WO2004090294A1 - Structure de filtration pour les gaz d'echappement d'un moteur a combustion interne - Google Patents
Structure de filtration pour les gaz d'echappement d'un moteur a combustion interne Download PDFInfo
- Publication number
- WO2004090294A1 WO2004090294A1 PCT/FR2004/000786 FR2004000786W WO2004090294A1 WO 2004090294 A1 WO2004090294 A1 WO 2004090294A1 FR 2004000786 W FR2004000786 W FR 2004000786W WO 2004090294 A1 WO2004090294 A1 WO 2004090294A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- face
- seal
- adhesion
- region
- zone
- Prior art date
Links
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
- F01N3/021—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
- F01N3/022—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters characterised by specially adapted filtering structure, e.g. honeycomb, mesh or fibrous
- F01N3/0222—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters characterised by specially adapted filtering structure, e.g. honeycomb, mesh or fibrous the structure being monolithic, e.g. honeycombs
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
- F01N3/021—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
- F01N3/022—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters characterised by specially adapted filtering structure, e.g. honeycomb, mesh or fibrous
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
- B01D46/24—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies
- B01D46/2403—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies characterised by the physical shape or structure of the filtering element
- B01D46/2418—Honeycomb filters
- B01D46/2422—Mounting of the body within a housing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/9445—Simultaneously removing carbon monoxide, hydrocarbons or nitrogen oxides making use of three-way catalysts [TWC] or four-way-catalysts [FWC]
- B01D53/9454—Simultaneously removing carbon monoxide, hydrocarbons or nitrogen oxides making use of three-way catalysts [TWC] or four-way-catalysts [FWC] characterised by a specific device
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/24—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
- F01N3/28—Construction of catalytic reactors
- F01N3/2839—Arrangements for mounting catalyst support in housing, e.g. with means for compensating thermal expansion or vibration
- F01N3/2842—Arrangements for mounting catalyst support in housing, e.g. with means for compensating thermal expansion or vibration specially adapted for monolithic supports, e.g. of honeycomb type
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2265/00—Casings, housings or mounting for filters specially adapted for separating dispersed particles from gases or vapours
- B01D2265/04—Permanent measures for connecting different parts of the filter, e.g. welding, glueing or moulding
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2450/00—Methods or apparatus for fitting, inserting or repairing different elements
- F01N2450/28—Methods or apparatus for fitting, inserting or repairing different elements by using adhesive material, e.g. cement
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/10—Internal combustion engine [ICE] based vehicles
- Y02T10/12—Improving ICE efficiencies
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S55/00—Gas separation
- Y10S55/05—Methods of making filter
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S55/00—Gas separation
- Y10S55/10—Residue burned
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S55/00—Gas separation
- Y10S55/30—Exhaust treatment
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24149—Honeycomb-like
Definitions
- the present invention relates to a filtration structure, in particular a particulate filter for the exhaust gases of an internal combustion engine, of the type comprising:
- Such structures are used in particular in the exhaust gas pollution control devices of internal combustion engines. These devices comprise an exhaust pipe comprising in series a catalytic purification member and a particulate filter.
- the catalytic purification unit is suitable for the treatment of pollutant emissions in the gas phase, while the particulate filter is adapted to retain the soot particles emitted by the engine.
- the filtering members comprise a set of adjacent conduits of parallel axes, separated by porous filtration walls. These ducts extend between an intake face of the exhaust gas to be filtered and a discharge face of the filtered exhaust gas. These ducts are also closed at one or other of their ends to define inlet chambers opening on the intake face and outlet chambers opening along the discharge face.
- These structures operate in a succession of filtration and regeneration phases. During the filtration phases, the soot particles emitted by the engine are deposited on the walls of the inlet chambers. The pressure drop across the filter increases gradually. Beyond a predetermined value of this pressure drop, a regeneration phase is performed.
- the soot particles composed mainly of carbon
- the soot particles are burned on the walls of the inlet chambers in order to restore the structure to its original properties.
- the soot particles do not accumulate homogeneously in the filtering members.
- the soot accumulates preferentially in the center of the filtration structure and towards the evacuation face of the exhaust gases.
- soot combustion causes a rise in temperature in the preferential accumulation zones, higher than the rise in temperature observed in the other zones of the structure.
- the temperature gradients within the filtration structure generate local expansions of different amplitudes, and consequently, longitudinal and transverse stresses in and / or between the different filtration members.
- connection joints whose thickness is chosen in the range of 0.3 to 3 mm and whose conductivity thermal is between 0.1 and 10 W / mK
- the main object of the invention is to overcome this disadvantage, that is to say to provide a porous filtration structure for a particle filter allowing prolonged use of the filter.
- the subject of the invention is a filtration structure of the aforementioned type, characterized in that the first face comprises at least a first zone of strong adhesion with said seal and at least one weak or zero adhesion zone with this seal, said zones respectively comprising a first region of strong adhesion with said seal and a weak or zero adhesion region with this seal, said regions being respectively disposed opposite a first weak or zero adhesion region; the second face with said seal, and a strong adhesion region of the second face with said seal.
