WO2005058482A1 - Adsorbants destines a eliminer des metaux lourds, et procedes de production et d'utilisation des adsorbants - Google Patents

Adsorbants destines a eliminer des metaux lourds, et procedes de production et d'utilisation des adsorbants Download PDF

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Publication number
WO2005058482A1
WO2005058482A1 PCT/US2004/042191 US2004042191W WO2005058482A1 WO 2005058482 A1 WO2005058482 A1 WO 2005058482A1 US 2004042191 W US2004042191 W US 2004042191W WO 2005058482 A1 WO2005058482 A1 WO 2005058482A1
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WO
WIPO (PCT)
Prior art keywords
adsorbent
heavy metal
metal
anions
iron
Prior art date
Application number
PCT/US2004/042191
Other languages
English (en)
Inventor
Toan Phan Vo
Original Assignee
Calgon Carbon Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from PCT/US2003/039925 external-priority patent/WO2005061099A1/fr
Priority claimed from US11/006,084 external-priority patent/US7429551B2/en
Priority claimed from US11/005,825 external-priority patent/US20050093189A1/en
Application filed by Calgon Carbon Corporation filed Critical Calgon Carbon Corporation
Publication of WO2005058482A1 publication Critical patent/WO2005058482A1/fr

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    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/28—Treatment of water, waste water, or sewage by sorption
    • C02F1/288—Treatment of water, waste water, or sewage by sorption using composite sorbents, e.g. coated, impregnated, multi-layered
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/64—Heavy metals or compounds thereof, e.g. mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B01J20/08—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04 comprising aluminium oxide or hydroxide; comprising bauxite
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J20/2803—Sorbents comprising a binder, e.g. for forming aggregated, agglomerated or granulated products
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    • B01J20/28033—Membrane, sheet, cloth, pad, lamellar or mat
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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J20/3042—Use of binding agents; addition of materials ameliorating the mechanical properties of the produced sorbent
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    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3202—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the carrier, support or substrate used for impregnation or coating
    • B01J20/3204—Inorganic carriers, supports or substrates
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    • B01J20/3234—Inorganic material layers
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    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
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Definitions

  • the present invention relates to adsorbents for removing heavy metals from a medium adjacent thereto and methods for producing and using the same.
  • the present invention relates to adsorbents for removing arsenic and/or selenium from a medium adjacent thereto and methods for producing and using the same.
  • the coagulant containing arsenic must be filtered, resulting in additional costs.
  • Lime softening techniques have been shown to be effective at pH levels greater than about 10.5; and, therefore, is not likely to be applicable in drinking water applications.
  • Adsorption treatment methods using activated alumina or ion exchange have been proposed and tested on a pilot-plant scale. However, adsorption of arsenic on alumina is seriously compromised when other ions are present, such, as selenium, fluoride, chloride, and sulfate.
  • the adsorption process using ion exchange adsorbents can remove arsenic, but sulfate, total dissolved solids ("TDS"), selenium, fluoride, and nitrate also compete with arsenic for the ion exchange capacity, thus decreasing likely effectiveness. Therefore, there is a need to provide simple and convenient materials and methods for removing heavy metals such as arsenic and/or selenium from the environment that do not have the disadvantages of the prior-art materials and methods. It is also desirable to provide convenient materials and methods for removing arsenic and/or selenium from the environment, which materials and methods can be made widely available at low cost.
  • the present invention provides materials and methods for removing heavy metals that exist as anions from the environment to acceptable levels.
  • the removal material comprises a carbon adsorbent, silica, alumina, zeolite, zirconium oxide ion exchange resins, for example.
  • the material has at least one oxygen-containing compound incorporated therein.
  • the oxygen-containing compound is a metal selected from the group consisting of iron, copper, aluminum, titanium, and zirconium.
  • the oxygen-containing compound of a metal is selected from the group consisting of oxides and hydroxides.
  • the oxygen-containing compound of a metal is incorporated into the material by a method of impregnating or dispersing at least a compound of the metal in the material.
  • Another embodiment of the present invention provides a method for producing a material capable of removing heavy metals that exist as anions. The method comprises the steps of: (1) providing a removal material; (2) impregnating the removal material with at least one compound of a metal selected from the group consisting of iron, copper, aluminum, titanium, zirconium, or combinations thereof; and (3) converting said compound into at least one oxygen-containing compound.
