WO2005100009A2 - Appret et procede pour creer un textile ignifuge resistant aux marques - Google Patents

Appret et procede pour creer un textile ignifuge resistant aux marques Download PDF

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Publication number
WO2005100009A2
WO2005100009A2 PCT/US2005/008285 US2005008285W WO2005100009A2 WO 2005100009 A2 WO2005100009 A2 WO 2005100009A2 US 2005008285 W US2005008285 W US 2005008285W WO 2005100009 A2 WO2005100009 A2 WO 2005100009A2
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WO
WIPO (PCT)
Prior art keywords
fabric
polymer
urethane polymer
finish
flame retardant
Prior art date
Application number
PCT/US2005/008285
Other languages
English (en)
Other versions
WO2005100009A3 (fr
Inventor
Robert C. Arnott
Original Assignee
Milliken & Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Milliken & Company filed Critical Milliken & Company
Publication of WO2005100009A2 publication Critical patent/WO2005100009A2/fr
Publication of WO2005100009A3 publication Critical patent/WO2005100009A3/fr

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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
    • D06M13/292—Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
    • D06M13/292—Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof
    • D06M13/298—Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof containing halogen atoms
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/14—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
    • D06N3/141—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes mixture of two or more polyurethanes in the same layer
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/30—Flame or heat resistance, fire retardancy properties
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2369—Coating or impregnation improves elasticity, bendability, resiliency, flexibility, or shape retention of the fabric
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2631—Coating or impregnation provides heat or fire protection
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2631—Coating or impregnation provides heat or fire protection
    • Y10T442/2672—Phosphorus containing

