WO2004106240A1 - Method of treating organic waste water and organic sludge and treatment equipment therefor - Google Patents

Method of treating organic waste water and organic sludge and treatment equipment therefor Download PDF

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Publication number
WO2004106240A1
WO2004106240A1 PCT/JP2004/008235 JP2004008235W WO2004106240A1 WO 2004106240 A1 WO2004106240 A1 WO 2004106240A1 JP 2004008235 W JP2004008235 W JP 2004008235W WO 2004106240 A1 WO2004106240 A1 WO 2004106240A1
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Prior art keywords
tank
wastewater
foam
sludge
generated
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PCT/JP2004/008235
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French (fr)
Japanese (ja)
Inventor
Yoshitada Hamasaki
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Asahi Organic Chemicals Industry Co., Ltd.
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Priority claimed from JP2003149848A external-priority patent/JP4019277B2/en
Priority claimed from JP2003350119A external-priority patent/JP2005074420A/en
Application filed by Asahi Organic Chemicals Industry Co., Ltd. filed Critical Asahi Organic Chemicals Industry Co., Ltd.
Priority to KR1020057022491A priority Critical patent/KR101102179B1/en
Publication of WO2004106240A1 publication Critical patent/WO2004106240A1/en

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • C02F3/12Activated sludge processes
    • C02F3/1236Particular type of activated sludge installations
    • C02F3/1268Membrane bioreactor systems
    • C02F3/1273Submerged membrane bioreactors
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/24Treatment of water, waste water, or sewage by flotation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/444Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by ultrafiltration or microfiltration
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/02Biological treatment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • C02F3/12Activated sludge processes
    • C02F3/1205Particular type of activated sludge processes
    • C02F3/1215Combinations of activated sludge treatment with precipitation, flocculation, coagulation and separation of phosphates
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/12Treatment of sludge; Devices therefor by de-watering, drying or thickening
    • C02F11/16Treatment of sludge; Devices therefor by de-watering, drying or thickening using drying or composting beds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/20Nature of the water, waste water, sewage or sludge to be treated from animal husbandry
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/22Nature of the water, waste water, sewage or sludge to be treated from the processing of animals, e.g. poultry, fish, or parts thereof
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/06Sludge reduction, e.g. by lysis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/12Prevention of foaming
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/24Separation of coarse particles, e.g. by using sieves or screens
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • C02F3/12Activated sludge processes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/10Biological treatment of water, waste water, or sewage
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/20Sludge processing

Definitions

  • the present invention relates to a method for treating organic wastewater generated from a fishing port, a fish market, or the like, wherein the wastewater from which solid matter such as fish meat pieces has been removed is subjected to aeration treatment, and foam generated by the aeration treatment is removed.
  • the first feature is that activated sludge treatment and membrane filtration are performed.
  • FIG. 5 is a configuration diagram schematically showing a test apparatus according to the present invention.
  • the present invention is not particularly limited as long as it can generate microbubbles that can be diffused by a diffuser.
  • the foam 7 floating on the water surface of the foam separation tank 5 is removed by a known wiper or the like. Are discharged.
  • Wastewater 4 may be pre-measured in a distribution weighing tank (not shown) and distributed to multiple foam separation units 5 for treatment! / ⁇ .
  • the properties of the foam 7 separated from the wastewater 4 are such that the pollution load concentration is higher than that of the wastewater 4, but the pollution concentration is almost constant and is extremely small compared to the amount of water before the aeration treatment. Therefore, it is in a state suitable for activated sludge treatment.
  • the foam 7 discharged from the foam discharge port 6 by the contacting machine is introduced into the membrane separation activated sludge treatment tank 10 by the transfer pump 9 and is subjected to the activated sludge treatment.
  • the activated sludge is sucked by the suction pump 13 through the membrane 12, and the activated sludge is membrane-separated and discharged as clear membrane-separated seawater.
  • Microfiltration membranes and ultrafiltration membranes can be used as the type of membrane used for the separator 12, and the shape of the membrane can be a sheet-shaped flat membrane or a tubular hollow fiber, but is particularly limited. It is not done.
  • the separation membrane module membrane area 0. lm 2, flux 0. lmVm 2 - day
  • the through hole and the Z or nonwoven fabric are installed at the bottom of the container 38, but they can also be installed on the side surface, and are not particularly limited.
  • the container 38 is not particularly limited as long as it can be configured to discharge the seawater generated after the excess sludge is filtered and digested and reduced.
  • the seawater filtered by the sand is transferred to the aquaculture tank 35, where the air is supplied by the air diffuser 36 to increase the dissolved oxygen content, and is sent to the container 38 by the circulation pump 34.
  • the benthic organism was used as a benthic organism, but other sediment-eating benthic organisms may be used, or a suspended food-eating benthic organism represented by bivalves may be used. You may use a mixture of benthic organisms
  • Membrane separation activated sludge treatment tank denitrification tank, nitrification tank installed, effective capacity 15L
  • the separation membrane module membrane area 0. lm 2, flux 0. 03mVm 2 - day
  • Aquaculture tank 5L flask (effective volume 3L), container 0.5L, weight of squid 20g

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Microbiology (AREA)
  • Analytical Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Activated Sludge Processes (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Physical Water Treatments (AREA)

Abstract

A treatment equipment for organic waste water and organic sludge, comprising foam separation tank (5) in which waste water after removal of solid matter such as fish meat piece is introduced; bubble generating means (16) disposed in the foam separation tank (5) and capable of generating fine bubbles in the waste water; membrane separation active sludge treating tank (10) in which the foam generated in the foam separation tank (5) is introduced; and culture water bath (35) in which excess organic sludge having occurred in the membrane separation active sludge treating tank (10) is introduced and in which benthic organism (32) is raised. Organic waste water having occurred in fishing ports, fish markets, land cultivation farms, etc. is subjected to active sludge treatment in the membrane separation active sludge treating tank (10). Thus generated excess organic sludge is introduced in the culture water bath (35), so that the excess organic sludge is digested, reduced in weight and disposed of as feeding stuff (feed) of benthic organism. As a result, purification treatment of organic waste water occurring in large volume in fishing ports, fish markets, land cultivation farms, etc. and treatment of excess organic sludge after the purification treatment can be carried out in economic advantage.

Description

明 細 書  Specification
有機性廃水及び有機性汚泥の処理方法と処理装置  Method and apparatus for treating organic wastewater and organic sludge
技術分野  Technical field
[0001] 本発明は、海洋汚染防止技術に関し、詳しくは、漁港、魚市場および陸上養殖場 等における魚の水揚げ、魚の洗浄、冷凍魚の解凍、魚の解体時に発生する血液や 肉片等を含む有機性廃水及び、陸上養殖における有機性廃水の処理方法及ぴ処 理装置と、前記有機性廃水の処理後に発生する余剰有機汚泥の処理方法及び、そ の装置に関するものである。  The present invention relates to a technology for preventing marine pollution, and more particularly, to an organic wastewater containing blood and meat fragments generated at the time of landing of fish, washing of fish, thawing of frozen fish, and demolition of fish in a fishing port, a fish market, a land farm, and the like. The present invention also relates to a method and an apparatus for treating organic wastewater in onshore aquaculture, a method for treating excess organic sludge generated after the treatment of the organic wastewater, and an apparatus therefor.
