WO2006117846A1 - Oil and fat composition for frying and fried food - Google Patents
Oil and fat composition for frying and fried food Download PDFInfo
- Publication number
- WO2006117846A1 WO2006117846A1 PCT/JP2005/008002 JP2005008002W WO2006117846A1 WO 2006117846 A1 WO2006117846 A1 WO 2006117846A1 JP 2005008002 W JP2005008002 W JP 2005008002W WO 2006117846 A1 WO2006117846 A1 WO 2006117846A1
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- Prior art keywords
- oil
- frying
- fat
- composition
- mass
- Prior art date
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- 239000003921 oil Substances 0.000 claims description 255
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- 239000003925 fat Substances 0.000 claims description 172
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- 239000002540 palm oil Substances 0.000 claims description 22
- 238000000034 method Methods 0.000 claims description 18
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- 238000005194 fractionation Methods 0.000 claims description 13
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- 239000004033 plastic Substances 0.000 claims description 11
- 235000004977 Brassica sinapistrum Nutrition 0.000 claims description 10
- 239000003995 emulsifying agent Substances 0.000 claims description 8
- 238000004806 packaging method and process Methods 0.000 claims description 8
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- 229940116226 behenic acid Drugs 0.000 claims description 7
- 239000012530 fluid Substances 0.000 claims description 3
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- 238000011156 evaluation Methods 0.000 description 21
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 18
- 239000011630 iodine Substances 0.000 description 18
- 229910052740 iodine Inorganic materials 0.000 description 18
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 206010011469 Crying Diseases 0.000 description 2
- 235000019485 Safflower oil Nutrition 0.000 description 2
- 229930006000 Sucrose Natural products 0.000 description 2
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- 239000003963 antioxidant agent Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
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- 239000002285 corn oil Substances 0.000 description 2
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- 238000002425 crystallisation Methods 0.000 description 2
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- 239000002600 sunflower oil Substances 0.000 description 2
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 1
- 241000233788 Arecaceae Species 0.000 description 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
- 240000008415 Lactuca sativa Species 0.000 description 1
- 235000021353 Lignoceric acid Nutrition 0.000 description 1
- CQXMAMUUWHYSIY-UHFFFAOYSA-N Lignoceric acid Natural products CCCCCCCCCCCCCCCCCCCCCCCC(=O)OCCC1=CC=C(O)C=C1 CQXMAMUUWHYSIY-UHFFFAOYSA-N 0.000 description 1
- 102000004882 Lipase Human genes 0.000 description 1
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- 239000002253 acid Substances 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
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- 230000015556 catabolic process Effects 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
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- GVJHHUAWPYXKBD-UHFFFAOYSA-N d-alpha-tocopherol Natural products OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 235000006694 eating habits Nutrition 0.000 description 1
- FARYTWBWLZAXNK-WAYWQWQTSA-N ethyl (z)-3-(methylamino)but-2-enoate Chemical compound CCOC(=O)\C=C(\C)NC FARYTWBWLZAXNK-WAYWQWQTSA-N 0.000 description 1
- 235000013355 food flavoring agent Nutrition 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 235000013611 frozen food Nutrition 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 239000000787 lecithin Substances 0.000 description 1
- 235000010445 lecithin Nutrition 0.000 description 1
- 229940067606 lecithin Drugs 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
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- 235000013599 spices Nutrition 0.000 description 1
- 229960001295 tocopherol Drugs 0.000 description 1
- 229930003799 tocopherol Natural products 0.000 description 1
- 235000010384 tocopherol Nutrition 0.000 description 1
- 239000011732 tocopherol Substances 0.000 description 1
- 239000010913 used oil Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- GVJHHUAWPYXKBD-IEOSBIPESA-N α-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23D—EDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS OR COOKING OILS
- A23D9/00—Other edible oils or fats, e.g. shortenings or cooking oils
Definitions
- the present invention relates to an oil and fat composition for frying, and a frying food cooked using the oil and fat composition for frying.
- Patent Documents 1, 2, and 3 disclose that cooking is performed using an oil and fat composition for deep-fried foods to which a milky additive is added in order to maintain a crispy texture of fried food. ing. There are many unclear parts about the mechanism of texture improvement by adding milky glazes. Perhaps due to the amphipathic nature of the emulsifier, the ingredients are efficiently replaced with the moisture and oil content during fried cooking, reducing the amount of moisture contained in the clothing after cooking, resulting in improved taste. It is presumed that
- Patent Document 5 discloses an oil composition for frying containing 5.1 to 35.0% by mass of extremely hardened oil.
- extremely hardened oil a component that is solidified on the surface of the food that has been fried and is edible. Since the components of the oil and fat remain in liquid form, the appearance of the fried food will be poor.
- edible oils and fats that are liquid at room temperature are added with 10% by mass or more of extremely hardened oil, the entire oils and fats become solid at around 10 ° C, and handling becomes a problem.
- Patent Document 1 Japanese Patent Laid-Open No. 6-153794
- Patent Document 2 JP-A-9-74999
- Patent Document 3 Japanese Patent Laid-Open No. 2001-8618
- Patent Document 4 Japanese Patent No. 3028588
- Patent Document 5 Japanese Patent Laid-Open No. 2001-69913
- the problem to be solved by the present invention is to improve the handling properties of a frying oil composition used for frying.
- the problem to be solved by the present invention is to improve the transportability of a frying fat composition contained in a plastic or flexible bag such as a pillow packaging bag.
- the problem to be solved by the present invention is to reduce the oozing of oil from the garment of the fried food, and to further reduce the texture and taste deterioration of the garment over time after the frying of the fried food. That is.
- an oil and fat that is liquid at 0 ° C an oil and fat having a melting point of 5 to 30 ° C, and a saturated fatty acid having 20 to 24 carbon atoms are all components.
- the present inventors have found that the above-mentioned problems can be solved by using a frying oil composition containing a specific ratio of 10 to 75% by mass of fatty acid, and the present invention has been completed.
- the first aspect (aspect) of the present invention contains 10 to 90% by mass of the following oil and fat A, 9.9 to 99.9% by mass of oil and fat B, and 0.1 to 5% by mass of oil and fat C.
- the oil composition for frying having fluidity at 25 ° C.
- Oil A Oil that is liquid at 0 ° C.
- Fats and oils B Fats and oils with a melting point of 5-30 ° C.
- Fats and oils C Fats and oils whose saturated fatty acids having 20 to 24 carbon atoms are 10 to 75% by mass of the total constituent fatty acids.
- the content of the saturated fatty acid having 20 to 24 carbon atoms in the total constituent fatty acids of the fats and oils in the frying fat composition is 0.05 to 0.49% by mass. It is a fat and oil composition for frying as described in the embodiment.
- a third aspect of the present invention is the oil composition for frying according to the first aspect or the second aspect, wherein the fat and oil B contains palm-based fats and oils.
- the fat and oil B contains a transesterified oil and fat obtained by an ester exchange reaction between a palm-based fat and oil and a liquid fat and oil at 0 ° C.
- Aspect power The oil composition for frying according to any one of the third aspect.
- the fat B is obtained by subjecting palm oil and fat to a liquid fat at 0 ° C to an ester exchange reaction, and further subjecting the obtained transesterified fat to a dry fractionation treatment.
- 1st aspect power which is obtained fats and oils
- the frying oil as described in any one aspect of 3rd aspect It is a fat composition.
- the fat and oil C is a rapeseed extremely hardened oil having a saturated fatty acid content (behenic acid content) of 22 carbon atoms in all the constituent fatty acids of 20 to 60% by mass. It is the oil-fat composition for frying according to any one of the first to fifth embodiments.
- the seventh aspect of the present invention is the first aspect power 100 parts by mass of the frying oil composition according to any one of the sixth aspects, and 0.05 to 5 parts by mass of an emulsifier. It is a fat and oil composition for frying.
- An eighth aspect of the present invention is the fry oil composition according to any one of the first aspect, the seventh aspect, and the bag having plasticity or flexibility,
- the oil / fat composition for bags with frying which has plasticity or a softness
- a bag-containing oil composition for frying having plasticity or flexibility according to the eighth aspect, wherein the plastic or flexibility bag is a pillow packaging bag. It is.
- the oil composition for frying according to any one aspect of the first aspect or the seventh aspect, or the oil composition composition for frying according to the eighth or ninth aspect. It is the fried food cooked using the fats and oils composition for frying.
- An eleventh aspect of the present invention is the first aspect power of the frying fat composition according to any one of the seventh aspect, or the eighth or ninth frying fat composition product. This is a method of using the oil composition for frying in a plastic or flexible bag.
- a twelfth aspect of the present invention is the method according to the first aspect, wherein the plastic or flexible bag is a pillow packaging bag.
- the frying fat composition of the present invention has fluidity at 25 ° C, and the entire fat and oil does not solidify in a wide temperature range of 10-40 ° C, and solid-liquid separation also occurs. Since it has fluidity, it is excellent in handling and can improve the workability of frying. Moreover, the oil composition for frying in the bag which has the plasticity or the softness
- the fat A used in the present invention is a fat that is liquid at 0 ° C.
- the fats and oils A include soybean oil, rapeseed oil, high rapeseed rapeseed oil, corn oil, safflower oil, sunflower oil, cottonseed oil, linseed oil, etc., and one or more of these can be used. .
- the iodine value of fat A is ⁇ , preferably ⁇ 75-190, more preferably ⁇ 80-180, and most preferably ⁇ 90-180. .
- the fats and oils used in the present invention are fats and oils having a melting point of 5 to 30 ° C, more preferably fats and oils having a melting point of 10 to 30 ° C, and most preferably fats and oils having a melting point of 13 to 28 ° C.
- fats and oils B for example, palm oils such as palm oil, palm oil fractionation liquid part, palm oil fractionation middle melting point part, and palm oil two-stage fractionation liquid part, etc. And the like obtained by subjecting a transesterified fat and oil obtained by subjecting to a transesterification reaction with a palm-based fat and oil and a liquid oil and fat at 0 ° C. One or more of these can be used.
- palm oil fractionation liquid part palm oil two-stage fractionation, because heat and oxidation stability are high and handling property is good because melting point is lower than iodine value.
- Transesterified oil obtained by transesterification of liquid oil, palm oil and fat at 0 ° C, or transesterified oil obtained by transesterification of palm oil and liquid oil at 0 ° C It is preferable to use fats and oils obtained by dry fractionation.
- the iodine value of fat B is preferably 40 to 95, more preferably 45 to 85, and most preferably 50 to 80.
- the palm oil fractionation liquid part for example, a liquid oil part (palm oil two-stage fractionation liquid part or palms bar oil) obtained by subjecting palm oil to dry fractionation treatment after slow cooling twice is used. can do.
- a liquid oil part for example, Nisshin Oilo Co., Ltd. product Delica Ace OL can be mentioned.
- Transesterification obtained by transesterification of palm-based fats and oils and liquid oils at 0 ° C Palm-based fats and oils of palm oils, palm oil fractionation liquid parts, palm oil two-stage fractionation liquid parts , And one or more of fats and oils such as palm middle melting point.
- oils and fats that are liquid at 0 ° C. include soybean oil, rapeseed oil, oil, ioletsk rapeseed oil, corn oil, safflower oil, sunflower oil, cottonseed oil, flaxseed oil, etc. Species or two or more can be used.
- transesterification known methods for transesterification of fats and oils can be used.
- transesterified fats and oils obtained by dry-separating the transesterified fats and oils obtained by subjecting the palm-based fats and oils and liquids at 0 ° C to a transesterification reaction are subjected to the dry separation process.
- Transesterified oils and fats are gradually cooled at a rate of 0.5 to 5 ° C per hour, and the liquid oil part is filtered by a press filter at 10 to 20 ° C, and the solid fat remaining in the filter is recovered. This is the method.
- liquid oil obtained by dry separation of transesterified fat and oil obtained by transesterification of palm fat and liquid oil at 0 ° C for example, products manufactured by Nisshin Oilio Co., Ltd .: Royal Dish Etc.
- the fat and oil C used in the present invention is a fat and oil in which a saturated fatty acid having 20 to 24 carbon atoms in all the constituent fatty acids is 10 to 75% by mass, more preferably 15 to 70% by mass, and most preferably 30 to 70% by mass. is there.
- the saturated fatty acid having 20 to 24 carbon atoms include araquinic acid, behenic acid (saturated fatty acid having 22 carbon atoms), lignoceric acid, and the like. Or two or more types.
- Examples of the fat C include rapeseed extremely hardened oil, fish oil extremely hardened oil, lard extremely hardened oil, etc., having a saturated fatty acid content of 22 carbon atoms (behenic acid content) in all the constituent fatty acids of 20 to 60% by mass. One or more of these can be used.
