WO2005025854A1 - Lamelle textile non-tisse reduisant la migration des particules et couche-culotte comportant un tel lamelle - Google Patents

Lamelle textile non-tisse reduisant la migration des particules et couche-culotte comportant un tel lamelle Download PDF

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Publication number
WO2005025854A1
WO2005025854A1 PCT/US2004/024310 US2004024310W WO2005025854A1 WO 2005025854 A1 WO2005025854 A1 WO 2005025854A1 US 2004024310 W US2004024310 W US 2004024310W WO 2005025854 A1 WO2005025854 A1 WO 2005025854A1
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WO
WIPO (PCT)
Prior art keywords
layer
fibers
nonwoven fabric
fabric laminate
laminate
Prior art date
Application number
PCT/US2004/024310
Other languages
English (en)
Inventor
Michael T. Morman
Mark G. Kupelian
Todd Sudduth
David M. Tran
James R. Morgan
Thomas G. Bolwerk
Hughey K. Jeffries
Riley K. Middleton, Iii
Original Assignee
Kimberly-Clark Worldwide, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US10/657,622 external-priority patent/US20050054255A1/en
Priority claimed from US10/657,498 external-priority patent/US20050054999A1/en
Application filed by Kimberly-Clark Worldwide, Inc. filed Critical Kimberly-Clark Worldwide, Inc.
Publication of WO2005025854A1 publication Critical patent/WO2005025854A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00—Bandages or dressings; Absorbent pads
    • A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/53—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium
    • A61F13/534—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium having an inhomogeneous composition through the thickness of the pad
    • A61F13/537—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium having an inhomogeneous composition through the thickness of the pad characterised by a layer facilitating or inhibiting flow in one direction or plane, e.g. a wicking layer
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00—Bandages or dressings; Absorbent pads
    • A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/51—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers
    • A61F13/511—Topsheet, i.e. the permeable cover or layer facing the skin
    • A61F13/51121—Topsheet, i.e. the permeable cover or layer facing the skin characterised by the material
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00—Bandages or dressings; Absorbent pads
    • A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/51—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers
    • A61F13/511—Topsheet, i.e. the permeable cover or layer facing the skin
    • A61F13/5116—Topsheet, i.e. the permeable cover or layer facing the skin being formed of multiple layers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00—Bandages or dressings; Absorbent pads
    • A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/51—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers
    • A61F13/511—Topsheet, i.e. the permeable cover or layer facing the skin
    • A61F13/513—Topsheet, i.e. the permeable cover or layer facing the skin characterised by its function or properties, e.g. stretchability, breathability, rewet, visual effect; having areas of different permeability
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00—Bandages or dressings; Absorbent pads
    • A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/53—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium
    • A61F13/531—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium having a homogeneous composition through the thickness of the pad
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00—Bandages or dressings; Absorbent pads
    • A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/15203—Properties of the article, e.g. stiffness or absorbency
    • A61F2013/15284—Properties of the article, e.g. stiffness or absorbency characterized by quantifiable properties
    • A61F2013/15406—Basis weight

Definitions

  • This invention relates to nonwoven fabric laminates and to absorbent articles such a diapers that include nonwoven fabric laminates.
  • Personal care absorbent articles such as disposable diapers
  • diapers for infants are typically designed to accept large volumes of urine in multiple doses which can measure 60-100 milliliter per dose.
  • Such diapers often require the use of high absorbency, superabsorbent particles to provide the needed absorbent capacity.
  • superabsorbent gel particles are blended with woodpulp fibers to create an absorbent matrix. The matrix, however, is often unable to adequately contain the superabsorbent particles.
  • the bodyside liner that separates the wearer from the absorbent portion of the diaper must be liquid pervious so that the absorbent can absorb liquid waste.
  • a single layer of spunbonded nonwoven fibers has been used as a body side liner in diapers because surfactant treated polypropylene spunbonded nonwoven fabrics are highly liquid pervious and inexpensive.
  • spunbonded nonwoven fabrics consist of coarse spunbonded fibers that typically have diameters in the range of from about 8 to about 30 microns.
  • Light weight spunbonded nonwoven fabrics used as diaper liners may have large pore sizes often in excess of ten times the spunbond fiber diameters. Dry superabsorbent gel particles can and frequently do migrate thorough spunbonded nonwoven webs.
  • barrier tissues and core wraps have been used to separate and contain the absorbent core portion of a diaper.
  • U.S. Patent no. 5,458,592 and EP 1073390 B1 describe thermoplastic fibrous tissues for wrapping absorbent cores that are referred to a core wraps.
  • a desirable barrier location to particles is at the wearer/product interface because a barrier may be placed around the absorbent structure to contain not only the particles in the absorbent but also particles that may be introduced during converting that may land on the formed, wrapped absorbent structure. These unintended particles can migrate to the skin. So, there remains a need to develop materials that further reduce or eliminate superabsorbent gel particle migration that are easy and economical to manufacture.
  • nonwoven fabric laminate that reduces or eliminates gel particle migration and that performs at parity of other properties of the diaper such as extensibility, fluid intake and flowback and so forth. It would also be desirable to produce a nonwoven fabric that can be used as a bodyside liner, a core wrap, a barrier tissue or as another layer between the absorbent portion of a diaper and the wearer to prevent or at least reduce gel migration from the absorbent to the wearer of the diaper.
  • One exemplary embodiment of the present invention provides a laminate for use in a disposable garment for the adsorption and containment of urine or other body exudates.
  • the disposable garment includes a liquid impervious backing sheet, a nonwoven fabric laminate that includes a thin layer of fine fibers, and an absorbent material disposed between the liquid pervious bodyside liner and the liquid impervious backing sheet wherein the thin layer of fine fibers has a basis weight of less than 1.5 grams per square meter.
