Classifications

• • G—PHYSICS
  • G02—OPTICS
  • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
  • G02B5/00—Optical elements other than lenses
  • G02B5/30—Polarising elements
  • G02B5/3025—Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state
  • G02B5/3033—Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state in the form of a thin sheet or foil, e.g. Polaroid
  • G02B5/3041—Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state in the form of a thin sheet or foil, e.g. Polaroid comprising multiple thin layers, e.g. multilayer stacks
  • G02B5/305—Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state in the form of a thin sheet or foil, e.g. Polaroid comprising multiple thin layers, e.g. multilayer stacks including organic materials, e.g. polymeric layers
• • G—PHYSICS
  • G02—OPTICS
  • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
  • G02B5/00—Optical elements other than lenses
  • G02B5/30—Polarising elements
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
  • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
  • B29C55/00—Shaping by stretching, e.g. drawing through a die; Apparatus therefor
  • B29C55/02—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets
  • B29C55/023—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets using multilayered plates or sheets
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
  • B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
  • B29D11/00—Producing optical elements, e.g. lenses or prisms
  • B29D11/0073—Optical laminates
• • G—PHYSICS
  • G02—OPTICS
  • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
  • G02B5/00—Optical elements other than lenses
  • G02B5/30—Polarising elements
  • G02B5/3025—Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state
  • G02B5/3033—Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state in the form of a thin sheet or foil, e.g. Polaroid
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
  • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
  • B29K2001/00—Use of cellulose, modified cellulose or cellulose derivatives, e.g. viscose, as moulding material
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
  • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
  • B29K2029/00—Use of polyvinylalcohols, polyvinylethers, polyvinylaldehydes, polyvinylketones or polyvinylketals or derivatives thereof as moulding material
  • B29K2029/04—PVOH, i.e. polyvinyl alcohol
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
  • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
  • B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
  • B29K2995/0018—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds having particular optical properties, e.g. fluorescent or phosphorescent
  • B29K2995/0034—Polarising
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
  • C09K2323/00—Functional layers of liquid crystal optical display excluding electroactive liquid crystal layer characterised by chemical composition
  • C09K2323/03—Viewing layer characterised by chemical composition
  • C09K2323/031—Polarizer or dye
• • G—PHYSICS
  • G02—OPTICS
  • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
  • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
  • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
  • G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
  • G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
  • G02F1/1333—Constructional arrangements; Manufacturing methods
  • G02F1/1335—Structural association of cells with optical devices, e.g. polarisers or reflectors
  • G02F1/133528—Polarisers
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
  • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10S359/00—Optical: systems and elements
  • Y10S359/90—Methods

Definitions

• the present invention relates to a liquid crystal display (LCD), an electroluminescence display (ELD), a plasma display panel (PDP), and an image of a field emission display (FED: Fie 1 d Emissio n D islay).
• the present invention relates to a method for producing a display device, particularly a polarizing film used for a liquid crystal display device, and further relates to a polarizing film obtained by this production method.
• the present invention also relates to an optical film in which an optical layer is laminated on the polarizing film, a polarizing plate, and an image display device having the polarizing film or the optical film. Background technology>
• a polarizing film used for an image display device (especially a liquid crystal display device) is required to have both a high transmittance and a high degree of polarization in order to provide an image which is bright and has good color reproducibility.
• a polarizing film is obtained by dyeing a film such as a polyvinyl alcohol (PVA) -based film with a dichroic substance such as dichroic iodine or a dichroic dye, and applying a method such as uniaxial stretching. It is manufactured by orienting.
• PVA polyvinyl alcohol
• An object of the present invention is to provide a method for manufacturing a polarizing film, which is manufactured through at least one treatment bath, and to provide a simple method for manufacturing a polarizing film without deteriorating optical characteristics such as transmittance and degree of polarization. I do. It is an object of the present invention to provide a polarizing film obtained by this manufacturing method, and further provide an optical film obtained by laminating an optical layer on the polarizing film and an image display device using the polarizing film or the optical film. Invention disclosure>
• the present inventors have conducted intensive studies in order to study the above problems, and have found that the above object can be achieved by the method for manufacturing a polarizing plate described below, and have completed the present invention. That is, the object of the present invention has been achieved by the following polarizing film manufacturing method, polarizing film, optical film, liquid crystal panel, image display device, and polarizing film manufacturing apparatus.
• An optical film comprising the polarizing film according to item 4, and an optical layer provided on at least one surface of the polarizing film.
• a liquid crystal panel comprising the polarizing film according to item 4.
• An image display device comprising the polarizing film according to item 4.
• a polarizing film manufacturing apparatus comprising a processing bath provided with a film transport holder for immersing a plurality of films simultaneously in at least one processing solution without contacting the films.
• FIG. 1 shows an example of a polarizing film manufacturing process according to the present invention.
• FIG. 2 shows an example of a conventional polarizing film manufacturing process.
• FIG. 3 is a cross-sectional view of the processing bath when the transport films are arranged in two rows horizontally using two film transport holders when viewed from the front in the transport direction.
• FIG. 4 is a cross-sectional view of the processing bath when viewed from the front in the transport direction when two transport films are arranged side by side using one film transport holder.
• FIG. 5 is a cross-sectional view of the processing bath as viewed from the front in the transport direction when the transport films are vertically arranged in three stages.
• FIG. 6 is a cross-sectional view of the processing bath when the transport film is arranged vertically and horizontally in two rows and two rows when viewed from the front in the transport direction.
• FIG. 7 shows three rows of transport films arranged side by side using three film transport holders.
• FIG. 4 is a sectional view of the processing bath when viewed from the front in the transport direction in the case.
• 1 is a processing bath
• 2 is a holder (roll) for film conveyance
• 3 is a processing liquid
• 4 is a raw film
• 5 is a conveyance film
• 6 is a polarizing film
• 11 is a swelling process.
• 12 is a dyeing process (bath)
• 13 is a crosslinking process
• 14 is a stretching process (bath)
• 15 is a rinsing process (bath)
• 16 is a drying process Step (bath).
• the present invention relates to a process for producing a polarizing film produced through a dyeing process in which a film is immersed in a processing solution containing a dichroic substance and a stretching process in which the film is uniaxially stretched and oriented. It has been found that by simultaneously processing a plurality of films, it is possible to easily increase the production of polarizing films without deteriorating the optical characteristics.
• polarizing film a film obtained by dyeing a raw film made of a polymer film such as a polyvinyl alcohol (PVA) film or the like with a dichroic substance such as iodine dichroic dye and uniaxially stretching is generally used. is there.
• a polarizing plate is obtained by laminating a transparent protective layer as an optical layer on one or both sides of this polarizing film.
• the polymer film used as the raw film is not particularly limited, and various types can be used.
