WO2005102141A1 - Distributeur - Google Patents

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Info

Publication number
WO2005102141A1
WO2005102141A1 PCT/GB2005/001546 GB2005001546W WO2005102141A1 WO 2005102141 A1 WO2005102141 A1 WO 2005102141A1 GB 2005001546 W GB2005001546 W GB 2005001546W WO 2005102141 A1 WO2005102141 A1 WO 2005102141A1
Authority
WO
WIPO (PCT)
Prior art keywords
dispenser
apertures
aperture
fragrance
blister
Prior art date
Application number
PCT/GB2005/001546
Other languages
English (en)
Inventor
Karl-Ludwig Gibis
Chris Efstathios Housmekerides
Rainer Link
Original Assignee
Reckitt Benckiser N.V.
Reckitt Benckiser (Uk) Limited
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Reckitt Benckiser N.V., Reckitt Benckiser (Uk) Limited filed Critical Reckitt Benckiser N.V.
Priority to EP05741955A priority Critical patent/EP1737333B1/fr
Priority to AU2005235344A priority patent/AU2005235344B2/en
Priority to BRPI0510037-2A priority patent/BRPI0510037A/pt
Priority to DE602005014960T priority patent/DE602005014960D1/de
Priority to US11/568,080 priority patent/US20080011870A1/en
Priority to CA002560006A priority patent/CA2560006A1/fr
Priority to AT05741955T priority patent/ATE433704T1/de
Publication of WO2005102141A1 publication Critical patent/WO2005102141A1/fr

Links

Classifications

    • A—HUMAN NECESSITIES
    • A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47L—DOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
    • A47L15/00—Washing or rinsing machines for crockery or tableware
    • A47L15/42—Details
    • A47L15/44—Devices for adding cleaning agents; Devices for dispensing cleaning agents, rinsing aids or deodorants
    • A47L15/4481—Deodorants, perfumes or odor removals
    • A—HUMAN NECESSITIES
    • A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47L—DOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
    • A47L15/00—Washing or rinsing machines for crockery or tableware
    • A47L15/42—Details
    • A47L15/44—Devices for adding cleaning agents; Devices for dispensing cleaning agents, rinsing aids or deodorants

