WO2005064232A1 - Wärmekraftanlage mit sequentieller verbrennung und reduziertem co2-ausstoss sowie verfahren zum bertreiben einer derartigen anlage - Google Patents
Wärmekraftanlage mit sequentieller verbrennung und reduziertem co2-ausstoss sowie verfahren zum bertreiben einer derartigen anlage Download PDFInfo
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- WO2005064232A1 WO2005064232A1 PCT/EP2004/053123 EP2004053123W WO2005064232A1 WO 2005064232 A1 WO2005064232 A1 WO 2005064232A1 EP 2004053123 W EP2004053123 W EP 2004053123W WO 2005064232 A1 WO2005064232 A1 WO 2005064232A1
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- exhaust gas
- pressure turbine
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- combustion
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- 238000002485 combustion reaction Methods 0.000 title claims abstract description 135
- 238000000034 method Methods 0.000 title claims abstract description 28
- 239000007789 gas Substances 0.000 claims abstract description 132
- 238000001816 cooling Methods 0.000 claims abstract description 37
- 238000000926 separation method Methods 0.000 claims abstract description 23
- 239000000112 cooling gas Substances 0.000 claims abstract description 19
- 239000000446 fuel Substances 0.000 claims description 29
- 230000003647 oxidation Effects 0.000 claims description 26
- 238000007254 oxidation reaction Methods 0.000 claims description 26
- 239000001301 oxygen Substances 0.000 claims description 26
- 229910052760 oxygen Inorganic materials 0.000 claims description 26
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 25
- 239000001257 hydrogen Substances 0.000 claims description 13
- 229910052739 hydrogen Inorganic materials 0.000 claims description 13
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 12
- 230000006835 compression Effects 0.000 claims description 5
- 238000007906 compression Methods 0.000 claims description 5
- 238000010304 firing Methods 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 238000011144 upstream manufacturing Methods 0.000 claims description 2
- 230000008878 coupling Effects 0.000 claims 1
- 238000010168 coupling process Methods 0.000 claims 1
- 238000005859 coupling reaction Methods 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
- 238000010586 diagram Methods 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- 230000008033 biological extinction Effects 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 239000005431 greenhouse gas Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000003134 recirculating effect Effects 0.000 description 1
- 238000009420 retrofitting Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C13/00—Apparatus in which combustion takes place in the presence of catalytic material
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/386—Catalytic partial combustion
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02C—GAS-TURBINE PLANTS; AIR INTAKES FOR JET-PROPULSION PLANTS; CONTROLLING FUEL SUPPLY IN AIR-BREATHING JET-PROPULSION PLANTS
- F02C1/00—Gas-turbine plants characterised by the use of hot gases or unheated pressurised gases, as the working fluid
- F02C1/04—Gas-turbine plants characterised by the use of hot gases or unheated pressurised gases, as the working fluid the working fluid being heated indirectly
- F02C1/08—Semi-closed cycles
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02C—GAS-TURBINE PLANTS; AIR INTAKES FOR JET-PROPULSION PLANTS; CONTROLLING FUEL SUPPLY IN AIR-BREATHING JET-PROPULSION PLANTS
- F02C3/00—Gas-turbine plants characterised by the use of combustion products as the working fluid
- F02C3/34—Gas-turbine plants characterised by the use of combustion products as the working fluid with recycling of part of the working fluid, i.e. semi-closed cycles with combustion products in the closed part of the cycle
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02C—GAS-TURBINE PLANTS; AIR INTAKES FOR JET-PROPULSION PLANTS; CONTROLLING FUEL SUPPLY IN AIR-BREATHING JET-PROPULSION PLANTS
- F02C6/00—Plural gas-turbine plants; Combinations of gas-turbine plants with other apparatus; Adaptations of gas-turbine plants for special use
- F02C6/003—Gas-turbine plants with heaters between turbine stages
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02C—GAS-TURBINE PLANTS; AIR INTAKES FOR JET-PROPULSION PLANTS; CONTROLLING FUEL SUPPLY IN AIR-BREATHING JET-PROPULSION PLANTS
- F02C6/00—Plural gas-turbine plants; Combinations of gas-turbine plants with other apparatus; Adaptations of gas-turbine plants for special use
