WO2005063923B1 - Carbonization apparatus for producing activated carbon - Google Patents

Carbonization apparatus for producing activated carbon

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Publication number
WO2005063923B1
WO2005063923B1 PCT/JP2004/016681 JP2004016681W WO2005063923B1 WO 2005063923 B1 WO2005063923 B1 WO 2005063923B1 JP 2004016681 W JP2004016681 W JP 2004016681W WO 2005063923 B1 WO2005063923 B1 WO 2005063923B1
Authority
WO
WIPO (PCT)
Prior art keywords
steam
furnace
carbonization
activated carbon
treated
Prior art date
Application number
PCT/JP2004/016681
Other languages
French (fr)
Japanese (ja)
Other versions
WO2005063923A1 (en
Inventor
Ikuyoshi Kohchi
Tadashi Yokoi
Original Assignee
Intellectual Property Bank
Ikuyoshi Kohchi
Tadashi Yokoi
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Intellectual Property Bank, Ikuyoshi Kohchi, Tadashi Yokoi filed Critical Intellectual Property Bank
Priority to JP2005516553A priority Critical patent/JPWO2005063923A1/en
Priority to US10/581,908 priority patent/US20070101912A1/en
Publication of WO2005063923A1 publication Critical patent/WO2005063923A1/en
Publication of WO2005063923B1 publication Critical patent/WO2005063923B1/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • C10B53/02Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00Carbon; Compounds thereof
    • C01B32/30Active carbon
    • C01B32/39Apparatus for the preparation thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B49/00Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated
    • C10B49/02Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with hot gases or vapours, e.g. hot gases obtained by partial combustion of the charge
    • C10B49/04Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with hot gases or vapours, e.g. hot gases obtained by partial combustion of the charge while moving the solid material to be treated
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B7/00Coke ovens with mechanical conveying means for the raw material inside the oven
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/10Biofuels, e.g. bio-diesel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency
    • Y02P20/129Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines

Abstract

A carbonization apparatus (10) for producing an activated carbon wherein an organic based material to be treated is carbonized, which comprises a carbonization furnace (40) wherein overheated steam is introduced to carbonize a material to be treated and the spent steam is discharged, a drying furnace (30) wherein the steam discharged from the carbonization furnace (40) is introduced to dry the material to be treated and the spent steam is discharged, a high temperature steam generating device (60) wherein steam is introduced and the high temperature overheated steam for use in supplying to the carbonization furnace (40) is formed, a deodorizing furnace (70) wherein impurities contained in the spent steam discharged from the drying furnace (30) are heated to deodorize them through burning and discharging a high temperature an exhaust gas is discharged, and a waste heat boiler (80) wherein water is heated by using the high temperature exhaust gas discharged from the deodorizing furnace (70) and the steam for supplying to the high temperature steam generating device (60) is formed. The carbonization apparatus allows the production of an activated carbon having high quality at a low cost, by recovering and reutilizing the heat contained in the exhaust gas which has been discharged from a deodorizing furnace and has been subjected to a burning treatment.