Definitions

  • the present invention relates to a dispenser for an automatic dishwashing machine, particularly for use in the dispense of a fragrance.
  • Automatic dishwashing is a well recognised field. It provides convenience to a consumer in comparison to manual dishwashing.
  • alodour One problem associated with the use of automatic dishwashers is that of alodour. This is typically caused by the presence of a residual amount of wash liquor retained in a part of the machine after use. Microbiological action on this residual liquor can cause a generation of malodour, which although harmless, is unwelcome .
  • the malodour is noticeable when the machine is left open between wash cycles and especially at the end of a wash cycle.
  • the emanators used generally comprise a cage for attachment to a part of the dishwasher and a source of fragrance (such as a blister) contained therein.
  • the first problem is that of the rate of release of the fragrance. Normally the fragrance release follows a reverse exponential curve: initially the release of fragrance is strong, with the rate of release diminishing with time. Indeed in the early stages of use the large amount of fragrance released, whilst addressing the malodour issue, can reach an equally unpleasant level. Conversely towards the end of the life cycle of the fragrance emanator the release of fragrance is often so weak that the malodour issue is not effectively addressed.
  • Fragrances whether a natural or man-made, comprise a complex admixture of components, wherein each component provides a different element to the overall fragrance.
  • a dispenser for an automatic dishwasher comprising a body having an aperture for release of an active component, the extent of opening of the aperture being controllable, and wherein the active is contained in a blister disposed in the body.
  • the active component is a fragrance.
  • the fragrance is generally used to address malodour issues prevalent in automatic dishwashers.
  • the dispenser of the present invention has been found to have excellent properties. These properties are particularly pertinent when the release profile of the most preferred active component, fragrance, is considered.
  • the dispenser has been found to be able to release the fragrance in a linear fashion both over and between a large number of automatic dishwasher wash cycles (typically between 50 and 100 wash cycles. This is in contrast to previous dispensers. Furthermore with the dispenser of the invention linear release has been observed at varying opening extents of the aperture. Thus not only is the dispenser able to dispense a fragrance at a linear rate but also the rate of the release has been found to be adjustable, without having an adverse effect on the linearity of the release.
  • the dispenser of the present invention has been found to overcome the problem of differential release of different components of the fragrances. That is to say, throughout the working life of the dispenser of the present invention the fragrance released is virtually identical to that of the ⁇ fresh' fragrance. Without wishing to be bound by theory it is postulated that this effect is achieved by the creation of a zone of saturated fragrance in the headspace of the dispenser.
  • the extent of opening of the aperture is controlled by a gate mounted on the body.
  • the gate is mounted such that it may be moved relative to the body to affect the opening extent of the aperture.
  • the gate is mounted relative to the body such that rotation of the gate relative to the body varies the opening extent of the aperture.
  • the gate preferably comprises an apertured member. In this way when the aperture of the gate is at least partially aligned with the body aperture dispense of the active component may occur.
  • the degree of alignment may preferably be varied to affect a variable rate of release.
  • the dispenser may have an indication system which displays the degree of alignment between the gate and the body (and hence the expected rate of release) to the user.
  • the aperture on the body may be split into a series of apertures with a bespoke aperture for each level of release.
  • the aperture on the body may be split into two separate apertures; one large aperture for a high rate of release (with the aperture on the gate being the same size as that of the body) and a smaller aperture for a lower rate of release.
  • the series of apertures may be on the gate rather than on the body.
  • the body has a plurality of apertures to allow release of the active component (and also for inflow/ drainage of wash liquor) .
  • the gate also has a plurality of apertures (most preferably one gate aperture per one body aperture) .
  • the aperture is subdivided into a series of apertures there may be a plurality of these series of apertures.
  • the apertures are arranged in a regular pattern on a side wall of the body.
  • the body has a means to permit attachment to the inside of a dishwasher.
  • the attachment means is in the form of a hook or a clip.
  • the body has a window so that the user is able to see the blister retained within the body. In this way the user is able to assess the contents of the blister and hence can obtain an indication of the likely remaining lifetime of the blister.
  • the window is most preferably in the form of an aperture in the body. Preferably the window is sealed by being filled with the blister.
  • the reservoir body comprises a substantially planar base.
  • the base is permeable to allow the contents of the blister to emanate in use. It is preferred that the reservoir (preferably enclosed in a skin) projects from a surface of the base. Most preferably the reservoir is stepped having a lower most and an upper most portion. Preferably, in use, the upper most portion of the reservoir body extends into the window aperture of the body. Preferably, in use, the lower most portion of the reservoir body extends beneath and behind a lower edge of the window aperture of the body.