  • the method comprises the steps of: (1) providing a material; (2) mixing at least one compound of a metal selected from the group consisting of iron, copper, aluminum, titanium, and zirconium or combinations thereof into the material to produce a mixture of the material and the metal; (3) forming the mixture into particles of a material containing the metal; and (4) converting the particles of the material containing the metal into particles of a material containing said metal.
  • the material of the present invention for use in removing metal anions from a liquid or gas medium may be made by: (1) pulverizing a carbonaceous material, a binder, and at least one compound of a metal selected from the group consisting of iron, copper, aluminum, titanium, zirconium, or combinations thereof to form a powdered mixture; (2) compacting said powdered mixture into shaped objects; and (3) crushing and screening the shaped objects into a metal-containing particulate material to produce said carbon adsorbent.
  • the carbonaceous material, binder and metal compound are pulverized together or, alternatively, the carbonaceous material, binder and metal compound are pulverized separately before making the pulverized mixture.
  • the compacting is accomplished by briquetting, pelletizing, densifying or extruding processes.
  • the method may also have an additional step four comprising gasifying said metal containing particulate material to produce said carbon absorbent.
  • the gasifying of step four is conducted under an atmosphere comprising an oxygen- containing gas at a temperature in a range from about 900 C to about 1100° C for a time sufficient to produce an adsorbent having a BET surface area of at least 10 m 2 /g.
  • the method may also comprise the additional step of oxidizing said metal-containing particulate material before the step of gasifying.
  • the method for removing heavy metals that exist as anions comprises the steps of: (1) providing a material containing a metal selected from the group consisting of iron, copper, aluminum, titanium, and zirconium; and (2) contacting said material containing said metal with a medium containing the heavy metal anions.
  • the method comprises the steps of: (1) contacting a material with a portion of a fluid or gas medium; and (2) filtering the material from the medium.
  • the material comprises a carbon, silica, alumina, , zeolite, zirconium oxide, and ion exchange resins, , for example.
  • the medium may be a liquid or gas phase or a slurry in which the metals exist as anions.
  • the medium is drinking water.
  • the present invention provides a material for removing heavy metals from a medium that comprises a material having at least one oxygen-containing compound of a metal incorporated therein, wherein said metal is selected from the group consisting of iron, copper, aluminum, titanium, and zirconium.
  • a metal is selected from the group consisting of iron, copper, aluminum, titanium, and zirconium.
  • Some heavy metals such as arsenic and selenium normally exist in the environment as anions and, thus, are soluble in water and difficult to be removed therefrom.
  • conventional adsorption methods of water treatment using conventional solid adsorbents such as activated carbon or alumina
  • the adsorbents typically develop negative charges on their surfaces when immersed in water.
  • the present invention provides materials that overcome this shortcoming of traditional carbon adsorbents, for example, by incorporating at least an oxygen-containing compound of a metal selected from the group consisting of iron, copper, aluminum, titanium, and combinations thereof into a porous support. It is contemplated that these and similar metals having metal oxides or hydroxides which are stable in liquid phase would work in the present invention.
  • the porous supports of the present invention retain a substantial amount of their microporosity enabling them to remove heavy metal anions such as arsenic and selenium anions and perhaps organic materials from the surrounding medium such as liquid or gas. In a preferred embodiment, the medium is drinking water.
  • the adsorbent is used to remove heavy metals and organics from process water or wastewater.
  • a metal-containing material of the present invention is preferably a microporous adsorbent, which has a large surface area as measured by the Brunauer- Emmett-Teller ("BET") method and has a substantial micropore volume for pores having diameter less than about 2 nm.
  • BET Brunauer- Emmett-Teller
  • micropore volume is the total volume of pores having diameter less than 2 nm.
  • Suitable adsorbents for use in the present invention are those having a BET surface area greater than about 10 m 2 /g, preferably greater than about 100 m 2 /g, more preferably greater than about 200 m 2 /g, and most preferably greater than about 400 or 600 m /g. In general, it is contemplated that the higher surface areas will capture more metal anions and other contaminants, for example organics.
  • These adsorbents typically have a micropore volume greater than about 20 cmVlOOg.
  • the adsorbents have a micropore volume greater than about 30 cmVlOOg, more preferably greater than about 40 cm 3 /100g, and most preferably greater than about 50 cm 3 /100g.
  • Suitable carbon adsorbents for use in the present invention may be made from any of a variety of starting materials.
