WO2005033252A1 - バイオディーゼル燃料改質剤、燃料、それらに関わる方法 - Google Patents
バイオディーゼル燃料改質剤、燃料、それらに関わる方法 Download PDFInfo
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- WO2005033252A1 WO2005033252A1 PCT/JP2004/014230 JP2004014230W WO2005033252A1 WO 2005033252 A1 WO2005033252 A1 WO 2005033252A1 JP 2004014230 W JP2004014230 W JP 2004014230W WO 2005033252 A1 WO2005033252 A1 WO 2005033252A1
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- WIPO (PCT)
- Prior art keywords
- fuel
- biodiesel fuel
- oil
- biodiesel
- modifier
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/1817—Compounds of uncertain formula; reaction products where mixtures of compounds are obtained
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/19—Esters ester radical containing compounds; ester ethers; carbonic acid esters
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
- C10L1/026—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only for compression ignition
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L10/00—Use of additives to fuels or fires for particular purposes
- C10L10/14—Use of additives to fuels or fires for particular purposes for improving low temperature properties
- C10L10/16—Pour-point depressants
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/04—Diesel oil
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/1802—Organic compounds containing oxygen natural products, e.g. waxes, extracts, fatty oils
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/1811—Organic compounds containing oxygen peroxides; ozonides
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/19—Esters ester radical containing compounds; ester ethers; carbonic acid esters
- C10L1/191—Esters ester radical containing compounds; ester ethers; carbonic acid esters of di- or polyhydroxyalcohols
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
Definitions
- Biodiesel fuel modifiers are Biodiesel fuel modifiers, fuels and related methods
- the present invention relates to a biodiesel fuel modifier to be added to biodiesel fuel (BDF), a fuel to which the modifier has been added, and a method related thereto. More specifically, a biodiesel fuel reforming agent obtained by ozonizing plant oils, especially biodiesel fuel reforming that lowers the pour point of biodiesel fuel and improves the torque and horsepower of diesel engines
- BDF biodiesel fuel
- the present invention relates to an agent, a fuel to which the modifier is added, and a method related thereto.
- Biodiesel fuel has attracted attention as a diesel engine fuel with low SOx emission from the viewpoint of air pollution prevention and the like.
- Biodiesel fuel is a liquid fuel produced from vegetable oil, and since the vegetable oil used as the raw material contains almost no sulfur, it is possible to keep SOx emissions low.
- Vegetable oil which is a raw material for biodiesel fuel, is produced from oil plants, so it can be self-sufficient and regenerated. In addition, oil plants have high carbon dioxide absorption capacity. Promoting the use of biodiesel fuel is also useful from the viewpoint of preventing global warming, and the spread of biodiesel fuel is being promoted mainly in Europe and the United States.
- the most practically used diesel fuels are those obtained by subjecting vegetable oils such as castor oil and soybean oil to a methylesteri reaction.
- This methyl esterified fuel has a drawback that its pour point is higher than that of light oil, which is a fuel for petroleum-based diesel engines.
- the pour point of commercial light oil is 15 ° C, while that of methyl esterified fuel is about 2 ° C. Therefore, methyl esterified fuel could not be used under low temperature conditions, and it was difficult to use it in cold regions.
- biodiesel fuel A mixture of 20% is called “B20”.
- Non-Patent Document 1-Non-Patent Document 4 describes the current status of Noo diesel fuel in various countries of the world.
- Non-patent document I http://www.meti.go.jp/report/downloadfiles/g30625d50e.pdf
- Non-patent document 2 NEDO Overseas Report, NO.913, August 20, 2003, Renewable energy trends in the UK — 2002, (
- Non-Patent Document 3 X. Lang, A.K.Dalai, N.N Bakhshi, M.J.Reaney and P.B.Hertz Preparation and Characterization of Bio-Diesels from Various Bio-Oils ",
- Non-Patent Document 4 S. binha and N.C.Misra, ⁇ Diesel Fuel Alternative from Egetable Oils, Chemical Engineering World, October, 1997, h
- Blended fuels such as B20 which are currently used, are only blended with petroleum-based light oil, and the pour point of biodiesel fuel is high. This does not fundamentally solve the problem. . Therefore, mixed fuels such as B20 still have a problem that the pour point is high, and there is a problem that the pour point becomes higher as the mixing ratio of biodiesel fuel is increased.
