WO2006062251A1 - Reflection preventing film having conductor layer for field emission type display, manufacturing method thereof, and field emission type display - Google Patents

Abstract

A reflection preventing film having a conductive layer for field emission type display includes a reflection preventing film on one surface of a transparent substrate and a transparent conductive layer on the other surface and has a minimal value of the ray transmission ratio in a wavelength of 440-460 nm or 530-550 nm or 560-640 nm. The reflection preventing film having the conductor layer for the FED can easily be manufactured and has an excellent reflection preventing ability and image display characteristic.

Description

 Specification

 Antireflection film with conductive layer for field emission display and method for producing the same

 And field emission display 1. Technical Field

 The present invention uses a surface-display (S ED) -containing anti-reflection film with a conductive layer for an emission-type display (F ED) and its production, and a self-prevention film with a conductive layer for the field-emission display. The present invention relates to a field emission display. 2. Background technology

 For flat panel displays, displays, and CRT displays such as liquid crystal displays, plasma displays (PDPs), and EL displays, the problem is that external light is slfed on the surface and internal visual information is difficult to see. Vsit has been known for a long time.

 In recent years, large displays have become the mainstream of displays, and PDs are becoming popular as next-generation large display devices. However, since the high-frequency pulse is generated and transmitted for the purpose of indicating this PD, there is a risk of infrared radiation that may cause malfunctions of the unnecessary n «radiation external line remote control, etc. In contrast, PDP anti-fiber film with conductive film (® «sinored window material) force S has various lines. For example, (1) a transparent film with a ^^ silver-containing conductive thin film, (2) a ^ 1 wire or a conductive | ¾ 縣 隹(3) A layer of copper foil or the like on the transparent film is etched into a net-like shape and an opening is provided. (4) Conductive (... Printed in mesh form, etc. are known.

, Surface m ^ display (SED) and m emission display (F ED) are attracting attention as displays that can display bright and high contrast, 1β; . SED is considered to be included in the FED trap. Even in such an FED, internal visual information is difficult to see due to the siting of outside light. There is a problem with that and it has been traded. In addition, the FED is considered to have the problem of electron H emission, surface charging, and the problem of light emission characteristics as well as conventional display devices.

 However, in such FED, fiber prevention, m ^, or antistatic, light emission characteristics! "As for the problem of raw correction etc., we are still in the forestry job stage! / Regarding F ED, for example, Japanese Patent Application Laid-Open No. 2 0 1-7 7 4 90 6 includes a hard coat layer, a transparent conductive layer, and a threat prevention layer on a base film. In this order, an anti-film film with a conductive H for PDP or FED that has been proposed in this order has been proposed.This anti-excitation film uses a silicon-based compound in the hard coat layer, thereby producing a low adhesion film and a high-quality film. It is supposed to have obtained.

3. Disclosure of the invention

 According to the study of the present invention group, the anti-reflection property required for the FED anti-fiber film, or the display characteristics depending on the emission characteristics of the F ED, Based on the assumption that FED emits electrons into the vacuum and collides with the fluorescent material coated on the phosphor screen, a Sit prevention film with a different structure from that required for PDP is considered necessary. From this point of view, the present invention has been studied.

 The Sit-preventing film described in Patent Document 1 is difficult to manufacture except for the film and the non-coated layer, which is disadvantageous from the viewpoint of manufacturing and is economically disadvantageous. Furthermore, it was found that this SI † -preventive film cannot be said to be efficient in terms of layer structure. In addition, improvements in the display characteristics of displays are strongly demanded as the size of the screen increases and the images become finer. In the FED, it is not necessary to shield the outside line as in the PDP, but on the basis of its appearance, since it has a display characteristic comparable to that of a conventional CRT, a higher quality display characteristic is required. Yes.

 Therefore, the present invention is easy to manufacture and prevents the 'F'

The purpose is to produce a κΐί prevention film with a guide for ED.

In addition, the present invention can be easily manufactured, and has excellent anti-fiber and anti-static display characteristics. The purpose is to create a Sit prevention film with FED guide mi! ^.

 It is another object of the present invention to provide a t method for an anti-fiber film for FE D having the above-mentioned excellent characteristics.

Still another object of the present invention is to provide an m-emitting display that is bonded to the surface of a ¾f-preventing film force image display glass plate with a conductive mi for a raw m-emitting display. And According to the study of the present invention group, the anti-filament film with anti-static for FED has, for example, an anti-destructive film as required for PDP, a single-wave blocking layer, and it is not necessary to ensure anti-static. On the other hand, it became clear that unique emission characteristics were required. As a result, we found that it can be easily removed and has a unique layer structure for FED. In addition, as described above, since it has a display characteristic comparable to that of a conventional CRT on the basis of ¹ fit, higher display characteristics are required. By introducing pigments and / or facial latencies into specific layers that make up the Hi-preventive film, light in a specific wavelength range is reduced! We found that the display characteristics of F ED ["raw (contrast, color tone, brightness, etc.) power S] improve significantly by setting ¾1 rate. In addition, by reducing the ¾ «1 rate in a specific wavelength range, it is possible to obtain a display light having a light emission distribution that matches the life of the human eye ¾ ^ I saw that it improved dramatically. Therefore, the present invention (first aspect)

An anti-fibrous film is provided on one surface of the transparent basket, and a transparent conductive layer ^{s is} provided on the surface of », and 4 4 0 to 4 60 nm, 5 3 0 to 5 50 nm and 5 6 0 to 6 4 O Light in at least one wavelength range of nm! An anti-St film with a conductive layer for a release-type display, which is based on the fact that it has a straight line of rate; and

One transparent male fiber preventing film is provided on the surface of the transparent electrically m force ^s provided another transparent retaining on one surface, two transparent爵反is Genkoku IX is layered岍铖Ϋ, which are bonded to each other via a pressure-sensitive adhesive layer, and are 4 4 0 to 4 60 nm, 5 3 0 to 5 50 nm and 5 6 0 to 6 4 O nm Have a value of ¾d, a value in at least one wavelength range of It is in a protective film with field effect display for the field emission type display. According to the above-mentioned invention, preferred embodiments of the anti-fibrous film (first i ^ t) with a guide m for an emission type display are as follows.

 (1) The tiif self-wavelength range is 5 60 to 6 4 O nm.

 (2) Bare skin length range force 4 at least one wavelength range of 4 0 to 4 60 nm, 5 3 0 to 5 50 nm, and 6 0 0 to 6 2 0 nm. Such a wavelength range is preferred, for the following reasons:

 Since the pixels (cells) corresponding to the black part of the display image are displayed by not emitting light, they do not show the original sufficiently deep black color. In addition, when viewing the display, there is a tendency that the external light power such as indoor lighting s the black power S gray because of the Klt on the surface and inside of the display device. For this reason, the contrast (brightness / darkness contrast) of the black image portion and the white image portion when the image is displayed on the display is lowered, and the display image cannot be adversely affected. Therefore, it is necessary to suppress Sit on external light displays. '

The three-wavelength fluorescent lamps used in many jl gardens are light that emphasizes blue (wavelength 45 nm), green (wavelength 54 nm), and red (wavelength 61 nm). However, the present inventor has found that a beautiful display image can be obtained by suppressing the inside of the display surface of light close to 3 waves. In other words, the AlfT external light on the display passes through the anti-reflection film, then reflects off the light-emitting display device of the display, and then passes through the anti-reflection film again. It is beautiful by absorbing the light of the sun on a scale! / A display image can be obtained. Therefore, it is effective to obtain a ^J H "Ku beauty Rere display image seen that lowering the 3Si ratio Te per cent Rere above words peel length.

 (3) The knitting wavelength range is 5 6 5 to 5 85 nm.

 It is thought that there is a light emission spectrum peculiar to SED that seems to be the influence of the enclosed gas around 5 75 nm, and by suppressing this, it becomes a legible display image for human eyes.

(4) The luminous efficiency; fg / Jt is 50 to 90%. This ¾ ί Nao is ^ (D On the other hand, this t !, the value of the pole / W in the upper skin length range in the range of the light f «i ratio in the wavelength range 400 to 700 nm. The ratio (ie relative ratio) ^ is generally 53-85%.

 (5) H occupant layer strength S above transparent guide m. Image display of the emission display Affixing to the surface S Easy.

 (6) The transparent lead mi or ί occupant layer contains a dye (a material) and ζ or a pigment. As a result, the light ratio of the specific wavelength range can be reduced. It is preferable to include it in the adhesive layer because it is close to the display.

 (7) The transparent lead m or ί occupant layer contains black and white and / or tetraazaporphyrin dyes. As a result, the light rate in the specific wavelength range (especially 560 to 640 nm) can be efficiently reduced.

 (8) The transparent conductive or lyophobic agent layer contains an anthraquinone dye, azo dye, quinophthalone dye or perylene dye as a dye having a conversion ratio in the wavelength range of 440 to 46011111; Contains.

 (9) The transparent conductive layer 1 or f occluding agent layer contains an anthraquinone dye or an azo dye as a dye having an average value of ¾i ratio in the wavelength range of 530 to 550 nm.

 (10) Transparent conductive © 1 or «^ The occupant layer contains a tetraazaporphyrin dye, an anthraquinone dye or an azo dye as a dye having a ϋW ratio of ftW in the wavelength range of 600 to 620 nm. I'm going. Tetraazavorphyrin dye is particularly preferred.

 (11) A tetraazaponolephyrin dye, an anthraquinone dye or an azo dye is used as a dye having a transparent conductive layer or an adhesive layer having a flat pole / W thickness in the wavelength range of 565 to 585 nm. Contains.

 (12) The transparent conductive layer, the fiber prevention layer, and the coating layer is coated. The inertia is improved. Economically 辩 u. Even if the transparent conductor m is painted; r®, it is difficult to obtain an anti-static function with an m-emitting display.

(13) The anti-fiber film is a film including a hard coat layer formed by coating, and a high refractive index layer formed by coating having a higher refractive index than that of the no coat layer provided thereon. Paint: τϋ, ^- With an emissive display, a sufficient lf prevention effect is likely to be obtained.

(14) The surface resistance value is 108Ω or less, especially in the range of 10 ⁵ to: 10 ⁸ Ω, especially 10 ⁶ to: 10 ⁸ Ω / mouth. In the S-emission type display, a conductive layer with a relatively high fiber size can provide a sufficient antistatic function.

 (15) The lightness index satisfies-3-a * 3 and-2-b * 10 Display special I "raw, especially the color tone is good.

 (16) The prevention film is a film including a hard coat layer formed by coating, and a high refractive index layer formed by coating having a higher refractive index than that of the no coat coating provided thereon.

 (17) Transparent film is plastic film (or PET). Continuous use is possible by using a long film.

 (18) A release sheet force is provided on the adhesive layer. Handling is easy.

 (19) The rate is more than 50% or more than 70%. The image on the display is easy to see.

 (20) The visible transmittance is 70% or more (preferably 80% or more).

 The present invention also provides

 An m-emission display guide m is provided with an orchid prevention film on one surface of the transparent male, a transparent conductive force s on the surface of the »male, and a visual recognition rate of 70% or more. A stop film; and

 Two transparent sickles, one transparent male with an anti-fibrous film on one surface and one transparent transparent m on the other surface. With a guide for field emission display, characterized in that the surface is bonded to each other via an adhesive layer and has a il recognizable conversion rate of 70% or more. Also on st prevention film.

