JP2019004875A - Plastic oil-and-fat composition - Google Patents
Plastic oil-and-fat composition Download PDFInfo
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- JP2019004875A JP2019004875A JP2018116539A JP2018116539A JP2019004875A JP 2019004875 A JP2019004875 A JP 2019004875A JP 2018116539 A JP2018116539 A JP 2018116539A JP 2018116539 A JP2018116539 A JP 2018116539A JP 2019004875 A JP2019004875 A JP 2019004875A
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- oil
- mass
- fat
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- oils
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Abstract
Description
本発明は、可塑性油脂組成物に関する。 The present invention relates to a plastic fat composition.
焼き菓子やパンなどの焼成品に用いられるマーガリンやショートニングなどの練り込み用の可塑性油脂組成物は、通常、0℃超10℃以下の冷蔵温度で流通もしくは保管される。練り込み用の可塑性油脂組成物は一般的に冷蔵温度では硬く、そのままでは焼成品用生地を製造する際に練り込みにくく使用しにくいため、適切な硬さに調整するために例えば20℃程度に調温して使用する。しかし、調温には時間がかかる上、調温設備がない場合には気温が高い夏場と気温が低い冬場とでは調温条件を変える必要があり、適度に調温することは難しい。そこで調温をおこなう必要がなく、冷蔵温度でも使用できる練り込み用の可塑性油脂組成物が求められている。 Plastic oil compositions for kneading such as margarine and shortening used in baked goods such as baked goods and bread are usually distributed or stored at a refrigeration temperature of more than 0 ° C. and 10 ° C. or less. The plastic fat composition for kneading is generally hard at the refrigeration temperature, and as it is, it is difficult to knead and difficult to use when producing a dough for a baked product, so that it is adjusted to an appropriate hardness, for example, about 20 ° C. Adjust the temperature before use. However, it takes time to control the temperature, and if there is no temperature control equipment, it is necessary to change the temperature control conditions in summer when the temperature is high and in winter when the temperature is low, and it is difficult to adjust the temperature appropriately. Therefore, there is a need for a kneading plastic fat composition that does not require temperature adjustment and can be used even at refrigerated temperatures.
従来の練り込み用の可塑性油脂組成物としては、例えばエステル交換油を含む油脂組成物が提案されている(特許文献1、特許文献2)。しかし、いずれの特許文献にも、冷蔵温度の可塑性油脂組成物を焼成品用生地へ練り込めることについては開示されていない。 As a conventional plastic oil composition for kneading, for example, an oil composition containing transesterified oil has been proposed (Patent Document 1, Patent Document 2). However, none of the patent documents disclose the kneading of the refrigerated plastic oil composition into a dough for a baked product.
マーガリンやショートニングの代わりに液状油を焼成品用生地原料として用いることもあるが、パウンドケーキなどのように油脂を多く配合する焼成品では、油染みが発生しやすいため、包装材に油が付着し、外観を損なうことや持った時に油で手を汚してしまうことが課題となっている。 Liquid oil may be used as a raw material for baking products in place of margarine and shortening, but baking products that contain a large amount of oil and fat, such as pound cake, are prone to oil stains. The problem is that the appearance is damaged and the hands are soiled with oil when held.
本発明は、0℃超10℃以下の冷蔵温度の可塑性油脂組成物を調温することなく使用し、焼成品用生地を作製する際に練り込みやすく、また焼成品からの油染みを低減しうる可塑性油脂組成物を提供することを目的とする。 The present invention uses a plastic oil and fat composition having a refrigeration temperature of more than 0 ° C. and not more than 10 ° C. without adjusting the temperature, and is easy to knead when preparing a dough for a baked product, and can reduce oil stain from the baked product. It aims at providing a plastic fat composition.
本発明者らは、上記課題を解決するために鋭意検討した結果、2種類のエステル交換油を含有し、上昇融点が10℃以下の油脂を所定量含む可塑性油脂組成物を用いれば、0℃超10℃以下の冷蔵温度で調温することなく焼成品用生地を作製する際に練り込みやすく、また焼成品からの油染みを低減しうることを見出し、本発明を完成した。 As a result of intensive studies to solve the above-mentioned problems, the present inventors have obtained a 0 ° C. when a plastic oil / fat composition containing two kinds of transesterified oils and containing a predetermined amount of oil / fat having a rising melting point of 10 ° C. or less is used. The inventors have found that it is easy to knead when preparing a dough for a baked product without adjusting the temperature at a refrigeration temperature of super 10 ° C. or less, and that oil stain from the baked product can be reduced, and the present invention has been completed.
すなわち、本発明は、以下の油脂A、油脂B及び油脂Cを含有する可塑性油脂組成物であって、前記可塑性油脂組成物の油脂中に前記油脂Cを62質量%以上85質量%以下含むことを特徴とする前記可塑性油脂組成物である。
油脂A:トリアシルグリセロールを構成する脂肪酸の総炭素数が38以上44以下のトリアシルグリセロール含有量が30質量%以上60質量%以下であり、かつ構成脂肪酸中のパルミチン酸含有量が10質量%以上35質量%以下であるエステル交換油。
油脂B:P2O含有量が18質量%以上28質量%以下であり、かつP2LとPL2の合計含有量が3質量%以上18質量%以下であるエステル交換油(ただし、P2Oは1分子中にパルミチン酸が2個、オレイン酸が1個エステル結合しているトリアシルグリセロール、P2Lは1分子中にパルミチン酸が2個、リノール酸が1個エステル結合しているトリアシルグリセロール、PL2は1分子中にパルミチン酸が1個、リノール酸が2個エステル結合しているトリアシルグリセロールを意味する)。
油脂C:上昇融点が10℃以下の食用油脂。
That is, this invention is a plastic fat composition containing the following fats and oils A, fats and oils B, and fats and oils C, and contains 62 to 85 mass% of the fats and oils in the fats and oils of the said plastic fat and oil composition. It is the said plastic fat composition characterized by these.
Fat and oil A: The triacylglycerol content in which the total carbon number of the fatty acid constituting the triacylglycerol is 38 to 44 is 30% by mass to 60% by mass, and the palmitic acid content in the constituent fatty acid is 10% by mass The transesterification oil which is 35 mass% or less.
Fat and oil B: Transesterified oil having a P2O content of 18% by mass to 28% by mass and a total content of P2L and PL2 of 3% by mass to 18% by mass (however, P2O is palmitic in one molecule) Triacylglycerol with two acids and one oleic acid ester-linked, P2L is a triacylglycerol with two palmitic acids and one linoleic acid in one molecule, PL2 is in one molecule Is a triacylglycerol in which one palmitic acid and two linoleic acids are ester-linked).
Fat and oil C: Edible fat and oil whose rising melting point is 10 ° C. or lower.
前記油脂Aを構成する脂肪酸中のステアリン酸含有量が25質量%以上50質量%以下であることが好ましい。 It is preferable that the stearic acid content in the fatty acid constituting the fat A is 25% by mass or more and 50% by mass or less.
前記油脂Aのヨウ素価が0以上2以下であることが好ましい。 The iodine value of the fat / oil A is preferably 0 or more and 2 or less.
前記油脂BのPO2含有量が5質量%以上20質量%以下であることが好ましい。(ただし、PO2は1分子中にパルミチン酸が1個、オレイン酸が2個エステル結合しているトリアシルグリセロールを意味する) It is preferable that PO2 content of the said fats and oils B is 5 to 20 mass%. (However, PO2 means triacylglycerol in which one palmitic acid and two oleic acids are ester-bonded in one molecule)
前記油脂Bのヨウ素価が35以上60以下であることが好ましい。 It is preferable that the iodine value of the fats and oils B is 35 or more and 60 or less.
前記可塑性油脂組成物の油脂中の前記油脂Aと前記油脂Bとの合計量が15質量%以上38質量%以下であることが好ましい。 The total amount of the fat A and the fat B in the fat of the plastic fat composition is preferably 15% by mass or more and 38% by mass or less.
前記油脂Bに対する前記油脂Aの質量比率が0.1以上10以下であることが好ましい。 The mass ratio of the fat A to the fat B is preferably 0.1 or more and 10 or less.
前記可塑性油脂組成物は油中水型であることが好ましい。 The plastic fat composition is preferably a water-in-oil type.
前記可塑性油脂組成物は練り込み用であることが好ましい。 The plastic fat composition is preferably used for kneading.
また、本発明は、前記可塑性油脂組成物を含有する焼成品用生地である。 Moreover, this invention is the cloth for baked goods containing the said plastic fat composition.
また、本発明は、前記生地を焼成して得られる焼成品である。 Moreover, this invention is a baked product obtained by baking the said dough.