  • Carbonaceous materials include, but are not limited to, coals of various ranks such as anthracite, semianthracite, bituminous, subbituminous, brown coals, or lignites; nutshell; wood; vegetables such as rice hull or straw; residues or by-products from petroleum processing; and natural or synthetic polymeric materials.
  • the carbonaceous material may be processed into carbon adsorbents by any conventional thermal or chemical method known in the art before incorporating the metal therein. They will inherently impart different surface areas and pore volumes.
  • lignites can result in carbon having surface areas about 500-600 m 2 /g and, typically, fiber-based carbons areas are about 1200- 1400 m 2 /g.
  • Certain wood-based carbons may have areas in the range of about 200 m 2 /g, but tend to have a very large pore volume which is generally suitable for depositing large amounts of impregnates.
  • Surface area and pore volume of coal based carbon may also be made to allow for some control of surface area and pore volumes.
  • the carbon is an activated carbon adsorbent.
  • at least one metal may be incorporated into the carbonaceous starting material, then the mixture may be processed into carbon adsorbents containing one or more of such metals.
  • the carbon adsorbent contains metal at a concentration of up to about 50% by weight of the carbon.
  • the metal is present at a concentration in the range from about 1% to about 40% or, more preferably, from about 2% to about 30% and, more preferably, from about 3% to about 20% by weight of the carbon.
  • a microporous carbon adsorbent is impregnated with at least one salt of a metal selected from the group consisting of iron, copper, and aluminum.
  • salts include halides, nitrates, sulfates, chlorates, carboxylates having from one to five carbon atoms such as formates, acetates, oxalates, malonates, succinates, or glutarates of iron, copper, or aluminum.
  • the impregnated salts are then converted to oxygen-containing compounds of iron, copper, or aluminum by either thermal decomposition or chemical reaction.
  • Preferred forms of the oxygen-containing compounds are hydroxides and oxides.
  • adsorbents such as silica, alumina, zeolite, zirconium oxide and ion exchange resins can be impregnated with salts of iron, copper, aluminum, titanium, or zirconium and then converted to oxygen-containing compounds of the metal through decomposition or reaction.
  • adsorbents such as silica, alumina, zeolite, zirconium oxide and ion exchange resins
  • ion exchange resins can be impregnated with salts of iron, copper, aluminum, titanium, or zirconium and then converted to oxygen-containing compounds of the metal through decomposition or reaction.
  • the following examples illustrate preferred embodiments of the present invention.
  • EXAMPLE 1 Preparation of an iron-impregnated carbon adsorbent: 4.6 ml of an aqueous ferric chloride solution (having a concentration of lOOg ferric chloride in 40 ml water) was diluted with 40.3 g of deionized water.
  • This solution was poured slowly into 50.0 g of oven-dried 12x30 mesh (U.S. sieve series) coconut shell-based PCBTM activated carbon (Calgon Carbon Corporation, Pittsburgh, Pennsylvania) contained in a pyrex glass dish.
  • PCBTM activated carbon has a BET surface area of about 1050 m 2 /g and a micropore volume of about 60 cm 3 /100g.
  • the impregnated carbon was stirred thoroughly while the solution was being poured into the carbon.
  • the wet impregnated carbon was dried in an oven at 105° C for 2 hours based on the amount of ferric chloride solution used for the impregnation.
  • the dried impregnated carbon had an iron content of about 7.9 % by weight of the carbon.
  • the dried impregnated carbon was taken out of the oven and cooled down in a hood.
  • a KOH solution was prepared by dissolving 12.47 g of KOH pellets in 60.02 g deionized water.
  • the KOH solution was poured into the dried impregnated carbon. This amount of KOH was enough to completely wet the impregnated carbon without leaving an excess solution.
  • the wet KOH-treated carbon was transferred into a 2000- ml beaker and the beaker was filled with deionized water.
  • the water from the beaker was decanted and fresh deionized was added to wash potassium chloride from the impregnated carbon. This process of washing was repeated until the pH of the solution was about 7, as indicated by pH paper.
  • the wet carbon was then dried in an oven at 105° C overnight. It was expected that the iron in the carbon would be in the form of ferric hydroxide.
  • the dried ferric hydroxide-impregnated carbon was pulverized in a titanium vial containing tungsten abrading balls for testing of the removal of heavy metal anions. This impregnated carbon was identified as "3224-31- 1."