- the rapeseed extremely hardened oil having a saturated fatty acid content of 22 carbon atoms (behenic acid content) in all the constituent fatty acids of 20 to 60% by mass is higher than fish oil hardened oil and lard extremely hardened oil.
- the total fatty acid content of C22 is high (behenic acid content). Therefore, when the same amount of these fats and oils is contained as the fat and oil C, the saturated fatty acid content having 20 to 24 carbon atoms in the total fatty acids of the fat and oil in the frying fat and oil composition can be increased. It has merit in cost.
- the saturated fatty acid content (behenic acid content) of 22 carbon atoms in the total fatty acid of the rapeseed extremely hardened oil is preferably 20-60. % By mass, more preferably 25 to 60% by mass, most preferably 30 to 60% by mass.
- the melting point of fat C is preferably 40 to 80 ° C, more preferably 40 to 70 ° C, and most preferably 50 to 70 ° C. Furthermore, the iodine value of the fat C is preferably 0 to 5, more preferably 0 to 3, and most preferably 0 to 1.5.
- the content of fat and oil A in the frying fat and oil composition of the present invention is 10 to 90% by mass, more preferably 30 to 70% by mass, and most preferably 40 to 60% by mass. If it is less than 10, the entire fats and oils solidify at low temperatures, and good handling properties cannot be obtained, and if it is more than 90% by mass, the solidification rate when it is made into a frozen food is reduced, preventing oil stains and improving the texture. This is because the effect cannot be obtained.
- the content of fat B in the frying fat yarn ⁇ product of [0034] the present invention 9.9 to 89.9 wt%, preferably Ri yo ⁇ is 29.9 to 69.9 mass 0/0, most preferably ⁇ is 39.9 to 59.9 mass 0/0. If it is less than 9, the amount of crystals decreases and the rate of solidification when it is made into fried foods decreases, resulting in oil dyeing. This is because when the amount exceeds 89.9% by mass, the entire fats and oils solidify at low temperatures and good handling properties cannot be obtained.
- the content of fat and oil C in the frying fat and oil composition of the present invention is 0.1 to 5% by mass, more preferably 0.1 to 4.5% by mass, and most preferably 0.1 to 3%. % By mass. If it is less than 0.1, the crystallization rate will not be sufficiently increased, and oil stain prevention and texture improvement effects will not be obtained. If it is more than 5% by mass, the entire oil and fat will be solidified at low temperatures. This is because handling is not possible.
- the saturated fatty acid content of 20 to 24 carbon atoms in the total fatty acids of the fats and oils in the frying fat and oil composition of the present invention varies depending on the content of component C in the frying fat and oil composition. In order to further improve the handleability of the composition and the texture of the resulting fried food, it is preferably 0.05 to 0.49% by mass in the total constituent fatty acids 0.1 to 0.45. More preferably, the amount is 0.1 to 0.4% by mass.
- the frying fat composition of the present invention may contain an emulsifier for the purpose of preventing solid-liquid separation during storage at ordinary temperature and low temperature.
- the emulsifier content is preferably 0.05 to 5 parts by mass, more preferably 0.1 to 4.0 parts by mass, and most preferably 0.1 to 3.0 parts by mass with respect to 100 parts by mass of the fat and oil composition for frying. Part by mass.
- emulsifier examples include glycerin fatty acid ester, polyglycerin fatty acid ester, sucrose fatty acid ester, sorbitan fatty acid ester and the like, and one or more of these can be used.
- sucrose fatty acid ester because it has a large effect on crystal behavior even in a small amount.
- Substances such as anti-oxidant agents, antifoaming agents, colorants, flavoring agents, spices and the like that are usually added to the oils and fats are usually added to the oil composition for frying according to the present invention. It can be added in the range of the specified amount.
- Specific examples of the additive substance include tocopherol, lecithin, and silicone corn fat.
- the frying oil / fat composition of the present invention is fluidized at 25 ° C, although it is entirely clouded and uniformly crystallized. Furthermore, in a wide temperature range of 10 to 40 ° C, the entire fats and oils do not solidify, and they have fluidity without causing solid-liquid separation, so they have excellent handling properties and improve the workability of frying. Can be made.
- the oils and fats solidify when fried in an environment of 10 to 40 ° C, the container force must be taken out or dissolved by heating, which is very laborious. It ’s going to happen.
- the oil and fat composition for frying of the present invention can be used in a wide temperature range of 10 to 40 ° C because it does not solidify the entire oil and fat and does not cause solid-liquid separation. In this case, effort is not required and the workability of frying is improved.
- the oil composition for frying of the present invention has such physical properties, for example, after holding a funnel can filled with the oil composition for frying for 6 hours at 10 ° C in a thermostatic bath. Hold at 5 ° C for 6 hours, then store at 10 ° C for 6 hours and at 5 ° C for 6 hours, then leave at 20 ° C for 1 hour, then open the canister and invert. However, the bulk of the fat and oil crystals can be smoothly discharged from the dough can. As described above, since the handling property is excellent, the working efficiency of the fly can be improved.
- the frying oil composition of the present invention can be used in a plastic or flexible bag such as a pillow packaging bag or a bouch.
- the oily composition for bag frying having plasticity or flexibility of the present invention is obtained by putting the oily composition for frying of the present invention described above in a bag having the above plasticity or flexibility.
- the fat and oil composition for frying of the present invention is characterized in that it becomes solid at or below o ° c. Therefore, the oil composition for frying of the present invention (plastic or flexible oil composition for frying bag having the flexibility or flexibility) put in a plastic or flexible bag such as a pillow-wrapped bag or a bouch is as follows. Excellent transportability and handling.
- plastic or flexible bags such as pillow packaging bags containing edible fats and oils
- plastic or flexible bags are usually lighter in weight than those filled in a can, and oil can be easily taken out.
- the oil and fat composition for frying of the present invention is hard at o ° c or less. Therefore, the frying oil / fat composition of the present invention (plastic / flexible bag oil / fat composition having flexibility or flexibility) put in a plastic or flexible bag such as a pillow packaging bag is not changed.
- freezing it can be handled as a solid material that is difficult to deform and can be easily transported.
- it has fluidity as explained above, so it has excellent handling properties.
- the fried food cooked using the oil composition for frying according to the present invention described so far can maintain a talispy texture for a long period of time, and further ooze oil from the fried food to paper napkins and the like. Can be significantly reduced.
- the obtained fried food does not feel an artificial off-flavor such as hydrogenated odor, and therefore has a good flavor.
- It can be produced by putting fats and oils A, fats and oils B and fats and oils C in a stainless steel container and mixing and dissolving them at 60 to 90 ° C. for 0.1 to 2 hours by stirring with an agitator.
- an additive such as an emulsifier and an antioxidant
- it may be added to the fat A in advance, or may be added after mixing the fat A, fat B, and fat C.
- the fried food of the present invention can be produced by using the frying fat composition described above and using a normal frying method. At that time, both non-frozen and frozen products can be used as the frying species.
- Soybean white oil (Nisshin Oilio Co., Ltd., trade name: Nissin Soybean White Oil, iodine value 128) is 50 kg as fat A, 49.8 kg of fat 1 obtained in Production Example 1 as fat B, Rapeseed extremely hardened oil as fat C (melting point 61 ° C, iodine value 0.6, saturated fatty acid having 20 to 24 carbon atoms in all constituent fatty acids 56 mass%, saturated fatty acid having 22 carbon atoms in all constituent fatty acids) 100 kg of frying oil composition 1 was obtained by putting 0.2 kg in a 150 liter stainless steel container and mixing and dissolving at 70 ° C. for 0.5 hour by stirring with an agitator.
- the obtained frying fat / oil composition has fluidity at 25 ° C, has a melting point of 4.7 ° C and an iodine value of 102, and is contained in all the constituent fatty acids of the fat / oil in the frying fat / oil composition.
- the content of saturated fatty acids having 20 to 24 carbon atoms was 0.11% by mass.
- Soy white squeezed oil (manufactured by Nisshin Oillio Co., Ltd., trade name: Nisshin Soy White Squeezed Oil, iodine value 128) as fat A and oil B, palm oil two-stage fractionated liquid part (melting point 14 ° C, iodine No.
- oil and fat C as rapeseed extremely hardened oil (melting point 61 ° C, iodine number 0.6, saturated fatty acids with 20 to 24 carbon atoms are 56% by mass of all constituent fatty acids, carbon in all constituent fatty acids
- the fat and oil composition for frying is obtained by putting the saturated fatty acid content of number 22 into a 0.6 kg 150 liter stainless steel container and mixing and dissolving at 70 ° C. for 0.5 hour by stirring with an agitator. 100kg was obtained.
- the resulting frying oil / fat composition has fluidity at 25 ° C, has a melting point of 2.8 ° C, an iodine value of 95, and carbon in all fatty acids of the oil / fat in the frying oil / fat composition.
- the saturated fatty acid content of the number 20-24 was 0.24% by mass.
- a croquette was fried in the same manner as in Example 3 except that the frying oil / fat composition 2 was used instead of the frying oil / fat composition 1.
- Each evaluation can be performed by repeating the same operation. Cooked as many fried croquettes as needed for the price.
- Oil composition for frying 1 instead of soy white squeezed oil (Nisshin Oilio Co., Ltd., trade name: Nisshin soy white squeezed oil, iodine value 128) and palm oil two-stage fractionated liquid part (melting point 14 ° C
- soy white squeezed oil Nisshin Oilio Co., Ltd., trade name: Nisshin soy white squeezed oil, iodine value 1278
- palm oil two-stage fractionated liquid part melting point 14 ° C
- the croquette was fried using the same method as in Example 3 except that the oil composition 3 for frying prepared at a mass ratio of 6: 4 was used. In addition, by repeating the same operation, the necessary number of fried croquettes were prepared for each evaluation.
- Oil composition for frying 1 instead of soybean white oil (Nisshin Oilio Co., Ltd., trade name: Nisshin soybean white oil, iodine value 128) and rapeseed extremely hardened oil (melting point 61 ° C, iodine value) 0.6, for frying, in which a saturated fatty acid having 20 to 24 carbon atoms is 56% by mass of the total fatty acid, and a saturated fatty acid content of 22 carbon atoms in the total fatty acid is 46% by mass) at a mass ratio of 95: 5
- the croquette was fried using the same method as in Example 3 except that the oil and fat composition 4 was used. In addition, by repeating the same operation, the necessary number of fried croquettes were prepared for each evaluation.
- the fried croquettes obtained by the cooking methods shown in Examples 3 and 4 and Comparative Examples 1 to 3 were placed on a stainless steel net immediately after being fried and allowed to cool for 10 minutes, and then a pair of paper wastes with constant weight.
- One product was placed on top of (Kureshia Co., Ltd., trade name: Kim Towel) and left at 20 ° C for 4 hours.
- Each fried croquette left for 4 hours was removed from the paper waste, the quality of the paper waste was measured, and the constant weight value of the paper waste before placing the fried croquette was subtracted to calculate the increased mass of the paper waste.
- Table 1 The results for the fried croquettes cooked in Examples 3 and 4 and Comparative Examples 1 to 3 are shown in Table 1.
- Table 1 are the average values of increased mass measured with 20 fried croquettes.
- the cause of the increase in the mass of paper waste is that it contains water in addition to the oil that exudes from croquettes.
- the same croquette was used in all tests, it was considered that there was no difference in the mass of the exuded water, and the difference in the increased mass was evaluated as the difference in the amount of oil oozing out from the fried croquette.
- the frying oil composition 1 and 2 are used in the frying fat composition 1 and 2 in spite of the fact that a saturated fatty acid having 20 to 24 carbon atoms is mixed with 56% by mass of rapeseed extremely hardened oil. The effect was not as good as when using.
- the acoustic evaluation shows that the average value of the sound pressure value in the crispness range is large! /, So that there is a sense of crispyness. It was evaluated to hold
- the fried croquette using the frying oil composition 1 and 2 is more crispness (crispiness, than the fried croquette using the soy bean oil extract and the frying oil composition 3 and 4. It was found that the sound pressure value in the sound range was significantly high, and that it had a good texture.
- the touch is rough.
- Oil composition for frying 1 to 4 and soybean white squeeze oil 15.Okg each was packed in a separately weighed can, left in a thermostatic bath at 10 ° C for 6 hours, and then 6 ° C at 5 ° C.
- a cycle storage test was conducted in which the sample was allowed to stand for 10 hours, and further allowed to stand at 10 ° C. for 6 hours, and further allowed to stand at 5 ° C. for 6 hours.
- each can was left in a room at 20 ° C for 1 hour. Then, each Ito can was opened and held upside down for 5 minutes to discharge the contents. The amount of residual material in the can was determined by measuring the mass of each can.