Definitions

  • the present disclosure relates to a low add-on polymeric finish for textile fabrics that provides a firm hand and that may provide flame retardant properties, while simultaneously resisting mark-off and yellowing over time.
  • the polymeric finish described herein is substantially transparent, thereby allowing the color and/or pattern of the underlying fabric to be visible.
  • Such a finish is particularly suited for use in a range of textile products, including, specifically, roller shades, vertical blinds, automotive upholstery, and other products where its properties are desirable.
  • Mark-off refers to a visible defect exhibited by a finished or coated fabric when localized contact is made with the fabric (e.g., when the fabric is scratched), resulting in the break of the polymer finish or the separation of the polymer finish from the fabric, either of which leads to visible scratch lines in the area of localized contact. Generally speaking, mark-off is more noticeable in dark-colored fabrics.
  • cross-linkable acrylic polymers to create the finish is problematic, because acrylics without flame retardant additives are generally incapable of passing most flammability tests.
  • the high level of particulate flame retardant required be incorporated into the acrylic polymer causes the coating to be slightly opaque.
  • most cross-linkable acrylic finishes contain formaldehyde, which is generally not a commercially preferred ingredient.
  • PVC polyvinyl chloride
  • PVC has the disadvantage of yellowing during processing, resulting in an undesirable appearance of the final product.
  • Finishing compositions incorporating aromatic bromine compounds and antimony oxide are successful at meeting the flame retardant requirements, but have the disadvantage of inviting close scrutiny with regard to toxicity concerns. For this reason, manufacturers tend to avoid the use of such compounds in creating flame retardant finishes.
  • the finish described herein overcomes the problems discussed above by providing the following advantages: (1 ) firm hand, flame retardance, and resistance to mark-off; (2) no formaldehyde; (3) non-yellowing over time or from exposure to sunlight; and (4) substantially transparent, allowing the colors, patterns, and/or textures of the underlying fabric to be seen. For these reasons, the present finish represents a useful advance over the prior art.
  • the present disclosure relates to a process for creating a flame retardant textile to which is applied a durable, transparent, non-yellowing, formaldehyde-free finish in order to produce a finished textile with firm hand and no mark-off problems.
  • the finish is comprised of a combination of urethane polymers that includes a high elongation, flexible polymer and a low elongation polymer, in which the high elongation polymer acts as a binder for the low elongation polymer.
  • the high elongation polymer component acts as a binding agent for the low elongation polymer component, providing flexibility in the fabric finish that enables the finish to resist mark-off.
  • Low elongation polymers, as described herein, typically have an elongation at break of less than 500%, and, preferably, exhibit a Sward Rocker Hardness of greater than 25.
  • the low elongation polymer component of the finish provides hand firmness in the finished fabric.
  • One example of a polymer having a relatively high elongation and a high degree of hardness is an aromatic polyester urethane, sold by Noveon, Inc. of Cleveland, Ohio, under the tradename SANCURE® 12249.
  • aromatic polymers have a tendency to yellow from exposure to sunlight, making these types of polymers less desirable.
  • aliphatic polymers such as aliphatic polyester urethanes, aliphatic polyether urethanes, and aliphatic polycarbonate urethanes, are preferred because they do not tend to yellow.
  • One example of an aliphatic polyester urethane suitable for this application contains
  • This high elongation polymer has an elongation at break of about 1000% and has a hardness of about 5 when measured on the Sward Rocker Hardness scale.
  • Another example of an aliphatic polyester urethane suitable for this application contains 30% solids and is sold by Noveon under the name SANCURE® 1073.
  • This preferred low elongation polymer which exhibits an elongation at break of about 18% and a hardness of about 34 as measured on the Sward Rocker Hardness scale, includes a flame retardant monomer as part of the polymer backbone.
  • an aliphatic polyether urethane is sold by Noveon under the tradename SANCURE® 2019, which exhibits a Sward Rocker Hardness of 4 and an elongation at break of about 500% (properties of a high elongation polymer).
  • An example of an aliphatic polycarbonate urethane is sold by Stahl, USA under the tradename RU-41-
  • the ratio of high elongation polymer to low elongation polymer can vary, but, when using the SANCURE® urethanes described above, the preferred ratio is between about 20:1 and about 5:1 , and more preferably about 10:1 , based on the percentage of solids.
  • the percent dry add-on of polymers applied to the textile can be as little as 2.5% of the weight of the fabric (owf), although more polymer blend could be added to create an even firmer hand if desired.
  • the percent dry add-on may be within the range of about 2% owf to about 15% owf, preferably between about 2.5% to about 5.0%, more preferably between about 2.5% owf and about 3.5% owf, with about 3% owf being most preferred.
  • thermoset polymers may be one of two types: thermoset polymers and thermoplastic polymers.
  • thermoset polymers especially when applied to polyester fabrics, tend to crosslink and form a film layer on the fabric surface rather than being partially incorporated therein (as are thermoplastic polymers that do not cross-link). Accordingly, thermoset polymers have a much greater tendency to fail the National Fire Prevention Association
  • thermoplastic polymers are commercially available. Polymers of this type are sold by Noveon under the tradename SANCURE®, several of which have been previously mentioned; by C.L. Hauthaway & Sons Corporation of Lynn, MA, under the tradename HAUTHANE®; and by Stahl, USA of Peabody, MA, under various tradenames. Some of these polymers have flame retardant monomers incorporated into the polymer molecule, for the purpose of imparting flame retardant properties to the surface coating.
  • the flame retardant chemicals were incorporated in the fabric.
  • the decision to incorporate flame retardant chemicals into the fabric allows more flexibility in selecting the polymer coating that is used.
  • the flame retardant chemistry (such as, for example,
  • Flameproof 1503® flame retardant from Apex Chemical of Spartanburg, SC; FR-2-728 flame retardant from Milliken Chemical, a division of Milliken & Company, Spartanburg, SC; or Pyrozyl EF9® flame retardant from Amitech, Inc. of Oxford, NJ) is exhausted into the fabric, preferably during the dyeing process.
  • Pyrozyl EF9® flame retardant which contains a chlorinated phosphate ester, is the preferred flame retardant for this application (i.e., when using 100% polyester knit fabrics).
  • the textile and flame retardant are placed into a jet- dyeing machine and heated to temperature (e.g., 265 °F).
  • the jet is held at temperature, preferably between 30 and 60 minutes, to allow the flame retardant to be exhausted into the textile, after which the textile is cooled and rinsed before further processing.
