WO2005011991A1 - Tampon pour art sur ongles - Google Patents

Tampon pour art sur ongles Download PDF

Info

Publication number
WO2005011991A1
WO2005011991A1 PCT/JP2004/008093 JP2004008093W WO2005011991A1 WO 2005011991 A1 WO2005011991 A1 WO 2005011991A1 JP 2004008093 W JP2004008093 W JP 2004008093W WO 2005011991 A1 WO2005011991 A1 WO 2005011991A1
Authority
WO
WIPO (PCT)
Prior art keywords
nail
ink
mark
handle
holder
Prior art date
Application number
PCT/JP2004/008093
Other languages
English (en)
Japanese (ja)
Inventor
Yutaka Watanabe
Original Assignee
Yutaka Watanabe
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Yutaka Watanabe filed Critical Yutaka Watanabe
Publication of WO2005011991A1 publication Critical patent/WO2005011991A1/fr

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41K—STAMPS; STAMPING OR NUMBERING APPARATUS OR DEVICES
    • B41K1/00—Portable hand-operated devices without means for supporting or locating the articles to be stamped, i.e. hand stamps; Inking devices or other accessories therefor
    • B41K1/36—Details
    • B41K1/38—Inking devices; Stamping surfaces
    • B41K1/50—Stamping surfaces impregnated with ink, or made of material leaving a mark after stamping contact
    • A—HUMAN NECESSITIES
    • A45—HAND OR TRAVELLING ARTICLES
    • A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D29/00—Manicuring or pedicuring implements
    • A—HUMAN NECESSITIES
    • A45—HAND OR TRAVELLING ARTICLES
    • A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D34/00—Containers or accessories specially adapted for handling liquid toiletry or cosmetic substances, e.g. perfumes
    • A45D34/04—Appliances specially adapted for applying liquid, e.g. using roller or ball
    • A45D34/042—Appliances specially adapted for applying liquid, e.g. using roller or ball using a brush or the like
    • A45D34/043—Appliances specially adapted for applying liquid, e.g. using roller or ball using a brush or the like movable within the container
    • A—HUMAN NECESSITIES
    • A45—HAND OR TRAVELLING ARTICLES
    • A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D2200/00—Details not otherwise provided for in A45D
    • A45D2200/10—Details of applicators
    • A45D2200/1009—Applicators comprising a pad, tissue, sponge, or the like
    • A45D2200/1018—Applicators comprising a pad, tissue, sponge, or the like comprising a pad, i.e. a cushion-like mass of soft material, with or without gripping means

