JP4651327B2 - Release oil - Google Patents

Release oil Download PDF

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JP4651327B2
JP4651327B2 JP2004239647A JP2004239647A JP4651327B2 JP 4651327 B2 JP4651327 B2 JP 4651327B2 JP 2004239647 A JP2004239647 A JP 2004239647A JP 2004239647 A JP2004239647 A JP 2004239647A JP 4651327 B2 JP4651327 B2 JP 4651327B2
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oil
acid ester
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polysorbate
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健市 渡辺
憲一 大塚
浩 西村
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株式会社J−オイルミルズ
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Description

本発明は食品調理、食品工業において利用される離型性油脂組成物に関する。詳しくは、主に炒め調理において用いられる炒め油、鉄板類における剥離作用を必要とする離型油、食品素材同士のひっつきを防止するほぐし油、製造工程において作業性を向上させるための離型油等、離型性が求められる食品製造、調理工程において利用される離型油に関する。   The present invention relates to a releasable oil and fat composition used in food cooking and food industry. Specifically, stir-fried oil mainly used in stir-fried cooking, mold release oil that requires peeling action on iron plates, loosening oil to prevent food material from sticking together, mold release oil to improve workability in the manufacturing process The present invention relates to a release oil used in food production and cooking processes that require release properties.

離型油は、製パン、炒め物、麺類等食品の幅広い分野で使用されており、製品のおいしさ、作業性、歩留まり等に大きく影響する。これまで、前記各用途において、食用油脂にレシチンを含む乳化剤を添加した離型油が種々提案されている。(特許文献1〜8)
これらは一定の機能を有しているものもあるが、使用状況によっては充分その機能が発揮されないものもあり、離型性、作業性、歩留まり、風味といった離型油に求められる要素を総合的に兼ね備えているとは言い難いのが実情である。
Release oils are used in a wide range of foods such as bread making, fried foods, and noodles, and greatly affect the taste, workability, and yield of products. Until now, various release oils in which an emulsifier containing lecithin is added to edible fats and oils have been proposed for each of the above uses. (Patent Documents 1-8)
Some of these have certain functions, but some of these functions may not be fully used depending on the conditions of use, and comprehensively consider the elements required for release oils such as releasability, workability, yield, and flavor. It is hard to say that they have both.

特開平10-248488号公報Japanese Patent Laid-Open No. 10-248488 特開2003-265105号公報JP 2003-265105 A 特開昭54-50008号公報JP 54-50008 特開平11-221033号公報Japanese Patent Laid-Open No. 11-221033 特開2001-352926号公報JP 2001-352926 特開2001-204407号公報JP 2001-204407 特開2003-18968号公報JP2003-18968 特開平5-30905号公報Japanese Patent Laid-Open No. 5-30905

本発明は、上記従来技術の問題点に鑑み、離型性、作業性、歩留まり、風味に関してより優れた離型油を提供することを目的とする。   The present invention has been made in view of the above-mentioned problems of the prior art, and an object of the present invention is to provide a release oil that is more excellent in terms of release properties, workability, yield, and flavor.

本発明者らは、上記課題に鑑み鋭意研究した結果、食品用途に用いられる離型油について、油脂にポリソルベートを所定量配合することにより、離型性、作業性、歩留まり、風味が共に優れた離型油が提供可能であることを見出して本発明を完成するに至った。すなわち本発明は、ポリソルベートを0.05〜10重量%含有することを特徴とする離型油である。
さらに本発明は、ポリソルベートに加えて、レシチンの他に、グリセリン脂肪酸エステル、ポリグリセリン脂肪酸エステル、グリセリン有機酸エステル、ショ糖脂肪酸エステル、ソルビタン脂肪酸エステル、ポリグリセリン縮合リシノレイン酸エステル、プロピレングリコール脂肪酸エステルから選ばれる1種類または2種類以上を配合してなる離型油である。
As a result of diligent research in view of the above problems, the present inventors have obtained excellent release properties, workability, yield, and flavor by incorporating a predetermined amount of polysorbate into fats and oils for use in food applications. The present inventors have found that a release oil can be provided and have completed the present invention. That is, this invention is a mold release oil characterized by containing 0.05-10 weight% of polysorbates.
Furthermore, in addition to lecithin, the present invention, in addition to lecithin, from glycerin fatty acid ester, polyglycerin fatty acid ester, glycerin organic acid ester, sucrose fatty acid ester, sorbitan fatty acid ester, polyglycerin condensed ricinoleic acid ester, propylene glycol fatty acid ester It is a release oil formed by blending one or more selected ones.