  • Testing of Arsenic Removal An aqueous arsenic solution having an arsenic concentration of about 100 parts per billion (“ppb") by weight was prepared for testing by diluting into deionized water an appropriate amount of an arsenic standard solution of arsenic trioxide in 10 % (by weight) nitric acid.
  • Polyethylene bottles having a nominal volume of 500 ml and magnetic stirring bars were cleaned with dilute nitric acid solution and dried.
  • An amount of about 500 g of the arsenic solution prepared as disclosed above was put into the bottle.
  • the bottle was then put on a multi-position stirring plate and the stirring continued for about 24 hours. At the end of the 24-hour period, a sample of the solution in the bottle was taken and filtered. The residual concentration of arsenic in the solution was analyzed by ICP/MS method.
  • activated carbons suitable for the present invention may be those made from wood chips in a chemical activation process employing phosphoric acid, or those made from phosphoric acid treatment of petroleum residue, or activated carbons made from gasification of carbonized polymeric materials, such as those derived from phenolic resins or polyesters.
  • Activated carbons suitable for the present invention may have the form of powder, granule, sphere, pellet, honeycomb, woven or nonwoven fiber, mat, or felt.
  • EXAMPLE 2 The same oven-dried PCBTM carbon was impregnated with ferric chloride to achieve a ferric ion loading of about 15.8 % by weight of the carbon using the same manufacturing method as in Example 1.
  • An arsenic solution having a targeted concentration of about 1 part per million (“ppm") was prepared from the arsenic trioxide standard solution as above. The results of this experiment are shown in Table 2. This carbon could remove a very high level of arsenic (841 ppb) to less than detection limit with only a small dose of the carbon. Table 2
  • EXAMPLE 3 Preparation of iron (II) impregnated carbon adsorbent: An iron (II) impregnated activated carbon was prepared similarly to the process disclosed in Example 1, except a ferrous chloride solution was prepared for impregnation, instead of ferric chloride. 1.778g of FeCl 2 -4H O was dissolved into 40.0 g of deionized water. The ferrous chloride solution was impregnated into 50.0 g of oven-dried 12x30 mesh PCBTM activated carbon. The dried impregnated carbon had a nominal iron (II) loading of about 1% by weight.
  • the dried impregnated carbon was reacted with a KOH solution consisting essentially of 1.27 g of KOH pellet dissolved in 70.16 g of deionized water.
  • the washed and dried impregnated carbon was pulverized as above and labeled as "3224-32-1 " for testing.
  • Testing for arsenic removal The arsenic solution and the method of testing were similar to those disclosed in Example 1. The results of the testing are shown in Table 3. Table 3
  • EXAMPLE 4 Oven-dried 12x30 PCBTM activated carbon was impregnated with aluminum chloride in the same manner as disclosed in Example 1.
  • the aluminum chloride solution was prepared by dissolving 89.48 g of AlCl 3 -6H 2 O in 80.0 g of deionized water.
  • the solution was impregnated into 100 g of oven-dried 12x30 PCBTM activated carbon.
  • the impregnated carbon has an aluminum loading of about 10% by weight of the carbon.
  • the aluminum chloride-impregnated carbon was reacted with a solution containing 63.17 g KOH in 120 g deionized water.
  • the steps of washing, drying, and pulverizing were the same as those of Example 1.
  • An arsenic solution having a targeted As concentration of about 1 ppm was prepared for testing.
  • the arsenic removal testing was the same as that disclosed in Example 1 except different amounts of impregnated carbon were used. The results are shown in Table 4. Table 4
  • EXAMPLE 5 Preparation of carbon adsorbent containing ferric oxide: 3.7325 g of Fe(NO 3 ) 3 -9H 2 O was dissolved into 37.70 g of deionized water. This solution was poured over a 50.02 g of oven dried 12x30 mesh PCBTM carbon in a glass dish. The impregnated carbon was mixed thoroughly and then dried in an oven at 105° C for 3 hours. The dried impregnated carbon was charged into a quartz tube having an inner diameter of about 2.54 cm. The carbon was retained in place by a piece of glass wool at each end. The quartz tube was inserted in a horizontal tube furnace and heated from ambient temperature to about 300 C in 30 minutes, then held at that temperature for about 20 hours.
  • the temperature was subsequently increased to 500° C in about 20 minutes and held for an additional 3 hours.