Definitions

  • the present invention relates to a nail art stamp that can be easily stamped by repeating a pattern on the surface of a nail.
  • a stamp base having a concave portion for positioning by placing a finger on the upper surface, The stamp body is pressed against the nail surface of the finger, thereby transferring a nail art image to the nail surface.
  • the stamp body is positioned on the stamp base and guides the stamp body to move up.
  • a nail-art stamping device including a guide frame that guides the nail to an appropriate position with respect to the nail surface has been proposed.
  • An object of the present invention is to provide a nail stamp for repeatedly and easily drawing a pattern on a nail surface. Disclosure of the invention
  • a penetrating mark made of a porous elastic body is provided at the tip of a handle, and the penetrating mark can absorb and hold the nail, and a nail pattern having a pattern shape is formed on the stamped surface of the penetrating mark.
  • An object of the present invention is to provide a stamp for nail art that has a seepage portion and can be repeatedly stamped.
  • the present invention also provides a nail art stamp in which the nail ink seeping portion of the pattern in the nail art stamp is a convex protrusion of the pattern shape.
  • the present invention also provides a nail art stamp in which the penetrating mark is provided between the tip of the handle and the penetrating mark via a holding tool.
  • the present invention provides the nail art stamp, wherein the body of the holder is thinner than the thickness of the handle.
  • the present invention also provides a nail art stamp in which a penetrating mark is provided at the tip of a handle via a cushioning material in the nail art stamp.
  • the present invention also provides the nail art stamp, wherein the cushioning material is a sponge-like elastic body and the penetrating mark is attached to the cushioning material via an adhesive layer.
  • the present invention also provides a nail art stamp in which a weight is built in a holder in the nail art stamp.
  • the present invention also provides a nail art stamp in which the permeation mark absorbs and holds nail ink.
  • FIG. 1 shows a perspective view of one embodiment of the nail art stamp of the present invention.
  • FIG. 2 shows one embodiment of the nail art stamp of the present invention in which the handle, the holder and the cap are separated.
  • Fig. 3 shows a cross-sectional view of the nail art stamp of Fig. 2 by moving the handle of the nail art stamp in the direction of the arrow to connect it to the holder, and keeping the cap separated.
  • FIGS. 4a and 5a are schematic cross-sectional views of one embodiment of the nail art stamp of the present invention
  • FIGS. 4b and 5b are plan views of the penetration mark.
  • FIG. 6 is a schematic cross-sectional view of one embodiment of the nail art stamp of the present invention. It is.
  • the arrow in the plan view of the penetration mark indicates that the cross section of the arrow is a schematic cross-sectional view of the upper part.
  • the permeation mark 3 is made of a porous elastic material.
  • the porous elastic body can absorb and hold the nail ink.
  • the penetrating mark 3 has a pattern-shaped nail ink seeping portion on the sign surface. Thereby, when the penetrating mark 3 is pressed against the surface of the nail, the nail ink can seep out from the nail-ink seeping portion in the pattern formed on the stamp face. In order to perform this function, each hole in the porous elastic body needs to communicate with each other.
  • the diameter of each hole is not particularly limited, but the average diameter of the holes is preferably from 1 to 100 m, more preferably from 6 to 50 ⁇ m, more preferably from 12 to 30 Aim, and from 15 to Especially preferred is 25m.
  • the most suitable porous elastic body is a continuous foamed porous elastic body.
  • the porous elastic body of the penetration mark 3 needs to have a capacity capable of absorbing and holding nail ink as much as possible by repeatedly stamping the pattern on the surface of the nail, and preferably having a capacity of 30 times or more. It is a capacity that can be repeatedly stamped, particularly preferably 50 times or more. Further, the upper limit of the capacity is preferably a capacity that can be stamped repeatedly 200 times or less, more preferably a capacity that can be stamped repeatedly 150 times or less, and a capacity that can be stamped repeatedly 120 times or less. Is particularly preferred. If the capacity is too large, problems will arise if the long-term shelf life of the nail is poor.
  • the thickness of the porous elastic body of the penetration mark 3 is preferably 0.1 to 10 mm, more preferably 0.3 to 5 mm, and particularly preferably 0.5 to 2.5 mm.
  • the porous elastic body of osmotic seal 3 is manufactured from one or a mixture of natural rubber, synthetic rubber and thermoplastic elastomer, and a mixture of natural rubber and synthetic rubber or thermoplastic elastomer is preferred. No.
  • thermoplastic elastomers include polyolefin-based thermoplastic elastomers, chlorinated polyethylene-based thermoplastic elastomers, polystyrene-based thermoplastic elastomers, polyurethane-based thermoplastic elastomers, polyester-based thermoplastic elastomers, and polyamide-based thermoplastics. And plastic elastomers. Among these, a polyolefin-based thermoplastic elastomer is preferred, and a polyethylene-based thermoplastic elastomer is particularly preferred.
  • the porous elastic body of the permeation mark 3 can be obtained by mixing a foaming agent into the above rubber or thermoplastic elastomer or a precursor thereof and foaming the mixture.
  • a method of obtaining continuous cells by destroying cells using a needle punch or the like in a foam having closed cells and a method disclosed in Japanese Patent Publication No. 47-39212,
  • a method of treating an elastomer with a polysulfide thermoplastic elastomer or a calcium sulfite or an elastomer with a polyolefin thermoplastic elastomer with an inorganic acid that dissolves calcium sulfite or sulfuric acid Japanese Patent Publication No. 57-426 As described in No.
  • the nail-ink exudes from the nail-ink exuding part of the penetrating mark 3 and adheres to the nail surface to form a pattern. Therefore, the nail ink seeping portion on the seal face of the penetration mark 3 has a pattern shape.
  • the pattern can be of various shapes, such as letters, symbols, lines, marks or one or a combination of two or more thereof.
  • patterns include heart marks, stars, human faces, lips, eyes, heads, hands, fingers, feet, etc., plants such as flowers, leaves, trees, grass, dogs, cats, egrets, birds, etc.
  • Various patterns such as animals, statues, buildings, towers, and other structures.
  • the maximum size of the pattern is preferably in the range of 1 to 10 mm, and particularly preferably in the range of 1 to 5 mm.
  • the surface of the penetrating mark 3 may be flat, but it is preferable that the protrusion 2 be provided in a convex shape. It is preferable that the tip of the convex protrusion 2 is flat. Its convex The flat portion at the tip of the projection 2 may be formed into a pattern.
  • the thickness of the convex protrusion is preferably from 0.01 to 2 mm, more preferably from 0.02 to 0.5 mm. If the thickness of the convex protrusion is too large, the nail is curved and slippery, and the pattern is displaced when stamped on the nail, which is not preferable.