背景技術  Background art
[0002] 従来、漁港や魚市場等では、魚の鮮度保持等の理由から水道水ではなく、ろ過 殺菌された海水を用いて、水揚げされた魚の洗浄、冷凍魚の解凍、魚の解体時に発 生する血液や肉片等の洗浄を行っている。これにより発生する有機性廃水は、漁獲 量に応じて水量が増減し、かつ水揚げされる魚の選別方法や鮮魚力 放血を行なう 活け締め等の作業内容に応じて汚濁濃度が増減する。このように水量や汚濁濃度が 変動する有機性廃水に対する生物処理は、汚濁負荷が一定しないという理由力 浄 化処理が困難であり、その殆どが未処理のまま海洋へ再放流されて!/ヽるのが現状で ある。  [0002] Conventionally, in fishing ports and fish markets, blood generated during washing of landed fish, thawing of frozen fish, and demolition of fish using seawater that has been filtered and sterilized instead of tap water for reasons such as maintaining freshness of fish. And cleaning of meat pieces. The amount of organic wastewater generated by this will increase or decrease according to the amount of fish caught, and the pollutant concentration will increase or decrease according to the method of selecting the fish to be landed or the work to be performed, such as live fish bleeding. Biological treatment of organic wastewater with varying water volume and pollutant concentration is difficult because of the variable pollution load, and it is difficult to purify the wastewater. Most of the wastewater is re-discharged to the ocean without treatment! / Puru is the current situation.
[0003] この問題を直接解決する技術はとくに見当らないが、関連する技術として、砂ろ過 で養魚水槽の廃水をろ過する水質浄化方法が提案されて ヽる (特許文献 1参照。 )。  [0003] There is no particular technique for directly solving this problem, but as a related technique, a water purification method for filtering wastewater from a fish tank using sand filtration has been proposed (see Patent Document 1).
[0004] しかしながら、特許文献 1に記載されて!/ヽる装置による汚濁成分の除去は、砂ろ過 材などを用いたろ過処理を主体として V、るので、これを漁港や魚市場等で発生する 有機性廃水処理に適用しょうとすると、ろ材の目詰まりが頻繁に生じるおそれがある。 そもそも、養殖水槽は汚濁濃度が低くほぼ一定で、発生する汚濁物質も魚の糞や残 餌等の固形物のみに起因し、水は循環して使用されるため廃水量の変動もほとんど 無いものであり、これを漁港や魚市場等力 大量発生する廃水処理に適用しようとし ても、とても実用に供するものではない。また、生物処理後に発生する余剰有機性汚 泥を底生生物を用いて消化減量させる先行技術は特に見当たらなレヽが、養殖海域 の底に堆積した残餌等の有機物汚泥を^^する方法として、予め大量に培養したィ トゴカイを撒布し、汚泥を消化減量させる方法が提案されている(特許文献 2参照)。 [0004] However, as described in Patent Document 1, the removal of contaminated components by the Puru device is mainly performed by filtration using a sand filter material, etc., which occurs at fishing ports and fish markets. When applied to organic wastewater treatment, filter media may frequently be clogged. In the first place, the aquaculture tanks have a low concentration of pollutants and are almost constant, and the pollutants generated are only due to solids such as fish droppings and bait, and the water is used in circulation, so there is almost no change in the amount of wastewater. However, even if it is applied to the treatment of wastewater generated in large quantities at fishing ports and fish markets, it is not very practical. In addition, there is no particular technology that digests and reduces excess organic sludge generated after biological treatment using benthic organisms. As a method for dispersing organic sludge such as residual food deposited on the bottom of a bed, a method has been proposed in which a large amount of cultivated silkworm is sprayed in advance to digest and reduce the sludge (see Patent Document 2).
[0005] 特許文献 1 :特開平 5— 96291号公報 (第 2— 3頁、第 1図) Patent Document 1: JP-A-5-96291 (pages 2-3, FIG. 1)
特許文献 2:特開平 2001— 231394号公報 (第 2— 5頁)  Patent Document 2: Japanese Patent Application Laid-Open No. 2001-231394 (pages 2-5)
発明の開示  Disclosure of the invention
[0006] 本発明は上記のような従来技術の課題に鑑み、漁港、魚市場および陸上養殖場等 で大量に発生する有機性廃水の浄化処理及び浄化処理後の余剰有機性汚泥処理 を経済的に行うことができる有機性廃水の処理方法及ぴその処理装置を提供するこ とを目的とするものである。  [0006] In view of the above-mentioned problems of the prior art, the present invention economically reduces the amount of organic wastewater generated in large quantities at fishing ports, fish markets, land farms, and the like, and the processing of excess organic sludge after the purification. It is an object of the present invention to provide a method of treating organic wastewater and a treatment apparatus therefor, which can be carried out in a short time.
[0007] すなわち、本発明は、漁港や魚市場等から発生する有機性廃水の処理方法であつ て、魚肉片等の固形物を除去処理した廃水を曝気処理し、曝気処理により発生した 泡沫を活性汚泥処理すると共に、膜ろ過することを第 1の特徴とする。  [0007] That is, the present invention relates to a method for treating organic wastewater generated from a fishing port, a fish market, or the like, wherein the wastewater from which solid matter such as fish meat pieces has been removed is subjected to aeration treatment, and foam generated by the aeration treatment is removed. The first feature is that activated sludge treatment and membrane filtration are performed.
[0008] また、本発明に係る漁港や魚市場等から発生する有機性廃水の処理装置は、魚肉 片等の固形物を除去処理した廃水が導入される泡沫分離槽と、該泡沫分離槽内に 設置され廃水中に微細気泡を発生させる気泡発生手段と、該気泡発生手段により発 生した泡沫が導入される膜分離活性汚泥処理槽とから構成されることを第2の特徴と し、さらに気泡発生手段が自吸式微細気泡発生装置であることを第 3の特徴とする。 [0008] Further, the apparatus for treating organic wastewater generated from a fishing port, a fish market, or the like according to the present invention includes a foam separation tank into which wastewater from which solid substances such as fish meat pieces have been removed is introduced, and a foam separation tank inside the foam separation tank. a bubble generating means for generating fine bubbles in the waste water is installed, and a second feature in that foam that occurred is configured from the membrane and the separation activated sludge treatment tank is introduced by the gas bubble generating means, further A third feature is that the bubble generation means is a self-priming fine bubble generation device.
[0009] さらに、本発明は、漁港、魚市場おょぴ陸上養殖場等から発生する有機性廃水を 受入れ、生物処理し、生物処理後に発生する余剰有機性汚泥を、底生生物が飼育 される養殖水槽へ導入し、前記余剰有機性汚泥を当該底生生物の飼料となして消 ィ匕減量処理することを第 4の特徴とし、前記生物処理が、活性汚泥法によるものであ ることを第 5の特徴とする。  [0009] Further, the present invention receives organic wastewater generated from a fishing port, a fish market, a land farm, or the like, performs biological treatment, and surpluses organic sludge generated after the biological treatment to produce benthic organisms. The fourth feature is that the biological treatment is carried out by an activated sludge method by introducing the excess organic sludge into feed for the benthic organisms to reduce the amount of the organic sludge. Is the fifth feature.
[0010] また、漁港、魚市場および陸上養殖場等から発生する有機性廃水及び有機性汚 泥の処理装置であって、魚肉片等の固形物を除去処理した廃水が導入される泡沫 分離槽と、該泡沫分離槽内に設置され廃水中に微細気泡を発生させる気泡発生手 段と、泡沫分離槽内で発生した泡沫が導入される膜分離活性汚泥処理槽と、該膜分 離活性汚泥処理槽力 発生する余剰有機性汚泥が導入されかつ底生生物が飼育さ れる養殖水槽とを具備することを第 6の特徴し、前記養殖水槽に砂等のろ過材を充 填し、ろ過水を得ることを第 7の特徴とする。さらに、前記底生生物が、堆積物食性底 生生物及び Zまたは懸濁物食性底生生物であることを第 8の特徴とする。 [0010] Further, the present invention is an apparatus for treating organic wastewater and organic sludge generated from a fishing port, a fish market, an onshore farm, and the like, wherein the wastewater from which solid matter such as fish meat pieces has been removed is introduced. A bubble generation means installed in the foam separation tank to generate fine bubbles in wastewater; a membrane separation activated sludge treatment tank into which foam generated in the foam separation tank is introduced; and the membrane separation activated sludge. Processing tank power The sixth characteristic is that the tank is provided with a culture tank in which surplus organic sludge generated is introduced and benthic organisms are bred, and the culture tank is filled with a filtering material such as sand. The seventh feature is to fill and obtain filtered water. Further, the eighth feature is that the benthic organism is a sedimentary benthic benthic and a Z or suspended sedimentary benthic organism.