• PVA-based finolem including modified PVA films such as partially formalized PVA-based films and acetoacetyl-modified PVA-based films
• PET polyethylene terephthalate
• ethylene-vinyl acetate copolymer-based films and the like.
• hydrophilic polymer films such as saponified finolem and cellulosic finolem
• oriented polyene films such as dehydrated PVA and dehydrochlorinated polyvinyl chloride.
• it is preferable to use a PVA-based film because of its excellent dyeability with a dichroic substance such as iodine.
• the polymerization degree of the polymer that is the material of the polymer film is generally 500 to 100,000, preferably 100 to 6,000, and 1,400 to 100,000. More preferably, it is in the range of 4,000. Furthermore, in the case of saponified film, Its saponification degree is preferably 75 mol 0/0 or more, more preferably 9 8 mol% or more, and more preferably in the range of 98.3 to 99.8 mol 0/0.
• the PVA-based film may be produced by any method such as a casting method, a casting method, or an extrusion method in which a stock solution dissolved in water or an organic solvent is cast. Can be used as appropriate.
• a film having a retardation value of 5 nm to 100 nm is preferably used.
• the in-plane retardation variation in the PVA-based film surface be as small as possible. It is preferably 10 nm or less at 000 nm, more preferably 5 nm or less.
• the single transmittance when measured with the polarizing film alone or the polarizing plate alone is 40% or more, and 43% or more. More preferably, it is particularly preferably in the range of 43.3 to 45.0%.
• two polarizing films or polarizing plates are prepared, and the orthogonal transmittance, which is measured by overlapping two polarizing films so that the absorption axes of the two polarizing films are at 90 ° to each other, is preferably smaller. It is preferably from 0.00% to 0.050%, and more preferably from 0.000 ° / 0 to 0.030%. Further, the degree of polarization is practically preferably not less than 99.9% and not more than 100%, particularly preferably not less than 99.93% and not more than 100%.
• the production of the polarizing film requires a dyeing process of dyeing a raw film such as a PVA-based film with a dichroic material, and a stretching process for controlling the orientation state of the dichroic material.
• these orders are not particularly limited.
• a method of impregnating the original film with a dichroic material and then stretching and orienting the film is preferable because a polarizing film having desired optical characteristics can be stably obtained.
• the stretching at this time is preferably uniaxial stretching, but is not limited to this. If the dichroic material can be brought into a desired orientation state, the biaxial stretching and the stretching direction were appropriately controlled. Stretching methods such as sequential stretching a plurality of times are also preferably used.
• the stretching method of the polarizing film is generally classified into a dry stretching method and a wet stretching method. If the manufacturing method has a treatment bath, the stretching method is not particularly limited to these stretching methods. The invention is applicable. Since the present invention is characterized by being manufactured by immersion in the same treatment liquid, it is preferable to use a wet stretching method in which stretching is performed in a treatment bath. In particular, when immersing a plurality of films in the same processing solution, the films need not be in contact with each other. When the films are in contact with each other, defects such as displacement and damage due to swelling and elongation of the films, sticking of the films, and uneven dyeing occur.
• an appropriate method can be used according to the conditions.
• the polymer film as a raw film is subjected to a swelling treatment step and a dyeing treatment step.
• a general method is a series of manufacturing steps as shown in FIG. 2, including a crosslinking step, a stretching step, a washing step, and a drying step.
• each processing is performed while the film is immersed in a processing liquid composed of various solutions.
• the order, number of times, and whether or not swelling, dyeing, crosslinking, stretching, washing, and drying are performed in each processing step are not particularly limited.Several processings are performed simultaneously in one processing step.
• the stretching treatment may be performed after the dyeing treatment, may be performed simultaneously with the swelling / dyeing treatment, or may be performed after the stretching treatment.
• an appropriate method can be used without limitation.
• a method of performing stretching by a peripheral speed difference between the knurls is preferably used.
• an additive such as boric acid, borax, or potassium iodide may be appropriately added to each treatment solution.
• the polarizing film according to the present invention may contain zinc borate / zinc sulfate, zinc chloride, It may contain potassium iodide and the like.
• stretching may be performed in the flow direction or the width direction as appropriate, and a water-washing process may be performed for each process.
• a polarizing film is produced by simultaneously processing a plurality of films in at least one of the processing steps (each processing bath) for manufacturing the polarizing film.
• the treatment (immersion) method of the film at this time is as follows.
• the form, the number, and the number of treatment baths to which a plurality of immersions are applied are not limited, and can be appropriately designed as needed.
• a plurality of films may be processed at the same time, if necessary, or may be processed separately under different conditions.
• a plurality of films can be horizontally (FIG. 3) or vertically (FIG. 5) using the film transport holders for the number of processed sheets.
• An arrangement in which the films are arranged and a combination thereof (FIG. 6), and an arrangement in which a plurality of films are processed with a film carrying holder smaller than the number of processed films (FIG. 4) can be used.
• the number of films to be processed is not particularly limited as long as it is two or more, but is preferably about 2 to 4 in view of simplicity of the manufacturing apparatus and stability of the processing bath. preferable.
• the film is placed horizontally with respect to the bottom of the processing bath.However, by adjusting the tension of the processing bath and the film transport, the film can be placed vertically or inclined to the bottom of the processing bath. The film may be transported.
• the form of the treatment bath may be different for each treatment step. Also, by simultaneously processing a plurality of films without contacting the films as in the present invention, as shown in FIG. 1, a method of processing films that have gone through different steps in the same bath, or conversely, It is also possible to design a manufacturing method that branches from the above step to a plurality of steps. Furthermore, in the production of a polarizing film in which it is important to design optical characteristics by adjusting the conditions of each processing step, the dyeing time of each film to be processed simultaneously can be changed by appropriately changing the design of the processing step by the method of the present invention. Since various conditions such as drawing ratio and stretching ratio can be changed, multi-product simultaneous production becomes possible in the same space as before.
• each processing step except for the drying processing step is performed in a processing bath filled with an appropriate solution (processing solution).
• processing solution an appropriate solution
• a plurality of substrates are processed in this processing bath. It is done at the same time.
• the processing bath must have a bathtub for storing various solutions and a holder for transporting the film. is there.
• the bath of the treatment bath can be used without any particular limitation as long as it is not damaged by the solution required for each treatment and is robust.
• Examples of the material include anoremi and stainless steel. Metals and ceramics are preferably used.
• the capacity can be appropriately determined according to the necessity, but generally about 1 to 20 Om 3 is used.
• a roll-shaped holder is preferably used as the holder for transporting the film used in the treatment bath.
• the holder is not limited to this, and may be a belt conveyor, a plate, a pinch, or a clip. And the like are appropriately used.
• tension during film transport can be adjusted, or the film can be stretched in the film flow direction.
• a rubber-based or metal-based material is preferably used as the material of the roll surface.
• the shape of the surface includes a concave shape, a convex shape, and a wavy shape.