- pour point depressants such as EVA (ethylene vinyl acetate copolymer) are also used for mixed fuels such as B20.
- EVA ethylene vinyl acetate copolymer
- the agent is used for petroleum-based light oil and has an effect on biodiesel fuel. It is not something that has power. Therefore, there is a problem that the effect is limited even when used for a mixed fuel such as B20, and that the pour point depressing action is hardly observed in the 100% biodiesel fuel.
- BDF biodiesel fuel
- the present invention provides a biodiesel fuel reformer obtained by subjecting vegetable oil to ozone treatment.
- the biodiesel fuel modifier according to the present invention can be produced, for example, by subjecting vegetable oils such as castor oil, rapeseed oil, and soybean oil to ozone treatment by aeration of an ozone-oxygen mixed gas. It comes out.
- Methyl esterified fuel which is currently the most popular biodiesel fuel (BDF) is obtained by refining vegetable oils such as castor oil, rapeseed oil, and soybean oil by methyl esterification.
- the pour point of the methyl esterified fuel can be significantly reduced by adding the fuel for diesel ester modification according to the present invention to the methyl esterified fuel. Therefore, by adding the biodiesel fuel modifier according to the present invention, biodiesel fuel can be used even in an area where the temperature is low such as a cold area.
- the biodiesel fuel modifier according to the present invention has an effect of improving the torque 'horsepower of a diesel engine. That is, by adding the biodiesel fuel modifier according to the present invention to biodiesel fuel, the engine performance of the diesel engine, particularly, the torque and horsepower at low speed rotation can be improved. This will enable the use of biodiesel fuel.
- the pour point depressing action of the noodiesel fuel modifier is related to the number of unsaturated double bonds contained in the vegetable oil used as the raw material of the biodiesel fuel modifier.
- Particularly effective as a raw material for a biodiesel fuel modifier is a vegetable oil having a large number of unsaturated double bonds, such as castor oil, linseed oil, and rapeseed oil.
- a biodiesel fuel modifier produced by ozone treatment of sunflower oil (“ozone-treated sunflower oil”) reduces the pour point of methylesterified fuel produced from sunflower oil and rapeseed oil. It can be lowered to about 30 ° C. This is lower than the pour point (-15 ° C) of petroleum gas oil.
- the degree of formation of ozone at the unsaturated double bond of triglyceride contained in the biodiesel fuel modifier is important in the mechanism of action. It is considered to have played a role. That is, the unsaturated double bond of triglyceride contained in the biodiesel fuel modifier according to the present invention acts on the unsaturated fatty acid contained in the ozo-docamethyl esterified fuel, thereby causing the unsaturated ester of the methyl esterified fuel to act. It is thought that the crystallization and adhesion of the fatty acid are prevented and the pour point is lowered.
- the present invention also provides a biodiesel fuel modifier in which the unsaturated double bond site of triglyceride forms an ozone. Since the pour point depressing action of the biodiesel fuel is considered to occur based on the above-mentioned mechanism of action, it is also possible to apply ozone treatment to artificially synthesized triglycerides having a large number of unsaturated double bond sites. Thus, a biodiesel fuel modifier that lowers the pour point of biodiesel fuel can be manufactured.
- ozone-treated rapeseed oil The biodiesel fuel modifier obtained by ozonation of rapeseed oil (ozone-treated rapeseed oil”) also had a sufficient pour point lowering effect on many methyl esterified fuels. This is considered to be because ozone-treated castor oil and ozone-treated rapeseed oil have a large number of ozone in a structure having a large number of unsaturated double bonds.
- the present invention provides a biodiesel fuel to which the biodiesel fuel modifier according to the present invention has been added.
- the pour point of biodiesel fuel is reduced by adding the biodiesel fuel-modifying agent of the present invention to biodiesel fuel from the pour point of common petroleum-based light oil (-15 ° C). Therefore, it is possible to use 100% biodiesel fuel without mixing with petroleum gas oil.
- biodiesel fuel modifier according to the present invention also lowers the flash point of the biodiesel fuel, not just the pour point (see Example 1, Table 2).
- the other issue of using fuel "biodiesel fuel has too high flash point,” can be solved.
- the biodiesel fuel modifier according to the present invention is also effective for a mixed fuel of petroleum-based light oil such as B20 and biodiesel fuel, which can be produced using only 100% biodiesel fuel.