  • the layer of fine fibers may consist essentially of meltblown fibers.
  • the nonwoven fabric laminate may include at least one spunbond layer and the thin layer of fine fibers may consist essentially of a layer of meltblown fibers.
  • the thin layer of fine fibers may be disposed between two spunbond layers.
  • the nonwoven fabric laminate may be used as a liquid pervious bodyside liner or a layer between the absorbent material and a liquid pervious bodyside liner in a diaper.
  • the nonwoven fabric laminate can be a layer between the absorbent material and a liquid pervious bodyside liner that envelops the absorbent material.
  • the thin layer of fine fibers may consist of a layer of fibers that has a basis weight of less than about 1 gram per square meter.
  • the thin layer of fine fibers may have a basis weight of less than about 0.8 gram per square meter, less than about 0.5 gram per square meter or even less than about 0.3 gram per square meter.
  • a nonwoven fabric laminate of the present invention may include a layer of bonded carded fibers.
  • the spunbonded fibers of nonwoven fabric laminate of the present invention may include fibers made from a polymer selected from the group consisting of lactic acid, vinyl alcohol, and mixtures thereof.
  • the present invention provides a nonwoven fabric laminate that consists essentially of a first layer of spunbonded fibers, a second layer of spunbonded fibers, and a layer of meltblown fibers disposed between the first layer of spunbonded fibers and the second layer of spunbonded fibers, wherein the layer of meltblown fibers has a basis weight of ranges from 0.06 grams per square meter to about 1.5 gram per square meter.
  • the meltblown fibers may have an average diameter in the range of up to about 8 microns and the spunbonded fibers have an average diameter in the range of from about 8 microns to about 30 microns.
  • the first spunbonded layer, the meltblown layer and the second spunbonded layer can be intermittently bonded to form the nonwoven fabric laminate. Suggested bonding techniques include thermal point bonding, ultrasonic bonding, adhesive lamination, and so forth.
  • Figure 1 illustrates a schematic diagram of an exemplary forming machine that can be used to form a laminate of the present invention.
  • Figure 2 illustrates a cross-section view of a three-layer embodiment of a laminate of the present invention showing a three-layer configuration including an internal fine fiber barrier layer and two continuous fiber layers.
  • Figure 3 illustrates a cross-section view of an alternative two-layer embodiment of a laminate of the present invention including a fine fiber barrier layer and one continuous fiber layer.
  • Figure 4 illustrates a partially cut away top plan view of an exemplary personal care absorbent article, in this case a diaper, which utilizes a laminate according to the present invention.
  • Figure 5 illustrates a perspective view of another absorbent article according to yet another embodiment of the present invention.
  • Figure 5A illustrates a cross-sectional side view of an absorbent article according to the present invention.
  • Figure 5B illustrates a cross-sectional side view of another absorbent article according to the present invention.
  • Figure 5C illustrates a cross-sectional side view of another absorbent article according to the present invention.
  • the present invention is directed to laminates, for example bodyside liners, that include at least one fine fiber layer.
  • the laminate is a lightweight nonwoven laminate of a meltblown nonwoven material layer consisting essentially of a layer of fine fibers and a spunbonded nonwoven material layer consisting of a layer of coarser fibers.
  • laminates of the present invention may include a laminate of a fine fiber, meltblown layer and another layer such as a bonded carded web of staple fibers.
  • the lightweight nonwoven laminate further includes a second spunbonded, continuous filament, nonwoven material layer.
  • the lightweight nonwoven laminate may optionally include additional layers, for example a perforated film.
  • the present invention also provides disposable, absorbent garments, for example diapers, that include a liquid pervious bodyside liner that is made of or includes such a lightweight nonwoven laminate or that include such a laminate between the absorbent care and the bodyside liner.
  • a laminate of the present invention can be used as the bodyside liner in a diaper or other disposable, absorbent article to contain superabsorbent gel particles or any other particles that are included in the absorbent portion of a diaper or other absorbent article.
  • the present invention provides absorbent articles that include a lightweight nonwoven laminate to contain particles that are included in the absorbent core portion of the article while allowing urine and other liquid wastes to be absorbed by the absorbent portion of the absorbent article.
  • a laminate of the present invention may form the bodyside liner portion of the absorbent article, a wrap for the absorbent core of the absorbent article or as any other layer between the absorbent portion of the article and the wearer in order to reduce particle migration from the absorbent portion of the diaper to the interior portion of the diaper that is in contact with the skin.
  • Gel particles that escape from the absorbent portion of such articles have been observed to adhere to human skin especially when the particles are wet. The particles are undesirable and can be troublesome to remove.
  • Laminates of the present invention provide an advantage by reducing or eliminating the amount of superabsorbent gel particles that migrate to the skin of a wearer of the absorbent article.
  • Laminates that include a fine fiber, for example meltblown layer are typically used as liquid barriers, for example in surgical garments to reduce blood strikethrough. These laminates have typically included a fine fiber layer of high basis weight to provide liquid barrier properties.
  • Laminates of the present invention are fluid permeable but still retain small particles.
  • laminates of the present invention can be used to solve the problem of migration of absorbent particles, other particles and fibers to a wearer's skin while still functioning as a liquid transfer medium.
  • the fine fiber layer of the present invention includes fibers having an average diameter in the range of up to about 8 microns.
  • the fine fiber layer includes fibers having an average diameter in the range of less than about 5 microns to even less than about 2 microns.
  • the fine fiber layer can be formed by conventional meltblown fiber making processes. Meltblown fiber making processes are well known and are described in U.S. Patent no. 3,849,241 to Butin et al. and U.S. Patent no.
  • the basis weight of the fine fiber layer may be in the range of from up to about 1.5 grams per square meter (gsm) to even as low as less than about 0.06 gsm, desirably less than about 1 gsm, more desirably less than about 0.8 gsm, and even less than about 0.5 gsm.