• a roll in which the roll itself is curved is appropriately used.
• the roll is convexly curved at the center, a stretching effect in the direction perpendicular to the film flow direction (film width direction) can be expected. Further, a roll obtained by subjecting the surface of the roll to processing such as grooves and embossing is preferably used as necessary.
• At least one film transfer holder is provided in the processing bath.
• a plurality of film transport holders may be provided so as to be sandwiched from both sides of the film, or a pinch-clip type film transport holder may be used. You may provide in the form which hold
• several types of film transport holders may be used in the same manufacturing process. The number and type of such film transport holders can be determined as appropriate according to the intended use.
• a roll as shown in FIG. Preferably, a method of holding a plurality of films in a hole or a method of holding one film per roll as shown in FIG. 3, FIG. 5, FIG. 6, or FIG.
• the swelling treatment step for example, immersion in a swelling bath filled with water.
• the polymer film is washed with water, so that dirt on the polymer film surface and an anti-blocking agent can be washed, and the effect of preventing unevenness such as uneven dyeing by swelling the polymer film can be expected.
• This water is preferably distilled water (pure water), but may be an aqueous solution to which glycerin / potassium iodide is appropriately added.
• the temperature of the swelling liquid is preferably in the range of 20 to 45 ° C, more preferably 25 to 40 ° C.
• the immersion time in the swelling liquid is preferably from 2 to 300 seconds, more preferably from 30 to 240 seconds, and particularly preferably from 60 to 180 seconds.
• the polymer film may be stretched in the swelling liquid, and the stretching ratio at that time is about 1.1 to 3.5 times the original length of the polymer film before the treatment.
• the polymer film is immersed in a dye solution containing a dichroic material such as iodine, so that the dichroic material is adsorbed on the polymer film and dyed.
• a dichroic material such as iodine
• dichroic substance a conventionally known substance can be used.
• examples include iodine and organic dyes.
• Organic dyes include, for example, Red BR, Red LR, Red R, Pink LB, Nolevin BL, Ponoredo GS, Sky Blue LG, Lemon Yellow, Punolay BR, Punolay 2R, Navy RY, Green LG, Violet LB, Violet B, Black H, Black] 3, Black GSP, Yellow 3G, Yellow R, Orange LR, Orange 3R, Scarlet GL, Scarlet KGL, Congo Red, Brilliant Violet BK, Supra Blue G, Supra Blue GL, Supra Orange GL, Direct Power Ivenore, Direct First Orange S, First Black, etc. can be used.
• iodine is preferably used from the viewpoint of dyeability and orientation.
• dichroic substances may be used, or two or more types may be used in combination.
• the organic dye it is preferable to combine two or more types from the viewpoint of, for example, neutralizing the visible light region.
• Red and Supra Blue G As a specific example, Red and Supra Blue G, Supra Orange GL and Direct Sky Blue, or Direct 1, Sky Blue and First Black.
• a solution in which the dichroic substance is dissolved in a solvent can be used.
• the solvent water is generally used, but an organic solvent compatible with water may be further added.
• the concentration of the dichroic substance in the solution is preferably in the range of 0.010 to 2.0% by weight based on the total amount of the staining solution, and is preferably in the range of 0.002 to 1.5% by weight. Is more preferably in the range of 0.025 to 1.0% by weight.
• the concentration of the dichroic substance is less than 0.01% by weight, it takes a lot of time to dye, and the productivity is remarkably reduced. If the content exceeds 2.0% by weight, it is difficult to control the dyeing because a desired dyeing amount can be obtained in a very short time, and unevenness is likely to occur due to a slight malfunction of the apparatus, which is not preferable.
• iodine When iodine is used as the dichroic substance, it is preferable to further add an iodide, since the dyeing efficiency can be further improved.
• the iodide include potassium iodide, lithium iodide, sodium iodide, zinc iodide, aluminum iodide, lead iodide, copper iodide, barium iodide, calcium iodide, and iodide. Tin and titanium iodide.
• the ratio (weight ratio) of iodine and potassium iodide is preferably in the range of 1: 5-1: 100, and 1: 6 to: L : 80, more preferably in the range of 1: 7 to 1:70.
• the immersion time of the polymer film in the dyeing solution is preferably from 10 to 600 seconds, and more preferably from 30 to 300 seconds. At this time, if the immersion time is less than 10 seconds, it is difficult to dye to a desired dyeing amount. If the immersion time exceeds 600 seconds, a large production apparatus is required and productivity is increased. It is not preferable because it becomes worse.
• the temperature of the dyeing bath is preferably in the range of 5 to 42 ° C, more preferably 10 to 35 ° C.
• the polymer film may be stretched in this dyeing bath, and the stretching magnification accumulated from the previous step in this stretching is about 1.1 to 4.0 times the original length of the polymer film before the treatment. is there.
• the cross-linking treatment step for example, the polymer film that has undergone the dyeing treatment step is immersed in a treatment liquid containing a cross-linking agent to cross-link.
• Conventionally known substances can be used as the cross-linking agent.
• boron compounds such as boric acid and borax, glyoxal, darthal aldehyde and the like can be mentioned.
• boric acid and borax are used alone or in combination of two or more.
• a combination of boric acid and borax is preferable.
• the addition ratio (molar ratio) of boric acid to borax is preferably in the range of 4: 6 to 9: 1, and more preferably in the range of 5.5: 4.5 to 7: 3. , 6: 4 is most preferred.
• crosslinking solution a solution in which the crosslinking agent is dissolved in a solvent can be used.
• solvent for example, water can be used, and further, an organic solvent compatible with water may be included.
• concentration of the crosslinking agent in the solution is not limited to this, but is preferably in the range of 1 to 10% by weight, preferably 2 to 6% by weight, based on the total amount of the crosslinking solution. More preferred. .
• An iodide may be added to the cross-linking solution from the viewpoint that uniform properties within the plane of the polarizing film can be obtained.
• the iodide include potassium iodide, lithium iodide, sodium iodide, zinc iodide, anolemminium iodide, lead iodide, copper iodide, barium iodide, calcium iodide, tin iodide, and tin iodide.
• the content thereof is 0.05 to 15% by weight / 0 , more preferably 0.5 to 8% by weight, based on the total amount of the crosslinking solution.
• boric acid and potassium iodide are preferred, and the ratio (weight ratio) of boric acid to potassium iodide is preferably in the range of 1: 0.1 to 1: 3.5. : 0.5 to 1: More preferably in the range of 2.5.
• the temperature of the crosslinking solution is usually in the range of 20 to 70 ° C.
• the immersion time of the polymer film is usually in the range of 1 second to 15 minutes, preferably 5 seconds to 10 minutes.
• a method of applying or spraying a solution containing a crosslinking agent may be used, and the polymer film may be stretched in the crosslinking bath.
