purifier.
  • activated carbon filter has been used in order to filter impurities in a tap water.
  • the ball prepared by the ceramic composition of the present invention is used for the filter for water purifier.
  • the filter for water purifier of the present invention having a structure as described above have a maximized function of water purification ability, such as antifungal and anti-bacterial ability, elimination ability of heavy metal, elimination ability of chlorine and organic pollutant, weak-alkalization ability of water, mono-moleculation and activation ability of water, improvement ability of intracellular penetration(easiness of nutriment absorption and discharge), promotion ability of metabolism(improvement of spontaneous cure ability and strengthening of immunity), radiation of far infrared and negative ion abundantly, improvement ability of water taste by reducing cluster of water, radiation ability of negative ion abundantly.
  • water purification ability such as antifungal and anti-bacterial ability, elimination ability of heavy metal, elimination ability of chlorine and organic pollutant, weak-alkalization ability of water, mono-moleculation and activation ability of water, improvement ability of intracellular penetration(easiness of nutriment absorption and discharge), promotion ability of metabolism(improvement of spontaneous cure ability and strengthening of immunity), radiation of far infrared and negative
  • the lagging material for heating apparatus is prepared by the method for the preparation plaster board using about 5 mm of particle which is produced by general method. More specifically, inner papers for plaster board are spread and piled up continuously, and core material and fiber were applied with regular thickness upon the said inner papers. Spaces between core material and fiber are filled with the ball prepared above to the thickness of 20 mm, and upper side of core material and fiber is covered with papers several times. Adhesives are applied onto papers, and finally finishing paper of mesh type is adhered onto the adhesive layer and then obtained the board for heating apparatus.
  • Example 1 Preparation of the filter for water purification and Test of purifying ability
  • a 5mm of sphere shape ball was prepared with a ceramic composition comprising 97.71 mg of Si, 31 mg of Mg and 1 mg of Ge per 1 kg of the ceramic composition. Then, a filter for water purification was prepared with the resulting sphere shape ball.
  • a tap water was purified by the obtained filter for water purification, and then purified water was requested to the Korea Health Industry Development Institute to analyze the component of water. The result was demonstrated in Table 1.
  • the filter of the present invention is superior in antibacterial and sterilization activity, elimination ability of heavy metal and elimination ability of chlorine and organic pollutants because any bacteria was not detected.
  • Example 2 Preparation of the lagging material A 5mm of sphere shape ball was prepared with a ceramic composition comprising 97.71 mg of Si, 31 mg of Mg and 1 mg of Ge per 1 kg of the ceramic composition and used as a ball for board of the lagging material. Then, inner papers for plaster board are spread and piled up continuously, and core material and fiber were applied with regular thickness upon the said inner papers. Spaces between core material and fiber are filled with the ball prepared above to the thickness of 20 mm, and upper side of core material and fiber is covered with papers several times. Adhesives are applied onto papers, and finally finishing paper of mesh type is adhered onto the adhesive layer and then obtained the board for heating apparatus.
  • Example 3 Test for the radiation ability of far infrared and radiation energy
  • the board for heating apparatus prepared by example 2 was entrusted to the Korea Far Infrared Association to test for the radiation ability of far infrared and the radiation energy. The result was demonstrated in Figure 1 and 2.
  • the board for heating apparatus of the present invention was shown 3.70 -X 10 W/m ' ⁇ m of the radiation energy, radiation ratio in 5 to 20 ⁇ m was 0.920 as Figure 1.
  • the ceramic composition of the present invention is superior in far infrared radiating ability and excellent in purification ability of water as well as has good radiating ability of radiation energy, and thus the filter for water purification of the ceramic composition has effect on the antibacterial and sterilizing action, the elimination of heavy metal, the elimination of chlorine and organic pollutants, radiating large quantity of far infrared, enhancing the water taste by reducing water cluster(molecular group). Also, besides the lagging material for heater, the ceramic composition of the present invention can be applied to the oven, heater and confectionary/bakery by using its radiation energy radiating ability for the purpose of heating by the method known to the ordinary person.

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Abstract

The present invention relates to a multipurpose ceramic composition comprising silicone, germanium and magnesium with regular proportion, and to its use in preparation of far infrared radiating material, the filter for water purification, and the lagging material for oven, heater and heating apparatus, the ceramic composition of the present invention is characterized in comprising 90 to 110 mg of Si, 20 to 40 mg of Mg and 0.5 to 1 mg of Ge per 1 kg of the ceramic composition.