 The self-preferred t (1) to (19) can also be applied to the above-mentioned anti-fiber film with guide. Note that the visual recognition rate is the ratio of the luminous flux (Φ and the luminous flux (Φ i) entering the Sli prevention film Φii) (Φ¾ / Φϋ).

The above-mentioned Sli-preventing film with a guiding US for an emission display according to the invention can be obtained from 辩 IJ by the following manufacturing method. That is, an anti-wrinkle film is formed on one surface of the transparent ¾fg by a coating method, and then on the surface of »

(Preferably containing a pigment desiccant) and / or a flag family) A transparent guide m is formed by a coating method, and the fed ratio of the light ratio is adjusted to a wavelength range of 5 60 to 64 0 nni. A method for producing an anti-fibrous film with a conductive mil for an m-emitting display comprising; and

One transparent mugwort which fiber preventing film is provided on the surface, on one surface (^ Mashiku dye (¾ charge) and z or new枓containing) transparent ®i force ^s provided another transparent flame The two transparent substrates are destroyed by layering, and the surfaces are opposed to each other through the pressure-sensitive adhesive layer. A method for producing a protective film with a guide for an emissive display having a rate of fJ in the wavelength range.

 According to the above method, it is preferable to form a pressure-sensitive adhesive layer further containing agility and / or dye on the transparent guide m by a coating method.

 In the above production, it is encouraging that the formation of the anti-reflection film and the transparent conductive layer and the occupant layer are all performed by coating. In addition, it is particularly preferable to apply sii prevention month and transparent coating using UV curable resin.

 Furthermore, a prevention film with a guide for a discharge type display which has a visibility of 70% or more according to the invention can also be obtained in the same manner by the above-described production.

 Further, the present invention is also a field emission display in which a sit prevention film with a guide m for m emission display is bonded to the surface of an image display glass plate. In addition, according to the study of the present invention, the anti-fiber film with the conductive S for FED, as described above, has the Si prevention property required for the PDP, the skin shielding film or the layer ensures the antistatic property. Therefore, it was found that good electromagnetic wave blocking or antistatic properties can be obtained with a unique layer structure for FED that can be obtained by a simple method.

 Therefore, the present invention (second aspect)

An anti-fibrous film is provided on one surface of the transparent male, a transparent conductive force S is provided on the surface thereof, and the surface resistance value is 10 ⁸ Ω / mouth or less. With Sit prevention film; and

Two transparent sickles, one transparent male with an anti-fibrous membrane on one surface and another transparent rod with one transparent surface on one surface, the word IX has a layer strength s. Anti-reflection with conductive layer for field emission display, which is a laminate formed by sandwiching the surfaces, and having a surface roughness value of 10 ⁸⁰ / b or less Also on film.

 In the present invention, the anti-fibrous film with a lead-to-release display for use in a display according to the present invention

SHt is as follows.

(1) The surface resistance value is in the range of 10 ⁵ to: 10 ⁸ Ω / mouth, particularly in the range of 10 ⁶ to 10 ⁸ Ω in the mouth. »With an emission display, an anti-static function can be obtained with a relatively small size.

 (2) The translucent mi is paint: Εϋ. With a conductive coating, it is easy to obtain a sufficient antistatic function for a release-type display.

 (3) Transparent conductive material 1 is a coating in which a conductive particle force S of a compound is dispersed in a polymer. By conducting such coating, a sufficient antistatic function is easily obtained.

 (4) Transparent conductive film is a conductive polymer coating layer. By conducting such coating, it is easy to obtain a sufficient antistatic function.

 (5) Prevention The S contains at least one coating layer. Even with painting, it is easy to obtain a sufficient Sli-preventing effect in the emissive display.

 (6) The prevention month is a film including a hard coat layer formed by coating, and a high refractive index layer formed by coating having a higher refractive index than the hard coat coating layer provided thereon.

 (7) Transparent male is plastic film 0; child or PET). Continuous production is possible by using a long film.

(8) On the transparent guide m®, d occupant layer strength ^{s is} provided. It is easy to attach to the image display surface of a remote-release display.

 (10) A release sheet is provided on the adhesive layer. Handling becomes easy.

(1 1) The light β ratio is 50% or more, preferably 70% or more. The image on the display is easy to see. The prevention film with an m guide for the m-emitting display of the above invention can be obtained by the following manufacturing method.

That is, including a step of forming an S † -preventing film on one surface of the transparent sickle by a coating method, and a step of forming a transparent lead m on the next surface by a coating method, and the surface key value is 10 ⁸ Ω / mouth or less A method of manufacturing an anti-st film with a conductive m for a field emission display;

Applying a ¾f-prevention moon-curing ultraviolet curable resin coating solution on one surface of the transparent film and forming a fiber-preventing film by manipulating the ultraviolet light, then forming a transparent conductive film on the surface. It includes an anti-reflection film with a conductive layer for field-emission displays that has a surface resistance of 10 ⁸ Ω / mouth or less, including the step of forming a transparent conductor i by applying a curable resin coating solution and curing it with ultraviolet light. A method for producing rum; and

Two transparent jars, one of which is a transparent jar with an anti-fibrous film on one surface and another transparent jar with a transparent conductive force s on one surface. A method for producing a field-emission display-preventing film having a surface resistance value of 10 ⁸ Ω or less, including a step of laminating, nailing, and pressure-bonding each other through an adhesive layer.

 Furthermore, the present invention also provides a field emission display that is bonded to the surface of an anti-fiber-resistant film force image display glass plate for an m emission display.

[The invention's effect]

 According to the first aspect of the present invention, the sit prevention film with a guide m for field emission display has a specific configuration in which a fiber prevention film is provided on one surface of the non-transparent surface and a transparent conductive force s is provided on the surface thereof. In addition, as a light source, the light n¾ rate in a specific wavelength range is set to be lowered, or the β flatness is set to a specific value or more. As a result, the display characteristics of F ED (4 (contrast, color, brightness, etc.) force S are greatly improved. In addition to these performances, the prevention function and antistatic function are also improved. .

In particular, to reduce the light ¾f ^ rate in at least one wavelength range of 44 0 to 4 60 nm, 5 3 0 to 5 50 nm and 6 0 0 to 6 20 nm as a specific wavelength range By setting to, the image quality can be greatly improved. That is, according to the examination of the present invention ^, The outside light that is Ait to play passes through the anti-fibrous film, then sits at the light emitting display device of the display and passes again through the protective film, so the blue, green, and red light emphasized by the three-wavelength fluorescent lamp It is possible to obtain a beautiful image and a display image that can be found by absorbing the water on a scale. Therefore, it is effective to obtain a beautiful and beautiful display image.

 Furthermore, in particular, all layers of the protective film, transparent conductive layer, and adhesive are formed by the coating method, which can be obtained by a simple manufacturing method, and the guide for the 雕 emission type display that has excellent wall properties. It can also be said that it is a prevention Finorem.

 In addition, the second! ^ Anti-fibrous anti-fibrous film for the release-type display according to the present invention has a anti-fibrous film on one surface of the transparent ridge, a relatively high surface on the ite surface, and a transparent surface resistance value. In addition to the prevention function, it is possible to prevent shelves on the shelves and block waves even with transparent guides with a relatively high level of transparency. It becomes les. In particular, it is a prevention film with a lead-in film for m-emission display, which can be obtained by a simple dumping method by forming a precautionary film and transparent lead m by a coating method. It can also be said.

4. Brief description of the drawings

 FIG. 1 is a schematic cross-sectional view of a typical example of an anti-fiber film with a guide for FED according to the present invention.

 FIG. 2 is a schematic cross-sectional view of another example of a β-like Sli-preventing film for FED use according to the present invention.

 FIG. 3 is a schematic cross-sectional view depicting an example of a suitable film in the anti-reflective film with an F m guide of the present invention.

 FIG. 4 is a schematic cross-sectional view showing another example of a suitable key in the Sit-preventing film with FED guide mi according to the present invention.

FIG. 5 is a schematic cross-sectional view depicting another example of a preferred example of the anti-wrinkle film with a guide fl¾ for FED of the present invention. FIG. 6 is a schematic cross-sectional view illustrating another example of suitable H in the anti-fiber film with a conductive fiber for FED of the present invention.

 FIG. 7 is a cross-sectional view of an example of a field emission display occupied by a prevention finoleka with a guide m for a remote emission display according to the present invention.

 FIG. 8 is a graph showing the transmissivity of the lead-type antireflection film for emission display obtained in Male Examples 4 and 5 according to the present invention.

 FIG. 9 is a graph showing the ratio of the anti-reflection film with a conductive layer for m-emitting display obtained in Male Example 6 according to the present invention.

 FIG. 10 is a graph showing the ¾ii rate of the anti-st film with m guide for m-emitting display obtained in Example 7 according to the present invention.

 FIG. 11 is a graph showing the ratio of the anti-emission film with a release-type display obtained in difficult example 8 according to the present invention.

 FIG. 12 is a graph showing the ¾1 rate of the hit-preventing film with a lead for a release type display obtained in Example 9 according to the present invention.

5. BEST MODE FOR CARRYING OUT THE INVENTION

 The following is a detailed description of the F It-proof film with a conductive layer for FED that provides excellent display hygiene for the emission display (F ED) of the present invention.

 FIG. 1 shows a schematic sectional view of a typical example of the antireflection film with a conductive layer for FED of the first and second embodiments of the present invention. Fig. 1 shows an antireflection film 1 on one surface of a transparent substrate 1 1

3 forces s are provided, and a clear m / i 2 forces S are provided on the other surface. Another layer such as an occupant layer may be provided between the transparent film 1 1 and the protective film 1 3, or between the S light 11 and the transparent H 1 2. . '

In the first and second aspects of the present invention, a layer provided on the surface opposite to the surface provided with the anti-reflection film is coated with a layer and a z or dye material. ) This allows you to tiff light in a specific wavelength range! ¾¾i Set to decrease the rate (generally ¾d of the rate in a specific wavelength range, the value is 50 to 90% or preferably 50 to 80%, In particular, 60% to 75%), or can be set to 辩 lj rate more than a specific value. By setting in this way, the FED display characteristics (contrast, color tone, brightness, etc.) power can be significantly improved. In particular, by setting the specific wavelength range to reduce the light rate in at least one wavelength range of 440 to 460 ηm, 530 to 550 nm, and 600 to 620 nm, external light, especially three-wavelength fluorescent lamps Reduce the ratio of blue light (wavelength 4 5 Onm), green light (wavelength 54 Onm), red light (wavelength 61 Onm), and light in the external light display. It is possible to improve black and white contrast and improve image quality. The same effect can be obtained relatively easily by setting the specific wavelength range to reduce the ^ ffli rate in the 565 to 585 nm wavelength range.

 The anti-fiber film 13 is generally a composite film of a hard coat layer having a lower refractive index than that of the collar and a high refractive index layer provided thereon, or preferably a higher refractive index layer cover on the folding index layer. This is a composite film. Even if only the hard coat layer having a higher refractive index than that of the anti-reflective film 13 is used, a certain layer is a shelf even if only the low refractive index layer. It is preferable from the viewpoints of productivity and economy that all of the layers constituting the anti-fiber film 13 are formed by coating.