- the test results are shown in Tables 7 and 8.
- Oil lipid content (kg) 15. 0 15. 0
- the oil composition for frying 1 and 2 of the present invention was accelerated by crystallization and became cloudy and slightly increased in viscosity by cycle storage. However, the coarse crystal lump could be discharged smoothly from the Ito Can.
- the oil composition for frying oil 3 containing no fats and oils with a saturated fatty acid content of 20 to 24 carbon atoms in the range of 10 to 75% by mass is mixed with countless fine crystals by changing the storage temperature in a cycle. Several crystal lumps of about 2 cm were formed, which proved that solid-liquid separation and crystal coarsening could not be suppressed.
- it contains oils and fats that are liquid at 0 ° C, and fats and oils whose saturated fatty acid content of carbon number 20 to 24 in all constituent fatty acids is 10 to 75% by mass. Does not contain oils with melting point 5 to 30 ° C.
- the oil / fat composition 4 was found to cause crystals to stick to the bottom of the can when the storage temperature was cycled, resulting in stickiness of the crystals.
- Soy white squeezed oil showed a slight increase in viscosity when the storage temperature was changed in a cycle. It was clear with no precipitation of crystals, and could be discharged with a high yield.
- the oil and fat composition for frying of the present invention can be used as a fat and oil for frying that is used when producing fried foods such as empty-baffled, fried food, and snacks.
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Abstract
Disclosed is an oil and fat composition for frying which contains 10-90% by mass of an oil or fat which is in a liquid state at 0°C, 9.9-89.9% by mass of an oil or fat having a melting point of 5-30°C, and 0.1-5% by mass of an oil or fat wherein a saturated fatty acid having 20-24 carbon atoms constitutes 10-75% by mass of the total constituent fatty acids. This oil and fat composition for frying has fluidity at 25°C.
Description
明 細 書 Specification
フライ用油脂組成物及びフライ食品 Oil composition for frying and fried food
技術分野 Technical field
[0001] 本発明は、フライ用油脂組成物、及び該フライ用油脂組成物を用いて調理したフラ ィ食品に関する。 [0001] The present invention relates to an oil and fat composition for frying, and a frying food cooked using the oil and fat composition for frying.
背景技術 Background art
[0002] 天ぶら、フライ、スナック菓子等のフライ食品における最近の消費者の嗜好は、外部 への油の染み出しが少なぐかつ衣の保形性が良好で、サクサクとしたクリスピ一な 食感のものが好まれる傾向にある。そして、一般家庭でサラダ油を用いて調理し、揚 げたてのものをすぐに食べてしまう場合には、その食感はほとんど問題になることは ない。しかし、調理して力 数時間経過してしまうと、その食感や風味の劣化は避ける ことができない。 [0002] The recent consumer preference for fried foods such as fried foods, fried foods, snacks, etc. is that there is little oil leaching to the outside, the shape of the clothes is good, and the crispy and crispy texture Tends to be preferred. And if you cook with salad oil in a general household and eat freshly fried foods immediately, the texture is hardly a problem. However, after cooking for several hours, deterioration of the texture and flavor cannot be avoided.
[0003] また、商業的にフライ食品を提供する場合には、フライ調理をして力も消費者がそ れを食するまでに数時間経過してしまうため、食感や風味の劣化してしまうことが避け られないのが現状である。このフライ食品の食感や風味の劣化は、フライ調理後の時 間が経過することで、具材力 衣へ水分が移行することによって衣の保形性が失わ れ、フライ食品全体がしんなりすることにより生じていると考えられる。 [0003] In addition, when providing fried foods commercially, it takes several hours for the consumer to eat fried food and eat it, so the texture and flavor deteriorate. This is unavoidable. The deterioration of the texture and flavor of this fried food is due to the passage of time after fried cooking, and the moisture content is transferred to the ingredients and the shape retention of the clothing is lost, and the whole fried food is softened. This is thought to be caused by
[0004] しかし、家庭でフライ食品を調理してもすぐに食しな 、ことは多ぐまた、消費者の食 生活の変化により、家庭で調理してフライ食品を食するよりも、お店でフライ食品を購 入する機会も増えたため、食感や風味の劣化をしにくいフライ食品が求められている 特に、商業的に提供するフライ食品においては、その商品価値を高めるために、衣 の保形性低下や食感 ·風味の劣化が可能な限り遅く発現するか、劣化が起こっても その程度が弱いものを提供しようとさまざまな検討が行われている。 [0004] However, even when fried food is cooked at home, it is often not eaten immediately. Also, due to changes in consumer eating habits, it is more likely to be eaten at a store than at home. Because of the increased opportunity to purchase fried foods, there is a need for fried foods that are less susceptible to deterioration in texture and flavor. Especially for fried foods that are provided commercially, in order to increase their commercial value, Various studies have been conducted to provide products that exhibit a decrease in formability, texture, and flavor as late as possible, or that weaken even when degradation occurs.
[0005] 特許文献 1、 2、及び 3には、フライ食品のサクサクとした食感を維持するために、乳 ィ匕剤を添加した揚げ物用油脂組成物を用いて調理を行うことが開示されている。乳 ィ匕剤を添加したことによる食感改良のメカニズムについては不明な部分が多いが、お
そらく乳化剤の両親媒性により、揚げ調理の際に具材ゃ衣の水分と油分との置換を 効率よく行い、調理後の衣に含まれる水分量を下げ、結果として食味の改善を達成 しているものと推測される。 [0005] Patent Documents 1, 2, and 3 disclose that cooking is performed using an oil and fat composition for deep-fried foods to which a milky additive is added in order to maintain a crispy texture of fried food. ing. There are many unclear parts about the mechanism of texture improvement by adding milky glazes. Perhaps due to the amphipathic nature of the emulsifier, the ingredients are efficiently replaced with the moisture and oil content during fried cooking, reducing the amount of moisture contained in the clothing after cooking, resulting in improved taste. It is presumed that
しかし、油脂を繰り返し使用することを考えると、この方法のみを用いてフライ食品を 製造した場合、繰り返し油脂を使用することで油脂中の乳化剤含量が減少してしまい 、それにより食感改善効果が減少してしまうという欠点がある。 However, considering the repeated use of fats and oils, when fried foods are produced using only this method, the use of repeated fats and oils reduces the emulsifier content in the fats and oils, thereby improving the texture. There is a disadvantage that it decreases.
[0006] また、水添硬化油脂等の融点 25°C以上の油脂に、油脂の固化速度を高める目的 で高工ルカ酸ナタネ油の極度硬化油脂を配合したドーナツ用フライ油脂を用いること で、油のべトつきゃシュガリングの泣き防止を改善することが開示されている(特許文 献 4)。しかし、この方法によって提供されるフライ油は、目的がドーナツのシュガリン グの泣き防止にほぼ限定されるため、フライ調理用の油脂としては、風味や常温にお けるハンドリング性の面で汎用性に欠けてしまうという問題がある。 [0006] Further, by using a frying fat for donuts in which an oil having a melting point of 25 ° C or higher such as hydrogenated hydrogenated fat is mixed with an extremely hardened oil of high-tech rapeseed oil for the purpose of increasing the solidification rate of the fat, It has been disclosed that oily stickiness improves the prevention of sugaring crying (Patent Document 4). However, since the purpose of the frying oil provided by this method is almost limited to preventing the crying of donut sugaring, it is versatile in terms of flavor and handling at room temperature. There is a problem of lacking.
[0007] さらに、特許文献 5には、極度硬化油を 5. 1〜35. 0質量%含有するフライ用油脂 組成物が開示されている。しかしながら、室温で液状の食用油脂に極度硬化油を 6 質量%程度添加したものを用いてフライをした場合、フライ調理した食品の表面で、 極度硬化油成分のみが固体化し、室温で液状の食用油脂の成分が液状のまま存在 するため、フライ食品の見栄えが悪くなつてしまう。また、室温で液状の食用油脂に、 極度硬化油を 10質量%以上添加したものについては 10°C付近で油脂全体が固体 化してしまうため、ハンドリング性が問題となってしまう。 [0007] Further, Patent Document 5 discloses an oil composition for frying containing 5.1 to 35.0% by mass of extremely hardened oil. However, if fried food is used with edible oils and fats that are liquid at room temperature, with about 6% by weight of extremely hardened oil, only the extremely hardened oil component is solidified on the surface of the food that has been fried and is edible. Since the components of the oil and fat remain in liquid form, the appearance of the fried food will be poor. In addition, when edible oils and fats that are liquid at room temperature are added with 10% by mass or more of extremely hardened oil, the entire oils and fats become solid at around 10 ° C, and handling becomes a problem.
特許文献 1:特開平 6— 153794号公報 Patent Document 1: Japanese Patent Laid-Open No. 6-153794
特許文献 2:特開平 9 - 74999号公報 Patent Document 2: JP-A-9-74999
特許文献 3:特開 2001 - 8618号公報 Patent Document 3: Japanese Patent Laid-Open No. 2001-8618
特許文献 4:特許第 3028588号公報 Patent Document 4: Japanese Patent No. 3028588
特許文献 5:特開 2001— 69913号公報 Patent Document 5: Japanese Patent Laid-Open No. 2001-69913
発明の開示 Disclosure of the invention
発明が解決しょうとする課題 Problems to be solved by the invention
[0008] 本発明が解決しょうとする課題は、フライ調理に用いるフライ用油脂組成物のハンド リング性を向上させることにある。
また、本発明が解決しょうとする課題は、ピロ一包装袋のような可塑性又は柔軟性 を有する袋に入れたフライ用油脂組成物の運搬性を向上させることにある。 [0008] The problem to be solved by the present invention is to improve the handling properties of a frying oil composition used for frying. The problem to be solved by the present invention is to improve the transportability of a frying fat composition contained in a plastic or flexible bag such as a pillow packaging bag.
さらに、本発明が解決しょうとする課題としては、フライ食品の衣からの油の染み出 しを減少させ、さらにフライ食品のフライ後の時間経過による衣の食感や食味の低下 を減少、させることである。 Further, the problem to be solved by the present invention is to reduce the oozing of oil from the garment of the fried food, and to further reduce the texture and taste deterioration of the garment over time after the frying of the fried food. That is.
課題を解決するための手段 Means for solving the problem
[0009] 本発明者らは、上記課題を解決するために鋭意研究した結果、 0°Cで液状の油脂 、融点 5〜30°Cの油脂、及び炭素数 20〜24の飽和脂肪酸が全構成脂肪酸の 10〜 75質量%である油脂を、特定割合含有するフライ用油脂組成物を用いれば、上記 課題を解決できることを見出し、本発明を完成するに至った。 [0009] As a result of intensive studies to solve the above problems, the present inventors have found that an oil and fat that is liquid at 0 ° C, an oil and fat having a melting point of 5 to 30 ° C, and a saturated fatty acid having 20 to 24 carbon atoms are all components. The present inventors have found that the above-mentioned problems can be solved by using a frying oil composition containing a specific ratio of 10 to 75% by mass of fatty acid, and the present invention has been completed.
すなわち、本発明の第 1の態様 (aspect)は、次の油脂 Aを 10〜90質量%、油脂 B を 9. 9〜89. 9質量%、油脂 Cを 0. 1〜5質量%含有し、 25°Cにおいて流動性を有 するフライ用油脂組成物である。 That is, the first aspect (aspect) of the present invention contains 10 to 90% by mass of the following oil and fat A, 9.9 to 99.9% by mass of oil and fat B, and 0.1 to 5% by mass of oil and fat C. The oil composition for frying having fluidity at 25 ° C.
油脂 A: 0°Cで液状の油脂。 Oil A: Oil that is liquid at 0 ° C.
油脂 B:融点 5〜30°Cの油脂。 Fats and oils B: Fats and oils with a melting point of 5-30 ° C.
油脂 C :炭素数 20〜24の飽和脂肪酸が、全構成脂肪酸の 10〜75質量%である油 脂。 Fats and oils C: Fats and oils whose saturated fatty acids having 20 to 24 carbon atoms are 10 to 75% by mass of the total constituent fatty acids.
[0010] 本発明の第 2の態様は、フライ用油脂組成物中の油脂の全構成脂肪酸中の炭素 数 20〜24の飽和脂肪酸含量が 0. 05〜0. 49質量%である第 1の態様に記載のフ ライ用油脂組成物である。 [0010] In the second aspect of the present invention, the content of the saturated fatty acid having 20 to 24 carbon atoms in the total constituent fatty acids of the fats and oils in the frying fat composition is 0.05 to 0.49% by mass. It is a fat and oil composition for frying as described in the embodiment.