- F02C6/18—Plural gas-turbine plants; Combinations of gas-turbine plants with other apparatus; Adaptations of gas-turbine plants for special use using the waste heat of gas-turbine plants outside the plants themselves, e.g. gas-turbine power heat plants
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C6/00—Combustion apparatus characterised by the combination of two or more combustion chambers or combustion zones, e.g. for staged combustion
- F23C6/04—Combustion apparatus characterised by the combination of two or more combustion chambers or combustion zones, e.g. for staged combustion in series connection
- F23C6/042—Combustion apparatus characterised by the combination of two or more combustion chambers or combustion zones, e.g. for staged combustion in series connection with fuel supply in stages
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C9/00—Combustion apparatus characterised by arrangements for returning combustion products or flue gases to the combustion chamber
- F23C9/08—Combustion apparatus characterised by arrangements for returning combustion products or flue gases to the combustion chamber for reducing temperature in combustion chamber, e.g. for protecting walls of combustion chamber
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23R—GENERATING COMBUSTION PRODUCTS OF HIGH PRESSURE OR HIGH VELOCITY, e.g. GAS-TURBINE COMBUSTION CHAMBERS
- F23R3/00—Continuous combustion chambers using liquid or gaseous fuel
- F23R3/28—Continuous combustion chambers using liquid or gaseous fuel characterised by the fuel supply
- F23R3/34—Feeding into different combustion zones
- F23R3/346—Feeding into different combustion zones for staged combustion
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
- C01B2203/0261—Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a catalytic partial oxidation step [CPO]
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/06—Integration with other chemical processes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/80—Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
- C01B2203/84—Energy production
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C2201/00—Staged combustion
- F23C2201/40—Intermediate treatments between stages
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C2202/00—Fluegas recirculation
- F23C2202/30—Premixing fluegas with combustion air
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C2900/00—Special features of, or arrangements for combustion apparatus using fluid fuels or solid fuels suspended in air; Combustion processes therefor
- F23C2900/09001—Cooling flue gas before returning them to flame or combustion chamber
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23D—BURNERS
- F23D2210/00—Noise abatement
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23R—GENERATING COMBUSTION PRODUCTS OF HIGH PRESSURE OR HIGH VELOCITY, e.g. GAS-TURBINE COMBUSTION CHAMBERS
- F23R2900/00—Special features of, or arrangements for continuous combustion chambers; Combustion processes therefor
- F23R2900/00014—Reducing thermo-acoustic vibrations by passive means, e.g. by Helmholtz resonators
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23R—GENERATING COMBUSTION PRODUCTS OF HIGH PRESSURE OR HIGH VELOCITY, e.g. GAS-TURBINE COMBUSTION CHAMBERS
- F23R2900/00—Special features of, or arrangements for continuous combustion chambers; Combustion processes therefor
- F23R2900/00016—Retrofitting in general, e.g. to respect new regulations on pollution
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23R—GENERATING COMBUSTION PRODUCTS OF HIGH PRESSURE OR HIGH VELOCITY, e.g. GAS-TURBINE COMBUSTION CHAMBERS
- F23R2900/00—Special features of, or arrangements for continuous combustion chambers; Combustion processes therefor
- F23R2900/03341—Sequential combustion chambers or burners
Definitions
- the invention relates to a thermal power plant, preferably a gas turbine plant, with sequential combustion and reduced CO 2 emissions, which has the following components, each of which is connected in series via at least one flow channel: a combustion air compressor unit, a first combustion chamber, a high-pressure turbine stage, and a second Combustion chamber and a low-pressure turbine stage, the second combustion chamber and / or the low-pressure turbine stage being able to be supplied with a cooling gas flow for cooling purposes. Furthermore, a method for operating a thermal power plant of the above type is described.
- the higher the C0 2 partial pressure in the exhaust gas stream the better the efficiency of the C0 2 separation.
