JP2003064395A - Oil and fat composition - Google Patents

Oil and fat composition

Info

Publication number
JP2003064395A
JP2003064395A JP2001252610A JP2001252610A JP2003064395A JP 2003064395 A JP2003064395 A JP 2003064395A JP 2001252610 A JP2001252610 A JP 2001252610A JP 2001252610 A JP2001252610 A JP 2001252610A JP 2003064395 A JP2003064395 A JP 2003064395A
Authority
JP
Japan
Prior art keywords
oil
weight
fat
fat composition
oleic acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2001252610A
Other languages
Japanese (ja)
Other versions
JP5153040B2 (en
Inventor
Machiko Noboriguchi
満知子 登口
Onori Ito
大典 伊藤
Shoshi Maruzeni
詔司 丸銭
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Adeka Corp
Original Assignee
Asahi Denka Kogyo KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Asahi Denka Kogyo KK filed Critical Asahi Denka Kogyo KK
Priority to JP2001252610A priority Critical patent/JP5153040B2/en
Publication of JP2003064395A publication Critical patent/JP2003064395A/en
Application granted granted Critical
Publication of JP5153040B2 publication Critical patent/JP5153040B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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  • Edible Oils And Fats (AREA)
  • Bakery Products And Manufacturing Methods Therefor (AREA)
  • Fats And Perfumes (AREA)

Abstract

PROBLEM TO BE SOLVED: To provide an oil and fat composition having a high oleic acid content, good oxidation stability and thermal stability, making meltability in the mouth, flavor and texture of the oil and fat composition and a food obtained by using the composition good, and not making the composition and the food greasy. SOLUTION: This oil and fat composition contains a transesterified oil and fat, and >=50 wt.% oleic acid. The transesterified oil and fat is obtained by subjecting (A) 99-40 wt.% oil and fat containing >=30 wt.% oleic acid, and (B) 1-60 wt.% extreme hardened oil obtained by hardening an oil and fat different from the oil and fat of the component (A), and containing >=60 wt.% stearic acid, to an ester-interchange reaction.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【発明の属する技術分野】本発明は、製パン・製菓用、
フライ用、その他調理用等として用いられる油脂組成物
に関するものである。
TECHNICAL FIELD The present invention relates to bread and confectionery,
The present invention relates to an oil and fat composition used for frying and other cooking.

【0002】[0002]

【従来の技術】消費者の嗜好の変化に伴い、口溶け、風
味、食感が良く、食べたときに油っぽくない食品が好ま
れ、そのような食品を提供できる油脂が求められてい
る。一方、健康志向の高まる昨今、血中のHDLコレス
テロールを減らさずLDLコレステロールのみを減らす
と言われているオレイン酸は、非常に注目されている。
菜種油、ハイオレイックキャノーラ油、ハイオレイック
サフラワー油、ハイオレイックひまわり油等は、オレイ
ン酸含量が高い。しかし、例えばフライ油として用いた
場合、熱安定性に欠けるため淡白な風味が持続せず、得
られたフライ食品はさくさく感に欠け油っぽくなり好ま
しくない。また、スプレー油として用いた場合には、酸
化安定性に欠けるため淡白な風味が持続せず、スプレー
した食品の食感もぱりぱり感に欠け油っぽくなり好まし
くない。さらに、マーガリンやショートニング製造用油
脂として用いた場合には、十分な可塑性を得ることが出
来ない。
2. Description of the Related Art As consumers' tastes change, foods that melt in the mouth, have a good taste and texture and are not oily when eaten are preferred, and oils and fats that can provide such foods are required. On the other hand, oleic acid, which is said to reduce LDL cholesterol alone without reducing HDL cholesterol in the blood, has been receiving a great deal of attention in recent years due to increasing health consciousness.
Rapeseed oil, high oleic canola oil, high oleic safflower oil, high oleic sunflower oil and the like have a high oleic acid content. However, when it is used as frying oil, for example, it lacks heat stability and the pale flavor does not continue, and the resulting fried food lacks crispness and becomes oily, which is not preferable. Further, when used as a spray oil, the pale flavor is not maintained due to lack of oxidative stability, and the sprayed food lacks a crisp texture and is oily, which is not preferable. Further, when it is used as a fat or oil for producing margarine or shortening, sufficient plasticity cannot be obtained.

【0003】このようなオレイン酸含量の高い油脂の欠
点を補うには、飽和脂肪酸の存在が必須と考えられる。
飽和脂肪酸割合を高める方法として、油脂を硬化する方
法や硬化油を配合する方法が挙げられる。このような油
脂を硬化する方法や硬化油を配合する方法は、物性を改
良し、油っぽさを低減させ、酸化安定性及び熱安定性を
改良する方法として、広く用いられてきた。しかし、油
脂を硬化する方法や硬化油を配合する方法では、口溶
け、風味、物性及び食感の良さと油っぽさの解消を同時
に満足できる食品は得がたい。
It is considered that the presence of saturated fatty acids is indispensable for compensating for the drawbacks of fats and oils having a high oleic acid content.
Examples of methods for increasing the saturated fatty acid ratio include a method of hardening fats and oils and a method of blending hardened oils. Such a method for hardening fats and oils and a method for blending hardened oils have been widely used as methods for improving physical properties, reducing oiliness, and improving oxidative stability and thermal stability. However, it is difficult to obtain a food that can be satisfied with melting in the mouth, good taste, physical properties and texture and elimination of oiliness at the same time by the method of hardening fats and oils and the method of blending hardened oil.

【0004】例えば、特開平4−173053号公報で
は、高エルシン菜種極度硬化油を油脂に対し0.5〜5
重量%と比較的少量配合することにより課題に対処して
いるが、これをフライ油として用いたフライ食品は、油
っぽさの面でやや問題がある。特開2001−6991
3号公報では、極度硬化油を油脂に対し5.1〜35.
0重量%と比較的多量に配合することにより課題に対処
しているが、これをフライ油として用いたフライ食品
は、口溶けの面でやや問題がある。
For example, in Japanese Patent Laid-Open No. 4-173053, high-erucin rapeseed extremely hardened oil is added in an amount of 0.5 to 5 with respect to fats and oils.
Although the problem is addressed by blending it in a relatively small amount such as wt%, fried foods using this as frying oil have some problems in terms of oiliness. JP 2001-6991 A
In Japanese Patent Laid-Open No. 3-5, an extremely hardened oil is added to fats and oils at 5.1 to 35.
The problem has been dealt with by blending a relatively large amount of 0% by weight, but fried foods using this as frying oil have some problems in terms of melting in the mouth.