- the present invention provides a diesel engine fuel containing at least petroleum gas oil or Z and a biodiesel fuel and the biodiesel fuel modifier according to the present invention as a composition.
- the conventional biodiesel fuel modifier acts on petroleum-based light oil, and exerts almost no effect on biodiesel fuel. Therefore, a stable pour point lowering effect can be achieved by adding the biodiesel fuel modifier according to the present invention to the mixed fuel alone or simultaneously with the pour point depressant for petroleum gas oil. be able to.
- biodiesel fuel modifier according to the present invention be added in an amount of 1% by weight or more based on the biodiesel fuel.
- biodiesel fuel modifier according to the present invention By adding the biodiesel fuel modifier according to the present invention to biodiesel fuel, the pour point of the biodiesel fuel can be lowered.
- biodiesel fuel modifier according to the present invention By adding the biodiesel fuel modifier according to the present invention to biodiesel fuel, it is possible to lower the bow I ignition point of the nodiesel fuel.
- the biodiesel fuel modifier according to the present invention itself contains almost no sulfur and is self-sufficient and renewable, so that it does not give an environmental load such as air pollution or global warming. .
- Biodiesel fuel is also a fuel with a low environmental load. Therefore, by adding the biodiesel fuel according to the present invention to the biodiesel fuel, it is possible to provide a diesel engine fuel that can be used in a wide area such as a cold region where the environmental load is small. it can.
- Example 1 is an experiment for examining the pour point drop when ozone-treated sunflower oil was added to a methyl esterified fuel derived from various vegetable oils. The procedure is as follows.
- Methyl esterified fuel was prepared by methyl esterifying vegetable oils such as sunflower oil, rapeseed oil, soybean oil, and palm oil. This methyl esterification reaction is performed by adding 300 g of each vegetable oil to CH OH6
- a methyl esterified fuel of origin was prepared.
- ozone-treated castor oil was prepared as a biodiesel fuel modifier.
- ozone-treated sunflower oil add 50 ml of sunflower oil to a small bubble column, and inject a mixture of ozone and oxygen with an ozone concentration of 40 g—O Zm 3 at a volume velocity of 0.5 LZmin for a predetermined time.
- the ozone-treated sunflower oil was prepared by measuring the ozone concentration at the entrance and exit of the bubble column with an ozone concentration meter during the passage of the ozone-oxygen mixed gas to obtain 0.183 and 0.206 g-O / ml. Two types of ozone concentration of oil were prepared.
- each of the vegetable oil-derived methyl esterified fuels was heated to 40 ° C, and 0.183 or 0.206 g-O Zml-oil ozone-treated sunflower oil was added to the fuel. Weight% and 1.5 weight
- the ozone-treated sunflower oil showed that other plants that only effectively lowered the pour point of the methyl esterified fuel produced from the sunflower oil could not be reduced. It was also found that methyl esterified fuel produced from oil has a pour point depressing effect.
- the ozone-treated sunflower oil according to the present invention has an effect of remarkably lowering the pour point of a methyl esterified fuel produced from rapeseed oil, and is extremely effective as an additive to a methyl esterified fuel derived from rapeseed oil. It indicates that there is. A certain pour point depressing effect was also observed for methyl esterified fuel produced from soybean oil.
- the biodiesel fuel modifier according to the present invention is a methyl ester derived from soybean oil. It is also shown to be effective for petrochemicals.
- ozone-treated sunflower oil showed no effect on methyl esterified fuel produced from palm oil. This is presumably because palm oil has a significantly higher content of saturated fatty acid esters than other vegetable oils.
- Example 2 the biodiesel fuel modifier of the present invention produced by ozone treatment of vegetable oils such as sunflower oil, rapeseed oil, soybean oil, and palm oil was used as the sunflower oil, rapeseed oil, soybean oil, and palm oil. This is an experiment to show whether there is an effect to lower the pour point of methyl esterified fuel produced from each vegetable oil.
- Methylesteri-dani fuel produced from the vegetable oils of castor oil, rapeseed oil, soybean oil, and palm oil was produced in the same manner as in Example 1.
- the no-diesel fuel modifier according to the present invention produced by ozone treatment was prepared using the same vegetable oil as castor oil, rapeseed oil, soybean oil, and palm oil in the same manner as the ozone-treated sunflower oil of Example 1. It was made using V.