 In the first H-like aspect of the present invention, the transparent conductive layer is provided on the surface on the opposite side to the side on which the ff prevention film is provided as described above. As a result, it is considered that light such as light generated when the electric spring collides with the fluorescent material can be optimized and charging can be eliminated. Even with a relatively high surface resistance layer that can be obtained by coating, it is considered that the force acts on the appropriateness of light and antistatic properties. Therefore, the above-mentioned Sit-preventing film with a lead for FED is coated with a new anti-fiber coating solution on one transparent surface, and $ (cured), and the surface for the next layer is coated with a transparent conductive film. It can be obtained easily and economically by coating and $ (curing) the working solution.

The antireflection film with a conductive layer for FED of the second embodiment of the present invention having the configuration shown in FIG. 1 has a surface resistance value of 10 ⁸ or less, preferably 10 ² to: in the range of L 0 ⁸ Ω, particularly 10 ⁶ ~: L 0

Has surface key value in the range of ⁸ Ω Higuchi. The transparent conductive mil 2 of this film is generally a conductive coating, for example, conductive particles of 匕 ^^) in the polymer. It is a coating or conductive polymer coating. The anti-filament film with a conductive mii for FED of the present invention has the above-mentioned 3 composition. The Sli prevention film 13 is the same as described above.

 Similarly to the first carrying, the second bag of the present invention also has a structure in which the transparent guide m is provided on the surface opposite to the side on which the m prevention film is provided as shown in FIG. . As a result, it is considered that the generation of electrification caused by the collision of the electric current with the fluorescent material can be eliminated by {}. In addition, it is considered that even a layer having a relatively high surface value obtained by coating will act effectively. Therefore, the anti-Si film with FED guide I is applied to one surface of the transparent substrate with anti-reflective S Shinshiro coating solution and dried, and then on the other surface for forming transparent guide m. It can be obtained easily and economically by applying and applying a coating solution.

 FIG. 2 shows a schematic cross-sectional view of another typical example of the antireflection film with a conductive layer for FED of the first and second embodiments of the present invention. In FIG. 2, the anti-fiber film 2 3 force S is provided on one surface of the transparent substrate 2 1 A, and the transparent guide 2 2 force S is provided on one surface of the transparent male 2 1 B. The transparent males are wrinkled through the adhesive layer 24 with the fiber-preventing MX facing the surfaces where the transparent conductive force S is not formed. The anti-fiber film with F m guide for FED having such a structure is prepared by preliminating the transparent male 2 1 A provided with the anti-fiber film 2 3 force S and the transparent 1 B provided with the transparent guide force S, Since it can be obtained by performing these at a desired time, there is an advantage that the degree of freedom of manufacturing is expanded.

 The surface on the side opposite to the surface with the anti-fibrous film is provided with a transparent conductive material © I 2 2 and an occupant layer 2 4 force. , V, misalignment, or re, are set to reduce the rate of specific wavelengths within a specific wavelength range by, for example, dispersing materials and / or pigments in both layers, or a specific value. Setting power to the above flat rate can be done in ¾ ^ IJ, which makes it possible to make the display characteristics (contrast, color, brightness, etc.) of the FED exceptional. In addition, it is preferable that the transparent layer is made to have flag material and Z or pigment from the adhesive layer because it is used as a display for FED.

The first sickle with the FED guide m with the structure shown in Fig. 2 is also transparent with ^ 1 † prevention film 2 3 »2 1 A, transparent guide © I Transparent 2 1 B There is an advantage that the degree of freedom of manufacturing is expanded because it can be obtained by pre-decision and applying these to the desired three tides.

 FIG. 3 shows a third cross-sectional view of a saddle cross-section depicting an example of ^ imt in the first and second FED guides for Sit-preventing finolems of the present invention. In FIG. 3, a g¾ prevention film 3 3 comprising a transparent coating 31, a high-refractive index layer 36, and a refractive index layer 37 is sequentially provided on one surface of the transparent screen 31. The light guide layer 2 and the adhesive layer 3 4 are provided in the order of force S. Thus, the Sit prevention film 13 composed of three layers shows a high prevention function. In addition, since the adhesive layer 34 is provided, it can be easily attached to the image display surface of the 1 ^ emission type display. The pressure-sensitive adhesive layer may not be provided.

 What is the surface on which the anti-oxidation film is provided?

3 4 power is provided, the first! In ^, it is set to reduce the rate of the specific wavelength range of the self by dispersing pigments and / or dyes in the layer, the misalignment, or both layers. The power to set the network rate of s 辩 ij, and get. As a result, the display characteristics 14 (contrast, color tone, brightness, etc.) of FE D can be markedly improved. In FIG. 3, it is preferable that the transparent layer S has an impact and a Z or pigment is applied to the pressure-sensitive adhesive layer because it is displayed on the FED display screen.

 In the second sickle according to Fig. 3 as well as the first scissors, the ^ f-preventing film 1 3 composed of three layers exhibits a high level of wrinkle-preventing function and the adhesive layer 3 4 force S Because it is provided, it is easy to attach the emission display to the image display surface.

FIG. 4 shows a schematic cross-sectional view of another example of the preferred H example in the anti- orchid film with FED 1) of the first and second ridges of the present invention. 3 is different from FIG. 3 in that it consists of two sheets spread through the adhesive layer 4 4, as shown in FIG. In Fig. 4, a transparent P hard stop 4 4 A force S is provided on one surface of 1 A, and a transparent layer 4 1 B is provided on one surface with a clear TO 4 2 and an adhesive layer 4 4 B force S is provided, and these two transparent ridges are crushed through the pressure-sensitive adhesive layer 4 4 A so that the fiber prevention X is formed with a transparent transduction force S and the surfaces are opposed to each other. ing. The orchid prevention film 4 3 provided on one surface of the transparent film 4 1 A is a 11 body in which a first coat layer _{4 5} , a high refractive index layer ₄ 6 and an O¾g refractive index layer 47 are provided in this order. . What is the surface on which the sit-prevention film is provided?

4 4 A, 4 4 B forces S are provided, and in the first H ^, at least one of these layers, for example, 廣 枓 and Z or 辦 to It can be advantageously obtained that the ratio of light intensity in the wavelength range is set to be lowered, or that the ratio is set to a net ratio higher than a specific value. As a result, the display characteristics of FED (contrast, color tone, brightness, etc.) can be markedly improved. In the present invention, it is preferable that the transparent conductive material 14 2 and the O-occlusion agent layer 44 B have a pigment, Z, or a dye to produce a display image of force FED. In particular, it is preferable that the pressure sensitive adhesive layer 4 4 A be agile and / or have a pigment Λ, since it is most suitable for the display rain of FED.

 FIG. 5 shows a schematic cross-sectional view of another example of the preferred embodiment of the antireflection film with a conductive layer for FED of the first and second embodiments of the present invention. In FIG. 5, on one surface of the transparent substrate 51, an anti-fiber film 5 comprising a coating layer 55, a high refractive index layer 5 6 and an mSIS refractive index layer 5 7 is formed.

Three powers are provided, and on top of that, 9-force swords are formed, and the surface of »is transparent.

5 2, Adhesive layer 5 4 and release sheet 5 8 Since the release sheet 48 is provided on the pressure-sensitive adhesive layer 54, it is easy to handle and can be appropriately attached to the image display surface of the release type display. The finolem shown in FIG. 5 has the same effect as described in FIG.

 FIG. 6 shows a cross-sectional view of another example of a preferred embodiment of the antireflection film with a conductive layer for FED according to the first and second embodiments of the present invention. It differs from FIG. 5 in that it consists of two sheets of transparent fiber 5 1 force with an adhesive layer 6 4 A as shown in FIG. In Fig. 6, transparent support 6 1 A is provided with anti-wrinkle film 6 3 force S on one surface and transparent fiber 6 1 B on one surface with i ^ S light guide TO 6 2 and adhesive layer 6 4 A B force S is provided, and these two pieces of transparency are glazed through an adhesive layer 6 4 A with the Sit-preventing X facing each other on which no transparent conduction is formed. The anti-fibrous film 6 3 provided on one surface of the transparent ridge 6 1 A is a knitted body in which a coating layer 65, a high refractive index layer 6 6 and an IHS refractive index layer 6 7 are provided in this order. . A protective layer 6 9 force S is further provided on the orchid prevention film 6 3.

On the surface opposite to the threatened surface provided with the orchid prevention film, as in Fig. 4, the transparent conductor «H6 2 and 3 Adhesive layers 6 4 A, 6 4 B force S are provided, and in the first case, for example, by dispersing soot and / or dyes in at least one of these layers, Setting to reduce the light intensity ratio in a specific wavelength range, or setting the light intensity ratio to a specific value that is greater than a specific value, can be set to IJ. As a result, the same effect as in Fig. 4 can be obtained. Transparent guide 6 2 and O Occupant abuse 6 4 B, in particular, it is preferable to let the adhesive layer 6 4 B have soot and / or dye.

 The anti-fiber film, transparent conductor, pressure-sensitive adhesive layer and the like of the present invention are preferably formed by coating. In particular, the anti-transparency transparent translucent m makes a sii-prevention finolem with high productivity and high productivity by applying and curing in a continuous manner using UV curing. Such a film or layer can be formed on a transparent film (generally a film or a sheet) or a continuous film on a transparent film, or on a continuous film. In the present invention, each layer is formed in a continuous manner, and generally in the form of Ronole-Touronore: In the present invention, the latter is particularly preferred.

 The materials used for the conductive sii prevention film for m-emitting display of the present invention will be described below.

Transparent, as the material thereof is not particularly limited as long as it is transparent (meaning "transparent to visible light".) Are Hirugaesa plastic film strength ^s in ~ «. For example, polyester {eg, polyethylene terephthalate (PET), polybutylene terephthalate}, polymethylol methacrylate (PMMA), attalinole resin, polycarbonate (PC), polystyrene, triacetate resin, polyvinyl alcohol, polychlorinated bur, poly Examples include vinyl chloride, polyethylene, ethylene monovinyl copolymer, polyvinyl butyl butylal, ionethylene monomethacrylic polymer, polyurethane, and cellophane. Among these, polyethylene terephthalate (PET), polycarbonate (PC), polymethylmetal phthalate are highly resistant to processing loads (heat, ^ IJ, bending, etc.) and particularly highly transparent. Rate (P 匪 A) is preferred. In particular, it is preferable because the PET power refractive index is high.

As for the thickness of unpleasant Si lucidum, it is the S emission prevention display std film Generally, it is 1 ^ m ~ 5mm @ ¾ force element, though it depends on the application.

The transparent conductive TO of the present invention has a surface of the resulting prevention film for the emission type display 1 with a surface of generally 10 ⁸ Ω inlet, preferably in the range of 10 ² to 10 ⁸ Ω / port, particularly It is set to be in the range of 10 ⁵ to 10 ⁸ Ω / mouth, even power, but 10 ⁶ to 10 ⁸ Ω. The transparent guide m is preferably a paint, but it may be a layer obtained due to difficulty in the play. It can be made thinner than usual. It may also be a grid-like guide m such as ^ !. Further, it may be an alternating film of a film of ^ S acid such as ΙΤ〇 and a ^ s layer of Ag or the like (eg, a laminate of ITO / silver / ITO / silver ZlTO).