  • the continuous filament web has filaments with an average diameter in the range of from about 8 microns to about 30 microns.
  • the continuous filaments have an average diameter in the range of from about 8 microns to about 25 microns.
  • the continuous filament web can be formed by conventional spunbonded fiber making processes.
  • Spunbonded fiber making processes are also well known and are described in for example U.S. Patent no. 4,340,563 to Appel et al., U.S. Patent no. 3,692,618 to Dorschner et al., U.S. Patent no. 3,802,817 to Matsuki et al., U.S. Patents nos. 3,338,992 and 3,341 ,394 to Kinney, U.S. Patent no. 3,502,763 to Hartman, and U.S. Patent no. 3,542,615 to Dobo et al.
  • the basis weight of the continuous filament web layer may be in the range of from about 4 gsm to about 30 gsm or in the range of from about 10 gsm to about 20 gsm.
  • the fine fiber layer and the continuous fiber layer can bonded intermittently for a total basis weight not to exceed about 55 gsm and the amount of fine fibers in the laminate based on the weight of the laminate can be as low as 10 weight percent, 5 weight percent and even as low as 1 weight percent.
  • the laminate basis weight in accordance with the invention is extremely low and within the range of up to about 10 gsm and the fine fibers constitute a low proportion of the laminate in the range of about 5 percent to about 25 percent by weight.
  • laminates of the present invention can have improved fluid permeability as measured by hydrostatic head of less than 15 cm. and breathability as measured in terms of Frazier porosity of at least 50 scfm.
  • Desirable commercial embodiments include spunbond continuous filament web and meltblown fine fiber webs as the respective layers.
  • the meltblown fine fiber nonwoven web layer can be formed by a melt-blown web forming process such as the process described in coassigned U.S. Patent no. 5,213,881 to Timmons et al. or U.S. Patent no. 5,492,751 to Butt, Sr. et al.
  • thermoplastic resins for example polyolefins including predominantly propylene polymer but which may include, polyethylene, or other alphaolefins polymerized with Ziegler-Natta catalyst technology, and copolymers, terpolymers, or blends thereof.
  • Polypropylene resins are desirable for the continuous filament web layer.
  • the continuous filaments can be made from inherently wettable, nonpolyolefin resins such as polymers and copolymers of vinyl acetate or lactic acid.
  • the filaments or a nonwoven web of the filaments can be treated with one or more surfactants to improve the wettability of the fibers and the resulting nonwoven web.
  • the meltblown fine fibers and fine fiber nonwoven webs can be formed from a propylene polymer resin having a broad molecular weight distribution and having a high melt flow rate which resin is modified by the addition of a small amount of peroxide prodegradant or heating prior to processing to achieve an even higher melt flow rate (lower viscosity).
  • the propylene resin can be modified using organic peroxides. Examples of modifying polypropylene using organic peroxides is described in U.S. Patent no. 4,451 ,589 which is hereby incorporated by reference herein.
  • the present invention may start with a propylene polymer in the form of reactor granules which polymer has a molecular weight distribution of 3.6 to 4.8 M w /M n , advantageously 3.6 to 4.0 M w /M n and a melt flow rate of about 400 gms/10 min to 3000 gms/10 min at 230° C.
  • a molecular weight reactor granule polymer is then modified to reduce and narrow the polymer's molecular weight distribution to a range from 2.2 to 3.5 M w /M n by the addition of up to 3000 parts per million (ppm) of peroxide prodegradant.
  • the modified reactor granule polymer increases in melt flow rate from 400 gms/10 min. to 3000, for example, to a range between 800 up to 5000 gms/10 min at 230° C.
  • Particularly advantageous embodiments for disposable aborbent applications include a polypropylene resin in the form of a reactor granule having a starting molecular weight distribution of 3.6 to 4.8 M w /M n and a melt flow rate of from 600 to 3000 gms/10 min. at 230° C. which is combined with a small amount of peroxide prodegradant, less than 500 ppm, to produce a modified polypropylene having a very high melt flow rate of up to 5000 gms/10 min.
  • an improved fine fiber web for use as a barrier layer can be formed by utilizing a resin, particularly polypropylene, having a narrow molecular weight distribution and having a lower melt flow rate which resin is modified by the addition of a larger amount of peroxide prodegradant prior to melt-blowing to achieve a high melt flow rate.
  • the starting reactor granule polypropylene resin in this case has a molecular weight distribution between 4.0 and 4.8 M w /M n and a melt flow rate ranging from 400 to 1000 gms/10 min. at 230° C.
  • the polypropylene resin is modified by adding peroxide in amounts ranging from 500 to 3000 ppm (the higher amounts of peroxide being used in connection with the lower initial melt flow rate).
  • the modified polypropylene resin has a melt flow rate, up to about 3000 gms/10 min. at 230° C. and a narrow molecular weight distribution of 2.2 to 2.8 M w /M n , for example.
  • the starting polypropylene resin for the fine fiber web of the lightweight nonwoven laminate of the present invention may be a polypropylene reactor granule which resin has a molecular weight distribution between 3.6 and 4.8 M w /M n , has a melt flow rate of up to 3000 gms/10 min.
  • FIG. 1 there is shown schematically a forming machine 10 which may be used to produce a nonwoven fabric laminate 12 having a fine fiber meltblown layer 32 and outer continuous filaments spunbond layer 28 in accordance with the present invention.
  • the forming machine 10 includes of an endless foraminous forming belt 14 wrapped around rollers 16 and 18 so that the belt 14 is driven in the direction shown by the arrows.
