WO2006028308A1 - Composition cosmetique solide sous forme d'emulsion d'eau dans une huile avec un agent gelifiant - Google Patents

Composition cosmetique solide sous forme d'emulsion d'eau dans une huile avec un agent gelifiant Download PDF

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Publication number
WO2006028308A1
WO2006028308A1 PCT/KR2004/002311 KR2004002311W WO2006028308A1 WO 2006028308 A1 WO2006028308 A1 WO 2006028308A1 KR 2004002311 W KR2004002311 W KR 2004002311W WO 2006028308 A1 WO2006028308 A1 WO 2006028308A1
Authority
WO
WIPO (PCT)
Prior art keywords
weight
water
cosmetic composition
oil
oil emulsion
Prior art date
Application number
PCT/KR2004/002311
Other languages
English (en)
Inventor
Byeong-Gyu Park
Jong-Sub Han
Cheon-Koo Lee
Original Assignee
Lg Household & Health Care Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lg Household & Health Care Ltd. filed Critical Lg Household & Health Care Ltd.
Priority to PCT/KR2004/002311 priority Critical patent/WO2006028308A1/fr
Publication of WO2006028308A1 publication Critical patent/WO2006028308A1/fr

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
    • A61Q1/06—Lipsticks
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/06—Emulsions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/06—Emulsions
    • A61K8/064—Water-in-oil emulsions, e.g. Water-in-silicone emulsions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/26—Aluminium; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A61K8/4973—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with oxygen as the only hetero atom
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P17/00—Drugs for dermatological disorders
    • A61P17/16—Emollients or protectives, e.g. against radiation
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments

Definitions

  • the present invention relates to solid cosmetic composition in the form of water-in-oil emulsion.
  • solid cosmetic materials may be mainly divided into three groups: a
  • powdery cosmetic material in which pigment is solidified as a major component by an
  • emulsion in which pigment is emulsified using oily components such as wax, and aqueous components.
  • the cosmetic material in the form of emulsion gives the clear and moist feeling that cannot be given by the aqueous phase-free powdery cosmetic material and the cosmetic material composed only of the oily components, and also has a natural makeup effect due to the light makeup.
  • the cosmetic composition in the form of emulsion is mainly classified into two types of an oil-in-water (O/W) emulsion and a water-in-oil (W/O) emulsion.
  • the oil-in-water (O/W) emulsion is hydrophilic, and has an advantage of
  • the water-in-oil (W/O) emulsion shows an excellent cosmetic endurance and water resistance, but has a disadvantage of imposing a stress on the skin due to its sticky, oily and waxy feeling. Also, it has a disadvantage of giving
  • the bad feeling such as a pasting property, a spread property and others.
  • the cosmetic composition in the form of water-in-oil emulsion including a large amount of volatile silicon oil is developed. Alike the cosmetic
  • water-in-oil emulsion including the volatile silicon oil has an advantage that its long-term stability is poor since its components are contracted due to volatilization of
  • composition in the form of water-in-oil emulsion is easily spread on the skin in its early
  • the cosmetic composition also has a disadvantage that it is
  • the cosmetic material in the form of emulsion has a disadvantage of giving a poor appearance and much discomfort upon its use because the sweating
  • the present invention is designed to solve the problems of the prior art, and therefore it is an object of the present invention to provide solid cosmetic composition
  • the present invention provides solid cosmetic composition in the form of water-in-oil emulsion including 0.1 to 2 % by
  • an inorganic gelling agent 0.1 to 6 % by weight of an organic gelling agent, 10 to 60 % by weight of oil components including volatile oil, 1.5 to 10 % by weight of wax, 1 to 5 % by weight of an emulsif ⁇ er, 10 to 50 % by weight of pigment components
  • component 5 to 40 % by weight of aqueous components based on the total weight of the composition.
  • the solid cosmetic composition in the form of water-in-oil emulsion of the present invention may be clearly phase-changed from the solid phase to the liquid phase, and from the liquid phase to the powder because the inorganic gelling agent and the organic gelling agent are used together to form a gel-emulsion structure for the cosmetic
  • the feeling is significantly improved by minimizing a content of the wax since
  • the gel-emulsion structure such as a solid matrix structure.
  • the gel-emulsion structure such as a solid matrix structure.
  • the sweating phenomenon arises due to difference of volume expansivity between wax and oil by change temperature. That is to say, the reduced
  • present invention may be applied to various products such as lipstick, eyeshadow, powder foundation, stick foundation and others.
  • Fig. Ia is a photograph showing a test result of evaluating a makeup transfer test on a commercially available liquid foundation
  • Fig. 1 b is a photograph showing a test result of evaluating a makeup transfer test on a commercially available powder foundation
  • Fig. Ic is a photograph showing a test result of evaluating a makeup transfer test
  • Fig. 2 is a diagram showing a test result of measuring dynamic friction
  • the solid cosmetic composition in the form of water-in-oil emulsion in the form of water-in-oil emulsion
  • the solid cosmetic composition in the form of water-in-oil emulsion of the present invention includes 0.1 to 2 % by weight of an inorganic gelling agent, 0.1 to 6 % by weight of an organic gelling agent, 10 to 60 % by weight of oil components included in volatile oil, 1.5 to 10 % by weight of wax, 1 to 5 % by weight of an emulsifier, 10 to 50 % by weight of pigment components, and 5 to 40 % by weight of aqueous components, based on the total weight of the composition.
  • present invention maintains the solid phase more easily by means of interaction of the inorganic gelling agent and the organic gelling agent included in the solid cosmetic
  • the content of the wax included in the cosmetic composition may be
  • the solid cosmetic composition in the form of water-in-oil emulsion of the present invention including both of the inorganic gelling agent and the organic gelling
  • agent has the organic/inorganic gel-emulsion structure which functions as a buffer.
  • the inorganic gelling agent included in the solid cosmetic composition in the form of water-in-oil emulsion of the present invention has an excellent sheer thinning effect.
  • the inorganic gelling agent for example the gelable hydrophilic and/or oleophilic clay-based inorganic gelling agent such as quaternium-18
  • magnesium aluminum silicate, stearalkonium bentonite and others may be used alone or in combination thereof. Considering the overall physical properties and feeling of the
  • the inorganic gelling agent of the present invention has a content of 0.1 to 2 % by weight, based on the total weight of the composition. The sheer thinning
  • the solid cosmetic composition in the form of water-in-oil emulsion of the present invention includes 0.1 to 6 % by weight of the organic gelling agent, based on the total weight of the composition.
  • organic gelling agent for example sorbitan olivate, 12-hydroxy stearic acid
  • glycol ester glycol ester, sorbitol fatty acid ester, solbide fatty acid ester, sorbitan fatty acid ester, dextrin fatty acid ester, cyclopentasiloxane (&)dimethicone/vinyldimethicone crosspolymer, dimethicone (&)dimethicone/vinyldimethicone crosspolymer, phenyl trimethicone (&)dimethicone/phenylvinylmethicone crosspolymer, isodecan (&)vinyldimethicone/lauryldimethicone crosspolymer and others may be used alone or in combination thereof.
  • cyclopentasiloxane &)dimethicone/vinyldimethicone crosspolymer
  • dimethicone &
  • phenyl trimethicone &)dimethicone/phenylvinylmethicone crosspol
  • sorbitan olivate 12-hydroxy stearic acid, hydrogenated castor oil, stearic acid octadecyl, ethylene glycol ester, propylene glycol ester, sorbitol fatty acid ester, solbide fatty acid ester and sorbitan fatty acid ester; and sorbitan olivate and stearic acid octadecyl are most preferred.
  • the organic gelling agent including metals such as stearic acid aluminum, stearic acid magnesium may be also included in the organic gelling agent.
  • present invention includes 0.1 to 6 % by weight of the organic gelling agent. It its content is less than 0.1 % by weight, the stability of the composition is relatively
  • the sweating phenomenon may arise due to change of the outer temperature (especially, at high temperature). If its content exceeds 6 % by
  • the lower amount of the organic gelling agent is used compared to the inorganic gelling agent, the more deteriorated the stability of the composition is.
  • the more amount of the organic gelling agent is used, the more deteriorated the feeling is. Accordingly, content ratio (a:b) of the organic gelling agent (a) and the