 The transparent conductor m is preferably a coating dispersed in the polymer with a conductive particle force s of the compound compound oi.

 Examples of conductive particles) include anoreminium, nickel, indium, chromium, gold, nonadium, tin, cadmium, silver, platinum, copper, titanium, cobanoreth, lead, etc. Alloy; or, ITO, indium oxide, tin oxide, oxidation port, indium tin oxide (ιτ〇, so-called indium dorf i 匕 tin :), acid-tin-acid-antimony (ATO, so-called Antimony monotin], conductive oxides such as aluminum oxide (Z AO; so-called aluminum dough: ffif port), etc. In particular, ITO is preferred. ^ ί 圣 is 10 ~: L 0000nm, especially 10 ~ 50nm.

 Examples of the polymer include acrylic resin, polyester resin, epoxy, f fat, urethane resin, phenol resin, maleic acid resin, melamine resin, urea resin, polyimide resin, and silicon-containing resin. Further, among these resins, an f! S-forming resin is preferable.

 In some cases, it is particularly preferable that the polymer is an ultraviolet curable resin that is shelved on the hard coat layer to be described later.

The formation of the transparent conductive material 1 by the above-mentioned coating is carried out by mixing the above-mentioned conductive particles with a mixture of the above-mentioned conductive '1¾¾ particles in the polymer application). Coat on transparent, and heat and cure as appropriate. By using a thermoplastic resin, the vehicle can be The rehabilitation type cocoon can be obtained by 喿. In the case of using an ultraviolet curable resin, it can be obtained after coating by drying as necessary and irradiating with ultraviolet light.

 The thickness of the transparent conductive layer formed by coating is preferably 0.1 to 5 μπι, particularly 0.05 to 3 μπι. If the density is 0.001 μπι * drops, the antistatic function may not be sufficient, while if it exceeds 5 μπι, the transparency of the resulting finolem may be reduced.

 The transparent conductive ms of the present invention is also preferably a conductive polymer layer formed by coating. For example, hydrocarbons such as polyacetylene, polyphenylene, polyphenylene vinylene, polyacene, polyphenylacetylene, polynaphthalene; polypyrrole, polyaniline, polythiophene, polyethylene vinylene, polyazulene, polyisothianaphthene, etc. Mention may be made of a polymer containing an atom. Polypyrrole and polythiophene are preferred. The thickness of the light conductive layer of the conductive polymer is preferably from 0.01 to 5 μm, particularly preferably from 0.05 to 3 to 111. If ttJlBW is less than 0.0 1〃ιη *, the antistatic function may be insufficient. On the other hand, if it exceeds 5 μm, the transparency of the resulting film may be reduced.

The age at which the transparent conductor m is formed due to difficulty, and its form of play is not particularly limited. Power snouting, ion plating, electron beam evaporation, vacuum evaporation, chemical vapor deposition, etc.

Examples include printing and coating, but vapor phase deposition (sputtering, ion plating, electron beam deposition, vacuum deposition, chemical vapor deposition) is preferable. A transparent guide m can be formed using a »f compound of self. When the transparent conductor m is formed with difficulty, the layer thickness is preferably 30 to 5 0 0 0 0 η m, especially 50 nm lit.

 An additional ^! Plating layer may be provided on the transparent conductive TO to improve conductivity. The metal plating layer can be formed by the mouth ¾ * plating method and the non-¾ plating method. As males to be divided into meshes, it is possible to shelf copper, copper alloy, nickel, anolemi, silver, gold, iron & tin etc., preferably copper, ^^ gold, silver, Or nickel, and in particular, from the viewpoint of economy and conductivity, it is preferable to use copper or a copper alloy.

As the transparent conductive TO, a »-shaped (mesh-shaped) conductive layer may be used. This makes the surface resistance Anti value is extremely reduced (typically 1 ⁰ 0 ~1 0- ² ΩΖ port). This: ^ is usually introduced into the adhesive layer.

 The mesh-shaped lead mi is made of ^ ϋ »Ι¾Ό ^ covered organic! ^ In a net-like shape, on a transparent film © I layer of the same foil, etc. is etched into a net-like shape, with an opening, transparent Conductive material on the film [· raw ink printed in mesh form, etc.] can be mentioned. Mesh-like guide ^^, and / or mesh as organic mesh! It is preferable to have a diameter of 1 m to 1 mm and an aperture ratio of 50 to 90%. The more preferred ratio is 10 to 500 / m, and the aperture ratio is 60 to 90%. Note that the opening ratio of the conductive mesh refers to the ratio of the opening portion occupied by the projection B¾ of the conductive mesh.

 ^ ¾ Male t¾u ^ Coated f fibers constituting the conductive mesh include copper, stainless steel, aluminum, nickel, titanium, tungsten, tin, lead, iron, silver, carbon or alloys thereof, Preferably, copper, stainless steel, aluminum force S is used. Polyester, nylon, vinylidene chloride, aramid, vinylon, cellulose, etc. are used as the organic coating material for male coated organic resin.

 The pattern of conductive foil such as metal foil, and the age of the copper, copper, stainless steel, aluminum, nickel, iron, brass, or alloy of these, preferably copper, stainless steel, aluminum Used.

 ^^ If the thickness of the foil is too thin, it will be unfavorable in terms of handling and n-type of pattern etching. If it is too thick, the thickness of the glass will be affected, and the etching process will take a long time. Therefore, it is 1 to 2 0 0 ^ 111 @ ¾.

The shape of the etching pattern is not particularly limited. For example, a lattice-shaped metal foil having a square hole formed therein, a circular, hexagonal, triangular or elliptical hole metal S formed with a punching metal-like metal foil, etc. Is mentioned. In addition, the holes are not limited to those arranged in a row, but may be a random pattern. Of this ^ M foil

Preferably, it is between 0 and 90%.

Alternatively, the mesh-shaped conductor ¾ is conducted to a transparent sickle! "It may be formed by pattern printing raw ink. Using the following conductive ink, screen printing method, inkjet printing method, static It can be printed on the surface of transparent s¾ by electroprinting method or the like.

 The ^ It prevention film of the present invention is generally a composite film of a hard coat layer having a higher refractive index than that of the substrate and a folding layer provided thereon, or preferably a higher refractive index on the folding layer. It is a composite film with layers. The wrinkle-preventing film is effective only with a high refractive hard coat layer having a higher refractive index than with a wrinkle or only with a low refractive index layer. If the refractive index of the substrate is low, a composite film consisting of a hard coat layer having a lower refractive index than that of the substrate and a highly flexible layer provided thereon, or a lower refractive index on the high refractive index layer. It may be a composite film provided with a stratified force s.

 The fiber-reinforced P-preventive film (first «) for the release-type display obtained by the present invention has an excellent display image of the release-type display held on the surface of the image display glass plate. In order to obtain light ^ tttt (¾ brightness, high contrast and vivid color tone), for example, the transparent guide or layer of the present invention, 〖occupant layer, pigment, pigment) This ^ I † -preventing Finolem itself is at least one wavelength range of 440 to 460 nm, 530 to 550 nm and 560 to 640 nm, and † SJ, value (M or 50 to 90 %, More preferably 50 to 80%, particularly preferably 60 to 75%), or a label has a visual recognition rate of 70% or more (preferably 80% or more, particularly preferably 90% or more). Has been.

As a preferred contribution, it has a rate pole / W ratio (preferably 50 to 90%, more preferably 50 to 80%, particularly preferably 60 to 75%) in the wavelength range of 560 to 640 nm. As another preferred rate, the wavelength range is 440 to 460 nm, 530 to 550 η m and at least one wavelength range of 600 to 620 nm, and the light% ¾rate ¾J, value or 50-90% And more preferably 50 to 80%, particularly preferably 60 to 75%). The light emission spectrum from the display is not only blue, green and red, but also a lot of light of other wavelengths, but the upper fB? it can. This is probably because of the following reason. In other words, since the pixels (cells) corresponding to the black portions of the display image are displayed by not emitting light, they do not show the original sufficiently deep black color. In addition, when actually viewing the display, ί! ¾ tends to become blackish gray because external light such as indoor lighting is slf on the surface and inside of the display device. For this reason, the contrast (brightness / darkness contrast) between the black image portion and the white image portion when the image is displayed on the display decreases, and the adverse effect on the display image cannot be ignored. Therefore, it is necessary to suppress the fineness of the external light display. “^ Three-wavelength fluorescent lamps shelves in the garden are light that emphasizes blue (wavelength 450 nm), green (wavelength 540 nm), and red (wavelength 61 nm). The present invention binding has found that it is possible to obtain a beautiful display image power S by suppressing it inside the display surface of light close to 3 waves. After passing through the anti- ^reflective film, ^{sit on} the light emission surface of the display and then pass through the protective film again. It is possible to obtain a beautiful display image that can be found by absorbing it into the eyelids, and therefore, it is effective to obtain a beautiful display image that can be seen to reduce the heel rate in the upper skin length.

 Such characteristics can be obtained by appropriately combining the protective film, the transparent conductive layer, and the pressure-sensitive adhesive layer with materials, etc., without including a parent material, a dye, and the like. be able to. The above-mentioned light H¾ ratio is the ¾i ratio of viewing light (wavelength II region 400 to 700 nm), and the average light ratio in the visible region is generally 50% or more, preferably 60% or more, particularly preferably 70% or more. is there. Also, ¾J, the half-value width in value is generally 20 to: 1550 nm, preferably 20 to 100 nm.

 In addition, the top f self-recognition, ¾1 rate is the light flux (Φ ί) and alt on the anti-film with ¾f anti-finolem in visible light H (¾; S! G 400 ~ 700 nm) shell area (The ratio of ΦΩ to (refers to Φ ΐΖΦ.

Examples of pigments and dye drying agents used above include black pigments such as carbon black and iron black; porphyrins, tetraazaponorphyrins, squaryliums, azomethines, cyanines, talented xenonors, Mention may be made of anthraquinone, xanthene, xenonor, azo or benzylidene dyes and chromium complexes. The amount of these parent materials and pigments is 0.1 to 5 mass ^0, preferably ⁰ . ~ 1 mass _^0/0.

In order to have the value of light f ii rate in the wavelength range of 560-640 nm; ¾ / J, the wavelength is 5 60η n! It force ^s preferably comprises a dye having an absorption maximum in the range of ~ 640 n m. As such a dye, a porphyrin-based, tetraazaporphyrin-based, cyanine-based, squarylium-based, azomethine-based, xanthene-based, oxonol-based, or azo-based compound is preferably used. Wavelength is 560 ηπ! Examples of dyes having absorption wrinkles in the range of ˜640 nm are shown below.

 (b2)

 (b3)

CHCH ₂ CS (¾

COO £ iO / SOOZdT / X3d TSii90 / 900i OAV

(1 2)

(b 1 3)

In the present invention, tetraazaporphyrin-based dyes (for example, the above-mentioned dye b-1 2) and porphyrin-based dyes (for example, the above-mentioned dye b-1 3) are particularly preferable.