【0005】一方、2種以上の油脂をエステル交換する
方法、あるいはエステル交換油脂を配合する方法も公知
である。例えば特開平11−289976号公報には、
ラード及び/又は分別ラードと炭素数22の飽和脂肪酸
を含有する油脂とのエステル交換油脂を含有した可塑性
油脂組成物が記載されている。また、特表平11−51
0396号公報には、ステアリン酸残基含量、パルミチ
ン酸残基含量、不飽和C18酸残基含量が特定量である
水素添加されていない植物性脂肪をエステル交換した油
脂を配合する油脂組成物が記載されている。しかし、こ
れらの方法を用いても、オレイン酸含量が高く、口溶け
が良く、食品の食感にも問題がない油脂組成物を得るの
は困難であった。
On the other hand, a method of transesterifying two or more kinds of fats and oils or a method of blending transesterified fats and oils is also known. For example, in Japanese Patent Laid-Open No. 11-289976,
A plastic oil / fat composition containing a transesterified oil / fat of lard and / or fractionated lard and an oil / fat containing a saturated fatty acid having 22 carbon atoms is described. In addition, special table flat 11-51
No. 0396 discloses an oil / fat composition containing a fat / oil obtained by transesterifying a non-hydrogenated vegetable fat having a specific amount of stearic acid residue content, palmitic acid residue content, and unsaturated C18 acid residue content. Have been described. However, even if these methods are used, it is difficult to obtain an oil / fat composition having a high oleic acid content, a good meltability in the mouth, and no problem in the texture of foods.

【0006】[0006]

【発明が解決しようとする課題】従って、本発明の目的
は、オレイン酸含量が高く、酸化安定性及び熱安定性が
良好であり、油脂組成物や該油脂組成物を用いた食品の
口溶け、風味、食感及び物性を良好なものとし、さらに
油っぽくないものとすることができる油脂組成物を提供
することにある。
Accordingly, the object of the present invention is to have a high oleic acid content, good oxidative stability and thermal stability, and an oil-fat composition or a food-soluble product using the oil-fat composition, which dissolves in the mouth, An object of the present invention is to provide an oil and fat composition which has good flavor, texture and physical properties and can be made not oily.

【0007】[0007]

【課題を解決するための手段】本発明者等は、種々検討
を重ねた結果、特定のエステル交換油脂を含有し、且つ
オレイン酸を特定量含有する油脂組成物が、上記課題を
解決し得ることを知見し、本発明に到達した。即ち、本
発明は、オレイン酸を30重量%以上含有する油脂
(A)99〜40重量%と、該油脂(A)と異なる油脂
を硬化したステアリン酸を60重量%以上含有する極度
硬化油(B)1〜60重量%とをエステル交換反応して
なるエステル交換油脂を含有し、オレイン酸を50重量
%以上含有する油脂組成物を提供するものである。
Means for Solving the Problems As a result of various studies by the present inventors, an oil and fat composition containing a specific transesterified oil and fat and containing a specific amount of oleic acid can solve the above problems. The inventors have found that and reached the present invention. That is, the present invention is an extremely hardened oil containing 99 to 40% by weight of oil (A) containing 30% by weight or more of oleic acid and 60% by weight or more of stearic acid obtained by hardening an oil or fat different from the oil (A) ( B) An oil and fat composition containing a transesterified oil and fat obtained by transesterification with 1 to 60% by weight and containing 50% by weight or more of oleic acid.

【0008】[0008]

【発明の実施の形態】以下、本発明の油脂組成物につい
て詳しく説明する。
BEST MODE FOR CARRYING OUT THE INVENTION The oil and fat composition of the present invention will be described in detail below.

【0009】本発明の油脂組成物に含有されるエステル
交換油脂の一方の原料である油脂(A)は、オレイン酸
を30重量%以上、好ましくは35〜90重量%、さら
に好ましくは40〜85重量%含有するものである。上
記油脂(A)は、オレイン酸以外の脂肪酸組成に特に規
定はなく、比較的やわらかい物性を目的とする場合は不
飽和脂肪酸含量が高いもの、比較的硬い物性を目的とす
る場合は飽和脂肪酸含量が高いものを選ぶが、前者であ
ればオレイン酸含量、後者であればステアリン酸含量が
高いことが好ましい。
The oil (A), which is one of the raw materials for the transesterified oil and fat contained in the oil and fat composition of the present invention, contains 30% by weight or more of oleic acid, preferably 35 to 90% by weight, more preferably 40 to 85%. It is the one containing wt%. The fats and oils (A) are not particularly limited in their fatty acid composition other than oleic acid, and have a high unsaturated fatty acid content for the purpose of relatively soft physical properties, and a saturated fatty acid content for the purpose of relatively hard physical properties. It is preferable that the former has a high oleic acid content and the latter has a high stearic acid content.

【0010】上記油脂(A)としては、例えば、低エル
シン菜種油、米油、とうもろこし油、落花生油、ゴマ
油、ハイオレイックキャノーラ油、ハイオレイックサフ
ラワー油、ハイオレイックひまわり油等の液状油、パー
ム油、サル脂、シア脂、マンゴー脂、コクム脂、イリッ
ペ脂、ラード、牛脂等の固形脂、これら固形脂の分別
油、あるいはこれら固形脂の2種以上の配合油の分別油
の中から選ばれた1種又は2種以上の配合油が挙げられ
る。これらの中では、低エルシン菜種油、ハイオレイッ
クキャノーラ油、ハイオレイックサフラワー油、ハイオ
レイックひまわり油、サル脂、サル脂分別軟部油又は牛
脂を用いるのが好ましい。また、オレイン酸含量30重
量%未満の油脂でも、上記のオレイン酸含量30重量%
以上の油脂と配合し、配合油のオレイン酸含量を30重
量%以上として用いることもできる。
Examples of the fats and oils (A) include liquid oils such as low-erucin rapeseed oil, rice oil, corn oil, peanut oil, sesame oil, high oleic canola oil, high oleic safflower oil, high oleic sunflower oil, palm, and the like. Solid fats such as oil, monkey fat, shea butter, mango fat, kokum butter, illipe fat, lard, beef tallow, etc., fractionated oils of these solid fats, or fractionated oils of two or more blended oils of these solid fats And one or more blended oils. Among these, it is preferable to use low erucin rapeseed oil, high oleic canola oil, high oleic safflower oil, high oleic sunflower oil, monkey fat, monkey fat separation soft part oil or beef tallow. In addition, even oils and fats having an oleic acid content of less than 30% by weight, the above oleic acid content of 30% by weight
The oleic acid content of the blended oil may be 30% by weight or more by blending with the above fats and oils.

【0011】本発明の油脂組成物に含有されるエステル
交換油脂の他方の原料である極度硬化油(B)は、上記
油脂(A)と異なる油脂を硬化した油脂であって、ステ
アリン酸を60重量%以上、好ましくは70重量%以
上、さらに好ましくは80重量%以上含有する極度硬化
油である。
The extremely hardened oil (B), which is the other raw material of the transesterified fats and oils contained in the fat and oil composition of the present invention, is a fat and oil obtained by hardening a fat and oil different from the fat and oil (A), and contains 60 stearic acid. It is an extremely hardened oil containing not less than 70% by weight, preferably not less than 70% by weight, more preferably not less than 80% by weight.