- the filtration structure according to the invention may comprise one or more of the following characteristics, taken separately or in any technically possible combination:
- the first face further comprises a second zone of strong adhesion with said seal having a second region of strong adhesion with said seal disposed opposite a second weak or zero adhesion region of the second face with said seal; in at least one section of the filtration structure, the weak or zero adhesion region with said seal of the first face is disposed between the first and second regions of strong adhesion with said seal of this first face;
- said section is a longitudinal section; - said section is a cross section;
- a filter member is a prismatic brick, each of the side faces is facing a side face of an associated filter member, a connecting joint of said faces extending between said faces; and each of the lateral faces of the brick comprises at least one zone of strong adhesion of this face of the brick with said seal and at least one zone of weak or zero adhesion of this face with said seal, said zones respectively comprising a region strong adhesion of this face of the brick with said seal and a low or no adhesion region of this face with said seal, said regions being respectively disposed opposite a weak or zero adhesion region with said seal the face facing the associated filter member and a strong adhesion region with said seal of the face facing the associated filter member;
- the region of strong adhesion with said seal of the first face of the brick is disposed opposite a weak or zero adhesion region with said seal of a second face of the same brick;
- each of the zones of weak or no adhesion with said joint is covered with a non-stick coating, at least before commissioning of the structure;
- the first and second filter members each comprise an intake face and an evacuation face connected respectively by said first and second faces, at least one weak or zero adhesion-free downstream region with said seal of the first face; extending to the common edge between the discharge face and said first face;
- downstream region has a length, taken parallel to a longitudinal direction of the first filter member, less than one fifth of the length of said first filter member, taken in said longitudinal direction; - said downstream region has a length, taken parallel to a longitudinal direction of the first filter member, less than half of at least one other region of the same face;
- the first filtering member further comprises a lateral face adjacent to the first face, the lateral face having a strong lateral region of adhesion with said seal extending to the common exit edge of said lateral face and face evacuation;
- the downstream region of low or no adhesion with the seal has, on the side of the joint, surface irregularities, including bosses and / or grooves.
- the term "prismatic brick” designates an assembly comprising an entrance face, an exit face and at least three lateral faces which connect the entry face to the exit face.
- FIG. 1 is a perspective view of a first filter structure according to the invention
- Figure 2 is a partial sectional view taken along the line II-II of the filtration structure of Figure 1;
- Figure 3 is a partial exploded perspective view of the filtration structure of Figure 1;
- - Figure 4 is a view similar to Figure 2 after several cycles of regeneration of the filter structure
- - Figure 5 is a view similar to Figure 3 of a variant of the first filter structure according to the invention
- FIG. 6 is a view similar to Figure 2 of a second filter structure according to the invention
- - Figure 7 is a view similar to Figure 4, on a larger scale, of a third filter structure according to the invention
- FIG. 8 is a view similar to Figure 3 of a fourth filter structure according to the invention.
- Figure 9 is a view similar to Figure 2, on a larger scale, of a fifth filtration structure according to the invention.
- the particulate filter 11 shown in Figure 1 is disposed in a line 13 of the exhaust gas of a motor vehicle diesel engine, shown partially.
- This exhaust line 13 extends beyond the ends of the particulate filter 11 and defines an exhaust flow passage.
- the particulate filter 11 extends along a longitudinal X-X 'direction of circulation of the exhaust gas. It comprises a plurality of filtration blocks 15 interconnected by connecting joints 17. Each filter unit 15 is of substantially rectangular parallelepipedal shape elongate in the longitudinal direction X-X '.
- each filtration unit 15A, 15B comprises a porous filtration structure 19, an inlet face 21 for the exhaust gases to be filtered, a face 23 for exhausting the filtered exhaust gases, and at least four lateral faces 24.
- the porous filtration structure 19 is made of a filtration material consisting of a monolithic structure, in particular ceramic (cordierite or silicon carbide).
- This structure 19 has a sufficient porosity to allow the passage of the exhaust gas. However, as known per se, the diameter of the pores is chosen small enough to ensure retention of the soot particles.
- the porous structure 19 comprises a set of adjacent ducts having an axis parallel to the longitudinal direction X-X '. These conduits are separated by porous filtration walls. In the example illustrated in FIG. 1, these walls 25 are of constant thickness and extend longitudinally in the filtration structure 19, from the intake face 21 to the discharge face 23.
- the ducts are divided into a first group of inlet ducts 27 and a second group of outlet ducts 29.
- the inlet ducts 27 and the outlet ducts 29 are arranged head to tail.
- the inlet ducts 27 are closed at the discharge face 23 of the filtration unit 15A, 15B and are open at their other end.
- outlet ducts 29 are closed at the inlet face 21 of the filtration unit 15A, 15B and open out along its evacuation face 23.
- inlet and outlet ducts 29 and 29 have constant sections along their entire length.
- the side faces 24 of the filter block located opposite another filtration unit are planar.
- the lateral faces 31 situated opposite the exhaust line 13 are of a shape adapted to ensure contact with the cylindrical inner wall of this line 13.