  • the place where the nail ink seeps out from the penetrating mark 3 is only the flat part at the tip of the convex protrusion 2. That is, it is preferable that the surface of the penetrating mark 3 where the convex protrusion 2 is not provided closes the hole of the porous elastic body so that the nail does not seep out. Further, it is preferable that the side surfaces of the convex protrusions 2 also close the pores of the porous elastic body so that the nail ink does not seep out.
  • the surface of the penetrating mark 3 other than the nail ink seeping portion of the pattern is made of a porous elastic material so that the nail ink does not seep out. It is preferable to close the holes in the body. As a result, the nail blinks out only from the pattern portion, and a clear pattern can be formed on the nail.
  • the method of closing the pores of the porous elastic body is to cover the surface of the porous elastic body by a method such as covering with a non-porous film, plate making by thermal head, plate making by flash flash, or thermal transfer method.
  • a method of closing a hole and the like can be mentioned.
  • the plate making process using flash flash is performed by irradiating the surface of the porous elastic body with light such as infrared light and causing the heating material to generate heat so that it is a mirror image and negative to the pattern shape. By melting the surface layer, a non-neilid exuding part and a nail exuding part are formed.
  • the plate making process using a flash light for example, light is applied to the surface of a porous elastic body in which a black pigment such as carbon black is previously blended or a layer containing the black pigment is laminated on the surface in advance. And a method in which a black pigment is heated to melt the surface of the porous elastic body to produce a permeation mark made of the porous elastic body in which open cells are closed.
  • a black pigment instead of the black pigment, another heating material that generates heat by light emitted from a light source can be used.
  • Other heat generating materials include, for example, phthalocyanine pigments described in JP-A-9-1314972.
  • a composition containing a black pigment, a resin component and, if necessary, a diluent is added to the surface of the porous elastic body. It can be formed by coating and drying if necessary.
  • the resin component examples include a resin component used for an ordinary adhesive.
  • the resin component preferably has no adhesiveness after light irradiation.
  • the penetrating mark 3 may be directly attached to the tip of the handle 1. Alternatively, the penetrating mark 3 may be held by the holder 5 of the penetrating mark 3 and the holder 5 may be attached to the tip of the handle 1. When the holder 5 is provided, the handle 1 and the permeable mark 3 can be easily attached.
  • the holder 5 has a mounting portion 7 for the handle 1 and a mounting portion 6 for the penetration mark 3.
  • the holder 5 may be formed integrally with the handle 1. When integrally formed, the holder 5 does not have the attachment portion 7 to the handle 1.
  • the handle 1 preferably has a shape that is easy to hold, and examples thereof include polygonal cylinders such as cylinders, square cylinders, pentagonal cylinders, hexagonal cylinders, and octagonal cylinders.
  • the length of the cross section, that is, the thickness, of the handle 1 is preferably such that the maximum length is in the range of 5 to 30 mm, particularly preferably in the range of 6 to 15 mm.
  • the material of the handle 1 can be various materials, but a hard material is preferable, and examples thereof include plastics such as thermoplastics and thermosetting plastics, and metals such as iron, aluminum, and aluminum alloy.
  • plastics such as thermoplastics and thermosetting plastics, and metals such as iron, aluminum, and aluminum alloy.
  • thermoplastic plastic include polystyrene resins, ABS resins, (meth) acrylic resins, polyolefin resins such as polypropylene resins, polyester resins, polyamide resins, and polycarbonate resins.
  • the handle 1 may be colored or transparent.
  • the material of the cap 13 is the same as the material of the handle 1.
  • the attachment of the holder 5 to the handle 1 may be made approximately the same as the outer diameter of the holder 5 and the inner diameter of the cylindrical handle 1, and the two may be fitted together and tightly fixed.
  • the thread may be provided with a thread 15 as shown in the illustration, or the surfaces of the retainer 5 and the nose or handle 1 may be made of a material having a high frictional force so that they are closely fitted and fixed to each other. .
  • the width of the groove is preferably from 0.5 to 2 mm, particularly preferably from 0.8 to 1.5 mm.
  • the depth of the groove is preferably from 0.0 l to l mm, particularly preferably from 0.5 to 0.5 mm.
  • the holder 5 preferably has a trunk portion 8.
  • the body 8 of the holder 5 includes, for example, polygonal cylinders such as cylinders, square cylinders, pentagonal cylinders, hexagonal cylinders, and octagonal cylinders, and polygonal columns such as cylinders, square pillars, pentagonal pillars, hexagonal pillars, and octagonal pillars.
  • the shape is preferably the same as that of the pattern 1.
  • the body 8 of the holder 5 is preferably thinner than the handle 1. If the body 8 of the holder 5 is thick, it may not be possible to clearly recognize the position where the pattern is to be applied when stamping the nail visually from above the handle 1.
  • the body 8 of the holder 5 By making the body 8 of the holder 5 thin, there is an advantage that the position where the pattern is to be applied when the nail is stamped can be clearly recognized from above the handle 1.
  • the degree of thinning is preferably 5 to 50% smaller than the thickness of the handle 1, and particularly preferably 10 to 40% thinner.
  • the body 8 of the holder 5 may have the same thickness as the handle 1.
  • the maximum length of the transverse section, that is, the thickness, of the body section 8 of the holder 5 is preferably 5 to 30 mm, and particularly preferably 6 to 15 mm.
  • the length of the body 8 of the holder 5 is preferably from 5 to 50 mm, particularly preferably from 10 to 35 mm.
  • the weight from the half of the entire length of the nail art stamp to the tip is made heavier than the other half.
  • the weight 14 is usually preferably 1 to 20 g, more preferably 2 to 10 g, and particularly preferably 3 to 7 g.
  • the material of the weight 14 is preferably a metal such as iron, stainless steel, steel, or nickel.
  • the shape of the mounting portion 6 of the penetrating mark 3 of the holder 5 may be a flat surface or a concave depression. It may be.
  • an adhesive As the adhesive, various adhesives can be used, and the same adhesive as described later can be used.
  • the penetrating mark 3 and the holder 5 are attached via the cushioning material 4 as shown in FIG. 4a.
  • the shape of the mounting portion 6 of the penetrating mark 3 of the holder 5 is preferably a concave depression, and all or a part of the cushioning material 4 is more preferably housed in the concave depression. Is preferred.