また、本発明は、前記可塑性油脂組成物を0℃超10℃以下で用いることを特徴とする、焼成品用生地の製造方法である。 Moreover, this invention is a manufacturing method of the dough for baked goods characterized by using the said plastic fat composition at over 0 degreeC and 10 degrees C or less.
また、本発明は、前記可塑性油脂組成物を用いて焼成品用生地を作製することを特徴とする、焼成品の油染みを低減させる方法である。 Moreover, this invention is a method of reducing the oil stain of a baked product characterized by producing the cloth for baked products using the said plastic fat composition.
本発明の可塑性油脂組成物を用いれば、0℃超10℃以下の冷蔵温度で調温することなく焼成品用生地を作製する際、練り込みやすく、また焼成品からの油染みが低減させることができる。 When the plastic fat composition of the present invention is used, it is easy to knead when preparing a dough for a baked product without adjusting the temperature at a refrigeration temperature of more than 0 ° C. and 10 ° C. or less, and the oil stain from the baked product can be reduced. it can.
本発明の可塑性油脂組成物は、以下の油脂A、油脂B及び油脂Cを含有し、前記可塑性油脂組成物の油脂中に前記油脂Cを62質量%以上85質量%以下含む。油脂Aは、トリアシルグリセロールを構成する脂肪酸の総炭素数(以後、CNとも記載)が38以上44以下のトリアシルグリセロール含有量が30質量%以上60質量%以下であり、かつ構成脂肪酸中のパルミチン酸含有量が10質量%以上35質量%以下であるエステル交換油である。油脂Bは、P2O含有量が18質量%以上28質量%以下であり、かつP2LとPL2の合計含有量が3質量%以上18質量%以下であるエステル交換油である。油脂Cは、上昇融点が10℃以下の食用油脂である。ここで、P2Oは1分子中にパルミチン酸が2個、オレイン酸が1個エステル結合しているトリアシルグリセロール、P2Lは1分子中にパルミチン酸が2個、リノール酸が1個エステル結合しているトリアシルグリセロール、PL2は1分子中にパルミチン酸が1個、リノール酸が2個エステル結合しているトリアシルグリセロールをそれぞれ意味する。CNが38以上44以下のトリアシルグリセロール含有量は基準油脂分析試験法の2.4.6.1−1996に従って測定することができる。オレイン酸、リノール酸、パルミチン酸などの構成脂肪酸含有量は基準油脂分析試験法の2.4.2.3−2013に従って測定することができる。P2O、P2L、PL2、PO2などのトリグリアシルグリセロール含有量はJAOCS,Vol70,No.11,1111−1114(1993)に記載の方法に従って測定することができる。上昇融点は基準油脂分析試験法の2.2.4.2−1996に従って測定することができる。 The plastic fat composition of the present invention contains the following fats and oils A, fats and oils B and fats and oils C, and the fats and oils of the plastic fat and oil composition contain 62% by mass or more and 85% by mass or less of the fats and oils. The fat / oil A has a triacylglycerol content of 30 to 44% by mass of the total carbon number of the fatty acid constituting the triacylglycerol (hereinafter also referred to as CN) of 38 to 44%. The transesterified oil has a palmitic acid content of 10% by mass to 35% by mass. The fat B is a transesterified oil having a P2O content of 18% by mass to 28% by mass and a total content of P2L and PL2 of 3% by mass to 18% by mass. Oil C is an edible oil having an ascending melting point of 10 ° C or lower. Here, P2O is a triacylglycerol in which two palmitic acids and one oleic acid are ester-bonded in one molecule, and P2L is an ester-linked two palmitic acids and one linoleic acid in one molecule. The triacylglycerol PL2 means triacylglycerol in which one palmitic acid and two linoleic acids are ester-bonded in one molecule. The content of triacylglycerol having a CN of 38 or more and 44 or less can be measured according to 2.4.6.1-1996 of the standard fat and oil analysis test method. The content of constituent fatty acids such as oleic acid, linoleic acid and palmitic acid can be measured according to 2.4.2.3-2013 of the standard oil analysis method. The content of triglycerylglycerol such as P2O, P2L, PL2, and PO2 is JAOCS, Vol 70, No. 11, 1111-1114 (1993). The rising melting point can be measured according to 2.2.4.2-1996 of the standard fat analysis method.
本発明におけるエステル交換油とは、従来公知の方法でエステル交換した油脂を指す。エステル交換に用いる触媒としてはナトリウムメトキシド等の化学触媒やリパーゼ等の酵素触媒等が挙げられる。エステル交換の方法は、ランダムエステル交換でも、グリセロールの1、3位に結合した脂肪酸に特異的なエステル交換でもよいが、ランダムエステル交換が好ましい。 The transesterified oil in the present invention refers to an oil and fat that has been transesterified by a conventionally known method. Examples of the catalyst used for transesterification include chemical catalysts such as sodium methoxide and enzyme catalysts such as lipase. The transesterification method may be random transesterification or transesterification specific to the fatty acid bonded to the 1,3-position of glycerol, but random transesterification is preferred.
本発明の可塑性油脂組成物の油脂中の前記油脂Aと前記油脂Bとの合計量は、焼成品の油染みを低減させる観点から、15質量%以上が好ましく、19質量%以上がより好ましく、22質量%以上がさらに好ましい。また、前記油脂Aと前記油脂Bとの合計量は、焼成品用生地を作製する際に練り込みやすくさせる観点から、38質量%以下であることが好ましく、36質量%以下がより好ましく、33質量%以下がさらに好ましい。 The total amount of the fats and oils A and B in the fats and oils of the plastic fat and oil composition of the present invention is preferably 15% by mass or more, more preferably 19% by mass or more, from the viewpoint of reducing oil stain of the fired product. The mass% or more is more preferable. In addition, the total amount of the fats and oils A and the fats and oils B is preferably 38% by mass or less, more preferably 36% by mass or less, from the viewpoint of easy kneading when preparing a baked article dough. A mass% or less is more preferable.
前記油脂Bに対する前記油脂Aの質量比率は、焼成品の油染みを低減させる観点から、0.1以上が好ましく、0.4以上がより好ましく、0.8以上がさらに好ましい。また、前記油脂Bに対する前記油脂Aの質量比率は、焼成品用生地を作製する際に練り込みやすくさせる観点から、10以下であることが好ましく、8以下であることがより好ましく、6以下であることがさらに好ましい。 From the viewpoint of reducing the oil stain of the fired product, the mass ratio of the fat A to the fat B is preferably 0.1 or more, more preferably 0.4 or more, and even more preferably 0.8 or more. In addition, the mass ratio of the fat A to the fat B is preferably 10 or less, more preferably 8 or less, and more preferably 6 or less from the viewpoint of easy kneading when preparing a baked article dough. More preferably it is.
本発明で用いられる前記油脂A中のCNが38以上44以下のトリアシルグリセロール含有量は、30質量%以上であり、32質量%以上であることが好ましく、34質量%以上であることがより好ましい。また、前記油脂A中のCNが38以上44以下のトリアシルグリセロール含有量は、60質量%以下であり、58質量%以下が好ましく、56質量%以下がより好ましい。所定の範囲にあると、焼成品の油染みを低減させることができる。 The triacylglycerol content of CN in the oil and fat A used in the present invention is from 38 to 44, preferably 30% by mass, preferably 32% by mass or more, and more preferably 34% by mass or more. preferable. Further, the content of triacylglycerol having a CN of 38 to 44 in the oil and fat A is 60% by mass or less, preferably 58% by mass or less, and more preferably 56% by mass or less. If it is within the predetermined range, the oil stain of the fired product can be reduced.
本発明で用いられる前記油脂Aの構成脂肪酸中のパルミチン酸含有量は10質量%以上であり、13質量%以上であることが好ましく、16質量%以上であることがより好ましい。また、前記油脂Aの構成脂肪酸中のパルミチン酸含有量は35質量%以下であり、33質量%以下であることが好ましく、31質量%以下であることがより好ましい。 The palmitic acid content in the constituent fatty acid of the fat A used in the present invention is 10% by mass or more, preferably 13% by mass or more, and more preferably 16% by mass or more. In addition, the palmitic acid content in the constituent fatty acid of the fat A is 35% by mass or less, preferably 33% by mass or less, and more preferably 31% by mass or less.
本発明で用いられる前記油脂Aの構成脂肪酸中のステアリン酸含有量は25質量%以上であることが好ましく、27質量%以上であることがより好ましく、30質量%以上であることがさらに好ましい。また、前記油脂Aの構成脂肪酸中のステアリン酸含有量は50質量%以下であることが好ましく、45質量%以下であることがより好ましく、40質量%以下であることがさらに好ましい。 The stearic acid content in the constituent fatty acid of the fat A used in the present invention is preferably 25% by mass or more, more preferably 27% by mass or more, and further preferably 30% by mass or more. Further, the stearic acid content in the constituent fatty acid of the fat A is preferably 50% by mass or less, more preferably 45% by mass or less, and further preferably 40% by mass or less.