- the amount of ozone absorbed by each ozone-treated vegetable oil was 0.168 g—O / mi-oil, ozone-treated soybean oil 0.179 g—O Zml—oil, ozone-treated rapeseed oil, respectively.
- Oil was 0.063g-O Zml-oil. This value correlates with the amount of unsaturated double bonds
- the ozone-treated sunflower oil was 0.206 g-O used in Example 1.
- the biodiesel fuel modifiers obtained by ozone treatment of sunflower oil, rapeseed oil, and soybean oil were methyl esterified fuels produced from sunflower oil, rapeseed oil, and soybean oil, respectively.
- the pour point is effectively lowered, indicating that it is very effective as a pour point depressant.
- ozone-treated sunflower oil reduces the pour point of methylesterified fuel produced from sunflower oil and rapeseed oil to around 130 ° C, and also reduces the methylesterified fuel produced from soybean oil. Since it has the same effect as other ozonized vegetable oils, it is effective as a pour point depressant for all methyl esterified fuels.
- ozone-treated palm oil also had a certain effect on methyl esterified fuel produced from castor oil, rapeseed oil, and soybean oil.
- the methyl esterified fuel produced from palm oil showed no pour point depressing effect due to the ozone-treated vegetable oil.
- Example 3 is an experiment showing that the biodiesel fuel modifier according to the present invention has an effect of improving the torque and horsepower of a diesel engine.
- the experimental procedure is as follows. [0051] First, a chassis dynamotor tester (trade name "Dynamaster 6000S", manufactured by Sakura Dino System Co., Ltd .; same hereafter), a diesel car (3.5L displacement, trade name "Land Cruiser I PZJ70", Toyota Land Cruiser manufactured by Automobile Co., Ltd. is a registered trademark, the same applies hereinafter).
- the chassis dynamometer is a horsepower 'torque automatic measuring device.
- biodiesel fuel produced by oneself was produced by using the sunflower oil as a raw material and performing a methyl esterification treatment in the same manner as in Example 1.
- the Noo diesel fuel reforming agent was also produced by ozone treatment using castor oil as a raw material in the same manner as in Example 1.
- diesel torque indicates the measured torque of petroleum gas oil
- BDF torque indicates the measured torque of biodiesel fuel
- BDF + Add torque indicates the biodiesel fuel.
- the measured torque values of the fuel added with the diesel fuel modifier are shown below.
- hp indicates French horsepower (ps).
- biodiesel fuel modifier according to the present invention has a function of lowering the pour point of biodiesel fuel when added to biodiesel fuel. Therefore, biodiesel fuel can be used even in an area where the temperature falls below ⁇ 2 ° C. (the pour point of the methyl esterified fuel derived from soybean oil when the fuel for diesel fuel of the present invention is not added). It has industrial applicability in that it can be used.
- biodiesel fuel will be further used in the future. Therefore, the present invention is useful for further widespread use of biodiesel fuel, and has industrial applicability.
- the present invention opens up the possibility of using 100% biodiesel fuel for diesel engines for cars, trains, and the like, and has industrial applicability.
- mixed fuel such as B20, which is becoming widespread, has a pour point lowering effect, and thus can be used industrially.
- biodiesel fuel modifier according to the present invention improves the engine performance of a diesel engine, in particular, the torque and horsepower during low-speed rotation, so that the biodiesel fuel can be applied to heavy trucks and the like. It is possible.
- FIG. 1 is a graph showing measured torque values.
- FIG. 2 is a graph showing horsepower measurement values.
