WO2005071127A1 - Al-si-mn-mg alloy for forming automotive structural parts by casting and t5 heat treatment - Google Patents
Al-si-mn-mg alloy for forming automotive structural parts by casting and t5 heat treatment Download PDFInfo
- Publication number
- WO2005071127A1 WO2005071127A1 PCT/US2005/000355 US2005000355W WO2005071127A1 WO 2005071127 A1 WO2005071127 A1 WO 2005071127A1 US 2005000355 W US2005000355 W US 2005000355W WO 2005071127 A1 WO2005071127 A1 WO 2005071127A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- aluminum alloy
- shaped casting
- casting
- alloy shaped
- heat treatment
- Prior art date
Links
- 238000005266 casting Methods 0.000 title claims abstract description 58
- 238000010438 heat treatment Methods 0.000 title claims abstract description 21
- 229910000861 Mg alloy Inorganic materials 0.000 title 1
- 229910000838 Al alloy Inorganic materials 0.000 claims abstract description 40
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 15
- 229910052742 iron Inorganic materials 0.000 claims abstract description 14
- 229910052712 strontium Inorganic materials 0.000 claims abstract description 14
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 11
- 229910052802 copper Inorganic materials 0.000 claims abstract description 10
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 10
- 229910052748 manganese Inorganic materials 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 14
- 238000004519 manufacturing process Methods 0.000 claims description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract description 15
- 239000011777 magnesium Substances 0.000 abstract description 12
- 229910052710 silicon Inorganic materials 0.000 abstract description 10
- 239000010936 titanium Substances 0.000 abstract description 8
- 239000011701 zinc Substances 0.000 abstract description 8
- 239000010949 copper Substances 0.000 abstract description 7
- 239000010703 silicon Substances 0.000 abstract description 6
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 abstract description 2
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 abstract description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 1
- 229910045601 alloy Inorganic materials 0.000 description 33
- 239000000956 alloy Substances 0.000 description 33
- 239000011572 manganese Substances 0.000 description 11
- 230000032683 aging Effects 0.000 description 6
- 238000004512 die casting Methods 0.000 description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 5
- 230000035882 stress Effects 0.000 description 5
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 239000003607 modifier Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 229910018125 Al-Si Inorganic materials 0.000 description 2
- 229910018520 Al—Si Inorganic materials 0.000 description 2
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 2
- 230000005496 eutectics Effects 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 229910000676 Si alloy Inorganic materials 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- CSDREXVUYHZDNP-UHFFFAOYSA-N alumanylidynesilicon Chemical compound [Al].[Si] CSDREXVUYHZDNP-UHFFFAOYSA-N 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 229910052790 beryllium Inorganic materials 0.000 description 1
- ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000009661 fatigue test Methods 0.000 description 1
- 238000007656 fracture toughness test Methods 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- 231100000206 health hazard Toxicity 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 239000011856 silicon-based particle Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 230000009974 thixotropic effect Effects 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/02—Alloys based on aluminium with silicon as the next major constituent
- C22C21/04—Modified aluminium-silicon alloys
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/04—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
- C22F1/043—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon of alloys with silicon as the next major constituent
Definitions
- This invention pertains to an aluminum-silicon alloy for shaped castings wherein the casting process is followed by a T5 heat treatment to improve or stabilize mechanical properties without introducing dimensional changes.
- the present invention is a method of making an aluminum alloy shaped casting.
- the method includes preparing an aluminum alloy melt with a composition substantially within the following ranges: Si: 6.3 wt. % - 9 wt. %, Mg: 0.05 wt. % - 0.4 wt. %, Mn ⁇ 0.8 wt.
- the present invention is a method of making an aluminum alloy shaped casting.
- the method includes: preparing an aluminum alloy melt with a composition substantially within the following ranges: Si: 6.3 wt. % - 9 wt.
- the method further includes thixoforming the melt in a mold configured to produce the shaped casting, and the method further includes a heat treating step wherein the shaped casting is held at a temperature between about 170 C and about 400 C for a time between about 10 minutes and about 180 minutes.