【0012】上記極度硬化油(B)としては、例えば、
大豆油、低エルシン菜種油、米油、綿実油、とうもろこ
し油、サフラワー油、ひまわり油、落花生油、ゴマ油、
ハイオレイックキャノーラ油、ハイオレイックサフラワ
ー油、ハイオレイックひまわり油等の極度硬化油、サル
脂、シア脂、マンゴー脂、コクム脂、イリッペ脂、ラー
ド、牛脂等の極度硬化油、及びサル脂、シア脂、マンゴ
ー脂、コクム脂、イリッペ脂、ラード、牛脂等の分別油
の極度硬化油の中から選ばれた1種又は2種以上の配合
油が挙げられる。これらの中で、大豆油又は低エルシン
菜種油の極度硬化油を用いるのが好ましい。
As the above-mentioned extremely hardened oil (B), for example,
Soybean oil, low-elsin rapeseed oil, rice oil, cottonseed oil, corn oil, safflower oil, sunflower oil, peanut oil, sesame oil,
Extremely hardened oils such as high oleic canola oil, high oleic safflower oil and high oleic sunflower oil, extremely hardened oils such as monkey butter, shea butter, mango butter, kokum butter, illipe fat, lard, beef tallow, and sal butter, One or more blended oils selected from extremely hardened oils of fractionated oils such as shea butter, mango butter, kokum butter, illipe butter, lard, and beef tallow. Of these, it is preferable to use soybean oil or extremely hardened oil of low erucin rapeseed oil.

【0013】上記の油脂(A)と極度硬化油(B)の配
合割合は、油脂(A)99〜40重量%と、極度硬化油
(B)1〜60重量%、好ましくは油脂(A)97〜4
5重量%と、極度硬化油(B)3〜55重量%、さらに
好ましくは油脂(A)95〜50重量%と、極度硬化油
(B)5〜50重量%である。
The fat and oil (A) and the extremely hardened oil (B) are compounded in proportions of 99 to 40% by weight of the fat and oil (A) and 1 to 60% by weight of the extremely hardened oil (B), preferably the fat and oil (A). 97-4
5% by weight, extremely hardened oil (B) 3 to 55% by weight, more preferably fat and oil (A) 95 to 50% by weight, and extremely hardened oil (B) 5 to 50% by weight.

【0014】上記のエステル交換の方法としては、リパ
ーゼを触媒として用いる方法又はナトリウムメチラート
等の金属触媒を用いる方法の何れの方法でもよいが、リ
パーゼを用いる方法の方が風味の良い油脂となる。上記
のリパーゼは、位置特異性を有するものでも、位置特異
性を有さないものでもよい。本発明で用いるリパーゼと
しては、例えば、アルカリゲネス属、リゾプス属、アス
ペルギルス属、ムコール属、ペニシリウム属、キャンリ
ダ属等から得られるリパーゼが挙げられる。これらのリ
パーゼは単体で使用することも可能であるが、通常はケ
イソウ土、アルミナ、活性炭、セラミック等の担体に固
定化させて用いるのがよい。リパーゼを用いたエステル
交換反応の反応条件は特に制限はないが、無溶媒下で行
うのが好ましく、反応温度60〜85℃で行うのが好ま
しい。反応は、カラム式の連続反応、バッチ式反応のど
ちらでもよい。また、ナトリウムメチラート等の金属触
媒を用いたエステル交換反応は、通常の方法に従って行
えばよい。
The above transesterification method may be either a method using a lipase as a catalyst or a method using a metal catalyst such as sodium methylate, but the method using a lipase produces a fat and oil having a good taste. . The above lipase may or may not have regiospecificity. Examples of the lipase used in the present invention include lipases obtained from the genera Alcaligenes, Rhizopus, Aspergillus, Mucor, Penicillium, Canrida and the like. These lipases can be used alone, but usually they are preferably used after being immobilized on a carrier such as diatomaceous earth, alumina, activated carbon or ceramics. The reaction condition of the transesterification reaction using lipase is not particularly limited, but it is preferably carried out in the absence of a solvent, preferably at a reaction temperature of 60 to 85 ° C. The reaction may be a column-type continuous reaction or a batch-type reaction. The transesterification reaction using a metal catalyst such as sodium methylate may be carried out according to a usual method.

【0015】このようなエステル交換反応で生成した油
脂は、通常の方法に従って、漂白、脱臭又は脱酸、漂
白、脱臭を行うことによって精製し、これをエステル交
換油脂として用いる。
The fats and oils produced by such a transesterification reaction are purified by bleaching, deodorizing or deoxidizing, bleaching and deodorizing according to a usual method, and used as transesterifying fats and oils.

【0016】本発明の油脂組成物は、このようにして得
られたエステル交換油脂を含有する。上記のエステル交
換油脂の含有量は、本発明の油脂組成物中、好ましくは
20重量%以上、さらに好ましくは25重量%以上、最
も好ましくは30重量%以上である。上記のエステル交
換油脂が20重量%未満であると、その効果が得られに
くい。例えばフライ油として用いた場合、熱安定性に欠
けるため淡白な風味が持続せず、得られたフライ食品は
さくさく感に欠け油っぽくなり好ましくない。また、ス
プレー油として用いた場合、酸化安定性に欠けるため淡
白な風味が持続せず、スプレーした食品の食感もぱりぱ
り感に欠け油っぽくなり好ましくない。さらに、マーガ
リンやショートニング製造用油脂として用いた場合に
は、十分な可塑性を得ることが出来ないので好ましくな
い。
The oil and fat composition of the present invention contains the transesterified oil and fat thus obtained. The content of the above transesterified oil or fat is preferably 20% by weight or more, more preferably 25% by weight or more, and most preferably 30% by weight or more in the oil or fat composition of the present invention. If the amount of the above transesterified oil / fat is less than 20% by weight, it is difficult to obtain the effect. For example, when used as frying oil, it lacks heat stability and the pale flavor does not continue, and the resulting fried food lacks crispness and becomes oily, which is not preferable. Further, when used as a spray oil, the pale flavor is not maintained due to lack of oxidative stability, and the sprayed food lacks a crisp texture and becomes oily, which is not preferable. Furthermore, when it is used as a fat or oil for producing margarine or shortening, sufficient plasticity cannot be obtained, which is not preferable.

【0017】また、本発明の油脂組成物はオレイン酸含
量が50重量%以上、好ましくは54重量%以上、さら
に好ましくは56重量%以上である。オレイン酸含量を
50重量%以上にすることにより、口溶けが良く風味も
淡白な食品とすることができ、さらに、血中のHDLコ
レステロールを減らさずLDLコレステロールのみを減
らすと言われているオレイン酸が脂肪酸割合の半分以上
を占める油脂組成物とすることができる。
The oil and fat composition of the present invention has an oleic acid content of 50% by weight or more, preferably 54% by weight or more, and more preferably 56% by weight or more. By adjusting the oleic acid content to 50% by weight or more, it is possible to obtain a food having a good mouth-melting property and a light taste, and further, it is said that oleic acid, which is said to reduce only LDL cholesterol without reducing HDL cholesterol in blood, An oil and fat composition that accounts for more than half of the fatty acid ratio can be obtained.

【0018】また、本発明の油脂組成物は、ステアリン
酸含量が好ましくは10重量%以上、さらに好ましくは
11重量%以上、最も好ましくは12重量%以上であ
る。ステアリン酸含量が10重量%よりも少ないと、熱
安定性及び酸化安定性に欠けやすく、そのため淡白な風
味が持続されにくく、食品の食感も油っぽくなりやす
い。さらに、マーガリンやショートニング製造用油脂と
して用いた場合には、十分な可塑性が得られにくい。
The oil and fat composition of the present invention has a stearic acid content of preferably 10% by weight or more, more preferably 11% by weight or more, and most preferably 12% by weight or more. When the content of stearic acid is less than 10% by weight, the thermal stability and the oxidative stability are likely to be poor, so that the pale flavor is unlikely to be maintained and the texture of food tends to be oily. Further, when it is used as a fat or oil for producing margarine or shortening, it is difficult to obtain sufficient plasticity.