• the stretching ratio accumulated from the previous step in the stretching is about 1.1 to 4.0 times the original length of the polymer film before the treatment.
• the stretching treatment step for example, in the wet stretching method, the film is stretched to about 2 to 7 times as a cumulative stretching ratio from the previous step while immersed in a bath.
• the solution (stretching solution) of the stretching bath is not particularly limited, but for example, a solution to which various metal salts or compounds of iodine, boron or zinc are added can be used.
• a solvent for this solution water, ethanol or various organic solvents are appropriately used.
• boric acid and / or potassium iodide are added in an amount of about 2 to 18% by weight / 0 with respect to the total amount of the stretching solution.
• the content ratio (weight ratio) is preferably about 1: 0.1 to 1: 4, and about 1: 0.5 to 1: 3. It is more preferable to use them in proportion.
• the temperature of the stretching liquid is, for example, preferably in the range of 40 to 75 ° C, more preferably 50 to 62 ° C.
• aqueous solution water washing solution
• An iodide may be added to the aqueous solution.
• sodium iodide potassium iodide is preferably used as the iodide.
• concentration is usually 0.1 to 10% by weight / 0 with respect to the total amount of the washing solution, and preferably 3 to 8% by weight.
• the temperature of the washing bath is preferably from 10 to 60 ° C, more preferably from 15 to 40 ° C.
• the number of times of the water washing treatment is not particularly limited, and may be performed plural times, and the type and concentration of the additive in each water washing bath may be changed.
• a roll of liquid such as a pinch roll may be used to prevent dripping, or a method such as scraping off the liquid with an air knife may be used. However, you may remove excess water.
• the drying treatment step an appropriate method such as natural drying, air drying, and heat drying can be used, but usually, heat drying is preferably used.
• the heating temperature is preferably about 20 to 80 ° C.
• the drying time is preferably about 1 to 20 minutes.
• the final stretch ratio (total stretch ratio) of the polarizing film produced through the above-described processing steps is 3.0 to 7.0 times the original length of the polymer film before the treatment. Is preferred, and more preferably in the range of 5.0 to 6.3 times. When the total stretching ratio is less than 3.0 times, it is difficult to obtain a polarizing film having a high degree of polarization, and when the total stretching ratio exceeds 7.0 times, the film is easily broken.
• the manufacturing method of the present invention is not limited to the above manufacturing method, but can be applied to other manufacturing methods for obtaining a polarizing film.
• the above-described dry stretching method a method of kneading a dichroic substance into a polymer film such as polyethylene terephthalate (PET), forming a film, further stretching after dyeing to obtain a polarizing film, and using a uniaxially oriented liquid crystal as a host.
• a method for obtaining an E-type polarizing film U.S. Pat. No. 6,049,428) using a dichroic lyopic pick liquid crystal or the like.
• the thickness of the polarizing film thus produced is not particularly limited, but is preferably 5 to 40 ⁇ m.
• the thickness is 5 ⁇ m or more, the mechanical strength does not decrease, and when the thickness is 40 m or less, the optical characteristics do not decrease, and thinning can be realized even when applied to an image display device.
• the polarizing film according to the present invention various optical layers can be laminated and used for practical use.
• the optical layer is not particularly limited as long as it meets the required optical characteristics.
• a transparent protective layer provided on one side or both sides of the polarizing film for the purpose of protecting the polarizing film may be mentioned.
• a polarizing plate is obtained by laminating a transparent protective layer on at least one side of a polarizing film.
• the surface of the transparent protective layer opposite to the surface that adheres to the polarizing film, or one or both surfaces of the polarizing film itself, is used for hard coating treatment, antireflection treatment, sticking prevention, diffusion or antiglare.
• a surface treatment may be performed, or an alignment liquid crystal layer for viewing angle compensation or the like, or an adhesive layer for laminating another film may be laminated.
• a polarization conversion element a reflection plate or a semi-transmission plate, a retardation plate (including a wavelength plate (plate) such as 1/2 or 1/4), a viewing angle compensation film, and a luminance direction
• a retardation plate including a wavelength plate (plate) such as 1/2 or 1/4
• a viewing angle compensation film and a luminance direction
• An optical film used for forming an image display device such as an upper film or the like may be a laminate of one or more layers.
• the timing may be after the lamination with the polarizing film or before the lamination with the polarizing film.
• the material for forming the transparent protective layer provided on one or both surfaces of the polarizing film is preferably a material having excellent transparency, mechanical strength, heat stability, moisture shielding property, isotropy and the like.
• polyester-based polymers such as polyethylene terephthalate / polyethylene naphthalate, cellulose-based polymers such as diacetyl cellulose / triacetyl cellulose, acryl-based polymers such as polymethyl methacrylate, polystyrene and acrylonitrile / styrene copolymer
• examples include styrene-based polymers such as coalescing (AS resin) and polycarbonate-based polymers.
• Polyamides such as polyethylene, polypropylene, polyolefin having a cyclic or norbornene structure, polyolefin polymers such as ethylene / propylene copolymers, vinyl chloride polymers, amide polymers such as nylon and aromatic polyamides, and imidazole polymers.
• the transparent protective layer can also be formed as a cured layer of a thermosetting or ultraviolet curable resin such as an acrylic, urethane, acrylic urethane, epoxy, or silicone resin.
• the transparent protective layer to be bonded to the polarizing film according to the present invention a triacetyl cellulose film whose surface has been saponified with an adhesive is preferable.
• a polymer film described in JP-A-2001-343529 WOO 1/37007
• the resin composition include a thermoplastic resin and (B) a thermoplastic resin having a substituted and Z- or non-substituted fluoro group and a nitrile group in a side chain.
• Specific examples thereof include a film of a resin composition containing an alternating copolymer composed of isobutene and N-methylmaleimide and an acrylonitrile-styrene copolymer.
• a film made of a mixed extruded product of a resin composition or the like can be used.
• the thickness of the transparent protective layer is not particularly limited, it is generally 500 ⁇ or less, preferably 1 to 300 ⁇ m. In particular, it is more preferable to be 5 to 200 ⁇ .
• the surface of the transparent protective layer is saponified with an adhesive from the viewpoint of improving the polarization characteristics, durability and adhesion characteristics.
• the transparent protective layer having a value represented by the following formula (1) is preferably 90 nm to 1075 nm. By using this, the coloring of the polarizing plate (optical coloring) caused by the transparent protective layer can be performed. ) Can be reduced. Further, R th is more preferably from ⁇ 90 to +75 11111, and particularly preferably from 80 nm to +60 nm.
• the transparent protective layer When the transparent protective layer is laminated on both sides of the polarizing film, those having different characteristics for each one side may be used.
• the properties are not limited to these, but include, for example, thickness, material, light transmittance, tensile modulus, presence or absence of an optical layer, and the like.
• the hard coat treatment is performed for the purpose of preventing the polarizing film or the polarizing plate surface on which the polarizing film and the transparent protective layer are laminated from being damaged.