前記油脂Aのヨウ素価が0以上2以下であることが好ましい。ヨウ素価は基準油脂分析試験法の2.3.4.1−1996に従って測定することができる。 The iodine value of the fat / oil A is preferably 0 or more and 2 or less. The iodine value can be measured according to 2.3.4.1-1996 of the standard oil analysis method.
前記油脂Aとしては、例えばヤシ油、パーム核油およびこれらを分別、水素添加等の加工をしたラウリン系油脂と、パーム油およびこれを分別、水素添加等の加工をしたパーム系油脂とを含む配合油脂のエステル交換油が挙げられ、前記ラウリン系油脂と前記パーム系油脂とのエステル交換油が好ましく挙げられる。前記油脂Aに用いられるラウリン系油脂は、パーム核油およびパーム核油の水素添加油からなる群から選択される1種または2種以上が好ましく、パーム核油の極度硬化油がより好ましい。前記油脂Aに用いられるパーム系油脂は、パームステアリン、パーム油の水素添加油およびパーム分別油の水素添加油からなる群から選択される1種または2種以上が好ましく、パームステアリン、パーム油の極度硬化油およびパーム分別油の極度硬化油からなる群から選択される1種または2種以上がより好ましく、パーム油の極度硬化油およびパーム分別油の極度硬化油からなる群から選択される1種または2種以上がさらに好ましく、パーム油の極度硬化油がさらにより好ましい。前記油脂Aが水素添加油脂を含むエステル交換油である場合、水素添加工程、エステル交換油の原料油脂を配合する配合工程およびエステル交換工程の順序は問わない。配合工程、エステル交換工程、水素添加工程の順でもよいし、配合工程、水素添加工程、エステル交換工程の順でもよいし、水素添加工程、配合工程、エステル交換工程の順でもよい。 Examples of the fat A include coconut oil, palm kernel oil, and lauric fats and oils that have been subjected to separation, hydrogenation, and the like, and palm oil and palm oils that have been subjected to separation, hydrogenation, and the like. The transesterified oil of compounded fats and oils is mentioned, The transesterified oil of the said lauric oil and fat and the said palm oil and fat is mentioned preferably. The lauric fat used in the fat A is preferably one or more selected from the group consisting of palm kernel oil and hydrogenated oil of palm kernel oil, more preferably extremely hardened oil of palm kernel oil. The palm fat used in the fat A is preferably one or more selected from the group consisting of palm stearin, hydrogenated oil of palm oil, and hydrogenated oil of palm fractionated oil. One or more selected from the group consisting of extremely hardened oil and extremely hardened oil of palm fractionated oil is more preferred, and 1 selected from the group consisting of extremely hardened oil of palm oil and extremely hardened oil of palm fractionated oil A seed or two or more are more preferred, and a palm oil extremely hardened oil is even more preferred. When the fats and oils A are transesterified oils containing hydrogenated fats and oils, the order of the hydrogenation step, the blending step of blending the raw fats and oils of the transesterified oils, and the transesterification step is not limited. The order of the blending process, the transesterification process, and the hydrogenation process may be the order of the blending process, the hydrogenation process, and the transesterification process, or the order of the hydrogenation process, the blending process, and the transesterification process.
本発明の可塑性油脂組成物の油脂中の前記油脂Aの含有量は、焼成品の油染みを低減させる観点から、9質量%以上が好ましく、11質量%以上がより好ましい。また、焼成品用生地に練り込みやすくさせる観点から、29質量%以下が好ましく、26質量%以下がより好ましい。 9 mass% or more is preferable from a viewpoint of reducing the oil stain of a baked product, and, as for content of the said fats and oils A in the fats and oils of the plastic fat composition of this invention, 11 mass% or more is more preferable. Moreover, from a viewpoint of making it easy to knead | mix into the baked goods dough, 29 mass% or less is preferable and 26 mass% or less is more preferable.
本発明で用いられる前記油脂B中のP2O含有量は18質量%以上であり、20質量%以上であることが好ましい。また、前記油脂B中のP2O含有量は28質量%以下であり、26質量%以下であることが好ましい。 P2O content in the said fats and oils B used by this invention is 18 mass% or more, and it is preferable that it is 20 mass% or more. Moreover, the P2O content in the fats and oils B is 28% by mass or less, and preferably 26% by mass or less.
本発明で用いられる前記油脂B中のP2LとPL2の合計含有量は3質量%以上であり、5質量%以上であることが好ましい。また、前記油脂B中のP2LとPL2の合計含有量は18質量%以下であり、16質量%以下であることが好ましい。 The total content of P2L and PL2 in the fat B used in the present invention is 3% by mass or more, and preferably 5% by mass or more. Moreover, the total content of P2L and PL2 in the oil and fat B is 18% by mass or less, and preferably 16% by mass or less.
本発明で用いられる前記油脂B中のPO2含有量は5質量%以上であることが好ましく、7質量%以上であることがより好ましく、9質量%以上であることがさらに好ましい。また、前記油脂B中のPO2含有量は20質量%以下であることが好ましく、18質量%以下であることがより好ましい。 The content of PO2 in the oil B used in the present invention is preferably 5% by mass or more, more preferably 7% by mass or more, and further preferably 9% by mass or more. Moreover, it is preferable that PO2 content in the said fats and oils B is 20 mass% or less, and it is more preferable that it is 18 mass% or less.
前記油脂Bのヨウ素価が35以上60以下であることが好ましく、35以上55以下であることがより好ましく、37以上55以下であることがさらに好ましい。 The iodine value of the fat and oil B is preferably 35 or more and 60 or less, more preferably 35 or more and 55 or less, and further preferably 37 or more and 55 or less.
前記油脂Bとしては、前記パーム系油脂を含む配合油脂のエステル交換油を挙げられ、前記パーム系油脂と、構成脂肪酸中のオレイン酸とリノール酸の合計含有量が65質量%以上100質量%以下である前記パーム系油脂以外の油脂(以後、油脂Dとも記載)とを含む配合油脂のエステル交換油を好ましく挙げられ、前記パーム系油脂と前記油脂Dとのエステル交換油をより好ましく挙げられる。前記油脂Bに用いられるパーム系油脂は、パーム油およびパーム分別油からなる群から選択される1種または2種以上が好ましい。前記油脂Bに用いられる油脂Dとしては、大豆油、菜種油、コーン油、綿実油、米油、ヒマワリ油、サフラワー油、ゴマ油、オリーブ油等を挙げられ、これらは1種単独で使用してもよく2種以上を併用してもよい。前記油脂Bが、油脂Dを含む配合油脂のエステル交換油である場合、前記油脂Bに用いられるパーム系油脂に対する油脂Dとの配合比率は、質量比で0.05以上が好ましく、0.07以上がより好ましく、0.1以上がさらに好ましい。また、前記油脂Bに用いられるパーム系油脂に対する油脂Dの配合比率は、質量比で0.5以下が好ましく、0.4以下がより好ましく、0.3以下がさらに好ましい。 Examples of the fats and oils B include transesterified oils of blended fats and oils containing the palm-based fats and oils, and the total content of the palm-based fats and oils, oleic acid and linoleic acid in the constituent fatty acids is 65% by mass or more and 100% by mass or less. Preferred are transesterified oils and fats other than the above-mentioned palm-based fats and oils (hereinafter also referred to as fats and oils D), and more preferred are the transesterified oils of the palm-based fats and oils and D. As for the palm type fats and oils used for the said fats and oils B, 1 type, or 2 or more types selected from the group which consists of palm oil and palm fractionation oil are preferable. Examples of the fat D used for the fat B include soybean oil, rapeseed oil, corn oil, cottonseed oil, rice oil, sunflower oil, safflower oil, sesame oil, olive oil and the like, and these may be used alone. Two or more kinds may be used in combination. When the fats and oils B are transesterified oils of the blended fats and oils containing the fats and oils D, the blending ratio with the fats and oils D with respect to the palm-based fats and oils used for the fats and oils B is preferably 0.05 or more, and 0.07 The above is more preferable, and 0.1 or more is more preferable. Moreover, the blending ratio of the fats and oils D to the palm-based fats and oils used for the fats and oils B is preferably 0.5 or less, more preferably 0.4 or less, and even more preferably 0.3 or less in terms of mass ratio.