【0019】本発明の油脂組成物では、上記のエステル
交換油脂以外の油脂を配合してもよい。上記のエステル
交換油脂以外の油脂としては特に制限はないが、好まし
くはオレイン酸含量が55重量%以上、さらに好ましく
は60重量%以上、最も好ましくは65重量%以上の油
脂を用いるのがよい。上記のエステル交換油脂以外の油
脂の含有量は、本発明の油脂組成物中、好ましくは80
重量%未満、さらに好ましくは75重量%未満、最も好
ましくは70重量%未満である。
In the oil / fat composition of the present invention, an oil / fat other than the above-mentioned transesterified oil / fat may be blended. There is no particular limitation on fats and oils other than the above transesterified fats and oils, but it is preferable to use fats and oils having an oleic acid content of 55% by weight or more, more preferably 60% by weight or more, and most preferably 65% by weight or more. The content of fats and oils other than the above transesterified fats and oils is preferably 80 in the fat and oil composition of the present invention.
It is less than wt%, more preferably less than 75 wt%, most preferably less than 70 wt%.

【0020】本発明の油脂組成物の融点は、好ましくは
25℃以上50℃未満、さらに好ましくは27℃以上4
5℃未満である。
The melting point of the oil / fat composition of the present invention is preferably 25 ° C. or higher and lower than 50 ° C., more preferably 27 ° C. or higher 4
It is less than 5 ° C.

【0021】上記の油脂組成物は、ドーナツ、揚げパ
ン、フリッター、フライドポテト、天ぷら、素揚げ、空
揚げ、フライ等の食品を製造する際のフライ用油脂組成
物、ポテトやコーン、米、小麦粉等を原料としたスナッ
ク菓子類、プレッツェル、ハードビスケット、クラッカ
ー等の菓子類、パン類、ケーキ類等の食品を製造する際
のスプレー用油脂組成物として用いることができる。さ
らに、食パン、菓子パン、パイ、デニッシュ、シュ、ド
ーナツ、ケーキ、クラッカー、クッキー、ビスケット、
ワッフル、スコーン、スナック菓子等を製造する際のマ
ーガリン用油脂組成物及びショートニング用油脂組成物
として用いることができ、この際マーガリン用油脂組成
物やショートニング用油脂組成物は、ロールイン用、練
りこみ用、サンド用、フィリング用、トッピング用、ス
プレッド用として用いることができる。その他調理用油
脂組成物、ハードバター用油脂組成物及びクリーム用油
脂組成物として本発明の油脂組成物を用いることもでき
る。
The above-mentioned oil and fat composition is a fat and oil composition for frying when producing foods such as donuts, fried bread, fritters, french fries, tempura, fried, fried, fried, potatoes, corn, rice, flour, etc. It can be used as an oil and fat composition for spraying when producing foods such as snacks, pretzels, hard biscuits, confectionery such as crackers, breads, cakes, etc. In addition, bread, sweet bread, pies, Danish, syrup, donuts, cakes, crackers, cookies, biscuits,
Waffles, scones, can be used as an oil and fat composition for margarine and a shortening oil and fat composition when producing snacks, etc., in which case the oil and fat composition for margarine and shortening oil and fat compositions for roll-in, kneading It can be used for sanding, filling, toppings and spreads. In addition, the oil / fat composition of the present invention can be used as an oil / fat composition for cooking, an oil / fat composition for hard butter, and an oil / fat composition for cream.

【0022】また、本発明の油脂組成物が乳化させた油
脂組成物である場合は、その乳化形態は油中水型、水中
油型及び二重乳化型のいずれでも構わない。本発明の油
脂組成物の油相と水相の重量割合は、好ましくは95/
5〜20/80である。
When the oil / fat composition of the present invention is an emulsified oil / fat composition, the emulsified form may be any of water-in-oil type, oil-in-water type and double-emulsion type. The weight ratio of the oil phase and the water phase of the oil and fat composition of the present invention is preferably 95 /
It is 5 to 20/80.

【0023】本発明の油脂組成物に必要により含有させ
ることができる成分としては、例えば水、乳化剤、増粘
安定剤、食塩、塩化カリウム等の塩味剤、酢酸、乳酸、
グルコン酸等の酸味料、糖類や糖アルコール類、ステビ
ア、アスパルテーム等の甘味料、β−カロチン、カラメ
ル、紅麹色素等の着色料、トコフェロール、茶抽出物等
の酸化防止剤、小麦蛋白や大豆蛋白といった植物蛋白、
卵及び各種卵加工品、着香料、乳製品、調味料、pH調
整剤、食品保存料、日持ち向上剤、果実、果汁、コーヒ
ー、ナッツペースト、香辛料、ココアマス、ココアパウ
ダー、穀類、豆類、野菜類、肉類、魚介類等の食品素材
や食品添加物が挙げられる。
Examples of components that can be optionally contained in the oil and fat composition of the present invention include water, emulsifiers, thickening stabilizers, salt, salting agents such as potassium chloride, acetic acid, lactic acid,
Acidulants such as gluconic acid, sugars and sugar alcohols, sweeteners such as stevia and aspartame, colorants such as β-carotene, caramel and red yeast rice pigments, tocopherols, antioxidants such as tea extract, wheat protein and soybeans. Plant proteins such as proteins,
Eggs and various egg products, flavorings, dairy products, seasonings, pH adjusters, food preservatives, shelf life improvers, fruits, fruit juices, coffee, nut pastes, spices, cocoa trout, cocoa powder, grains, beans, vegetables , Food materials such as meat and seafood, and food additives.

【0024】上記乳化剤としては、グリセリン脂肪酸エ
ステル、蔗糖脂肪酸エステル、ソルビタン脂肪酸エステ
ル、プロピレングリコール脂肪酸エステル、グリセリン
有機酸脂肪酸エステル、ポリグリセリン脂肪酸エステ
ル、ポリグリセリン縮合リシノレイン酸エステル、ステ
アロイル乳酸カルシウム、ステアロイル乳酸ナトリウ
ム、ポリオキシエチレン脂肪酸エステル、ポリオキシエ
チレンソルビタン脂肪酸エステル、レシチン、サポニ
ン、植物ステロール類等が挙げられ、これらの中から選
ばれた1種又は2種以上を用いることができる。上記乳
化剤の含有量は、特に制限はないが、本発明の油脂組成
物中、好ましくは0.01〜5重量%、さらに好ましく
は0.05〜3重量%、最も好ましくは0.1〜1重量
%である。また、本発明の油脂組成物において、上記乳
化剤が必要でなければ、乳化剤を用いなくてもよい。
Examples of the emulsifier include glycerin fatty acid ester, sucrose fatty acid ester, sorbitan fatty acid ester, propylene glycol fatty acid ester, glycerin organic acid fatty acid ester, polyglycerin fatty acid ester, polyglycerin condensed ricinoleic acid ester, calcium stearoyl lactylate, sodium stearoyl lactylate. , Polyoxyethylene fatty acid ester, polyoxyethylene sorbitan fatty acid ester, lecithin, saponin, plant sterols and the like, and one or more selected from these can be used. The content of the emulsifier is not particularly limited, but is preferably 0.01 to 5% by weight, more preferably 0.05 to 3% by weight, and most preferably 0.1 to 1 in the fat and oil composition of the present invention. % By weight. Further, in the oil and fat composition of the present invention, if the above emulsifier is not necessary, the emulsifier may not be used.