 A dye having a wavelength range of 6 00 to 6 20 nm can also be appropriately selected from the above examples. Tetraazavorphyrin-based dyes are preferred. Specifically, for example, Taza P-10 (tetraazaporphyrin-based dye) (maximum wavelength of light absorption: 6 10 nm; manufactured by Yamada Chemical Co., Ltd.) can be mentioned.

Examples of the dye having a wavelength range of 44 to 460 nm include anthraquinone dyes, azo dyes, quinophthalone dyes, and berylene dyes. Specifically, for example, CI Solvent Yellow dye (light absorption maximum wavelength: 4500 nm; manufactured by Hodogaya Chemical Co., Ltd.) Can be mentioned.

 Examples of the dye having a wavelength range of 530 to 50 nm include anthraquinone dyes and azo dyes. Specifically, for example, Ade force Arcles TY-2 3 5 (light absorption maximum wavelength: 5400 nm; manufactured by Asahi Denka Kogyo Co., Ltd.) can be mentioned.

 Dye in the wavelength range of 5 6 5 to 5 85 nm can also be appropriately scaled from the examples of dyes in the wavelength range of 5 6 0 to 6 40 nm. Examples thereof include anthraquinone dyes, azo dyes, tetraazaporphyrin dyes, and the like. Specifically, for example, tetraazaporphyrin-based dye TAP-5 (light absorption wavelength: 575 nm; manufactured by Yamada Chemical Co., Ltd.) can be mentioned.

 Examples of the coating layer include an acrylic resin layer, an epoxy resin, a fat layer, an ureta fat layer, a silicon mono / grease layer, and the thickness thereof is usually 1 to 50 m, preferably 1 to 10 ^ α m. Either a saccharifying resin or an ultraviolet curable resin may be used, but an ultraviolet resin is preferred.

 Examples of the curable resin include phenol resin, resorcinol resin, urea resin, melamine resin, epoxy, fat, acrylic resin, urethane resin, furan resin, and silicone resin.

Examples of UV curable resins (monomers and oligomers) include 2-hydroxychetinore (meth) acrylate, 2-hydroxypropinole (meth) acrylate, 4-hydroxy butyl (meth) acrylate, 2-ethyl hexylole polyethoxy (Meth) acrylate, benzyl (meth) acrylate, isobornyl (meth) acrylate, phenyloxy til (meth) acrylate, tricyclodecane mono (meth) acrylate, di-cyclopentenyl xylate (meth) acrylate, Tetrahydrofurfuryl (meth) acrylate, acryloylololin, N-vininole power prolatatam, 2-hydroxy-3-phenyloxypropyl (meth) acrylate, 0-phenylphenyloxychetyl (meth) Chryrate, neopentyl glycol di (meth) acrylate, neopentyl glycol dipropoxydi (meth) acrylate, neopentyl glycol di (meth) hydroxypivalate di (meth) acrylate, tricyclodecane dimethylonoresi (meth) acrylate, 1, 6 Monohexane; ^ Luji (meth) attalylate, Nonanediol di (meth) acrylate, Trimethylone propane tri (meth) acrylate, Pentaerythritol ^ / Tri (meth) acrylate, Pentaerythritole tetra ) Atalylate, Tris [(Meth) finished cryokischechinore] Isocyanurate, Ditrimethylolpropane tetra (meth) Atallate, etc. (Meth) Atalylate monomer ^ ¾, Poly (eg, ethylene glycol, propylene Gliconole, Neopentinoleglycol, 1, 6—Hexanedi, 1—Methyl-1,5—Pentanediol, 1,9—Nonandi; ^ Nole, 2-Ethyl-2-Butinole 1, 3_Propanedionol, Trimethylonorepronone, Diethylene glycol, Dipropylene Ricohanol, polypropylene glycolol, 1,4 dimethylol / recyclohexane, bisphenol A polyethoxydiol, polytetramethylene daricool polyol, flit self-polyols and succinic acid, maleic acid, itaconic acid, Most of adipic acid, 7_K-added dimer acid, phthalano, isophthalano, and terephthalano are polyester polyols, © ίΐΒ polyols, and ε-strength prolactones that are examples of these τκ compounds. Poly-strength polylatones, 151-poly; ^ and t & t-sel, multi-: ^ are those with ε-strength prolactone, polycarbonate polyol, polymer polyol 1) and organic polyiso Cyanate (eg, tolylene diisocyanate, isophorone diisocyanate, xylylene diisocyanate, diphenol Norethane 4,4'-diisocyanate, di-cyclopentaninoresiocyanate, hexamethylene diisocyanate, 2,4,4'-trimethylhexamethylene diisocyanate, 2, 2 and 4-trimethyl Xamethylene diisocyanate, etc.) and hydrated (meth) acrylate (eg, 2-hydroxyethyl (meth) acrylate, 2-hydroxypropyl (meth) acrylate, 4-hydroxybutyl (meth) acrylate 2-Hydroxy-3-Phenenyloleoxypropyl (meth) Atalylate, Cyclohexane 1,4-Dimethylol Mono (meth) Atalylate, Pentaerythri Tonorethri (meth) Atalylate, Pentaerythri Tonole Penta (meth) Atallate, Dipentaerythritol Tall Hexa (Meta) Ata Rate, grayed Riserinji (meth) Atari rate, etc.) of those in which the polyurethane (meth) Atari rate, bisphenol A type Epoki, # fat, bisphenol F type Epoki: ^ # Bisufueno one Norre of butter, and the like (Meth) acrylate oligomers such as bisphenol type epoxy (meth) acrylate, which is a product of type epoxy, fat and (meth) acrylo ^. These compounds can be used as a mixture of two or more. Particularly preferred is a mixture of urethane acrylate and acrylate monomers. These ultraviolet curable resins can be used as f¾M individual resins together with thermal synthesis.

 In order to form a coating layer, among the above UV curable resins (monomers and oligomers), pentaerythritol teroretri (meth) acrylate, pentaerythritol penta (meth) acrylate, dipentaerythritol hexa (meth) acrylate, etc. It is preferable to hesitate mainly with hard multi-monomers.

 Any compound suitable for the properties of the UV curable resin can be used as the UV cure. For example, 2-hydroxy-1,2-methyl-1,1-phenylpropylene, 1-one, 1-hydroxy hexyl ketone, 2-methylolene 1- (4- (methylthio) phenolinole) 1-2, monorefori Acetofenones such as Nopropane-1, Benzonoresmethinoreketanol and other Benzoines, Benzophenone, 4-Benzenolebenzophenones, Benzophenones such as hydroxybenzophenones, Isopropinoxanthone, 2-4 -Thioxanthones such as Jetylthioxanthone, and other special products such as methylphenyldoxylate can be used. Particularly preferably, 2-hydroxy-2-methyl-1-monopropanepropane 1-one, 1-hydroxycyclohexyl phenyl ketone, 2-methyl-1-one (4- (methino) phenyl) one 2-morpholinopropane mono 1, benzophenone and the like. These photopolymerizations can be carried out by using one or more conventional ^ {adducts such as benzoic acids or tertiary amines such as 4-dimethylenoaminobenzoic acid, if necessary. Can be mixed and used at a ratio of Moreover, it can be carried out by mixing one kind or two kinds or more of photopolymerization cleavage ^ alone. In particular, 1-hydroxy hexyl phenyl ketone (Chipa Specialty Chemicanores, Neno Inregacure 18 4) is preferable.

The amount of ¾S cleavage ^ is 0.1 to: L 0 mass ^0, preferably 0.1 to 5 mass%, based on the resin yarn. The coating coat layer has a lower refractive index than transparent males. S It is preferable to obtain a refractive index lower than that of sickle by using the above UV curable resin. Therefore, it is preferable to use a material with high refractive index, such as PET, as a transparent film. Therefore, the node coat layer preferably has a refractive index of 1.60 or less. MJ ¥ is as shown in ΙϋΙ3.

The high refractive index layer, the polymer frame properly ultraviolet curing resin) in, Ι ΤΟ, ΑΤΟ, S b 2 〇 _3, S B_〇 _2, I n ₂ 〇 _3, Sn_〇 _2, ZnO, and A l it is preferable that the doped ZnO, T i 0 conductive麵酸of glue救粒Ko匕合of such ₂₎ force ¾ ^ layers. Oxidized rice is preferably 10 to 10000 nm, preferably 10 to 50 nm. In particular, ITO having a particle size of 10 to 50 nm is preferable. It is preferable that the refractive index is 1.64 or more. Is generally in the range of 10 to 500 nm, preferably 20 to 200 nm.

 In addition, since the high refractive index layer is derived, by setting the refractive index of this high refractive index layer to 1.64 or more, the minimum ratio of the surface ratio of the anti-fiber film can be made within 1.5%, 1. 69 or more, preferably 1.69 to: 1.82, the minimum surface reflectance of the Sit prevention film can be made within 1.0%.

It is preferable that the coating layer has a visible ¾ | ₇ ¾f rate of 85% or more. Visibility of high refractive index layer and high refractive index layer is also more than 85%.

The low refractive index layer is made of fine particles such as silica and fluororesin, preferably hollow silica, 10 to 40 times *% or 10 to 30 mass ⁰ / mass. ) Is a layer (hard Wi) dispersed in a polymer (preferably UV curable resin). The refractive index of this low refractive index layer is preferably 1.45 to 1.51. If the refractive index is more than 1.51, the prevention characteristics of the prevention film are reduced. The wrinkles are generally in the range of 10 to 500 nm, preferably 20 to 200 nm. The hollow silica preferably has an average particle diameter of 10 to 100 nm, preferably 10 to 50 nm, and a specific gravity of 0.5 to 1.0, preferably 0.8 to 0.9.

The prevention film is composed of the above three layers: ^, e.g., the thickness of the coating layer is 2 to 20 βΐη, the thickness of the high refractive index layer is 75 to 90 nm, the thickness of the refractive index layer Is preferably 85 to 110 nm. To open each layer of the Sl † -preventive film, blend the above fine particles as necessary with tflt polymer, polymer or ultraviolet # hatching resin as required, and apply the resulting coating solution. After the coating, it can be dried, and if necessary, it can be dried, or if necessary, it can be dried and irradiated with ultraviolet rays. At this age, each layer can be applied one layer at a time. As a special method of coating, a gravure coating solution prepared by using an ultraviolet curable resin containing acrylic monomers and the like in f 鍾 such as toluene is used for gravure. Coating with a coater, etc., followed by desiccation, followed by curing with UV irradiation at the next layer: can be mentioned: This wet coating method has the advantage that it can be applied uniformly and inexpensively at high speed. After this coating, for example, ultraviolet rays are irradiated to harden This improves the adhesion and increases the hardness of the film.

Of Murasakigaijo Muchika: ¾ ^ can many things force ^s employed which emits ultraviolet to see areas as raw, eg if ultrahigh pressure, high pressure, {± 7k T, chemical lamp, xenon lamp, halogen lamp, Ma one Curie halogen lamp, carbon arc lamp, white i¾t, laser light, etc. Irradiation time cannot be determined unconditionally depending on the lamp's approval and the intensity of the field, but it is from a few to a few fS. In order to accelerate curing, the laminate may be preheated to 40 to 120 ° C. and irradiated with ultraviolet rays.