Claims

補正書の請求の範囲 [2005年 7月 7曰 (07.07.05) 国際事務局受理:出願当初の請求の範囲 1-3は補正された; 他の請求の範囲は変更なし。 ] Scope of claims for amendments [July 7, 2005 (07.07.05) International Bureau accepted: Scope of claims for initial application 1-3 was amended; the scope of other claims remains unchanged. ]
1 . (補正後) 生ごみ、 木材、 肉骨粉、 衣類屑、 プラスチックス等の有機系の 処理対象物を水蒸気で加熱して乾燥、 乾留、 賦活等の炭化処理を行なう活性炭製 造用炭化装置において、 1 (After correction) Activated carbon making equipment for producing activated carbon that performs organic treatment such as garbage, wood, meat and bone meal, clothing waste, plastics etc. with organic vapor heating and drying, dry distillation, activation, etc. In
過熱水蒸気を導入して処理対象物と直接接触伝熱によつて処理対象物を乾燥し、 炭化させ、 使用済みの水蒸気を排出する乾燥炭化炉と、  A drying carbonization furnace which introduces superheated steam and dries the object to be treated by direct contact heat transfer with the object to be treated, carbonizes it, and discharges used steam,
水蒸気を導入して乾燥炭化炉に供給する高温の過熱水蒸気を生成する高温水蒸 気発生装置と、  A high temperature water vapor generator for generating high temperature superheated steam which introduces steam and supplies it to the drying and carbonizing furnace;
乾燥炭化炉から排出された使用済みの水蒸気に含まれる不純物を加熱して脱臭 燃焼させ、 高温の排気を排出する脱臭炉と、  A deodorizing furnace which heats, deodorizes and burns impurities contained in the used steam discharged from the dry carbonizing furnace and discharges high temperature exhaust;
脱臭炉から排出される高温の排気を用いて水を加熱し、 高温水蒸気発生装置に 供給する水蒸気を生成する廃熱ポイラと、  Waste heat spoiler which heats water using high temperature exhaust gas discharged from the deodorizing furnace and generates steam to be supplied to a high temperature steam generator;
を備えたことを特徴とする活性炭製造用炭化装置。  A carbonizing apparatus for producing activated carbon characterized by comprising:
2 . (補正後) 生ごみ、 木材、 肉骨粉、 衣類屑、 プラスチックス等の有機系の 処理対象物を水蒸気で加熱して乾燥、 乾留、 賦活等の炭化処理を行なう活性炭製 造用炭化装置において、  2 (After correction) Activated carbon making equipment for producing activated carbon that performs organic treatment such as organic waste, wood, meat and bone meal, clothing waste, plastics etc. with steam heating and drying, dry distillation, activation, etc. In
過熱水蒸気を導入して処理対象物と直接接触伝熱によつて処理対象物を炭化さ せ、 使用済みの水蒸気を排出する炭化炉と、  A carbonizing furnace which introduces superheated steam and carbonizes the object to be treated by direct contact heat transfer with the object to be treated and discharges used steam;
炭化炉から排出した水蒸気を導入して処理対象物と直接接触伝熱によって処理 対象物を乾燥させ、 使用済みの水蒸気を排出する乾燥炉と、  A drying furnace for introducing the water vapor discharged from the carbonizing furnace and drying the material to be treated by direct contact heat transfer with the material to be treated and discharging the used water vapor;
水蒸気を導入して炭化炉に供給する高温の過熱水蒸気を生成する高温水蒸気発 生装置と、  A high temperature steam generator for introducing steam and generating high temperature superheated steam to be supplied to the carbonizing furnace;
乾燥炉から排出された使用済みの水蒸気に含まれる不純物を加熱して脱臭燃焼 させ、 高温の排気を排出する脱臭炉と、  A deodorizing furnace that heats and deodorizes the impurities contained in the used steam discharged from the drying furnace and discharges high-temperature exhaust;
脱臭炉から排出される高温の排気を用いて水を加熱し、 高温水蒸気発生装置に 供給する水蒸気を生成する廃熱ボイラと、  A waste heat boiler that heats water using high temperature exhaust discharged from a deodorizing furnace and generates steam to be supplied to a high temperature steam generator;
を備えたことを特徴とする活性炭製造用炭化装置。  A carbonizing apparatus for producing activated carbon characterized by comprising:
3 . (補正後) 生ごみ、 木材、 肉骨粉、 衣類屑、 プラスチックス等の有機系の 捕正された用紙 (条約第 I9条;) 22 3 (After amendment) Organically collected paper such as garbage, wood, meat and bone meal, clothing waste, plastics etc. (Article 9 of the Convention;) twenty two