  • the illustrated forming machine 10 has three stations: spunbond station 20, meltblown station 22, and spunbond station 24 to produce a spunbond/meltblown/spunbond (SMS) laminate as described in U.S. Patent no. 4,041 ,203 which is hereby incorporated by reference herein. It should be understood that more than three forming stations may be utilized to build up additional layers to produce a laminate of more layers or having a higher basis weight and each forming station can have multiple banks or dies. Alternatively, each of the laminate layers may be formed separately, rolled, and later converted to the fabric laminate off-line. In addition the fabric laminate 12 could be formed of more than or less than three layers depending on the requirements for the particular end use for the fabric laminate 12.
  • the spunbond stations 20 and 24 can be conventional extruders with spinnerets which form continuous filaments of a polymer and deposit those filaments onto the forming belt 14 in a random interlaced fashion.
  • the spunbond stations 20 and 24 may include one or more spinnerets heads depending on the speed of the process and the particular polymer or polymers being used. Forming spunbonded material is conventional in the art, and the design of such a spunbonded forming station is within the ability of those of ordinary skill in the art.
  • the nonwoven spunbonded webs 28 and 36 can be formed using known methods such as those described and illustrated in the following patents: U.S. Patent no. 3,692,618 to Dorschner et al.; U.S. Patent nos. 3,338,992 and 3,341 ,394 to Kinney; U.S. Patent no. 3,502,538 to Levy; U.S. Patent nos. 3,502,763 and 3,909,009 to Hartmann; U.S. Patent no. 3,542,615 to Dobo et al.; Canadian Patent no. 803,714 to Harmon; U.S. Patent no. 3,802,817 to Matsuki et al. and U.S. Patent no. 4,340,563 to Appel et al.
  • Spunbonded materials prepared with continuous filaments generally have at least three common features.
  • the polymer is continuously extruded through a spinneret to form discrete filaments.
  • the filaments are drawn either mechanically or pneumatically without breaking in order to molecularly orient the polymer filaments and achieve increased tenacity.
  • the continuous filaments are deposited in a substantially random manner onto a carrier belt to form a web and are then bonded to form a laminate.
  • the spunbond station 20 produces spunbond filaments 26 from a fiber forming polymer. The filaments are randomly laid on the belt 14 to form a spunbonded external layer 28.
  • the spunbonded layer can be optionally bonded.
  • the fiber forming polymer is described in greater detail below.
  • the meltblown station 22 consists of a die 31 which is used to form microfibers 30 having an average diameter in the range of up to about 8 microns or even as low as an average diameter in the range of about 5 microns, 2 microns and even as low as 1.5 microns.
  • Meltblown station 22 may consist of multiple meltblown die tips (not shown). For example, meltblown station 22 may include 2, 3, 4 or more die tips.
  • the throughput of the die 31 is specified in pounds of polymer melt per inch of die width per hour (PIH). As the thermoplastic polymer exits the die 31, high pressure fluid, usually heated air, attenuates and spreads the polymer stream to form microfibers 30.
  • PHI polymer melt per inch of die width per hour
  • the microfibers 30 are randomly deposited on top of the spunbond layer 28 and form a meltblown layer 32.
  • the distance between the die tip and the forming wire is typically between about 3 and 18 inches.
  • the short distance and the uniform spacing of holes in the die tip produce a very uniform fiber laydown that is desired for particle filtration performance.
  • the construction and operation of the meltblown station 22 for forming microfibers 30 and meltblown layer 32 is considered conventional, and the design and operation are well within the ability of those of ordinary skill in the art. Such skill is demonstrated by NRL Report 4364, "Manufacture of Super-Fine Organic Fibers", by V. A. Wendt, E. L. Boon, and C. D.
  • the meltblown station 22 produces fine fibers 30 from a fiber forming polymer which will be described in greater detail below.
  • the fibers 30 are randomly deposited on top of spunbond layer 28 to form a meltblown layer 32.
  • Meltblown layer 32 may be an internal fine fiber layer in a SMS laminate.
  • the meltblown barrier layer 32 may have a basis weight of less than about 2 gsm, more desirably less than about 1 gsm, even more desirably less than about 0.8 gsm, still even more desirably less than about 0.5 gsm and even as low as more desirably less than about 0.3 gsm.
  • the meltblown barrier layer 32 may have a basis weight of less than about 14 gsm, desirably less than 2 gsm, more desirably less than about 1 gsm, even more desirably less than about 0.8 gsm, still even more desirably less than about 0.5 gsm and even as low as more desirably less than about 0.3 gsm.
  • the layers 28 and 36 each have a basis weight of commonly from about 3 gsm to about 30 gsm, more advantageously about 5 gsm to about 20 gsm.
  • the polymer that is used to make the spunbond layers and the basis weight of the spunbond layers 28 and 36 may be the same or different.
  • the resulting SMS fabric laminate web 12, shown in greater detail in Figure 2 is then fed through bonding rolls 38 and 40.
  • the surfaces of one or both of the bonding rolls 38 and 40 are provided with a raised pattern such as spots or grids.
  • the bonding rolls are heated to the softening temperature of the polymer used to bond the layers of the web 12.
  • the material is compressed and heated by the bonding rolls in accordance with the pattern on the rolls to create a pattern of discrete areas, such as 41 shown in Figure 2, which areas are bonded from layer to layer and are bonded with respect to the particular filaments and/or fibers within each layer.
  • discrete area or spot bonding is well-known in the art and can be carried out as described by means of heated rolls or by means of ultrasonic heating of the web 12 to produced discrete area thermally bonded filaments, fibers, and layers.
  • Figure 3 is a cross-section similar to Figure 2 showing a two layer laminate 13 of the present invention which includes one fine fiber layer 32 and one continuous filament layer 36 combined by thermal bond 39.
  • the total basis weight of the laminate is in the range generally of up to about 55 gsm, more desirably less than about 34 gsm for applications such as liners and core wraps for absorbent product applications, still more desirably less than about 20 gsm and even less than 10 gsm for liner and core wrap applications.