  • the heating was conducted under a flow of nitrogen at substantially ambient pressure at about 300 cm 3 /minute.
  • the tube with the carbon still inside was cooled down under nitrogen flow to ambient temperature. It was expected that ferric nitrate decomposed to ferric oxide under this treatment condition.
  • a representative sample of the ferric oxide- loaded carbon was pulverized as described in Example 1 above for testing. The results of the testing are shown in Table 5. The results show that arsenic was removed even at low doses of carbon. Table 5
  • briquette shapes and sizes also may be used.
  • the mixture also may be extruded into pellets instead of the above pressing to briquettes.
  • the compaction pressure may be appropriately chosen for the particular coal used. It may be higher or lower than the pressure disclosed above, but typically is in the range from about 8 MPa to about 16 MPa.
  • the briquettes were crushed and screened to produced particles having a mesh size of about 6x14. The produced particles were oxidized under an excess flow of air in an indirectly heated rotary kiln, the temperature of which was increased from ambient to about 250° C at a rate of 45° C per hour, and then from 250° C to about 450° C at a rate of 60° C per hour.
  • oxidizing gases such as a mixture of oxygen and air or an inert gas, which mixture has an oxygen concentration greater than about 21% by volume, or a combustion product from a combustor containing oxygen, steam, and other gases.
  • oxidizing gases such as a mixture of oxygen and air or an inert gas, which mixture has an oxygen concentration greater than about 21% by volume, or a combustion product from a combustor containing oxygen, steam, and other gases.
  • the resulting oxidized iron-containing coal particulate material was gasified in steam at 925-950 C for about 40-45 minutes to produce an iron-containing porous carbon adsorbent of the present invention.
  • activation The step of gasifying the carbon precursor, such as this coal particulate, in an oxidizing atmosphere is usually termed "activation.”
  • activation temperature and time are chosen to be appropriate for the type of coal, the compaction technique, the type of activation furnace used in the process of manufacture, and the desired microporosity of the activated product.
  • higher-rank coals and higher compaction would require a higher temperature and/or a longer time.
  • a longer activation time produces a more porous activated carbon.
  • Activation furnace types that provide a very intimate contact between the solid and the gas phase and a well-mixed solid therein usually require a shorter activation time.
  • Activation temperature is typically in the range from about 900° C to about 1100° C, and activation time is typically in the range from about 10 minutes to about 10 hours.
  • other oxygen-containing gases may also be present.
  • the steps of oxidizing the coal particles and of gasifying the oxidized coal particles were carried out in this example in a rotary kiln.
  • furnaces or kilns may also be used in which an intimate contact between the solid and the gas phase can be maintained. Suitable furnaces or kilns are fluidized-bed kilns, belt furnaces, and Herreshoff furnaces. A representative sample of this adsorbent was pulverized in titanium vials using tungsten balls as disclosed above for testing.
  • Testing for arsenic removal An arsenic solution was prepared similarly to that of Example 1, except the targeted As concentration was 1 ppm. The testing procedure was similar to that described in Example 1. The results of the testing are shown in Table 6. Table 6
  • Example 7 Testing for selenium removal
  • a solution containing selenium was prepared as follows.
  • An aqueous selenium solution having a selenium concentration of about 300 parts per billion by weight was prepared for testing by diluting into Milli-Q water an appropriate amount of a 1000 ppm selenium standard reference solution.
  • the reference solution was purchased from Fisher Scientific and is commonly used as the standard solution for atomic absorption spectroscopy.
  • the method of testing was similar to that described in Example 1. The results of the testing are shown in Table 7. Table 7
  • Example 8 Testing for selenium removal
  • the carbon of Example 5 was tested for selenium removal.
  • the solution containing selenium was prepared as described in Example 7.
  • the method of testing was similar to that described in Example 1.
  • the results of the testing are shown in Table 8. Table 8
  • Example 9 Testing for selenium removal
  • the carbon of Example 4 was tested for selenium removal.
  • a solution containing selenium was prepared to have a target selenium concentration of about 300 ppb by diluting a selenium atomic absorption standard solution containing 100 ppm selenium dioxide in water.
  • the method of testing was similar to that described in Example 1. The results of the testing are shown in Table 9.
  • Table 9 Table 9
  • the adsorbents of the present invention may be used to remove heavy metal anions from a medium adjacent thereto in many arrangements.