本発明の可塑性油脂組成物の油脂中の前記油脂Bの含有量は、焼成品の油染みを低減させる観点から、4質量%以上が好ましく、5質量%以上がより好ましい。また、焼成品用生地を作製する際に練り込みやすくさせる観点から、28質量%以下が好ましく、22質量%以下がより好ましい。 4 mass% or more is preferable from a viewpoint of reducing the oil stain of a baked product, and, as for content of the said fats and oils B in the fats and oils of the plastic fat composition of this invention, 5 mass% or more is more preferable. Moreover, from a viewpoint of making it easy to knead | mix when producing the baked goods dough, 28 mass% or less is preferable and 22 mass% or less is more preferable.
本発明で用いられる前記油脂Cは上昇融点が10℃以下の油脂であり、上昇融点が5℃以下の油脂が好ましく、上昇融点が0℃以下の油脂がより好ましい。前記油脂Cとしては、大豆油、菜種油、コーン油、綿実油、米油、ヒマワリ油、サフラワー油、ゴマ油、オリーブ油、パームオレイン等を挙げられ、これらは1種単独で使用してもよく2種以上を併用してもよい。大豆油、菜種油、コーン油、パームオレインからなる群から選択される1種または2種以上を好ましく挙げられ、大豆油、菜種油からなる群から選択される1種または2種をより好ましく挙げられる。 The fats and oils C used in the present invention are fats and oils having an ascending melting point of 10 ° C or lower, fats and oils having an ascending melting point of 5 ° C or less are preferable, and oils and fats having an ascending melting point of 0 ° C or less are more preferable. Examples of the fat C include soybean oil, rapeseed oil, corn oil, cottonseed oil, rice oil, sunflower oil, safflower oil, sesame oil, olive oil, palm olein, and the like. You may use the above together. One or more kinds selected from the group consisting of soybean oil, rapeseed oil, corn oil and palm olein are preferred, and one or two kinds selected from the group consisting of soybean oil and rapeseed oil are more preferred.
本発明の可塑性油脂組成物の油脂中の油脂Cの含有量は、62質量%以上85質量%以下である。焼成品用生地を作製する際に練り込みやすくさせる観点から、本発明の可塑性油脂組成物の油脂中の油脂Cの含有量は、64質量%以上が好ましく、67質量%以上がより好ましい。また、焼成品の油染みを低減させる観点から、83質量%以下が好ましく、80質量%以下がより好ましい。 Content of the fats and oils C in the fats and oils of the plastic fat composition of this invention is 62 mass% or more and 85 mass% or less. From the viewpoint of facilitating kneading when preparing a dough for a baked product, the content of the fat C in the fat of the plastic fat composition of the present invention is preferably 64% by mass or more, and more preferably 67% by mass or more. Moreover, from a viewpoint of reducing the oil stain of a baked product, 83 mass% or less is preferable and 80 mass% or less is more preferable.
本発明の可塑性油脂組成物には、効果を損なわない範囲において、前記油脂A、前記油脂Bおよび前記油脂C以外の油脂を含有してもよい。前記油脂A、前記油脂Bおよび前記油脂C以外の油脂としては、前記油脂A及び前記油脂B以外のエステル交換油やパーム油、パーム核油、ヤシ油、ラード、牛脂、乳脂等、およびこれらの分別油、水素添加油脂等の上昇融点が10℃超の食用油脂を挙げられ、これらは1種単独で使用してもよく2種以上を併用してもよい。 In the plastic fat composition of the present invention, fats and oils other than the fat A, the fat B, and the fat C may be contained as long as the effects are not impaired. As fats other than the fats and oils A, the fats and oils B, and the fats and oils C, transesterified oils other than the fats and oils A and the fats and oils B, palm oil, palm kernel oil, coconut oil, lard, beef tallow, milk fat, and the like, and these Examples thereof include edible fats and oils having a rising melting point of more than 10 ° C. such as fractionated oils and hydrogenated fats and oils, and these may be used alone or in combination of two or more.
本発明の可塑性油脂組成物における油脂含有量は、好ましくは50質量%以上100質量%以下、より好ましくは60質量%以上100質量%以下、さらに好ましくは70質量%以上100質量%以下である。 The fat content in the plastic fat composition of the present invention is preferably 50% by mass to 100% by mass, more preferably 60% by mass to 100% by mass, and further preferably 70% by mass to 100% by mass.
本発明の可塑性油脂組成物は、油脂を含む油相と水を含む水相とを油中水型に乳化した油中水型可塑性油脂組成物であってもよいし、水分が0.5質量%以下であるショートニングであってもよいが、油中水型可塑性油脂組成物であることが好ましい。油中水型可塑性油脂組成物の場合、油相の含有量は、好ましくは50質量%以上99.4質量%以下、より好ましくは60質量%以上98質量%以下、さらに好ましくは、70質量%以上85質量%以下である。水相の含有量は、好ましくは0.6質量%以上50質量%以下、より好ましくは2質量%以上40質量%以下、さらに好ましくは、15質量%以上30質量%以下である。油中水型可塑性油脂組成物の例としては、ファットスプレッドやマーガリン等が挙げられる。 The plastic fat composition of the present invention may be a water-in-oil plastic fat composition in which an oil phase containing fat and oil and an aqueous phase containing water are emulsified in a water-in-oil type, and the water content is 0.5 mass. %, But it is preferably a water-in-oil type plastic fat composition. In the case of a water-in-oil plastic fat composition, the content of the oil phase is preferably 50% by mass or more and 99.4% by mass or less, more preferably 60% by mass or more and 98% by mass or less, and further preferably 70% by mass. It is 85 mass% or less. The content of the aqueous phase is preferably 0.6% by mass to 50% by mass, more preferably 2% by mass to 40% by mass, and still more preferably 15% by mass to 30% by mass. Examples of the water-in-oil type plastic fat composition include fat spread and margarine.
本発明の可塑性油脂組成物には、油脂と水以外に、従来の公知の成分を含んでもよい。公知の成分としては、特に限定されないが、例えば乳、乳製品、蛋白質、糖質、塩類、酸味料、pH調整剤、抗酸化剤、香辛料、着色成分、香料、乳化剤等が挙げられる。乳としては、牛乳等が挙げられる。乳製品としては、脱脂乳、クリーム、チーズ(ナチュラルチーズ、プロセスチーズ等)、発酵乳、濃縮乳、脱脂濃縮乳、無糖れん乳、加糖れん乳、無糖脱脂れん乳、加糖脱脂れん乳、全粉乳、脱脂粉乳、クリームパウダー、ホエイパウダー、蛋白濃縮ホエイパウダー、ホエイ蛋白コンセントレート、ホエイ蛋白アイソレート、バターミルクパウダー、トータルミルクプロテイン、カゼインナトリウム、カゼインカリウム等が挙げられる。蛋白質としては、大豆蛋白質、エンドウ豆蛋白質、小麦蛋白質等の植物蛋白質等が挙げられる。糖質としては、単糖(グルコース、フルクトース、ガラクトース、マンノース等)、二糖類(ラクトース、スクロース、マルトース、トレハロース等)、オリゴ糖、糖アルコール、デンプン、デンプン分解物、多糖類等が挙げられる。抗酸化剤としては、L−アスコルビン酸、L−アスコルビン酸誘導体、トコフェロール、トコトリエノール、リグナン、ユビキノン類、キサンチン類、オリザノール、植物ステロール、カテキン類、ポリフェノール類、茶抽出物等が挙げられる。香辛料としては、カプサイシン、アネトール、オイゲノール、シネオール、ジンゲロン等が挙げられる。着色成分としては、カロテン、アナトー、アスタキサンチン等が挙げられる。香料としては、バターフレーバー、ミルクフレーバー等が挙げられる。乳化剤としては、ソルビタン脂肪酸エステル、ポリグリセリン脂肪酸エステル、レシチン、モノグリセリン脂肪酸エステル、有機酸グリセリン脂肪酸エステル、ショ糖脂肪酸エステル、ポリグリセリン縮合リシノレイン酸エステル、プロピレングリコール脂肪酸エステル、ステアロイル乳酸カルシウム、ステアロイル乳酸ナトリウム、ポリオキシエチレンソルビタン脂肪酸エステル等が挙げられ、本発明の効果を損なわない範囲において添加することができる。 The plastic oil / fat composition of the present invention may contain conventionally known components in addition to the oil / fat and water. Although it does not specifically limit as a well-known component, For example, milk, dairy products, protein, saccharides, salts, a sour agent, a pH adjuster, an antioxidant, a spice, a coloring component, a fragrance | flavor, an emulsifier etc. are mentioned. Examples of milk include milk. Dairy products include skim milk, cream, cheese (natural cheese, processed cheese, etc.), fermented milk, concentrated milk, skim concentrated milk, sugar-free milk, sweetened milk, sugar-free skimmed milk, sweetened skimmed milk, Examples include whole milk powder, skim milk powder, cream powder, whey powder, protein concentrated whey powder, whey protein concentrate, whey protein isolate, buttermilk powder, total milk protein, casein sodium, and casein potassium. Examples of the protein include plant proteins such as soybean protein, pea protein, and wheat protein. Examples of the saccharide include monosaccharides (glucose, fructose, galactose, mannose, etc.), disaccharides (lactose, sucrose, maltose, trehalose, etc.), oligosaccharides, sugar alcohols, starches, starch degradation products, polysaccharides and the like. Examples of the antioxidant include L-ascorbic acid, L-ascorbic acid derivatives, tocopherol, tocotrienol, lignan, ubiquinones, xanthines, oryzanol, plant sterols, catechins, polyphenols, tea extracts and the like. Examples of spices include capsaicin, anethole, eugenol, cineol, gingerone and the like. Examples of the coloring component include carotene, anato, astaxanthin and the like. Examples of the fragrances include butter flavor and milk flavor. Emulsifiers include sorbitan fatty acid ester, polyglycerin fatty acid ester, lecithin, monoglycerin fatty acid ester, organic acid glycerin fatty acid ester, sucrose fatty acid ester, polyglycerin condensed ricinoleic acid ester, propylene glycol fatty acid ester, calcium stearoyl lactate, sodium stearoyl lactate And polyoxyethylene sorbitan fatty acid esters, and the like, and can be added within a range not impairing the effects of the present invention.