【0025】上記増粘安定剤としては、グアーガム、ロ
ーカストビーンガム、カラギーナン、アラビアガム、ア
ルギン酸類、ペクチン、キサンタンガム、プルラン、タ
マリンドシードガム、サイリウムシードガム、結晶セル
ロース、カルボキシメチルセルロース、メチルセルロー
ス、寒天、グルコマンナン、ゼラチン、澱粉、化工澱粉
等が挙げられ、これらの中から選ばれた1種又は2種以
上を用いることができる。上記増粘安定剤の含有量は、
特に制限はないが、本発明の油脂組成物中、好ましくは
0〜10重量%、さらに好ましくは0〜5重量%であ
る。また、本発明の油脂組成物において、上記増粘安定
剤が必要でなければ、増粘安定剤を用いなくてもよい。
Examples of the thickening stabilizer include guar gum, locust bean gum, carrageenan, gum arabic, alginates, pectin, xanthan gum, pullulan, tamarind seed gum, psyllium seed gum, crystalline cellulose, carboxymethyl cellulose, methyl cellulose, agar, gluco. Examples thereof include mannan, gelatin, starch, modified starch and the like, and one or more selected from these can be used. The content of the thickening stabilizer is
Although not particularly limited, it is preferably 0 to 10% by weight, more preferably 0 to 5% by weight in the oil and fat composition of the present invention. Moreover, in the oil / fat composition of this invention, if the said thickening stabilizer is not needed, a thickening stabilizer does not need to be used.

【0026】次に本発明の油脂組成物の製造方法を説明
する。
Next, a method for producing the oil / fat composition of the present invention will be described.

【0027】本発明では、上記の油脂組成物を可塑性を
有さないものとする場合は、原料を混合することにより
製造することができる。
In the present invention, when the above-mentioned oil and fat composition does not have plasticity, it can be produced by mixing the raw materials.

【0028】一方、本発明の油脂組成物を可塑性油脂組
成物とする場合は、上記に記載した油相に、必要により
水相を混合乳化する。そして、次に殺菌処理するのが望
ましい。殺菌方法はタンクでのバッチ式でも、プレート
型熱交換機や掻き取り式熱交換機を用いた連続式でも構
わない。次に、冷却可塑化する。冷却する機器として
は、密閉型連続式チューブ冷却機、例えばボテーター、
コンピネーター、パーフェクター等のマーガリン製造機
やプレート型熱交換機等が挙げられ、また、開放型のダ
イアクーラーとコンプレクターの組み合わせが挙げられ
る。また、上記可塑性油脂組成物を製造する際のいずれ
かの製造工程で、窒素、空気等を含気させても、させな
くても構わない。
On the other hand, when the oil / fat composition of the present invention is used as a plastic oil / fat composition, the oil phase described above is optionally mixed with an aqueous phase and emulsified. Then, sterilization is desirable next. The sterilization method may be a batch type in a tank or a continuous type using a plate heat exchanger or a scraping heat exchanger. Next, it is cooled and plasticized. As a device for cooling, a closed continuous tube cooler, for example, a voter,
Examples include a margarine manufacturing machine such as a compinator and a perfector, a plate heat exchanger, and the like, and a combination of an open type diacooler and a compactor. Further, in any of the manufacturing steps for manufacturing the above-mentioned plastic oil / fat composition, nitrogen, air or the like may or may not be aerated.

【0029】上記可塑性油脂組成物をロールイン用とし
て用いる場合は、その形状を、シート状、ブロック状、
円柱状等の形状としてもよい。各々の形状についての好
ましいサイズは、シート状:縦50〜1000mm、横
50〜1000mm、厚さ1〜50mm、ブロック状:
縦10〜1000mm、横10〜1000mm、厚さ1
0〜500mm、円柱状:直径1〜25mm、長さ5〜
100mmである。
When the above-mentioned plastic oil / fat composition is used for roll-in, its shape may be sheet, block,
It may have a cylindrical shape or the like. A preferred size for each shape is a sheet shape: length 50 to 1000 mm, width 50 to 1000 mm, thickness 1 to 50 mm, block shape:
Length 10-1000mm, width 10-1000mm, thickness 1
0-500 mm, cylindrical: diameter 1-25 mm, length 5-
It is 100 mm.

【0030】また、上記の油脂組成物を含有する食品と
しては、食パン、菓子パン、パイ、デニッシュ、シュ、
ドーナツ、ケーキ、スフレ、タルト、クラッカー、クッ
キー、ビスケット、ワッフル、スコーン、スナック菓
子、米菓、和菓子、冷菓子、飲料、デザート、カレー、
シチュー、コロッケ、グラタン、麺類、チョコレート、
ペースト状食品、チーズ類、米飯類、惣菜類、揚げ物
類、練り製品等が挙げられる。
Foods containing the above-mentioned oil and fat composition include bread, confectionery bread, pies, Danish, choux,
Donuts, cakes, souffles, tarts, crackers, cookies, biscuits, waffles, scones, snacks, rice crackers, Japanese sweets, cold sweets, beverages, desserts, curries,
Stew, croquette, gratin, noodles, chocolate,
Pasty foods, cheeses, cooked rice, prepared foods, fried foods, paste products and the like can be mentioned.

【0031】[0031]

【実施例】次に実施例により本発明を詳細に説明する
が、本発明はこれらの実施例によって限定されるもので
はない。
EXAMPLES The present invention will now be described in detail with reference to examples, but the present invention is not limited to these examples.

【0032】(実施例1)オレイン酸含量83重量%の
ハイオレイックキャノーラ油50重量%、オレイン酸含
量42重量%のパームオレイン40重量%及びステアリ
ン酸含量88重量%の大豆極度硬化油10重量%を配合
し、10kgの配合油を得た。上記の配合油10kg
を、反応温度70℃、触媒としてリパーゼQLC(名糖
産業(株)製)50gを用いて、15リットルの反応槽
でエステル交換反応を行った。反応終了後(反応時間4
8hr)、漂白(白土量対油3重量%、85℃、10m
mHgの減圧下、30分間)、脱臭(250℃、水蒸気
吹き込み量対油3重量%、1mmHgの減圧下、60分
間)を行い、エステル交換油脂を得た。このエステル交
換油脂にトコフェロール200ppmを添加し、オレイ
ン酸含量58重量%、ステアリン酸含量12重量%、融
点28℃の油脂組成物を得た。
(Example 1) 50% by weight of high oleic canola oil having an oleic acid content of 83% by weight, 40% by weight of palm olein having an oleic acid content of 42% by weight, and 10% by weight of soybean soybean hardened oil having a stearic acid content of 88% by weight. % Was blended to obtain 10 kg of blended oil. 10 kg of the above blended oil
Was subjected to transesterification reaction in a 15-liter reaction tank at a reaction temperature of 70 ° C. and 50 g of lipase QLC (manufactured by Meito Sangyo Co., Ltd.) as a catalyst. After completion of reaction (reaction time 4
8 hr), bleaching (white clay amount to oil 3% by weight, 85 ° C, 10 m
Under reduced pressure of mHg for 30 minutes) and deodorization (250 ° C., amount of steam blown to 3% by weight of oil, reduced pressure of 1 mmHg for 60 minutes) were performed to obtain a transesterified oil and fat. Tocopherol (200 ppm) was added to this transesterified oil and fat to obtain an oil and fat composition having an oleic acid content of 58% by weight, a stearic acid content of 12% by weight, and a melting point of 28 ° C.