- each of the flat faces 24 situated facing another filtration unit comprises at least one zone 33 firmly attached to the gasket 17, and at least one zone 35, which during manufacture of the structure 19, is covered with a non-stick coating.
- This coating is for example based on paper, polytetrafluoroethylene, or boron nitride.
- the zone 33 constitutes a region of strong adhesion with the seal 17, while the zone 35 constitutes a weak or zero adhesion region with the seal 17.
- the adhesion between the connecting joint 17 and the flat faces 24 of the filtration units 15 in the areas 33 of strong adhesion is at least 10 times greater than that of areas of low or no adhesion, this adhesion being between 0 and 50 MPa.
- the arrangement of the zones 33 and the zones 35 on the flat faces 24 of the filtration units 15 is illustrated in FIGS. 2 and 3.
- the first planar face 24A of the first filtration unit 15A comprises successively, in the longitudinal direction X-X ', a first zone 33A of strong adhesion with the seal 17, a zone 35A of low or no adhesion with the seal 17 and a second zone 33C of strong adhesion with the seal 17
- the second filtration unit 15B comprises a second face 24B, facing the first face 24A.
- This second face 24B comprises successively in the direction X-X ', a first zone 35B with little or no adhesion opposite the first zone 33A of strong adhesion of the first face 24A, a zone 33B of strong adhesion, in view of the zone 35B low or no adhesion of the first face 24A, and a second zone 35C low or no adhesion facing the second zone 33C strong adhesion of the first face 24A.
- the connecting joint 17 is disposed between the flat faces 24 of the filtration blocks 15.
- This connecting joint 17 is made of ceramic cement, generally consisting of silica and / or silicon carbide and / or aluminum nitride . After sintering, this cement has a modulus of elasticity of about 5000 MPa. This cement secures the filtration blocks together.
- a first filtration stage is constituted by two-by-two assembly along vertical surfaces of filter blocks 15 by means of the connecting joint 17.
- a second filtration stage is then produced according to the same process.
- connection joint is made of a very rigid cement
- protections for example cardboard covers
- the particulate-laden exhaust gases are guided to the inlet faces 21 of the filtration units 15 via the exhaust line 13. As indicated by arrows on the 2, they then enter the inlet ducts 27 and pass through the walls 25 of the porous structure 19. During this passage, the soot is deposited on the walls 25 of the inlet ducts 27. preferentially deposited in the center of the particulate filter 11 and towards the evacuation face 23 filtration blocks 15 (right in the drawing).
- the filtered exhaust gas escapes through the exhaust ducts 29 and is guided towards the outlet of the exhaust pipe.
- the pressure drop across the filter 11 increases significantly. A regeneration phase is then performed.
- soot is oxidized by raising the temperature of the filter 11. This oxidation is exothermic.
- the inhomogeneous distribution of soot in filter 11 causes a temperature gradient between areas of high soot accumulation and areas of low soot accumulation.
- the filtration blocks and the joints expand under the effect of temperature.
- the local amplitude of this expansion depends on the temperature.
- the areas of low or no adhesion and those of strong adhesion are arranged in such a way that, if the thermomechanical stresses are too strong for the structure, the cracking is done in privileged zones 41.
- the propagation of the cracks 41 in the joints 17 is guided along the areas of little or no adhesion of the seal 17 on the plane faces 24 of the filtration blocks 15.
- the cracks 41 between the first filtration unit 15A and the second filtration unit 15B are located along the first zone 35B with little or no adhesion of the second face 24B, then between the right end of this zone 35B and the left end of the zone 35A with little or no adhesion of the first face and following the latter zone 35A with little or no adhesion.
- a first portion 43A of seal 17 remains integral with the first filter unit 15A following the first zone 33A of strong adhesion of the first face 24A.
- a second portion 43B of seal 17 of complementary shape to the first portion 43A remains integral with the second filtration unit 15B following the strong adhesion zone 33B of the second face 24B.
- first and second portions 43A and 43B of joint 17 prevents the relative longitudinal movement of the first filter unit 15A with respect to the second filter unit 15B towards the discharge faces 23 of the filtration units 15A and 15B. Furthermore, the propagation of cracks 41 is guided between the right end of zone 35A with little or no adhesion from first face 24A to the left end of second zone 35C with little or no adhesion to the second face 24B and following this second zone 35C.
- the first filter unit 15A remains integral with a third portion 43C of seal 17 opposite the second zone 33C of strong adhesion of the first face 24A.
- This third portion 43C is of complementary shape to the second portion 43B of seal 17.
- This third portion 43C cooperates with the second portion 43B to prevent relative movement of the first block 15A relative to the second block 15B in the longitudinal direction XX 'to the inlet faces 21 of the filter blocks 15A and 15B.
- relaxation of thermomechanical stresses is ensured, depending on their intensity, by the structure itself (in the event of presence of zones of zero adhesion), and by the formation of cracks 41 whose propagation is controlled .
- areas 33 of strong adhesion with the seal 17 and areas of low or no adhesion with the seal 17, on each of the flat faces 24 of the filtration units 15, are successively alternately arranged on the one hand, directions parallel to the longitudinal direction XX 'and on the other hand, directions parallel to the transverse directions Y-Y' and ZZ 'perpendicular at the longitudinal direction X-X '.