本発明の可塑性油脂組成物は、公知の方法により製造することができる。例えば油中水型に乳化した形態のものは、前記油相と前記水相とを、適宜に加熱し混合して乳化した後、コンビネーター、パーフェクター、ボテーター、ネクサス等の密封式急冷捏和装置により急冷捏和し得ることができる。ショートニングは、前記油相を加熱した後、コンビネーター、パーフェクター、ボテーター、ネクサス等の密封式急冷捏和装置により急冷捏和し得ることができる。急冷捏和後には、必要に応じて20℃程度の温度で数日保管する熟成工程を経てもよい。 The plastic fat composition of the present invention can be produced by a known method. For example, in the form of emulsification in a water-in-oil type, the oil phase and the water phase are appropriately heated, mixed and emulsified, and then combined with a quenching quenching agent such as a combinator, a perfector, a botter and a nexus. It can be quenched and quenched by the device. In the shortening, after heating the oil phase, the oil phase can be quenched and cooled by a sealed quenching and kneading apparatus such as a combinator, a perfector, a botter, and a nexus. After quenching and kneading, an aging step of storing for several days at a temperature of about 20 ° C. may be performed as necessary.
本発明の可塑性油脂組成物は、練り込み用としてパンや菓子等の焼成品用生地に用いることができる。焼成品用生地を作製する工程において、本発明の可塑性油脂組成物を0℃超10℃以下の冷蔵温度で用いることができるが、本発明の可塑性油組成物を添加する工程の順は問わない。本発明の可塑性油脂組成物を添加する工程の後に、本発明の可塑性油脂組成物以外の焼成品用生地原料を添加する工程があってもよいし、本発明の可塑性油脂組成物以外の焼成品用生地原料を添加する工程の後に、本発明の可塑性油脂組成物を添加する工程があってもよい。 The plastic fat composition of the present invention can be used for dough for baking products such as bread and confectionery for kneading. In the step of producing a dough for a baked product, the plastic fat composition of the present invention can be used at a refrigeration temperature of more than 0 ° C. and not more than 10 ° C., but the order of the steps of adding the plastic oil composition of the present invention does not matter. . After the step of adding the plastic fat composition of the present invention, there may be a step of adding a raw material for a fired product other than the plastic fat composition of the present invention, or a fired product other than the plastic fat composition of the present invention. There may be a step of adding the plastic fat composition of the present invention after the step of adding the dough raw material.
本発明の可塑性油脂組成物を含有する焼成品用生地を適宜成形して、焼成することによってパンや菓子等の焼成品が得られる。前記焼成品用生地の焼成は、例えば公知の条件及び方法に従っておこなうことができる。本発明の可塑性油脂組成物を用いて焼成品用生地を作製すると、焼成品の油染みを低減させることができる。 A baked product such as bread or confectionery can be obtained by appropriately forming and baking a dough for a baked product containing the plastic fat composition of the present invention. The baking of the dough for a baked product can be performed, for example, according to known conditions and methods. If the dough for baked goods is produced using the plastic fat composition of this invention, the oil stain of a baked goods can be reduced.
本発明の焼成品用生地は、穀粉を主成分とし、穀粉としては、通常、焼成品用生地に配合されるものであれば、特に限定されないが、例えば小麦粉(強力粉、中力粉、薄力粉等)、大麦粉、米粉、とうもろこし粉、ライ麦粉、そば粉、大豆粉、澱粉等が挙げられる。 The dough for the baked product of the present invention is mainly composed of flour, and the flour is not particularly limited as long as it is usually blended with the dough for the baked product. For example, wheat flour (strong flour, medium flour, weak flour, etc.) ), Barley flour, rice flour, corn flour, rye flour, buckwheat flour, soybean flour, starch and the like.
本発明の焼成品用生地における本発明の可塑性油脂組成物の配合量は、焼成品の種類によっても異なり特に限定されないが、焼成品用生地に配合される穀粉100質量部に対する可塑性油脂組成物量として好ましくは2質量部以上150質量部以下であり、より好ましくは10質量部以上120質量部以下である。 The blending amount of the plastic fat composition of the present invention in the baked product dough of the present invention varies depending on the type of baked product and is not particularly limited, but as the amount of the plastic fat composition for 100 parts by mass of flour blended in the baked product dough Preferably they are 2 mass parts or more and 150 mass parts or less, More preferably, they are 10 mass parts or more and 120 mass parts or less.
本発明の焼成品用生地には、穀粉と本発明の可塑性油脂組成物以外にも、通常、焼成品用生地に配合されるものであれば、特に制限なく配合することができる。また、これらの配合量も、特に制限されない。具体的には、例えば、水や、前記可塑性油脂組成物が含む成分として挙げた乳、乳製品、蛋白質、糖質の他、卵、卵加工品、塩類、乳化剤、乳化起泡剤(乳化油脂)、イースト、イーストフード、カカオマス、ココアパウダー、チョコレート、コーヒー、紅茶、抹茶、野菜類、果物類、果実、果汁、ジャム、フルーツソース、肉類、魚介類、豆類、豆腐、豆乳、大豆蛋白質、膨張剤、甘味料、調味料、香辛料、着色料、香料等が挙げられる。 In addition to the flour and the plastic oil composition of the present invention, the fired product dough of the present invention can be blended without particular limitation as long as it is usually blended into the fired product dough. Also, the amount of these is not particularly limited. Specifically, for example, water, milk, dairy products, proteins, carbohydrates, eggs, processed eggs, salts, emulsifiers, emulsifying foaming agents (emulsified fats and oils) mentioned as components included in the plastic fat composition. ), Yeast, yeast food, cacao mass, cocoa powder, chocolate, coffee, tea, green tea, vegetables, fruits, fruits, fruit juice, jam, fruit sauce, meat, seafood, legumes, tofu, soy milk, soy protein, swelling Examples include agents, sweeteners, seasonings, spices, coloring agents, and fragrances.
焼成品としては、例えば食パン、ロールパン、菓子パン、調理パン、シュトーレン、パネトーネ、ブリオッシュなどのパン類;デニッシュ、クロワッサン、パイなどのペストリー;パウンドケーキ、スポンジケーキ、ホットケーキなどのケーキ類;ビスケット、クッキー、焼きドーナツ、ブッセ、ワッフルなどの焼き菓子等が挙げられる。 Examples of baked products include breads such as bread, rolls, sweets, cooked bread, stollen, panettone, brioche; pastries such as Danish, croissant, pie; cakes such as pound cake, sponge cake, hot cake; biscuits, cookies Baked confectionery such as baked donuts, busses and waffles.
以下、実施例および比較例を挙げて、本発明をさらに詳細に説明する。しかし、以下の実施例は、本発明を限定するものではない。 Hereinafter, the present invention will be described in more detail with reference to Examples and Comparative Examples. However, the following examples do not limit the present invention.