  • the cross-sectional shape of the concave depression is preferably the same as the cross-sectional shape of the buffer material 4.
  • the bottom surface of the concave depression is preferably flat.
  • the depth of the concave depression is preferably from 1 to 1 Omm, more preferably from 1 to 6 mm, and particularly preferably from 1 to 4 mm! /.
  • the attachment of the penetrating mark 3 and the holder 5 or the buffer 4 and the attachment of the buffer 4 and the holder 5 are preferably performed by fixing with an adhesive.
  • an elastic body is preferable.
  • the elastic body a foamed elastic body is preferable, and a sponge-like elastic body is particularly preferable.
  • the foamed elastic body or the sponge-shaped elastic body is preferably a porous body having a continuous porous structure.
  • Preferred examples of the component constituting the elastic body include chloroprene rubber, ethylene-propylene rubber, polyurethane rubber, acryl rubber, styrene-butadiene rubber, butyl rubber, and thermoplastic elastomer.
  • the planar shape of the cross section of the cushioning material 4 is preferably the same as the shape of the penetration mark 3. Therefore, it is preferable that the size of the planar shape of the cushioning material 4 be the same as the shape of the penetrating mark 3.
  • the thickness of the cushioning material 4 is preferably 1 to 20 mm, more preferably 5 to 15 mm. Particularly preferred is 113 mm.
  • the cushioning material 4 be crushed and shrunk when a force is applied.
  • the cushioning material 4, which is crushed and shrunk can reliably apply the nail art pattern to the curved nail surface when stamping the nail with the nail art stamp. Then, when the nail art stamp is released from the nail, the cushioning material 4 that has been crushed and shrunk returns to its original shape.
  • the extent to which the cushioning material 4 is crushed and shrunk is preferably 20 to 90% of the thickness in a state where no force is applied when the nail is actually stamped with a nail art stamp, and 30 to 7%. 0% is particularly preferred.
  • the shrinking length is preferably 1 to 7 mm, 1.5 to 5 mm is more preferable, and 1.5 to 4 mm is particularly preferable.
  • the penetration mark 3 may be adhered through an adhesive layer, or may be adhered by heat fusion or the like. When the penetrating mark 3 is adhered to the buffer material 4 via the adhesive layer, it is possible to prevent the nail ink impregnated in the penetrating mark from permeating the buffer material 4.
  • Various adhesives can be used as the adhesive used for the adhesive layer, for example, acrylic resin-based adhesive, polyolefin resin-based adhesive, polyurethane resin-based adhesive, melamine resin-based adhesive, epoxy Examples include resin adhesives, polyester adhesives, polyamide adhesives, phenolic resin adhesives, vinyl acetate resin adhesives, and polyvinyl alcohol adhesives.
  • the thickness of the adhesive is not particularly limited, but is preferably 1 to 200 ⁇ m, more preferably 1 to 100 ⁇ , and particularly preferably 3 to 50 ⁇ m.
  • the buffer material 4 does not soak or hardly soaks the nail ink. That is, it is preferable that the nail ink is impregnated only into the porous elastic body constituting the penetration mark 3. If the nail ink soaks into the cushioning material 4, the nail ink soaked into the cushioning material 4 may ooze out and adhere to the nails when the nail art is stamped on the nails. Absent.
  • the length of the cushioning material 4 is usually preferably 1 to 30 mm, and particularly preferably 3 to 22 mm.
  • the cushioning material 4 with the penetrating mark 3 is applied from the tip of the handle 1 when attaching to the handle 1 only without passing through the holder 5, or from the tip of the holder 5 when attaching the holder 5 to the handle 1. It is preferable to mount so as to protrude, and the protruding length is usually 1 to 2 Omm, and 3 to 15 mm is particularly preferable.
  • the length from the top of the handle 1 to the tip of the penetrating mark 3 is preferably 3 to 30 cm, and particularly preferably 5 to 20 cm.
  • the penetrating mark 3 or the penetrating mark 3 and the cushioning material 4 are preferably provided with a cap 13 to prevent the nail ink from evaporating.
  • the cap 13 is preferably fitted to the holder 5.
  • the cap 13 is moved in the direction of the arrow so as to fit the holder 5.
  • the width of the convex outer annular zone 10 is preferably from 0.2 to 3 mm, particularly preferably from 0.5 to 2 mm.
  • the height of the convex outer orbicular zone 10 is preferably from 0.1 to 1 mm, particularly preferably from 0.05 to 0.5 mm.
  • the number of the convex outer orbicular zones 10 is preferably one or more, more preferably two or more, and particularly preferably three or more.
  • Convex outer ring The upper limit of the number of 10 is not particularly limited and may be appropriately selected depending on the size of the holder 5, but is preferably 6 or less, more preferably 5 or less, and particularly preferably 4 or less.
  • the interval between each convex outer orbicular zone 10 is preferably 0.5 to 5 mm, and particularly preferably 0.8 to 3 mm.
  • a thread 15 is applied to the outer periphery of the holder 5, and a thread 15 is applied to the inner surface of the cap 13, and the cap 13 is attached to the holder 5. May be attached. Further, as shown in FIG. 3, when the thread 15 is provided together with the convex outer ring zone 10 on the outer periphery of the holder 5, the airtightness of the cap 13 can be further improved. Further, in order to prevent evaporation of nail ink, it is preferable that a thin film 16 is laminated on the inner surface of the cap 13 to increase the airtightness of the cap 13.
  • the material of the thin film 16 examples include rubber and an elastomer similar to the material of the penetrating mark 3 and the cushioning material 4, and further include the same resin as the material of the handle 1, particularly the rubber and the elastomer. Soft materials such as are preferred.
  • the thickness of the thin membrane 16 is preferably between 10 / m and 2 zm.
  • the retainer 5 is provided with a stopper for fitting the cap 13. Thereby, the seal surface of the penetration mark 3 can be protected from the inside of the cap 13.
  • the fitting of the cap 13 is preferably a shape that is in close contact with the tip end surface of the cap 13. Specifically, it is preferable to provide a convex flange 9 on the outer periphery of the holder 5.
  • the convex flange 9 also functions as a stopper for fitting the handle 1 when the flange 9 is fitted.
  • the holder 5 is preferably formed by integrally forming the groove 11, the groove 12, the convex outer orbicular zone 10, and the convex flange 9.
  • the penetrating mark 3 can be joined to a nail-ink tank 17 as shown in FIG. 5a.
  • the nail ink can be sequentially soaked from the nail ink tank 17.
  • the nail ink tank 17 is preferably configured to be housed inside the handle 1. Further, it is preferable that the top of the nail ink tank 17 be detachably sealed with a tank lid 18. It is preferable to connect the nail ink tank 17 to the holder 5 so that the nail ink tank 17 can be easily attached to the handle 1.
  • the capacity of the nail ink tank 17 is preferably a capacity that can be repeatedly stamped 100 or more times, and particularly preferably a capacity that can be repeatedly stamped 200 or more times.