- the recirculated exhaust gas being diluted with fresh air, which on the one hand increases the oxygen content of the combustion air to be compressed by the compressor unit and the CO 2 concentration of the recirculated air Exhaust gas can be reduced. Due to the lower oxygen content of the compressed mixed air resulting from the recirculated exhaust gas flow, which is fed to the burner in the further flow of the gas turbine system, in which the mixed air is converted into an ignitable fuel-air mixture by the addition of fuel and is ultimately brought to ignition in the combustion chamber.
- combustion instabilities occur, in particular, in which the combustion takes place within the combustion chamber without any excess of oxygen.
- combustion instabilities lead, on the one hand, to high CO emissions and, on the other hand, to the formation of thermoacoustic vibrations, which can severely impair the operation of the gas turbine system.
- the reduced C0 2 content in the recirculated, compressed exhaust gas flow due to the mixture with combustion air leads to a lower efficiency of the C0 2 separation.
- the invention is intended to remedy this problem and to show a way of operating gas turbine plants with which efficient CO 2 separation from the recirculated exhaust gas flow is possible without having a lasting effect on the stable burner behavior.
- the invention is based on the object of developing a thermal power plant, preferably a gas turbine plant with sequential combustion and reduced CO 2 emissions, according to the preamble of claim 1 in such a way that the least possible, technical investment, the most efficient CO 2 separation possible from the exhaust gas stream of a gas turbine system without permanently impairing the operating behavior and in particular the emission behavior of the gas turbine system.
- the measure according to the invention is also intended to permit the possibility of retrofitting on gas turbines which are already in operation. It is also important to specify a corresponding method for operating a gas turbine plant in this regard.
- the solution to the problem on which the invention is based is specified in claim 1.
- the subject of claim 16 is a method for operating a thermal power plant, preferably a gas turbine plant.
- a thermal power plant preferably a gas turbine plant with sequential combustion and reduced CO 2 emissions
- a thermal power plant preferably a gas turbine plant with sequential combustion and reduced CO 2 emissions
- At least part of the compressed exhaust gas stream emerging from the cooling unit is fed as cooling gas stream via a cooling line to the second combustion chamber and / or the low-pressure turbine stage for cooling purposes, as a result of which the gas turbine components exposed to the hot gases generated within the second combustion chamber can be effectively cooled.
- a CO 2 separator unit is provided in the cooling line, which separates at least parts of CO 2 from the cooling gas flow.
- the invention thus essentially builds on a gas turbine system with sequential combustion, at which the recirculated exhaust gas is compressed to an intermediate pressure via a correspondingly provided compressor unit, at which the C0 2 separation takes place and which also allows the C0 2 depleted exhaust gas stream as a cooling gas stream at the intermediate pressure level for the purposes of cooling in the second combustion chamber and preferably also feed into the low pressure turbine stage.
- the pre-compressed, recirculated exhaust gas stream is passed through a cooler before entering the C0 2 separator unit.
- the part of the cooling gas flow used to cool the second combustion chamber is heated up again to the working temperature of the low-pressure turbine by the sequential combustion, whereby there is no loss of efficiency.
- the firing of the second combustion chamber provides for the use of a partial oxidation, in which, in order to set a stoichiometric combustion, the second combustion chamber is combined with an oxidation unit, by means of the fuel for firing the second combustion chamber at least partially is oxidized with the release of hydrogen and is ignited with the formation of a stoichiometric fuel-oxygen mixture at least with the C0 2 depleted exhaust gas stream serving as cooling gas.
- the hot gases emerging from the high-pressure turbine stage can be proportionally mixed with the cooling gas stream. Further details related to this can also be found in the exemplary embodiments described below.
- the method according to the invention for operating a thermal power plant with sequential combustion and reduced CO 2 emissions is characterized in that at least a portion of the exhaust gas emerging from the low-pressure turbine stage is recirculated, compressed and fed to a CO 2 separator for the production of CO 2 and that C0 2 depleted exhaust gas stream is also provided as a cooling gas stream for cooling.