  • the amount of fine fibers compared to continuous filaments is generally at least about 1 percent (by weight) generally and up to about 30 weight percent based on total weight of fine fiber layer and the continuous filament layer(s).
  • Laminates of the present invention include, but are not limited to: SMSMS, SSMS, SMMMS, and other possible multiple layer combinations of spunbond and meltblown banks.
  • a nonwoven fabric laminate of the present invention for example the three-layer laminate 12 illustrated and described with reference to Figure 2, a two-layer laminate 13 illustrated and described with reference to Figure 3 or a laminate of additional layers, may be used in a wide variety of applications, not the least of which includes personal care absorbent articles such as diapers, training pants, incontinence devices and feminine hygiene products such as sanitary napkins.
  • An exemplary article 80, in this case a diaper is shown generally in Figure 4 of the drawings. Other more complicated diaper constructions are known and are described and illustrated in greater detail in for example U.S. Patent no.
  • most such personal care absorbent articles 80 include a liquid permeable top sheet or liner 82, a back sheet or outercover 84 and an absorbent core 86 disposed between and contained by the top sheet 82 and back sheet 84.
  • Articles 80 such as diapers may also include some type of fastening means 88 such as adhesive fastening tapes or mechanical hook and loop type fasteners.
  • a nonwoven fabric laminate of the present invention by itself, or in other forms, such as a component in multilayer laminate including additional layers or some other composite structure, may be used to form various portions of the article including, but not limited to, the top sheet 82, as a wrap for the absorbent core 86 or a layer between the absorbent core 86 and the interior of the absorbent article 80, that is as a layer between the absorbent core 86 and a wearer of the article.
  • a laminate of the present invention is a wrap for the absorbent core 86 and/or the liner 82 portion of the diaper and can be formed completely from or include one of the laminates described herein to minimize the migration of particles from the absorbent core to the wearer's skin.
  • a laminate of the present invention is to be used as a top sheet 82, a core wrap material or as a layer between the absorbent core and a wearer, the laminate is desirably liquid permeable while retaining absorbent particles that may be contained in the absorbent core 86.
  • Absorbent particles may have diameters as small as 0.001 inches, therefore it would be desirable that the fine fiber layer of the laminate has holes no larger than 0.001 inches in diameter.
  • a theoretically, perfect laid down grid of one micron polypropylene fibers would act as a barrier for 0.001 inch particles at a basis weight of 0.06 gsm.
  • laminates of the present invention may include a fine fiber or meltblown layer having a basis weight of at least 0.06 grams per square meter (gsm). Laminates of the present invention with their fine fiber layers and resulting small pore size distribution can have superior particle retention and water permeability properties.
  • laminates of the present invention can be used as a wrap for the absorbent core of an absorbent article or as a layer between the absorbent core and the interior of the absorbent article.
  • laminates of the present invention may be substituted as the core wrap material in a diaper such as the core wrap material described in U.S. Patent no. 5,458,592 which is hereby incorporated be reference herein.
  • laminate materials of the present invention are particularly well-suited for containing absorbent cores which are made partially or completely from particulate matter such as superabsorbent particles.
  • the laminate of the present invention is particularly useful for reducing the migration of superabsorbent particles in articles that contain superabsorbent particles.
  • the laminate is particularly useful in articles having an absorbent portion that has a high superabsorbent particle content such as greater than 50 weight percent.
  • the present invention is not restricted to use with superabsorbent particles but any particulate material such as odor absorbing and ion exchange resin particles and controlled release agents such as moisturizers, emollients and perfumes which require retention.
  • a “superabsorbent” or “superabsorbent material” refers to a water-swellable organic or inorganic material capable, under the most favorable conditions, of absorbing at least about 20 times its weight and, more desirably, at least about 30 times its weight in an aqueous solution containing 0.9 weight percent sodium chloride.
  • Organic materials suitable for use as a superabsorbent material in conjunction with the present invention can include natural materials such as agar, pectin, guar gum, and so forth; as well as synthetic materials, such as synthetic hydrogel polymers.
  • Such hydrogel polymers include, for example, alkali metal salts of polyacrylic acids, polyacrylamides, polyvinyl alcohol, ethylene maleic anhydride copolymers, polyvinyl ethers, methyl cellulose, carboxymethyl cellulose, hydroxypropylcellulose, polyvinylmorpholinone; and polymers and copolymers of vinyl sulfonic acid, polyacrylates, polyacrylamides, polyvinylpyrridine, and so forth.
  • Other suitable polymers include hydrolyzed acrylonitrile grafted starch, acrylic acid grafted starch, and isobutylene maleic anhydride polymers and mixtures thereof.
  • the hydrogel polymers are preferably lightly crosslinked to render the materials substantially water insoluble.
  • Crosslinking may, for example, be accomplished by irradiation or by covalent, ionic, van der Waals, or hydrogen bonding.
  • the superabsorbent materials may be in any form suitable for use in absorbent composites including particles, fibers, flakes, spheres, and so forth. Such superabsorbents are usually available in particle sizes ranging from about 20 to about 1000 microns.
  • the absorbent core 86 can contain from 0 to 100 percent superabsorbent by weight based upon the total weight of the absorbent core.
  • an absorbent core 86 for a personal care absorbent product will include superabsorbent particles and, optionally, additional absorbent material such as absorbent fibers including, but not limited to, wood pulp fluff fibers, synthetic wood pulp fibers, synthetic fibers and combinations of the foregoing.
  • Wood pulp fluff such as CR-1654 wood pulp available from Bowater Incorporated of Greenville, South Carolina is an effective absorbent supplement.
  • a common problem with wood pulp fluff, however, is its lack of integrity and its tendency to collapse when wet.