- the present invention is an aluminum alloy shaped casting having a composition substantially in the range Si: 6.3 wt. % - 9 wt. %, Mg: 0.05 wt. % - 0.4 wt. %, Mn ⁇ 0.8 wt. %, Cu ⁇ 0.5 wt. %, Zn ⁇ 1.0 wt. %, Fe ⁇ 0.2 wt. %, Ti ⁇ 0.2 wt. % Sr ⁇ 0.04 wt. %; the aluminum alloy shaped casting receiving a T5 heat treatment.
- Figure 1 is a photograph of a shaped casting used for testing tensile, yield and elongation properties of alloys according to the present invention after artificial ageing;
- Figure 2 is a plot of ultimate tensile strength, yield stress and elongation versus artificial ageing of an alloy according to the present invention;
- Figure 3 is a plot presenting fatigue data for an alloy according to the present invention in comparison with prior art alloys after solution heat treatment.
- the invention consists of an Al-Si base alloy for die castings or semi-solid metal forming with the following composition ranges (all in weight percent): Si about 6.3 - 9 wt. %, Mg about 0.05 - 0.4 wt. %, Mn ⁇ 0.8 wt. %, Cu ⁇ 0.5 wt. %, Zn ⁇ 1.0 wt. %, Fe less than about 0.2 wt. %, Ti less than about 0.2 wt. %, Sr ⁇ 0.04, the balance aluminum, incidental elements and impurities.
- Plates (12 mm thick) made with selected compositions within the aforementioned composition ranges using a steel book mold have shown ultimate tensile strengths (UTS) greater than 30 ksi (207 megaPascals), yield strengths (YS) greater than 15 ksi (103 megaPascals), and elongations greater than 15%> in the as-cast condition.
- UTS ultimate tensile strengths
- YS yield strengths
- elongations greater than 15%> in the as-cast condition.
- the mechanical properties after a T5 temper, at 190°C for 90 minutes were 35 ksi UTS (241 megaPascals), 23 ksi YS (159 megaPascals), and 10%> elongation.
- FIG. 1 is a photograph of a vacuum die cast part comprised of an aluminum alloy including: 6.8 wt. % Si, 0.097 wt. % Fe, 0.577 wt. % Mn, 0.251 wt. % Mg, 0.0652 wt. % Ti, 0.0163 wt. % Ga, and 0.0313 wt. % Sr.
- Figure 2 presents tensile, yield and elongation (TYE) data for samples cut from the casting shown in Figure 1. Data are shown for various amounts of artificial ageing at 330 C. The ultimate tensile strength (UTS), Yield stress (YS) and elongation, all desirable properties, decrease during the artificial ageing. The reason for the artificial ageing is to stabilize the properties of the casting, so they do not change during service. This is particularly a concern for parts which are made for service near a hot engine.
- the alloy labeled as lot 2 was the alloy cited above.
- the alloy labeled as lot 5 was an aluminum alloy including: 7.19 wt. % Si; 0.1 wt. % Fe; 0.619 wt. % Mn; 0.271 wt. % Mg; 0.1023 wt. % Ti; 0.0174 wt. % GA; and 0.0294 wt. % Sr.
- the following table presents yield, tensile and elongation data for the two alloys.
- the column labeled "Lot" defines the alloy.
- the column labeled "Position” gives one of three positions cut from the casting.
- the row labeled “Average” presents averaged data for the three positions. Each entry in the table is an average often or more measurements.
- the data for yield stress (YS) were obtained at a strain of 0.2%.
- the column labeled UTS refers to ultimate tensile strength.
- the column labeled Elong. machine refers to elongation in percent measured by machine, and Elong. manual refers to elongation in percent measured manually.
- a Fracture toughness test (Kahn Tear) was also performed on the alloy of lot 2.
- the fracture toughness in kilo Joules/square meter was 54.9.
- the fracture toughness was 53.4.
- Axial stress smooth fatigue tests were also performed comparing the alloy of lot 2, which is in accordance with the present invention, with two prior art alloys, denoted C65K and C448.
- the alloy denoted C65K is an aluminum alloy including about: 10 wt. % Si, 0.13 wt % Fe, 0.60 wt % Mn, 0.32 wt % Mg, 0.02 wt.