食用油脂にポリソルベートを0.05〜10重量%配合することにより、離型性、作業性、歩留まり、風味共に優れた離型油が得られ、それを用いることにより優れた炒め物、麺類、パン類を提供し得る。   Mixing 0.05 to 10% by weight of polysorbate with edible fats and oils provides release oils that are excellent in mold release, workability, yield, and flavor. Can provide a kind.

本発明におけるポリソルベートは、ソルビタン脂肪酸エステルにエチレンオキシド20モルを付加させた非イオン性界面活性剤で、ポリソルベート20(ポリオキシエチレン(20)ソルビタンモノラウレート)、ポリソルベート60(ポリオキシエチレン(20)ソルビタンモノステアレート)、ポリソルベート65(ポリオキシエチレン(20)ソルビタントリステアレート)、ポリソルベート80(ポリオキシエチレン(20)ソルビタンモノオレエート)が用いられる。分散性、溶解性の問題から、比較的親油性であるポリソルベート65がより望ましい。
本発明の離型油中におけるポリソルベートの含量は、0.05〜10重量%、好ましくは0.1〜5重量%、さらに好ましくは0.1〜3重量%である。0.05重量%未満ではその機能が充分発揮されず、また10重量%を越えると離型油の風味に悪影響を及ぼす。
The polysorbate in the present invention is a nonionic surfactant obtained by adding 20 mol of ethylene oxide to a sorbitan fatty acid ester. Polysorbate 20 (polyoxyethylene (20) sorbitan monolaurate), polysorbate 60 (polyoxyethylene (20) sorbitan) Monostearate), polysorbate 65 (polyoxyethylene (20) sorbitan tristearate), polysorbate 80 (polyoxyethylene (20) sorbitan monooleate) are used. In view of dispersibility and solubility, polysorbate 65 that is relatively lipophilic is more desirable.
The polysorbate content in the release oil of the present invention is 0.05 to 10% by weight, preferably 0.1 to 5% by weight, and more preferably 0.1 to 3% by weight. If it is less than 0.05% by weight, the function is not sufficiently exhibited, and if it exceeds 10% by weight, the flavor of the release oil is adversely affected.

本発明において油脂組成物の主成分となる油脂としては以下のようなものが挙げられる。すなわち、食用の大豆油、菜種油、コーン油、パーム油、パームオレイン、綿実油、落花生油、紅花油、ひまわり油、米油、小麦胚芽油、大豆胚芽油、ぶどう油、ゴマ油、シソ油、パーム核油、やし油、カカオ脂、えごま油、牛脂、ラード、鶏油、魚油、乳脂、MCT及びこれらの水添油、分別油、エステル交換油等であり、これらは単独であるいは2種以上を混合して使用できる。
常温で液状油である油をベースとして用いる場合はポリソルベートの溶解性、分散性がある程度必要とされるが、固型脂がベースとなるものについては溶解性、分散性がやや低い場合でも、ポリソルベートを物理的に分散させた状態が維持できるため、比較的設計範囲が広くなる。
In the present invention, the following oils and fats are the main components of the oil and fat composition. Edible soybean oil, rapeseed oil, corn oil, palm oil, palm olein, cottonseed oil, peanut oil, safflower oil, sunflower oil, rice oil, wheat germ oil, soybean germ oil, grape oil, sesame oil, perilla oil, palm kernel Oil, palm oil, cacao butter, sesame oil, beef tallow, lard, chicken oil, fish oil, milk fat, MCT and their hydrogenated oil, fractionated oil, transesterified oil, etc. Can be mixed and used.
When using an oil that is a liquid oil at room temperature as a base, the solubility and dispersibility of the polysorbate are required to some extent, but for those based on solid fat, even if the solubility and dispersibility are slightly low, the polysorbate Can be maintained in a physically dispersed state, so that the design range is relatively wide.