[0011] 本発明の第 3の態様は、油脂 Bが、パーム系油脂を含有するものである第 1の態様 又は第 2の態様に記載のフライ用油脂組成物である。 [0011] A third aspect of the present invention is the oil composition for frying according to the first aspect or the second aspect, wherein the fat and oil B contains palm-based fats and oils.
[0012] 本発明の第 4の態様は、油脂 Bが、パーム系油脂と 0°Cで液状の油脂とを、エステ ル交換反応して得られるエステル交換油脂を含有するものである第 1の態様力 第 3 の態様のいずれか 1つの態様に記載のフライ用油脂組成物である。 [0012] In a fourth aspect of the present invention, the fat and oil B contains a transesterified oil and fat obtained by an ester exchange reaction between a palm-based fat and oil and a liquid fat and oil at 0 ° C. Aspect power The oil composition for frying according to any one of the third aspect.
[0013] 本発明の第 5の態様は、油脂 Bが、パーム系油脂と 0°Cで液状の油脂とを、エステ ル交換反応し、さらに得られたエステル交換油脂を乾式分別処理することにより得ら れる油脂である第 1の態様力 第 3の態様のいずれか 1つの態様に記載のフライ用油
脂組成物である。 [0013] In a fifth aspect of the present invention, the fat B is obtained by subjecting palm oil and fat to a liquid fat at 0 ° C to an ester exchange reaction, and further subjecting the obtained transesterified fat to a dry fractionation treatment. 1st aspect power which is obtained fats and oils The frying oil as described in any one aspect of 3rd aspect It is a fat composition.
[0014] 本発明の第 6の態様は、油脂 Cが、全構成脂肪酸中の炭素数 22の飽和脂肪酸含 量 (ベヘン酸含量)が 20〜60質量%である菜種極度硬化油、である第 1の態様から 第 5の態様のいずれか 1つの態様に記載のフライ用油脂組成物である。 [0014] In a sixth aspect of the present invention, the fat and oil C is a rapeseed extremely hardened oil having a saturated fatty acid content (behenic acid content) of 22 carbon atoms in all the constituent fatty acids of 20 to 60% by mass. It is the oil-fat composition for frying according to any one of the first to fifth embodiments.
[0015] 本発明の第 7の態様は、第 1の態様力 第 6の態様のいずれか 1つの態様に記載 のフライ用油脂組成物を 100質量部、及び乳化剤を 0. 05〜5質量部含有するフライ 用油脂組成物である。 [0015] The seventh aspect of the present invention is the first aspect power 100 parts by mass of the frying oil composition according to any one of the sixth aspects, and 0.05 to 5 parts by mass of an emulsifier. It is a fat and oil composition for frying.
[0016] 本発明の第 8の態様は、第 1の態様力 第 7の態様のいずれか 1つの態様に記載 のフライ用油脂組成物と、可塑性又は柔軟性を有する袋を有し、前記フライ用油脂 組成物が前記袋に入れられたものである可塑性又は柔軟性を有する袋入りフライ用 油脂組成物である。 [0016] An eighth aspect of the present invention is the fry oil composition according to any one of the first aspect, the seventh aspect, and the bag having plasticity or flexibility, The oil / fat composition for bags with frying which has plasticity or a softness | flexibility which is the oil-fat composition put into the said bag.
[0017] 本発明の第 9の態様は、前記可塑性又は柔軟性を有する袋が、ピロ一包装袋であ る第 8の態様に記載の可塑性又は柔軟性を有する袋入りフライ用油脂組成物製品で ある。 [0017] According to a ninth aspect of the present invention, there is provided a bag-containing oil composition for frying having plasticity or flexibility according to the eighth aspect, wherein the plastic or flexibility bag is a pillow packaging bag. It is.
[0018] 本発明の第 10の態様は、第 1の態様力も第 7の態様のいずれか 1つの態様に記載 のフライ用油脂組成物、又は第 8又は第 9のフライ用油脂組成物製品のフライ用油脂 組成物を用いて調理したフライ食品である。 [0018] According to a tenth aspect of the present invention, there is provided the oil composition for frying according to any one aspect of the first aspect or the seventh aspect, or the oil composition composition for frying according to the eighth or ninth aspect. It is the fried food cooked using the fats and oils composition for frying.
[0019] 本発明の第 11の態様は、第 1の態様力 第 7の態様のいずれか 1つの態様に記載の フライ用油脂組成物、又は第 8又は第 9のフライ用油脂組成物製品のフライ用油脂組 成物を、可塑性又は柔軟性を有する袋に入れて使用する方法である。 [0019] An eleventh aspect of the present invention is the first aspect power of the frying fat composition according to any one of the seventh aspect, or the eighth or ninth frying fat composition product. This is a method of using the oil composition for frying in a plastic or flexible bag.
[0020] 本発明の第 12の態様は、可塑性又は柔軟性を有する袋が、ピロ一包装袋である第 1 1の態様に記載の方法である。 [0020] A twelfth aspect of the present invention is the method according to the first aspect, wherein the plastic or flexible bag is a pillow packaging bag.
発明の効果 The invention's effect
[0021] 本発明のフライ用油脂組成物は、 25°Cで流動性を有し、さらに 10〜40°Cという広 い温度範囲においても油脂全体が固化せず、また、固液分離も起こさないで流動性 を有するものであるため、ハンドリング性が優れ、フライ調理の作業性が向上させるこ とができる。また、運搬性の向上した可塑性又は柔軟性を有する袋に入ったフライ用 油脂組成物を得ることができる。
[0022] さらに、本発明のフライ用油脂組成物をフライ調理の油として使用することで、得ら れるフライ食品は、クリスピ一な食感を長時間保持でき、さらにフライ食品から紙ナブ キン等への油の染み出しを有意に減少させることができる。さらに、得られるフライ食 品は、水添臭のような人工的な異味異臭を感じないため、風味が良好なものとなる。 発明を実施するための最良の形態 [0021] The frying fat composition of the present invention has fluidity at 25 ° C, and the entire fat and oil does not solidify in a wide temperature range of 10-40 ° C, and solid-liquid separation also occurs. Since it has fluidity, it is excellent in handling and can improve the workability of frying. Moreover, the oil composition for frying in the bag which has the plasticity or the softness | flexibility which improved the conveyance property can be obtained. [0022] Further, by using the frying oil composition of the present invention as an oil for frying, the obtained fried food can maintain a crispy texture for a long time, and further, from fried food to paper napkin etc. The oil seepage into the water can be significantly reduced. Furthermore, the obtained fried food does not feel an artificial off-flavor such as hydrogenated odor, so that the flavor is good. BEST MODE FOR CARRYING OUT THE INVENTION
[0023] まず、本発明に用いる油脂 Aについて説明する。 [0023] First, the fat A used in the present invention will be described.
本発明に用いる油脂 Aは、 0°Cで液状の油脂である。油脂 Aとして、例えば、大豆 油、菜種油、ハイォレイツク菜種油、とうもろこし油、サフラワー油、ひまわり油、綿実 油、アマ-油等が挙げられ、これらの 1種又は 2種以上を使用することができる。 その中でも特に、油脂 B及び油脂 Cとの相溶性が良好であるという理由で、菜種油、 大豆油、又は菜種油と大豆油の混合油を使用するのが最も好ましい。 The fat A used in the present invention is a fat that is liquid at 0 ° C. Examples of the fats and oils A include soybean oil, rapeseed oil, high rapeseed rapeseed oil, corn oil, safflower oil, sunflower oil, cottonseed oil, linseed oil, etc., and one or more of these can be used. . Among them, it is most preferable to use rapeseed oil, soybean oil, or a mixed oil of rapeseed oil and soybean oil because the compatibility with the fats and oils B and C is good.
さらに、低温における粘度上昇を抑制し、ハンドリング性を高めるために、油脂 Aの ヨウ素価 ίま、好ましく ίま 75〜190、より好ましく ίま 80〜180、最ち好ましく ίま 90〜180 である。 Furthermore, in order to suppress an increase in viscosity at low temperatures and improve handling properties, the iodine value of fat A is ί, preferably ί75-190, more preferably ί80-180, and most preferably ί90-180. .
[0024] 次に、本発明に用いる油脂 Βについて説明する。 [0024] Next, the fats and oils used in the present invention will be described.
本発明に用いる油脂 Βは、融点 5〜30°Cの油脂であり、より好ましくは融点 10〜30 °Cの油脂であり、最も好ましくは融点 13〜28°Cの油脂である。油脂 Bとして、例えば 、パーム油、パーム油分別液状部、パーム油分別中融点部、及びパーム油ニ段階 分別液状部等のパーム系の油脂や、パーム系油脂と 0°Cで液状の油脂とをエステル 交換反応して得られるエステル交換油脂、パーム系油脂と 0°Cで液状の油脂とを、ェ ステル交換反応したエステル交換油脂を乾式分別処理することにより得られる油脂 等が挙げられ、これらの 1種又は 2種以上を使用することができる。 The fats and oils used in the present invention are fats and oils having a melting point of 5 to 30 ° C, more preferably fats and oils having a melting point of 10 to 30 ° C, and most preferably fats and oils having a melting point of 13 to 28 ° C. As fats and oils B, for example, palm oils such as palm oil, palm oil fractionation liquid part, palm oil fractionation middle melting point part, and palm oil two-stage fractionation liquid part, etc. And the like obtained by subjecting a transesterified fat and oil obtained by subjecting to a transesterification reaction with a palm-based fat and oil and a liquid oil and fat at 0 ° C. One or more of these can be used.
[0025] その中でも特に、熱および酸化安定性が高ぐまた、ヨウ素価に比して融点が低いた めハンドリング性が良好であるという理由から、パーム油分別液状部、パーム油ニ段 階分別液状部、パーム系油脂と 0°Cで液状の油脂とをエステル交換反応して得られ るエステル交換油脂、又はパーム系油脂と 0°Cで液状の油脂とをエステル交換反応 したエステル交換油脂を乾式分別処理することにより得られる油脂を使用することが 好ましい。
さらに、油脂 Bのヨウ素価は、好ましくは 40〜95、より好ましくは 45〜85、最も好ま しくは 50〜80の油脂である。 [0025] Among these, palm oil fractionation liquid part, palm oil two-stage fractionation, because heat and oxidation stability are high and handling property is good because melting point is lower than iodine value. Transesterified oil obtained by transesterification of liquid oil, palm oil and fat at 0 ° C, or transesterified oil obtained by transesterification of palm oil and liquid oil at 0 ° C It is preferable to use fats and oils obtained by dry fractionation. Furthermore, the iodine value of fat B is preferably 40 to 95, more preferably 45 to 85, and most preferably 50 to 80.
[0026] パーム油分別液状部としては、例えば、パーム油を、徐冷後の乾式分別処理を 2度 行って得られる液状油部分 (パーム油ニ段階分別液状部又はパームス一バーオレイ ン)を使用することができる。パーム油分別液状部の市販品として、例えば日清ォイリ ォ (株)製の商品デリカエース OL等が挙げられる。 [0026] As the palm oil fractionation liquid part, for example, a liquid oil part (palm oil two-stage fractionation liquid part or palms bar oil) obtained by subjecting palm oil to dry fractionation treatment after slow cooling twice is used. can do. As a commercial product of the palm oil separation liquid part, for example, Nisshin Oilo Co., Ltd. product Delica Ace OL can be mentioned.
[0027] パーム系油脂と 0°Cで液状の油脂とをエステル交換反応して得られるエステル交換 油脂のパーム系油脂としては、パーム油、パーム油分別液状部、パーム油ニ段階分 別液状部、及びパーム中融点部等の油脂の 1種又は 2種以上が挙げられる。そして 、 0°Cで液状の油脂としては、例えば、大豆油、菜種油、ノ、ィォレイツク菜種油、とうも ろこし油、サフラワー油、ひまわり油、綿実油、アマ-油等が挙げられ、これらの 1種 又は 2種以上を使用することができる。エステル交換には、公知の油脂のエステル交 換方法を用いることができる。 [0027] Transesterification obtained by transesterification of palm-based fats and oils and liquid oils at 0 ° C. Palm-based fats and oils of palm oils, palm oil fractionation liquid parts, palm oil two-stage fractionation liquid parts , And one or more of fats and oils such as palm middle melting point. Examples of oils and fats that are liquid at 0 ° C. include soybean oil, rapeseed oil, oil, ioletsk rapeseed oil, corn oil, safflower oil, sunflower oil, cottonseed oil, flaxseed oil, etc. Species or two or more can be used. For the transesterification, known methods for transesterification of fats and oils can be used.