Description

[Specification]
MULTIPURPOSE CERAMIC COMPOSITION AND USAGE THEREOF [Technical Field]
The present invention relates to multipurpose ceramic composition and the use thereof, more specifically to the composition comprising silicone, germanium and magnesium in the regular ratio and the use thereof as far infrared dispenser, the filter for water purifier and the lagging material for oven, heater and heating apparatus.
[Background Art] Generally, ceramic is named as fine ceramics or new ceramics, which is also known as ceramics produced by the extruding method and the firing method which can be highly controlled the chemical composition minutely composed with an artificial material or a carefully selected material, unlike the conventional ceramics such as ceramic ware. Fine ceramics can be used in many purposes because it is more efficient than the conventional ceramics and has a new ability hitherto unknown to the art.
Fine ceramics can be divided into oxide based ceramics and non-oxide based ceramics, in which oxide based ceramics comprise alumina(Al2O3), ferrite(Fe2O3), zirconia(ZrO2) and titania(TiO2) etc., and non-oxide based ceramics comprise silicon carbide(SiC), silicon nitride(Si3N4) etc. Recently, unearth abilities of the fine ceramics such as thermal ability, mechanical ability, biological and chemical ability, electric and electronic ability and optical ability have been found. In the mean time, far infrared is a radiation having 4 to 400 μm of wavelength. According to the fact recently found out, it has been identified by the experiments that far infrared has a characteristic of interfering in all organic material to change its molecular motion besides general characteristics as a radiation. Especially, far infrared having 8 to 20 μm of wavelength have good permeability and act on organic materials to activate it. Particularly, it is known that as far infrared being applied to the human structures, it cause resonances in constituent molecular of the human structures to activate molecular motion and thus to stimulate the circulation of blood and metabolism. The efficiency of far infrared like this have been discovered gradually and hereupon various products utilizing far infrared have been forwarded.
Accordingly, there are many studies about the material which releases far infrared having characteristics described above. According to the thing to be found out to the present time, various ceramics are used as far infrared radiating structures, in which ceramic sources and natural mineral sources are used as materials for synthesizing ceramic. Especially, ceramic sources include materials on the basis of alumina, silicone, zirconia, titania etc. Natural mineral sources include clay, mica, petalite, cordierite, mullite or sphene etc. and it used in synthesizing of far infrared radiating ceramic materials. Such far infrared radiating ceramics are classified in accordance with its constituents, such as 1. alumina silicone series, 2. zircon series, 3. cordierite series and 4. synthetic product of other ceramic radiating materials. Far infrared radiating structures of alumina silicone series are made of kaolinite, clay and talcum obtained in nature as main ingredient and it formed into the crystal by firing rather than non-firing in order to increase far infrared radiating efficiency. Also, far infrared radiating structures are constructed by mixing proper materials with proper amount according to the use. Also, far infrared radiating structures of zircon series are made of zircon sand obtained in nature as main ingredient, and it constructed by adding small amount of transition element such as Fe2O3 and MnO2, and used as a raw material of tube type far infrared radiating structures and coating type far infrared radiating structures. Also, the far infrared radiating structures of cordierite series are made of kaolinite, clay and talcum obtained in nature as main ingredient and it used as a raw material of honeycomb type far infrared heating element which is prepared by press molding because it has high resistance to the heat-shock and very low thermal expansion coefficient due to the addition of MgO. Also, far infrared radiating structures synthesized by other ceramic radiating materials include one of adding Si3N4, SiC etc. to increase mechanical strength of ceramics. Also, there is far infrared radiating ceramic material, in which CuO, Fe2O3, MnO2, NiO, CoO etc. are added to increase far infrared radiating efficient.
Other natural materials radiating the far infrared include silicone, ferric oxide, titanium oxide, alumina calcium oxide, magnesium oxide, sodium oxide, potassium oxide. In order to constitute ceramics having high far infrared radiating efficiency, natural mineral material or ceramic materials are mixed according to its use, and then the mixture are sintered and processed. In accordance with the use of the ceramics, namely far infrared radiating ceramic materials for low temperature or high temperature and the required uses, mixing materials and mixing ratios can be varied. Thus, in constituting far infrared radiating ceramics, mixing of materials, management of plastic temperature, minute mixing ratio and mixing technique of other characteristic materials has been become the know-how
However, it is the actual circumstances that the above various ceramic materials were studied and referred nothing but to far infrared radiating ability, studied to water purification ability or emission ability of radiation energy in accordance with the constitution of the ceramic composition did not performed.
Accordingly, the present inventor accomplish the present invention by establishing the fact that the ceramic composition having specific constitution is superior in far infrared radiating ability, excellent in water purification as well as have good emission ability of radiation energy to provide the use for the lagging material for oven, heater and heating apparatus.
[Disclosure] [Technical Problem]
Accordingly, the object of the present invention is to present the ceramic composition having superior far infrared radiating ability, excellent in water purification ability and heat energy radiating ability.
Another object of the present invention is to present the use of the ceramic composition.
[Technical Solution] In order to accomplish the above objects, the ceramic composition of the present invention is consist of 90 to 110 mg of Si, 20 to 40 mg of Mg and 0.5 to 1 mg of Ge per 1 kg of the ceramic composition.
In another aspect of the present invention, the filter for water purification of the present invention is characterized in that the ceramic composition is formed into the sphere shape particle having diameter of below 10 mm and filled the tube for filter of the water purifier with the particle. Preferably, the size of the particle can be made vary from 3 to 10 mm according to the size of the water purifier.
In another aspect of the present invention, the lagging material for heating of the present invention is characterized in that the ceramic composition is formed into the sphere shape particle having below 10 mm, preferably below 5 mm of diameter and made it into the board type.