• the hard coat treatment can be achieved by, for example, a method of adding a cured film having excellent hardness and sliding properties to an appropriate UV-curable resin such as acryl or silicone to the surface of the transparent protective layer.
• the anti-reflection treatment is performed to prevent reflection of external light on the polarizing plate surface. This can be achieved by forming an antireflection film or the like according to the related art.
• the anti-stating treatment is performed for the purpose of preventing adhesion to the adjacent layer.
• the anti-glare treatment is performed for the purpose of preventing external light from being reflected on the surface of the polarizing plate and hindering the permeation of light transmitted through the polarizing plate.
• the anti-glare treatment can be achieved by, for example, imparting a fine uneven structure to the surface of the transparent protective layer by an appropriate method such as a sandblasting method, a roughening method by an embossing method, or a method of blending transparent fine particles.
• Examples of the fine particles to be included for forming the surface fine uneven structure include silica, alumina, titania, zirconia, tin oxide, indium oxide, cadmium oxide, and oxide having an average particle size of 0.5 to 50 ⁇ .
• Transparent fine particles such as inorganic fine particles made of antimony or the like and capable of imparting conductivity, and organic fine particles made of a crosslinked or uncrosslinked polymer or the like are used.
• the amount of fine particles used is generally about 2 to 70 parts by weight relative to 100 parts by weight of the transparent resin forming the finely uneven surface structure, and 5 to 5 parts by weight. 0 parts by weight is preferred.
• the anti-glare layer may also serve as a diffusion layer (such as an angle-magnifying function) for diffusing light transmitted through the polarizing plate to increase the viewing angle and the like.
• optical layers such as the antireflection layer, antistating layer, diffusion layer and antiglare layer can be provided on the transparent protective layer or the polarizing film itself, or separately provided separately from the transparent protective layer. You can also.
• the bonding treatment is not particularly limited.
• an adhesive composed of a bur polymer, boric acid, borax, dartartaldehyde, or the like may be used.
• This adhesive layer can be formed as a layer for applying and drying an aqueous solution.
• other additives and a catalyst such as an acid can be added as necessary.
• a reflective polarizing plate is a polarizing plate provided with a reflective layer. This is for forming a liquid crystal display device etc. that reflects and reflects the emitted light, and has the advantage that the built-in light source such as a backlight can be omitted and the liquid crystal display device can be made thinner. .
• the reflective polarizing plate can be formed by an appropriate method such as a method in which a reflective layer made of metal or the like is provided on one surface of the polarizing plate via a transparent protective layer or the like, if necessary.
• a reflective layer is formed by attaching a foil-deposited film made of a reflective metal such as aluminum to one surface of a transparent protective layer that has been matted, if necessary. And so on.
• a transparent protective layer containing fine particles to form a fine surface uneven structure
• a reflective layer having a fine uneven structure thereon may be mentioned.
• the reflective layer having the above-described fine uneven structure has an advantage that the incident light is diffused by irregular reflection to prevent a directional glare and to suppress uneven brightness.
• the transparent protective layer containing fine particles also has an advantage that the incident light and the reflected light are diffused when transmitting the light and the unevenness of brightness and darkness can be further suppressed.
• the reflection layer having a fine uneven structure reflecting the fine uneven structure on the surface of the transparent protective layer is formed by, for example, depositing a metal by an appropriate method such as a vapor deposition method such as a vacuum evaporation method, an ion plating method, a sputtering method or a plating method. It can be performed by a method of directly attaching to the surface of the transparent protective layer.
• the reflection plate can be used as a reflection sheet or the like in which a reflection layer is provided on an appropriate film conforming to the transparent film, instead of the method of directly applying the reflection plate to the transparent protective layer of the polarizing plate. Since the reflective layer is usually made of metal, it is recommended to use it with its reflective surface covered with a transparent protective layer or a polarizing plate, etc. It is preferable in terms of avoiding the separate attachment of the protective layer.
• the transflective polarizing plate can be obtained by providing a transflective reflective layer such as a half mirror that reflects and transmits light in the above. The transflective polarizing plate is usually provided on the back side of the liquid crystal cell.
• a liquid crystal display device When a liquid crystal display device is used in a relatively bright atmosphere, an image is displayed by reflecting incident light from the viewing side (display side).
• a type of liquid crystal display that displays images using a built-in light source such as a backlight built into the backside of a transflective polarizing plate, etc. Can be formed.
• a transflective polarizing plate can save energy for using a light source such as a backlight in a bright atmosphere, and can be used to form a liquid crystal display device of a type that can be used with a built-in light source even in a relatively dark atmosphere. Useful.
• An elliptically polarizing plate or a circularly polarizing plate in which a retardation plate is further laminated on a polarizing plate will be described.
• a phase difference plate or the like is used.
• a so-called quarter-wave plate also referred to as a ⁇ 4 plate
• a 1Z two-wave plate (also called a ⁇ / 2 plate) is usually used to change the polarization direction of linearly polarized light.
• the elliptically polarizing plate effectively compensates (prevents) the coloring (blue or yellow) caused by the birefringence of the liquid crystal layer of the super twisted nematic (STN) type liquid crystal display device, and is used effectively in the case of black and white display without the coloring.
• a device in which the three-dimensional refractive index is controlled is preferable because coloring that occurs when the screen of the liquid crystal display device is viewed from an oblique direction can be compensated (prevented).
• the circularly polarizing plate is effectively used, for example, when adjusting the color tone of an image of a reflection type liquid crystal display device for displaying an image in color, and has a function of preventing reflection.
• the retardation plate examples include a birefringent film obtained by uniaxially or biaxially stretching a polymer material, an alignment film obtained by aligning a liquid crystal monomer, and then cross-linking and polymerizing the alignment film, an alignment film of a liquid crystal polymer, and a liquid crystal polymer. And the like, in which the alignment layer is separately supported by a film.
• the stretching treatment can be performed by, for example, a roll stretching method, a long gap stretching method, a tenter stretching method, a tubular stretching method, or the like.
• the stretching ratio is generally about 1.1 to 3 times in the case of uniaxial stretching, but is not limited thereto.
• the thickness of the phase difference plate is not particularly limited either, but is generally from 10 to 20 ⁇ , preferably from 20 to 100 ⁇ .
• polymer material examples include polybiol alcohol, polybutyrupinole, polymethinolebininoleatenore, polyhydroxyxenotinolate acrylate, hydroxyxinetinoresenorelose, and hydroxypropinoresenorelose.
• Mechinoresenororesu Po Recarbonate, polyarylate, polysulfone, polyethylene terephthalate, polyethylene naphthalate, polyethenoles nolephone, polyphenylene snoleide, polyphenylene oxide, polyarynosulfone, polybutylanolecole, polyamide, polyamide, polyolefin, Examples thereof include polyvinyl chloride, cellulosic polymers, binary and ternary copolymers thereof, graft copolymers, and mixtures thereof. These polymer materials become oriented materials (stretched films) by stretching or the like.