- the zones 33 and the zones 35 thus form a checkerboard structure on each face 24 of each block 15.
- the areas 33 of strong adhesion with the seal 17 and the areas 35 of low or no adhesion with the seal 17 of a face 24 of a block 15 are situated respectively opposite areas of low adhesion or zero with the seal 17 and zones 33 of strong adhesion with the seal 17 of a face 24 of another block 15.
- 15C comprises successively in the direction X-X ', on a first face 24D, a single zone 33D of strong adhesion with the seal 17 and a single zone 35D of weak adhesion with the seal 17. It furthermore comprises on a second face 24E opposite the first face 24D, a second zone 35E with little or no adhesion opposite the first zone 33D of strong adhesion with the seal 17, and a second zone 33E of strong adhesion with the seal 17 opposite the first zone 35D low or no adhesion with the seal 17.
- Filtration 15D and 15E situated opposite the first and second faces 24D and 24E comprise zones of strong adhesion and areas of weak adhesion facing, respectively, areas of low adhesion 35D, 35E and areas of strong adhesion. 33D, 33E of the first and second faces 24D and 24E of the central filter block 15C.
- a portion of a zone of strong adhesion of a face of a block may be arranged facing a portion of a strong bond zone of a facing block.
- a part of a zone of weak or zero adhesion of a face of a block may be arranged facing a part of a zone of weak or no adhesion of a facing block.
- the first face 24A comprises successively, from upstream to downstream, parallel to the longitudinal direction X-X ', a fourth zone 33E of strong adhesion with the joint 17, a fifth zone 35F of low or no adhesion with the seal 17, a sixth zone 33G of strong adhesion with the seal 17 and a seventh zone 35H of weak or no adhesion with the seal 17.
- Each zone 33 of strong adhesion with the seal 17 of the first face 24A is disposed facing a zone 35 of low or no adhesion with the seal 17 of the second face 24B.
- each area 35 of low or no adhesion with the seal 17 of the first face 24A is disposed opposite a zone 33 of strong adhesion with the seal 17 of the second face 24B.
- the seventh zone 35H with little or no adhesion to the seal 17 is delimited downstream by the common edge 71 between the first face 24A and the outlet face 23 of the first filtration unit 15A.
- each of the sixth zone 33G and the seventh zone 35H taken along the longitudinal direction XX ' is less than one fifth of the length of the first filtering unit 15A, taken along the longitudinal direction X-X', and at half the length of each of the third and fourth zones 33E and 35F, also taken in the longitudinal direction X-X '.
- this arrangement makes it possible to retain any downstream portion 115A of the first filtration unit 15A delimited by a transverse cracking plane P, situated between the inlet face 21 and a transverse plane P 'passing through the downstream edge 73 of the sixth zone 33G.
- any downstream portion of the second filter block 15B delimited by a transverse cracking plane located between the face of the input 21 and a plane P "passing through the downstream edge 75 of the fifth zone 35F, is retained.
- each block 15 has at least a first face 24K which presents successively, from upstream to downstream, a first zone 35K with little or no adhesion to the joint 17, a zone 33K strong adhesion with the seal 17 and a second zone 35L of low or no adhesion with the seal 17, delimited downstream by the edge 71 K common between the first face 24K and the exit face 23.
- each block 15 furthermore has a lateral face 24M, adjacent to the first face 24K, which presents successively, from upstream to downstream, a first zone 33M of strong adhesion with the joint 17, a zone 35M of low or no adhesion with the seal 17 and a second zone 33 N of strong adhesion with the seal 17, adjacent to the output edge 71 M, common to the side face 24M and the outlet face 23.
- each zone 33 of strong adhesion with the seal 17 of the first face 24K is adjacent to a zone 35 of low or no adhesion with the seal 17 of the adjacent face 24M.
- the areas of low or zero adhesion of each block also have, on the side of the joint 17, surface irregularities 81, such as grooves and / or bores, as described in the French application No. 03 08588 of the Applicant.
- these surface irregularities 81 extend parallel to a direction inclined or transverse to the longitudinal direction X-X 'of the block 15. These irregularities 81 cause an increase in the roughness of the areas of low or zero adhesion.