  • 0.05 to 1 ml is preferable, and 0.1 to 0.3 ml is particularly preferable. Further, as shown in FIG. 6, it is more preferable to adopt a structure in which the nail ink storage body 19 is housed inside the handle 1 instead of or together with the nail ink tank 17.
  • the nail ink holding force of the nail ink storage body 19 be weaker than the nail ink holding force of the penetration mark 3.
  • the nail ink occluding body 19 is not particularly limited as long as it can absorb and store nail ink, but a porous body having a continuous porous structure is preferable.
  • Examples of the material of the nail ink occlusion body 19 include a sponge-like elastic body, porous ceramic, porous plastic, and porous sintered body. It is preferable to use a nail ink occlusion body 19 made of the same material as that of the penetrating mark 3 because both can be easily thermally bonded and bonded.
  • a hard presser 20 having a function of supporting the penetration mark 3 so as not to fall into the inside of the handle is stored in the upper part of the nail ink storage body 19.
  • the material of the hard retainer 20 is, for example, a hard plastic, a hard foamed plastic (such as a hard foamed polystyrene), and the like.
  • the handle 1 and the penetration mark 3 can be easily replaced.
  • the handle 1 is made of a transparent or translucent material, the holder 5 can be easily seen from the outside of the handle 1 and is absorbed and held by the penetrating mark 3 on the surface of the holder 5 or the nail ink tank 17. It is preferable to teach the color of the nail ink, since the color of the nail ink can be checked from the outside of the pattern 1 while holding the pattern 1 even after the pattern 1 is attached.
  • the nail ink that can be absorbed and held by the penetration mark 3 of the nail art stamp of the present invention contains a resin, a pigment and a coloring agent of Z or dye, and a solvent.
  • Various solvents can be used as the solvent.
  • Specific examples of the solvent include water, monohydric alcohols, polyhydric alcohols, fatty acid esters such as fatty acid esters of polyhydric alcohols, alkyl ethers of polyhydric alcohols, polyanoalkylene glycols, polyalkylene glycol alkyl ethers, and hydrocarbons. Solvents and ketones are preferred.
  • Monohydric alcohols include aliphatic monohydric alcohols such as ethanol, propanol and butanol, and benzyl alcohol Aromatic monohydric alcohols.
  • polyhydric alcohol examples include alkylene glycols such as ethylene glycol, propylene glycol and butylene glycol, and glycerin.
  • fatty acid esters of polyhydric alcohols include mono-, di-, tri- or tetra-fatty acid esters of polyhydric alcohols having 2 to 10 carbon atoms.
  • the fatty acid ester includes a fatty acid ester having 1 to 10 carbon atoms.
  • Specific examples of fatty acid esters of polyhydric alcohols include, for example, 2,2,4-trimethyl-1,3-pentanediol monoisobutyrate.
  • alkyl ether of a polyhydric alcohol examples include mono- or dialkyl ethers of a polyhydric alcohol having 2 to 10 carbon atoms.
  • alkyl group in the alkyl ether of the polyhydric alcohol an alkyl group having 1 to 10 carbon atoms is preferable, and an alkyl group having 1 to 6 carbon atoms is particularly preferable.
  • alkyl ethers of polyhydric alcohols include ethylene glycol monoethylene ether, ethylene glycol monopropynole ether, ethylene glycol monobutyl ether, propylene glycol monoethylene ethanol, propylene glycol 1 / lemonopropyl ether, propyleneglycol / lemonoptinoleatenole, and the like.
  • polyalkylene glycol examples include polyethylene glycol, polypropylene glycol, and polybutylene glycol.
  • the number of repeating oxyalkylene groups in the polyalkylene glycol is not particularly limited as long as it functions as a solvent, but is preferably in the range of 1 to 10, more preferably in the range of 1 to 6, A range of 1 to 4 is particularly preferred.
  • the polyalkylene glycol alkyl ether may be any of a polyalkylene glycol monoalkyl ether and a polyalkylene glycol dialkyl ether.
  • examples of the polyalkylene glycol include the above-mentioned polyalkylene glycols.
  • the alkyl group in the polyalkylene glycol alkyl ether is preferably an alkyl group having 1 to 10 carbon atoms, particularly preferably an alkyl group having 1 to 6 carbon atoms. It may have a substituent.
  • polyanorylene glycol alkyl ether examples include diethylene glycol monoethyl ether, diethylene glycol monopropyl ether, diethylene glycol monobutynoate ether, dipropylene glycol monomethyl / lethetenol, and dipropylene glycol monoethyl ether.
  • Ether dipropylene d'arycone monopropynoleate, dipropyleneglyconele monoptinolate, triethyleneglyconele monoethylenate, triethyleneglycol / lemonopropynolate, triethylene glycol monop Butyl ether, tripropylene glycol monomethyl ether, tripropylene glycol monoethyl ether, tripropylene glycol monopropyl ether, Pro Pirendariko one / Les monobutyl Honoré ether Honoré, tetraethylene glycol Honoré mono ethyl Honoré ether Honoré, tetraethylene glycol monopropyl ether, tetraethylene glycol monomethyl Petit ether, and the like.
  • hydrocarbon solvent examples include an aliphatic hydrocarbon solvent such as hexane, heptane, and otatan; an alicyclic hydrocarbon solvent such as cyclohexane; and an aromatic hydrocarbon solvent such as toluene.
  • Ketones include acetone, methylethyl ketone, and the like.
  • dry refers to a state in which nail ink does not adhere to a finger even when the finger is touched with the finger.
  • the solvent include polyhydric alcohols, alkyl ethers of polyhydric alcohols, polyalkylene glycols, and polyalkylene glycol alkyl ethers. If water is not contained in the solvent, drying is easy at an early stage.
  • the content of the solvent is preferably from 40 to 90% by mass, particularly preferably from 50 to 80% by mass, based on the total amount of the nail ink.
  • the solvent preferably contains water and alcohol.
  • the ratio of the content of water to the content of alcohol is preferably in the range of 1:15 to 10: 1, more preferably 1: 1 to 1: 1 and particularly preferably 1:10 to 1: 5.
  • the total content of water and alcohol is preferably 1 to 60% by mass, more preferably 30 to 60% by mass, and particularly preferably 40 to 60% by mass of the total amount of the nail link.
  • the content of solvents other than water and alcohol is 5 to 40 mass of the total amount of nail ink. / 0 are preferred, 1 0-4 0 weight 0/0 and more preferably les.
  • resins can be used as the resin, for example, petroleum resin, acrylic resin, vinyl chloride / butyl acetate copolymer resin, chlorinated polypropylene resin, phenolic resin, oil-modified alkyd resin, maleic acid resin, and mouth-modified maleic Acid resin, polyamide resin, polyurethane resin, epoxy resin, melamine resin, polyester resin, ketone resin, nitrocellulose resin, urea resin, chlorinated rubber, cyclized rubber, ester gum, cured rosin, etc.
  • Polymer resins are preferred, and ataryl copolymers are particularly preferred.
  • acrylic copolymer resin examples include (a) a methacrylic acid or an acrylic acid ester of an alkyl alcohol having 1 to 20 carbon atoms as an essential component, and (b) a hydroxyl having a polymerizable double bond, if necessary.
  • a monomer obtained by copolymerizing a group-containing monomer, (c) a carboxyl group-containing monomer having a polymerizable double bond, (d) styrene, and / or (e) another monomer is preferable.