【0033】(比較例1)オレイン酸含量73重量%の
ハイオレイックキャノーラ油にトコフェロール200p
pmを添加し、オレイン酸含量73重量%、ステアリン
酸含量2重量%、融点0℃以下の油脂組成物を得た。
Comparative Example 1 Tocopherol 200 p was added to high oleic canola oil having an oleic acid content of 73% by weight.
pm was added to obtain an oil and fat composition having an oleic acid content of 73% by weight, a stearic acid content of 2% by weight, and a melting point of 0 ° C. or less.

【0034】〔フライテスト1〕実施例1及び比較例1
において得られた油脂組成物をフライ用油脂組成物とし
て用い、市販品冷凍フレンチフライドポテトを揚げ、以
下のように評価した。実施例1及び比較例1において得
られた油脂組成物3.8kgをフライヤーに挿入し18
5℃に加熱後、市販品冷凍フレンチフライドポテトを揚
げた。フライドポテトは凍ったまま揚げ油中に200g
入れ、2.5分間揚げた後、速やかに油を切った。フラ
イは3時間で20回行い、油の加熱時間は揚げ時間も含
め1日7時間とした。フライテスト3日目にフライした
フライドポテトでパネルテストを行い、12名のパネル
により、フライドポテトの口溶け、風味(劣化臭)、さく
さく感及び油っぽさを下記評価基準に従って評価した。
これらの結果を〔表1〕に示した。
[Fly Test 1] Example 1 and Comparative Example 1
Using the oil / fat composition obtained in 1 above as a frying oil / fat composition, a commercial product frozen French fried potato was fried and evaluated as follows. 3.8 kg of the oil / fat composition obtained in Example 1 and Comparative Example 1 was inserted into a fryer.
After heating to 5 ° C., commercial frozen French fries were fried. 200 g of fried potatoes in fried oil while frozen
After putting it in and frying for 2.5 minutes, the oil was quickly drained. The frying was performed 20 times for 3 hours, and the heating time of the oil was 7 hours a day including the frying time. Fry test A panel test was performed on the fried potatoes fried on the 3rd day, and the melting of the fried potatoes, the flavor (deteriorated odor), the crispness, and the oiliness of the fried potatoes were evaluated by 12 panelists according to the following evaluation criteria.
The results are shown in [Table 1].

【0035】<評価基準> 口溶けの評価―◎:非常に良好、○:良好、△:やや不
良、×:不良 風味の評価―◎:非常に良好、○:良好、△:やや不
良、×:不良 さくさく感の評価―◎:非常にさくさく感がある、○:
さくさく感がある、△:あまりさくさく感がない、×:
さくさく感がない 油っぽさの評価―◎:非常にあっさりしている、○:あ
っさりしている、△:やや油っぽい、×:油っぽい
<Evaluation Criteria> Evaluation of melting in the mouth- ◎: Very good, ○: Good, △: Slightly bad, ×: Evaluation of bad flavor- ◎: Very good, ○: Good, Δ: Slightly bad, ×: Evaluation of poor crispness- ◎: Very crisp, ○:
Crunchy, △: Not very crunchy, ×:
Evaluation of oiliness without crispness- ◎: Very light, ○: Light, △: Slightly oily, ×: Oily

【0036】[0036]

【表1】 [Table 1]

【0037】〔フライテスト2〕実施例1及び比較例1
において得られた油脂組成物をフライ用油脂組成物とし
て用い、市販品冷凍ケーキドーナツを揚げ、以下のよう
に評価した。実施例1及び比較例1において得られた油
脂組成物4.5kgをフライヤーに挿入し180℃に加
熱後、市販品冷凍ケーキドーナツを揚げた。冷凍ケーキ
ドーナツ(フライ前約45g/個)は凍ったまま揚げ油
中に5個入れ、3分間揚げた後、速やかに油を切った。
フライは3時間で20回行い、油の加熱時間は揚げ時間
も含め1日7時間とした。フライテスト3日目にフライ
したドーナツでパネルテストを行い、12名のパネルに
より、ドーナツの口溶け、風味(劣化臭)、さくさく感
及び油っぽさを下記評価基準に従って評価した。これら
の結果を〔表2〕に示した。
[Fly Test 2] Example 1 and Comparative Example 1
Using the oil / fat composition obtained in 1. as an oil / fat composition for frying, a commercially available frozen cake donut was fried and evaluated as follows. 4.5 kg of the oil / fat composition obtained in Example 1 and Comparative Example 1 was inserted into a fryer and heated to 180 ° C., and then a commercial frozen cake donut was fried. Frozen cake donuts (about 45 g / frying before frying) were put in the frying oil as they were frozen, fried for 3 minutes, and then immediately drained.
The frying was performed 20 times for 3 hours, and the heating time of the oil was 7 hours a day including the frying time. Fry test A panel test was conducted on the fried donuts on the third day, and the dough melted in the mouth, taste (deteriorated odor), crispness and oiliness were evaluated by 12 panelists according to the following evaluation criteria. The results are shown in [Table 2].

【0038】<評価基準> 口溶けの評価―◎:非常に良好、○:良好、△:やや不
良、×:不良 風味の評価―◎:非常に良好、○:良好、△:やや不
良、×:不良 さくさく感の評価―◎:非常にさくさく感がある、○:
さくさく感がある、△:あまりさくさく感がない、×:
さくさく感がない 油っぽさの評価―◎:非常にあっさりしている、○:あ
っさりしている、△:やや油っぽい、×:油っぽい
<Evaluation Criteria> Evaluation of melting in the mouth-⊚: very good, ○: good, Δ: somewhat poor, ×: evaluation of poor flavor-⊚: very good, ○: good, Δ: slightly bad, ×: Evaluation of poor crispness- ◎: Very crisp, ○:
Crunchy, △: Not very crunchy, ×:
Evaluation of oiliness without crispness- ◎: Very light, ○: Light, △: Slightly oily, ×: Oily

【0039】[0039]

【表2】 [Table 2]

【0040】〔クラッカー製造テスト〕実施例1及び比
較例1において得られた油脂組成物をスプレー用油脂組
成物として用い、次のような配合及び製法にて得られた
クラッカーにスプレーし、評価を行った。
[Cracker Production Test] The oil / fat composition obtained in Example 1 and Comparative Example 1 was used as an oil / fat composition for spraying, and the cracker obtained by the following formulation and production method was sprayed and evaluated. went.