(原料)
配合油脂および焼成品用油脂組成物の調製に際し、以下のものを使用した。
(油脂)
菜種油(上昇融点0℃以下、構成脂肪酸中のオレイン酸とリノール酸の合計含有量81.1質量%、株式会社J−オイルミルズ社製)
大豆油(上昇融点0℃以下、構成脂肪酸中のオレイン酸とリノール酸の合計含有量77.5質量%、株式会社J−オイルミルズ社製)
パーム油(株式会社J−オイルミルズ社製)
パームステアリン(ヨウ素価32、株式会社J−オイルミルズ社製)
パーム核油(株式会社J−オイルミルズ社製)
(乳化剤)
レシチン(製品名:J レシチンFA、株式会社J−オイルミルズ社製)
モノグリセリン脂肪酸エステル(製品名:エキセルO−95R、花王株式会社製)
(その他)
脱脂粉乳(森永乳業株式会社製)
香料(市販のバターフレーバー)
(material)
The following were used in the preparation of the blended fat and oil and the fat and oil composition for fired products.
(Oil and fat)
Rapeseed oil (increased melting point 0 ° C. or less, total content of oleic acid and linoleic acid in constituent fatty acids 81.1% by mass, manufactured by J-Oil Mills Co., Ltd.)
Soybean oil (rising melting point 0 ° C. or less, total content of oleic acid and linoleic acid in constituent fatty acid 77.5% by mass, manufactured by J-Oil Mills Co., Ltd.)
Palm oil (manufactured by J-Oil Mills Co., Ltd.)
Palm stearin (Iodine value 32, manufactured by J-Oil Mills Co., Ltd.)
Palm kernel oil (manufactured by J-Oil Mills Co., Ltd.)
(emulsifier)
Lecithin (Product name: J Lecithin FA, manufactured by J-Oil Mills)
Monoglycerin fatty acid ester (Product name: Excel O-95R, manufactured by Kao Corporation)
(Other)
Nonfat dry milk (Morinaga Milk Industry Co., Ltd.)
Fragrance (commercially available butter flavor)
(測定方法)
原料油脂、エステル交換油および配合油脂の下記の項目について下記の方法で測定した。
(Measuring method)
It measured by the following method about the following item of raw material fats and oils, transesterification oil, and mixing | blending fats and oils.
トリアシルグリセロールを構成する脂肪酸の総炭素数(以後、CNとも記載)が38以上44以下のトリアシルグリセロール含有量は、基準油脂分析試験法(社団法人日本油化学会)の「2.4.6.1−1996 トリアシルグリセリン組成(ガスクロマトグラフ法)」により測定して、算出した。 The triacylglycerol content in which the total number of carbon atoms (hereinafter also referred to as CN) of the fatty acid constituting the triacylglycerol is 38 or more and 44 or less is determined according to the standard oil analysis method (Japan Oil Chemistry Society) “2.4. 6.1-1996 Triacylglycerol composition (gas chromatographic method) "and calculated.
構成脂肪酸中のオレイン酸含有量、リノール酸含有量、パルミチン酸含有量およびステアリン酸含有量は、基準油脂分析試験法(社団法人日本油化学会)の「2.4.2.3−2013 脂肪酸組成(キャピラリーガスクロマトグラフ法)」により測定した。 The oleic acid content, linoleic acid content, palmitic acid content and stearic acid content in the constituent fatty acids were measured according to “2.4.2.3-2013 Fatty Acids” of the standard fat analysis method (Japan Oil Chemists' Society). Composition (capillary gas chromatographic method) ".
P2O含有量、P2L含有量、PO2含有量およびPL2含有量は、カラム長が60mのものを使用したこと以外は、JAOCS,Vol70,No.11,1111−1114(1993)に記載の方法にしたがって測定した。。 The P2O content, P2L content, PO2 content and PL2 content are the same as those in JAOCS, Vol 70, No. 1, except that the column length is 60 m. 11, 1111-1114 (1993). .
ヨウ素価は、基準油脂分析試験法(社団法人日本油化学会)の「2.3.4.1−1996 ヨウ素価(ウィイス−シクロヘキサン法)」により測定した。 The iodine value was measured by “2.3.4.1-1996 Iodine value (Wiis-Cyclohexane method)” of the standard oil analysis method (Japan Oil Chemists' Society).
上昇融点は、基準油脂分析試験法(社団法人日本油化学会)の「2.2.4.2−1996 融点(上昇融点)」により測定した。 The rising melting point was measured by “2.2.4.2-1996 melting point (rising melting point)” of the standard fat analysis method (Japan Oil Chemists' Society).
(エステル交換油1の製造)
パーム油を30質量部及びパーム核油を70質量部混合した混合油に対して、ナトリウムメトキシドを触媒として0.3質量部添加し、80℃、真空度2.7kPaの条件で60分間攪拌しながらランダムエステル交換反応をおこなった。ランダムエステル交換反応後、水洗して触媒を除去し、水素添加をおこなった。水素添加後、活性白土を用いて脱色し、更に脱臭をおこなってエステル交換油1を得た。エステル交換油1中の、CNが38以上44以下のトリアシルグリセロール含有量は53.2質量%、パルミチン酸含有量は19.9質量%、ステアリン酸含有量は32.2質量%、ヨウ素価は1であった。
(Manufacture of transesterified oil 1)
0.3 parts by mass of sodium methoxide as a catalyst is added to a mixed oil obtained by mixing 30 parts by mass of palm oil and 70 parts by mass of palm kernel oil, and stirred for 60 minutes under conditions of 80 ° C. and a degree of vacuum of 2.7 kPa. The random transesterification reaction was carried out. After the random transesterification reaction, the catalyst was removed by washing with water, and hydrogenation was performed. After hydrogenation, decolorization was performed using activated clay, and further deodorization was performed to obtain transesterified oil 1. The transacyl oil 1 has a triacylglycerol content of 53.2% by mass, a palmitic acid content of 19.9% by mass, a stearic acid content of 32.2% by mass, and an iodine value. Was 1.
(エステル交換油2の製造)
パーム油を50質量部及びパーム核油を50質量部混合した混合油を用いたこと以外は、エステル交換油1と同じ方法で、エステル交換油2を製造した。エステル交換油2中の、CNが38以上44以下のトリアシルグリセロール含有量は36.6質量%、パルミチン酸含有量は27.2質量%、ステアリン酸含有量は38.1質量%、ヨウ素価は1であった。
(Production of transesterified oil 2)
Transesterified oil 2 was produced in the same manner as transesterified oil 1 except that a mixed oil obtained by mixing 50 parts by mass of palm oil and 50 parts by mass of palm kernel oil was used. The transacyl oil 2 has a triacylglycerol content of 36.6% by mass, a palmitic acid content of 27.2% by mass, a stearic acid content of 38.1% by mass, and an iodine value. Was 1.
(エステル交換油3の製造)
パームステアリンを75質量部、パーム油を10質量部及び大豆油を15質量部混合した混合油に対して、ナトリウムメトキシドを触媒として0.3質量部添加し、80℃、真空度2.7kPaの条件で60分間攪拌しながらランダムエステル交換反応をおこなった。ランダムエステル交換反応後、水洗して触媒を除去し、更に脱臭をおこなってエステル交換油3を得た。エステル交換油3中の、P2O含有量は22.1質量%、P2LとPL2との合計含有量は13.6質量%、PO2含有量は11.4質量%、ヨウ素価は50であった。
(Manufacture of transesterified oil 3)
0.3 parts by mass of sodium methoxide as a catalyst is added to a mixed oil obtained by mixing 75 parts by mass of palm stearin, 10 parts by mass of palm oil and 15 parts by mass of soybean oil, and 80 ° C. and a vacuum degree of 2.7 kPa. A random transesterification reaction was carried out with stirring for 60 minutes under the above conditions. After the random transesterification reaction, the catalyst was removed by washing with water, and further deodorization was performed to obtain a transesterified oil 3. In the transesterified oil 3, the P2O content was 22.1% by mass, the total content of P2L and PL2 was 13.6% by mass, the PO2 content was 11.4% by mass, and the iodine value was 50.
(エステル交換油4の製造)
パームステアリンを75質量部、パーム油を10質量部及び菜種油を15質量部混合した混合油を用いたこと以外は、エステル交換油3と同じ方法で、エステル交換油4を製造した。エステル交換油4中の、P2O含有量は26.8質量%、P2LとPL2との合計含有量は7.2質量%、PO2含有量は16.3質量%、ヨウ素価は48であった。
(Production of transesterified oil 4)
Transesterified oil 4 was produced by the same method as transesterified oil 3 except that 75 parts by mass of palm stearin, 10 parts by mass of palm oil and 15 parts by mass of rapeseed oil were used. In the transesterified oil 4, the P2O content was 26.8% by mass, the total content of P2L and PL2 was 7.2% by mass, the PO2 content was 16.3% by mass, and the iodine value was 48.