  • the (a) component methacrylic acid or acrylic acid ester of an alkyl-alcohol having 1 to 20 carbon atoms (hereinafter referred to as “acrylic ester”) used as an essential component is 10% based on the mass of all monomers. It is preferably used in a proportion of up to 90% by mass, and a particularly preferred amount is in the range of 30 to 80% by mass.
  • the alkyl alcohol having 1 to 20 carbon atoms forming the acrylic ester of the component (a) may be any of linear, branched and cyclic alcohols having an alkyl group.
  • acrylic ester of the component (a) examples include, for example, methyl methacrylate, methyl methacrylate, ethyl methacrylate, ethyl acrylate, methacrylic acid-n-propyl, acrylic acid-n-propyl, and isopropyl methacrylate.
  • the hydroxyl group-containing monomer having a polymerizable double bond as the component (b) is preferably used in a proportion of 10 to 50% by mass based on the mass of all the monomers. It is in the range of 10 to 40% by mass.
  • Examples of the hydroxy group-containing monomer having a polymerizable double bond as the component (b) include, for example, hydroxyshethyl methacrylate, hydroxyethyl acrylate, hydroxypropyl methacrylate, and hydroxypropyl methacrylate.
  • versatic Adducts of glycidyl ester and Akuri Le acids such as adduct thereof et al are of versatic acid glycidyl ester and Metariku acid. These may be used alone or in combination of two or more.
  • the carboxyl group-containing monomer having a polymerizable double bond as the component (c) is not an essential monomer component but may be used in a proportion of 0 to 10% by mass based on the mass of all monomers. preferable.
  • carboxyl group-containing monomer having a polymerizable double bond as the component (c) examples include, for example, methacrylic acid, acrylic acid, itaconic acid, mesaconic acid, maleic acid, fumaric acid, and the like. These may be used alone or in combination of two or more. Further, the styrene of the component (b) is preferably used in a proportion of 20% by mass or less based on the mass of all the monomers, and a particularly preferable use amount is in a range of 1 to 18% by mass.
  • component (e) is not essential components. It is appropriately selected and used. When another monomer is used, it is preferable to use it in a proportion of 10% by mass or less based on the mass of all the monomers.
  • the acrylic copolymer include, for example, an acrylic ester copolymer, an acrylic ester / acrylamide copolymer, an acrylic ester / hydroxyethyl methacrylate styrene copolymer, and the like.
  • the acryl ester may be copolymerized by one kind or two or more kinds.
  • the content of the resin is preferably from 5 to 40% by mass, more preferably from 10 to 40% by mass, based on the total amount of the nail ink.
  • the colorant may be either a pigment or a dye, or a mixture of both.
  • a pigment and various inorganic coloring pigments and organic coloring pigments.
  • Inorganic coloring pigments include carbon black, red iron oxide, molybdate orange, titanium white, ultramarine, navy blue, cobalt blue, titanium yellow, graphite, zinc white, etc., barium sulfate, calcium carbonate, alumina white, silica, Examples include finely powdered caic acid, iron oxide yellow, aluminum, bronze, and pearl pigments.
  • Organic coloring pigments include monoazo pigments, disazo pigments, condensed azo pigments, quinacridone pigments, pyranthrone pigments, dipromzanthrone pigments, thioindigo pigments, perylene pigments, penzimidazolone pigments, Perinone pigments, metal complex salt azomethine pigments, isoindolinone pigments, anthraquinone pigments, anthrapyrimidine pigments, flavanthrone facial pigments, quinophthalone pigments, metal complex azo pigments, phthalocyanine pigments, copper Examples thereof include a phthalocyanine pigment, an indant pigment, a dioxazine pigment, a pyrrole pigment, and a daylight fluorescent pigment.
  • the pigments can be used alone or in combination of two or more.
  • Dyes include direct dyes, acid dyes, basic dyes, oil-soluble dyes, Healthy dyes, mordant dyes, sulfur dyes, naphthol dyes, disperse dyes, reactive dyes, and the like.
  • the content of the coloring agent is preferably from 1 to 30% by mass, more preferably from 1 to 20% by mass, and particularly preferably from 2 to 18% by mass of the entire nail ink.
  • a surfactant, an antioxidant, a fragrance, a plasticizer, an anti-settling agent, a filling amount, a modifier, and the like can be appropriately added to the nail ink as needed.
  • the plasticizer include aromatic esters such as phthalic acid esters such as dioctanol phthalate, dibutyl phthalate, butyl benzyl phthalate, diisotesyl phthalate, didodecyl phthalate, dioctyl adipate, and adipic acid.
  • Aliphatic acid diesters such as adipic acid diesters such as di-n-butyl, sebacic acid esters such as dibutyl sebacate, triaromatic hydrocarbon phosphates such as tricresyl phosphate and triphenyl phosphate, octyl diphenyl phosphate, tesyl diphate Phosphoric acid esters such as anolequinolesiphenylphenyl phosphate such as enyl phosphate and dodecyl diphenyl phosphate, and the like.
  • adipic acid diesters such as di-n-butyl
  • sebacic acid esters such as dibutyl sebacate
  • triaromatic hydrocarbon phosphates such as tricresyl phosphate and triphenyl phosphate
  • octyl diphenyl phosphate tesyl diphate Phosphoric acid esters
  • Nail-art stamps similar to the nail-art stamps in FIGS. 1 and 2 were prepared and used by fitting the cylindrical handle 1 and the holder 5.
  • the cylindrical handle 1 (outer diameter 1 lmm, inner diameter 9 mm, length 4 Omm) is made of pernor white plastic (polystyrene resin), and similarly, the holder 5 is made of pearl white. It was formed by integral molding of colored plastic (polystyrene resin).
  • the retainer 5 has a longitudinal groove 1 1 (groove width: l mm, depth 0.5 mm, length 7 mm) and an outer annular groove 1 2 (groove width: 1 mm, depth 0.5 mm) on the handle 1 (cylindrical shape, outer diameter 9 mm, inner diameter 7 mm, length 7 mm), and convex flange 9 (outer diameter 11 mm, thickness 1 mm), torso 8 (cylindrical shape, outer diameter 9 mm, diameter 7 mm, length 17 mm) and two convex outer ring zones 10 (width l mm, height 0.2 mm) It has a mounting portion 6 (outer diameter 9 mm, inner diameter 6.5 mm, depth 3 mm of the concave depression) provided on the outer periphery.
  • the penetrating mark 3 is composed of a continuous porous material (thickness: 1.5 mm, cross-sectional shape: circle, circular diameter: 6.5 mm) manufactured from polyethylene-based plastic elastomer and having an average diameter of 20 ⁇ .
  • a convex projection 2 thickness 100 m, plane shape: heart shape, maximum length of the heart shape: 4 mm
  • a projection 2 are provided in the seal surface of the penetrating mark 3 which was not filled. In the seal surface of the penetrating mark 3 which was not filled, the hole of the hole was melted to close the hole, and the nail-ink could seep out only from the surface of the convex protrusion 2.
  • the penetrating mark 3 was fixed to the holder 5 with an acrylic adhesive as a cushioning material 4 through an open-cell polyurethane rubber sponge elastic body (diameter 6.5 mm, thickness 6 mm).
  • the open-cell polyurethane rubber sponge elastic material is a cubic cushioning material 4 with a side length of 1 cm.