処理対象物を水蒸気で加熱して乾燥、 乾留、 賦活等の炭化処理を行なう活性炭製 造用炭化装置において、 An activated carbon manufacturing carbonization apparatus which heats the object to be treated with steam and carries out carbonization treatment such as drying, dry distillation, activation, etc.
過熱水蒸気を導入して処理対象物と直接接触伝熱によつて処理対象物の炭化を 促進させ、 使用済みの水蒸気を排出する炭化促進炉と、  A carbonization promoting furnace that introduces superheated steam to promote carbonization of the processing object by direct contact heat transfer with the processing object, and discharges the used water vapor;
炭化促進炉から排出した水蒸気を導入して処理対象物と直接接触伝熱によって 処理対象物を炭化させ、 使用済みの水蒸気を排出する炭化炉と、  A carbonization furnace for introducing the water vapor discharged from the carbonization promoting furnace to carbonize the object to be treated by direct contact heat transfer with the object to be treated and discharging the used water vapor;
炭化炉がら排出した水蒸気を導入して処理対象物と直接接触伝熱によって処理 対象物を乾燥させ、 使用済みの水蒸気を排出する乾燥炉と、  A drying furnace for introducing the water vapor discharged from the carbonizing furnace and drying the processing object by direct contact heat transfer with the object to be treated and discharging the used water vapor;
水蒸気を導入して炭化促進炉に供給する高温の過熱水蒸気を生成する高温水蒸 気発生装置と、  A high temperature water vapor generator for generating high temperature superheated steam which introduces steam and supplies it to the carbonization promoting furnace;
乾燥炉から排出された使用済みの水蒸気に含まれる不純物を加熱して脱臭燃焼 させ、 高温の排気を排出する脱臭炉と、  A deodorizing furnace that heats and deodorizes the impurities contained in the used steam discharged from the drying furnace and discharges high-temperature exhaust;
脱臭炉から排出される高温の排気を用いて水を加熱し、 高温水蒸気発生装置に 供給する水蒸気を生成する廃熱ボイラと、  A waste heat boiler that heats water using high temperature exhaust discharged from a deodorizing furnace and generates steam to be supplied to a high temperature steam generator;
を備えたことを特徴とする活性炭製造用炭化装置。  A carbonizing apparatus for producing activated carbon characterized by comprising:
4. 請求項 1乃至 3に記載の活性炭製造用炭化装置の乾燥炉、 炭化炉、 乾燥炭 化炉又は炭化促進炉において、  4. The drying furnace, the carbonization furnace, the drying carbonization furnace or the carbonization promoting furnace according to any one of claims 1 to 3.
処理対象物を供給する処理対象物供給口と、 処理対象物を攪拌移動させる円筒 部と、 処理対象物を排出する排出口と、 過熱水蒸気又は使用済みの水蒸気を円筒 部外側から円筒內面の接線方向に導入する水蒸気導入口とを有する円筒シェルと、 前記円筒シェル内で処理対象物を携拌移動させる回転可能な攪拌羽根と、 を備えたことを特徴とする活性炭製造用炭化装置。  A processing object supply port for supplying the processing object, a cylindrical portion for stirring and moving the processing object, an outlet for discharging the processing object, superheated steam or used water vapor from the outside of the cylindrical portion A carbonization apparatus for producing activated carbon, comprising: a cylindrical shell having a water vapor inlet port introduced tangentially; and a rotatable stirring blade for carrying and moving an object to be treated within the cylindrical shell.
5 . 請求項 4に記載の活性炭製造用炭化装置の円筒シェルに設けた水蒸気導入 口は、 5. The steam inlet provided in the cylindrical shell of the carbonizing apparatus for producing activated carbon according to claim 4 is:
過熱水蒸気又は使用済みの水蒸気を、 前記攪拌羽根の回転方向と同じ方向の円 筒内面接線方向に導入する水蒸気導入口としたことを特徴とする活性炭製造用炭 化装置。  A steam introduction port for introducing superheated steam or used steam in the in-cylinder interview line direction in the same direction as the rotation direction of the stirring blade, wherein the carbonization apparatus for producing activated carbon is characterized.
6 . 請求項 5に記載の水蒸気導入口を、 活性炭製造用炭化装置の円筒シェルに  6. The steam inlet according to claim 5 is used as a cylindrical shell of a carbonizing apparatus for producing activated carbon.
楠正された用紙 (条約第 23 Corrected form twenty three