図面の簡単な説明  BRIEF DESCRIPTION OF THE FIGURES
[0011] 以下、本発明の実施態様について図 1乃至図 10に基づいて説明するが、本発明 が本実施態様に限定されな!/、ことは言うまでもな!/、。  Hereinafter, an embodiment of the present invention will be described with reference to FIGS. 1 to 10, but the present invention is not limited to this embodiment! / Needless to say! / ,.
[図 1]本発明に係る有機性廃水の処理装置を模式的に示す構成図である。  FIG. 1 is a configuration diagram schematically showing an organic wastewater treatment apparatus according to the present invention.
[図 2]泡沫分離槽の縦断面図である。  FIG. 2 is a longitudinal sectional view of a foam separation tank.
[図 3]自吸式微細気泡発生装置の要部断面図である。  FIG. 3 is a sectional view of a main part of a self-priming microbubble generator.
[図 4]膜分離活性汚泥処理槽の縦断面図である。  FIG. 4 is a longitudinal sectional view of a membrane separation activated sludge treatment tank.
[図 5]本発明に係る試験装置を模式的に示す構成図である。  FIG. 5 is a configuration diagram schematically showing a test apparatus according to the present invention.
[図 6]本発明に係る有機性廃水及び有機性汚泥の処理装置を模式的に示す構成図 である。  FIG. 6 is a configuration diagram schematically showing an organic wastewater and organic sludge treatment apparatus according to the present invention.
[図 7]養殖水槽における水位調整方法の他の実施例を模式的に示す構成図である。  FIG. 7 is a configuration diagram schematically showing another embodiment of a method for adjusting a water level in a culture tank.
[図 8]本発明に係る試験装置を模式的に示す構成図である。  FIG. 8 is a configuration diagram schematically showing a test apparatus according to the present invention.
[図 9]汚泥の投入状態を示す養殖水槽の内部写真である。  FIG. 9 is an internal photograph of the aquaculture tank showing the state of sludge introduction.
[図 10]ゴカイによる汚泥の消化減量状態を示す養殖水槽の内部写真である。  FIG. 10 is an internal photograph of an aquaculture tank showing sludge digestion and weight loss by kaikai.
発明を実施するための最良の形態  BEST MODE FOR CARRYING OUT THE INVENTION
[0012] 以下、図面を参照しながら、本発明を実施するための最良の形態について詳述す る。 Hereinafter, the best mode for carrying out the present invention will be described in detail with reference to the drawings.
実施例 1  Example 1
[0013] 図中、 1は漁港や魚市場等から発生する有機性廃水で、予め、沈砂槽 2ゃスクリー ン 3等の固液分離手段により魚肉片等の固形物の除去などの前処理が施される。前 処理された廃水 4は泡沫分離槽 5へ導入され泡沫分離槽 5内の自吸式微細気泡発 生装置 16により一定時間曝気されて泡沫分離処理される。自吸式微細気泡発生装 置 16は気泡の大きさを変えることができる。尚、ここで発生する気泡の大きさは lmm 以下である。また、本実施例では自吸式微細気泡発生装置の例を示しているが、散 気装置でも良ぐ微細気泡を発生するものであれば、特に限定されない。そして泡沫 分離槽 5の水面に浮上した泡沫 7は公知の搔き取機などで搔きとり、泡沫排出口 6か ら排出される。ここで、泡沫分離槽 5では、廃水 4を槽内に一定時間滞留させる必要 力あることから、泡沫分離槽 5の 1台分の収容能力を超える廃水 4を処理せざる得な い場合は、廃水 4を分配計量槽 (図示せず)で予め計量し、複数台の泡沫分謹 5に 分配して処理してもよ!/ヽ。泡沫分離槽 5で曝気処理された曝気処理水 8の汚濁負荷 量は十分に しているので、通常はそのまま放流できる力 更に、オゾンガスと接 触させて酸化処理したり、凝集剤を混合し凝集沈殿槽へ導き沈殿分離処理を行った り、接触曝気槽などへ導入して微生物処理を施して汚濁負荷量を更に低減させて放 流するとなお良い。 [0013] In the figure, reference numeral 1 denotes organic wastewater generated from a fishing port, a fish market, or the like, which has been subjected to pretreatment such as removal of solids such as fish meat pieces by a solid-liquid separation means such as a settling tank 2 and a screen 3 in advance. Will be applied. The pre-treated wastewater 4 is introduced into a foam separation tank 5 and aerated for a certain period of time by a self-priming microbubble generator 16 in the foam separation tank 5 to be subjected to a foam separation treatment. The self-priming microbubble generator 16 can change the size of bubbles. The size of the bubbles generated here is less than lmm. In this embodiment, an example of a self-priming microbubble generator is shown. However, the present invention is not particularly limited as long as it can generate microbubbles that can be diffused by a diffuser. The foam 7 floating on the water surface of the foam separation tank 5 is removed by a known wiper or the like. Are discharged. Here, in the foam separation tank 5, since the wastewater 4 needs to be retained in the tank for a certain period of time, if the wastewater 4 that exceeds the capacity of one foam separation tank 5 must be treated, Wastewater 4 may be pre-measured in a distribution weighing tank (not shown) and distributed to multiple foam separation units 5 for treatment! / ヽ. Since the aeration treatment water 8 aerated in the foam separation tank 5 has a sufficient pollution load, it can be discharged normally as it is.Furthermore, it can be oxidized by contact with ozone gas, or coagulated by mixing a flocculant. It is more preferable to conduct the sedimentation separation treatment by introducing into the sedimentation tank, or to introduce into the contact aeration tank and perform microbial treatment to further reduce the pollution load and discharge.
[0014] 一方、廃水 4から分離された泡沫 7の性状は、廃水 4よりも汚濁負荷濃度が高くなつ てはいるものの、汚濁濃度がほぼ一定で、曝気処理前の水量に比して極めて少量に なるため、活性汚泥処理に適した状態となる。接き取機により泡沫排出口 6から排出 された泡沫 7は、移送ポンプ 9により膜分離活性汚泥処理槽 10へ導入され、活性汚 泥処理されると共に、活性汚泥処理された処理水は分離膜 12を介して吸引ポンプ 1 3により吸引されて活性汚泥が膜分離され、清澄な膜分離海水として放流される。分 鋼莫 12に用いられる膜の種類としては精密ろ過膜や限外ろ過膜などが利用でき、膜 の形状としてはシート状の平膜やチューブ状の中空糸などが利用できるが、特に限 定されるものではない。  [0014] On the other hand, the properties of the foam 7 separated from the wastewater 4 are such that the pollution load concentration is higher than that of the wastewater 4, but the pollution concentration is almost constant and is extremely small compared to the amount of water before the aeration treatment. Therefore, it is in a state suitable for activated sludge treatment. The foam 7 discharged from the foam discharge port 6 by the contacting machine is introduced into the membrane separation activated sludge treatment tank 10 by the transfer pump 9 and is subjected to the activated sludge treatment. The activated sludge is sucked by the suction pump 13 through the membrane 12, and the activated sludge is membrane-separated and discharged as clear membrane-separated seawater. Microfiltration membranes and ultrafiltration membranes can be used as the type of membrane used for the separator 12, and the shape of the membrane can be a sheet-shaped flat membrane or a tubular hollow fiber, but is particularly limited. It is not done.