The anti-glare layer of the present invention can be shaped by coating as described above.

It may be formed by a method. Usually, the high refractive index layer and the low refractive index layer can be enormously increased by the object: deposition method or chemical deposition method. The physical vapor deposition methods include vacuum deposition method, sputtering method, ion plating method, and laser ablation method. In general, the spattering method is enormous. Examples of the 着 ^^ deposition method include the normal pressure C VD method, the 赃 C VD method, and the plasma C VD method.

Examples of the combination of the high refractive index layer and the Δδ refractive index layer include the following. (a) High refractive index layer / Folding index layer, one layer each, converted into a total of 2 layers, (b) High refractive index layer / Folding index layer, 2 layers alternately, total 4 hires (B) Medium refractive index layer Z High refractive index layer 1 layer each in the order of the refractive index layer, 3 layers in total (3) (3) (d) High refractive index layer / Fractive index layer Each layer is alternately 3 layers, a total of 6 layers ¾ layer. Is, I TO (indium tin oxide) or Z n O, Z doped with A 1 n O, can be employed films such as T I_〇 _{2, S n 0 2, Z} r O. As the low-refractive-fold index layer, S I_〇 _{2, M g F 2, A} l 2 0 3 such as the refractive index of 1 may be used. 6 or less thin.

The top invitation can be increased by the dressing method or the dressing method. Examples of the m method include a vacuum evaporation method, a sputtering method, an ion plating method, and a laser ablation method.匕 蒸 着 常 CVD 常 CVD CVD CVD 戲 、, 戲 CVD and plasma CVD.

 Examples of the material for the pressure-sensitive adhesive layer include attaryl resin, epoxy, and tffil ^ polymer. The pressure-sensitive adhesive layer is a mixture of polymer and reversible U, and the self, relatives and / or dyes are separated or revolved to create a coating solution, which is applied, dried, and cured as necessary. Is formed. You may use your own UV curable resin as the polymer. The thickness of the pressure-sensitive adhesive layer is generally 10 to 5 0 111, preferably 10 to 30 0 η.

 The protective layer should be formed in the same way as the hard coat layer.

 As a material for the release sheet, a transparent polymer having a glass layer of 50 ° C. or higher is preferable. Examples of such materials include polyester resins such as polyethylene terephthalate, polycyclohexylene terephthalate, and polyethylene naphthalate. Nylon 46, modified nylon 6T, nylon MXD 6, polyamide shelves such as polyphthalamide, ketone resins such as polyphenylene sulfide and polythioether sulfone, and sanolephone resins such as polysulfone and polyether monosulfone In addition, a resin containing a polymer such as polyether nitrinole, polyarylate, poly-terimide, polyamide imide, polycarbonate, polymethyl methacrylate, triacetino H-rulose, polystyrene, polybialkoxide is used. It is possible. Of these, polycarbonate, polymethylmethacrylate, polyvinylenochloride, polystyrene, and polyethylene terephthalate force can be suitably used. Thickness is preferably 10 to 20 μ πι force, particularly 30 to 1 0 0; u m force S.

The sl-stopping film with guide for m emission type display of the present invention obtained in this way is attached to the surface of the image display glass plate of the m emission type display and shelves. FIG. 7 shows a cross-sectional view of an example of a discharge-type display to which the present invention is applied.

 Electrons (®f emission electrons) generated by the E difference between the force sword and the gate return 73, and the force S are released. The electrons collide with the fluorescent material 76 formed inside the anode glass sheet 72 and emit light. The field-emission display lead film f 71 according to the present invention is affixed to the outer side of the canode glass sheet 72 and exhibits a fiber prevention effect and an antistatic effect.

Therefore, the emission display of the present invention (F ED including S ED) has excellent anti-fibrous effect and anti-static property and almost no leakage of dangerous waves. You can use the correct display.

[Example]

 EXAMPLES Hereinafter, although an Example and a comparative example are shown and this invention is demonstrated concretely, this invention is not limited to the following male examples.

 (I) Sit-preventing film having a straightness of ¾% in 560 to 640 nm, or antireflection film having a rate of 70% or more (Examples:! To 5 and Comparative Examples:! To 3)

 [Example 1]

A long, thin film with a thickness of 100 μm Τ Τ シ リ カ Is a silica fine-particle UV curable resin (resin with acryloyl group (trade name Ζ 7 5 0 1; manufactured by JSR)) on one surface of the film? Ranaru hard coat layer forming coating solution (silica content 5 1 mass _^0/0 (solid content)), coating with a gravure coater, and cured by m ultraviolet irradiation, a hard coat layer having a thickness of 6 μ πι (Corresponding to 55 in Fig. 5).

Then, on the hard coat layer, I TO microparticles (mean i St 4 0 nm) UV-curable resin containing a dispersed (I TO content 3 5 mass _^0/0 (solid content)) and a膽己Similarly, coating and curing were performed to form a high refractive index layer (corresponding to 56 in FIG. 5) having a thickness of 0. μm πι.

Furthermore, porous silica on the high refractive index layer (the hollow silica, average male 4 0 μ πι) UV was dispersed «I cured † raw resin (silica content 2 0.5 mass _^0/0 (solids) ) Curing was performed to form a ■ index layer (corresponding to 57 in Fig. 5) with a thickness of 0 Ι μπι. The above process was continuously carried out to roll the anti-reflection film 1 in a roll.

 On the surface of the obtained ^ prevention film 1, an ultraviolet resin (ITO content 40 mass% (solid content)) in which ITO fine particles (average ¾¾g40 nm) are dispersed is applied in the same manner as in the knitting. Then, a transparent conductor (corresponding to 52 in Fig. 5) with a thickness of 1 µm was formed. In this way, a roll-shaped antireflection film 2 with a transparent conductive layer was produced.

Next, an acrylic adhesive (trade name: SK Dyne 181 1 L _; manufactured by Keigaku Co., Ltd.) is added with cetyl Z toluene (80/20 quality ¾: 匕) to obtain a solid content of 19% by mass. An adhesive layer-shaped dramatic coating liquid was obtained. The mask was coated on a masked surface of a long PET release sheet (thickness 37 μπι) and dried to form a correspondence with a 20 βm thick adhesive layer (54 in Fig. 5). Another PET release sheet (corresponding to 58 in FIG. 5) was laminated on this pressure-sensitive adhesive layer to obtain a roll-shaped pressure-sensitive adhesive film 3 sandwiching the pressure-sensitive adhesive layers.

 flit The self-rolled Slf-preventive film 2's transparent guide m® surface is rolled onto the surface of the adhesive film 3 while continuously peeling the PET film on one side, Laminated. This prevents fiber prevention! ¾Meiori Z transparent conductor 1 / adhesive layer Z release sheet

Make a roll-shaped protective film A with transparent conductive MS having the structure of / P E T release sheet 7

 [Example 2]

 In Example 1, the coating solution for forming the pressure-sensitive adhesive layer was mixed with a chromium complexing agent Droplet name Black MH special, Hodo Sugaku Kogyo Co., Ltd.) in an amount of 0.2% by mass (solid content) ) A roll-shaped transparent anti-rotation film B was removed in the same manner except that it was removed. The resulting anti-fiber film B exhibited a crane percentage of 80%.

[Example 3]

In Example 1, the coating solution for forming the adhesive layer was coated with a chrome complex (trade name: Black MH special, Hodo ^ {manufactured by Eigaku Kogyo Co., Ltd.), magenta labor (Chemical ^ !: CI Disperse Violet 31 brand name Plas Red 8380, Arimoto Chemical Industry Co., Ltd.) and Cyanol (Chemical ^) name CISolvent Blue 35, trade name Oil Blue S502, Hayashi Chemical Industry Co., Ltd.) for acrylic adhesives Each 0.1 mass ⁰ I 0.0 7% by weight, 0.0 3 mass _^0/0 (solids) Karoete ^ ¾ is not a except Similarly I a roll of a transparent electrically m with safety film c and懷did. The obtained antiglare film C exhibited a luminous transmittance of 80%.

[Example 4]

 In male example 1, the adhesive layer-type dramatic coating solution was mixed with tetraazaborphyrin-based dye (light absorption fe ^ skin length: 592 nm, product name TAP 2, manufactured by Yamada Chemical Co., Ltd.) ) Was applied in the same manner as above except that 0.1% by mass (solid content) was added to the acrylic pressure-sensitive adhesive. The obtained Sit prevention film D shows a g / J value of 70% and a net problem rate at 592 nm, as shown in the rate graph in Fig. 8. Showed 95%.

[Bells 5]

 In Example 1, a tetraazaporphyrin dye (light absorption maximum wavelength: 592 nm, trade name: TAP 2, Yamada Chemical Co., Ltd.) is used as an acrylic adhesive in an adhesive layer-type dramatic coating solution. On the other hand, a roll-shaped Sli-preventing film E with a transparent conductive film was coated in the same manner except that 0.1% by mass (solid content) was added and dispersed. The obtained prevention film E showed a value of ¾ J at a rate of 60% at 59 2 nm, as shown in the transmittance graph in Fig. 8, and a rate of ¾βϋ of 95%. Indicated.

[Comparative Example 1]

In Example 1, a chromium complexing agent (trade name: Black MH special, manufactured by Hodo Rigaku Kogyo Co., Ltd.) was added to the acrylic adhesive in an amount of 0.2 mass ⁰ / ₀ (Solid content) A roll-shaped antireflection film F with a transparent conductive TO was coated in the same manner except that it was dispersed. The obtained 3f-preventing film F exhibited a flattening rate of 45 ° / ₀ .

[Comparative Example 2]

In Example 1, the coating solution for forming the pressure-sensitive adhesive layer was mixed with a chromium complexing agent (trade name: Black MH special, Hodo ^ fg Gaku Kogyo Co., Ltd.), magenta agent (chemical name: CI Disperse Violet 31 , Brand name Plas Red 8380, manufactured by Arimoto Chemical Industry Co., Ltd.) and cyanide (compound name l. Solvent Blue 35, brand name Oil Blue S502, Arimoto Chemical Industry Co., Ltd.) for acrylic adhesives Each 0.1 mass ⁰ I 0.07 mass%, 0.03 mass _^0/0 (solid content) was added I mouth Lumpur shaped transparent m with碰preventing film G in the same manner except were dispersed懷did. The obtained anti-fiber film G exhibited a luminous transmittance of 60%.

 [Comparative Example 3]

 In construction example 1, add tetraazaborphyrin dye (light absorption wavelength: 592 nm, trade name: TAP 2, Yamada Chemical Co., Ltd.) to the adhesive layer-type dramatic coating liquid. The roll-shaped transparent H-preventing anti-static film H was tilted in the same manner except that 0.1% by mass (solid content) was reduced. The obtained Sit prevention film H showed a minimum value of 3¾1 rate of 40% at 592 nm.

[Evaluation of wrinkle prevention film with transparent guide]

 (1) Crab ratio

 Measured according to JIS-K-7105-1981. The measurement wavelength was 400-700 nm. A spectrophotometer (U4000 (manufactured by Hitachi, Ltd.)) was used as a measuring instrument.

 (2) Minimal value of visible ^ H¾i rate

 Measured according to J I S -K-7105-1981. The measurement wavelength was 400 to 700 nm. A spectrophotometer (U4000 (manufactured by Hitachi, Ltd.)) was used as a measuring instrument.