  • the body is opaque, only the portion of the reservoir body which extends into the window aperture is visible when the blister is mounted in the body.
  • the blister has a hidden portion, which may, when appropriate conceal a residue of a component which is to be released from the emanator. In this way the presence of any residue (particularly from a fragrance composition) does not detrimentally effect the impression of the user as to whether the blister needs to be replaced.
  • the volume of the portion of the reservoir body which is hidden may be varied to suit the expected amount of residue remaining in the blister.
  • the volume of the reservoir body which is hidden comprises around 15% of the volume of the entire reservoir. (It has been found that typical fragrance compositions leave a residue of up to 15% by volume after the active components thereof have been allowed to/cause to emanate. Thus a large portion of the reservoir body (around 85% by volume) may be observed by user. This gives excellent indication of the use of the blister contents and end-of- life indication.
  • the blister more particularly the skin of the blister, is transparent so as to allow the user to view the contents thereof.
  • the blister contains a fragrance composition.
  • the fragrance composition contains a dye and/or a colouring agent.
  • the dye/colouring agent may give an indication of the nature of the fragrance for added consumer recognition/appeal.
  • an apple' fragrance may have a green colour and a ⁇ citrus' fragrance a yellow/orange colour.
  • Figure 1 is a plan view of the components of the body of the dispenser of the invention.
  • Figure 2 is an underneath plan view of the components of the body of the dispenser of the invention.
  • Figure 3 is a perspective view of an exploded device of the invention.
  • Figure 4 is an alternative perspective view of an exploded device of the invention.
  • Figure 5 is a plan view of the components of the body of an alternative embodiment of the invention.
  • Figure 6 is an underneath plan view of an assembled device of the alternative embodiment of the dispenser of the invention;
  • Figure 7 is a side view of an assembled device of the alternative embodiment of the dispenser of the invention.
  • Figures 8 and 9 show side views of a preferred embodiment of a blister which can be used in the dispense of the invention.
  • Figures 10 and 11 show cross sections of the blister of figures 8 and 9 taken along the longitudinal access A-A and the equatorial access B-B respectively.
  • the dispenser 1 of the present invention comprises a body 2, a blister 3 and a gate 4.
  • the body 2 comprises a front section 5 and a rear section 6. Both the front section 5 and the rear section 6 include a largely circular portion 7 and an extended portion 8. The front section 5 and the rear section 6 adjoin by virtue of a ⁇ snap fit' arrangement.
  • the extended section 8 of the front section 5 includes a hook 10 for mounting the body within an automatic dishwasher (not shown) .
  • the interior side of the front section 5 has a lip 11 arranged around the window aperture 9. The lip 11 provides support for the blister 3 to be mounted within the body 2 adjacent the window aperture a 9 such that the contents of the blister 3 are visible form the exterior of the body 2.
  • the circular portion 7 of the rear section 6 is stepped. This provides a volume within the body 2 for retention of the blister 3.
  • the circular portion 7 includes a number of clusters of apertures 12 arranged with regular spacing. Each cluster 12 comprises three individual apertures; a,b,c, arranged in an inverted ⁇ I/ configuration .
  • the extended section 8 of the rear section 6 includes a series of markings; ⁇ HI' , MED' and ⁇ LO' . The significance of these markings will become clear with reference to the gate 4.
  • the gate 4 includes a largely circular portion 7 and a limb extension 13.
  • the circular portion 7 of the gate 4 is stepped in the same way as the rear section 6 of the body 2.
  • the circular portion 7 includes a number of clusters of apertures 14 arranged with regular spacing. Each cluster 14 comprises two individual apertures; I, II, arranged in an I ' configuration.
  • the limb extension 13 of the gate 4 extends beyond the markings on the extended section 8 of the rear portion 6.
  • the limb extension 13 includes a window 15. The markings are intended to be visible through the window 15 of the limb extension 13.
  • the gate 4 is mounted adjacent the rear section 6 so that the gate 4 may be rotated relative to the rear section 6. In this way the clusters of apertures 14 on the gate 4 may be arranged relative to the cluster of apertures 12 on the rear section 6.
  • the window 15 of the limb extension 13 of the gate 4 is aligned such that the marking ⁇ LO' is visible therethrough. In this orientation none of the apertures I, II on the gate 4 are aligned with the apertures a,b,c on the rear section 6.
  • the window 15 of the limb extension 13 of the gate 4 is aligned such that the marking ⁇ MED' is visible therethrough.
  • the apertures I on the gate 4 are aligned with the apertures a on the rear section 6.
  • the window 15 of the limb extension 13 of the gate 4 is aligned such that the marking HI' is visible therethrough.
  • the apertures I and II on the gate 4 are aligned with the apertures b and c on the rear portion 6.
  • the body 2 comprises a front section 5 and a rear section 6.
  • the front section 5 and the rear section 6 adjoin by virtue of a ''snap fit' arrangement. Both the front section 5 and the rear section 6 are dished to provide a volume within the body 2 for retention of the blister 3.