【0041】 <配合> 中種 小麦粉(中力粉) 70重量部 イースト 0.25重量部 水 30重量部 本捏 小麦粉(強力粉) 30重量部 ショートニング 10重量部 麦芽水飴 1.5重量部 食塩 1.5重量部 重曹 0.65重量部[0041] <Compound> Medium seed Flour (medium strength flour) 70 parts by weight 0.25 part by weight of yeast 30 parts by weight of water Main kneading Wheat flour (strong flour) 30 parts by weight Shortening 10 parts by weight Malt syrup 1.5 parts by weight 1.5 parts by weight of salt 0.65 parts by weight of baking soda

【0042】<製法> (1)上記中種配合を縦型ミキサーで低速2分ミキシン
グし、捏ね上げ温度を23℃とする。 (2)上記(1)で得られた中種生地を27℃にて18
時間発酵させる。 (3)発酵した中種生地に、本捏配合を加え、縦型ミキ
サーにて低速2分、中速2分ミキシングする。 (4)上記(3)で得られた生地を27℃にて4時間発
酵させる。 (5)上記(4)で得られた生地を、3つ折り2回行
い、生地厚を2mmまで圧延する。 (6)型抜きし、260℃で4分焼成する。 (7)焼成後、ただちにスプレー用油脂組成物をスプレ
ーする。
<Manufacturing Method> (1) The above intermediate compound is mixed at a low speed for 2 minutes with a vertical mixer, and the kneading temperature is set to 23 ° C. (2) The medium seed dough obtained in (1) above was heated at 27 ° C for 18
Ferment for hours. (3) Add the main kneading mixture to the fermented medium-sized dough, and mix with a vertical mixer for 2 minutes at low speed and 2 minutes at medium speed. (4) Ferment the dough obtained in (3) above at 27 ° C. for 4 hours. (5) The dough obtained in (4) above is folded in three twice and rolled to a dough thickness of 2 mm. (6) Die cutting and baking at 260 ° C. for 4 minutes. (7) Immediately after firing, the spray fat composition is sprayed.

【0043】<クラッカーの評価法>12名のパネルに
より、クラッカーの口溶け、風味(劣化臭)、ぱりぱり感
及び油っぽさを下記評価基準に従って評価した。さら
に、焼成したクラッカーに食塩と粉チーズを振り掛けた
後、スプレー用油脂組成物をスプレーし、30℃にて保
管し、24時間後と48時間後の風味(劣化臭)及び表
面のべたつきを下記評価基準に従って評価した。これら
の結果を〔表3〕に示した。
<Cracker Evaluation Method> A panel of 12 people evaluated the meltability of the cracker in the mouth, flavor (deteriorated odor), crispness and oiliness according to the following evaluation criteria. Furthermore, after sprinkling salt and powdered cheese on a baked cracker, spraying the oil and fat composition for spraying and storing at 30 ° C., the flavor (deteriorated odor) and surface stickiness after 24 hours and 48 hours are shown below. It evaluated according to the evaluation criteria. The results are shown in [Table 3].

【0044】<評価基準> 口溶けの評価―◎:非常に良好、○:良好、△:やや不
良、×:不良 風味の評価―◎:非常に良好、○:良好、△:やや不
良、×:不良 ぱりぱり感の評価―◎:非常にぱりぱり感がある、○:
ぱりぱり感がある、△:あまりぱりぱり感がない、×:
ぱりぱり感がない 油っぽさの評価―◎:非常にあっさりしている、○:あ
っさりしている、△:やや油っぽい、×:油っぽい べたつきの評価―◎:非常に良好、○:良好、△:やや
不良、×:不良
<Evaluation Criteria> Evaluation of melting in the mouth- ◎: Very good, ○: Good, Δ: Slightly bad, ×: Evaluation of poor flavor- ◎: Very good, ○: Good, Δ: Slightly bad, ×: Evaluation of defective crispness- ◎: Very crisp, ○:
Crisp, △: Not very crisp, ×:
No greasy evaluation of oiliness- ◎: Very light, ○: Light, △: Slightly oily, ×: Evaluation of oily stickiness- ◎: Very good, ○ : Good, △: Slightly bad, ×: Bad

【0045】[0045]

【表3】 [Table 3]

【0046】(実施例2)オレイン酸含量55重量%の
サル脂分別軟部油70重量%とステアリン酸含量88重
量%の大豆極度硬化油30重量%を配合し、10kgの
配合油を得た。実施例1と同様の方法で上記配合油のエ
ステル交換、漂白及び脱臭を行い、エステル交換油脂を
得た。このエステル交換油脂50重量%、オレイン酸含
量74重量%のハイオレイックキャノーラ50重量%を
配合し、トコフェロール200ppmを添加し、オレイ
ン酸含量56重量%、ステアリン酸含量23重量%、融
点44℃の油脂組成物を得た。
(Example 2) 70% by weight of a salfaction-fractionated soft part oil having an oleic acid content of 55% by weight and 30% by weight of an extremely hardened soybean oil having a stearic acid content of 88% by weight were blended to obtain 10 kg of a blended oil. The compounded oil was transesterified, bleached and deodorized in the same manner as in Example 1 to obtain a transesterified oil and fat. 50% by weight of this transesterified oil and fat and 50% by weight of high oleic canola having an oleic acid content of 74% by weight were added, and 200 ppm of tocopherol was added, and oleic acid content of 56% by weight, stearic acid content of 23% by weight, and melting point of 44 ° C. An oil and fat composition was obtained.

【0047】(実施例3)オレイン酸含量41重量%の
サル脂90重量%とステアリン酸含量88重量%の大豆
極度硬化油10重量%を配合し、10kgの配合油を得
た。実施例1と同様の方法で上記配合油のエステル交
換、漂白及び脱臭を行い、エステル交換油脂を得た。こ
のエステル交換油脂30重量%、オレイン酸含量74重
量%のハイオレイックキャノーラ70重量%を配合し、
トコフェロール200ppmを添加し、オレイン酸含量
62重量%、ステアリン酸含量15重量%、融点39℃
の油脂組成物を得た。
Example 3 90% by weight of salfat having an oleic acid content of 41% by weight and 10% by weight of soybean hardened oil having a stearic acid content of 88% by weight were blended to obtain 10 kg of a blended oil. The compounded oil was transesterified, bleached and deodorized in the same manner as in Example 1 to obtain a transesterified oil and fat. 30% by weight of this transesterified oil and fat and 70% by weight of high oleic canola having an oleic acid content of 74% by weight,
Tocopherol 200ppm was added, oleic acid content 62% by weight, stearic acid content 15% by weight, melting point 39 ° C.
To obtain a fat composition.

【0048】(比較例2)オレイン酸含量83重量%の
ハイオレイックキャノーラ油にトコフェロール200p
pmを添加し、オレイン酸含量83重量%、ステアリン
酸含量2重量%、融点0℃以下の油脂組成物を得た。
Comparative Example 2 Tocopherol 200 p was added to high oleic canola oil having an oleic acid content of 83% by weight.
pm was added to obtain an oil and fat composition having an oleic acid content of 83% by weight, a stearic acid content of 2% by weight, and a melting point of 0 ° C or lower.

【0049】〔マーガリン製造テスト〕実施例2、3及
び比較例2において得られた油脂組成物をマーガリン用
油脂組成物として用い、次のような配合でマーガリンを
製造した。
[Margarine Production Test] The oil / fat compositions obtained in Examples 2 and 3 and Comparative Example 2 were used as an oil / fat composition for margarine to produce margarine with the following formulation.