複数設けたことを特徴とする活性炭製造用炭化装置。 A plurality of carbonization devices for producing activated carbon characterized by being provided.
7 . 請求項 4に記載の活性炭製造用炭化装置の円筒シェルに、  7. The cylindrical shell of the carbonizing apparatus for producing activated carbon according to claim 4
円筒シェル内で処理対象物を加熱した後の使用済み水蒸気を、 円筒部内面から 円筒部外側へ、 円筒部内面の接線方向に排出する水蒸気排出口を備えたことを特 徴とする活性炭製造用炭化装置。  For activated carbon production characterized by having a steam outlet for discharging the used steam after heating the object to be treated in the cylindrical shell from the inner surface of the cylindrical part to the outer side of the cylindrical part in the tangential direction of the inner surface of the cylindrical part. Carbonization equipment.
8 . 請求項 5に記載の活性炭製造用炭化装置の円筒シェルに、  8. The cylindrical shell of the carbonizing apparatus for producing activated carbon according to claim 5
円筒シェル内で処理対象物を加熱した後の使用済み水蒸気を、 円筒部内面から 円筒部外側へ、 円筒部内面の接線方向に排出する水蒸気排出口を備えたことを特 徴とする活性炭製造用炭化装置。  For activated carbon production characterized by having a steam outlet for discharging the used steam after heating the object to be treated in the cylindrical shell from the inner surface of the cylindrical part to the outer side of the cylindrical part in the tangential direction of the inner surface of the cylindrical part. Carbonization equipment.
9 . 請求項 6に記載の活性炭製造用炭化装置の円筒シェルに、 .  9. A cylindrical shell of a carbonization apparatus for producing activated carbon according to claim 6,
円筒シェル内で処理対象物を加熱した後の使用済み水蒸気を、 円筒部内面から 円筒部外側へ、 円筒部内面の接線方向に排出する水蒸気排出口を備えたことを特 徴とする活性炭製造用炭化装置。  For activated carbon production characterized by having a steam outlet for discharging the used steam after heating the object to be treated in the cylindrical shell from the inner surface of the cylindrical part to the outer side of the cylindrical part in the tangential direction of the inner surface of the cylindrical part. Carbonization equipment.
1 0 . 請求項 1乃至 3に記載の活性炭製造用炭化装置において、  In the carbonizing apparatus for producing activated carbon according to any one of claims 1 to 3,
前記乾燥炉、 炭化炉、 乾燥炭化炉又は炭化促進炉に供給する過熱水蒸気又は使 用済みの水蒸気の流速を 5乃至 2 0 (m/ s ) に調節する圧力調節機構又は絞り を備えたことを特徴とする活性炭製造用炭化装置。  Having a pressure control mechanism or throttling to adjust the flow rate of the superheated steam or used steam supplied to the drying furnace, carbonization furnace, drying carbonization furnace or carbonization promoting furnace to 5 to 20 (m / s) A carbonization device for producing activated carbon that is characterized.
1 1 . 請求項 4に記載の活性炭製造用炭化装置において、  1 1. In the carbonization apparatus for producing activated carbon according to claim 4,
前記乾燥炉、 炭化炉、 乾燥炭化炉又は炭化促進炉に供給する過熱水蒸気又は使 用済みの水蒸気の流速を 5乃至 2 0 (m/ s ) に調節する圧力調節機構又は絞り を備えたことを特徴とする活性炭製造用炭化装置。  Having a pressure control mechanism or throttling to adjust the flow rate of the superheated steam or used steam supplied to the drying furnace, carbonization furnace, drying carbonization furnace or carbonization promoting furnace to 5 to 20 (m / s) A carbonization device for producing activated carbon that is characterized.
1 2 請求項 5乃至 9に記載の活性炭製造用炭化装置において、  1 2 In the carbonization apparatus for producing activated carbon according to claims 5 to 9,
前記乾燥炉、 炭化炉、 乾燥炭化炉又は炭化促進炉に供給する過熱水蒸気又は使 用済みの水蒸気の流速を 5乃至 2 0 (m/ s ) に調節する圧力調節機構又は絞り を備えたことを特徴とする活性炭製造用炭化装置。  Having a pressure control mechanism or throttling to adjust the flow rate of the superheated steam or used steam supplied to the drying furnace, carbonization furnace, drying carbonization furnace or carbonization promoting furnace to 5 to 20 (m / s) A carbonization device for producing activated carbon that is characterized.
補正された用紙 (条約第 19条) Amended paper (Article 19 of the Convention)