  • a test piece was prepared, and the length of shrinkage when a load of 500 g was applied to the test piece was 2 mm.
  • the penetrating mark 3 and the cushioning material 4 were adhered to each other via an acrylic adhesive layer (thickness: 50 mm). By this ataryl adhesive layer, it was possible to prevent the nail ink impregnated in the penetration mark 3 from impregnating the buffer material 4.
  • the cylindrical cap 13 (outside diameter 1 lmm, inside diameter 9 mm) is made of pearl white polystyrene resin, and if the cap 13 is used to cover the holder 5, The cap 13 can be fitted to the convex flange 9.
  • the nail ink was dropped on the surface of the convex protrusion 2 of the penetrating mark 3 of the nail art stamp, and the nail ink for 100 times of the stamp was absorbed and held. Then, the pattern was repeatedly stamped on the nail surface. Even after repeated stamping 100 times, a clear pattern could be stamped.
  • the degree of crushing and shrinking of the cushioning material 4 was about 40% of the thickness in a state where no force was applied when actually stamping the nail with a nail art stamp.
  • the cushioning material 4 when stamped had a degree of shrinkage of about 45%.
  • a thread 15 is formed inside the tip of the cap 13
  • a thin film 16 of silicone rubber (maximum thickness l mm) is laminated inside the cap 13
  • a A weight 14 g (mass: 5 g) made of stainless steel was put in the inside to prepare a nail art stamp in the same manner as described above.
  • This nail art stamp was repeatedly stamped with a pattern on the nail surface in the same manner as described above. Even after stamping 100 times, a clear pattern could be stamped without shifting to the target position.
  • this nail art stamp has extremely high airtightness of the cap, and even after leaving it at room temperature for 6 months with the cap on, the pattern on the nail surface could be repeatedly stamped.
  • the material of the handle 1, the holder 5 and the cap 13 was made of aluminum metal, and the dimensions of the handle 1 were 9 mm in outer diameter, 8.5 mm in inner diameter, and 9 cm in length, and held.
  • the dimensions of the tool 5 are 8.5 mm in outer diameter, 8 mm in inner diameter, and 4 cm in body length.
  • the dimensions of the cap 13 are 9111111 in outer diameter, 8.5 mm in inner diameter, 5 cm in length, and the penetration mark 3 Make the face of the mark flat, make the pattern of the part that exudes the nail ink a face, and make the convex protrusion 2
  • a nail art stamp was prepared in the same manner as in Example 1 except that the stamp was not provided.
  • the acrylic ink (containing carbon black, acrylic resin component, and diluent) is attached to the permeated mark 3 on the nail ink seeping part of the human face pattern shape,
  • the nail ink was dropped on the stamped surface of the permeation mark 3 of the nail art stamp, and the nail ink of the stamp 100 times was absorbed and held. Then, the pattern was repeatedly stamped on the nail surface. Even after repeated stamping 100 times, a clear pattern could be stamped.
  • the cushioning material 4 when stamped had a degree of shrinkage of about 45%. The nail ink that had been stamped and adhered to the nail dried within 5 seconds. Also,
  • the cap is threaded 15, a thin layer of silicone rubber 16 (maximum thickness l mm) is laminated inside the cap, and a stainless steel weight 1 4 is placed inside the holder 5. (5 g in mass), and a nail art stamp was prepared in the same manner as above.
  • This nail art stamp was repeatedly stamped with a pattern on the nail surface in the same manner as described above. Even after stamping 100 times, a clear pattern could be stamped without shifting to the target position.
  • this nail art stamp has extremely high airtightness of the cap, and even after leaving it at room temperature for 6 months with the cap on, the pattern on the nail surface could be repeatedly stamped.
  • the cylindrical handle 1 was formed of a transparent plastic (polystyrene resin).
  • the infiltration mark 3 is composed of a continuous porous elastic body having an average diameter of 30 ⁇ m manufactured from a mixture of 20% by mass of natural rubber and 80% by mass of a polyolefin-based thermoplastic elastomer.
  • the stamped surface of the permeation mark 3 where the side surface portion 2 and the convex protrusion 2 are not provided is a non-porous coating of the same material as the elastic body. was covered. After the nail ink was absorbed and held in the nail art stamp, a pattern was repeatedly stamped on the surface of the nail. Even after stamping 50 times, a clear pattern could be stamped.
  • a nail-art stamp similar to the nail-art stamp shown in Fig. 5a was created and used.
  • the cylindrical handle 1 was formed of a transparent material.
  • the penetrating mark 3 is composed of a continuous porous elastic body having an average diameter of 30 ⁇ manufactured from a mixture of 20% by mass of natural rubber and 80% by mass of polyurethane rubber.
  • the stamped surface of the penetrating mark 3 without the protruding portion 2 was covered with a non-porous coating of the same material as the elastic body.
  • a pattern was repeatedly stamped on the surface of the nail. Since a sufficient amount of nail ink was stored in the cylindrical nail ink tank 17 (capacity: 0, 3 m 1), a clear pattern could be stamped even after stamping 200 times.
  • the penetration mark 3 is composed of a continuous porous elastic body having an average diameter of 30 ⁇ manufactured from a mixture of 20% by mass of natural rubber and 80% by mass of 0 / 0 % of polyurethane rubber.
  • the surface of the penetrating mark 3 without the side surface and the convex protrusion 2 ' was covered with a non-porous coating of the same material as the elastic body.
  • a sponge 8 having a continuous porous structure that is slightly harder than the elastic body of the penetrating mark 3 is provided in contact with the penetrating mark 3, and a hard plastic (hard) is provided on the sponge 8. (Polystyrene foam) is provided.
  • the average diameter of the pores of the sponge 19 having a continuous porous structure is 6 Ozm, so that the nail ink can be absorbed and stored.
  • the hard presser 20 has a function of supporting the penetrating mark 3 so as not to fall into the inside of the handle 1. After the same nail ink as in Example 1 was absorbed and held in the nail art stamp, a pattern was repeatedly stamped on the nail surface. The series housed inside handle 1 Since a sufficient amount of nail ink was absorbed and stored in the sponge 19 having a continuous porous structure, a clear pattern could be stamped even after stamping 200 times.
  • a hard presser 20 was housed so as to be in contact with the penetration mark 3, and the entire inside of the cylindrical handle 1 was hard presser 20.
  • a nail art stamp was prepared and used in the same manner as in Example 3, except that the pattern 1 was formed of hard plastic colored in gray. After the same nail ink as in Example 1 was absorbed and held in this nail art stamp, the nail was stamped by repeating the pattern on the surface. Penetration mark 3 was thick, and enough nail ink was absorbed and stored in penetration mark 3, so even after repeated stamping 100 times, a clear pattern could be stamped.
  • the nail art stamp of the present invention has various patterns repeatedly on the surface of the nail.