  • invention preferably ranges from 0.5:1 to 60:1 and more preferably from 3:1 to 15:1, considering the stability and the feeling of the composition.
  • the solid cosmetic composition in the form of water-in-oil emulsion in the form of water-in-oil emulsion
  • squalene capryliccapric triglyceride, pentaerythrityl tetraethylhexanoate, butyleneglycol dicaprylatecaprate, hexyl laurate, dimethylpolysiloxane, methylphenylpolysiloxane, decamethylcyclopentasiloxane, methyl trimethicone, phenyl trimethicone, liquid-phase
  • lanoline olive oil, avocado oil, Jojoba oil, macadamia oil and others may be used as the oil.
  • composition in the form of water-in-oil emulsion of the present invention allows the cosmetic materials to facilitate the phase change from the liquid phase to the powder after its application. That is to say, the solid-phase cosmetic composition of the
  • present invention is phase-changed into the liquid phase during its application, and then
  • phase change from the liquid phase to the powder is facilitated as the aqueous
  • silicon-based oil may also be used as the non-volatile oil.
  • silicon-based oil may also be used as the non-volatile oil.
  • volatile oil and cyclomethicone, which is a volatile and raw material odor-free cyclic silicon 4-mer to 6mer, is most preferably used.
  • the content of the non-volatile oil is more preferably lower than that of the volatile oil in the oil components including the volatile oil.
  • the solid cosmetic composition in the form of water-in-oil emulsion of the present invention includes wax.
  • the wax is generally used to solidify the cosmetic materials or give a luster.
  • Vegetable wax such as candelilla wax, carnauba wax, rice wax and others; animal wax such as Bees wax, lanoline and others; mineral wax such as
  • microcrystalline wax polyethylene wax and others may be used for this purpose.
  • the wax used in the cosmetic composition of the present invention is preferably
  • ester-based wax which is solid at 25 ° C, for example cerecine wax or
  • Candelilla wax may be also used.
  • the wax preferably has a content of 1.5 to 10 % by weight. If the content of the wax is less than 1.5 % by weight, then a level of solidification is relatively lower, and if it exceeds 10 % by weight, the pasting property may be deteriorated and the sweating phenomenon may arise since it is difficult to undergo the
  • solid cosmetic composition in the form of water-in-oil emulsion of the
  • the present invention includes 1 to 5 % by weight of the emulsifier, based on the total weight of the composition.
  • the ionic or non-ionic surfactant generally used in the cosmetic materials may be used for the emulsifier.
  • an anionic surfactant such as higher alkyl sulfate, alkyl ether sulfate, higher fatty acid amid sulfonate, alkyl benzene sulfonate, N-acyl glutaminate, higher fatty acid ester sulfonate and others
  • a cationic surfactant such as alkyl trimethyl ammonium salt, dialkyldimethyl ammonium salt, alkyl pyridinium salt, alkyldimethyl benzyl ammonium salt, alkylamine salt, polyamine fatty acid derivatives, amyl alcohol fatty acid derivatives and others; a
  • positive surfactant such as imidazole-based positive surfactant, betain-based positive
  • non-ionic surfactant such as sorbitan fatty acid ester, glycerine poly glycerine fatty acids, propylene glycol fatty acid ester, glycerine alkyl
  • silicone polyoxyethylene glycerine fatty acid esters, polyoxyethylene alkyl ether, tetra
  • polyoxyethylene tetra polyoxypropylene ethylene diamine condensate and others may be
  • Polyoxy alkylene-modified silicone or alkylpolyoxy alkylene-positively modified silicone is most preferred, considering the feeling, the emulsion stability and so on of the cosmetic composition.
  • the solid cosmetic composition in the form of water-in-oil emulsion of the present invention includes 10 to 50 % by weight, and preferably 15 to 30 % by weight of
  • Clay mineral powder such as titanium dioxide, particulate titanium dioxide, zinc oxide, iron oxide,
  • titanium dioxide/zinc oxide complex titanium dioxide/zinc oxide complex, alumina, talc, mica, kaolin, barium silicate, zeolite,
  • the pigment powder is more preferably hydrogenated.
  • the surface of the pigment powder is treated with high-viscosity silicone, treated by reacting alkyl hydrogen polysiloxane, treated with a cationic, anionic or non-ionic surfactant, or surface-coated with wax, may be used as the hydrogenation, but not
  • present invention includes 5 to 40 % by weight, and preferably 10 to 25 % by weight of
  • the aqueous component based on the total weight of the composition.
  • component is a major component that gives the clear and moist feeling to the cosmetic
  • composition of the present invention composition of the present invention.
  • Polyol-based moisturizing agents such as betain,
  • butyleneglycol, polydric alcohol, sugar-protein complex, organic acid, organic salts, glycerine and propyleneglycol, dipropyleneglycol and others may be used alone or in combination thereof together with water.
  • compositions of Examples 1 to 3 and Comparative examples 1 to 3 were prepared on the basis of components and their contents as listed in the following Table 1.
  • materials 1-9 were heated to 80-85 ° C and dissolved, and then materials
  • liquid phase to the powder the pasting property, the powdery feeling, and the overall satisfaction index were evaluated according to the following evaluation.
  • composition according to the present invention has the excellent feeling such as the
  • the solid cosmetic composition in the form of water-in-oil emulsion of the present invention is a stable composition in which the sweating phenomenon is inhibited at high temperature due to
  • Lipstick was prepared on the basis of components and their contents as listed in
  • materials 10-13 were added thereto and homogeneously dispersed to obtain lipstick.
  • the lipstick prepared in the Example 4 was evaluated for the feeling and
  • Fig. Ib the commercially available powder foundation
  • Fig. Ic the cosmetic
  • the solid cosmetic composition in the form of water-in-oil emulsion of the present invention has the excellent finishing effect of the makeup nearly identical to the commercially available powder foundation.
  • the dynamic friction coefficient was measured by an in vitro method using
  • a PE film was firstly adhered to a backlight plate, and then 2 mg/cm 2 of
  • the cosmetic composition was applied to a path in which a cylindric probe moves. Then, another PE film was also adhered to the cylindric probe. The dynamic friction coefficients were measured with a load cell by reciprocating the cylindric probe at a rate
  • Fig. 2 As shown in Fig. 2, it was revealed that, in the case A, the dynamic friction coefficient was constantly maintained with the passage of time from the beginning when the stress is increased, while, in the case B, the initial dynamic friction coefficient was measured high, but the dynamic friction coefficient was significantly lowered as the force is increased, and then constantly maintained. From the fact that the initial dynamic friction coefficients was significantly lowered due to the sheer thinning effect of the gelling agent, it was seen that the phase change from the solid phase to the liquid
  • emulsion according to the present invention may be useful to show an excellent stability