- the increased roughness in the zone 35C with little or no adhesion with the seal 17, adjacent to the common edge 71 of the first block 15A makes it possible to retain a downstream portion 115A of the first filtration unit which could detach in case of cracking following a transverse plane within the first block 15A.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Toxicology (AREA)
- Biomedical Technology (AREA)
- Physics & Mathematics (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Geometry (AREA)
- Filtering Materials (AREA)
- Filtering Of Dispersed Particles In Gases (AREA)
- Exhaust Gas After Treatment (AREA)
- Cylinder Crankcases Of Internal Combustion Engines (AREA)
- Sampling And Sample Adjustment (AREA)
- Processes For Solid Components From Exhaust (AREA)
- Gasket Seals (AREA)
Abstract
Description
Claims
Priority Applications (11)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA002520349A CA2520349A1 (fr) | 2003-04-01 | 2004-03-29 | Structure de filtration, notamment filtre a particules pour les gaz d'echappement d'un moteur a combustion interne |
BRPI0409543-0A BRPI0409543A (pt) | 2003-04-01 | 2004-03-29 | estrutura de filtração |
AU2004227139A AU2004227139A1 (en) | 2003-04-01 | 2004-03-29 | Filtration structure for the exhaust gas from an internal combustion engine |
EP04742387A EP1611322B1 (fr) | 2003-04-01 | 2004-03-29 | Structure de filtration pour les gaz d echappement d un moteur a combustion interne |
DE602004006398T DE602004006398T2 (de) | 2003-04-01 | 2004-03-29 | Filtrationskonstruktion für das abgas aus einer brennkraftmaschine |
PL04742387T PL1611322T3 (pl) | 2003-04-01 | 2004-03-29 | Struktura filtracyjna dla gazów spalinowych z silnika spalinowego wewnętrznego spalania |
DK04742387T DK1611322T3 (da) | 2003-04-01 | 2004-03-29 | Filterstruktur til udstödningsgasser fra en forbrændingsmotor |
MXPA05010485A MXPA05010485A (es) | 2003-04-01 | 2004-03-29 | Estructura de filtracion para gas del escape de motor de combustion interna. |
US10/552,276 US7445656B2 (en) | 2003-04-01 | 2004-03-29 | Filtration structure for the exhaust gas from an internal combustion engine |
JP2006505765A JP4364240B2 (ja) | 2003-04-01 | 2004-03-29 | 内燃機関からの排気ガス用のフィルタ構造体 |
NO20054464A NO20054464L (no) | 2003-04-01 | 2005-09-27 | Filtreringskonstruksjon for eksosgass fra en innvendig forbrenningsmotor |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0304052A FR2853255B1 (fr) | 2003-04-01 | 2003-04-01 | Structure de filtration, notamment filtre a particules pour les gaz d'echappement d'un moteur a combustion interne |
FR0304052 | 2003-04-01 | ||
FR0401080A FR2853256B1 (fr) | 2003-04-01 | 2004-02-04 | Structure de filtration, notamment filtre a particules pour les gaz d'echappement d'un moteur a combustion interne. |
FR0401080 | 2004-02-04 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2004090294A1 true WO2004090294A1 (fr) | 2004-10-21 |
Family
ID=32992524
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/FR2004/000786 WO2004090294A1 (fr) | 2003-04-01 | 2004-03-29 | Structure de filtration pour les gaz d'echappement d'un moteur a combustion interne |
Country Status (18)
Country | Link |
---|---|
US (1) | US7445656B2 (fr) |
EP (1) | EP1611322B1 (fr) |
JP (1) | JP4364240B2 (fr) |
KR (1) | KR101042172B1 (fr) |
AT (1) | ATE362042T1 (fr) |
AU (1) | AU2004227139A1 (fr) |
BR (1) | BRPI0409543A (fr) |
CA (1) | CA2520349A1 (fr) |
DE (1) | DE602004006398T2 (fr) |
DK (1) | DK1611322T3 (fr) |
ES (1) | ES2285478T3 (fr) |
FR (1) | FR2853256B1 (fr) |
MX (1) | MXPA05010485A (fr) |
NO (1) | NO20054464L (fr) |
PL (1) | PL1611322T3 (fr) |
PT (1) | PT1611322E (fr) |
RU (1) | RU2338896C2 (fr) |
WO (1) | WO2004090294A1 (fr) |
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2896823A1 (fr) | 2006-01-31 | 2007-08-03 | Saint Gobain Ct Recherches | Filtre catalytique presentant un temps d'amorcage reduit |
CN101072929B (zh) * | 2004-12-07 | 2010-06-23 | 圣戈班欧洲设计研究中心 | 过滤结构体及相关的排放管线 |
WO2010072971A1 (fr) | 2008-12-23 | 2010-07-01 | Saint-Gobain Centre De Recherches Et D'etudes Europeen | Structure filtrante dont les faces d'entree et de sortie presentent un materiau de bouchage different |
WO2010149908A1 (fr) | 2009-06-22 | 2010-12-29 | Saint-Gobain Centre De Recherches Et D'etudes Europeen | Structure de filtration d'un gaz a canaux hexagonaux irregulier |
WO2010149940A1 (fr) | 2009-06-26 | 2010-12-29 | Saint-Gobain Centre De Recherches Et D'etudes Europeen | Grains fondus d'oxydes comprenant al, ti, si et produits ceramiques comportant de tels grains |