条約 1 9条に基づく説明書 請求の範囲第 1項については、 「処理対象物と直接接触伝熱によって」 を追加し補正しました。 この補正は明細書中の 9ページ [0031] 段 落 7〜8行目の 「過熱水蒸気を円筒部 43外側から攪拌羽根 44の回転 方向と同じ方向の円筒内面接線方向 (タンジェンシャル方向) に導入す る水蒸気導入口 46と、 ' · ·」、 およぴ図 1、 2の記載に基づくもので あります。  Treaty Item 9 Article 9 Based on claim 1 of the claim, we have added and corrected “with the object to be treated and direct contact heat transfer”. This correction is given on page 9 of the specification. [0031] Step 7-8 [Lines of superheated steam from the outside of the cylindrical part 43 from the outside of the cylinder 43 in the same direction as the direction of rotation of the stirring blade 44] It is based on the water vapor inlet 46 to be introduced, and the description of '· · ·', and Figures 1 and 2.

請求の範囲第 2項については、 「処理対象物と直接接触伝熱によって」 を 2個所に追加し補正しました。 この補正は明細書中の 9ページ [00 30] 段落 5〜7行目の 「 · · ·水蒸気を円筒部 33外側から攪拌羽根 34の回転方向と同じ方向の円筒内面接線方向(タンジェンシャル方向) に導入する水蒸気導入口 36と、 ' · ·」、 13ページ [0050] 段落 4〜 5行目の 「 · · ·水蒸気は攪拌羽根 34にて拡販移動されている処 理対象物とよく混合しながら加熱分解 · · ·」、 およぴ図 1、 2の記載に 基づくものであります。  With regard to claim 2 item, “with the object to be processed and direct contact heat transfer” was added and corrected in two places. This correction is given on page 9 of the specification. [00 30] Paragraphs 5 to 7 [· · · · Water vapor from the outside of the cylindrical portion 33 from the outer side of the stirring blade 34 in the same direction as the direction of rotation of the stirring blade 34 (tangential direction Water vapor inlet 36 to be introduced into the), · · ·, page 13 [0050] Paragraphs 4 to 5 "· · · Water vapor mixes well with the processing object being sold and moved by the stirring blade 34 While the thermal decomposition · · · · ·, and is based on the description of Figure 1 and 2.

請求の範囲第 3項については、 「処理対象物と直接接触伝熱によって」 を 3個所に追加し插正しました。 この補正は明細書中の 9ページ [00 30] 段落 5〜 7行目、 13ページ [0050] 段落 4〜5行目、 1 1 ページ [0044] 段落 1〜2行目、 1 7ページ [0070] 段落 2〜 5行目、 およぴ図 1、 2の記載に基づくものであります。  With regard to claim 3 item, we corrected “by processing object and direct contact heat transfer” at three locations and corrected. This correction is made on page 9 of the specification [00 30] paragraph 5 to line 7, page 13 [0050] paragraph 4 to line 5, page 1 1 [0044] paragraph 1 to line 2, page 7 [0070] ] Based on the description in paragraphs 2 to 5 and figures 1 and 2.

また、 請求の範囲の 4一 1 2項は変更ありません。  There is no change to items 4 and 12 of the claims.

引用文献 1〜4には、 過熱水蒸気 (または水蒸気) と処理対象物との 直接接触伝熱によつて処理対象物を乾燥し、 炭化させることについては 何等開示されておらず、 示唆すらされておりません。  The cited documents 1 to 4 disclose nothing about drying and carbonizing the object to be treated by direct contact heat transfer between the superheated steam (or steam) and the object to be treated, and it is even suggested. not here.

また、 引用文献 5は、 分離槽に水蒸気を含有するエアーが接線方向か ら導入されることが記載されているが、 これはエアーからタール等を分 離する目的であり、 本願発明のような 「処理対象物とよく混合しながら 加熱し、 直接接触伝熱によって処理対象物を乾燥し、 炭化させる」 目的 とは異なり、 したがって、 本願発明は引用文献 1、 2、 5から容易に発 明できるものではありません。 Also, cited reference 5 indicates that the air containing steam is tangential to the separation tank. However, this is the purpose of separating tar etc. from air, as in the present invention, “It is heated while mixing well with the object to be treated, and the object to be treated is treated by direct contact heat transfer. Unlike the purpose of drying and carbonizing objects, the present invention is therefore not easily identifiable from the cited references 1, 2 and 5.

以上のことから、補正された請求の範囲は、引用文献の全てについて、 新規性、 進歩性を有するものであると思料致します。  From the above, the amended claims are considered to be novel and inventive in all of the cited documents.

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PCT/JP2004/016681 2003-12-08 2004-11-10 Carbonization apparatus for producing activated carbon WO2005063923A1 (en)

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