[0015] 次に、本発明装置の動作を各構成要素ごとに説明する。  Next, the operation of the device of the present invention will be described for each component.
図 2は、泡沫分離槽 5の縦断面図である。前処理された廃水 4は泡沫分離槽 5の水 槽本体 15の下方より導入される。そして、導入された廃水 4の曝気処理を行なうので あるが、本発明装置では自吸式微細気泡発生装置 16のインペラ 18がモータ 17によ り回転駆動し、インペラ 18が回転すると同時に、上端が水槽本体 15外の水槽水面よ り高い位置に大気開放され、下端が該水槽本体 15内に設置されたインペラ 18の中 心内側に差し込まれた空気導入管 19から空気が吸 ヽ込まれ廃水中に混入する。そ して、混入した空気はインペラ 18の回転により発生する渦流とせん断力により微細気 泡を発生させる。発生した微細気泡は、廃水 4中の有機物や微細な浮遊物などを気 泡表面に付着させなカ¾泡沫排出口 6へ向力つて浮上移動し、排出口 6近傍の水面 上に泡沫 (スカム)層 7を形成する。泡沫層 7は、従来公知の搔き取機にて水槽本体 1 5外に排出される。一方、曝気後の泡沫分離された処理水は、排出口 6から垂下して 泡沫分離槽 5内部を区画する堰板 20の下方に開けられた移流口 21を通り、処理水 排出口 22より放流される。 FIG. 2 is a longitudinal sectional view of the foam separation tank 5. The pretreated wastewater 4 is introduced from below the tank body 15 of the foam separation tank 5. Then, aeration treatment of the introduced wastewater 4 is performed. In the apparatus of the present invention, the impeller 18 of the self-priming microbubble generator 16 is rotationally driven by the motor 17, and at the same time as the impeller 18 rotates, the upper end is rotated. Air is released to the atmosphere outside the water tank body 15 at a position higher than the water surface of the water tank, and the lower end is sucked in from the air introduction pipe 19 inserted inside the center of the impeller 18 installed in the water tank body 15, and wastewater is discharged. Mixed in. The mixed air generates fine bubbles due to the vortex generated by the rotation of the impeller 18 and the shearing force. The generated microbubbles move upward to move toward the foam outlet 6, which does not allow organic substances and fine suspended matter in the wastewater 4 to adhere to the bubble surface, and foams on the water surface near the outlet 6 (scum). ) Layer 7 is formed. The foam layer 7 is separated from the water tank body 1 by a conventionally known removing machine. 5 Discharged outside. On the other hand, the treated water separated from the foam after aeration is discharged from the treated water discharge port 22 through the advection port 21 opened below the weir plate 20 that divides the inside of the foam separation tank 5 from the discharge port 6. Is done.
[0016] 図 3は自吸式微細気泡発生装置 16の要部縦断面図である。モータ 17の駆動によ り内部が中空状の攪拌体であるインペラ 18が回転するとインペラ 18の中空部内に連 通して差し込まれた空気導入管 19近傍に負圧が生じ、空気導入管 19の大気開放さ れた上端より自ずと空気が吸引される構造にされている。この負圧は、インペラ 18付 近の水がインペラ 18から離反する方向に移動されるよう攪拌によって作用し生じる。 尚、自吸式微細気泡発生装置 16は本実施例に限定されず、他の構造の自吸式微 細気泡発生装置を使用してもよい。また、図中、 23は整流板で、インペラ 18による泡 沫分離槽 5内の水が共回りすることを防止するために水槽本体 15内の底部に設けら れている。 FIG. 3 is a longitudinal sectional view of a main part of the self-priming microbubble generator 16. When the motor 17 drives the impeller 18, which is a hollow agitator, rotates, a negative pressure is generated in the vicinity of the air introduction pipe 19, which is inserted into the hollow part of the impeller 18, and the air in the air introduction pipe 19 is released. The air is naturally sucked from the open upper end. This negative pressure acts by stirring so that water near the impeller 18 is moved away from the impeller 18. The self-priming microbubble generator 16 is not limited to the present embodiment, and a self-priming microbubble generator having another structure may be used. In the figure, reference numeral 23 denotes a flow straightening plate, which is provided at the bottom of the water tank main body 15 to prevent the water in the foam separation tank 5 from rotating together with the impeller 18.
[0017] 図 4は、膜分離活性汚泥処理槽 10の縦断面図である。膜分離活性汚泥処理槽 10 は、廃水中の窒素分を除去する脱窒槽 24とアンモニア分を微生物等を用いて硝ィ匕 処理する硝化槽 27とが仕切壁 26により区画されて!/ヽるが、活性汚泥処理による処理 水 11の性状に特に問題が無ければ、硝化槽 27だけで構成しても構わない。泡沫分 離槽 5で分離された泡沫 (スカム) 7は、移送ポンプ 9により移送され脱窒槽 24に導入 される。脱窒槽 24には泡沫 7の他に、硝化槽 27からの循環液が循環配管 28と循環 ポンプ 29により移送導入される。脱窒槽 24の底部には攪拌機 25が設けられており、 泡沫 (スカム) 7とこの循環液との攪拌混合を行なう。そして、脱窒槽 24内に許容量以 上の混合液が貯留すると、仕切壁 26を越して硝化槽 27へ流入する。硝化槽 27には 、槽内を好気的状態に維持するための散気装置 31とこれに空気を送るブロワ 30、散 気装置 31の上方に設置された分離膜 12及び分離膜 12を介して膜分離処理水を吸 引する吸引ポンプ 13が設置されている。硝化槽 27に流入した混合液は散気攪拌さ れながら、分離膜 12と吸引ポンプ 13により膜分離処理水 11と活性汚泥とに分離され 、処理水 11は膜分離活性汚泥処理槽 10の系外へ放流される。尚、吸引ポンプ 13は 、硝化槽 27内の水位が HWL (上限水位)になった時に起動され、 7J位が LWL (下 限水位)になった時に停止される。 [0018] 本発明の廃水処理方法及ぴ処理装置を用いると、現状では処理されていない漁港 や魚市場等の魚の水揚げ、魚の洗浄、冷凍魚の解凍、魚の解体時に発生する血液 や肉片等を含む大量の有機性廃水から汚濁成分を短時間で分離処理することがで きる。さらに、処理廃水に微生物処理等を施すことで海洋に再放流される海水の汚 濁負荷量を低減できる。 FIG. 4 is a longitudinal sectional view of the membrane separation activated sludge treatment tank 10. The membrane separation activated sludge treatment tank 10 is divided by a partition wall 26 into a denitrification tank 24 for removing nitrogen from wastewater and a nitrification tank 27 for nitrifying ammonia using microorganisms or the like. However, if there is no particular problem in the properties of the treatment water 11 by the activated sludge treatment, the treatment water 11 may be constituted only by the nitrification tank 27. The foam (scum) 7 separated in the foam separation tank 5 is transferred by the transfer pump 9 and introduced into the denitrification tank 24. In addition to the foam 7, a circulating fluid from a nitrification tank 27 is transferred and introduced into a denitrification tank 24 by a circulation pipe 28 and a circulation pump 29. A stirrer 25 is provided at the bottom of the denitrification tank 24, and stirs and mixes the foam (scum) 7 with the circulating liquid. Then, when a mixed liquid of an allowable amount or more is stored in the denitrification tank 24, it flows into the nitrification tank 27 through the partition wall 26. In the nitrification tank 27, an air diffuser 31 for maintaining the inside of the tank in an aerobic state, a blower 30 for sending air thereto, a separation membrane 12 installed above the air diffuser 31 and a separation membrane 12 are provided. A suction pump 13 is installed to suck the membrane separation treatment water. The mixed liquid flowing into the nitrification tank 27 is separated into membrane-treated water 11 and activated sludge by the separation membrane 12 and the suction pump 13 while being agitated and agitated, and the treated water 11 is treated by the membrane separation activated sludge treatment tank 10. Released outside. The suction pump 13 is activated when the water level in the nitrification tank 27 reaches HWL (upper limit water level), and is stopped when the 7J position becomes LWL (lower limit water level). [0018] Using the wastewater treatment method and the wastewater treatment apparatus of the present invention, blood and meat fragments generated during fish landing, washing, thawing frozen fish, and demolition of fish, which are not currently treated, are included. Pollutant components can be separated from large amounts of organic wastewater in a short time. Furthermore, the pollution load of seawater re-discharged to the ocean can be reduced by treating the treated wastewater with microorganisms.