As described above, as the ceramic composition of the present invention is applied to the filter for water purification or the lagging material for heating apparatus, the reason for forming the ceramic composition into the sphere shape of below specific size is to maximize its surface area. Especially, the shape of the particle is not limited as long as it does not affect to surface area of the particle.
In addition, besides the lagging material for heater, the ceramic composition of the present, invention can be applied to the oven, heater and confectionary/bakery by using its radiation energy radiating ability for the purpose of heating by the method known to the ordinary person.
[Brief Description of the Figures]
Figure 1 is a graph showing an radiating ratio resulted by testing the negative ion radiation ability of the ceramic composition of the present invention, Figure 2 is a graph comparing radiation energy of the present invention and that of a black structures,
Figure 3 is a perspective view showing a cutting plane of center part of the filter for water purification filled with the ball which is prepared with the ceramic composition of the present invention.
** Explanation of a symbol in the principal part of drawings **
C: the ball for the filter of purifier
T: the tube for the filter of purifier
[Best Mode for Carrying Out the Invention]
In the followings, the present invention is described more detailed with reference to attached Figures.
Figure 3 is a perspective view showing a cutting plane of center part of the filter for water purification filled with the ball which is prepared with the ceramic composition of the present invention. The ball which is filled into the filter for water purification of the present invention is prepared by forming the ceramic composition of the present invention into sphere shape ball having diameter of 5 mm and filling it into filter tube (T) of water purifier.
In the general water purifier for purifying a tap water, activated carbon filter has been used in order to filter impurities in a tap water. On the contrary, instead of activated carbon filter, the ball prepared by the ceramic composition of the present invention is used for the filter for water purifier.
That is to say, the filter for water purifier of the present invention having a structure as described above have a maximized function of water purification ability, such as antifungal and anti-bacterial ability, elimination ability of heavy metal, elimination ability of chlorine and organic pollutant, weak-alkalization ability of water, mono-moleculation and activation ability of water, improvement ability of intracellular penetration(easiness of nutriment absorption and discharge), promotion ability of metabolism(improvement of spontaneous cure ability and strengthening of immunity), radiation of far infrared and negative ion abundantly, improvement ability of water taste by reducing cluster of water, radiation ability of negative ion abundantly.
By using emission ability of radiation energy of the ceramic composition according to the present invention, it is possible to make the ceramic composition into board type to use various construction materials. The lagging material for heating apparatus is prepared by the method for the preparation plaster board using about 5 mm of particle which is produced by general method. More specifically, inner papers for plaster board are spread and piled up continuously, and core material and fiber were applied with regular thickness upon the said inner papers. Spaces between core material and fiber are filled with the ball prepared above to the thickness of 20 mm, and upper side of core material and fiber is covered with papers several times. Adhesives are applied onto papers, and finally finishing paper of mesh type is adhered onto the adhesive layer and then obtained the board for heating apparatus.
The invention will be illustrated with reference to the non-limiting examples described hereinafter. Example 1. Preparation of the filter for water purification and Test of purifying ability
A 5mm of sphere shape ball was prepared with a ceramic composition comprising 97.71 mg of Si, 31 mg of Mg and 1 mg of Ge per 1 kg of the ceramic composition. Then, a filter for water purification was prepared with the resulting sphere shape ball.
A tap water was purified by the obtained filter for water purification, and then purified water was requested to the Korea Health Industry Development Institute to analyze the component of water. The result was demonstrated in Table 1.
<Table 1>
Figure imgf000009_0001
Figure imgf000010_0001
As seen by the above table 1, in the result of purifying a tap water by the filter using the ceramic composition of the invention, it can be understood that the filter of the present invention is superior in antibacterial and sterilization activity, elimination ability of heavy metal and elimination ability of chlorine and organic pollutants because any bacteria was not detected.
Example 2. Preparation of the lagging material A 5mm of sphere shape ball was prepared with a ceramic composition comprising 97.71 mg of Si, 31 mg of Mg and 1 mg of Ge per 1 kg of the ceramic composition and used as a ball for board of the lagging material. Then, inner papers for plaster board are spread and piled up continuously, and core material and fiber were applied with regular thickness upon the said inner papers. Spaces between core material and fiber are filled with the ball prepared above to the thickness of 20 mm, and upper side of core material and fiber is covered with papers several times. Adhesives are applied onto papers, and finally finishing paper of mesh type is adhered onto the adhesive layer and then obtained the board for heating apparatus.
Example 3: Test for the radiation ability of far infrared and radiation energy
The board for heating apparatus prepared by example 2 was entrusted to the Korea Far Infrared Association to test for the radiation ability of far infrared and the radiation energy. The result was demonstrated in Figure 1 and 2.
As seen by Figure 2, the board for heating apparatus of the present invention was shown 3.70 -X 10 W/m 'μm of the radiation energy, radiation ratio in 5 to 20 μm was 0.920 as Figure 1.
[Industrial Availability] As described above, the ceramic composition of the present invention is superior in far infrared radiating ability and excellent in purification ability of water as well as has good radiating ability of radiation energy, and thus the filter for water purification of the ceramic composition has effect on the antibacterial and sterilizing action, the elimination of heavy metal, the elimination of chlorine and organic pollutants, radiating large quantity of far infrared, enhancing the water taste by reducing water cluster(molecular group). Also, besides the lagging material for heater, the ceramic composition of the present invention can be applied to the oven, heater and confectionary/bakery by using its radiation energy radiating ability for the purpose of heating by the method known to the ordinary person.