WO2011004351A1 (fr) | 2009-07-09 | 2011-01-13 | Saint-Gobain Centre De Recherches Et D'etudes Europeen | Structure en nid d'abeille marquée |
WO2011015766A1 (fr) | 2009-07-28 | 2011-02-10 | Saint-Gobain Centre De Recherches Et D'etudes Europeen | Grains fondus d'oxydes comprenant al, ti et produits ceramiques comportant de tels grains |
WO2011036397A1 (fr) | 2009-09-22 | 2011-03-31 | Saint-Gobain Centre De Recherches Et D'etudes Europeen | Structure poreuse du type titanate d'alumine |
WO2011036396A1 (fr) | 2009-09-22 | 2011-03-31 | Saint-Gobain Centre De Recherches Et D'etudes Europeen | Structure poreuse du type titanate d'alumine |
WO2011138555A1 (fr) | 2010-05-04 | 2011-11-10 | Saint-Gobain Centre De Recherches Et D'etudes Europeen | Structure de filtration de gaz |
WO2011138552A1 (fr) | 2010-05-04 | 2011-11-10 | Saint-Gobain Centre De Recherches Et D'etudes Europeen | Structure de filtration de gaz |
WO2011157939A1 (fr) | 2010-06-15 | 2011-12-22 | Saint-Gobain Centre De Recherches Et D'etudes Europeen | Filtre catalytique pour la filtration d'un gaz comprenant un ciment de joint incorporant un materiau geopolymere |
EP2468382A1 (fr) | 2010-12-23 | 2012-06-27 | Saint-Gobain Centre de Recherches et d'Etudes Européen | Filtre a particules du type assemble |
WO2013038103A1 (fr) | 2011-09-14 | 2013-03-21 | Saint-Gobain Centre De Recherches Et D'etudes Europeen | Élément en nid d'abeille a coins renforces |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2865661B1 (fr) * | 2004-02-04 | 2006-05-05 | Saint Gobain Ct Recherches | Structure de filtration, notamment filtre a particules pour les gaz d'echappement d'un moteur a combustion interne, et ligne d'echappement associee. |
DE102005050273A1 (de) * | 2005-10-20 | 2007-04-26 | Robert Bosch Gmbh | Partikelfilter und Verfahren zu seiner Herstellung |
USD647607S1 (en) | 2008-05-27 | 2011-10-25 | Ibiden Co., Ltd. | Particulate filter for diesel engine |
DE102009038049A1 (de) * | 2009-08-19 | 2011-03-10 | Saint-Gobain Industriekeramik Rödental GmbH | Filterelement, Partikelfilter, Verfahren zur Markierung eines Filterelements, Verfahren zur Herstellung eines Partikelfilters und Verwendung eines Filterelements |
JP7002377B2 (ja) | 2018-03-19 | 2022-01-20 | 日本碍子株式会社 | ハニカム構造体 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0816065A1 (fr) * | 1996-01-12 | 1998-01-07 | Ibiden Co, Ltd. | Structure ceramique |
EP1142619A1 (fr) * | 1999-09-29 | 2001-10-10 | Ibiden Co., Ltd. | Filtre en nid d'abeilles et ensemble de filtres ceramiques |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4335783A (en) * | 1980-11-10 | 1982-06-22 | Corning Glass Works | Method for improving thermal shock resistance of honeycombed structures formed from joined cellular segments |
US6126833A (en) * | 1999-02-22 | 2000-10-03 | Ceramem Corporation | Cross-flow filtration device with filtrate conduit network and method of making same |
JP4511065B2 (ja) * | 2000-06-05 | 2010-07-28 | 日本碍子株式会社 | ハニカム構造体とハニカムフィルター、及びそれらの製造方法 |
JP4408183B2 (ja) * | 2001-03-16 | 2010-02-03 | 日本碍子株式会社 | 排ガス浄化用ハニカムフィルター |
JP2003010616A (ja) * | 2001-06-29 | 2003-01-14 | Ngk Insulators Ltd | ハニカム構造体 |
JP4246425B2 (ja) * | 2001-10-15 | 2009-04-02 | 日本碍子株式会社 | ハニカムフィルター |
FR2833857B1 (fr) * | 2001-12-20 | 2004-10-15 | Saint Gobain Ct Recherches | Corps filtrant comportant une pluralite de blocs filtrants, notamment destine a un filtre a particules |
ATE431321T1 (de) * | 2003-11-12 | 2009-05-15 | Ibiden Co Ltd | Verfahren zur herstellung der keramikstruktur |
-
2004
- 2004-02-04 FR FR0401080A patent/FR2853256B1/fr not_active Expired - Fee Related
- 2004-03-29 AU AU2004227139A patent/AU2004227139A1/en not_active Abandoned
- 2004-03-29 EP EP04742387A patent/EP1611322B1/fr not_active Expired - Lifetime
- 2004-03-29 WO PCT/FR2004/000786 patent/WO2004090294A1/fr active IP Right Grant
- 2004-03-29 DK DK04742387T patent/DK1611322T3/da active
- 2004-03-29 JP JP2006505765A patent/JP4364240B2/ja not_active Expired - Fee Related
- 2004-03-29 PT PT04742387T patent/PT1611322E/pt unknown
- 2004-03-29 RU RU2005133625/06A patent/RU2338896C2/ru not_active IP Right Cessation
- 2004-03-29 BR BRPI0409543-0A patent/BRPI0409543A/pt not_active IP Right Cessation
- 2004-03-29 KR KR1020057018221A patent/KR101042172B1/ko not_active IP Right Cessation
- 2004-03-29 DE DE602004006398T patent/DE602004006398T2/de not_active Expired - Lifetime
- 2004-03-29 AT AT04742387T patent/ATE362042T1/de not_active IP Right Cessation
- 2004-03-29 MX MXPA05010485A patent/MXPA05010485A/es unknown
- 2004-03-29 US US10/552,276 patent/US7445656B2/en not_active Expired - Fee Related