• thermopick property is preferable from the viewpoint of workability.
• those having a basic skeleton of a biphenyl derivative, a phenylbenzoate derivative, a stilbene derivative or the like into which a functional group such as an atalyloyl group, a vinyl group or an epoxy group is introduced, and the like can be given.
• Such a liquid crystal monomer is aligned using, for example, a method using heat or light, a method using rubbing on a substrate, a method using an alignment aid, and the like.
• a method of fixing the orientation by crosslinking and polymerizing with an electron beam or the like is preferably used.
• liquid crystal polymer examples include various types of main chain type and side chain type in which a conjugated linear atom group (mesogen) imparting liquid crystal orientation is introduced into a main polymer side chain of the polymer.
• main chain type liquid crystal polymer examples include a structure in which a mesogen group is bonded at a spacer portion that imparts flexibility, such as a nematic-aligned polyester-based liquid crystal polymer, a discotic polymer, and a cholesteric polymer. And the like.
• the side-chain type liquid crystalline polymer include polysiloxane, polyatalylate, polymetharylate, or polymalonate as a main chain skeleton, and a nematic through a spacer portion composed of a conjugated atomic group as a side chain.
• examples thereof include those having a mesogen moiety composed of a para-substituted cyclic compound unit capable of imparting orientation.
• These liquid crystal polymers are, for example, those obtained by rubbing the surface of a thin film of polyimide or polyvinyl alcohol formed on a glass plate, or those obtained by obliquely depositing silicon oxide. This is performed by developing the solution and performing heat treatment.
• the retardation plate may have an appropriate retardation according to the purpose of use, such as, for example, various wavelength plates or those for the purpose of compensating for a viewing angle or the like due to birefringence of a liquid crystal layer.
• a device in which optical characteristics such as a phase difference are controlled by laminating a phase difference plate may be used.
• the above-mentioned elliptically polarizing plate or reflection type elliptically polarizing plate is obtained by laminating a polarizing plate or a reflection type polarizing plate and a retardation plate in an appropriate combination.
• Such an elliptically polarizing plate or the like can also be formed by sequentially and separately laminating a (reflection type) polarizing plate and a retardation plate in the process of manufacturing a liquid crystal display device so as to form a combination.
• an optical film such as an elliptically polarizing plate is excellent in quality stability, laminating workability, and the like, and has an advantage that the manufacturing efficiency of a liquid crystal display device or the like can be improved.
• the viewing angle compensation film is a film for widening the viewing angle so that an image can be seen relatively clearly even when the screen of the liquid crystal display device is viewed not obliquely but perpendicularly to the screen.
• a viewing angle compensation film includes, for example, an alignment film such as a retardation film and a liquid crystal polymer, and a film in which an alignment layer such as a liquid crystal polymer is supported on a transparent substrate.
• a common retardation plate is a birefringent polymer film uniaxially stretched in the plane direction, whereas a retardation plate used as a viewing angle compensation film is biaxially stretched in the plane direction.
• Bidirectional stretching such as a polymer film with birefringence or a uniaxially stretched in the plane direction and also stretched in the thickness direction, a birefringent polymer with a controlled refractive index in the thickness direction or an obliquely oriented film Film and the like are used.
• the obliquely oriented film include a film obtained by bonding a heat shrinkable film to a polymer film and subjecting the polymer film to a stretching treatment and / or a shrinkage treatment under the action of the shrinkage force caused by heating, or an obliquely oriented liquid crystal polymer. Things are listed.
• the raw material polymer for the retardation plate the same polymer as described for the retardation plate is used to prevent coloring etc. due to changes in the viewing angle based on the phase difference due to the liquid crystal cell, and to increase the viewing angle for good visibility Any appropriate one for the purpose can be used.
• an optically anisotropic layer composed of a liquid crystal polymer alignment layer, particularly a tilted alignment layer of a discotic liquid crystal polymer, is supported by a triacetyl cellulose film.
• a compensating retardation plate can be preferably used.
• the polarization conversion element include an anisotropic reflection type polarization element and an anisotropic scattering type polarization element.
• the anisotropic reflection-type polarizing element may be either left-handed or right-handed, such as a cholesteric liquid crystal layer, in particular, an alignment film of a cholesteric liquid crystal polymer, or an alignment liquid crystal layer supported on a film substrate.
• a material exhibiting the characteristic of transmitting linearly polarized light having a predetermined polarization axis and reflecting other light such as a multilayer thin film of a dielectric material or a multilayer laminate of thin film films having different refractive index anisotropies.
• the former include the PCF series manufactured by Nitto Denko, and examples of the latter include the DBEF series manufactured by 3M.
• a reflective grid polarizer can be preferably used as the anisotropic reflective polarizing element.
• a polarizing plate in which a polarizing plate and a brightness enhancement film are bonded together is usually used by being provided on the back side of a liquid crystal cell.
• the brightness enhancement film reflects linearly polarized light of a predetermined polarization axis or circularly polarized light of a predetermined direction when natural light enters due to reflection from the back side of a backlight of a liquid crystal display device, etc., and exhibits the property of transmitting other light.
• the polarizing plate in which the brightness enhancement film is laminated with the polarizing plate receives light from a light source such as a knock light to obtain transmitted light in a predetermined polarization state and transmits light other than the predetermined polarization state. Reflections.
• the light reflected on the brightness enhancement film surface is further inverted through a reflection layer or the like provided on the rear side thereof and re-entered on the brightness enhancement film, and a part or all of the light of a predetermined polarization state is obtained.
• Increasing the amount of light that passes through the brightness enhancement film by transmitting it as light, and increasing the amount of light that can be used for liquid crystal image display, etc. by supplying polarized light that is difficult to absorb into the polarizing film It can be done.
• the brightness enhancement film reflects light having a polarization direction that can be absorbed by the polarizing film, without being incident on the polarizing film, but once reflects the light on the brightness enhancement film, and further passes through a reflective layer provided on the back side. Reversing the process of inverting the light and re-entering it on the brightness enhancement film, transmitting only the polarized light whose polarization direction has been changed so that the polarization direction of the reflected and inverted light between the two can pass through the polarizer. Since light is supplied to the polarizing film, light from a backlight or the like can be efficiently used for displaying an image on the liquid crystal display device, and the screen can be brightened.
• a diffusion plate may be provided between the brightness enhancement film and the above-mentioned reflection layer or the like.
• the light in the polarization state reflected by the brightness enhancement film is directed toward the reflection layer and the like, and is uniformly diffused by passing through the installed diffusion plate, and at the same time, the polarization state is eliminated and the light enters the non-polarization state. That is, the state returns to the original natural light state.