Landscapes

  • Pens And Brushes (AREA)

Abstract

L'invention concerne un tampon pour art sur ongles capable de dessiner de façon répétée et simple un motif sur la surface d'un ongle par impression au tampon. Un joint de pénétration (3) composé d'un corps élastique poreux est disposé à l'extrémité d'un tube (1) de manière que le joint peut absorber et contenir l'encre à ongles et une partie de suintement d'encre à ongles ayant la forme d'un motif est placée à la surface du joint de pénétration (3). Si nécessaire, le joint de pénétration (3) est disposé entre l'extrémité du tube (1) et le joint de pénétration (3) par l'intermédiaire d'un support (5).
PCT/JP2004/008093 2003-07-31 2004-06-03 Tampon pour art sur ongles WO2005011991A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2003-205032 2003-07-31
JP2003205032 2003-07-31

Publications (1)

Publication Number Publication Date
WO2005011991A1 true WO2005011991A1 (fr) 2005-02-10

Family

ID=34113662

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2004/008093 WO2005011991A1 (fr) 2003-07-31 2004-06-03 Tampon pour art sur ongles

Country Status (1)

Country Link
WO (1) WO2005011991A1 (fr)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2427135A (en) * 2005-06-14 2006-12-20 Dina Suzanne Malick Apparatus and method for decorating nails
US7874298B2 (en) 2007-12-13 2011-01-25 Dina Suzanne Malick Unit and method for decorating nails
US8613286B2 (en) 2011-09-19 2013-12-24 Melvin R. Kennedy Method and device for dispensing a material into a representation on a surface
WO2018132239A1 (fr) * 2017-01-10 2018-07-19 L'oreal Compositions de vernis à ongles sans colorant et procédés associés
US10684547B2 (en) 2017-01-10 2020-06-16 L'oréal Devices and methods for non-planar photolithography of nail polish

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3000450U (ja) * 1994-01-26 1994-08-09 株式会社六甲工芸社 繰り出し口紅容器型印鑑
JPH08207409A (ja) * 1995-02-03 1996-08-13 Mitsubishi Pencil Co Ltd 浸透印版の製造方法
JPH1111512A (ja) * 1997-04-15 1999-01-19 L'oreal Sa 液体製品の収容塗布ユニット
JP3058619U (ja) * 1998-10-21 1999-06-22 株式会社 ビーム 印 判
JP2002051829A (ja) * 2000-08-09 2002-02-19 Michiko Shibazaki ネイルアート用スタンプ装置
JP2002273995A (ja) * 2001-03-21 2002-09-25 Horie:Kk 印 鑑

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3000450U (ja) * 1994-01-26 1994-08-09 株式会社六甲工芸社 繰り出し口紅容器型印鑑
JPH08207409A (ja) * 1995-02-03 1996-08-13 Mitsubishi Pencil Co Ltd 浸透印版の製造方法
JPH1111512A (ja) * 1997-04-15 1999-01-19 L'oreal Sa 液体製品の収容塗布ユニット
JP3058619U (ja) * 1998-10-21 1999-06-22 株式会社 ビーム 印 判
JP2002051829A (ja) * 2000-08-09 2002-02-19 Michiko Shibazaki ネイルアート用スタンプ装置
JP2002273995A (ja) * 2001-03-21 2002-09-25 Horie:Kk 印 鑑

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2427135A (en) * 2005-06-14 2006-12-20 Dina Suzanne Malick Apparatus and method for decorating nails
GB2427135B (en) * 2005-06-14 2008-11-26 Dina Suzanne Malick A unit and method for decorating nails
US7874298B2 (en) 2007-12-13 2011-01-25 Dina Suzanne Malick Unit and method for decorating nails
US8613286B2 (en) 2011-09-19 2013-12-24 Melvin R. Kennedy Method and device for dispensing a material into a representation on a surface
WO2018132239A1 (fr) * 2017-01-10 2018-07-19 L'oreal Compositions de vernis à ongles sans colorant et procédés associés
US10362850B2 (en) 2017-01-10 2019-07-30 L'oréal Dye-free nail varnish compositions and methods thereof
US10684547B2 (en) 2017-01-10 2020-06-16 L'oréal Devices and methods for non-planar photolithography of nail polish

Similar Documents

Publication Publication Date Title
CN202047292U (zh) 一种在人造物品上制作所需标记的浸注染料成套用具
US5958525A (en) Device and kit
US9161606B1 (en) Makeup application component
DE50205815D1 (de) Farbige Beschriftung und Markierung von Kunststoffen und Lacken
RU2001116591A (ru) Композиция металлосодержащих чернил для пишущих инструментов с волокнистым стержнем
DE102019001423B4 (de) Vorrichtung, die ein Objekt aus Knetmasse oder Modelliermasse durch Beschichten verfestigen kann
WO2005011991A1 (fr) Tampon pour art sur ongles
JP2005059583A (ja) ネイルアート用スタンプ
Ge et al. Development of multi-dimensional cell co-culture via a novel microfluidic chip fabricated by DMD-based optical projection lithography
US20130337225A1 (en) Body art/eyebrow application device
KR20180025541A (ko) 글자 또는 도안이 전사된 배출망을 구비한 화장품 용기 및 이의 제조방법
CN204484819U (zh) 透气保湿的面膜结构
CA2149118C (fr) Echantillonneurs de liquides volatils, et procede de fabrication
JP3219486U (ja) 小物物品
US11747242B2 (en) Compositions and methods for laser capture microdissection
CN2132640Y (zh) 彩色人造琥珀多用工艺品
JPH0193391A (ja) 金属蒸着層の転写方法及びこれに用いる転写フイルム
JP3107295U (ja) 虫除け用扇ぎ具
JP4880317B2 (ja) 可逆変色性表示体セット
US20230358395A1 (en) Buoyant apparatus
CH419917A (de) Verfahren zum Verzieren oder Beschriften von Gebilden aus thermoplastischem Kunststoff
JP2017169513A (ja) 植物包装体
CN215102969U (zh) 一种可粘贴膜
JPH02128845A (ja) 印刷装置、並びにその製造方法および使用方法
CN201217536Y (zh) 一种新型盖、储物瓶及储物罐

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BW BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE EG ES FI GB GD GE GH GM HR HU ID IL IN IS KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NA NI NO NZ OM PG PH PL PT RO RU SC SD SE SG SK SL SY TJ TM TN TR TT TZ UA UG US UZ VC VN YU ZA ZM ZW

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): BW GH GM KE LS MW MZ NA SD SL SZ TZ UG ZM ZW AM AZ BY KG KZ MD RU TJ TM AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LU MC NL PL PT RO SE SI SK TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG

121 Ep: the epo has been informed by wipo that ep was designated in this application
32PN Ep: public notification in the ep bulletin as address of the adressee cannot be established

Free format text: COMMUNICATION PURSUANT TO RULE 69 (1) EPC SENT 28.04.06

122 Ep: pct application non-entry in european phase