[0028] パーム系油脂と 0°Cで液状の油脂とを、エステル交換反応したエステル交換油脂を 乾式分別処理することにより得られる油脂のエステル交換油脂としては、先に説明し たエステル交換油脂を用いることができる。エステル交換油脂の乾式分別処理として [0028] The transesterified fats and oils obtained by dry-separating the transesterified fats and oils obtained by subjecting the palm-based fats and oils and liquids at 0 ° C to a transesterification reaction are subjected to the dry separation process. Can be used. As a dry separation process for transesterified oils and fats
、例えば次の方法が挙げられる。 For example, the following method is mentioned.
エステル交換油脂を、 1時間に 0. 5〜5°Cの割合で徐冷し、 10〜20°Cにおいて液状 油部分を圧搾濾過機により濾別し、濾過機内に残った固形脂を回収するという方法 である。 Transesterified oils and fats are gradually cooled at a rate of 0.5 to 5 ° C per hour, and the liquid oil part is filtered by a press filter at 10 to 20 ° C, and the solid fat remaining in the filter is recovered. This is the method.
パーム系油脂と 0°Cで液状の油脂とをエステル交換反応したエステル交換油脂を乾 式分別処理することにより得られる液状油の市販品として、例えば日清オイリオ (株) 製の商品:ロイヤルディッシュ等が挙げられる。 As a commercial product of liquid oil obtained by dry separation of transesterified fat and oil obtained by transesterification of palm fat and liquid oil at 0 ° C, for example, products manufactured by Nisshin Oilio Co., Ltd .: Royal Dish Etc.
[0029] 次に、本発明に用いる油脂 Cについて説明する。 [0029] Next, the fat C used in the present invention will be described.
本発明に用いる油脂 Cは、全構成脂肪酸中の炭素数 20〜24の飽和脂肪酸が 10 〜75質量%、より好ましくは 15〜70質量%、最も好ましくは 30〜70質量%である油 脂である。炭素数 20〜24の飽和脂肪酸としては、例えばァラキン酸、ベヘン酸 (炭 素数 22の飽和脂肪酸)、リグノセリン酸等が挙げられるが、これらから選ばれる 1種の
ものでも、又は 2種以上のものでも良い。 The fat and oil C used in the present invention is a fat and oil in which a saturated fatty acid having 20 to 24 carbon atoms in all the constituent fatty acids is 10 to 75% by mass, more preferably 15 to 70% by mass, and most preferably 30 to 70% by mass. is there. Examples of the saturated fatty acid having 20 to 24 carbon atoms include araquinic acid, behenic acid (saturated fatty acid having 22 carbon atoms), lignoceric acid, and the like. Or two or more types.
油脂 Cとして、例えば、全構成脂肪酸中の炭素数 22の飽和脂肪酸含量 (ベヘン酸含 量)が 20〜60質量%である菜種極度硬化油、魚油極度硬化油、ラード極度硬化油 等が挙げられ、これらの 1種又は 2種以上を使用することができる。 Examples of the fat C include rapeseed extremely hardened oil, fish oil extremely hardened oil, lard extremely hardened oil, etc., having a saturated fatty acid content of 22 carbon atoms (behenic acid content) in all the constituent fatty acids of 20 to 60% by mass. One or more of these can be used.
[0030] その中でも特に、全構成脂肪酸中の炭素数 22の飽和脂肪酸含量 (ベヘン酸含量) が 20〜60質量%である菜種極度硬化油は、魚油極度硬化油やラード極度硬化油 に比べて全構成脂肪酸中の炭素数 22の飽和脂肪酸含量 (ベヘン酸含量)が多い。 したがって、油脂 Cとして、これらの油脂を同じ量含有させた場合に、フライ用油脂組 成物中の油脂の全構成脂肪酸中の炭素数 20〜24の飽和脂肪酸含量を多くするこ とができ、コスト面でのメリットを有する。 [0030] Among them, the rapeseed extremely hardened oil having a saturated fatty acid content of 22 carbon atoms (behenic acid content) in all the constituent fatty acids of 20 to 60% by mass is higher than fish oil hardened oil and lard extremely hardened oil. The total fatty acid content of C22 is high (behenic acid content). Therefore, when the same amount of these fats and oils is contained as the fat and oil C, the saturated fatty acid content having 20 to 24 carbon atoms in the total fatty acids of the fat and oil in the frying fat and oil composition can be increased. It has merit in cost.
[0031] 成分 Cの含有量を少なくすることでコストを抑え、また、少な 、成分 Cの含有量で効 率よく油脂組成物全体の固液の分離を防止し、さらに、得られるフライ調理品の良好 な食感の保持や油の染み出しをより防止するために、菜種極度硬化油の全構成脂 肪酸中の炭素数 22の飽和脂肪酸含量 (ベヘン酸含量)は、好ましくは 20〜60質量 %、より好ましくは 25〜60質量%、最も好ましくは 30〜60質量%である。 [0031] By reducing the content of component C, the cost can be reduced, and by reducing the content of component C, the solid-liquid separation of the entire oil-fat composition can be effectively prevented, and the resulting fried cooked product can be obtained. In order to further maintain the good texture and prevent the oil from exuding, the saturated fatty acid content (behenic acid content) of 22 carbon atoms in the total fatty acid of the rapeseed extremely hardened oil is preferably 20-60. % By mass, more preferably 25 to 60% by mass, most preferably 30 to 60% by mass.
[0032] また、油脂 Cの融点は、 40〜80°Cであること力好ましく、 40〜70°Cであることがより 好ましぐ 50〜70°Cであることが最も好ましい。さらに、油脂 Cのヨウ素価は、好ましく は 0〜5、より好ましくは 0〜3、最も好ましくは 0〜1. 5である。 [0032] The melting point of fat C is preferably 40 to 80 ° C, more preferably 40 to 70 ° C, and most preferably 50 to 70 ° C. Furthermore, the iodine value of the fat C is preferably 0 to 5, more preferably 0 to 3, and most preferably 0 to 1.5.
[0033] 次に、本発明のフライ用油脂組成物中の成分 A、成分 B、及び成分 Cの含量につ いて説明する。 [0033] Next, the contents of Component A, Component B, and Component C in the frying fat composition of the present invention will be described.
本発明のフライ用油脂組成物中における油脂 Aの含量は、 10〜90質量%、より好 ましくは 30〜70質量%、最も好ましくは 40〜60質量%である。 10未満であると、低 温時に油脂全体が固化し、良好なハンドリング性が得られず、 90質量%より多いとフ ライ食品にした時の固化速度が小さくなり、油染み防止や食感の改善効果が得られ ないからである。 The content of fat and oil A in the frying fat and oil composition of the present invention is 10 to 90% by mass, more preferably 30 to 70% by mass, and most preferably 40 to 60% by mass. If it is less than 10, the entire fats and oils solidify at low temperatures, and good handling properties cannot be obtained, and if it is more than 90% by mass, the solidification rate when it is made into a frozen food is reduced, preventing oil stains and improving the texture. This is because the effect cannot be obtained.
[0034] 本発明のフライ用油脂糸且成物中における油脂 Bの含量は、 9. 9〜89. 9質量%、よ り好まし <は 29. 9〜69. 9質量0 /0、最も好まし <は 39. 9〜59. 9質量0 /0である。 9. 9 未満であると、結晶量が減少してフライ食品にした時の固化速度が小さくなり、油染
み防止や食感の改善効果が得られず、 89. 9質量%より多いと低温時に油脂全体が 固化し、良好なハンドリング性が得られな 、からである。 The content of fat B in the frying fat yarn且成product of [0034] the present invention, 9.9 to 89.9 wt%, preferably Ri yo <is 29.9 to 69.9 mass 0/0, most preferably <is 39.9 to 59.9 mass 0/0. If it is less than 9, the amount of crystals decreases and the rate of solidification when it is made into fried foods decreases, resulting in oil dyeing. This is because when the amount exceeds 89.9% by mass, the entire fats and oils solidify at low temperatures and good handling properties cannot be obtained.
[0035] 本発明のフライ用油脂組成物中における油脂 Cの含量は、 0. 1〜5質量%、より好 ましくは 0. 1〜4. 5質量%、最も好ましくは 0. 1〜3質量%である。 0. 1未満であると 、結晶化速度を十分に上昇させるに至らずに、油染み防止や食感の改善効果が得 られず、 5質量%より多いと低温時に油脂全体を固化させて良好なハンドリング性が 得られないからである。 [0035] The content of fat and oil C in the frying fat and oil composition of the present invention is 0.1 to 5% by mass, more preferably 0.1 to 4.5% by mass, and most preferably 0.1 to 3%. % By mass. If it is less than 0.1, the crystallization rate will not be sufficiently increased, and oil stain prevention and texture improvement effects will not be obtained. If it is more than 5% by mass, the entire oil and fat will be solidified at low temperatures. This is because handling is not possible.
[0036] 次に、本発明のフライ用油脂組成物中の油脂の全構成脂肪酸中の炭素数 20〜24 の飽和脂肪酸含量にっ 、て説明する。 [0036] Next, the saturated fatty acid content of 20 to 24 carbon atoms in the total constituent fatty acids of the fats and oils in the frying fat and oil composition of the present invention will be described.
本発明のフライ用油脂組成物中の油脂の全構成脂肪酸中の炭素数 20〜24の飽 和脂肪酸含量は、フライ用油脂組成物中の成分 Cの含量により異なってくるが、フラ ィ用油脂組成物のハンドリング性、及び得られるフライ食品の食感をより向上させるた めに、全構成脂肪酸中 0. 05〜0. 49質量%であることが好ましぐ 0. 1〜0. 45質 量%であることがより好ましぐ 0. 1〜0. 4質量%であることが最も好ましい。 The saturated fatty acid content of 20 to 24 carbon atoms in the total fatty acids of the fats and oils in the frying fat and oil composition of the present invention varies depending on the content of component C in the frying fat and oil composition. In order to further improve the handleability of the composition and the texture of the resulting fried food, it is preferably 0.05 to 0.49% by mass in the total constituent fatty acids 0.1 to 0.45. More preferably, the amount is 0.1 to 0.4% by mass.
[0037] 本発明のフライ用油脂組成物には、常温および低温保存時の固液分離を防止する 目的で、乳化剤を含有させることができる。乳化剤含量は、フライ用油脂組成物 100 質量部に対して、好ましくは 0. 05〜5質量部、より好ましくは 0. 1〜4. 0質量部、最 も好ましくは 0. 1〜3. 0質量部である。 [0037] The frying fat composition of the present invention may contain an emulsifier for the purpose of preventing solid-liquid separation during storage at ordinary temperature and low temperature. The emulsifier content is preferably 0.05 to 5 parts by mass, more preferably 0.1 to 4.0 parts by mass, and most preferably 0.1 to 3.0 parts by mass with respect to 100 parts by mass of the fat and oil composition for frying. Part by mass.
含有させる乳化剤としては、例えばグリセリン脂肪酸エステル、ポリグリセリン脂肪酸 エステル、ショ糖脂肪酸エステル、ソルビタン脂肪酸エステル等が挙げられ、これらの 1種又は 2種以上を使用することができる。 Examples of the emulsifier to be included include glycerin fatty acid ester, polyglycerin fatty acid ester, sucrose fatty acid ester, sorbitan fatty acid ester and the like, and one or more of these can be used.
この中でも特に、少量で結晶挙動に大きく影響するという理由力 ショ糖脂肪酸ェ ステルを使用するのが好まし 、。 Among them, it is particularly preferable to use sucrose fatty acid ester because it has a large effect on crystal behavior even in a small amount.
[0038] 本発明のフライ用油脂組成物には、必要に応じて通常油脂に添加されている抗酸 ィ匕剤、消泡剤、着色剤、着香料、香辛料等の物質を、通常添加されている量の範囲 で添加することができる。添加物質として具体的には、トコフエロール、レシチン、シリ コーン榭脂等が挙げられる。 [0038] Substances such as anti-oxidant agents, antifoaming agents, colorants, flavoring agents, spices and the like that are usually added to the oils and fats are usually added to the oil composition for frying according to the present invention. It can be added in the range of the specified amount. Specific examples of the additive substance include tocopherol, lecithin, and silicone corn fat.
[0039] 次に、本発明のフライ用油脂組成物の物性及びノ、ンドリング性について説明する。
本発明のフライ用油脂組成物は、 25°Cにお 、て全体に白濁して均一に結晶化して いるが流動性を有する。さらに、 10〜40°Cという広い温度範囲において、油脂全体 が固化することなぐまた、固液分離も起こさず流動性を有するものであるため、ハン ドリング性が優れ、フライ調理の作業性を向上させることができる。 [0039] Next, the physical properties, knotting and ringing properties of the frying oil composition of the present invention will be described. The frying oil / fat composition of the present invention is fluidized at 25 ° C, although it is entirely clouded and uniformly crystallized. Furthermore, in a wide temperature range of 10 to 40 ° C, the entire fats and oils do not solidify, and they have fluidity without causing solid-liquid separation, so they have excellent handling properties and improve the workability of frying. Can be made.