  • it is often advantageous to add a stiffer reinforcing fiber into the absorbent core such as polyolefin meltblown fibers or shorter length staple fibers.
  • Such combinations of fibers are sometimes referred to as "coform".
  • meltblown fibers and combinations of meltblown fibers with superabsorbents and/or wood pulp fibers are well known.
  • meltblown webs are made from fibers formed by extruding a molten thermoplastic material through a plurality of fine, usually circular dye capillaries as molten threads or filaments into a high-velocity heated air stream which attenuates the filaments of molten thermoplastic material to reduce their diameters.
  • Shaped and/or multicomponent fibers may also be used.
  • the meltblown fibers are carried by the high-velocity gas stream and are deposited on a collecting surface to form a web of randomly dispersed meltblown fibers.
  • meltblown process is well known and is described in various patents and publications, including NRL Report 4364, "Manufacture of Super-Fine Organic Fibers” by V. A. Wendt, E. L.. Boone and C. D. Fluharty; NRL Report 5265, "An Improved Device For the Formation of Super-Fine Thermoplastic Fibers” by K. D. Lawrence, R. T. Lukas and J. A. Young; and U.S. Patent no. 3,849,241 , issued Nov. 19, 1974 to Buntin et al.
  • additional components are mixed with the meltblown fibers as the fibers are deposited onto a forming surface.
  • superabsorbent particles and/or staple fibers and/or wood pulp fibers may be injected into the meltblown fiber stream so as to be entrapped and/or bonded to the meltblown fibers.
  • U.S. Patent no. 4,100,324 to Anderson et al. U.S. Patent no. 4,587,154 to Hotchkiss et al.
  • Laminates of the present invention that are intended to be used as a core wrap material or as a bodyside liner can be designed and formed to include a fibrous nonwoven web layer made from fine diameter thermoplastic fibers with particular pore sizes and air permeability.
  • thermoplastic fibers it is meant fibers which are formed from polymers such that the fibers can be bonded to themselves using heat or heat and pressure. While not being limited to the specific method of manufacture, meltblown fibrous nonwoven webs have been found to work particularly well. With respect to polymer selection, polyolefin fibers and especially polypropylene-based polymers have been found to work well. The general manufacture of such meltblown fibrous nonwoven webs is well known. See for example, the previously mentioned meltblown patents referred to above.
  • the fibers may be hydrophilic or hydrophobic, though it is desirable that the resultant web, bodyside liner and core wrap be hydrophilic.
  • the fibers may be formed from inherently wettable resins, such as polylactic acid, polyvinyl alcohol resins or polyesters, or can be treated to be hydrophilic as by the use of a surfactant treatment.
  • the meltblown web In order to function well as a core wrap, the meltblown web should have certain specific properties.
  • a common problem with paper tissue wrap is that it has inadequate strength in the wet state. Typically a paper tissue wrap will have a wet to dry strength ratio in either the machine direction (MD) or cross-machine direction (CD) as measured by the test method outlined below of less than 0.5.
  • a absorbent core wrap of the present invention illustrated as layer 54 in Figures 5, 5A, 5B and 5C, should have wet to dry strength ratios above 0.5 and sometimes 1.0 or higher.
  • Figure 5 illustrates a an absorbent core 52 that is wrapped or otherwise enveloped by a laminate of the present invention to form a wrapped absorbent core 50 that can be used as an absorbent portion of a diaper, for example, that does not release absorbent particles on the wearer.
  • the laminate wrap material 54 may be simply folded around the absorbent core 52 as illustrated in cross-sectional Figure 5A, wrapped and bonded around one edge, as illustrated in Figure 5B, two layers bonded around the absorbent core 52 as illustrated in Figure 5C or unsealed.
  • the laminate may be included as an additional layer in between the absorbent portion of an absorbent article and the skin contacting or body sideliner of the absorbent article.
  • a two-layer nonwoven laminate such as that illustrated in Figure 3 as the top sheet 82
  • laminates of the present invention can be used in other absorbent articles including, but not limited to, incontinence garments, pantiliners and so forth.
  • a laminate of the present invention is surface treated with one or more surfactants to improve the wettability of the laminate.
  • One commercially available surfactant that can be used to surface treat a laminate of the present invention can be obtained from Union Carbide Chemicals and Plastics Company, Inc., of Danbury,
  • the fabric laminate may be surface treated with about 0.3 weight percent of a surfactant mixture that contains a mixture of AHCOVEL Base N-62 and GLUCOPON 220 UP surfactant in a 3:1 ratio based on a total weight of the surfactant mixture.
  • AHCOVEL Base N-62 can be obtained from Uniqema Inc., a business having offices in New Castle, Delaware, and includes a blend of hydrogenated ethoxylated castor oil and sorbitan monooleate.
  • GLUCOPON 220 UP can be obtained from Cognis Corporation, a business having offices in Ambler, Pennsylvania, and includes alkyl polyglycoside.
  • the surfactant may be applied by any conventional means, such as dip and squeeze, spraying, printing, brush coating or the like.
  • the surfactant may be applied to the entire laminate or may be selectively applied to particular sections of the laminate, such as the medial section along the longitudinal centerline of a diaper or other personal care product, to provide greater wettability of such sections.
  • Exemplary surface treatment compositions and methods of applying surface treatment compositions are described in U.S. Patent nos. 5,057,361 ; 5,683,610 and 6,028,016 which also are hereby incorporated by reference herein. Run-off Test Procedure All run-off data reported herein were obtained using the following run off test.
  • a sheet of the material measuring 325 mm long, in the machine direction, and 150 mm wide is laid against the absorbent of a HUGGIES® brand diaper size 3.
  • the test material is smoothed out on the absorbent by rubbing it lengthwise 3 times with a downward hand motion.