Abstract

L'invention concerne une composition cosmétique solide sous forme d'émulsion d'eau dans une huile. Cette composition cosmétique solide sous forme d'émulsion d'eau dans une huile contient 0,1 à 2 % en masse d'un agent gélifiant inorganique, 0,1 à 6 % en masse d'un agent gélifiant organique, 10 à 60 % en masse de composants huileux, notamment une huile volatile, 1,5 à 10 % en masse de cire, 1 à 5 % en masse d'un émulsifiant, 10 à 50 % en masse de pigments et 5 à 40 % en masse de composants aqueux, sur la base de la masse totale de la composition. Cette composition cosmétique solide sous forme d'émulsion d'eau dans une huile présente une excellente stabilité à la transpiration, ainsi qu'un excellent indice de satisfaction global pour la sensation d'humidité, une très faible propriété de collage en raison d'un changement de phase facile entre une phase solide et une phase liquide lors de son application, et un effet de fini du maquillage en poudre dû au changement de phase rapide entre la phase liquide et la poudre après son application.
PCT/KR2004/002311 2004-09-10 2004-09-10 Composition cosmetique solide sous forme d'emulsion d'eau dans une huile avec un agent gelifiant WO2006028308A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PCT/KR2004/002311 WO2006028308A1 (fr) 2004-09-10 2004-09-10 Composition cosmetique solide sous forme d'emulsion d'eau dans une huile avec un agent gelifiant

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/KR2004/002311 WO2006028308A1 (fr) 2004-09-10 2004-09-10 Composition cosmetique solide sous forme d'emulsion d'eau dans une huile avec un agent gelifiant

Publications (1)

Publication Number Publication Date
WO2006028308A1 true WO2006028308A1 (fr) 2006-03-16

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Country Link
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI693945B (zh) * 2015-08-03 2020-05-21 日商資生堂股份有限公司 油中水型乳化固形化妝料
US20200214948A1 (en) * 2018-02-07 2020-07-09 Shiseido Company, Ltd. Solid w/o cosmetic composition
WO2022270398A1 (fr) * 2021-06-22 2022-12-29 株式会社 資生堂 Matériau cosmétique solide émulsifié de type eau dans huile

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5552136A (en) * 1994-05-25 1996-09-03 The Procter & Gamble Company Gel stick compositions comprising optically enriched gellants
US5948393A (en) * 1992-11-30 1999-09-07 Shiseido Company, Ltd. Make-up cosmetic composition
US6210692B1 (en) * 1998-08-16 2001-04-03 L'oreal S.A. Emulsion comprising a hydrophilic thickening compound and a polysaccharide alkyl ether, compositions and products comprising the emulsion, and uses thereof
KR20020007062A (ko) * 2000-07-15 2002-01-26 손 경 식 실리콘유중수형 에멀젼 제형의 화장료 조성물

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5948393A (en) * 1992-11-30 1999-09-07 Shiseido Company, Ltd. Make-up cosmetic composition
US5552136A (en) * 1994-05-25 1996-09-03 The Procter & Gamble Company Gel stick compositions comprising optically enriched gellants
US6210692B1 (en) * 1998-08-16 2001-04-03 L'oreal S.A. Emulsion comprising a hydrophilic thickening compound and a polysaccharide alkyl ether, compositions and products comprising the emulsion, and uses thereof
KR20020007062A (ko) * 2000-07-15 2002-01-26 손 경 식 실리콘유중수형 에멀젼 제형의 화장료 조성물

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI693945B (zh) * 2015-08-03 2020-05-21 日商資生堂股份有限公司 油中水型乳化固形化妝料
US20200214948A1 (en) * 2018-02-07 2020-07-09 Shiseido Company, Ltd. Solid w/o cosmetic composition
WO2022270398A1 (fr) * 2021-06-22 2022-12-29 株式会社 資生堂 Matériau cosmétique solide émulsifié de type eau dans huile

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