WO2006022002A1 - レベリング剤および該レベリング剤を含む水性フロアーポリッシュ組成物 - Google Patents
レベリング剤および該レベリング剤を含む水性フロアーポリッシュ組成物 Download PDFInfo
- Publication number
- WO2006022002A1 WO2006022002A1 PCT/JP2004/012210 JP2004012210W WO2006022002A1 WO 2006022002 A1 WO2006022002 A1 WO 2006022002A1 JP 2004012210 W JP2004012210 W JP 2004012210W WO 2006022002 A1 WO2006022002 A1 WO 2006022002A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- floor polish
- integer
- aqueous floor
- leveling agent
- nonionic surfactant
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09G—POLISHING COMPOSITIONS; SKI WAXES
- C09G1/00—Polishing compositions
- C09G1/04—Aqueous dispersions
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/47—Levelling agents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09G—POLISHING COMPOSITIONS; SKI WAXES
- C09G1/00—Polishing compositions
- C09G1/06—Other polishing compositions
- C09G1/08—Other polishing compositions based on wax
- C09G1/10—Other polishing compositions based on wax based on mixtures of wax and natural or synthetic resin
Definitions
- Leveling agent and aqueous floor polish composition comprising the leveling agent
- the present invention relates to a leveling agent useful as a component of an aqueous floor polish.
- the present invention also relates to an aqueous floor polish composition containing the leveling agent and having excellent leveling properties, glossiness, water resistance, storage stability and the like.
- water-based polishes have a wide range of use, for example, for protecting various articles, for brewing to maintain aesthetics, as floor polish for commercial facilities such as supermarkets, department stores, hotels, or households, and for buildings. It is useful for painting outer walls of structures such as bridges and bridges, or as a mold release agent.
- the coating film formed by applying aqueous polish to the surface should be excellent in properties such as glossiness, water resistance, acid resistance, alkali resistance, weather resistance, abrasion resistance and adhesion, depending on the application. Is needed.
- floor polish used for flooring is required to have the performance of maintaining the appearance and cleanliness by the squeezing effect, as well as the wear of flooring, prevention of dirt adhesion, and prevention of slip accidents.
- TBEP trisbutoxetyl phosphate
- aqueous floor polish formulations are described in Patent Document 1, Patent Document 2, JIS K3920 (Floor Polish Test Method), JFPA Standard (Japanese Floor Polish Industry Association Standard), and the like. According to these, leveling agents, emulsion polymerization resin emulsions, wax emulsions, alkali-soluble resins, plasticizers, solvents, and compounds having a surfactant action are blended in the aqueous floor polish. Yes. By blending all or part of them in appropriate amounts, the interaction of each component occurs and is required for specific applications. Performance is obtained.
- Examples of compounds blended in an aqueous floor polish for improving performance include alkoxylated linear aliphatic alcohols described in Patent Documents 3 and 8, adipic acid esters described in Patent Document 4, and the like. N-methyl-2-pyrrolidones and the like, alkylcarboxylic acids described in Patent Document 6, polyethoxylated fatty alcohols described in Patent Document 7, and the like are known. However, when these compounds are released into the environment, there is a high risk of adverse effects on the human body and ecosystem. There is no known floor polish that can sufficiently satisfy leveling properties, glossiness, water resistance, and storage stability without using such a compound.
- Patent Document 1 SHOKO 44-24407
- Patent Document 2 Shoko 49-1458
- Patent Literature 3 Japanese Patent Publication 6-23335
- Patent Document 4 JP-A-6-80933
- Patent Document 5 JP 2001-302990 A
- Patent Document 6 Special Table 2002-506479
- Patent Document 7 JP-A-6-33016
- Patent Document 8 USP4131585
- the present invention is sufficient in leveling properties, glossiness, water resistance, and storage stability without using a compound that has a high risk of adversely affecting the human body and ecosystem when released into the environment.
- An object is to provide an aqueous floor polish having excellent performance.
- the present invention relates to a leveling agent for aqueous floor polish containing a nonionic surfactant, wherein the nonionic surfactant is a compound represented by the following general formula (1):
- R 1 represents an alkyl group having 4 to 10 carbon atoms
- R 2 represents an alkyl group having 6 to 12 carbon atoms
- m is an integer from 1 to 10
- n is an integer from 0 to 6.
- the order of addition of the ethylene oxide unit and the propylene oxide unit is arbitrary, and the block type force random type may be shifted or shifted.