- the alloy denoted C448 is an aluminum alloy including about: 10 wt. % Si, 0.13 wt. % Fe, 0.6 wt. % Mn, 0.18 wt. % Mg 0.02 wt. % Sr.
- the alloy of lot 2 was in T5 condition, the prior art alloys were in T6 condition. Results are presented in Figure 3. The stress levels were cycled equally between tension and compression, in accordance with the ordinate in Figure 3. The abscissa denotes the number of cycles to failure. The samples were cycled at 25 Hz, and the environment was laboratory air.
- the group of samples at the lower right labeled DNF are samples which did not fail after 5 million or ten million cycles.
- the alloy, C611 which is in accordance with the present invention, compares favorably with the prior art alloys, C65K and C448.
- the presently preferred composition ranges are as follows: Si about 7 - 8.5 wt. %, Mg about 0.1 - 0.3 wt. %, Mn 0.3 - 0.7 wt. %, Cu ⁇ 0.15 wt. %, Zn ⁇ 0.5 wt. %, Fe less than about 0.15 wt.
- each incidental element should, preferably, have a concentration of no more than 0.05 wt. %, and the total of incidental elements should, preferably, be no more than about 0.15 wt. %>.
- the heat treatment should be a T5 temper in the range from 170 C to 400 C with a time at temperature of at least about ten minutes, and no more than about 180 minutes.
- the preferred heat treatment includes heating the casting quickly to a temperature in the range from 250 C to 350 C and holding it at that temperature for a time of at least ten minutes, and no more than about half an hour.
- a lower silicon concentration provides better ductility
- a higher silicon concentration provides better castability, i.e., less shrinkage and cracking.
- lower magnesium provides better ductility
- higher magnesium provides better strength.
- manganese it is believed that lower manganese provides better ductility and toughness, and that higher manganese prevents die sticking. Cobalt, Chromium, Vanadium or Molybdenum may also be used to prevent die sticking.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Body Structure For Vehicles (AREA)
Abstract
Description
Claims
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US53571304P | 2004-01-09 | 2004-01-09 | |
US60/535,713 | 2004-01-09 | ||
US11/031,095 | 2005-01-06 | ||
US11/031,095 US20050167012A1 (en) | 2004-01-09 | 2005-01-06 | Al-Si-Mn-Mg alloy for forming automotive structural parts by casting and T5 heat treatment |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2005071127A1 true WO2005071127A1 (en) | 2005-08-04 |
Family
ID=34810455
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2005/000355 WO2005071127A1 (en) | 2004-01-09 | 2005-01-07 | Al-si-mn-mg alloy for forming automotive structural parts by casting and t5 heat treatment |
Country Status (2)
Country | Link |
---|---|
US (1) | US20050167012A1 (en) |
WO (1) | WO2005071127A1 (en) |
Cited By (8)
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WO2007051162A3 (en) * | 2005-10-28 | 2008-04-03 | Alcoa Inc | A HIGH CRASHWORTHINESS AL-SI-Mg ALLOY AND METHODS FOR PRODUCING AUTOMOTIVE CASTING |
EP2138593A3 (en) * | 2008-06-24 | 2010-10-27 | BDW technologies GmbH | Casting component and method for its manufacture |
RU2405852C2 (en) * | 2008-12-25 | 2010-12-10 | Общество с ограниченной ответственностью "Литейный завод "РосАЛит" | Castable aluminium alloy |
EP2471967A1 (en) * | 2010-12-28 | 2012-07-04 | Casa Maristas Azterlan | Method for obtaining improved mechanical properties in recycled aluminium castings free of platelet-shaped beta-phases |
CN104975209A (en) * | 2015-03-13 | 2015-10-14 | 宝山钢铁股份有限公司 | 6000 series aluminum alloy material with high natural aging stability, aluminum alloy plate and preparing method of aluminum alloy plate |
WO2017027734A1 (en) * | 2015-08-13 | 2017-02-16 | Alcoa Inc. | Improved 3xx aluminum casting alloys, and methods for making the same |