すなわち、 10〜40°Cの環境下でフライをする際に、油脂が固化してしまうと、容器 力も取り出しに《なったり、加熱して溶解させたりしなければならず、非常に手間が 力かってしまう。し力しながら本発明のフライ用油脂組成物は、 10〜40°Cという広い 温度範囲において、油脂全体が固化することなぐまた、固液分離も起こさず流動性 を有するものであるため、使用の際に手間が力からず、フライ調理の作業性が向上す る。 In other words, if the oils and fats solidify when fried in an environment of 10 to 40 ° C, the container force must be taken out or dissolved by heating, which is very laborious. It ’s going to happen. However, the oil and fat composition for frying of the present invention can be used in a wide temperature range of 10 to 40 ° C because it does not solidify the entire oil and fat and does not cause solid-liquid separation. In this case, effort is not required and the workability of frying is improved.
[0040] 本発明のフライ用油脂組成物はこのような物性を有するため、例えば、フライ用油 脂組成物を充填した一斗缶を、恒温槽内で 10°Cにて 6時間保持した後、 5°Cで 6時 間保持し、さらに 10°Cで 6時間、 5°Cで 6時間のサイクル保存を行い、その後、 20°C で 1時間放置した後に一斗缶を開けて逆さにしても、粗大な油脂結晶の塊は無ぐス ムーズに斗缶から吐出させることができる。このように、ハンドリング性が優れているの で、フライの作業効率も向上させることができる。 [0040] Since the oil composition for frying of the present invention has such physical properties, for example, after holding a funnel can filled with the oil composition for frying for 6 hours at 10 ° C in a thermostatic bath. Hold at 5 ° C for 6 hours, then store at 10 ° C for 6 hours and at 5 ° C for 6 hours, then leave at 20 ° C for 1 hour, then open the canister and invert. However, the bulk of the fat and oil crystals can be smoothly discharged from the dough can. As described above, since the handling property is excellent, the working efficiency of the fly can be improved.
[0041] また、本発明のフライ用油脂組成物は、ピロ一包装袋、バウチ等の可塑性又は柔 軟性を有する袋に入れて使用することができる。本発明の可塑性又は柔軟性を有す る袋入りフライ用油脂組成物は、先に説明した本発明のフライ用油脂組成物が、上 記可塑性又は柔軟性を有する袋に入れられたものである。そして、本発明のフライ用 油脂組成物は、 o°c以下では固体ィ匕するという特徴を有する。したがって、ピロ一包 装袋、バウチ等の可塑性又は柔軟性を有する袋へ入れた本発明のフライ用油脂組 成物(可塑性又は柔軟性を有する袋入りフライ用油脂組成物)は、以下の理由により 運搬性及びハンドリング性に優れる。 [0041] Further, the frying oil composition of the present invention can be used in a plastic or flexible bag such as a pillow packaging bag or a bouch. The oily composition for bag frying having plasticity or flexibility of the present invention is obtained by putting the oily composition for frying of the present invention described above in a bag having the above plasticity or flexibility. . And the fat and oil composition for frying of the present invention is characterized in that it becomes solid at or below o ° c. Therefore, the oil composition for frying of the present invention (plastic or flexible oil composition for frying bag having the flexibility or flexibility) put in a plastic or flexible bag such as a pillow-wrapped bag or a bouch is as follows. Excellent transportability and handling.
すなわち、通常、食用油脂を入れたピロ一包装袋等の可塑性又は柔軟性を有する 袋は、使用する際には、一斗缶に充填したものより軽量であり、また、油の取り出しも 容易であるが、持ち運びをする際には形状が簡単に変形してしまうので、非常に運 搬しにくいという欠点を有する。しかし、本発明のフライ用油脂組成物は o°c以下で固
体ィ匕するため、ピロ一包装袋等の可塑性又は柔軟性を有する袋へ入れた本発明の フライ用油脂組成物(可塑性又は柔軟性を有する袋入りフライ用油脂組成物)は、そ のまま冷凍することで、変形をしにくい固体状のものとして取り扱うことができ、運搬が 容易となる。そして、運搬後、 10〜40°Cの室温下で使用する時には、先に説明した ように流動性を有するため、ハンドリング性が優れたものとなる。 In other words, plastic or flexible bags, such as pillow packaging bags containing edible fats and oils, are usually lighter in weight than those filled in a can, and oil can be easily taken out. However, it has the disadvantage that it is very difficult to carry because it is easily deformed when carrying. However, the oil and fat composition for frying of the present invention is hard at o ° c or less. Therefore, the frying oil / fat composition of the present invention (plastic / flexible bag oil / fat composition having flexibility or flexibility) put in a plastic or flexible bag such as a pillow packaging bag is not changed. By freezing, it can be handled as a solid material that is difficult to deform and can be easily transported. And when used at room temperature of 10-40 ° C after transportation, it has fluidity as explained above, so it has excellent handling properties.
[0042] これまで説明した本発明のフライ用油脂組成物を用いて調理したフライ食品は、タリ スピーな食感を長時間保持でき、さらにフライ食品から紙ナプキン等への油の染み出 しを有意に減少させることができる。また、得られるフライ食品は、水添臭のような人工 的な異味異臭を感じな 、ため、風味が良好なものである。 [0042] The fried food cooked using the oil composition for frying according to the present invention described so far can maintain a talispy texture for a long period of time, and further ooze oil from the fried food to paper napkins and the like. Can be significantly reduced. In addition, the obtained fried food does not feel an artificial off-flavor such as hydrogenated odor, and therefore has a good flavor.
[0043] 次に、本発明のフライ用油脂組成物の製造方法について説明するが、この製造方 法のみに限定するものではない。 [0043] Next, a method for producing the frying fat composition of the present invention will be described, but it is not limited to this production method.
油脂 A、油脂 B、油脂 Cをステンレス容器に入れて、 60〜90°Cで 0. 1〜2時間、ァ ジテーター攪拌により混合溶解することにより製造することができる。 It can be produced by putting fats and oils A, fats and oils B and fats and oils C in a stainless steel container and mixing and dissolving them at 60 to 90 ° C. for 0.1 to 2 hours by stirring with an agitator.
乳化剤及び抗酸化剤等の添加物を含有させる場合は、油脂 Aへ予め添加しても良 いし、油脂 A、油脂 B、及び油脂 Cを混合後に添加しても良い。 When an additive such as an emulsifier and an antioxidant is contained, it may be added to the fat A in advance, or may be added after mixing the fat A, fat B, and fat C.
[0044] 本発明のフライ食品は、先に説明したフライ用油脂組成物を用いて、通常のフライ 方法を用いることで、製造することができる。その際、フライ種としては、非冷凍品、冷 凍品のどちらも使用することができる。 [0044] The fried food of the present invention can be produced by using the frying fat composition described above and using a normal frying method. At that time, both non-frozen and frozen products can be used as the frying species.
実施例 Example
[0045] 以下に、実施例を挙げて本発明を具体的に説明する力 本発明はこれらに限定さ れるものではない。 [0045] In the following, the ability to specifically describe the present invention with reference to examples The present invention is not limited to these.
[0046] 〔製造例 1〕油脂 1 (油脂 Bの一例)の製造 [0046] [Production Example 1] Production of fat 1 (an example of fat B)
菜種油(日清オイリオ (株)製、商品名:菜種白絞油、ヨウ素価 118) 50kgと、パーム 油分別液状部(融点 21°C、ヨウ素価 56) 50kgとを混合し、グリセリドの 1, 3位に特異 性のあるリパーゼ酵素製剤を用いて、 60°Cで 16時間、攪拌しながらエステル交換し た後、 1時間に 0. 5〜5°Cの割合で徐冷し、 8〜12°Cにおいて液状油部分を圧搾濾 過機により濾別し、濾過機内に残った固形脂を回収することにより、油脂 1を 15. 2kg 得た。得られた油脂 1の融点は 23°C、ヨウ素価は 76であった。
[0047] 〔実施例 1〕フライ用油脂組成物 1の製造 50 kg of rapeseed oil (Nisshin Oilio Co., Ltd., trade name: white rapeseed oil, iodine value 118) and 50 kg of palm oil fractionated liquid part (melting point 21 ° C, iodine value 56) are mixed with 1, Transesterification with stirring at 60 ° C for 16 hours using a lipase enzyme preparation specific for the 3-position, followed by slow cooling at a rate of 0.5 to 5 ° C per hour, 8-12 The liquid oil portion was filtered by a press filter at ° C, and the solid fat remaining in the filter was recovered to obtain 15.2 kg of fat 1. The resulting oil 1 had a melting point of 23 ° C. and an iodine value of 76. [Example 1] Production of oil composition 1 for frying
油脂 Aとして大豆白絞油(日清オイリオ (株)製、商品名:日清大豆白絞油、ヨウ素価 128)を 50kg、油脂 Bとして製造例 1で得られた油脂 1を 49. 8kg、油脂 Cとして菜種 極度硬化油(融点 61°C、ヨウ素価 0. 6、全構成脂肪酸中の炭素数 20〜24の飽和脂 肪酸が 56質量%、全構成脂肪酸中の炭素数 22の飽和脂肪酸含量が 46質量%) 0 . 2kgを、 150リットルステンレス容器に入れて、 70°Cで 0. 5時間、アジテーター攪拌 により混合溶解することで、フライ用油脂組成物 1を 100kg得た。得られたフライ用油 脂組成物は 25°Cで流動性を有するもので、融点が 4. 7°C、ヨウ素価は 102であり、フ ライ用油脂組成物中の油脂の全構成脂肪酸中の炭素数 20〜24の飽和脂肪酸含量 は 0. 11質量%あった。 Soybean white oil (Nisshin Oilio Co., Ltd., trade name: Nissin Soybean White Oil, iodine value 128) is 50 kg as fat A, 49.8 kg of fat 1 obtained in Production Example 1 as fat B, Rapeseed extremely hardened oil as fat C (melting point 61 ° C, iodine value 0.6, saturated fatty acid having 20 to 24 carbon atoms in all constituent fatty acids 56 mass%, saturated fatty acid having 22 carbon atoms in all constituent fatty acids) 100 kg of frying oil composition 1 was obtained by putting 0.2 kg in a 150 liter stainless steel container and mixing and dissolving at 70 ° C. for 0.5 hour by stirring with an agitator. The obtained frying fat / oil composition has fluidity at 25 ° C, has a melting point of 4.7 ° C and an iodine value of 102, and is contained in all the constituent fatty acids of the fat / oil in the frying fat / oil composition. The content of saturated fatty acids having 20 to 24 carbon atoms was 0.11% by mass.
[0048] 〔実施例 2〕フライ用油脂組成物 2の製造 [Example 2] Production of oil composition 2 for frying
油脂 Aとして大豆白絞油(日清オイリオ (株)製、商品名:日清大豆白絞油、ヨウ素価 128)を 50kg、油脂 Bとしてパーム油ニ段階分別液状部(融点 14°C、ヨウ素価 62)を 49. 4kg、油脂 Cとして菜種極度硬化油(融点 61°C、ヨウ素価 0. 6、炭素数 20〜24 の飽和脂肪酸が全構成脂肪酸の 56質量%、全構成脂肪酸中の炭素数 22の飽和脂 肪酸含量が 46質量%)を 0. 6kg、 150リットルステンレス容器に入れて、 70°Cで 0. 5 時間、アジテーター攪拌により混合溶解することで、フライ用油脂組成物 2を 100kg 得た。得られたフライ用油脂組成物は 25°Cで流動性を有するもので、融点が 2. 8°C 、ヨウ素価は 95であり、フライ用油脂組成物中の油脂の全構成脂肪酸中の炭素数 2 0〜24の飽和脂肪酸含量は 0. 24質量%あった。 Soy white squeezed oil (manufactured by Nisshin Oillio Co., Ltd., trade name: Nisshin Soy White Squeezed Oil, iodine value 128) as fat A and oil B, palm oil two-stage fractionated liquid part (melting point 14 ° C, iodine No. 62) 49.4 kg, oil and fat C as rapeseed extremely hardened oil (melting point 61 ° C, iodine number 0.6, saturated fatty acids with 20 to 24 carbon atoms are 56% by mass of all constituent fatty acids, carbon in all constituent fatty acids The fat and oil composition for frying is obtained by putting the saturated fatty acid content of number 22 into a 0.6 kg 150 liter stainless steel container and mixing and dissolving at 70 ° C. for 0.5 hour by stirring with an agitator. 100kg was obtained. The resulting frying oil / fat composition has fluidity at 25 ° C, has a melting point of 2.8 ° C, an iodine value of 95, and carbon in all fatty acids of the oil / fat in the frying oil / fat composition. The saturated fatty acid content of the number 20-24 was 0.24% by mass.