本発明においては、ポリソルベートの溶解性の向上、離型性の向上等を目的として乳化剤を添加することもできる。添加される乳化剤としてはHLBが比較的低めで親油性の高いもので、いわゆる食品用乳化剤であるグリセリン脂肪酸エステル、ポリグリセリン脂肪酸エステル、グリセリン有機酸エステル、ショ糖脂肪酸エステル、ソルビタン脂肪酸エステル、ポリグリセリン縮合リシノレイン酸エステル、プロピレングリコール脂肪酸エステル、レシチン等が挙げられる。
これら乳化剤のうちレシチンは特に離型作用が強いため併用して用いられることが望ましい。本発明におけるレシチンとは、リン脂質を主成分としたもので、食品へ用いられるもので香味良好であれば特に限定されない。一般には大豆より抽出された大豆レシチンが用いられるが、卵由来の卵黄レシチン等も使用できる。
また、ペースト状のクルードレシチン、油脂分を除去した脱脂レシチン、ホスフォリパーゼ等の酵素で処理した酵素処理レシチン、溶剤等で特定の成分割合を高めた分画レシチンも用いられる。それぞれのレシチンはリン脂質を有効成分としており、リン脂質濃度は高いことが望ましいが、他の成分が含まれる場合は有効成分であるリン脂質の含量で本発明品への含まれる量を規定することとなる。
In the present invention, an emulsifier may be added for the purpose of improving the solubility of polysorbate, improving the releasability, and the like. As the added emulsifier, HLB is relatively low and highly lipophilic, so-called food emulsifier glycerin fatty acid ester, polyglycerin fatty acid ester, glycerin organic acid ester, sucrose fatty acid ester, sorbitan fatty acid ester, polyglycerin. Examples include condensed ricinoleic acid ester, propylene glycol fatty acid ester, and lecithin.
Of these emulsifiers, lecithin is particularly desirable because it has a strong releasing action. The lecithin in the present invention is a phospholipid as a main component and is not particularly limited as long as it is used for food and has a good flavor. Generally, soybean lecithin extracted from soybean is used, but egg-derived egg yolk lecithin or the like can also be used.
In addition, paste-like crude lecithin, defatted lecithin from which oils and fats have been removed, enzyme-treated lecithin treated with an enzyme such as phospholipase, and fractionated lecithin in which a specific component ratio is increased with a solvent or the like are also used. Each lecithin contains phospholipid as an active ingredient, and it is desirable that the phospholipid concentration is high. However, when other ingredients are included, the content of phospholipid as an active ingredient defines the amount contained in the product of the present invention. It will be.

レシチンの添加量としては0.2〜5重量%が望ましい。0.2%重量未満では必要とする離型性が得られず、また5重量%を越えると風味に悪影響を及ぼす。
また上記乳化剤のうち、溶解性がより向上するポリグリセリン脂肪酸エステルも併用することが好ましい。乳化剤の添加量は0.01〜10重量%が望ましく、より好ましくは0.01〜5重量%である。あまり添加量が多くなると風味に悪影響を与える上、乳化剤そのものの溶解性、分散性が低下するため自ずと添加量は規定される。
これら乳化剤の組み合わせによっては、それぞれが相互的に作用し、溶解性が高まる機能も期待できる。
The amount of lecithin added is preferably 0.2 to 5% by weight. If it is less than 0.2% by weight, the required releasability cannot be obtained, and if it exceeds 5% by weight, the flavor is adversely affected.
Moreover, it is preferable to use together the polyglycerol fatty acid ester from which the solubility improves among the said emulsifiers. The addition amount of the emulsifier is desirably 0.01 to 10% by weight, and more preferably 0.01 to 5% by weight. If the amount added is too large, the flavor is adversely affected, and the solubility and dispersibility of the emulsifier itself are lowered, so the amount added is naturally defined.
Depending on the combination of these emulsifiers, the functions of each of them interacting with each other can be expected to increase the solubility.