  • Granular particles of the adsorbents of the present invention may be disposed or installed in a fixed or fluidized bed, batch treatment system, or as part of a vessel, container, or pipe.
  • Granular adsorbents are particularly suitable to be packaged in small cartridges for installation at the point of use.
  • An adsorbent in powder form may be injected into a stirred tank and then removed by filtration or settling.
  • Adsorbents in fiber form may be inserted in a section of the water supply piping.
  • Such other types of adsorbents are, for example, zeolites, ion exchange resins, silica gel, alumina, and unimpregnated activated carbons.
  • EXAMPLE 10 A silicon oxide support was impregnated with a soluble commercially- available titanium (III) salt which was then oxidized and neutralized using sodium hydroxide solution to precipitate titanium (IV) hydroxide. The neutralized materials were then rinsed in situ with Dl water at least 20 times to remove the salts of neutralization and finally oven-dried overnight at 110°C.
  • the titanium (III) salt used for the impregnation was a commercially-available 20% solution of titanium (III) sulfate in 2% sulfuric acid (Alfa Aesar 39664).
  • the isotherms were carried out using 0.1 g, and 0.5g, dosages of the impregnated support and the unimpregnated control in 500 mL of a 300 ppb arsenic solution prepared by adding 6.0 mL (pipet) of a 1000 mg/L As(V) standard solution to 20 liters of Dl water.
  • One-inch Teflon stir bars were used to stir the solutions for at least 2 days at 500 RPM, prior to measuring the pH of each and filtering through 0.8 micron filter membranes.
  • the acidified filtrates were then analyzed for arsenic by ICP with an MDL of about 3 ppb arsenic. Table 10
  • EXAMPLE 11 lue. Upon standing with stirring for one hour, the color of the solution became completely white and opaque, indicating air oxidation of the Ti(III) to Ti(IV).
  • the zirconium (IV) salt used for the impregnation was zirconium (IV) dichloride oxide (Alfa Aesar 86108). To make the zirconium impregnating solution, 51 grams of this salt were dissolved in 50 mL of MilliQ water.
  • the titanium (III) salt used for the impregnation was a commercially- available 20% solution of titanium (III) sulfate in 2% sulfuric acid (Alfa Aesar 39664). To determine the neutralization requirements, 2 mL of this solution was added to 50 mL of MilliQ water and titrated with l.ON NaOH solution. The initial pH was 1.90 and the solution was a deep violet color. About 10.2 mL of 1.ON NaOH was required to achieve a pH of 9.0 at which point the color of the solution changed from violet to bwater and titrated with l.ON NaOH solution. The initial pH was 1.40.
  • the isotherms were carried out using 0.1 g, and 0.5g, dosages of the impregnated support and the unimpregnated control in 500 mL of a 300 ppb arsenic solution prepared by adding 6.0 mL (pipet) of a 1000 mg/L As(V) standard solution to 20 liters of Dl water.
  • One-inch Teflon stir bars were used to stir the solutions for at least 2 days at 500 RPM, prior to measuring the pH of each and filtering through 0.8 micron filter membranes.
  • the acidified filtrates were then analyzed for arsenic by ICP with an MDL of about 3 ppb arsenic. Table 11

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Abstract

L'invention concerne des adsorbants destinés à éliminer des anions de métaux lourds, et des procédés de production et d'utilisation des adsorbants. Des adsorbants d'élimination de métaux comprennent un matériau poreux dans lequel est incorporé au moins un composé oxygéné de fer, de cuivre, d'aluminium, de titane et/ou de zirconium. Le composé oxygéné peut être incorporé dans les milieux poreux par imprégnation ou dispersion d'un précurseur approprié dudit composé. Le précurseur peut être traité de nouveau en vue de produire le composé oxygéné. Les adsorbants de l'invention sont particulièrement utiles pour l'élimination d'arsenic et/ou de sélénium de l'environnement, et peuvent être utilisés dans le traitement de sources d'eau potable.
PCT/US2004/042191 2003-12-16 2004-12-16 Adsorbants destines a eliminer des metaux lourds, et procedes de production et d'utilisation des adsorbants WO2005058482A1 (fr)

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USPCT/US/39925 2003-12-16
US11/006,084 US7429551B2 (en) 2001-08-27 2004-12-07 Adsorbents for removing heavy metals
US11/005,825 US20050093189A1 (en) 2001-08-27 2004-12-07 Adsorbents for removing heavy metals and methods for producing and using the same
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