(配合油脂の調製)
表1および表2の配合にしたがって配合油脂を調製した。
(Preparation of blended fats and oils)
Formulated fats and oils were prepared according to the formulations shown in Tables 1 and 2.
(焼成品用油脂組成物の調製)
表3の配合にしたがって焼成品用油脂組成物を調製した。
(Preparation of fired oil composition)
A fired oil composition was prepared according to the formulation shown in Table 3.
(マーガリンの調製)
表3のマーガリンの油相の配合にしたがい、調製例1−1〜1−2、調製例1−4〜1−5、調製例2−1〜2−6の配合油脂をそれぞれ70℃に加温して配合油脂以外の油相成分を溶解し、油相を準備した。表3の水相の配合にしたがい、水道水に脱脂粉乳を溶解後、60℃30分の条件で加熱殺菌し、水相を準備した。次に、前記油相に前記水相を添加し、プロペラ撹拌機で撹拌して混合乳化した乳化液をパーフェクターによって急冷捏和し、可塑性油脂組成物のマーガリンを得た。得られたマーガリンは5℃の恒温槽に保管した。
(Preparation of margarine)
According to the blending of the margarine oil phase in Table 3, the blended fats and oils of Preparation Examples 1-1 to 1-2, Preparation Examples 1-4 to 1-5, and Preparation Examples 2-1 to 2-6 were added to 70 ° C., respectively. The oil phase components other than the blended fats and oils were dissolved by heating to prepare an oil phase. In accordance with the composition of the aqueous phase in Table 3, the skim milk powder was dissolved in tap water, and then heat sterilized at 60 ° C. for 30 minutes to prepare an aqueous phase. Next, the water phase was added to the oil phase, and the emulsified liquid obtained by stirring and mixing and emulsifying with a propeller stirrer was rapidly cooled and kneaded with a perfector to obtain a margarine of a plastic fat composition. The obtained margarine was stored in a constant temperature bath at 5 ° C.
(ショートニングの調製)
表3のショートニングの配合にしたがい、調製例1−3の配合油脂を70℃に加温して配合油脂以外の油相成分を溶解し、油相を準備した。油相をパーフェクターによって急冷捏和し、可塑性油脂組成物のショートニングを得た。得られたショートニングの水分は0.1質量%であった。得られたショートニングは5℃の恒温槽に保管した。
(Preparation of shortening)
In accordance with the shortening formulation shown in Table 3, the blended fats and oils of Preparation Example 1-3 were heated to 70 ° C. to dissolve oil phase components other than the blended fats and oils to prepare an oil phase. The oil phase was quenched and kneaded with a perfector to obtain a shortening of the plastic fat composition. The moisture of the obtained shortening was 0.1% by mass. The shortening obtained was stored in a constant temperature bath at 5 ° C.
(液状油脂組成物の調製)
表3の液状油脂組成物の配合にしたがい、調製例1−6の配合油脂を70℃に加温して配合油脂以外の油相成分を溶解し、液状油脂組成物を得た。得られた液状油脂組成物の水分は0.1質量%であった。得られた液状油脂組成物は5℃の恒温槽に保管した。
(Preparation of liquid oil composition)
According to the blending of the liquid fat composition of Table 3, the blended fat of Preparation Example 1-6 was heated to 70 ° C. to dissolve the oil phase components other than the blended fat, thereby obtaining a liquid fat composition. The water content of the obtained liquid fat composition was 0.1% by mass. The obtained liquid fat composition was stored in a thermostatic bath at 5 ° C.
(パウンドケーキの作製および評価)
焼成品用油脂組成物を用いて、表4の配合のパウンドケーキを下記の作業手順で作製し、下記評価基準で評価した。
(Production and evaluation of pound cake)
Using the fat and oil composition for fired products, a pound cake having the composition shown in Table 4 was prepared according to the following work procedure, and evaluated according to the following evaluation criteria.
5℃の焼成品用油脂組成物を卓上ホバートミキサーのボウルに入れて、ビーターを使用して低速で30秒ミキシングした。上白糖を追加してさらに低速で30秒、中速で1分ミキシングした。全卵を100g加え、中速で30秒ミキシングする作業を3回おこなった。薄力粉とベーキングパウダーを加えて低速で30秒ミキシングし、パウンドケーキ生地を得た。パウンド型に300gずつパウンドケーキ生地を入れて、上段180℃、下段190℃に加熱したオーブンで40分焼成し、パウンドケーキを作製した。 The oil / fat composition for a fired product at 5 ° C. was placed in a bowl of a desktop Hobart mixer, and mixed at a low speed for 30 seconds using a beater. Super white sugar was added and mixing was continued for 30 seconds at low speed and for 1 minute at medium speed. 100 g of whole eggs were added, and the work of mixing for 30 seconds at medium speed was performed three times. Weak flour and baking powder were added and mixed at low speed for 30 seconds to obtain a pound cake dough. 300 g of pound cake dough was put in a pound mold and baked in an oven heated to an upper stage of 180 ° C. and a lower stage of 190 ° C. for 40 minutes to prepare a pound cake.
<練り込みやすさ>
マーガリン又はショートニングに上白糖を追加しミキシングした際にマーガリン又はショートニングの塊がなくなる状態から目視により練り込みやすさを評価した。
◎ とても練り込みやすい
○ 練り込みやすい
△ やや練り込みやすい
× 練り込みにくい
<Ease of kneading>
Ease of kneading was evaluated by visual observation from the state in which the mass of margarine or shortening disappeared when adding white sucrose to the margarine or shortening and mixing.
◎ Very easy to knead ○ Easy to knead △ Slightly easy to knead × Hard to knead
<油染み>
焼成したパウンドケーキを20℃まで放冷後、紙の上に5分間乗せ、パウンドケーキを取り除いた時に、紙への油の付着度合いから油染みを評価した。
◎ 油染みがとても少ない
○ 油染みが少ない
△ 油染みがやや少ない
× 油染みが多い
<Oil stain>
The fired pound cake was allowed to cool to 20 ° C. and then placed on paper for 5 minutes. When the pound cake was removed, the oil stain was evaluated from the degree of oil adhesion to the paper.
◎ Very little oil stain ○ Less oil stain △ Somewhat less oil stain × Many oil stains
<外観>
焼成したパウンドケーキの表面に、白い斑点があるかを目視で評価した。
◎ 白い斑点が見られない
○ 白い斑点がほとんど見られない
△ 白い斑点があまり見られない
× 白い斑点が見られる
<Appearance>
The surface of the baked pound cake was visually evaluated for white spots.
◎ No white spots are seen ○ Little white spots are seen △ Little white spots are seen × White spots are seen
<内部の気泡>
焼成したパウンドケーキを切った際、断面に大きな気泡があるかを目視で評価した。
◎ 大きな気泡が見られない
○ 大きな気泡がほとんど見られない
△ 大きな気泡があまり見られない
× 大きな気泡が見られる
<Bubble inside>
When the fired pound cake was cut, it was visually evaluated whether there were large bubbles in the cross section.
◎ Large bubbles are not seen ○ Large bubbles are hardly seen △ Large bubbles are not seen very much × Large bubbles are seen
<口どけ>
焼成して冷めてからポリ袋に入れ、20℃で1日間おいたパウンドケーキを、専門パネラー6人で食して、合議の上、下記の評価基準により口どけを評価した。ここで口どけがよいとは、口内で長く残ることがなく、短時間でくずれ、飲み込みやすい状態を意味する。
◎ とても口どけがよい
○ 口どけがよい
△ やや口どけがよい
× 口どけが悪い
<Drilling>
After baking and cooling, it was put in a plastic bag and baked at 20 ° C for 1 day with 6 expert panelists. After consultation, the mouthfeel was evaluated according to the following evaluation criteria. Here, the phrase “good mouth” means a state in which the mouth does not remain for a long time, breaks in a short time, and is easy to swallow.
◎ Very mouthful ○ Good mouthfeel △ Good mouthfeel × Bad mouthfeel
<パサつき>
焼成して冷めてからポリ袋に入れ、20℃で1日間おいたパウンドケーキを、専門パネラー6人で食して、合議の上、下記の評価基準によりパサつきを評価した。ここでパサつくとは、しっとりしておらず、口内の水分を奪う感じを意味する。
◎ パサつかない
○ ほとんどパサつかない
△ あまりパサつかない
× パサつく
<With path>
After baking and cooling, the cake was put in a plastic bag and kept at 20 ° C. for 1 day with 6 expert panelists. After discussion, the texture was evaluated according to the following evaluation criteria. Here, “pasting” means feeling moist and depriving the mouth of moisture.
◎ It doesn't pass ○ It almost doesn't pass △ It doesn't pass much
パウンドケーキの評価結果を表5および表6に示す。 Table 5 and Table 6 show the evaluation results of the pound cake.