[0049] 〔実施例 3〕揚げコロッケの調理 [0049] [Example 3] Cooking fried croquettes
油量 3リットルの電気式フライヤ一(エイシン電気 (株)製、商品名: EF— 3L)にフラ ィ用油脂組成物 1を 3kg入れ、市販の業務用冷凍コロッケ (ニチ口 (株)製、商品名: あけぼの北海道サクサク野菜コロッケ) 4個を油温 180°Cで 5分間揚げた。同様の操 作を繰り返し行うことで、各評価に必要な個数の揚げコロッケを調理した。 Put 3kg of oil composition 1 for frying in a 3 liter electric fryer (made by Aisin Denki Co., Ltd., trade name: EF-3L) and put it on a commercial refrigerated croquette (manufactured by Nichiguchi Co., Ltd.) (Product name: Akebono Hokkaido Crispy Vegetable Croquette) 4 pieces were fried at an oil temperature of 180 ° C for 5 minutes. By repeating the same operation, the necessary number of fried croquettes were prepared for each evaluation.
[0050] 〔実施例 4〕揚げコロッケの調理 [Example 4] Cooking fried croquettes
フライ用油脂組成物 1の替わりに、フライ用油脂組成物 2を用いた以外は実施例 3と 同様の方法を用いてコロッケを揚げた。また、同様の操作を繰り返し行うことで、各評
価に必要な個数の揚げコロッケを調理した。 A croquette was fried in the same manner as in Example 3 except that the frying oil / fat composition 2 was used instead of the frying oil / fat composition 1. Each evaluation can be performed by repeating the same operation. Cooked as many fried croquettes as needed for the price.
[0051] 〔比較例 1〕揚げコロッケの調理 [0051] [Comparative Example 1] Cooking fried croquettes
フライ用油脂組成物 1の替わりに、大豆白絞油(日清オイリオ (株)製、商品名:日清 大豆白絞油、ヨウ素価 128)を用 、た以外は実施例 3と同様の方法を用 、てコロッケ を揚げた。また、また、同様の操作を繰り返し行うことで、各評価に必要な個数の揚げ コロッケ調理した。 The same method as in Example 3 except that instead of the frying oil composition 1, soy white squeezed oil (Nisshin Oilio Co., Ltd., trade name: Nisshin soy white squeezed oil, iodine value 128) was used. I fried croquettes. Also, by repeating the same operation, the necessary number of fried croquettes were prepared for each evaluation.
[0052] 〔比較例 2〕揚げコロッケの調理 [0052] [Comparative Example 2] Cooking fried croquette
フライ用油脂組成物 1の替わりに、大豆白絞油(日清オイリオ (株)製、商品名:日清 大豆白絞油、ヨウ素価 128)とパーム油ニ段階分別液状部 (融点 14°C、ヨウ素価 62) とを質量比 6 :4で調合したフライ用油脂組成物 3を用いた以外は実施例 3と同様の方 法を用いてコロッケを揚げた。また、同様の操作を繰り返し行うことで、各評価に必要 な個数の揚げコロッケ調理した。 Oil composition for frying 1 instead of soy white squeezed oil (Nisshin Oilio Co., Ltd., trade name: Nisshin soy white squeezed oil, iodine value 128) and palm oil two-stage fractionated liquid part (melting point 14 ° C The croquette was fried using the same method as in Example 3 except that the oil composition 3 for frying prepared at a mass ratio of 6: 4 was used. In addition, by repeating the same operation, the necessary number of fried croquettes were prepared for each evaluation.
[0053] 〔比較例 3〕揚げコロッケの調理 [0053] [Comparative Example 3] Cooking fried croquette
フライ用油脂組成物 1の替わりに、大豆白絞油(日清オイリオ (株)製、商品名:日清 大豆白絞油、ヨウ素価 128)と菜種極度硬化油(融点 61°C、ヨウ素価 0. 6、炭素数 20 〜24の飽和脂肪酸が全構成脂肪酸の 56質量%、全構成脂肪酸中の炭素数 22の 飽和脂肪酸含量が 46質量%)とを質量比 95: 5で調合したフライ用油脂組成物 4を 用いた以外は実施例 3と同様の方法を用いてコロッケを揚げた。また、同様の操作を 繰り返し行うことで、各評価に必要な個数の揚げコロッケ調理した。 Oil composition for frying 1 instead of soybean white oil (Nisshin Oilio Co., Ltd., trade name: Nisshin soybean white oil, iodine value 128) and rapeseed extremely hardened oil (melting point 61 ° C, iodine value) 0.6, for frying, in which a saturated fatty acid having 20 to 24 carbon atoms is 56% by mass of the total fatty acid, and a saturated fatty acid content of 22 carbon atoms in the total fatty acid is 46% by mass) at a mass ratio of 95: 5 The croquette was fried using the same method as in Example 3 except that the oil and fat composition 4 was used. In addition, by repeating the same operation, the necessary number of fried croquettes were prepared for each evaluation.
[0054] 〔揚げコロッケからの油の染み出し評価試験〕 [0054] [Evaluation test of oil oozing from fried croquettes]
実施例 3、 4及び比較例 1〜3に示す調理方法で得られた揚げコロッケを、揚げた直 後にステンレスの網上に載せて 10分間放冷した後、 2組重ねにして恒量した紙ウェス (クレシァ (株)製、商品名:キムタオル)の上に 1個ずっ静置して、 20°Cで 4時間放置 した。 4時間放置したそれぞれの揚げコロッケを紙ウェス上から除去して紙ウェスの質 量を測定し、揚げコロッケを載せる前の紙ウェスの恒量値を差し引いて、紙ウェスの 増加質量を算出した。実施例 3、 4及び比較例 1〜3で調理した揚げコロッケについて の結果を表 1に示す。なお、表 1の数値は、揚げコロッケ 20個で測定した増加質量の 平均値である。
今回の評価試験において、紙ウェスの質量の増加した原因として、コロッケから染み 出した油分以外に、水分も含まれていると推測される。しかし、すべての試験で同一 のコロッケを用いているため、染み出した水分の質量には差が無いと考えられ、増加 質量の違いを揚げコロッケからの油の染み出し量の違いとして評価した。 The fried croquettes obtained by the cooking methods shown in Examples 3 and 4 and Comparative Examples 1 to 3 were placed on a stainless steel net immediately after being fried and allowed to cool for 10 minutes, and then a pair of paper wastes with constant weight. One product was placed on top of (Kureshia Co., Ltd., trade name: Kim Towel) and left at 20 ° C for 4 hours. Each fried croquette left for 4 hours was removed from the paper waste, the quality of the paper waste was measured, and the constant weight value of the paper waste before placing the fried croquette was subtracted to calculate the increased mass of the paper waste. The results for the fried croquettes cooked in Examples 3 and 4 and Comparative Examples 1 to 3 are shown in Table 1. The values in Table 1 are the average values of increased mass measured with 20 fried croquettes. In this evaluation test, it is speculated that the cause of the increase in the mass of paper waste is that it contains water in addition to the oil that exudes from croquettes. However, since the same croquette was used in all tests, it was considered that there was no difference in the mass of the exuded water, and the difference in the increased mass was evaluated as the difference in the amount of oil oozing out from the fried croquette.
[0055] [表 1] [0055] [Table 1]
[0056] 表 1の結果から、フライ用油脂組成物 1及び 2を使用して揚げた揚げコロッケは、大 豆白絞油、フライ用油脂組成物 3及び 4を使用したものより、紙ウェス増加質量が有 意に少なぐ揚げコロッケからの油の染み出しが少ないことがわ力つた。また、フライ 用油脂組成物 3を使用した場合、大豆白絞油を使用した場合よりも紙ウェス増加質 量が小さ力つたことから、大豆白絞油に中融点油脂を混合したものを用いると揚げコ 口ッケカもの油の染み出しが少なくなる傾向があることがわ力つた。しかし、本発明の フライ用油脂組成物 1及び 2を使用した場合ほどの効果は得られな力 た。 [0056] From the results in Table 1, fried croquettes fried using frying oil compositions 1 and 2 increased in paper waste compared to those using soybean white oil and frying oil compositions 3 and 4. It was clear that there was little oil oozing out from deep-fried croquettes with significantly less mass. In addition, when the oil composition for frying 3 was used, the amount of paper waste increase was smaller than when using the white soybean oil. It was obvious that there was a tendency for the oil to leak out from the deep-fried food. However, the effect as much as when using the frying oil compositions 1 and 2 of the present invention was not obtained.
また、フライ用油脂組成物 4には、炭素数 20〜24の飽和脂肪酸が全構成脂肪酸 の 56質量%の菜種極度硬化油が配合されているにもかかわらず、フライ用油脂組成 物 1及び 2を使用した場合ほどの効果は得られなかった。 In addition, the frying oil composition 1 and 2 are used in the frying fat composition 1 and 2 in spite of the fact that a saturated fatty acid having 20 to 24 carbon atoms is mixed with 56% by mass of rapeseed extremely hardened oil. The effect was not as good as when using.
[0057] 〔揚げコロッケの音響による食感評価〕 [0057] [Evaluation of texture by sound of fried croquette]
実施例 3、 4及び比較例 1〜3に示す調理方法で得られた揚げコロッケ各 10個を、
特開 2003— 114218に記載されている方法に準じて食品破砕装置に供して、破砕 時の音響を解析することにより食感評価を行った。測定した音響における 2000〜40 00Hzの周波数帯域におけるクリスプネス (パリパリ感、サクサク感)音域の音圧値を 抽出した、クリスプネス音域の数値ィヒ結果を表 2に示す。表 2に示す結果は、得られ たコロッケ 10個のクリスプネス音域の音圧値の平均値である。 10 fried croquettes obtained by the cooking methods shown in Examples 3 and 4 and Comparative Examples 1 to 3, The food texture was evaluated by analyzing the sound during crushing using a food crushing apparatus according to the method described in JP-A-2003-114218. Table 2 shows the numerical results of the crispness range obtained by extracting the sound pressure values of the crispness (crispiness, crispy) range in the frequency band of 2000 to 400 Hz in the measured sound. The results shown in Table 2 are average values of the sound pressure values of the 10 crispness ranges obtained.
音響評価では、クリスプネス音域の音圧値の平均値が大き!/、ほどサクサク感がある ことを示すので、今回は、クリスプネス音域の音圧値の平均値が 50dB以上であると 良好な食感を保持して ヽると評価した。 The acoustic evaluation shows that the average value of the sound pressure value in the crispness range is large! /, So that there is a sense of crispyness. It was evaluated to hold
[0058] [表 2] [0058] [Table 2]
[0059] 表 2の結果から、フライ用油脂組成物 1及び 2を用いた揚げコロッケは、大豆白絞油 、フライ用油脂組成物 3及び 4を用いた揚げコロッケよりも、クリスプネス (パリパリ感、 サクサク感)音域の音圧値が有意に高 ヽことから、良好な食感を保持して ヽることが わかった。 [0059] From the results in Table 2, the fried croquette using the frying oil composition 1 and 2 is more crispness (crispiness, than the fried croquette using the soy bean oil extract and the frying oil composition 3 and 4. It was found that the sound pressure value in the sound range was significantly high, and that it had a good texture.
[0060] 〔揚げコロッケの官能評価〕 [0060] [Sensory evaluation of fried croquettes]
実施例 3、 4及び比較例 1〜3に示す調理方法で得られた揚げコロッケ((1)〜(5) ) の各 10個を用いて、 a〜; jの 10名のパネラーにより食感及び風味にっ 、て官能評価 を行った。評価は順位付けにより行い、最も評価の良力つたものを 1位として 5点、以
下、 2位のものを 4点、 3位のものを 3点、 4位のものを 2点、最も評価の悪かったものを 5位として 1点と得点化し、揚げコロッケごとに 10名の評価得点の総合点を算出した。 各パネラーによる官能評価順位結果を表 3に示し、表 3中の(1)〜(5)の揚げコロッ ケについての説明を表 4に示す。また、(1)〜(5)の揚げコロッケの官能評価結果を 表 5及び 6に示す。 Using 10 pieces of each of fried croquettes ((1) to (5)) obtained by the cooking methods shown in Examples 3 and 4 and Comparative Examples 1 to 3, the texture of 10 panelists a to j In addition, sensory evaluation was performed on the taste. The evaluation is based on ranking, and the one with the best evaluation is ranked first, giving 5 points. Below, we scored 4 points for the 2nd place, 3 points for the 3rd place, 2 points for the 4th place, and 5 points for the worst place, giving 10 points for each fried croquette. The total score was calculated. The sensory evaluation ranking results by each panel are shown in Table 3, and Table 4 describes the fried croquettes (1) to (5) in Table 3. Tables 5 and 6 show the sensory evaluation results of fried croquettes (1) to (5).