EP3235917B1 (en) | 2016-04-19 | 2018-08-15 | Rheinfelden Alloys GmbH & Co. KG | Alloy for pressure die casting |
US11421305B2 (en) | 2016-04-19 | 2022-08-23 | Rheinfelden Alloys Gmbh & Co. Kg | Cast alloy |
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JP2005281829A (en) * | 2004-03-30 | 2005-10-13 | Honda Motor Co Ltd | Al-si based alloy and alloy member made of the alloy |
US9353429B2 (en) | 2007-02-27 | 2016-05-31 | Nippon Light Metal Company, Ltd. | Aluminum alloy material for use in thermal conduction application |
US8349462B2 (en) | 2009-01-16 | 2013-01-08 | Alcoa Inc. | Aluminum alloys, aluminum alloy products and methods for making the same |
CN102051505B (en) * | 2010-12-28 | 2012-06-20 | 浙江金盾风机股份有限公司 | High-strength casting aluminum alloy |
EP2735621B1 (en) * | 2012-11-21 | 2015-08-12 | Georg Fischer Druckguss GmbH & Co. KG | Aluminium die casting alloy |
US9677158B2 (en) | 2013-03-15 | 2017-06-13 | GM Global Technology Operations LLC | Aluminum alloy suitable for high pressure die casting |
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US20170107599A1 (en) | 2015-10-19 | 2017-04-20 | GM Global Technology Operations LLC | New high pressure die casting aluminum alloy for high temperature and corrosive applications |
US20200010933A1 (en) * | 2017-02-23 | 2020-01-09 | Randolf Scott BEALS | Process for low-cost tempering of aluminum casting |
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US12031199B2 (en) * | 2022-03-30 | 2024-07-09 | Relativity Space, Inc. | Aluminum alloy compositions, articles therefrom, and methods of producing articles therefrom |
CN115627394A (en) * | 2022-11-08 | 2023-01-20 | 帅翼驰新材料集团有限公司 | High-pressure cast aluminum alloy for automobile integrated auxiliary frame and preparation method thereof |
CN115948682B (en) * | 2023-02-22 | 2023-08-15 | 有研工程技术研究院有限公司 | High-heat-conductivity aluminum alloy material for 5G communication large-scale heat dissipation cavity and rheological die casting forming method thereof |
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US5922147A (en) * | 1995-05-19 | 1999-07-13 | Tenedora Nemak, S.A. De C.V. | Method and apparatus for simplified production of heat-treatable aluminum alloy castings |
Family Cites Families (1)
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JP2002105572A (en) * | 2000-09-26 | 2002-04-10 | Ryobi Ltd | ALUMINUM ALLOY FOR DIECASTING, AUTOMOBILE SUBFRAME AND DIECASTING PROCESS ! Al-Mg-Si BASED Al ALLOY SHEET HAVING EXCELLENT BENDING WORKABILITY |
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2005
- 2005-01-06 US US11/031,095 patent/US20050167012A1/en not_active Abandoned
- 2005-01-07 WO PCT/US2005/000355 patent/WO2005071127A1/en active Application Filing
Patent Citations (1)
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US5922147A (en) * | 1995-05-19 | 1999-07-13 | Tenedora Nemak, S.A. De C.V. | Method and apparatus for simplified production of heat-treatable aluminum alloy castings |
Non-Patent Citations (1)
Title |
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"ASM Specialty Handbook: Aluminum and Aluminum Alloys", 1993, ASM INTERNATIONAL, article DAVIS J.R. ET AL: "pages 29, 89-90, 101-105, 315-316" * |
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WO2007051162A3 (en) * | 2005-10-28 | 2008-04-03 | Alcoa Inc | A HIGH CRASHWORTHINESS AL-SI-Mg ALLOY AND METHODS FOR PRODUCING AUTOMOTIVE CASTING |
EP2138593A3 (en) * | 2008-06-24 | 2010-10-27 | BDW technologies GmbH | Casting component and method for its manufacture |
RU2405852C2 (en) * | 2008-12-25 | 2010-12-10 | Общество с ограниченной ответственностью "Литейный завод "РосАЛит" | Castable aluminium alloy |
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US11421305B2 (en) | 2016-04-19 | 2022-08-23 | Rheinfelden Alloys Gmbh & Co. Kg | Cast alloy |
Also Published As
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