  • the rear section 6 includes a hook 10 for mounting the body within an automatic dishwasher.
  • the periphery of the front section 5 includes a number of clusters of apertures 12 arranged with regular spacing. Each cluster 12 comprises four individual apertures; a,b,c,d, arranged in a row. The periphery of the rear section 6 is cutaway in sections to create four projections 16.
  • the front section 5 is mounted adjacent the rear section 6 so that the front section 5 may be rotated relative to the rear section 6. In this way the clusters of apertures 12 on the front section 5 may be arranged relative to the projections 16.
  • the front section 5 is aligned such that all of the apertures a,b,c,d are adjacent the projections 16 on the rear section 6. Thus none of the apertures a,b,c,d is open.
  • the front section 5 is aligned such that a decreasing number of the apertures a,b,c,d is adjacent the projections 16 on the rear section 6.
  • progressively the apertures a,b,c,d are opened with, finally in the fifth arrangement, all of the apertures a,b,c,d being open.
  • FIGS 8 to 11 show the preferred embodiment of the blister 3 for use with the dispenser 1.
  • the blister 3 comprises a base 17 in the form of an oval strip.
  • the oval base 17 comprises a permeable skin for release of the fragrance.
  • the base 17 is provided with two-stepped platforms 18 and 19 which project on the front side of the base 17.
  • the platform 18 has a similar shape to the base 17, namely it is oval, yet is smaller than the base 17, thus leaving a non-platformed perimeter 20 therearound.
  • the stepped platform 19 has a circular surface 21.
  • the surface 21 is inclined at an angle about an axis therethrough, the said axis being arranged parallel to the equatorial axis of the blister B-B.
  • the stepped platform 19 has a depth which varies along longitudinal axis A-A.
  • the surface 21 and most preferably the entire blister 3 is transparent.
  • the blister 3 is preferably supported in the body 2 by the lip 11 such that at least a portion of the surface 21 of the stepped platform 19 is visible through the window aperture 9. This allows the user to visually determine the amount of fragrance contained within the blister 3.
  • the platform 18 extends beneath and behind a lower edge of the window aperture 9. This arrangement allows the last remnants of liquid in the blister 3 to be hidden from a user. This serves as an aid to the user for blister replacement as typically the last remnants of fragrance solution contain little or no fragrance and mostly comprise colorant, i.e. is inactive' . If this portion is seen the user may perceive that the blister 3 is still capable of functioning thus the replacement of the blister 3 may be delayed. When hidden the presence of this ' 'inactive' will not dissuade the user from replacing the unit and thus the high efficacy of the blister 3 is maintained.
  • the blister 3 is mounted such that the longitudinal axis A-A is substantially vertical with the deepest part of the recess 19 uppermost. This serves to reduce the appearance of under-fill of the blister 3 - an important consideration for consumers.
  • the surface 22A of retainer 22 against which the upper surface 21 of the blister 3 abuts is arranged so as to be co-planer therewith. In the illustrated embodiment this is achieved by surface 22A being substantially domed.
  • the invention will be further illustrated with reference to the following non-limiting examples.
  • the fragrance dispense rate of a dispenser in accordance with the invention was measured in an automatic dishwashing machine.
  • a dispenser as shown in Figures 1 to 4 was used.
  • the dispenser contained a blister as shown in Figures 8 to 11.
  • the blister contained 4 grams of a commercially available dishwasher fragrance.
  • the fragrance release rate was measured by taking the weight of the blister after a number of cycles in an automatic dishwasher (Miele, model G 676 SC, program "Universal") which was run for a number of cycles at 65°C.
  • the weight loss was expressed as a percentage of fragrance lost from the blister (referring to the initial weight of 4g) .
  • LO means 0 open apertures.
  • MED means 8 open apertures.
  • HI means 16 open apertures.
  • the dispenser in accordance with the present invention has excellent release properties. Not only is the fragrance release linear in mature but also the rate of release can be varied (whilst still remaining linear) to suit the output required.
  • the Comparative Example has a very large uncontrollable rate of release with the rate of release displaying the usual reverse exponential decay.
  • a dispenser as shown in Figures 1 to 4 was used.
  • the dispenser contained a blister as shown in Figures 8 to 11.
  • the blister contained 4 grams of a commercially available dishwasher fragrance.
  • the nature of the fragrance released was tested taking a sample of the fragrance (from the inside of the blister) and feeding the sample into a Gas-Chromatograph (Agilent, model 6890 Series, columns HP-1, HP-5 Carbowax, carrier gas: Helium 1 ml/min; program 80°C to 250°C (10 min) , heating rate 6°C/min) . In this way the content of the fragrance could be measured.
  • Example 2 For the fragrance the top note, the medium notes and the low notes were measured after 60 washes under the wash conditions in Example 1 (with the dispenser at the medium setting) .
  • the measurements for the dispenser in accordance with the present invention were compared with the pure fragrance and with the fragrance from a dispenser which is outside the scope of the present invention.
  • the results of the analysis are shown in Table 2 (given as total peak area %) .
  • the fragrance after 60 washes is much closer to that of the fresh fragrance than that of the comparative Example.