  • the test material functions as a core wrap or a liner and particle barrier between the absorbent and anything above the absorbent, for example a baby's bottom.
  • the absorbent was obtained from a diaper which had its inner body side liner and surge layer removed. Note that in some cases a surge layer that had been removed from the diaper was laid on top of the absorbent before the liner was applied.
  • any elastic leg, flap, and elastic waist material was also removed so that the absorbent will assume a generally flat configuration.
  • the polyethylene film backing and tissue top cover are left on the absorbent to give it integrity so that it can be handled.
  • the absorbent is cut to about 100 mm wide and 300 mm long. The 300 mm is measured from the front, top end of the diaper absorbent and the excess cut off.
  • the absorbent Prior to placement of the test material on top of the absorbent, the absorbent is placed, film side down, on a water impervious plane inclined at 30 degrees to horizontal and terminating, at its lower edge, with a V-shaped raised edge which directs any fluid impacting the raised edge toward a hole in the plane which is centrally located at the vertex of the "V".
  • a 250 milliliter beaker is located beneath the hole to collect any fluid passing therethrough.
  • the absorbent is positioned on the inclined plane so that the top of the front panel (the uncut end) constitutes its upper free edge on the inclined plane.
  • the lower free edge is located approximately 200 millimeters from the point of impact of testing fluid.
  • a funnel arrangement with a stopcock is positioned above the diaper approximately 200 millimeters from the lower free edge of the absorbent and in such manner that an approximate 50 millimeter clearance exists between the top of the absorbent and the lower tip of the funnel.
  • the lower free edge of the absorbent is located approximately 50 millimeters up the incline from the hole in the inclined plane.
  • the test material is positioned over the absorbent so that it overhangs it by about 25 millimeters.
  • SAM Superabsorbent Material
  • a SMS fabric laminate (80 percent SB and 20 percent MB) was produced by forming and laminating a first 0.14 (4.75 gsm) osy spunbond layer, a 0.07 osy (2.4 gsm) meltblown layer, and a second 0.14 osy spunbond layer at a line speed of about 1996 feet per minute (fpm).
  • the SMS laminate having an overall basis weight 0.35 osy (1.9 gsm) was and was heated online with a Hot Air Knife (HAK) at 435° F as described in U.S. Patent no. 6,019,152 and then thermally bonded using a wire weave bond pattern.
  • HAK Hot Air Knife
  • the SMS laminate was surface treated off-line with an aqueous treatment solution consisting of water and about 0.3 weight percent of a surfactant mixture that consisted of a mixture of AHCOVEL Base N-62 and GLUCOPON 220 UP surfactant at a 3:1 ratio based on a total weight of the surfactant mixture using the dip and squeeze method and targeting an 80 percent wet pick-up value.
  • the 0.35 osy laminate was tested using the SAM shake test.
  • the 0.35 osy SMS laminate achieved a 99.6 percent SAM retention level using the SAM shake test.
  • a control example of a conventional spunbond liners at 0.6 osy achieved about 83 percent SAM retention level using the SAM shake test.
  • the 0.35 osy SMS laminate of Example 1 provides superior particle retention properties.
  • the 0.35 osy SMS laminate of Example 1 was also tested for Run-Off using the above-described procedure measured 1.9 grams of run-off without the surge layer and 1.5 grams of run-off with the surge layer.
  • the control example of a conventional necked spunbond liners of about 0.6 osy measured 7.9 grams of run-off without the surge layer and 17.9 grams of run-off with the surge layer. A run-off of less than 50 grams is acceptable and a run-off of less than 20 grams is desired.
  • SMS fabric laminate 80 percent SB and 20 percent MB was produced by forming and laminating a first 0.18 osy (6.1 gsm) spunbond layer, a 0.09 osy (3.0 gsm) meltblown layer, and a second 0.18 osy spunbond layer at a line speed of about 1843 fpm.
  • the necked SMS laminate had an overall basis weight 0.45 osy (15.3 gsm).
  • This SMS laminate was also surface treated with an aqueous treatment solution consisting of water and about 0.3 weight percent of a surfactant mixture that consisted of a mixture of AHCOVEL Base N-62 and GLUCOPON 220 UP surfactant at a 3:1 ratio based on a total weight of the surfactant mixture using the dip and squeeze method and targeting an 80 percent wet pick-up value.
  • a surfactant mixture that consisted of a mixture of AHCOVEL Base N-62 and GLUCOPON 220 UP surfactant at a 3:1 ratio based on a total weight of the surfactant mixture using the dip and squeeze method and targeting an 80 percent wet pick-up value.
  • the 0.45 osy laminate was tested using the SAM shake test.
  • the 0.45 osy SMS laminate of Example 2 achieved a 100 percent SAM retention level using the SAM shake test.
  • the 0.45 osy SMS laminate of Example 2 was also tested for Run-Off using the above-described procedure and measured 2.3 grams of run-off without the surge layer and 4.9 grams of run-off with the surge layer.
  • EXAMPLE 3 A SMS fabric laminate (90 percent SB and 10 percent MB) was produced by forming and laminating a first 0.1575 osy (5.3 gsm) spunbond layer, a 0.035 osy (1.2 gsm) meltblown layer, and a second 0.1575 osy spunbond layer at a line speed of about 1996 fpm.
  • the necked SMS laminate had an overall basis weight 0.35 osy (11.9 gsm).
  • This SMS laminate of Example 3 was also surface treated with the same treatment solution using the dip and squeeze method at a targeting 80 percent wet pick-up.
  • the 0.35 osy laminate was tested using the SAM shake test.
  • the 0.35 osy SMS laminate of Example 3 achieved a 98.8 percent SAM retention level using the SAM shake test.
  • the 0.35 osy SMS laminate of Example 3 was also tested for Run-Off using the above-described procedure and measured 0.9 grams of run-off without the surge layer and 0.7 grams of run-off with the surge layer.