- 2004-03-29 ES ES04742387T patent/ES2285478T3/es not_active Expired - Lifetime
- 2004-03-29 CA CA002520349A patent/CA2520349A1/fr not_active Abandoned
- 2004-03-29 PL PL04742387T patent/PL1611322T3/pl unknown
-
2005
- 2005-09-27 NO NO20054464A patent/NO20054464L/no not_active Application Discontinuation
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0816065A1 (fr) * | 1996-01-12 | 1998-01-07 | Ibiden Co, Ltd. | Structure ceramique |
EP1142619A1 (fr) * | 1999-09-29 | 2001-10-10 | Ibiden Co., Ltd. | Filtre en nid d'abeilles et ensemble de filtres ceramiques |
Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101072929B (zh) * | 2004-12-07 | 2010-06-23 | 圣戈班欧洲设计研究中心 | 过滤结构体及相关的排放管线 |
FR2896823A1 (fr) | 2006-01-31 | 2007-08-03 | Saint Gobain Ct Recherches | Filtre catalytique presentant un temps d'amorcage reduit |
WO2010072971A1 (fr) | 2008-12-23 | 2010-07-01 | Saint-Gobain Centre De Recherches Et D'etudes Europeen | Structure filtrante dont les faces d'entree et de sortie presentent un materiau de bouchage different |
WO2010149908A1 (fr) | 2009-06-22 | 2010-12-29 | Saint-Gobain Centre De Recherches Et D'etudes Europeen | Structure de filtration d'un gaz a canaux hexagonaux irregulier |
WO2010149940A1 (fr) | 2009-06-26 | 2010-12-29 | Saint-Gobain Centre De Recherches Et D'etudes Europeen | Grains fondus d'oxydes comprenant al, ti, si et produits ceramiques comportant de tels grains |
WO2011004351A1 (fr) | 2009-07-09 | 2011-01-13 | Saint-Gobain Centre De Recherches Et D'etudes Europeen | Structure en nid d'abeille marquée |
WO2011015766A1 (fr) | 2009-07-28 | 2011-02-10 | Saint-Gobain Centre De Recherches Et D'etudes Europeen | Grains fondus d'oxydes comprenant al, ti et produits ceramiques comportant de tels grains |
WO2011036397A1 (fr) | 2009-09-22 | 2011-03-31 | Saint-Gobain Centre De Recherches Et D'etudes Europeen | Structure poreuse du type titanate d'alumine |
WO2011036396A1 (fr) | 2009-09-22 | 2011-03-31 | Saint-Gobain Centre De Recherches Et D'etudes Europeen | Structure poreuse du type titanate d'alumine |
WO2011138555A1 (fr) | 2010-05-04 | 2011-11-10 | Saint-Gobain Centre De Recherches Et D'etudes Europeen | Structure de filtration de gaz |
WO2011138552A1 (fr) | 2010-05-04 | 2011-11-10 | Saint-Gobain Centre De Recherches Et D'etudes Europeen | Structure de filtration de gaz |
WO2011157939A1 (fr) | 2010-06-15 | 2011-12-22 | Saint-Gobain Centre De Recherches Et D'etudes Europeen | Filtre catalytique pour la filtration d'un gaz comprenant un ciment de joint incorporant un materiau geopolymere |
EP2468382A1 (fr) | 2010-12-23 | 2012-06-27 | Saint-Gobain Centre de Recherches et d'Etudes Européen | Filtre a particules du type assemble |
WO2013038103A1 (fr) | 2011-09-14 | 2013-03-21 | Saint-Gobain Centre De Recherches Et D'etudes Europeen | Élément en nid d'abeille a coins renforces |
US9546115B2 (en) | 2011-09-14 | 2017-01-17 | Saint-Gobain Centre De Recherches Et D'etudes Europeen | Honeycomb element with reinforced corners |
Also Published As
Publication number | Publication date |
---|---|
DE602004006398D1 (de) | 2007-06-21 |
NO20054464L (no) | 2005-10-25 |
JP2006522267A (ja) | 2006-09-28 |
US20060191244A1 (en) | 2006-08-31 |
KR20050120676A (ko) | 2005-12-22 |
US7445656B2 (en) | 2008-11-04 |
CA2520349A1 (fr) | 2004-10-21 |
FR2853256A1 (fr) | 2004-10-08 |
ATE362042T1 (de) | 2007-06-15 |
PL1611322T3 (pl) | 2007-09-28 |
PT1611322E (pt) | 2007-08-14 |
DK1611322T3 (da) | 2007-06-18 |
FR2853256B1 (fr) | 2005-10-21 |
EP1611322B1 (fr) | 2007-05-09 |
NO20054464D0 (no) | 2005-09-27 |
BRPI0409543A (pt) | 2006-04-18 |
MXPA05010485A (es) | 2006-05-25 |
KR101042172B1 (ko) | 2011-06-20 |
DE602004006398T2 (de) | 2008-01-10 |
AU2004227139A1 (en) | 2004-10-21 |
RU2338896C2 (ru) | 2008-11-20 |
RU2005133625A (ru) | 2006-06-27 |
EP1611322A1 (fr) | 2006-01-04 |
JP4364240B2 (ja) | 2009-11-11 |
ES2285478T3 (es) | 2007-11-16 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP1611322B1 (fr) | Structure de filtration pour les gaz d echappement d un moteur a combustion interne | |
EP1455923B1 (fr) | Corps filtrant comportant une pluralite de blocs filtrants, notamment destine a un filtre a particules | |
EP1792063B1 (fr) | Bloc filtrant a ailettes pour la filtration de particules contenues dans les gaz d'echappement d'un moteur a combustion interne | |
EP1792064B1 (fr) | Structure de filtration des gaz d'echappement d'un moteur a combustion interne et ligne d'echappement associee | |
EP2244804B1 (fr) | Structure de filtration d'un gaz a canaux hexagonaux assymetriques | |