Abstract

La présente invention concerne un distributeur (1) pour un lave-vaisselle automatique. Ce distributeur comprend un corps (2) qui présente un orifice (12, 14) conçu pour libérer un composant actif. Il est possible de contrôler l'envergure d'ouverture de cet orifice. Ledit composant actif est contenu dans un étui qui est placé dans ledit corps.
PCT/GB2005/001546 2004-04-21 2005-04-21 Distributeur WO2005102141A1 (fr)

Priority Applications (7)

Application Number Priority Date Filing Date Title
EP05741955A EP1737333B1 (fr) 2004-04-21 2005-04-21 Distributeur
AU2005235344A AU2005235344B2 (en) 2004-04-21 2005-04-21 Dispenser
BRPI0510037-2A BRPI0510037A (pt) 2004-04-21 2005-04-21 dispensador
DE602005014960T DE602005014960D1 (de) 2004-04-21 2005-04-21 Spender
US11/568,080 US20080011870A1 (en) 2004-04-21 2005-04-21 Dispenser
CA002560006A CA2560006A1 (fr) 2004-04-21 2005-04-21 Distributeur
AT05741955T ATE433704T1 (de) 2004-04-21 2005-04-21 Spender

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB0408811.8 2004-04-21
GB0408811A GB2413262B (en) 2004-04-21 2004-04-21 Dispenser for dishwashing additives

Publications (1)

Publication Number Publication Date
WO2005102141A1 true WO2005102141A1 (fr) 2005-11-03

Family

ID=32344088

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB2005/001546 WO2005102141A1 (fr) 2004-04-21 2005-04-21 Distributeur

Country Status (12)

Country Link
US (1) US20080011870A1 (fr)
EP (1) EP1737333B1 (fr)
CN (1) CN100581436C (fr)
AT (1) ATE433704T1 (fr)
AU (1) AU2005235344B2 (fr)
BR (1) BRPI0510037A (fr)
CA (1) CA2560006A1 (fr)
DE (1) DE602005014960D1 (fr)
ES (1) ES2328500T3 (fr)
GB (1) GB2413262B (fr)
WO (1) WO2005102141A1 (fr)
ZA (1) ZA200607479B (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008141473A1 (fr) 2007-05-23 2008-11-27 Givaudan Sa Dispositif de diffusion de parfum
WO2012114085A1 (fr) 2011-02-25 2012-08-30 Reckitt Benckiser N.V. Dispositif diffuseur
EP3066972A1 (fr) * 2015-03-09 2016-09-14 Henkel AG & Co. KGaA Dispositif d'emission de parfum pour un lave-vaisselle, lave-vaisselle comprenant un dispositif d'emission de parfum et procede destine a parfumer un lave-vaisselle

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070243507A1 (en) * 2006-04-14 2007-10-18 Denise Taylor Method for associative learning based upon the use of controlled release fragrances from substrates and product produced in accordance therewith
DE102008022219A1 (de) * 2008-05-06 2009-11-12 BSH Bosch und Siemens Hausgeräte GmbH Wasserführendes Haushaltsgerät und Kunststoffteil hierfür
US8616375B2 (en) 2012-01-13 2013-12-31 Whirlpool Corporation Packets for treating chemistry
EP2976983B1 (fr) 2014-07-24 2022-05-11 Whirlpool EMEA S.p.A. Distributeur de substance pour lave-vaisselle
AU2020397937A1 (en) 2019-12-06 2022-06-23 S. C. Johnson & Son, Inc. Dispenser and method of use thereof
US11382998B2 (en) 2019-12-19 2022-07-12 Wildlife Research Center, Inc. Scent device