[¾3] [¾3]
[表 4]
表 4 官能評価結果中の (1) 〜 (5) の揚げコロッケの説 明 [Table 4] Table 4 Explanation of fried croquettes (1) to (5) in sensory evaluation results
揚げコロッケの番号 調理方法 フライに使用した油脂 Fried croquette number Cooking method Oil used for frying
(1) 実施例 3 フライ用油脂組成物 1(1) Example 3 Oil composition for frying 1
(2) 実施例 4 フライ用油脂組成物 2(2) Example 4 Oil composition for frying 2
(3) 比較例 1 大豆白絞油(3) Comparative Example 1 Soybean white oil
(4) 比較例 2 フライ用油脂組成物 3(4) Comparative Example 2 Oil composition for frying 3
(5) 比較例 3 フライ用油脂組成物 4 (5) Comparative Example 3 Oil composition for frying 4
[0064] [表 6]
表 6 官能評価結果 [0064] [Table 6] Table 6 Sensory evaluation results
揚げコ口ッケの番 Fried rice cake turn
( 3 ) ( 4 ) ( 5 ) (3) (4) (5)
号 Issue
フライ用油脂組成 フライ用油脂組成物 使用した油脂 大豆白絞油 Oil composition for frying Oil composition for frying Oil used Oil white soybean oil
物 3 4 Object 3 4
官能評価総得点 1 9 2 2 2 0 Sensory evaluation total score 1 9 2 2 2 0
官能評価順位 5 3 4 Sensory evaluation rank 5 3 4
全体にベタ Overall solid
ッとしてい 少し油く ささを感 I feel a little oily
油の臭いが強い。 舌 総合官能評価 る。 油く さ じる。 甘い臭いがす The smell of oil is strong. Tongue comprehensive sensory evaluation. Oily. Smells sweet
触りがザラつく。 The touch is rough.
い。 柔らか る。 Yes. Soften.
い。 Yes.
[0065] 表 5及び 6の結果より、本発明のフライ用油脂組成物 1及び 2が、揚げコロッケのとし て食感及び風味において最も好まれることがわ力つた。 [0065] From the results in Tables 5 and 6, it was found that the frying oil compositions 1 and 2 of the present invention are most preferred in terms of texture and flavor as fried croquettes.
[0066] 〔フライ用油脂組成物のハンドリング性評価試験〕 [0066] [Handling property evaluation test of oil composition for frying]
フライ用油脂組成物 1〜4、及び大豆白絞油、各 15. Okgを、別々に秤量した一斗 缶に詰め、恒温槽内において 10°Cで 6時間静置した後 5°Cで 6時間静置し、さらに 1 0°Cで 6時間静置し、また 5°Cで 6時間静置するというサイクル保管試験を行った。サ イタル保管試験終了後、各一斗缶を 20°Cの部屋で 1時間静置した。その後、各一斗 缶を開けて 5分間逆さに保持し、内容物を吐出除去させた。それぞれの一斗缶の質 量を測定することにより缶内の残留物質量を求めた。試験結果を表 7及び 8に示す。 Oil composition for frying 1 to 4 and soybean white squeeze oil, 15.Okg each was packed in a separately weighed can, left in a thermostatic bath at 10 ° C for 6 hours, and then 6 ° C at 5 ° C. A cycle storage test was conducted in which the sample was allowed to stand for 10 hours, and further allowed to stand at 10 ° C. for 6 hours, and further allowed to stand at 5 ° C. for 6 hours. After completion of the site storage test, each can was left in a room at 20 ° C for 1 hour. Then, each Ito can was opened and held upside down for 5 minutes to discharge the contents. The amount of residual material in the can was determined by measuring the mass of each can. The test results are shown in Tables 7 and 8.
[0067] [表 7]
表 7 フライ用油脂組成物のハンドリング性評価試験結果 [0067] [Table 7] Table 7 Results of handling test for frying oil composition
フライ用油脂組成物 フライ用油脂組成物 試験対象油脂 Oil composition for frying Oil composition for frying Test oil
1 2 1 2
充填した油脂質量 (k g) 15. 0 15. 0 Oil lipid content (kg) 15. 0 15. 0
一斗缶空質量 (k g) 1. 1 3 1. 13 Ito can empty mass (kg) 1. 1 3 1. 13
吐出後の一斗缶質量 (k g) 1. 58 1. 49 Canister weight after discharge (kg) 1. 58 1. 49
缶内残留物質量 (k g) 0. 45 0. 36 Residual substance in can (kg) 0. 45 0. 36
吐出歩留 (質量%) 97. 0 97. 6 Discharge yield (mass%) 97. 0 97. 6
全体に白く均一に結 全体に白く均一に結 缶内残留物の状態 Whole white and uniform ligation Whole white and uniform ligation
晶化し、 流動性ある。 晶化し、 流動性ある。 [表 8] Crystallizes and is fluid. Crystallizes and is fluid. [Table 8]
表 7及び 8の結果力ももわ力るように、本発明であるフライ用油脂組成物 1及び 2は、 サイクル保管することにより、結晶化が促進して白濁して粘度が少し上昇していたが、 粗大な結晶の塊は無ぐ一斗缶からスムーズに吐出させることが出来た。 As shown in Tables 7 and 8, the oil composition for frying 1 and 2 of the present invention was accelerated by crystallization and became cloudy and slightly increased in viscosity by cycle storage. However, the coarse crystal lump could be discharged smoothly from the Ito Can.
また、 0°Cで液状の油脂、及び融点 5〜30°Cの油脂は含有するが、全構成脂肪酸
中の炭素数 20〜24の飽和脂肪酸含量が 10〜75質量%である油脂を含有しないフ ライ用油脂組成物 3は、保管温度をサイクル変化させことで細かい無数の結晶に混じ り直径 l〜2cmほどの結晶の塊が数個形成され、固液の分離や結晶の粗大化を抑 制できないことがわ力つた。一方で、 0°Cで液状の油脂、及び全構成脂肪酸中の炭 素数 20〜24の飽和脂肪酸含量が 10〜75質量%である油脂を含有する力 融点 5 〜30°Cの油脂を含有しない油脂組成物 4は、保管温度をサイクル変化させると、缶 の底部に結晶が堆積し、結晶のへばりつきを生じてしまうことがわ力つた。 Also, it contains fats and oils that are liquid at 0 ° C, and fats and oils with a melting point of 5 to 30 ° C. The oil composition for frying oil 3 containing no fats and oils with a saturated fatty acid content of 20 to 24 carbon atoms in the range of 10 to 75% by mass is mixed with countless fine crystals by changing the storage temperature in a cycle. Several crystal lumps of about 2 cm were formed, which proved that solid-liquid separation and crystal coarsening could not be suppressed. On the other hand, it contains oils and fats that are liquid at 0 ° C, and fats and oils whose saturated fatty acid content of carbon number 20 to 24 in all constituent fatty acids is 10 to 75% by mass. Does not contain oils with melting point 5 to 30 ° C. The oil / fat composition 4 was found to cause crystals to stick to the bottom of the can when the storage temperature was cycled, resulting in stickiness of the crystals.
大豆白絞油は、保管温度をサイクル変化させることで若干の粘度上昇は見られた 力 結晶の析出は無く清澄で、一斗缶力 歩留よく吐出させることができた。 Soy white squeezed oil showed a slight increase in viscosity when the storage temperature was changed in a cycle. It was clear with no precipitation of crystals, and could be discharged with a high yield.
産業上の利用可能性 Industrial applicability
本発明のフライ用油脂組成物は、天ぶら、フライ、スナック菓子等のフライ食品を製 造する際に使用するフライ用油脂として利用できる。
The oil and fat composition for frying of the present invention can be used as a fat and oil for frying that is used when producing fried foods such as empty-baffled, fried food, and snacks.
Claims
[1] 次の油脂 Aを 10〜90質量%、油脂 Bを 9. 9〜89. 9質量%、油脂 Cを 0. 1〜5質 量%含有し、 25°Cにお 、て流動性を有するフライ用油脂組成物。 [1] The following oil and fat A contains 10 to 90 mass%, oil and fat B 9.9 to 99.9 mass%, oil and fat C 0.1 to 5 mass%, and is fluid at 25 ° C. The oil composition for frying which has.
油脂 A: 0°Cで液状の油脂。 Oil A: Oil that is liquid at 0 ° C.
油脂 B:融点 5〜30°Cの油脂。 Fats and oils B: Fats and oils with a melting point of 5-30 ° C.
油脂 C :全構成脂肪酸中の炭素数 20〜24の飽和脂肪酸含量が 10〜75質量%であ る油脂。 Fats and oils C: Fats and oils having a saturated fatty acid content of 20 to 24 carbon atoms in all constituent fatty acids of 10 to 75% by mass.
[2] フライ用油脂組成物中の油脂の全構成脂肪酸中の炭素数 20〜24の飽和脂肪酸 含量が 0. 05〜0. 49質量%である請求項 1に記載のフライ用油脂組成物。 [2] The oil composition for frying according to claim 1, wherein the content of the saturated fatty acid having 20 to 24 carbon atoms in all fatty acids of the oil and fat in the oil composition for frying is 0.05 to 0.49 mass%.
[3] 前記油脂 Bが、パーム系油脂を含有するものである請求項 1に記載のフライ用油脂 組成物。 [3] The oil composition for frying according to claim 1, wherein the oil B contains palm oil.
[4] 前記油脂 Bが、パーム系油脂と 0°Cで液状の油脂とを、エステル交換反応して得ら れるエステル交換油脂を含有するものである請求項 1に記載のフライ用油脂組成物。 [4] The frying fat composition according to claim 1, wherein the fat B contains a transesterified fat obtained by subjecting a palm fat and a liquid fat at 0 ° C to a transesterification reaction. .
[5] 前記油脂 Bが、パーム系油脂と 0°Cで液状の油脂とを、エステル交換反応し、さらに 得られたエステル交換油脂を乾式分別処理することにより得られる油脂である請求項 [5] The fats and oils B are fats and oils obtained by subjecting a palm oil and fats and fats and oils that are liquid at 0 ° C to a transesterification reaction, and further subjecting the obtained transesterified fats and oils to a dry fractionation treatment.
1に記載のフライ用油脂組成物。 2. The oil composition for frying according to 1.
[6] 前記油脂 Cが、全構成脂肪酸中の炭素数 22の飽和脂肪酸含量 (ベヘン酸含量) が 20〜60質量%である菜種極度硬化油、である請求項 1に記載のフライ用油脂組 成物。 [6] The fat and oil set for frying according to claim 1, wherein the fat and oil C is a rapeseed extremely hardened oil having a saturated fatty acid content (behenic acid content) of 22 carbon atoms in all the constituent fatty acids of 20 to 60% by mass. Adult.
[7] 請求項 1に記載のフライ用油脂組成物を 100質量部、及び乳化剤を 0. 05〜5質量 部含有するフライ用油脂糸且成物。 [7] A frying fat and thread composition comprising 100 parts by mass of the frying fat composition according to claim 1 and 0.05 to 5 parts by mass of an emulsifier.
[8] 請求項 1から 7のいずれ力 1項に記載したフライ用油脂組成物と、可塑性又は柔軟 性を有する袋を有し、前記フライ用油脂組成物が前記袋に入れられたものである可 塑性又は柔軟性を有する袋入りフライ用油脂組成物。 [8] The oil composition for frying according to any one of claims 1 to 7 and a bag having plasticity or flexibility, wherein the oil composition for frying is put in the bag. Oil composition for frying bag having plasticity or flexibility.
[9] 前記可塑性又は柔軟性を有する袋が、ピロ一包装袋である請求項 8に記載の可塑 性又は柔軟性を有する袋入りフライ用油脂組成物。 [9] The oily composition for frying bag having plasticity or flexibility according to claim 8, wherein the plasticity or flexibility bag is a pillow packaging bag.
[10] 請求項 1から 7のいずれ力 1項に記載のフライ用油脂組成物を用いて調理したフラ イ^;ロロ。
請求項 1から 7のいずれ力 1項に記載のフライ用油脂組成物を、可塑性又は柔軟性 を有する袋に入れて使用する方法。 [10] A fly cooked using the frying oil composition according to any one of claims 1 to 7 according to claim 1. A method of using the frying fat composition according to any one of claims 1 to 7 in a bag having plasticity or flexibility.
前記可塑性又は柔軟性を有する袋が、ピロ一包装袋である請求項 11に記載の方 法。
12. The method according to claim 11, wherein the plastic or flexible bag is a pillow packaging bag.
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