- FIG. 2-7 schematic process diagrams for gas turbine plant designed according to the invention with sequential combustion and a C0 2 - reduced exhaust gas flow.
- the gas turbine system essentially consists of a high-pressure turbine stage 3 and a low-pressure turbine stage 5 with a sequential combustion 4 in between.
- Supply air L is compressed to a high pressure level in a combustion supply air compressor unit 1 via two compressor stages LP, HP.
- this air is premixed with fuel B and burned.
- the hot gas generated in the combustion chamber 3 is then expanded to the intermediate pressure in the high-pressure turbine stage 3. Since the hot gas originating from the first lean premix combustion still contains more than half of its original oxygen content, fuel B is again mixed in directly in front of a special sequential combustion chamber 4 and brought to ignition.
- This reheated hot gas expands downstream to atmospheric pressure in a low-pressure turbine stage 5, the relaxed hot gases ultimately being released into the free atmosphere in the form of an exhaust gas stream A.
- a portion of the combustion air pre-compressed in the low-pressure compressor part LP is branched off and cooled via a cooling unit KA1 and fed to the sequential combustion chamber 4 and also to the low-pressure turbine stage 5 for cooling purposes.
- the exhaust gas A emerging from the low-pressure turbine stage 5 is recirculated via a recirculation line 6 into the supply air flow of the low-pressure compressor unit 7, in which the recirculated exhaust gas with the supply air mixed and compressed to an intermediate pressure level.
- the recirculated exhaust gas A passes along the recirculation line 6 through a heat exchanger unit D, on which heat is transferred to a steam circuit, for example for driving a steam turbine (not shown further).
- the recirculation line 6 provides a cooler unit KA1, in which the exhaust gas is cooled and dehumidified by condensation.
- the exhaust gas which has been pre-compressed to intermediate pressure by the low-pressure compressor part LP, now passes via a so-called cooling line 8 into a C0 2 separating unit 9, in which a thoroughly efficient C0 2 separation takes place due to the prevailing high intermediate pressure level.
- a further cooler unit KA2 is advantageously provided upstream of the CO 2 separator unit 9.
- Known separation devices such as chemical absorption, for example based on MEA or physically acting separators, for example based on membranes. With the help of such C0 2 separation units, C0 2. Separator effects between 70 and 99% can be achieved.
- the CO2-depleted exhaust gas stream emerging from the C0 2 separating unit 9 is subsequently fed to the sequential burner unit 4 and the low-pressure turbine stage 5 for cooling purposes.
- the part of the cooling gas flow used to cool the second combustion chamber is heated up again to the working temperature of the low-pressure turbine by the sequential combustion, as a result of which there is no loss of efficiency.
- the recirculated exhaust gas is mixed into the combustion air L to such an extent that the oxygen content in the air supply to the combustion chamber 2 is just sufficient to burn the fuel B supplied.
- the sequential combustion takes place in the combustion chamber 4 with a lack of oxygen.
- fuel B is first reacted with a lack of oxygen in the context of a so-called oxidation unit 11.
- the oxidation unit 11 is advantageously designed as a catalyst unit, to which the fuel B to be oxidized and an amount of oxygen in the range between 20 and 75% of the theoretical oxygen requirement for complete oxidation of the fuel are supplied.
- the amount of oxygen supplied takes place via the feed line 10, which branches off part of the CO 2 -enriched exhaust gas from the cooling line 8.
- parts of the hot gases escaping from the high pressure turbine stage 3 can additionally be mixed in via the supply line 12 in the CO 2 depleted exhaust gas stream for feeding into the oxidation stage 11 ,
- part of the hydrogen is separated from the hydrocarbon compounds of the fuel B and after the partial oxidation stage 11 is present as free hydrogen in the hot outlet mixture before entering the sequential combustion stage 4. If the hot gases emerging from the high-pressure turbine stage 3 are fed to the sequential combustion stage 4 with this gas mixture containing hydrogen components, the high temperature and the high reactivity of the hydrogen contained lead to a spontaneous reaction and the complete burnout in the form of hydrogen, CO and remaining hydrocarbons still existing fuel.