Claims

[Claims] 1.
A multipurpose ceramic composition comprising 90 to 110 mg of Si, 20 to 40 mg of Mg and 0.5 to 1 mg of Ge per 1 kg of the ceramic composition.
2.
A filter for water purification which prepared by forming the ceramic composition comprising 90 to 110 mg of Si, 20 to 40 mg of Mg and 0.5 to 1 mg of Ge per 1 kg of the ceramic composition into sphere shape particle having diameter of below 10 mm and filling the particle into the tube of water purifier.
3.
A lagging material for heating apparatus which prepared by forming the ceramic composition comprising 90 to 110 mg of Si, 20 to 40 mg of Mg and 0.5 to 1 mg of Ge per 1 kg of the ceramic composition into sphere shape particle having diameter of below 10 mm and producing the board shape material with the particle.
PCT/KR2006/002278 2005-06-14 2006-06-14 Multipurpose ceramic composition and usage thereof WO2006135195A1 (en)

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CN102070324A (en) * 2010-09-25 2011-05-25 东莞乔隆家具配件制品有限公司 Making process of far infrared ceramic balls
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WO2000053541A1 (en) * 1999-03-09 2000-09-14 Song Si Hoon A vital matter and a producing method
KR20020039205A (en) * 2000-12-22 2002-05-25 호 근 김 Earthenware Pot for Storage of Water Containing Germanium
KR20030091175A (en) * 2002-05-24 2003-12-03 신일산업 주식회사 Ceramic heating element and method of the same

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000053541A1 (en) * 1999-03-09 2000-09-14 Song Si Hoon A vital matter and a producing method
KR20020039205A (en) * 2000-12-22 2002-05-25 호 근 김 Earthenware Pot for Storage of Water Containing Germanium
KR20030091175A (en) * 2002-05-24 2003-12-03 신일산업 주식회사 Ceramic heating element and method of the same

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