  • This technique results in the flame retardant chemistry being durably incorporated into the fibers themselves. Weight analysis reveals that between 60% and 7'5% of the available flame retardant is typically incorporated into the fabric using this technique.
  • the dyeing process, using disperse dyes can be done before or, preferably, simultaneously with the flame retardant treatment.
  • Applying the polymer combination to the textile is easily accomplished by padding the fabric (a process in which the fabric is dipped in an aqueous solution containing a combination of urethane polymers and then passed through squeeze rolls to remove the excess).
  • Other application methods such as spraying, single- or double-side foam coating, knife coating, and other techniques as are known in the art may be used, although padding is a preferred method.
  • a 100% polyester raschel knit textile having 28 X 28 courses and wales, 150/36 yarns, and a weight of about 30 ounces per linear yard at 96 inches was used.
  • Each 100 gram portion of the textile was put into a jet-dyeing machine with about 500 cc of water to wet the textile, after which a flame retardant chemical (Pyrozyl EF-9®, dispersed in about 200 grams of water) was added, at 6% of the weight of the fabric. Additional water was added to bring the total volume to 1500 cc.
  • Each textile sample was heated by increasing the temperature to 265 °F at a rise rate of 12 °F/minute. The solution was held at temperature for at least 30 minutes, after which the temperature was dropped and the textile samples were rinsed and dried.
  • a textile sample was padded into one of various solutions of polymer coating, using laboratory scale equipment at a roll pressure of 50 pounds per square inch, resulting in a wet pick-up of between 65% and 70%. Each sample was then placed on pin frames to maintain dimensional stability and dried at 380 °F for about 3 minutes. The samples were evaluated for mark-off problems and for desired hand as shown in Data Table 1.
  • Hand was evaluated using ASTM Test Method D6828-02, entitled “Standard Test Method for Stiffness of Fabric by the Blade / Slot Procedure.” Using this method, hand is a measure of the force necessary to bend a piece of fabric to fit into a 10 mm wide gap. Force is measured in grams, using a 4 inch x 4 inch piece of fabric. The maximum reading is about 1000. When testing individual samples (using the same operator to test each sample), the standard deviation is 16 grams. The first number reported represents the force required to bend the fabric in the wales direction and the second number represents the force required to bend the fabric in the direction of the courses. Higher n umbers indicate fabrics having a firmer hand, whereas lower numbers indicate a more flexible fabric.
  • the hand should measure at least 900 grams in the wales direction and at least 400 grams in the courses direction. Obviously, other applications may have different hand req eriements. As is seen in the final sample of Data Table 1 , the combination of a high elongation polymer and a smaller amount of a low elongation polymer provides the most desired stiffness in the final product. This combination produces fabric having a hand that is significantly better (for this application) than the fabric produced using twice as much high elongation polymer alone.
  • the combination described above provides an economical means to obtain the desired stiffness. Simultaneously, the combination of polymer urethanes in a relatively low addon level contributes to the flame retardant properties by minimizing the likelihood of flame spreading, due to presence of a high amount of coating on the surface of the fabric.
  • a 100% polyester raschel knit textile having 28 X 28 courses and wales, 150/36 yarns, and a weight of about 30 ounces per linear yard at 96 inches was used.
  • the following solution was constructed (all percentages are by weight of the fabric): 4% Pyrozyl EF9® flame retardant from Amitech; 0.4% acetic acid used to control pH; 0.75% Leveler 528, an additive used to ensure color uniformity; 0.5% Defoamer RETM, a defoaming agent used to ease processing; and 5% of a combination of disperse dyes to yield a black color.
  • the fabric was added to the jet, and the temperature was increased to a temperature of about 160 °F at a rise rate of about 4° / minute. The temperature was further increased to a temperature of about 280 °F at a rise rate of about 2° / minute. This higher temperature was held for about 30 minutes, after which the fabric was cooled at a drop rate of about 2° / minute. Finally, the dyed, flame retardant-treated fabric was removed from the jet and rinsed.
  • the fabric was padded with an aqueous polymer solution containing 5% SANCURE® 20025 polyester urethane (48% solids) on a solids basis and 0.5% SANCURE® 1049C polyester urethane (30% solids) on a solids basis.
  • the ratio of high elongation polymer to low elongation polymer was approximately 10:1 , on a solids basis.
  • the wet add-on of the polymer solution was about 65% at a pad pressure of about 50 psi.
  • the coated fabric was then dried at a temperature of 390 °F for about 1.5 minutes.
  • a second fabric was produced using the same methods described above, but using a combination of disperse dyes to create a thistle-colored product.
  • the production-scale trials confirm that the process of exhausting a flame retardant chemical into the fabric and then coating it with a combination of a high elongation polymer and a low elongation polymer provides the desired properties for the present fabric.
  • the coated fabric (1 ) possesses the desired stiffness for its intended applications and (2) meets flammability requirements.
  • the coating is transparent, allowing the color of the underlying fabric to be readily appreciated. CONCLUSION Although the preferred combination of high elongation and low elongation polymers has been shown for use on knit fabrics, it is contemplated that similar benefits may be obtained on other textile constructions, such as woven or nonwoven fabrics.
  • the coating may further include chemistries designed to enhance ultraviolet absorption, ultraviolet inhibitors, antimicrobials, mildew inhibitors, water repellents, soil release chemistries, polychromatic chemistries, odor absorbents, or the like.
  • the process of (a) exhausting a flame retardant into a fabric and then (b) coating the textile with a combination of high elongation polymer and low elongation polymer is capable of creating a flame retardant fabric with a desired hand and resistance to mark-off.
  • a coating comprising the combination of a high elongation polymer and a low elongation polymer in a ratio ranging between about 20:1 to about 5:1 provides the desired firmness in the coated fabric in an economical manner, while also assisting in maintaining the flame retardant characteristics of the underlying fabric.
  • the present finish (1) contains no formaldehyde; (2) does not yellow over time or from exposure to sunlight; and (3) provides a substantially transparent coating through which the colors, patterns, and/or texture of the underlying fabric can be seen.
  • the present finish and process represent useful advances over the prior art.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