- R 3 represents a residue of at least one aliphatic alcohol selected from 3, 5, 5-trimethylhexanol, isooctyl alcohol, isodecyl alcohol, isodecyl alcohol and isotridecyl alcohol; p is an integer of 0 8, q is an integer of 0—8, and p + q is an integer of 2 8.
- the addition order of the ethylene oxide unit and the propylene oxide unit is arbitrary, and may be either a block type or a random type.
- a leveling agent for aqueous floor polish characterized in that it is at least one nonionic surfactant selected from the group consisting of: and an aqueous floor polish characterized by containing the above leveling agent It is a composition.
- R 1 in the above general formula (I) is an alkyl group having 4 to 10 carbon atoms, preferably 4 to 8 carbon atoms, more preferably 4 to 6 carbon atoms
- R 2 is 6 to 12 carbon atoms, preferably 6 to 10 carbon atoms, More preferably, it is 8 10 alkyl groups.
- R 1 and R 2 can each be a single alkyl group or a mixture of two or more alkyl groups.
- R 1 and R 2 are, for example, 2-butyldecanol, 2-hexyloctanol, 2_hexyldecanol, 2-octyldecanol, 2_hexyldecanol, It can be a residue of 2-octyldodecanol, 2-decyltetradecanol.
- m which specifies the number of moles of ethylene oxide added, is an integer of 1 to 10, preferably an integer of 2 to 8, more preferably an integer of 3 to 5.
- N which specifies the number of moles of propylene oxide added, is an integer from 0 to 6, preferably an integer from 1 to 5, and more preferably an integer from 24.
- p specifies the number of moles of ethylene oxide added.
- P is an integer of 0 8, preferably an integer of 1 to 8, more preferably an integer of 26.
- Q which specifies the number of moles of propylene oxide added, is an integer of 08, preferably an integer of 06, and more preferably an integer of 115.
- a leveling agent comprising a nonionic surfactant of the above general formula (I) or (i) in which ethylene oxide and / or propylene oxide is added to a branched aliphatic alcohol into the floor polish
- Performance improvements such as leveling, gloss, water resistance and storage stability can be achieved.
- these nonionic surfactants are not phosphorus compounds, they can be preferably used as yarns and compositions for aqueous floor polish that do not adversely affect the ecosystem even when released into the environment.
- the amount of at least one nonionic surfactant selected from the above general formulas (I) and (II) in the aqueous floor polish composition is preferably 0.1 to 15% by weight.
- An emulsion polymerization resin emulsion obtained by emulsion polymerization of at least one ethylenically unsaturated monomer is added to the aqueous floor polish composition of the present invention in a solid content of 5 to 60% by weight, preferably 10%. — By containing 30% by weight, a more uniform coated surface can be provided.
- This emulsion polymerization resin emulsion is composed of ethyl acrylate, propyl acrylate, butyl acrylate, isobutyl acrylate, octyl acrylate, dodecyl acrylate, 2-ethylhexyl acrylate, methyl methacrylate, methacrylic acid.
- C1-C8 alkyl acrylate and meta acrylate such as ethyl acetate, propylene methacrylate, ethyl hexyl methacrylate, butyl methacrylate, mono- and di (C1-C5) alkyl itaconate and fumarate, maleic acid Anhydride, vinylidene chloride, styrene, m-methylstyrene, o-methylstyrene, p-methylstyrene, p-phenylstyrene, p-chlorostyrene, dichloros Tylene, butyltoluene, acrylonitrile, methacrylonitrile, acrylic amide, methacrylic amide, acrylic acid, methacrylic acid, itaconic acid, fumaric acid, citraconic acid, crotonic acid, beta-ataryloxypropionic acid, and hydroxy (C1 1 C6) alkyl ate relay It can be obtained
- the MFT (minimum film-forming temperature) of the emulsion polymerization resin emulsion is 50 ° C or higher and 85 ° C or lower, preferably 55 ° C or higher and 80 ° C or lower, the floor polish composition has excellent contamination resistance. Things are obtained.
- the polymerization resin emulsion whose MFT is less than 50 ° C can also be used in combination as necessary for the purpose of imparting slip resistance, etc.If it is less than 50 ° C, tackiness is severe and contamination resistance is reduced, which is preferable. Nare ,.
- a polymerization resin emulsion having an MFT of less than 50 ° C it is preferably used in combination with a polymerization resin emulsion having an MFT of 30% by weight or more based on the resin content in the polymerization resin emulsion of 50 ° C or more.
- the coating strength of the aqueous floor polish composition of the present invention is improved by further blending a polyolefin having a carboxyl group with an average particle size of 20 to 500 nm, preferably 20 to 300 nm. be able to.