  • SMS fabric laminate (90 percent SB and 10 percent MB) was produced by forming and laminating a first 0.2025 osy (6.9 gsm) spunbond layer, a 0.045 osy (1.5 gsm) meltblown layer, and a second 0.2025 osy spunbond layer at a line speed of about 1552 fpm.
  • the necked SMS laminate had an overall basis weight 0.45 osy 15.3 gsm).
  • This SMS laminate of Example 4 was also surface treated with the same treatment solution using the dip and squeeze method at a targeting 80 percent wet pick-up.
  • the 0.45 osy SMS laminate of Example 4 achieved a 99.6 percent SAM retention level using the SAM shake test.
  • the 0.45 osy SMS laminate of Example 4 was also tested for Run-Off using the above-described procedure and measured 1.0 grams of runoff without the surge layer and 1.3 grams of run-off with the surge layer.
  • EXAMPLE 5 A necked SMS fabric laminate with a wire weave bond pattern was produced having a first 0.3375 osy (11.4 gsm) spunbond layer, a 0.072 osy (2.4 gsm) meltblown layer, and a second 0.3375 osy spunbond layer.
  • the necked SMS laminate had an overall basis weight 0.72 osy and was necked at 27 percent, i.e. to 83 % of its unnecked width.
  • the SMS laminate was surface treated with an aqueous foam treatment solution consisting of water and about 20 weight percent of a surfactant mixture that consisted of a mixture of AHCOVEL Base N-62 and GLUCOPON 220 UP surfactant at a 3:1 ratio based on a total weight of the surfactant mixture using the dip and squeeze method and targeting an 80 percent wet pick-up value.
  • the 0.72 osy laminate was tested using the SAM shake test.
  • the 0.72 osy SMS laminate achieved a 99.6 percent SAM retention level using the SAM shake test.
  • current necked spunbond liners achieve about 80 percent SAM retention level using the SAM shake test.
  • the 0.72 osy SMS laminate of Example 5 provides superior particle retention properties.
  • the 0.72 osy SMS laminate of Example 5 was tested for CD extensibility using a Sintec Tensile Tester using a 3 inch wide sample and a jaw separation of 3 inches.
  • the 0.72 osy SMS laminate of Example 5 had 40 percent extension at 79 grams. It is understood by one of ordinary skill in the art that the present discussion is a description of exemplary embodiments only, and is not intended as limiting the broader aspects of the present invention, which broader aspects are embodied in the exemplary constructions. The invention is shown by example in the appended claims.

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  • Epidemiology (AREA)
  • Engineering & Computer Science (AREA)
  • Biomedical Technology (AREA)
  • Heart & Thoracic Surgery (AREA)
  • Vascular Medicine (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Absorbent Articles And Supports Therefor (AREA)
  • Nonwoven Fabrics (AREA)

Abstract

La présente invention se rapporte à un lamellé textile non-tissé qui comporte une couche mince de fibres fines ayant un poids de base inférieur à 1,5 grammes par m2. La présente invention se rapporte également à des vêtements absorbants jetables, tels que des couches-culottes, qui comportent un tel lamellé textile non-tissé pour réduire la migration des particules dans les vêtements absorbants.
PCT/US2004/024310 2003-09-08 2004-07-26 Lamelle textile non-tisse reduisant la migration des particules et couche-culotte comportant un tel lamelle WO2005025854A1 (fr)

Applications Claiming Priority (4)

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US10/657,622 US20050054255A1 (en) 2003-09-08 2003-09-08 Nonwoven fabric liner and diaper including a nonwoven laminate liner
US10/657,498 US20050054999A1 (en) 2003-09-08 2003-09-08 Nonwoven fabric laminate that reduces particle migration
US10/657,498 2003-09-08
US10/657,622 2003-09-08

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2513246A (en) * 2013-03-15 2014-10-22 Procter & Gamble Nonwoven substrates
WO2021028925A1 (fr) * 2019-08-15 2021-02-18 Avgol Ltd. Substrat non-tissé à effet haute barrière

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5458592A (en) * 1994-06-30 1995-10-17 Kimberly-Clark Corporation Thermoplastic fibrous nonwoven webs for use as core wraps in absorbent articles
US5620785A (en) * 1995-06-07 1997-04-15 Fiberweb North America, Inc. Meltblown barrier webs and processes of making same
WO1999006207A1 (fr) * 1997-07-29 1999-02-11 Bba Nonwovens Simpsonville, Inc. Textile non tisse, souple, fabrique par extrusion de matiere fondue
EP1073390A1 (fr) * 1998-04-22 2001-02-07 The Procter & Gamble Company Structures absorbantes a fort pouvoir d'aspiration de liquides

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5458592A (en) * 1994-06-30 1995-10-17 Kimberly-Clark Corporation Thermoplastic fibrous nonwoven webs for use as core wraps in absorbent articles
US5620785A (en) * 1995-06-07 1997-04-15 Fiberweb North America, Inc. Meltblown barrier webs and processes of making same
WO1999006207A1 (fr) * 1997-07-29 1999-02-11 Bba Nonwovens Simpsonville, Inc. Textile non tisse, souple, fabrique par extrusion de matiere fondue
EP1073390A1 (fr) * 1998-04-22 2001-02-07 The Procter & Gamble Company Structures absorbantes a fort pouvoir d'aspiration de liquides

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2513246A (en) * 2013-03-15 2014-10-22 Procter & Gamble Nonwoven substrates
GB2513246B (en) * 2013-03-15 2015-12-09 Procter & Gamble Absorbent article nonwoven substrates
WO2021028925A1 (fr) * 2019-08-15 2021-02-18 Avgol Ltd. Substrat non-tissé à effet haute barrière

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