実施例の焼成品用油脂組成物は練り込みやすく、油染みが低減されたパウンドケーキが焼成でき、パウンドケーキの外観が良好で、内部の気泡が均質で、食したときに口どけが良好で、パサつきが抑えられていた。特に菜種油もしくは大豆油を70質量%以上76質量%以下含む配合油脂を使用した焼成品用油脂組成物は特に練り込みやすく、パウンドケーキの油染みも抑制できた。液状油脂組成物を使用した比較例5−3は、上白糖を追加しても均一に混ぜられなかった。焼成品は油染みが多く、かつ表面に白い斑点が目立ち、食したときの口どけが悪く、パサついていた。 The fat and oil composition for the baked product of the example is easy to knead, can bak a pound cake with reduced oil stain, the appearance of the pound cake is good, the internal bubbles are homogeneous, and the mouthfeel is good when eaten, Pasiness was suppressed. In particular, an oil / fat composition for a baked product using a blended oil / fat containing 70% by mass or more and 76% by mass or less of rapeseed oil or soybean oil was particularly easy to knead, and the oil stain of the pound cake could be suppressed. In Comparative Example 5-3 using the liquid fat composition, even when sucrose was added, it was not mixed uniformly. The baked product had a lot of oil stains, white spots on the surface were noticeable, and the mouthfeel was bad when eaten.
(パンの作製および評価)
表1および表2に示す調製例2−3、調製例1−5及び調製例2−5の配合油脂により調製したマーガリンを用いて、表7の配合のパンを下記の作業手順で作製し、下記評価基準で評価した。
(Bread making and evaluation)
Using the margarine prepared with the blended fats and oils of Preparation Example 2-3, Preparation Example 1-5, and Preparation Example 2-5 shown in Table 1 and Table 2, the breads of the blending of Table 7 are prepared according to the following work procedure. Evaluation was performed according to the following evaluation criteria.
パンの作製には、ホームベーカリー(型番:SD−BM102−H、株式会社パナソニック社製)を用いた。マーガリンとドライイースト以外の材料を羽根がセットされたパンケースに入れた。材料の入ったパンケースをホームベーカリー本体にセットし、イースト容器にドライイーストをセットした後、ホームベーカリーの蓋を閉め、コースをドライイースト、メニューを早焼きにそれぞれ設定して、スタートボタンを押した。ドライイーストが投下されてから1分後にホームベーカリーの蓋を開け、5℃のマーガリンをホームベーカリーに入れて、練り込みやすさの評価が完了後、ホームベーカリーの蓋を閉めた。焼成が完了したブザーが鳴ったら、ホームベーカリーの蓋を開けて、速やかにパンケースから焼成したパンを取り出した。 A home bakery (model number: SD-BM102-H, manufactured by Panasonic Corporation) was used for bread production. Ingredients other than margarine and dry yeast were placed in a pan case with feathers. The bread case containing the ingredients was set in the home bakery body, the dry yeast was set in the yeast container, the lid of the home bakery was closed, the course was set to dry yeast, and the menu was pre-baked, and the start button was pressed. One minute after the dry yeast was dropped, the lid of the home bakery was opened, 5 ° C. margarine was placed in the home bakery, and after the evaluation of ease of kneading was completed, the lid of the home bakery was closed. When the buzzer that completed baking rang, the lid of the home bakery was opened, and the baked bread was quickly taken out from the bread case.
<練り込みやすさ>
マーガリンを入れてから、マーガリンの塊がなくなる時間を目視により評価した。
◎ 1分以上1分30秒未満
○ 1分30秒以上2分未満
△ 2分以上2分30秒未満
× 2分30秒経っても塊がなくならない
<Ease of kneading>
After the margarine was added, the time until the margarine lumps disappeared was visually evaluated.
◎ 1 minute or more and less than 1 minute and 30 seconds ○ 1 minute and 30 seconds or more and less than 2 minutes △ 2 minutes or more and less than 2 minutes and 30 seconds × Even if 2 minutes and 30 seconds pass, the lump does not disappear
<油染み>
焼成したパンを20℃で20分放置した後、紙の上に5分間乗せ、パンを取り除いた時に、紙への油の付着度合いから油染みを評価した。
◎ 油染みがとても少ない
○ 油染みが少ない
△ 油染みがやや少ない
× 油染みが多い
<Oil stain>
The baked bread was left at 20 ° C. for 20 minutes and then placed on paper for 5 minutes. When the bread was removed, oil stain was evaluated from the degree of oil adhesion to the paper.
◎ Very little oil stain ○ Less oil stain △ Somewhat less oil stain × Many oil stains
<ふくらみ>
焼成したパンがどの程度ふくらんだか、高さを測定し評価した。
◎ 18cm以上
○ 17.5cm以上18cm未満
△ 17cm以上17.5cm未満
× 17cm未満
<Bulge>
The height of the baked bread was measured and evaluated.
◎ 18cm or more ○ 17.5cm or more and less than 18cm △ 17cm or more and less than 17.5cm × less than 17cm
<口どけ>
油染み評価後のパンをポリ袋に入れて、20℃で1日間おいたパンを、専門パネラー6人で食して、合議の上、下記の評価基準により口どけを評価した。
◎ とても口どけがよい
○ 口どけがよい
△ やや口どけがよい
× 口どけが悪い
<Drilling>
After the oil stain evaluation, the bread was put in a plastic bag, and the bread left at 20 ° C. for 1 day was eaten by 6 expert panelists.
◎ Very mouthful ○ Good mouthfeel △ Good mouthfeel × Bad mouthfeel
<パサつき>
油染み評価後のパンをポリ袋に入れて、20℃で1日間おいたパンを、専門パネラー6人で食して、合議の上、下記の評価基準によりパサつきを評価した。
◎ パサつかない
○ ほとんどパサつかない
△ あまりパサつかない
× パサつく
<With path>
The bread after the oil stain evaluation was put in a plastic bag, and the bread left at 20 ° C. for 1 day was eaten by 6 expert panelists.
◎ It doesn't pass ○ It almost doesn't pass △ It doesn't pass much
パンの評価結果を表8に示す。 Table 8 shows the bread evaluation results.
調製例2−3の配合油脂を含有するマーガリンを使用した実施例8−1は、生地作製時に練り込みやすく、油染みが低減されたパンを焼成できた。焼成したパンは充分ふくらんでおり、パンを食したときの口どけはとても良好で、パサつきはほとんど感じられなかった。 In Example 8-1 using margarine containing the blended fats and oils of Preparation Example 2-3, it was easy to knead at the time of preparing the dough, and bread with reduced oil stain could be baked. The baked bread was fully swelled, the mouthfeel when eating bread was very good, and almost no puffiness was felt.
Claims (13)
油脂A:トリアシルグリセロールを構成する脂肪酸の総炭素数が38以上44以下のトリアシルグリセロール含有量が30質量%以上60質量%以下であり、かつ構成脂肪酸中のパルミチン酸含有量が10質量%以上35質量%以下であるエステル交換油。
油脂B:P2O含有量が18質量%以上28質量%以下であり、かつP2LとPL2の合計含有量が3質量%以上18質量%以下であるエステル交換油(ただし、P2Oは1分子中にパルミチン酸が2個、オレイン酸が1個エステル結合しているトリアシルグリセロール、P2Lは1分子中にパルミチン酸が2個、リノール酸が1個エステル結合しているトリアシルグリセロール、PL2は1分子中にパルミチン酸が1個、リノール酸が2個エステル結合しているトリアシルグリセロールを意味する)。
油脂C:上昇融点が10℃以下の食用油脂。 It is a plastic fat composition containing the following fats and oils A, fats and oils B and fats and oils C, wherein the fats and oils of the plastic fat and oil composition contain 62% by mass or more and 85% by mass or less of the fats and oils. Oil composition.
Fat and oil A: The triacylglycerol content in which the total carbon number of the fatty acid constituting the triacylglycerol is 38 to 44 is 30% by mass to 60% by mass, and the palmitic acid content in the constituent fatty acid is 10% by mass The transesterification oil which is 35 mass% or less.
Fat and oil B: Transesterified oil having a P2O content of 18% by mass to 28% by mass and a total content of P2L and PL2 of 3% by mass to 18% by mass (however, P2O is palmitic in one molecule) Triacylglycerol with two acids and one oleic acid ester-linked, P2L is a triacylglycerol with two palmitic acids and one linoleic acid in one molecule, PL2 is in one molecule Is a triacylglycerol in which one palmitic acid and two linoleic acids are ester-linked).
Fat and oil C: Edible fat and oil whose rising melting point is 10 ° C. or lower.
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