- Polyolefin emulsions having carboxynole groups can be produced by various emulsification methods using olefin waxes with carboxyl groups, such as oxidized polyethylene wax, oxidized polypropylene wax, acid-modified polyethylene wax, and acid-modified polypropylene wax.
- the particle size of the emulsion obtained varies depending on the emulsification method, the type of surfactant, and the amount used, and affects the performance and stability of the floor polish.
- the average particle size of emulsion obtained by emulsifying under pressure is larger than 500 nm, the gloss of the aqueous polish is poor and the gloss after coating is lowered.
- the amount of the leveling agent used in the present invention is preferably 1 to 20% by weight based on the solid content of the emulsion polymerization resin emulsion. More preferably, it is 5 15% by weight. By using in this amount range, sufficient leveling performance can be obtained, and deterioration in durability can be avoided. That power s.
- a surfactant other than the nonionic surfactants represented by the general formulas (I) and (II) may be used in combination.
- aqueous floor polish composition of the present invention can be combined with various additives other than those described above.
- additives include alkali-soluble resins, nonionic or anionic dispersants, wetting agents, alkaline compounds, transition metal crosslinking agents, waxes, plasticizers, film-forming aids such as glycol solvents, triazines or thiazolines. These include antiseptics of the type, silicone type or fluorine type antifoaming agent.
- MFT was measured based on JIS K6828-2.
- Ethylene oxide (EO) at 160 ° C-170 ° C and propylene oxide (P0) at 130-140 ° C were added to the branched aliphatic alcohols shown in Table 1 using caustic potash as a catalyst. .
- Table 1 shows the number of moles of alcohol and ethylene oxide and propylene oxide used.
- Raw materials 1 to 4 are charged into a mixing container at room temperature and stirred for 10 minutes, and then raw materials 56 are charged and stirred for 10 minutes. Thereafter, the raw material 7 was charged, stirred for 10 minutes, filtered through a 150 mesh filter, and allowed to stand for 24 hours or more to obtain a floor polish composition.
- the test was carried out in accordance with JIS K3920 15.
- the results shown in Table 2 are after 3 times of application ⁇ Peelability test>
- the test was performed according to JIS K3920 20.
- the aqueous floor polish containing the leveling agent of the present invention (Examples 11-7) has leveling properties, glossiness, peelability, recoatability, It was excellent in water resistance and storage stability.
- the potassium persulfate lg was freed, and then a monomer mixture of 130 g of styrene, 30 g of methinolemethalate, 60 g of atanolenoic acid butynoate and 20 g of methacrylic acid was added in 2 hours using a dropping funnel. It was dropped and polymerized. On the way, potassium persulfate lg was added. Subsequently, after aging at about 75-80 ° C for 2 hours, it was cooled to obtain an emma / resion. The MFT was 55 ° C.
- Inner volume with a thermometer, stirrer, and temperature controller 1.5 g of emulsification equipment, melting point 135 ° C, density 0.93 polyethylene oxide (formerly known as Alide Chemical Co. AC-392) 300 g, ion-exchanged water 650g, Pegnol D_208, Pegnol D_210, Pegnol D-214 (all nonionic surfactants manufactured by Toho Chemical Industry Co., Ltd.) 30g each and 48% potassium hydroxide lOg were added and replaced with nitrogen. Thereafter, the mixture was emulsified by stirring at 160 ° C for 2 hours at high speed. Subsequently, it cooled and the sample was obtained. The average particle size was 120 nm ⁇ Preparation of aqueous floor polish>
- raw materials 1 to 4 are charged into a mixing container and stirred for 10 minutes, and then raw materials 56 are charged and stirred for 10 minutes. Thereafter, the raw material 7 was charged, stirred for 10 minutes, filtered through a 150 mesh filter, and allowed to stand for 24 hours or more to obtain a floor polish composition.
- the test was performed in accordance with 22 ⁇ of JIS K-3920.
- the aqueous floor polish (Examples 8 to 14) containing the leveling agent of the present invention has leveling properties, heel mark resistance, water resistance, It was excellent in gloss, recoatability and storage stability.
- the leveling agent of the present invention can provide an aqueous floor polish having excellent leveling properties, glossiness, water resistance, and storage stability.