[0019] [試験例]  [0019] [Test Example]
次に、本発明に基づいて廃水処理試験を行った結果を以下に示す。図 5に示す試 験装置を使用し、下記の試験条 O件で、漁港より採取した水揚げ、荷捌き廃水を泡沫 分離槽及ぴ膜分離活性汚泥処理槽にて廃水処理した。その結果を表 1に示す。 試験条件;  Next, the results of a wastewater treatment test based on the present invention are shown below. Using the test equipment shown in Fig. 5, under the following test conditions, the landing and unloading wastewater collected from the fishing port was treated in a foam separation tank and a membrane separation activated sludge treatment tank. The results are shown in Table 1. Test condition;
泡沫分離槽:自吸式泡沫分離槽 (有効容量 25L、滞留時間 30分間)  Foam separation tank: Self-priming foam separation tank (effective volume 25L, residence time 30 minutes)
膜分離活性汚泥処理槽:硝化槽のみ設置 (有効容量 5L、滞留時間約 12時間) 泡沫分離槽処理水量: 50L/時  Membrane separation activated sludge treatment tank: Installed only nitrification tank (effective capacity 5L, residence time about 12 hours) Foam separation tank treated water volume: 50L / hour
泡沫発生量:約 420ml/時  Foam generation amount: about 420ml / hour
膜ろ過水量:約 420ml/時 (7槽水位による間欠運転)  Membrane filtration water volume: about 420ml / h (intermittent operation by 7 tank water level)
分離膜モジュール:膜面積 0. lm2、フラックス 0. lmVm2-日 The separation membrane module: membrane area 0. lm 2, flux 0. lmVm 2 - day
[0020] [表 1] [0020] [Table 1]
Figure imgf000008_0001
Figure imgf000008_0001
[0021] 尚、表中、 C〇D¾JIS K0102 19アルカリ性過マンガン酸カリウムによる酸素消 費量で、濁度 ¾IIS K0101 9. 2透過光濁度 (波長 660nm)で、また蛋白質は分 光光度計による吸収スペクトル (波長 280nm)により測定した。 [0021] In the table, C〇D¾JIS K0102 19 Oxygen consumption by alkaline potassium permanganate, turbidity KIIS K0101 9.2 Transmitted light turbidity (wavelength 660 nm), and protein is measured by a spectrophotometer. It was measured by an absorption spectrum (wavelength 280 nm).
[0022] 次に、漁港における未処理廃水の汚濁濃度を測定した。その結果を表 2に示す。  Next, the pollution concentration of the untreated wastewater at the fishing port was measured. The results are shown in Table 2.
[0023] [表 2] 項目 濁度 (一) 蛋白質 (一) 海洋へ排水される廃水 36.7 0.085 0.461 [0024] 表 1、表 2の結果力も明らかなように、本発明の廃水処理により廃水の汚濁負荷は 約 50%低減され、除去された汚濁成分は約 97. 5%活性汚泥処理されていることが 確認された。 [Table 2] Items Turbidity (1) Protein (1) Wastewater discharged to the ocean 36.7 0.085 0.461 [0024] As is clear from the results in Tables 1 and 2, the pollution load of the wastewater is reduced by about 50% by the wastewater treatment of the present invention, and the removed pollutant is treated with about 97.5% activated sludge. Was confirmed.
実施例 2  Example 2
[0025] 図 6において、 1は漁港、魚市場および陸上養殖場等から発生する海水を主成分と する有機性廃水で、予め沈砂槽 2やスクリーン 3等の固液分離手段により魚肉片等の 固形物の除去などの前処理が施される。前処理された廃水 4は泡沫分離槽 5へ導入 され泡沫分離槽 5内の自吸式微細気泡発生装置 16により一定時間曝気されて泡沫 分離処理される。自吸式微細気泡発生装置 16は吸気量を可変できるため、気泡の 大きさを変えることができる。尚、ここで発生する気泡の大きさは lmm以下である。ま た、本実施例では自吸式微細気泡発生装置の例を示しているが、散気装置でも良く 、微細気泡を発生するものであれば、特に限定されるものではない。そして泡沫分離 槽 5の水面に浮上した泡沫 7は公知の搔き取機などで搔きとり、泡沫排出口 6から排 出される。ここで、泡沫分離槽 5では、廃水 4を槽内に一定時間滞留させる必要があ ることから、泡沫分離槽 5の 1台分の収容能力を超える廃水 4を処理せざるを得な!/ヽ 場合は、廃水 4を分配計量槽 (図示せず)で予め計量し、複数台の泡沫分離槽 5に 分配して処理しても良 ヽ。泡沫分離槽 5で曝気処理された曝気処理水 8の汚濁負荷 量は十分に低減しているので、通常はそのまま放流できる力 更に、オゾンガスと接 触させて酸化処理したり、凝集剤を混合し凝集沈殿槽へ導き沈殿分離処理を行った り、接触曝気槽などへ導入して微生物処理を施して汚濁負荷量を更に低減させて放 流するとなお良い。  In FIG. 6, reference numeral 1 denotes organic wastewater mainly composed of seawater generated from a fishing port, a fish market, an onshore farm, and the like. Pretreatment such as removal of solids is performed. The pretreated wastewater 4 is introduced into the foam separation tank 5 and is aerated for a certain time by the self-priming microbubble generator 16 in the foam separation tank 5 to be subjected to foam separation processing. Since the self-priming microbubble generator 16 can change the amount of intake air, the size of bubbles can be changed. The size of the bubbles generated here is 1 mm or less. Further, in this embodiment, an example of a self-priming microbubble generator is shown, but a diffuser may be used, and there is no particular limitation as long as it generates microbubbles. The foam 7 floating on the water surface of the foam separation tank 5 is removed by a known wiper or the like, and is discharged from the foam discharge port 6. Here, in the foam separation tank 5, since the wastewater 4 needs to stay in the tank for a certain period of time, the wastewater 4 that exceeds the capacity of one foam separation tank 5 must be treated! In the case of / ヽ, the wastewater 4 may be measured in advance in a distribution measuring tank (not shown) and distributed to a plurality of foam separation tanks 5 for treatment. Since the pollution load of the aerated water 8 aerated in the foam separation tank 5 has been sufficiently reduced, it is usually possible to discharge the water as it is.Furthermore, it can be oxidized by contact with ozone gas or mixed with a coagulant. It is more preferable to conduct the sedimentation separation treatment by leading to the coagulation sedimentation tank, or to introduce into the contact aeration tank and perform microbial treatment to further reduce the pollution load and discharge.