- the high reactivity of the burner mixture leads to a stable combustion within the sequential combustion stage 4, so that the disadvantages mentioned at the outset with regard to the occurrence of thermoacoustic vibrations, high CO emissions and the extinguishing of the premix burner flame can be completely avoided.
- the use of a fuel supply lance within the sequential combustion stage 4 is suitable, within which the reaction of the supplied fuel B required for the release of hydrogen takes place through the use of a catalyst.
- the primary aim according to the invention is to reduce the CO 2 content of the exhaust gases released by the gas turbine system.
- the C0 2 separation unit 9 used according to the invention in the cooling line 8 works the more effectively, the greater the CO 2 concentration supplied to the separation unit in the inflow.
- the recirculated exhaust gas is pre-compressed by means of the low-pressure compressor part LP of the combustion air compressor unit 1.
- the recirculated exhaust gas mixes with the supplied air L. and is thus compressed together within the low pressure compressor part LP.
- a diluted, precompressed exhaust gas stream thus reaches the C0 2 separating unit 9.
- a separate compressor for the recirculated exhaust gas Shaft W along which the combustion air compressor unit 1 and the high and low pressure turbine stages 3, 5 are arranged, a separate exhaust gas compressor unit 7 is provided, in which only the recirculated exhaust gas is compressed via the recirculation line 6 and via the cooler unit KA2 the C0 2 - Separation unit 9 is supplied. In this way, the high C0 2 concentration in the exhaust gas is maintained, whereby an increase in efficiency of the C0 2 separation unit 9 can be achieved.
- the exhaust gas no longer contains oxygen and, as a result, can no longer be used for combustion, for example by partial oxidation.
- the process diagram of the exemplary embodiment in FIG. 4 does not provide a partial oxidation stage, rather the CO 2 -reduced exhaust gas is only used for cooling purposes within the sequential combustion stage 4 and the low-pressure turbine stage 5.
- return lines 13 are provided, via which the recirculated exhaust gas compressed in the exhaust gas compressor unit 7 is either direct, cooled or C0 2 -reduced after passing through the C0 2 separation unit 9 of the high-pressure compressor stage HP is supplied for the purpose of a metered admixture to the supply air L.
- a bypass line 14 optionally serves to bypass the C0 2 separating unit 9 of part of the compressed and cooled recirculated exhaust gas flow in cases in which the recirculated exhaust gas flow exceeds the absorption capacity of the C0 2 separating unit 9.
- FIG. 5 shows a further exemplary embodiment, which, comparable to the exemplary embodiment in FIG. 4, provides a separate CO 2 compressor stage 7, in addition the sequential combustion takes place by means of a partial oxidation, the amount of oxygen supplied to the partial oxidation stage 11 via a bypass line 15 takes place, which, downstream of the low-pressure compressor part LP, enables a specific discharge of part of the pre-compressed supply air L into the oxidation unit 11, in which the fuel is partially oxidized with the release of hydrogen. It would also be possible, alternatively or in combination with the bypass line 15, via the line 12 from the high-pressure turbine stage 3 to use escaping hot gases from the oxidation unit 11 to carry out the partial oxidation of the fuel B.
- All of the exemplary embodiments described above relate to gas turbine systems, along the single shaft W of which the generator unit G, the combustion air compressor unit 1 and the high-pressure turbine stage 3 and low-pressure turbine stage 5 are arranged. In cases in which the recirculated exhaust gas is compressed in a separate exhaust gas compressor unit 7, this is also attached along the common shaft W.
- FIG. 6 A process diagram of such a gas turbine system is shown in FIG. 6. If the process diagram described in FIG. 2 is used as the basis, the gas turbine system according to FIG. 6 differs in that a second shaft W is provided, which is separated from a separate gas turbine, consisting of the high-pressure turbine part 3 'and low-pressure turbine part 5' is driven. The high-pressure turbine part 3 'and the low-pressure turbine part 5' are each charged with hot gases, which each emerge from the combustion chambers 2 'and 4'.