本発明における炒め調理とは、主として炒飯、焼きそば、スパゲティ等の調理を意味するがこれに限定されるものではない。
油脂の作用としては鉄板面とのひっつき防止に加え、素材同士のひっつき防止による調理性の向上、風味の付与、加熱の均一化等が挙げられる。さらに本発明品は主要な機能として剥離性を有することから天板上での焼き物にも当然ながら利用することができる。あるいは、食パン焼成に使用されるボックスからの型抜きについても剥離用途として挙げられる。
The stir-fried cooking in the present invention mainly means cooking of fried rice, fried noodles, spaghetti and the like, but is not limited thereto.
The action of the oils and fats includes, in addition to preventing sticking to the iron plate surface, improving cooking properties, imparting flavor, and uniform heating by preventing sticking between materials. Furthermore, since the product of the present invention has peelability as a main function, it can of course be used for baking on a top plate. Or it is mentioned as a peeling use also about the die cutting from the box used for bread baking.

以下に本発明の実施例を示すが、本発明の主旨ははこれに限定されるものではない。   Examples of the present invention are shown below, but the gist of the present invention is not limited thereto.

<油脂組成物の調製>
表1の配合で油脂組成物を調製し、性状を確認した。
<Preparation of oil and fat composition>
An oil and fat composition was prepared with the formulation shown in Table 1, and the properties were confirmed.

Figure 0004651327
Figure 0004651327

<炒め調理による評価>
生米を浸漬したのち重量比95%の水を加え炊飯を行う。炊飯後のご飯は粗熱をとった状態で保管しておく。
回転型炒め機を加熱し釜の温度が約240℃になった時点で表1の油脂組成物のうち、A、C、G、サラダ油を離型油として50g添加する。釜全体に油が行き渡るよう釜を約60秒程度回転させた後、余分な油を廃棄する。再度、本発明の離型油35gを添加する。液卵200gを投入後、すぐにご飯3kgを投入、ほぐしながら1分間炒める。液体調味料300gと具材を添加し約4分間炒める。
炒め終了後直ちに真空冷却機にかけ、品温が20℃になるまで冷却する。冷却した炒飯を容器に充填し20℃で1日保管、電子レンジで加熱しパネラー20名にて官能検査を実施した。
<Evaluation by fried cooking>
After soaking raw rice, add 95% water by weight and cook rice. Store the cooked rice in a state of rough heat.
When the rotary stirrer is heated and the temperature of the kettle reaches about 240 ° C., 50 g of A, C, G and salad oil are added as release oil among the oil and fat compositions shown in Table 1. Rotate the kettle for about 60 seconds so that the oil reaches the entire kettle, and then discard excess oil. Again, 35 g of the release oil of the present invention is added. After adding 200g of liquid egg, immediately add 3kg of rice and fry for 1 minute while loosening. Add 300g of liquid seasoning and ingredients and fry for about 4 minutes.
Immediately after the frying, apply a vacuum cooler and cool until the product temperature reaches 20 ° C. The cooled fried rice was filled in a container, stored at 20 ° C. for 1 day, heated in a microwave oven, and subjected to a sensory test by 20 panelists.

Figure 0004651327
Figure 0004651327

表2より、参考実施例1、2共に炒飯の離型性および風味は比較例1、2に比べ優れていた。
From Table 2, the releasability and flavor of the fried rice were superior to Comparative Examples 1 and 2 in both Reference Examples 1 and 2.

<ほぐし油としての効果>
市販のうどんを茹で、150gに小分けした後、表1の油脂組成物のうちA、C、G、またはサラダ油をほぐし油として各3重量%添加し、冷蔵で保存したのち、ほぐれ性を確認した。同時に、食味を評価した。
<Effect as unraveling oil>
After submerging commercially available udon into 150 g, add 3% by weight of A, C, G, or salad oil among the oil / fat compositions in Table 1 as unraveling oil, and storing in refrigeration. . At the same time, the taste was evaluated.

Figure 0004651327
Figure 0004651327

表3より、実施例3、4共にうどんのほぐれ性および風味は比較例3、4に比べ優れていた。   From Table 3, the looseness and flavor of udon were superior to Comparative Examples 3 and 4 in both Examples 3 and 4.