[0026] 一方、廃水 4から分離された泡沫 7の性状は、廃水 4よりも汚濁負荷濃度が高くはな つているものの、汚濁濃度がほぼ一定で、曝気処理の前の水量に比して極めて少量 になるため、活性汚泥処理に適した状態となる。搔き取機により泡沫排出口6から排 出された泡沫 7は、移送ポンプ 9により膜分離活性汚泥処理槽 10へ導入され、活性 汚泥処理されると共に、活性汚泥処理された処理水は分離膜 12を介して吸引ボン プ 13により吸引されて活性汚泥が膜分離され、清澄な膜分離処理水 11として放流さ れる。分離膜 12に用いられる膜の種類としては精密ろ過膜や限外ろ過膜などが利用 でき、膜の形状としてはシート状の平膜やチューブ状の中空糸膜などが利用できるが 、特に限定されるものではない。 [0026] On the other hand, the properties of the foam 7 separated from the wastewater 4 have a higher pollutant load concentration than the wastewater 4, but the pollutant concentration is almost constant, which is extremely large compared to the amount of water before the aeration treatment. Since the amount is small, it is suitable for activated sludge treatment. The foam 7 discharged from the foam discharge port 6 by the extractor is introduced into a membrane separation activated sludge treatment tank 10 by a transfer pump 9, where the activated sludge is treated. The activated sludge is sucked by the suction pump 13 through the membrane 12 to be subjected to membrane separation, and is discharged as clear membrane separation treated water 11. Microfiltration membrane or ultrafiltration membrane is used as the type of membrane used for the separation membrane 12. As the shape of the membrane, a sheet-like flat membrane or a tubular hollow fiber membrane can be used, but is not particularly limited.
[0027] 膜分離活性汚泥処理槽 10の余剰汚泥 14は、ポンプなど吸排出手段により底生生 物であるゴカイ 32が養殖される養殖水槽 35へ導入される。養殖水槽 35内にはろ過 材である砂 39が充填され、底部に砂が脱落せずかつ透水可能な連通穴が底部に設 けられ及ぴ または不織布が砂の下部に設置されてレヽる容器 38と、ブロワ一 37から 送られる空気を用いて養殖水槽内に空気を供給する散気装置 36と、養殖水槽 35内 部のろ過水を適宜容器 38へ還流させる循環ポンプ 34とから構成されている。ここで 、違通穴及び Zまたは不織布は容器 38の底部に設置されているが、側面にも設置 でき、特に限定されるものではない。容器 38は、余剰汚泥がろ過及び消化減量され た後にでる海水を排出できるように構成すれば良ぐ特に限定されるものではない。  [0027] The excess sludge 14 in the membrane separation activated sludge treatment tank 10 is introduced into a culture tank 35 in which benthic organisms 32 are cultured by suction and discharge means such as a pump. The culture tank 35 is filled with sand 39, which is a filtering material, and the bottom is provided with a communication hole that does not allow the sand to fall off and is permeable to water, or a non-woven fabric is installed at the bottom of the sand. 38, an air diffuser 36 that supplies air into the culture tank using air sent from the blower 37, and a circulation pump 34 that appropriately returns the filtered water in the culture tank 35 to the container 38. I have. Here, the through hole and the Z or nonwoven fabric are installed at the bottom of the container 38, but they can also be installed on the side surface, and are not particularly limited. The container 38 is not particularly limited as long as it can be configured to discharge the seawater generated after the excess sludge is filtered and digested and reduced.
[0028] 次に、本発明装置の動作を各構成要素ごとに説明する。  Next, the operation of the device of the present invention will be described for each component.
前処理された廃水 4は、泡沫分離槽 5の下部より供給され、該分離槽内で自吸式微 細気泡発生装置 16により曝気処理される。該微細気泡発生装置にて発生した気泡 は、泡沫分離槽 5内の廃水 4中の有機物や微細な浮遊物などを気泡表面に付着しな がら泡沫排出口 6へ向カゝつて浮上移動し、排出口 6近傍の水面上に泡沫層 7を形成 する。泡沫層 7は、従来公知の搔き取機にて泡沫分离廳5外へ排出される。一方曝 気後の泡沫分離された処理水 8は排出口 6から垂下して泡沫分離槽 5內部を区画す る板の下方を通り泡沫分離槽 5外へ排水される。  The pretreated wastewater 4 is supplied from the lower part of the foam separation tank 5 and is aerated by the self-priming microbubble generator 16 in the separation tank. The bubbles generated by the fine bubble generator float and move toward the foam discharge port 6 while adhering organic matter and fine suspended matter in the wastewater 4 in the foam separation tank 5 to the bubble surface. A foam layer 7 is formed on the water surface near the outlet 6. The foam layer 7 is discharged to the outside of the foam fractionating room 5 by a conventionally known wiper. On the other hand, the treated water 8 from which the foam has been separated after aeration is dripped from the outlet 6, and is discharged to the outside of the foam separation tank 5 through the lower part of the plate dividing the foam separation tank 5 內.
[0029] 泡沫分離槽 5で発生した泡沫 7は移送ポンプ 9にて膜分離活性汚泥処理槽 10へ送 られる。処理槽 10では、分離された泡沫 7の有機物分が活性汚泥により生物^?さ [0029] The foam 7 generated in the foam separation tank 5 is sent to a membrane separation activated sludge treatment tank 10 by a transfer pump 9. In the treatment tank 10, the organic matter in the separated foam 7 is converted into biological matter by activated sludge.
' れ、分離膜 12と吸引ポンプ 13により活性汚泥と処理水 11とに固液分離される。処理 槽 10内にはブロワ 16から供給される空気を槽内に供給する散気装置 17が設置され ており、活性汚泥への酸素供給と分離膜 12の空気洗浄を同時に行って 、る。 Then, solid-liquid separation into activated sludge and treated water 11 is performed by the separation membrane 12 and the suction pump 13. An air diffuser 17 for supplying the air supplied from the blower 16 into the treatment tank 10 is installed in the treatment tank 10, and simultaneously supplies oxygen to the activated sludge and cleans the separation membrane 12 with air.
[0030] —方、泡沫 7を活性汚泥処理し、増えて余剰となった余剰汚泥 14は、従来公知の ポンプ等で容器 38に充填された砂の上部に導入される。導入された余剰汚泥 14は 、ろ過材 39により固形物分がろ過され、容器 38の下部よりろ過水が養殖水槽 35へ 流れ出る仕組みとなっている。容器 38の内部のろ過材 39中にはゴカイ 32が飼育さ れており、余剰汚泥 14が導入され固形物分がろ過材 39により補足されると、その固 形物はゴカイ 32の飼料 (餌)として消化減量される。一方砂によりろ過された海水は、 養殖水槽 35へ移行し、散気装置 36により空気を供給されることにより溶存酸素度を 高め、循環ポンプ 34により容器 38へ送られる。尚、本実施例においては、底生生物 にゴカイを用いているが、他の堆積物食性底生生物でも良ぐまた二枚貝に代表され る懸濁物食生底生生物でも良く、さらには両者底生生物を混在させて用いても良い On the other hand, the foam 7 is subjected to activated sludge treatment, and the excess sludge 14 that has become excess is introduced into the upper portion of the sand filled in the container 38 by a conventionally known pump or the like. The surplus sludge 14 introduced has a structure in which a solid content is filtered by a filter medium 39, and filtered water flows out from a lower part of the container 38 into a culture tank 35. Gokai 32 is bred in the filter media 39 inside the container 38. When the excess sludge 14 is introduced and the solid matter is captured by the filter medium 39, the solid matter is digested and reduced as feed for the creature 32. On the other hand, the seawater filtered by the sand is transferred to the aquaculture tank 35, where the air is supplied by the air diffuser 36 to increase the dissolved oxygen content, and is sent to the container 38 by the circulation pump 34. In the present example, the benthic organism was used as a benthic organism, but other sediment-eating benthic organisms may be used, or a suspended food-eating benthic organism represented by bivalves may be used. You may use a mixture of benthic organisms
[0031] ここで養殖水槽 35の水位は、導入される余剰汚泥 14力 S移送されることにより増加 するが、図示しない従来公知の水位検出器を用いて水位を検出し、一定レベルに水 位が達したら、水槽下部の水位調整パルプ' 33を開き、通常のレベルまで水位を落と すことができる。その他の水位調整手段としては、図 7に示すようなォ一パーフロー管 40を用!/ヽても良く、流出先の高さによって使!/ヽ分ければ良レ、。 [0031] Here, the water level in the aquaculture tank 35 is increased due to the transfer of the excess sludge introduced by 14 S, but the water level is detected using a conventionally known water level detector (not shown), and the water level is maintained at a certain level. When the water level reaches, you can open the water level adjusting pulp '33 at the bottom of the tank and lower the water level to the normal level. As another water level adjusting means, use an overflow pipe 40 as shown in Fig. 7! / You may use it depending on the height of the outflow destination.