Le présent apprêt utilise un polymère d'uréthane élastique durable comme constituant primaire mélangé à une quantité inférieure de polymère d'uréthane de faible allongement, pour conférer la texture souhaitée au tissu ainsi apprêté. Cette combinaison, dans laquelle le polymère de fort allongement entoure essentiellement le polymère de faible allongement, offre un moyen économique d'empêcher l'apparition de marques dans le tissu ainsi apprêté. Pour satisfaire aux exigences d'ignifugation, une substance chimique ignifuge est de préférence appliquée sur le tissu pendant la teinture, ce qui permet d'incorporer durablement l'agent ignifuge dans la fibre. Un procédé pour appliquer cet apprêt afin de créer un tissu enduit d'agent ignifuge est également présenté.
PCT/US2005/008285 2004-03-26 2005-03-11 Appret et procede pour creer un textile ignifuge resistant aux marques WO2005100009A2 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/810,955 2004-03-26
US10/810,955 US20050214596A1 (en) 2004-03-26 2004-03-26 Finish and process to create flame-retardant textile that resists mark-off

Publications (2)

Publication Number Publication Date
WO2005100009A2 true WO2005100009A2 (fr) 2005-10-27
WO2005100009A3 WO2005100009A3 (fr) 2006-06-29

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ID=34990300

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2005/008285 WO2005100009A2 (fr) 2004-03-26 2005-03-11 Appret et procede pour creer un textile ignifuge resistant aux marques

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US (1) US20050214596A1 (fr)
WO (1) WO2005100009A2 (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7737059B1 (en) * 2009-02-19 2010-06-15 Milliken & Company Airbag coating
CN114622318A (zh) * 2020-12-14 2022-06-14 无锡高仕康新材料科技有限公司 长纤维高强力纱线的制备方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4104222A (en) * 1974-02-11 1978-08-01 Toyo Boseki Kabushiki Kaisha Dispersion of linear polyester resin
US5981407A (en) * 1996-05-13 1999-11-09 Kaneka Corporation Thermal resistance-improved flame retardant cloth
US20040219852A1 (en) * 2001-07-16 2004-11-04 Hans-Dieter Eichhorn Flameproof textile surface structures

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4276212A (en) * 1978-12-11 1981-06-30 E. I. Du Pont De Nemours And Company High solids coating composition of a low molecular weight acrylic polymer and an alkylated melamine cross-linking agent
US4396672A (en) * 1982-02-08 1983-08-02 E. I. Du Pont De Nemours & Co. Substrate having a pigmented color coat and a clear coat of a _composition of an acrylic, polyester and a melamine resin
EP0193636A1 (fr) * 1985-03-08 1986-09-10 Konrad Hornschuch Aktiengesellschaft Bande textile réflectrice, procédé pour sa préparation et son utilisation
US5594061A (en) * 1992-09-14 1997-01-14 Gencorp Inc. Aqueous coating for vinyl chloride polymer substrate
US5389430A (en) * 1993-02-05 1995-02-14 Th. Goldschmidt Ag Textiles coated with waterproof, moisture vapor permeable polymers
US6001906A (en) * 1997-08-04 1999-12-14 Golumbic; Harvey J. Water based plasticizer free poly urethane-wax coating & repair composition & method
US6537931B1 (en) * 2000-02-24 2003-03-25 Robert E. Pflug Durable coated fabric, method of making same and products incorporating same
US6511515B1 (en) * 2000-07-13 2003-01-28 Milliken & Company Roller shade treatment and method
US6723433B2 (en) * 2001-03-02 2004-04-20 3M Innovative Properties Company Printable film and coating composition exhibiting stain resistance
US20050215147A1 (en) * 2004-03-26 2005-09-29 Masters Charles R Sunscreen fabric and method of making same

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4104222A (en) * 1974-02-11 1978-08-01 Toyo Boseki Kabushiki Kaisha Dispersion of linear polyester resin
US5981407A (en) * 1996-05-13 1999-11-09 Kaneka Corporation Thermal resistance-improved flame retardant cloth
US20040219852A1 (en) * 2001-07-16 2004-11-04 Hans-Dieter Eichhorn Flameproof textile surface structures

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US20050214596A1 (en) 2005-09-29
WO2005100009A3 (fr) 2006-06-29

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