【0050】 <配合> 油脂組成物 100重量部 グリセリン脂肪酸エステル 0.1重量部 レシチン 0.1重量部 水 20重量部[0050] <Compound> Fat composition 100 parts by weight Glycerin fatty acid ester 0.1 part by weight Lecithin 0.1 part by weight 20 parts by weight of water

【0051】得られたマーガリンの可塑性及び風味を下
記評価基準に従って評価した。これらの結果を〔表4〕
に示した。
The plasticity and flavor of the obtained margarine were evaluated according to the following evaluation criteria. These results are shown in [Table 4].
It was shown to.

【0052】<評価基準> 可塑性の評価―◎:非常に良好、○:良好、△:やや不
良、×:不良 風味の評価―◎:非常に良好、○:良好、△:やや不
良、×:不良
<Evaluation Criteria> Evaluation of plasticity-⊚: very good, ◯: good, Δ: somewhat poor, ×: evaluation of poor flavor- ◎: very good, ◯: good, Δ: slightly poor, ×: Bad

【0053】[0053]

【表4】 [Table 4]

【0054】〔ショートニング製造テスト〕実施例2、
3及び比較例2において得られた油脂組成物をショート
ニング用油脂組成物として用い、次のような配合でショ
ートニングを製造した。
[Shortening Manufacturing Test] Example 2,
Using the oil / fat composition obtained in Example 3 and Comparative Example 2 as an oil / fat composition for shortening, a shortening was produced with the following formulation.

【0055】 <配合> 油脂組成物 100重量部 グリセリン脂肪酸エステル 0.1重量部 レシチン 0.1重量部[0055] <Compound> Fat composition 100 parts by weight Glycerin fatty acid ester 0.1 part by weight Lecithin 0.1 part by weight

【0056】得られたショートニングの可塑性及び風味
を下記評価基準に従って評価した。これらの結果を〔表
5〕に示した。
The plasticity and flavor of the obtained shortening were evaluated according to the following evaluation criteria. The results are shown in [Table 5].

【0057】<評価基準> 可塑性の評価―◎:非常に良好、○:良好、△:やや不
良、×:不良 風味の評価―◎:非常に良好、○:良好、△:やや不
良、×:不良
<Evaluation Criteria> Evaluation of plasticity-⊚: Very good, ◯: Good, Δ: Slightly bad, ×: Evaluation of poor flavor- ◎: Very good, ◯: Good, Δ: Slightly bad, ×: Bad

【0058】[0058]

【表5】 [Table 5]

【0059】[0059]

【発明の効果】本発明の油脂組成物によれば、オレイン
酸含量が高く、酸化安定性及び熱安定性が良好で、油脂
組成物や該油脂組成物を用いた食品の口溶け、風味、食
感及び物性を良好なものとし、さらに油っぽくないもの
とすることができる。
EFFECTS OF THE INVENTION According to the oil and fat composition of the present invention, the oleic acid content is high, the oxidative stability and the thermal stability are good, and the oil and fat composition and the foods using the oil and fat composition melt in the mouth, flavor, and food. It can have good feeling and physical properties and can be made not to be oily.

───────────────────────────────────────────────────── フロントページの続き (72)発明者 丸銭 詔司 東京都荒川区東尾久7丁目2番35号 旭電 化工業株式会社内 Fターム(参考) 4B026 DC01 DC04 DC06 DG01 DG11 DH01 DH02 DH03 DH05 DL02 DP01 DX02 4B032 DB01 DB05 DB23 DB24 DK18 DL06 4H059 BA33 BB02 BB04 BB06 BC03 BC13 CA34 CA35    ─────────────────────────────────────────────────── ─── Continued front page    (72) Inventor Maruzen Shoji             7-35 Higashiokyu, Arakawa-ku, Tokyo Asahiden             Chemical Industry Co., Ltd. F term (reference) 4B026 DC01 DC04 DC06 DG01 DG11                       DH01 DH02 DH03 DH05 DL02                       DP01 DX02                 4B032 DB01 DB05 DB23 DB24 DK18                       DL06                 4H059 BA33 BB02 BB04 BB06 BC03                       BC13 CA34 CA35

Claims (3)

【特許請求の範囲】[Claims] 【請求項1】 オレイン酸を30重量%以上含有する油
脂(A)99〜40重量%と、該油脂(A)と異なる油
脂を硬化したステアリン酸を60重量%以上含有する極
度硬化油(B)1〜60重量%とをエステル交換反応し
てなるエステル交換油脂を含有し、オレイン酸を50重
量%以上含有する油脂組成物。
1. An extremely hardened oil (B) containing 99 to 40% by weight of an oil (A) containing 30% by weight or more of oleic acid, and 60% by weight or more of stearic acid obtained by hardening an oil or fat different from the oil (A). ) An oil and fat composition containing a transesterification oil and fat obtained by transesterification with 1 to 60% by weight, and containing 50% by weight or more of oleic acid.
【請求項2】 ステアリン酸を10重量%以上含有する
請求項1記載の油脂組成物。
2. The oil and fat composition according to claim 1, which contains stearic acid in an amount of 10% by weight or more.
【請求項3】 請求項1又は2に記載の油脂組成物を用
いた食品。
3. A food using the oil or fat composition according to claim 1.
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JP2006160906A (en) * 2004-12-08 2006-06-22 Asahi Denka Kogyo Kk Plastic composition of fat and oil
JP2006197884A (en) * 2005-01-24 2006-08-03 House Foods Corp Instant cooked food
JP2006288231A (en) * 2005-04-07 2006-10-26 Kaneka Corp Oil-and-fat composition for roux having small amount of low trans acid
JP2007267603A (en) * 2006-03-30 2007-10-18 Showa Sangyo Co Ltd Oil and fat for fry
JP2009095246A (en) * 2007-10-12 2009-05-07 Adeka Corp Foamable emulsifier composition for cake
CN105794997A (en) * 2014-12-29 2016-07-27 丰益(上海)生物技术研发中心有限公司 Oil composition replacing beef tallow and preparation method thereof
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Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006160906A (en) * 2004-12-08 2006-06-22 Asahi Denka Kogyo Kk Plastic composition of fat and oil
JP2006197884A (en) * 2005-01-24 2006-08-03 House Foods Corp Instant cooked food
JP4536530B2 (en) * 2005-01-24 2010-09-01 ハウス食品株式会社 Instant cooked food
JP2006288231A (en) * 2005-04-07 2006-10-26 Kaneka Corp Oil-and-fat composition for roux having small amount of low trans acid
JP2007267603A (en) * 2006-03-30 2007-10-18 Showa Sangyo Co Ltd Oil and fat for fry
JP4646320B2 (en) * 2006-03-30 2011-03-09 昭和産業株式会社 Oil for frying
JP2009095246A (en) * 2007-10-12 2009-05-07 Adeka Corp Foamable emulsifier composition for cake
CN105794997A (en) * 2014-12-29 2016-07-27 丰益(上海)生物技术研发中心有限公司 Oil composition replacing beef tallow and preparation method thereof
WO2022138398A1 (en) * 2020-12-22 2022-06-30 日清オイリオグループ株式会社 Fat or oil composition
JPWO2022138398A1 (en) * 2020-12-22 2022-06-30
JP7280451B2 (en) 2020-12-22 2023-05-23 日清オイリオグループ株式会社 fat composition

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