[0032] 本発明の処理方法及び処理装置を用いると、現状では処理されて!/ヽな ヽ漁港、魚 市場おょぴ陸上養殖場等の魚の水揚げ、魚の洗浄、冷凍魚の解凍、魚の解体時に 発生する血液や肉片等を含む海水を主成分とする有機性廃水から汚濁成分のみを 短時間で分離し、次!/、で分離した廃水に微生物処理を施すことで海洋に流れ込む 汚濁負荷量を削減でき、さらに、微生物^;理で発生した余剰汚泥をゴカイ等の堆積 物食性底生生物及び/または二枚貝に代表される懸濁物食性底生生物の飼料 (餌 )とし消化減量させることで、最終の余剰汚泥処理費用を削減できる。本実施例では 、海水を主成分とする有機性廃水について述ぺたが、魚類の処理に起因する廃水 であれば、海水や淡水など処理対象が特に限定されるものではな ヽ。  [0032] With the processing method and the processing apparatus of the present invention, the processing is currently performed! / Pana fishing port, fish market, landing of fish at land farms, washing of fish, thawing of frozen fish, and only pollutants from organic wastewater mainly composed of seawater, including blood and meat fragments generated when fish are dismantled Is separated in a short time and the next! Microbial treatment of wastewater separated in /, can reduce the pollution load flowing into the ocean, and the excess sludge generated by microorganisms can be represented by sedimentary edible benthic organisms such as creatures and / or bivalves The final sludge disposal cost can be reduced by reducing the amount of suspended sludge by using it as feed (feed) for edible benthic organisms. In the present embodiment, the organic wastewater containing seawater as a main component has been described. However, as long as the wastewater is caused by the treatment of fish, the object to be treated such as seawater or freshwater is not particularly limited.
[0033] P室上養殖場の廃水を処理する場合は、有德性廃水中に大きな固形物や砂等の夾 雑物が含まれな 、ので、養殖水槽から出てきた排水を直接泡沫分離槽 5へ投入し、 これまで説明した方法にて処理することができる。  [0033] When treating the wastewater from the P-room upper aquaculture farm, since the wastewater does not contain large solids or contaminants such as sand, the wastewater coming out of the aquaculture tank is directly foam-separated. It is put into the tank 5 and can be treated by the method described above.
[0034] 次に、図 8に示す試験装置を使用して、本発明方法に基づいて有機性廃水及ぴ有 機性汚泥の処理試験を行った。  Next, using the test apparatus shown in FIG. 8, a treatment test of organic wastewater and organic sludge was performed based on the method of the present invention.
前処理槽 、流量調整槽8、接触曝気槽 C及び沈殿槽 Dからなる実際の魚市場の 廃水処理施設 Fに泡沫分離槽を設置し、流入する廃水を前記廃水処理施設 Pの流 量調整槽 B力もポンプにて泡沫分離槽 5へ移送し、曝気処理し、発生した泡沫の一 部を泡末貯留タンク 41に一旦貯留した後、小規模の膜分離活性汚泥処理槽 10へ 投入し活性汚泥処理を行った後、活性汚泥をゴカイ 32が飼育されて Vヽる養殖水槽 3 5へ 1日 1回 40ml採取し投入した。水質は、流量調整槽 Bから移送する廃水、曝気処 理水、発生した泡沫、および膜分離活性汚泥の処理水について測定を行なった。そ の結果を表 3に示す。 A foam separation tank is installed in the actual fish market wastewater treatment facility F consisting of a pretreatment tank, a flow control tank 8, a contact aeration tank C, and a sedimentation tank D, and inflows wastewater to the wastewater treatment facility P. The volume adjustment tank B is also transferred to the foam separation tank 5 by a pump, aerated, and a part of the generated foam is temporarily stored in the foam storage tank 41, and then put into the small-scale membrane separation activated sludge treatment tank 10. After performing the activated sludge treatment, 40 ml of the activated sludge was collected and fed once a day to the culture tank 35, where Pokai 32 was bred. Water quality was measured for wastewater transferred from the flow control tank B, aerated water, generated foam, and treated water of membrane separation activated sludge. The results are shown in Table 3.
[0035] 試験装置及ひ 験条件; [0035] test equipment and test conditions;
泡沫分離槽:自吸式泡沫分離槽、有効容量 600L、滞留時間 120分  Foam separation tank: Self-priming foam separation tank, effective capacity 600L, residence time 120 minutes
膜分離活性汚泥処理槽:脱窒槽、硝化槽を設置、有効容量 15L  Membrane separation activated sludge treatment tank: denitrification tank, nitrification tank installed, effective capacity 15L
滞留時間:約 5日  Residence time: about 5 days
泡沫分離槽処理水量: 300L/時  Water treatment volume of foam separation tank: 300L / hour
泡沫発生量:約 15L/時  Foam generation: about 15L / hour
膜ろ過水量:約 125LZ時冰槽水位による間欠運転)  Membrane filtration water volume: Approximately 125LZ, intermittent operation by ice tank water level)
分離膜モジュール:膜面積 0. lm2、フラックス 0. 03mVm2-日 The separation membrane module: membrane area 0. lm 2, flux 0. 03mVm 2 - day
養殖水槽: 5Lフラスコ(有効容量 3L)、容器 0. 5L、ゴカイ重量 20g  Aquaculture tank: 5L flask (effective volume 3L), container 0.5L, weight of squid 20g
養殖水槽への投入余剰汚泥量:約 3g/日(乾物)(湿潤状態 .'40mlZ日) 還流水量: SOmlZ分  Surplus sludge input to aquaculture tanks: Approx. 3 g / day (dry matter) (wet state .'40 mlZ day)
[0036] [表 3] [Table 3]
Figure imgf000012_0001
Figure imgf000012_0001
[0037] 尚、表中、 COD^JIS K0102 19アルカリ性過マンガン酸カリウムによる酸素消 費量で、濁度は HACH社製 DR2000の FTU濁度計で、また蛋白質は Lowry— Fol in法における吸収スペクトル (波長 750nm)を測定し、検量線より水中の濃度を算出 した。 [0037] In the table, COD ^ JIS K0102 19 Oxygen consumption by alkaline potassium permanganate, turbidity is measured by FTU turbidity meter of DR2000 manufactured by HACH, and protein is measured by Lowry-Fol in method. (Wavelength 750 nm) and the concentration in water was calculated from the calibration curve.