Claims (3)

ポリソルベートを0.05〜10重量%およびレシチンを0.05〜5重量%含有する油脂を添加することを特徴とする麺類ほぐれ性を向上させる方法。 A method for improving the looseness of noodles , comprising adding an oil containing 0.05 to 10% by weight of polysorbate and 0.05 to 5% by weight of lecithin. ポリソルベートがポリソルベート20である請求項1に記載の方法。 The method of claim 1, wherein the polysorbate is polysorbate 20. 油脂に、グリセリン脂肪酸エステル、ポリグリセリン脂肪酸エステル、グリセリン有機酸エステル、ショ糖脂肪酸エステル、ソルビタン脂肪酸エステル、ポリグリセリン縮合リシノレイン酸エステル、プロピレングリコール脂肪酸エステルから選ばれる1種類または2種類以上を配合してなる請求項1又は2に記載の方法。 One or more selected from glycerin fatty acid ester, polyglycerin fatty acid ester, glycerin organic acid ester, sucrose fatty acid ester, sorbitan fatty acid ester, polyglycerin condensed ricinoleic acid ester, propylene glycol fatty acid ester The method according to claim 1 or 2.
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JP4663696B2 (en) * 2007-08-08 2011-04-06 株式会社J−オイルミルズ Oil composition for cooking
JP5812709B2 (en) * 2011-06-16 2015-11-17 日清オイリオグループ株式会社 Oil-and-fat composition for improving looseness, non-baked foods using oil-and-fat compositions for improving looseness, and method for producing non-fired foods
JP5174293B1 (en) * 2011-08-29 2013-04-03 株式会社J−オイルミルズ Oil composition for frying and method for producing the same
CN102792986B (en) * 2012-08-17 2013-07-31 芝兰雅烘焙原料(无锡)有限公司 Demoulding oil for bread
JP5685338B1 (en) * 2014-06-06 2015-03-18 株式会社J−オイルミルズ Method for producing stir-fried cooked rice
JP6375153B2 (en) * 2014-06-19 2018-08-15 ミヨシ油脂株式会社 Release oil

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US3415660A (en) * 1965-12-29 1968-12-10 Procter & Gamble Clear cooking and salad oils having antispattering properties
JPH04326936A (en) * 1991-04-24 1992-11-16 Dai Ichi Kogyo Seiyaku Co Ltd Emulsifier composition for processed oils and fats
KR950003530B1 (en) * 1992-07-02 1995-04-14 제일제당 주식회사 Edible oil
JP2004065216A (en) * 2002-08-05 2004-03-04 Amacos:Kk Improving agent of cooked rice and noodle, and cooked rice and noodle
JP2004215543A (en) * 2003-01-14 2004-08-05 Taiyo Kagaku Co Ltd Noodle quality improving agent and method for producing noodle
JP2005312344A (en) * 2004-04-28 2005-11-10 Riken Vitamin Co Ltd Oil and fat composition for cooked rice, or the like
JP2006006132A (en) * 2004-06-23 2006-01-12 Riken Vitamin Co Ltd Oil and fat composition for improving loosening property of noodles

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3355302A (en) * 1964-01-24 1967-11-28 Procter & Gamble Anti-spattering plastic shortening
US3415660A (en) * 1965-12-29 1968-12-10 Procter & Gamble Clear cooking and salad oils having antispattering properties
JPH04326936A (en) * 1991-04-24 1992-11-16 Dai Ichi Kogyo Seiyaku Co Ltd Emulsifier composition for processed oils and fats
KR950003530B1 (en) * 1992-07-02 1995-04-14 제일제당 주식회사 Edible oil
JP2004065216A (en) * 2002-08-05 2004-03-04 Amacos:Kk Improving agent of cooked rice and noodle, and cooked rice and noodle
JP2004215543A (en) * 2003-01-14 2004-08-05 Taiyo Kagaku Co Ltd Noodle quality improving agent and method for producing noodle
JP2005312344A (en) * 2004-04-28 2005-11-10 Riken Vitamin Co Ltd Oil and fat composition for cooked rice, or the like
JP2006006132A (en) * 2004-06-23 2006-01-12 Riken Vitamin Co Ltd Oil and fat composition for improving loosening property of noodles

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