• the light in the non-polarized state that is, in the natural light state, repeatedly travels toward the reflection layer and the like, is reflected through the reflection layer and the like, passes through the diffusion plate again, and reenters the brightness enhancement film.
• the diffuser By providing the diffuser for returning to the original natural light state, it is possible to maintain the brightness of the display screen and at the same time reduce the unevenness of the brightness of the display screen and provide a uniform bright screen. It is thought that by providing a diffuser to return to the original natural light state, the number of repetitions of reflection of the first incident light increased moderately, and it was possible to provide a uniform and bright display screen in combination with the diffuser function of the diffuser. Can be
• the brightness enhancement film has a characteristic of transmitting linearly polarized light having a predetermined polarization axis and reflecting other light, such as a multilayer thin film of a dielectric or a multilayer laminate of thin films having different refractive index anisotropies. As shown in the figure, either the left-handed or right-handed circularly polarized light is reflected and the other light is transmitted, such as an alignment film made of a cholesteric liquid crystal polymer or an alignment liquid crystal layer supported on a film substrate. Any suitable material such as one exhibiting the characteristics described above can be used.
• a brightness enhancement film that transmits linearly polarized light having a predetermined polarization axis as described above the transmitted light can be directly incident on the polarizing plate with the polarization axis aligned.
• a brightness enhancement film that transmits circularly polarized light such as a cholesteric liquid crystal layer, can be directly incident on the polarizing film.
• the circularly polarized light is linearly polarized through a retardation plate. It is preferable to convert the light into a polarizing plate. By using a quarter-wave plate as the retardation plate, circularly polarized light can be converted to linearly polarized light.
• a retardation plate that functions as a quarter-wave plate in a wide wavelength range such as the visible light region is, for example, a retardation layer that functions as a quarter-wave plate for monochromatic light with a wavelength of 550 nm and another phase difference plate. It can be obtained by a method in which a retardation layer exhibiting characteristics, for example, a retardation layer functioning as a half-wave plate is overlapped. Therefore, the retardation plate disposed between the polarizing plate and the brightness enhancement film may be composed of one or more retardation layers.
• the cholesteric liquid crystal layer can also reflect different wavelengths by combining two or three or more layers to obtain circularly polarized light in a wide wavelength range such as the visible light region. Based on this, it is possible to obtain circularly polarized light transmitted over a wide wavelength range.
• the polarizing plate of the present invention may be formed by laminating a polarizing plate and two or three or more optical layers as in the above-mentioned polarized light separating type polarizing plate. Therefore, a reflective elliptically polarizing plate or a transflective elliptically polarizing plate obtained by combining the above-mentioned reflective polarizing plate, semi-transmissive polarizing plate and retardation plate may be used.
• An optical film in which the optical layer is laminated on a polarizing plate can also be formed by a method in which the optical film is laminated separately in the manufacturing process of a liquid crystal display device or the like. It has the advantage of being superior in stability and assembly work, and can improve the manufacturing process of liquid crystal display devices and the like.
• an appropriate bonding means such as an adhesive layer can be used.
• their optical axes can be set at an appropriate arrangement angle according to the intended retardation characteristics and the like.
• the polarizing film according to the present invention and the optical layer may be provided with an adhesive layer for bonding to another member such as a liquid crystal cell.
• the adhesive layer is not particularly limited Instead, for example, it can be formed of an appropriate adhesive such as acrylic, silicone, polyester, polyurethane, polyether, or rubber.
• the pressure-sensitive adhesive is used to prevent foaming and peeling phenomena due to moisture absorption, to prevent deterioration of optical properties due to differences in thermal expansion, to prevent liquid crystal cells from warping, and to form an image display device having high quality and excellent durability. Therefore, it is preferable that the adhesive layer has a low moisture absorption rate and excellent heat resistance.
• a material that does not require a high-temperature process for curing or drying is preferable, and a material that does not require a long curing treatment or drying time is preferable.
• an acrylic adhesive is preferably used.
• an adhesive layer or the like which contains fine particles and exhibits light diffusibility can be used.
• the adhesive layer may be provided on a necessary surface as needed.
• a polarizing plate comprising a polarizing film and a transparent protective layer as in the present invention, if necessary, one or both surfaces of the protective layer may have an adhesive layer. What is necessary is just to provide a layer.
• the thickness of the adhesive layer is not particularly limited, but is preferably 5 to 35 / im, more preferably 15 to 25 ⁇ . By setting the thickness of the adhesive layer in this range, the stress accompanying the dimensional behavior of the polarizing film and the polarizing plate can be reduced.
• the separator is a method in which an appropriate release film such as a silicon-based ⁇ long-chain alkyl-based, fluorine-based, or molybdenum sulfide is applied to an appropriate film conforming to the above transparent protective layer, etc., if necessary. And the like.
• the transparent protective layer, optical layer, adhesive layer, and other layers forming the above-mentioned polarizing plate and optical film are made of, for example, a salicylate compound, a benzophenone compound, a benzotriazole compound, a cyanoacrylate compound, and nickel. It may have an ultraviolet absorbing ability by an appropriate method such as a method of treating with an ultraviolet absorbing agent such as a complex salt compound.
• the polarizing film according to the present invention can be used for a liquid crystal display (LCD), It can be preferably used for forming an image display device such as a display device (ELD), a plasma display panel (PDP), and a field emission display (FED).
• LCD liquid crystal display
• ELD display device
• PDP plasma display panel
• FED field emission display
• the polarizing film of the present invention can be preferably used for forming various devices such as a liquid crystal display device.
• a reflection type or half-type in which a polarizing film or a polarizing plate is arranged on one side or both sides of a liquid crystal cell. It can be used for a liquid crystal display device such as a transmission type or a transmission / reflection type.
• the liquid crystal cell substrate may be a plastic substrate or a glass substrate.
• the liquid crystal cell forming the liquid crystal display device is arbitrary, for example, an active matrix driving type typified by a thin film transistor type, a simple matrix driving type typified by a twisted nematic type or a super twisted nematic type, and the like.
• a liquid crystal cell of a type may be used.
• polarizing plates or other optical films When polarizing plates or other optical films are provided on both sides of the liquid crystal cell, they may be the same or different. Further, when forming the liquid crystal display device, one or more layers such as a prism array sheet, a lens array sheet, a light diffusion plate, and a backlight can be arranged at appropriate positions.
• organic electroluminescence display device organic EL display device
• a transparent electrode, an organic light emitting layer, and a metal electrode are sequentially laminated on a transparent substrate to form a light emitting body (organic electroluminescent light emitting body).