[0038] 表 1から明ら力なように、本発明の処理方法により廃水の汚濁負荷が約 78%低減さ れ、除去された汚濁成分は約 96%活性汚泥処理されて!/、ることが確認された。 [0039] ゴカイによる汚泥の消化減量度合については、ろ過により捕足された汚泥の捕食具 合を目視にて経過観察した。その経過状態を図 9及ぴ図 10に示す。図 9は活性汚泥 投入後 1時間経過した養殖水槽の内部写真、図 10は活性汚泥投入後約 1日経過し た養殖水槽の内部写真である。これらの写真から判るように、活性汚泥投入後約 1日 で、投入された汚泥は、ゴカイによりほぼ全量捕食された。尚、こうして養殖されたゴ カイは釣り餌としての利用を図ることもできる。 [0038] As is apparent from Table 1, the treatment method of the present invention reduces the pollution load of wastewater by about 78%, and the removed pollutant components are treated by activated sludge by about 96%! /, It was confirmed. [0039] Regarding the degree of sludge digestion and weight loss by the creatures, the degree of predation of the sludge caught by filtration was visually observed. The progress is shown in FIGS. 9 and 10. Fig. 9 is a photograph of the inside of the aquaculture tank one hour after the activated sludge was injected, and Fig. 10 is a photograph of the inside of the aquaculture tank approximately one day after the activated sludge was introduced. As can be seen from these photographs, approximately one day after the input of activated sludge, almost all of the input sludge was eaten by Gokai. The larvae cultivated in this way can also be used as fishing baits.
産業上の利用可能性  Industrial applicability
[0040] 以上のように、本発明の廃水処理方法及ぴ装置により、漁港や魚市場等で大量に 発生する有機性廃水の浄ィ匕処理を可能にすることができ、その結果、海洋汚染の防 止に大きく寄与することができる。  [0040] As described above, the wastewater treatment method and apparatus of the present invention can enable purification treatment of organic wastewater generated in large quantities at fishing ports, fish markets, and the like. This can greatly contribute to the prevention of noise.
本発明の処理方法及び装置により、再放流廃水の汚濁負荷を約 80%程度削減で きる。さらにゴカイ等の底生生物に汚泥を捕食させ消化減量することにより、最終的な 残滓の焼却処理が不要になるので、処理施設の維持管理コストが削減できるばかり でなぐ化石燃料等の省資源対策の一環となり得る。ざらに、本発明方法により養殖 されたゴカイは釣り餌として利用できるので、省資源並びに資源リサイクルに大きく寄 与することができる  The treatment method and apparatus of the present invention can reduce the pollution load of re-discharge wastewater by about 80%. In addition, by preserving sludge by benthic organisms such as moss and reducing digestion, it is not necessary to incinerate the final residue, so that it is not only possible to reduce the maintenance cost of the treatment facility, but also to save resources such as fossil fuel Can be part of In addition, since the larvae cultivated by the method of the present invention can be used as fishing baits, they can greatly contribute to resource saving and resource recycling.

Claims

請求の範囲 The scope of the claims
[1] 漁港や魚市場等力 発生する有機性廃水の処理方法であって、魚肉片等の固形 物を除去処理した廃水を曝気処理し、曝気処理により発生した泡沫を活性汚泥処理 すると共に、膜ろ過することを特徴とする漁港や魚市場等から発生する有機性廃水 の処理方法。  [1] A method for treating organic wastewater generated at fishing ports, fish markets, etc., in which wastewater from which solids such as fish meat pieces have been removed is aerated and foam generated by the aeration is treated with activated sludge. A method for treating organic wastewater generated from fishing ports, fish markets, etc., characterized by membrane filtration.
[2] 漁港や魚市場等力 発生する有機性廃水の処理装置であって、魚肉片等の固形 物を除去処理した廃水が導入される泡沫分離槽と、該泡沫分離槽内に設置され廃 水中に微細気泡を発生させる気泡発生手段と、発生した泡沫が導入される膜分離活 性汚泥処理槽とを有することを特徴とする漁港や魚市場等から発生する有機性廃水 の処理装置。  [2] An organic wastewater treatment device that generates power at fishing ports and fish markets, etc., and a foam separation tank into which wastewater from which solid substances such as fish meat pieces have been removed is introduced, and a wastewater separation tank installed in the foam separation tank. An apparatus for treating organic wastewater generated from a fishing port, a fish market or the like, characterized by having a bubble generating means for generating fine bubbles in water and a membrane separation activated sludge treatment tank into which the generated foam is introduced.
[3] 気泡発生手段が自吸式微細気泡発生装置であることを特徴とする請求項 2記載の 漁港や魚市場等から発生する有機†生廃水の処理装置。  [3] The apparatus for treating organic raw wastewater generated from a fishing port or a fish market according to claim 2, wherein the bubble generating means is a self-priming fine bubble generating apparatus.
[4] 漁港、魚市場およぴ睦上養殖場等から発生する有機性廃水を受入れ、生物処理し[4] Accept organic wastewater generated from fishing ports, fish markets, mud farms, etc. and treat it biologically.
、生物処理後に発生する余剰有機性汚泥を、底生生物が飼育される養殖水槽へ導 入し、前記余剰有機性汚泥を当該底生生物の飼料となして消化減量処理することを 特徴とする有機性汚泥の処理方法。 Introducing excess organic sludge generated after biological treatment into a culture tank in which benthic organisms are bred, and treating the excess organic sludge as feed for the benthic organisms for digestion and weight reduction. Organic sludge treatment method.
[5] 前記生物処理が、活性汚泥法によるものであることを特徴とする請求項 4に記載の有 機性汚泥の処理方法。 [5] The method for treating organic sludge according to claim 4, wherein the biological treatment is performed by an activated sludge method.
[6] 漁港、魚市場および陸上養殖場等から発生する有機性廃水及び有機性汚泥の処 理装置であって、魚肉片等の固形物を除去処理した廃水が導入される泡沫分離槽と 、該泡沫分離槽内に設置され廃水中に微細気泡を発生させる気泡発生手段と、泡 沫分離槽内で発生した泡沫が導入される膜分離活性汚泥処理槽と、該膜分離活性 汚泥処理槽から発生する余剰有機性汚泥が導入されかつ底生生物力 S飼育される養 殖水槽とを具備することを特徴とする有機性廃水及び有機性汚泥の処理装置。  [6] A device for treating organic wastewater and organic sludge generated from a fishing port, a fish market, a land farm, etc., wherein a wastewater from which solid matter such as fish pieces has been removed is introduced, A bubble generating means installed in the foam separation tank to generate fine bubbles in waste water; a membrane separation activated sludge treatment tank into which foam generated in the foam separation tank is introduced; and a membrane separation activated sludge treatment tank. An apparatus for treating organic wastewater and organic sludge, comprising: a culture tank in which surplus organic sludge generated is introduced and benthic biomass is bred.
[7] 前記養殖水槽に砂等のろ過材を充填し、ろ過水を得ることを特徴とする請求項 4乃 至請求項 6のいずれかに記載の有機性汚泥の処理方法と有機性廃水及ぴ有機性 汚泥の処理装置。  [7] The method for treating organic sludge and the method for treating organic wastewater according to any one of claims 4 to 6, wherein the culture tank is filled with a filtering material such as sand to obtain filtered water.ぴ Organic sludge treatment equipment.
[8] 前記底生生物が、堆積物食性底生生物及び Zまたは懸濁物食性底生生物である ことを特徴とする請求項 4乃至請求項 7のいずれかに記載の有機性汚泥の処理方法 と有機性廃水及び有機性汚泥の処理装置。 [8] The benthic organism is a sedimentary benthic benthic and a Z or suspended sedimentary benthic The method for treating organic sludge and the apparatus for treating organic wastewater and organic sludge according to any one of claims 4 to 7, characterized in that:
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CN111423060A (en) * 2020-04-09 2020-07-17 山东瑞赛克环保有限公司 Blood wastewater treatment process and device
US11518699B2 (en) 2019-03-29 2022-12-06 Aqua-Terra Consultants Wastewater treatment system and methods utilizing chemical pre-treatment and foam fractionation

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CN111423060A (en) * 2020-04-09 2020-07-17 山东瑞赛克环保有限公司 Blood wastewater treatment process and device

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