Abstract
Description
Claims
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/570,883 US20070039238A1 (en) | 2003-10-02 | 2004-09-20 | Biodiesel fuel modifying agent, fuel and method related thereto |
EP04788296A EP1681338A4 (en) | 2003-10-02 | 2004-09-29 | MODIFIER FOR BIODIESEL FUEL, FUEL AND ASSOCIATED METHODS |
JP2005514437A JP4094637B2 (ja) | 2003-10-02 | 2004-09-29 | バイオディーゼル燃料改質剤、燃料、それらに関わる方法 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2003344051 | 2003-10-02 | ||
JP2003-344051 | 2003-10-02 |
Publications (1)
Publication Number | Publication Date |
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WO2005033252A1 true WO2005033252A1 (ja) | 2005-04-14 |
Family
ID=34419366
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2004/014230 WO2005033252A1 (ja) | 2003-10-02 | 2004-09-29 | バイオディーゼル燃料改質剤、燃料、それらに関わる方法 |
Country Status (5)
Country | Link |
---|---|
US (1) | US20070039238A1 (ja) |
EP (1) | EP1681338A4 (ja) |
JP (1) | JP4094637B2 (ja) |
KR (1) | KR20080017226A (ja) |
WO (1) | WO2005033252A1 (ja) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2008132917A1 (ja) * | 2007-04-23 | 2008-11-06 | Sun Care Fuels Corporation | ディーゼルエンジン用混合燃料及びその流動点降下方法 |
JP2010053270A (ja) * | 2008-08-29 | 2010-03-11 | Nihon Univ | バイオディーゼル燃料及びその製造方法 |
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WO2011036611A1 (en) * | 2009-09-23 | 2011-03-31 | African Explosives Limited | Explosive |
US8301359B1 (en) | 2010-03-19 | 2012-10-30 | HyCogen Power, LLC | Microprocessor controlled automated mixing system, cogeneration system and adaptive/predictive control for use therewith |
US8846587B2 (en) | 2011-03-24 | 2014-09-30 | Elevance Renewable Sciences, Inc. | Functionalized monomers and polymers |
US9315748B2 (en) | 2011-04-07 | 2016-04-19 | Elevance Renewable Sciences, Inc. | Cold flow additives |
US9012385B2 (en) | 2012-02-29 | 2015-04-21 | Elevance Renewable Sciences, Inc. | Terpene derived compounds |
US20140274832A1 (en) | 2013-03-12 | 2014-09-18 | Elevance Renewable Sciences, Inc. | Maleinized ester derivatives |
US20150057204A1 (en) | 2013-03-12 | 2015-02-26 | Elevance Renewable Sciences, Inc. | Maleanized Ester Derivatives |
EP2981597A1 (en) | 2013-04-03 | 2016-02-10 | GFO Oil LLC | Methods and systems for generating aldehydes from organic seed oils |
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GB277326A (en) * | 1927-09-06 | 1929-01-07 | Avenarius Geb | A method for preventing the knocking of motor fuel |
GB321633A (en) * | 1928-05-10 | 1929-11-11 | James Mckee | Improvements in or relating to the ozonization of oils |
DE3606735C2 (de) * | 1986-03-01 | 1994-11-10 | Haensler J Gmbh | Verfahren zur Herstellung von stabilen ozonisierten Ölen aus ungesättigten Pflanzenölen |
US6051538A (en) * | 1999-01-26 | 2000-04-18 | The Procter & Gamble Company | Pour point depression of heavy cut methyl esters via alkyl methacrylate copolymer |
JP2000219886A (ja) * | 1999-02-01 | 2000-08-08 | Masatoshi Matsumura | 植物油(バージン油)又は植物性廃油のディーゼルエンジン用燃料化精製方法及び装置 |
US7201837B2 (en) * | 2002-03-19 | 2007-04-10 | Bunge North America, Inc. | Energy source using hydrogenated vegetable oil diluted into diesel fuel |
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2004
- 2004-09-20 US US10/570,883 patent/US20070039238A1/en not_active Abandoned
- 2004-09-29 KR KR1020067005819A patent/KR20080017226A/ko not_active Application Discontinuation
- 2004-09-29 WO PCT/JP2004/014230 patent/WO2005033252A1/ja active Application Filing
- 2004-09-29 EP EP04788296A patent/EP1681338A4/en not_active Ceased
- 2004-09-29 JP JP2005514437A patent/JP4094637B2/ja not_active Expired - Fee Related
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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WO2008132917A1 (ja) * | 2007-04-23 | 2008-11-06 | Sun Care Fuels Corporation | ディーゼルエンジン用混合燃料及びその流動点降下方法 |
JP2010053270A (ja) * | 2008-08-29 | 2010-03-11 | Nihon Univ | バイオディーゼル燃料及びその製造方法 |
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JP4094637B2 (ja) | 2008-06-04 |
KR20080017226A (ko) | 2008-02-26 |
EP1681338A1 (en) | 2006-07-19 |
US20070039238A1 (en) | 2007-02-22 |
EP1681338A4 (en) | 2008-11-19 |
JPWO2005033252A1 (ja) | 2008-04-03 |
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