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US4545917A (en) * 1984-02-09 1985-10-08 Creative Products Resource Associates Ltd. Automatic dishwasher product in solid form
US4617157A (en) * 1985-04-22 1986-10-14 Whirlpool Corporation Fragrance dispenser for room air conditioner
FR2585248A1 (fr) * 1985-07-25 1987-01-30 Rhodic Sa Sachet de parfum perfectionne utilisable dans les lave-vaisselle
DE10036850A1 (de) * 2000-07-28 2001-10-18 Henkel Kgaa Vorrichtung und Verfahren zur Abgabe eines flüssigen Produktes in den Innenraum einer Geschirrspülmaschine
US20040003724A1 (en) * 2002-04-08 2004-01-08 Ellis Earle R. Automatically controlling the interaction of a medium with an external environment
WO2004020004A1 (fr) * 2002-08-09 2004-03-11 Henkel Kommanditgesellschaft Auf Aktien Systeme de liberation de substances odoriferantes

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US4567675A (en) * 1982-05-20 1986-02-04 Lever Brothers Company Device for conditioning fabrics in a tumble-dryer
USD280757S (en) * 1982-09-23 1985-09-24 Airwick Industries, Inc. Dispenser for solid material
US4849606A (en) * 1987-12-23 1989-07-18 S. C. Johnson & Son, Inc. Tamper-resistant container utilizing a flexible seal
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US7426799B2 (en) * 2004-06-30 2008-09-23 S.C. Johnson & Son, Inc. Air freshener with frame and refill holder

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Publication number Priority date Publication date Assignee Title
US4545917A (en) * 1984-02-09 1985-10-08 Creative Products Resource Associates Ltd. Automatic dishwasher product in solid form
US4617157A (en) * 1985-04-22 1986-10-14 Whirlpool Corporation Fragrance dispenser for room air conditioner
FR2585248A1 (fr) * 1985-07-25 1987-01-30 Rhodic Sa Sachet de parfum perfectionne utilisable dans les lave-vaisselle
DE10036850A1 (de) * 2000-07-28 2001-10-18 Henkel Kgaa Vorrichtung und Verfahren zur Abgabe eines flüssigen Produktes in den Innenraum einer Geschirrspülmaschine
US20040003724A1 (en) * 2002-04-08 2004-01-08 Ellis Earle R. Automatically controlling the interaction of a medium with an external environment
WO2004020004A1 (fr) * 2002-08-09 2004-03-11 Henkel Kommanditgesellschaft Auf Aktien Systeme de liberation de substances odoriferantes

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008141473A1 (fr) 2007-05-23 2008-11-27 Givaudan Sa Dispositif de diffusion de parfum
US20100132743A1 (en) * 2007-05-23 2010-06-03 Philippe Blondeau Fragrance Dissemination Device
US8177916B2 (en) 2007-05-23 2012-05-15 Givaudan S.A. Fragrance dissemination device
WO2012114085A1 (fr) 2011-02-25 2012-08-30 Reckitt Benckiser N.V. Dispositif diffuseur
US9339577B2 (en) 2011-02-25 2016-05-17 Reckitt Benckiser N.V. Emanator device
RU2627126C2 (ru) * 2011-02-25 2017-08-03 Рекитт Бенкизер Финиш Б.В. Испускающее устройство
US10350323B2 (en) 2011-02-25 2019-07-16 Reckitt Benckiser Finish B.V. Emanator device
EP3066972A1 (fr) * 2015-03-09 2016-09-14 Henkel AG & Co. KGaA Dispositif d'emission de parfum pour un lave-vaisselle, lave-vaisselle comprenant un dispositif d'emission de parfum et procede destine a parfumer un lave-vaisselle

Also Published As

Publication number Publication date
ZA200607479B (en) 2008-05-28
CN1946327A (zh) 2007-04-11
EP1737333B1 (fr) 2009-06-17
ES2328500T3 (es) 2009-11-13
CN100581436C (zh) 2010-01-20
AU2005235344A1 (en) 2005-11-03
GB0408811D0 (en) 2004-05-26
DE602005014960D1 (de) 2009-07-30
EP1737333A1 (fr) 2007-01-03
US20080011870A1 (en) 2008-01-17
CA2560006A1 (fr) 2005-11-03
GB2413262B (en) 2006-08-16
BRPI0510037A (pt) 2007-10-02
GB2413262A (en) 2005-10-26
AU2005235344B2 (en) 2010-09-23
ATE433704T1 (de) 2009-07-15

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