- the leveling agent has the advantage that it has a low environmental impact and high safety.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Dispersion Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
Abstract
Description
Claims
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/JP2004/012210 WO2006022002A1 (ja) | 2004-08-25 | 2004-08-25 | レベリング剤および該レベリング剤を含む水性フロアーポリッシュ組成物 |
US11/660,740 US20090114117A1 (en) | 2004-08-25 | 2004-08-25 | Leveling agent and water-based floor-polishing composition comprising the leveling agent |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/JP2004/012210 WO2006022002A1 (ja) | 2004-08-25 | 2004-08-25 | レベリング剤および該レベリング剤を含む水性フロアーポリッシュ組成物 |
Publications (1)
Publication Number | Publication Date |
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WO2006022002A1 true WO2006022002A1 (ja) | 2006-03-02 |
Family
ID=35967225
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2004/012210 WO2006022002A1 (ja) | 2004-08-25 | 2004-08-25 | レベリング剤および該レベリング剤を含む水性フロアーポリッシュ組成物 |
Country Status (2)
Country | Link |
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US (1) | US20090114117A1 (ja) |
WO (1) | WO2006022002A1 (ja) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2008056862A (ja) * | 2006-09-01 | 2008-03-13 | Pentel Corp | ボールペン用水性インキ |
Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4131585A (en) * | 1976-11-15 | 1978-12-26 | Sybron Corporation | Leveling agent for floor polishes |
JPH0693233A (ja) * | 1992-09-11 | 1994-04-05 | Kao Corp | 床用被覆組成物 |
JPH0693232A (ja) * | 1992-09-11 | 1994-04-05 | Kao Corp | 木材用つや出し剤組成物 |
JPH06108011A (ja) * | 1992-10-01 | 1994-04-19 | Kao Corp | 水性床用つや出し剤組成物 |
JPH08504860A (ja) * | 1992-12-22 | 1996-05-28 | ヘンケル・エコラープ・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング・ウント・コンパニー・オッフェネ・ハンデルスゲゼルシャフト | 床保護のための中性自己光輝エマルジョン(▲iii▼) |
JP2004091713A (ja) * | 2002-09-03 | 2004-03-25 | Jsr Corp | 艶出し剤用組成物 |
JP2004238593A (ja) * | 2003-02-04 | 2004-08-26 | Toho Chem Ind Co Ltd | 水性フロアーポリッシュ用レベリング剤 |
JP2004238596A (ja) * | 2003-02-04 | 2004-08-26 | Toho Chem Ind Co Ltd | 水性フロアーポリッシュ用組成物 |
JP2004238594A (ja) * | 2003-02-04 | 2004-08-26 | Toho Chem Ind Co Ltd | 水性フロアーポリッシュ用レベリング剤 |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4460734A (en) * | 1983-04-19 | 1984-07-17 | Rohm And Haas Company | Self-leveling floor polish compositions |
-
2004
- 2004-08-25 WO PCT/JP2004/012210 patent/WO2006022002A1/ja active Application Filing
- 2004-08-25 US US11/660,740 patent/US20090114117A1/en not_active Abandoned
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4131585A (en) * | 1976-11-15 | 1978-12-26 | Sybron Corporation | Leveling agent for floor polishes |
JPH0693233A (ja) * | 1992-09-11 | 1994-04-05 | Kao Corp | 床用被覆組成物 |
JPH0693232A (ja) * | 1992-09-11 | 1994-04-05 | Kao Corp | 木材用つや出し剤組成物 |
JPH06108011A (ja) * | 1992-10-01 | 1994-04-19 | Kao Corp | 水性床用つや出し剤組成物 |
JPH08504860A (ja) * | 1992-12-22 | 1996-05-28 | ヘンケル・エコラープ・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング・ウント・コンパニー・オッフェネ・ハンデルスゲゼルシャフト | 床保護のための中性自己光輝エマルジョン(▲iii▼) |
JP2004091713A (ja) * | 2002-09-03 | 2004-03-25 | Jsr Corp | 艶出し剤用組成物 |
JP2004238593A (ja) * | 2003-02-04 | 2004-08-26 | Toho Chem Ind Co Ltd | 水性フロアーポリッシュ用レベリング剤 |
JP2004238596A (ja) * | 2003-02-04 | 2004-08-26 | Toho Chem Ind Co Ltd | 水性フロアーポリッシュ用組成物 |
JP2004238594A (ja) * | 2003-02-04 | 2004-08-26 | Toho Chem Ind Co Ltd | 水性フロアーポリッシュ用レベリング剤 |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2008056862A (ja) * | 2006-09-01 | 2008-03-13 | Pentel Corp | ボールペン用水性インキ |
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US20090114117A1 (en) | 2009-05-07 |
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