• the organic light emitting layer is a laminate of various organic thin films, for example, a laminate of a hole injection layer made of a triphenylamine derivative or the like and a light emitting layer made of a fluorescent organic solid such as anthracene, or A structure having various combinations such as a laminate of such a light emitting layer and an electron injection layer made of a perylene derivative or a laminate of these hole injection layer, light emitting layer, and electron injection layer is known. Have been. In an organic EL display device, holes and electrons are injected into an organic light emitting layer by applying a voltage to a transparent electrode and a metal electrode, and the energy generated by the recombination of these holes and electrons is converted into a fluorescent substance.
• the mechanism of recombination in the middle is It is the same as a general diode, and as can be expected from this, the current and emission intensity show strong nonlinearity due to rectification with respect to the applied voltage.
• At least one of the electrodes must be transparent in order to extract light emitted from the organic light emitting layer, and is usually formed of a transparent conductor such as indium tin oxide (IT ⁇ ).
• An electrode is used as the anode.
• metal electrodes such as Mg_Ag and A1_Li.
• the organic light emitting layer is generally formed of a very thin film having a thickness of about 10 nm. For this reason, the organic light emitting layer transmits light almost completely similarly to the transparent electrode. As a result, the light that enters from the surface of the transparent substrate during non-light emission, passes through the transparent electrode and the organic light-emitting layer, and is reflected by the metal electrode, returns to the surface of the transparent substrate again.
• the display surface of the OLED display looks like a mirror.
• an organic EL display device including an organic electroluminescent luminous element having a transparent electrode on the front side of an organic luminescent layer that emits light by applying a voltage and a metal electrode on the back side of the organic luminescent layer
• the transparent electrode A polarizing plate can be provided on the surface side, and a retardation film can be provided between the transparent electrode and the polarizing plate.
• the retardation film and the polarizing film have a function of polarizing light incident from the outside and reflected by the metal electrode, there is an effect that a mirror surface of the metal electrode is not visually recognized from the outside by the polarizing action.
• the retardation film is composed of a 14-wavelength plate and the angle between the polarization directions of the polarizing plate and the retardation film is adjusted to ⁇ / 4, the mirror surface of the metal electrode can be completely shielded.
• linearly polarized light components of the external light incident on the organic EL display device are transmitted by the polarizing plate.
• This linearly polarized light is generally converted into elliptically polarized light by the retardation film.
• the retardation film is a quarter-wave plate and the angle between the polarization directions of the polarizing plate and the retardation film is ⁇ / 4, the linearly polarized light becomes circularly polarized light. Become.
• This circularly polarized light passes through the transparent substrate, the transparent electrode, and the organic thin film, is reflected by the metal electrode, passes through the organic thin film, the transparent electrode, and the transparent substrate again, and is again linearly polarized by the retardation film. It becomes. Since this linearly polarized light is orthogonal to the polarization direction of the polarizing plate, it cannot pass through the polarizing plate. As a result, the mirror surface of the metal electrode can be completely shielded.
• the PDP generates electric discharge in a rare gas enclosed in the panel, especially a gas mainly composed of neon, and the R, G, B phosphor coated on the panel cells by the vacuum ultraviolet rays generated at that time
• the image display becomes possible by generating.
• the size of the chip-cut polarizing film is arbitrary, and the length S is generally 10 c ⁇ ⁇ 13 0 c ⁇ , Those with a width of 10 cm to 130 cm are used.
• the size of the display there is no upper limit on the size of the display, but it depends on the transparent protective film that can be made at present and the width of the substrate for polarizing films such as PVA films.
• the polarizing film obtained by the present invention has excellent in-plane uniformity.
• the process of bonding to image display elements such as liquid crystal display elements and EL display elements can be performed in one line without going through the transportation, packing, and unpacking steps. Examples>
• a triacetyl cellulose film (80 ⁇ thick) saponified by immersing it in an alkaline aqueous solution for 60 seconds on both sides of this polarizing film was adhered with a PVA-based adhesive. After drying at 60 ° C for 4 minutes, a polarizing plate was obtained.
• the film was conveyed using a roll, and the film was stretched by using the peripheral speed difference of the pinch roll before and after the processing step.
• the conditions in each processing step of the polarizing film manufacturing process are as follows.
• Example 3 A polarizing film and a polarizing film were prepared in the same manner as in Example 1 except that two films were processed in a form in which the jaws were arranged vertically in two stages in each processing bath as shown in FIG. And a polarizing plate. Table 1 shows the measurement results of the obtained polarizing plates. '' Reference examples
• Example 1 Using a PVA film having a width and length of 10 O mm, the same procedure as in Example 1 was performed except that one film was conveyed to one Lorenole as shown in FIG. A polarizing film and a polarizing plate were obtained. Table 1 shows the measurement results of the obtained polarizing plates. Comparative Example 1
• Example 2 Same as Example 1 except that a 20-mm-wide PVA film was used to transport one film per roll as shown in Fig. 2 (conventional method). Thus, a polarizing film and a polarizing plate were obtained. Table 1 shows the measurement results of the obtained polarizing plates. Comparative Example 2
• Example 2 Same as Example 1 except that a film was transported using a PVA finolem with a width and length of 30 O mm, and one film was transported per lonoré as shown in Fig. 2 (conventional method). Thus, a polarizing film and a polarizing plate were obtained. Table 1 shows the measurement results of the obtained polarizing plates.
• the polarizing plate manufactured in the example, reference example or comparative example was cut into a size of 35 mm ⁇ 25 mm so as to be at 45 ° with respect to the stretching direction, and a spectrophotometer (Murakami Color Research Institute) Manufactured by: DOT-3), the single transmittance, the parallel transmittance (H :.) and the orthogonal transmittance (I- 19 .) Were measured, and the degree of polarization was calculated from the values by the following formula. . Note that this These transmittances are Y values that have been subjected to luminosity correction using a 2-degree field of view (C light source) of J 1 SZ8701.
• Polarization degree (%) ⁇ (H. one H 9. ) / (H. + H 9. ) ⁇ 1/2 X 100
• the production amount per unit time can be more simply increased without deteriorating the optical characteristics.
• the method of the present invention uses a manufacturing apparatus having a wide processing bath for manufacturing a wide polarizing film even when compared with a polarizing film manufactured using a wide film as conventionally attempted. , Fig. 3 and fig.
• the optical properties and surface condition that had been a problem when widening did not occur were the force ⁇ per unit time
• the production volume can be as high as the production of wide films. That is, a large amount of a polarizing film having more excellent optical properties can be obtained. Further, in the manufacturing process of the polarizing film, even if the concentration of the processing solution in the processing bath slightly changes, the optical characteristics greatly change.
• the manufacturing method of the present invention By simultaneously processing a plurality of films, the desired production volume can be obtained in a shorter time, so that it is less susceptible to changes over time in the substances contained in the processing solution and the concentration of the processing solution, and has almost the same characteristics Can be mass-produced. Therefore, when the manufacturing method of the present invention is used, an effect is obtained that it is possible to easily cope with an increase in the amount of polarizing film produced due to an increase in demand for an image display device.

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