- the high-pressure compressor stage HP ' is likewise supplied, like the high-pressure compressor stage HP, by the pre-compressed supply air L, which originates from the low-pressure compressor stage LP of the combustion supply air compressor unit 1.
- the recirculated exhaust gas which is fed via the recirculation line 6 to the low-pressure compressor stage LP 'of the combustion air compressor unit 1' and compressed to an intermediate pressure, is not admixed to the combustion air supply, but is fed exclusively into the CO 2 separator unit 9 via a cooled discharge line.
- the C0 2 separator unit Due to the separate compression of the recirculated exhaust gas in the context of the low-pressure compressor stage LP ', the C0 2 separator unit is supplied with a highly compressed and, above all, high-concentration C0 exhaust gas stream, from which C0 can be separated very efficiently.
- the significantly reduced C0 2 exhaust gas flow is also, as already described in the above exemplary embodiments, supplied for cooling purposes to the sequential combustion chamber 4 and 4 'and also to the low-pressure turbine stages 5 and 5'.
- the CO 2 portion of the exhaust gas stream A emerging from the gas turbine system can be significantly reduced, but a complete CO 2 separation from the exhaust gas stream escaping into the free atmosphere is not possible due to the system.
- exhaust gas components from the low-pressure turbine stage 5 are contained in the exhaust gas stream A and remain in the exhaust gas stream due to the lack of recirculation.
- the last exemplary embodiment according to FIG. 7 provides for the use of partial oxidation.
- the process diagram shown in FIG. 7 is a further development of the process diagram shown in FIG. 6 in the sense of the partial oxidation described with reference to FIG. 5.
- bypass line 15, 15 ' also serves for the targeted supply of oxygen within the range of between 20 and 75% of the theoretical oxygen requirement for complete oxidation, which in connection with the hydrogen release due to the catalytic fuel conversion leads to a reactive, ignitable mixture , which ensures a stable combustion process.
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- General Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
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Abstract
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
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AT04820847T ATE549577T1 (de) | 2003-12-23 | 2004-11-26 | Wärmekraftanlage mit sequentieller verbrennung und reduziertem co2-ausstoss sowie verfahren zum betreiben einer derartigen anlage |
EP04820847A EP1702176B1 (de) | 2003-12-23 | 2004-11-26 | Wärmekraftanlage mit sequentieller verbrennung und reduziertem co2-ausstoss sowie verfahren zum betreiben einer derartigen anlage |
CA002550675A CA2550675A1 (en) | 2003-12-23 | 2004-11-26 | Thermal power plant with sequential combustion and reduced-co2 emission, and a method for operating a plant of this type |
US11/453,971 US7503178B2 (en) | 2003-12-23 | 2006-06-16 | Thermal power plant with sequential combustion and reduced-CO2 emission, and a method for operating a plant of this type |
NO20063395A NO338858B1 (no) | 2003-12-23 | 2006-07-21 | Teknisk kraftanlegg med sekvensiell forbrenning og reduserte utslipp av CO2, og en fremgangsmåte for drift av et anlegg av denne type |
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DE10360951A DE10360951A1 (de) | 2003-12-23 | 2003-12-23 | Wärmekraftanlage mit sequentieller Verbrennung und reduziertem CO2-Ausstoß sowie Verfahren zum Betreiben einer derartigen Anlage |
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Also Published As
Publication number | Publication date |
---|---|
EP1702176A1 (de) | 2006-09-20 |
CA2550675A1 (en) | 2005-07-14 |
ATE549577T1 (de) | 2012-03-15 |
EP1702176B1 (de) | 2012-03-14 |
CN1898499A (zh) | 2007-01-17 |
NO338858B1 (no) | 2016-10-24 |
US7503178B2 (en) | 2009-03-17 |
DE10360951A1 (de) | 2005-07-28 |
US20060272331A1 (en) | 2006-12-07 |
NO20063395L (no) | 2006-08-18 |
CN100561046C (zh) | 2009-11-18 |
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