 (3) Visible light ^ Si ratio (brightness)

 Measured according to JIS-K-7105-1981. The measurement wavelength was 400-700 nm. The measuring instrument was a shelves (U4000 (manufactured by Hitachi)). The evaluation was as follows.

 ○: The average rate is 80% or less Jbo

 Δ: The average rate is 50% or more and less than 80%.

 X: Average rate is less than 50%

 (4) Antistatic property

The obtained anti-fiber film with transparent conductive m was cut according to the size of the heel of the release type display, and attached to the surface of the heel (glass plate) of the display. In this state, The display was energized to display an image. After 1 hour, the surface charge state was visually evaluated as follows.

 〇: Almost dusty, tere, nare.

 Δ: Dust slightly attached.

 X: A lot of dust is attached.

 (5) Orchid prevention

 The obtained transparent conductive anti-glare film was cut according to the size of the release-type display and attached to the surface of the display (glass plate). In this state, the display was energized to display an image, and the eyelids were visually evaluated as follows. 〇: Almost ¾f.

 △ I feel light.

 X: I feel light.

 (6) Contrast

 The obtained sii-preventing film with a transparent guide m was cut according to the size of the heel of the release type display, and shells were placed on the surface of the heel (glass plate) of the display. In this state, the display was energized to display an image, and the contrast @ ¾ was visually stated as follows.

 . : St, feel the light.

 Δ: ^ S I feel light.

 X: I feel the reflected light.

 (7) Color tone (lightness index)

 The brightness index a *, b * was measured according to JIS—K—8720-2000. The measurement wavelength was 400-700 nm. The measuring instrument used was a ^ ¾ photometer (U4000 (manufactured by Hitachi, Ltd.)).

 (8) Luminescent color boat

The colored yarn cover was measured according to JIS-K-8720-2000. The measurement wavelength was 400-70 Onm. The measuring instrument was a 6 6 meter (U4000 (manufactured by Hitachi)). The difference between the color yarn cover before and after the application of D Sit prevention film was measured, and it was presented as follows. ◯: Color purity was improved.

 Δ: The color was improved.

 X: Color yarn does not improve.

 Table 1 shows the results.

 table 1

(I I) Sit-preventing film having minimum value of 440 460 nm 530 550 600 620 nm or 565 5 85 nm (Example 69)

 [Example 6]

A hard coat made of silica fine particle UV curable resin (resin yarn with acryloyl group JJ ») (trade name Z 7501; JSR Co., Ltd.) on one surface of a long PET film with a thickness of 100 / im the layers form Gekinurikoeki (silica content 51 mass _^0/0 (solid content)), coating with a gravure coater, ultraviolet irradiation and cured, hard coat layer having a thickness of 6 (corresponding to FIG. 5 of 55 ) Formed.

Next, on this hard coat layer, UV curable resin (ITO content 35% by mass (solid content)) in which I TO fine particles (ί 40 nm) are dispersed is applied and cured in the same manner as Akemi. A high refractive index layer (corresponding to 56 in Fig. 5) with a thickness of 0. Furthermore, an ultraviolet curable resin (silica content 20.5 mass% (solid content)) in which porous silica (hollow silica, average particle size 40 im) is dispersed on the high refractive index layer, ttjfB In the same manner, coating and curing were performed to form a 0.1 lm-thickness ratio layer (corresponding to 57 in Fig. 5). The above steps were carried out continuously to produce a mouth-like Sit prevention film 1.

The surface of the obtained Κΐί prevention film 1 ftt, I TO microparticles (flat: ^ Ki圣4 O nm) and distributed to cause the ultraviolet撫更of resin (I TO content 4 0 mass _^0/0 (solid Min))) was applied and cured in the same manner as the knitting to form a transparent conductive film having a thickness of m (corresponding to 52 in FIG. 5). As a result, a roll-shaped transparent protective film 2 with a roll-shaped transparent electrode was provided.

Further IJ is mixed with an acrylic adhesive (trade name: SK Dyne 1 8 1 1 L; manufactured by Eigaku Co., Ltd.) with 酉 獺 ethyl-toluene (80,20 mass ratio) to obtain a solid content of 1 ? 9 mass _^0/0 ^ obtained the night, this CI Solvent Yellow dye:; (light absorption ¾ ^ skin length 4 5 O nm groundnut ^ {匕学industry (Co.) M) to solid of裔夜content and添Ka卩0.1 mass _^0/0 (solids) for to obtain a pressure-sensitive adhesive layer coating liquid. The film was coated and dried on a screen of a long PET release sheet (0? 3 7 μπι), and a correspondence was formed with a 20 m thick adhesive layer (54 in Fig. 5). Another PET release sheet (corresponding to 5 8 in Fig. 5) was laminated on this pressure-sensitive adhesive layer to obtain a roll-shaped pressure-sensitive adhesive film 3 sandwiched with the pressure-sensitive adhesive layer.

 The self-rolled Ht-preventing film 2 obtained by the self-adhesive film 3 is continuously adhered to the surface of the transparent adhesive © 1 while peeling one PET film on the surface. Laminated. As a result, we have prepared a Sit-preventing film with a transparent transparent TO with a structure of prevention ^^ transparent 纖 Z transparent guide E / adhesive layer Z release sheet and Ρ Ε Τ release sheet.

 As shown in FIG. 9, the obtained Sit-preventing film showed a minimum value of 68% at a wavelength of 4500 nm and a net rate of 95%.

[Example 7]

In male example 1, in preparation of adhesive layer-type dramatic coating liquid, the magenta dye Ade force Arcles TY—2 3 5 (light absorption wavelength: 5400 nm; Asahi Denki Kogyo) instead of CI Solvent Yellow dye In the same way, a roll-shaped anti-fiber film with transparent transduction using Did.

 As shown in FIG. 10, the obtained anti-fiber finerole showed a minimum value of 6% and a rate of 95% at a wavelength of 5400 nm.

 [Example 8]

 In the first row, in preparation of the adhesive layer-type dramatic coating liquid, instead of CI Solvent Yellow dye, TAP— 1 0 (light absorption fe ^ skin length: 6 1 In the same way, a roll-like transparent anti-rotation film was used using 0 nm (manufactured by Yamada Yigaku Kogyo Co., Ltd.).

 As shown in FIG. 11, the obtained anti-fiber film showed a minimum value of 67% ¾ii rate at a wavelength of 61 nm, and a 95% Ne fan rate i rate.

 [Example 9]

 In difficult example 1, in the preparation of the adhesive layer-type fine coating solution, instead of CI Solvent Yellow dye, tetraazapolyphyllin dye TAP _ 1 0 (light absorption; wavelength: 6 10 nm; Yamada Yi) We used Tsugaku Industry Co., Ltd.)! In the same way, a roll-shaped transparent conductive film with a transparent conductive film was used.

 As shown in FIG. 12, the obtained anti-fiber film showed a minimum value of 6% of the yield rate at a wavelength of 575 nm, and a 1% rate of 95%.

 Measurements of the conversion rate and the O¾¾S rate in Examples 6 to 9 were performed as described above.

 The results are summarized in Table 2.

Table 2

(I I I) Antireflection film having a surface resistance value of 8 Ω or lower (Example 1 0 to 15) [Example 1 1]

Silica fine particles ^ ¹ ? ^ UV curable resin (trade name: Z 7 5 0 1; manufactured by JSR Corporation) was applied to one surface of a long Ρ ノ inolem with a thickness of 100 μm UV curable resin A hard coat layer development coating solution (silica content: 51% by mass (solid content)) consisting of a resin yarn having a polymer group Jj ^) is applied with a gravure coater, after the vehicle is subjected to ultraviolet light » Cured to form a 6 μπι hard coat layer (corresponding to 35 in FIG. 3).

 Next, an ultraviolet curable resin (ITO content: 35% by mass (solid content)) in which ITO fine particles (flat: t ^ ¾40 nm) are dispersed is applied on the hard coat layer in the same manner as the self. Then, a high refractive index layer (corresponding to 36 in Fig. 3) with a thickness of 0.1 µm was formed.

Furthermore, an ultraviolet curable resin (silica content: 20.5 mass% (solid content)) in which porous silica (hollow silica, flat: ^;) ¾ ^ 40μπι) is placed on the high refractive index layer is added. In the same way as in Xie Ji, coating and renewal were carried out to form a 0.1 ^ _m- thick index layer (corresponding to 37 in Fig. 3). The above process was continuously carried out to obtain a roll-shaped antireflection film 1. , UV-degradable resin (ITO content: 35 mass ⁰ /. (Solid content)) obtained by dispersing ITO fine particles (average particle size: 40 nm) on the surface of the obtained antistatic film 1 This was coated and cured in the same manner as the self, forming a transparent conductor Ml (corresponding to 32 in Fig. 3) with a thickness of 1 / zm. In this way, a roll-shaped antireflection film A with a transparent conductive layer was produced.

[Example 11]

 The surface of the anti-fiber film 1 obtained in Example 10 was coated with a polythiophene-based polymer in the same manner as the self, and was heated to a calorie heat to have a thickness of 1 m (see Fig. 3). Corresponding to 32). As a result, the roll-shaped transparent prevention film B with transparent guide was tilted.

[Fine row 12]

 透明 Transparent lead of I Τ〇 H (see 32 in Fig. 3) in the same way, except that the thickness was changed from 1 μm to 0.5 μm on the fte surface of anti-fiber film 1 obtained in 10. Response) was established. In this way, a roll-shaped antireflection film C with a transparent conductive layer was produced.

[Male example 13]

On the surface of anti-fiber film 1 obtained in Difficult Example 10, a transparent film M (corresponding to 32 in Fig. 3) has a five-layer film (1 07 08/1 0 / ^ _{§ /} ^/ 1 C); Thickness 4011111/12 nm / 90 nm / 12 nm / 40 nm) is formed by vacuum deposition and another 100 μm long PET PET FEM is provided with each layer. Yeah! / Face the surface of the law Adhesion was carried out using an acrylic adhesive (trade name: SK Dyne 1811 L _; manufactured by Eigaku Co., Ltd.) (adhesive layer thickness 17 ^ m). As a result, the roll-shaped transparent conductive Sli prevention film D was tilted.

 [Example 14]

 The same foil was attached to one surface of another 100 m thick PET film having a thickness of 10 ^ m <7) |. A dot pattern is formed on this foil using a photolithographic method, and the exposed copper foil is etched to form a lattice pattern surface foil (尉 圣 1 Ομιη, pitch 250 ^ m). Obtained. .

 Next, an electrically conductive film is provided on the surface of the Sit prevention film 1 obtained in Example 1, and each layer is provided so that the surface of the layer is opposed to the talyl adhesive ( Product name: SK Dyne 1811L; Occupied Uniform U layer with a thickness of 17 μm) glued by Ryugaku Co., Ltd.). In this way, a sit-proof film E with a transparent transparent guide was created.