FR2925354A1 (fr) | Structure de filtration d'un gaz a canaux hexagonaux asymetriques | |
EP2101982B1 (fr) | Bloc pour la filtration de particules contenues dans les gaz d' echappement d un moteur a combustion interne | |
EP1649149B1 (fr) | Bloc pour la filtration de particules contenues dans les gaz d'echappement d un moteur a combustion interne. | |
EP1713560B1 (fr) | Structure de filtration, notamment filtre a particules pour les gaz d echappement d un moteur a combustion interne et ligne d echappement associee | |
FR2947735A1 (fr) | Structure en nid d'abeille marquee | |
FR2853255A1 (fr) | Structure de filtration, notamment filtre a particules pour les gaz d'echappement d'un moteur a combustion interne | |
EP1825107B1 (fr) | Structure de filtration, notamment filtre a particules pour les gaz d'echappement d'un moteur a combustion interne, et ligne d'echappement associee | |
FR2925355A1 (fr) | Structure de filtration d'un gaz a canaux hexagonaux concaves ou convexes. | |
EP1706605B1 (fr) | Structure de filtration, notamment filtre a particules, pour les gaz d'echappement d'un moteur a combustion interne et organe d'armature destine a une telle structure | |
FR2901308A1 (fr) | Dispositif de traitement de gaz d'echappement d'un moteur thermique de vehicule automobile | |
FR2874963A1 (fr) | Structure de filtration des gaz d'echappement d'un moteur a combustion interne et ligne d'echappement associee | |
FR2867508A1 (fr) | Filtre a particules pour ligne d'echappement d'un moteur a combustion interne et ligne d'echappement comprenant un tel filtre a particules. | |
MXPA06008625A (en) | Filtering structure, especially particle filter for exhaust gases of an internal combustion engine, and associated exhaust line |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AK | Designated states |
Kind code of ref document: A1 Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BW BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE EG ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NA NI NO NZ OM PG PH PL PT RO RU SC SD SE SG SK SL SY TJ TM TN TR TT TZ UA UG US UZ VC VN YU ZA ZM ZW |
|
AL | Designated countries for regional patents |
Kind code of ref document: A1 Designated state(s): BW GH GM KE LS MW MZ SD SL SZ TZ UG ZM ZW AM AZ BY KG KZ MD RU TJ TM AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LU MC NL PL PT RO SE SI SK TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG |
|
121 | Ep: the epo has been informed by wipo that ep was designated in this application | ||
WWE | Wipo information: entry into national phase |
Ref document number: 2006191244 Country of ref document: US Ref document number: 10552276 Country of ref document: US |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2004742387 Country of ref document: EP |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2005/07703 Country of ref document: ZA Ref document number: 200507703 Country of ref document: ZA |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2520349 Country of ref document: CA Ref document number: 2004227139 Country of ref document: AU |
|
WWE | Wipo information: entry into national phase |
Ref document number: 1020057018221 Country of ref document: KR |
|
WWE | Wipo information: entry into national phase |
Ref document number: PA/a/2005/010485 Country of ref document: MX Ref document number: 2455/CHENP/2005 Country of ref document: IN |
|
WWE | Wipo information: entry into national phase |
Ref document number: 20048090106 Country of ref document: CN |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2006505765 Country of ref document: JP |
|
ENP | Entry into the national phase |
Ref document number: 2004227139 Country of ref document: AU Date of ref document: 20040329 Kind code of ref document: A |
|
WWP | Wipo information: published in national office |
Ref document number: 2004227139 Country of ref document: AU |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2005133625 Country of ref document: RU |
|
WWP | Wipo information: published in national office |
Ref document number: 1020057018221 Country of ref document: KR |
|
WWP | Wipo information: published in national office |
Ref document number: 2004742387 Country of ref document: EP |
|
ENP | Entry into the national phase |
Ref document number: PI0409543 Country of ref document: BR |
|
WWP | Wipo information: published in national office |
Ref document number: 10552276 Country of ref document: US |
|
WWG | Wipo information: grant in national office |
Ref document number: 2004742387 Country of ref document: EP |