 [Example 15] (Preparation of antireflection film with transparent conductive layer with release sheet)

Acrylic pressure-sensitive adhesive (trade name SK Dyne 1811 L;麵匕Science (Ltd.) M), and Tori懺Echiru to obtain a coating solution having a solid content of 19 mass _^0/0 and «with toluene (80Z20 mass ratio) . It was coated and dried on the side of a long PET film (thickness 75μπι) on the ridge of the release sheet to form a 17 m thick adhesive layer. Another PET film was laminated on the pressure-sensitive adhesive layer to obtain a roll-shaped pressure-sensitive adhesive film having a sandwiched adhesive layer.

 Next, the roll-like ^) "preventive films A to E obtained in Examples 10 to 14" Each of the guiding strengths S of the prevention films A to E was applied to the above-mentioned roll-like adhesive film on one side of the PET film. The film was continuously laminated while being peeled off to obtain a roll-shaped antireflection film with a transparent conductive film having a structure of a PET film z transparent muz adhesive layer z release sheet.

 [Example 16] (Preparation of antireflection film with transparent conductive layer with release sheet)

Akurinore system Motomeuranai ChakuHitoshi IJ (trade name SK Dyne 1811 L;匕学Co., Ltd.), coating the Tori懒Echiru / toluene solids 19 mass and jobs at (80/20 weight ratio) _^0/0 A liquid was obtained. The adhesive sheet of 17 mm thick was formed by coating and drying on the side of a long sheet of male PET film with a release sheet of 0 mm (75 im). This obtained the roll-shaped adhesive film which has an adhesive layer. Next, the adhesive layer of the above-mentioned roll-shaped adhesive film is laminated on the surface of each of the roll-shaped Sit prevention films A to E obtained in Examples 10 to 4 on the surfaces where the adhesive strength S is formed. First, a roll-shaped antireflection film with transparent conductive film Jf having the structure of anti-scattering SP ET film Z transparent conductive film 1 / adhesive layer Z release sheet (the structure is the same as in Example 15) was obtained.

[Advisory of wrinkle prevention film with transparent conductive film i]

 (1) Surface resistance value

 Measured according to JIS-K- 6911-1995.

 (2) Visibility rate

 Measured according to J I S -K-7105-1987. The measurement wavelength was 400 to 700 nm. The measuring instrument (U4000, manufactured by Hitachi, Ltd.) was used. I made the following statement:

○: Rate is 80% or more on average ± o

 Δ: The average rate is 50% or more and less than 80%.

 X: Average rate is less than 50%

 (3) Antistatic property

 The obtained anti-fiber film with light guide m was cut according to the size of the heel of the release type display, and attached to the surface of the heel (glass plate) of the display. In this state, the display was energized to display an image, and after 1 hour, the surface condition was visually checked as follows.

 〇: Mostly dusty, very lazy.

 Δ: Dust S Slightly attached.

 X: A lot of dust is attached.

Table 3 shows the test results. Table 3

Even when the anti-fiber film obtained in Example 16 was used, the same result as above was obtained. [Explanation of symbols]

 11, 21 mm, 21 mm, 31, 41, 51, 61

 12, 22, 32, 42, 52, 62 Transparent conductive layer

 13, 23, 33, 43, 53, 63 Anti-fiber membrane

 35, 45, 55, 65 Hard coat layer

 36, 46, 56, 66 High refractive index layer

 37, 47, 57, 67 Low refractive index layer

 24, 34, 44mm, 44mm, 54, 64mm, 64mm Adhesive

 68 Peeling sheet

 59, 69 Protective layer

6. Industrial applicability

The first release emissive display for guiding © I with fiber prevention film纖of the invention, FED of wearing: ^, display characteristics (contrast, hue, brightness, etc.) force S significantly improved _s further Hotome FED with improved function and antistatic function can be obtained

 In addition, according to the present invention, the second anti-glare film for lead-on display according to the present invention has a relatively high level surface transparency value in addition to the anti-fiber function by attaching the FED. Even in this case, FED capable of preventing charging and blocking the skin can be obtained in ¾5.

Claims

The scope of the claims

1. + Transparent ¾K is provided with sii-preventing film on one surface, and transparent guide m is provided on the surface of fte, and 4 4 0 to 4 60 nm, 5 30 to 5 50 nm and 5 60 to An anti-reflection film with a guide m for a release-type display, which has a light transmittance of at least one wavelength range of 6400 nm and has a light-gigi rate of W.

2. Two transparent wisteria, a transparent male with a fiber-preventing film on one surface, and another transparent rod with a transparent lead on one surface. Non-bonded surfaces via an adhesive layer and having at least one of 4 40 to 4 60 nm, 5 3 0 to 5 50 nm, and 5 60 to 6 40 nm A st-preventing film with a conductive m for field emission displays that has a minimum value of the light ffl rate in one wavelength range.

3. The cocoon skin length range is 5 60 to 6 40 η m. The antireflection film with a conductive layer for an Eft emission display according to claim 1 or 2, wherein:

4. The skin length range is at least one wavelength range of 4 40 to 4 60 nm, 5 3 0 to 5 50 nm, and 6 0 0 to 6 2 0 nm, according to claims 1 to 3! / ヽ The reflection-preventing film with a conductive layer for the emission type display according to item 1.

5. The antireflection film with a conductive layer for a field emission display according to claim 1, wherein the peeling length range is 5 65 5 to 5 85 nm.

6. The fiber-proof anti-fiber film for a field emission display according to claim 1, wherein the light transmittance in the range of ΙίΠΕί skin length is 50 to 90%.

7. The adhesive layer strength is provided on the transparent guide, and the components of claims 1 to 6 are separated. 導 ί prevention film with guide TO for emissive display.

8. The transparent conductive layer or the pressure-sensitive adhesive layer contains dyes and wrinkles or pigments that absorb light in the skin length range as described above. With anti-reflection film for display.

9. Transparent material m or «I occupant layer strength 560 to 640 nm The wavelength range of 560 to 640 nm The material containing a black ^! ¾ !! · Leading Si prevention film for emissive display.

10. The transparent conductor 11 or 3 or 3, wherein the adhesive layer contains a tetraazaporphyrin-based dye as a dye having a direct ratio of ¾ii in the wavelength range of 560 to 640 nm. Or a lead wrinkle prevention film for a field emission display according to 8,

11. Transparent Conductive® or W¾ Adhesive Layer has an anthraquinone dye, azo dye, quinophthalone dye or berylene dye as a dye having a value of ¾d and value in the wavelength range of 440 to 460 nm. The Sit-preventing film with a conductive ttll for a field emission display according to claim 1, 2, 4, 6, 7, or 8.

12. The transparent lead or ttf occluding agent layer contains an anthraquinone dye or an azo dye as a dye having a ratio of ¾J in the wavelength range of 530 to 550 nm. The ¾f-preventing film with a conductive m for field emission display according to 4, 6, 7 or 8.

13. The antireflection film with a guide for a field emission display according to any one of claims: to 12, wherein the transparent layer and the anti-reflection adhesive layer are coatings.

14. The surface resistance value is 10 ⁸ Ω or less, and the level deviation of 13 to 13 is: Antireflection film with conductive layer for field emission display,

 1 5 · The light-emitting fiber for a field emission display according to any one of claims 1 to 14, wherein the lightness index satisfies −3 <a * <3 and −2 <b * <l0. Prevention film.

 1 6. Light! ¾¾i ratio is 50% or more. Claims 1 to: 15 of the level deviation or 1 of claim 1.

 1 7. For m-emission type display where a protective film is provided on one surface of the transparent support and a transparent conductive force is provided on the surface of the ite, and the visual recognition and ¾% rate is 70% or more Thin film with guiding mi.

 1 8. Two transparent males, one with a transparent difficulty with an anti-reflective coating on one surface and another with a transparent guide on one surface, the MX has a layer strength S formation Anti-reflection for field emission displays based on the fact that the surface is bonded to each other through an adhesive layer, and the recognition rate is 70% or more. the film.

1 9. A field-emission display that has an anti-wrinkle film on one surface that is difficult to be transparent, a transparent mil force on the surface, and has a surface resistance of 10 ⁸ Ω / mouth or less. Preventive film with conductive layer.

2 0. Two transparent sickles, one with a transparent warehouse with an orchid-preventing film on one surface and another with a transparent guide on one surface. A wrinkle-preventing film with a conductive film for field emission display 1, wherein the film is a laminate formed by adhering surfaces that are not present and have a surface resistance value of 10 ⁸ Ω or less.

2 1. The critical value of the surface is in the range of 10 ⁵ to 10 ⁸ Ω / mouth. Antireflection film with conductive layer for field emission display.

22. The st-preventing film with a guide for field emission type display according to any one of claims 19 to 21, wherein the transparent conductor i is a coating.

23. The transparent conducting M with the guide for a remote-release display according to any one of claims 19 to 22, wherein the transparent guide M is a coating in which a polymer is introduced into the polymer. .

24. The antireflection film with a conductive layer for a field emission display according to any one of claims 19 to 22, wherein the transparent conductor 1 is a coating of a conductive polymer.

25. The Sli-preventing film with guide for m-emitting display according to any one of claims 1 to 24, wherein the transparent texture is a plastic film.

·

 26. Claim: Protective film cover with a release-type display guide with a gap of ~~ 25 m. Emission type that is glued to the surface of the image display glass plate. display.

27. An antireflection film is formed on one surface of the transparent substrate by a coating method, and transparent conductive HI! Is formed on the other surface by a coating method, and 440 to 460 nm, 530 to 550 nm, and 56 0-640 A method of producing a ^ It-preventing film with a guide for a light-emitting display having a minimum value of the luminous efficiency in at least one wavelength range of nm.

28. —The two transparent males, the transparent cocoon with the anti-fibrous film on the surface and the transparent conductor on one surface, and the other transparent male, are made to form an enormous amount or layer strength S. Being les, nales, face-to-face through the rice occupant layer] ^, 440-460nm, 530-550n A method of manufacturing an anti-m-St film with a conductive m for a field emission display having a value of † SJ, a value of light rate in at least one wavelength range of m and 5 60 to 6 40 nm.

29. The antireflection film with a conductive layer for a field emission display according to claim 27, wherein the coating liquid for opening the transparent conductive film i contains a pigment and Z or a dye. ISt ^ law.

30. The adhesive layer for the key emission display according to claim 27, wherein the adhesive layer further containing a pigment and / or a pigment is formed on the transparent guide m by a coating method. Prevention Fil / Rem manufacturing method.

3 1. Including a step of forming a protective film on one surface of a transparent substrate by a coating method, a step of forming a transparent conductive layer on the surface of the next substrate by a coating method, and the surface S¾ value is 10 ⁸ Ω or less A method for producing a ^ it-preventing film with a conductive film for a field emission display.

3 2. Applying anti-storage wisteria UV curable resin coating solution on one surface of the transparent plate, forming the anti-reflection film by UV-curing, the transparent coating on the surface of the ite. For field emission displays with a surface resistance of 1 ο ⁸ Ω / mouth or less, including the step of applying UV curable resin coating liquid for ML formation and forming a transparent conductor 1 by UV curing A method for producing an antireflection film with a conductive layer.

3 3. IX is a layer of transparency, with a transparent barrier on one surface and a transparent male ® on the other surface and another transparent male. Manufactures antireflection finolems with field-emission display guides that have a surface resistance of 10 ⁸ Ω or less, including the step of facing through unadhered surfaces with an adhesive layer. how to.