WO2004042103A1 - Magnesiumwerkstoff und verwendungen desselben - Google Patents
Magnesiumwerkstoff und verwendungen desselben Download PDFInfo
- Publication number
- WO2004042103A1 WO2004042103A1 PCT/EP2003/012174 EP0312174W WO2004042103A1 WO 2004042103 A1 WO2004042103 A1 WO 2004042103A1 EP 0312174 W EP0312174 W EP 0312174W WO 2004042103 A1 WO2004042103 A1 WO 2004042103A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- material according
- thin layer
- long
- layer
- matrix
- Prior art date
Links
- 239000000463 material Substances 0.000 title claims abstract description 47
- 239000011777 magnesium Substances 0.000 title abstract description 27
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 title abstract description 5
- 229910052749 magnesium Inorganic materials 0.000 title abstract description 5
- 239000000835 fiber Substances 0.000 claims abstract description 29
- 239000011159 matrix material Substances 0.000 claims abstract description 16
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 11
- 239000000956 alloy Substances 0.000 claims abstract description 11
- 230000002787 reinforcement Effects 0.000 claims abstract description 10
- 239000007795 chemical reaction product Substances 0.000 claims abstract description 6
- 230000004888 barrier function Effects 0.000 claims abstract description 3
- 238000006243 chemical reaction Methods 0.000 claims abstract description 3
- 238000009792 diffusion process Methods 0.000 claims abstract description 3
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 11
- 238000002485 combustion reaction Methods 0.000 claims description 9
- 238000004519 manufacturing process Methods 0.000 claims description 6
- 210000001170 unmyelinated nerve fiber Anatomy 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- 229910052804 chromium Inorganic materials 0.000 claims description 2
- 229910052735 hafnium Inorganic materials 0.000 claims description 2
- 229910052758 niobium Inorganic materials 0.000 claims description 2
- 238000004544 sputter deposition Methods 0.000 claims description 2
- 229910052715 tantalum Inorganic materials 0.000 claims description 2
- 229910052719 titanium Inorganic materials 0.000 claims description 2
- 229910052726 zirconium Inorganic materials 0.000 claims description 2
- 238000005240 physical vapour deposition Methods 0.000 claims 1
- 230000015572 biosynthetic process Effects 0.000 abstract description 2
- 239000003999 initiator Substances 0.000 abstract 1
- 229910000861 Mg alloy Inorganic materials 0.000 description 7
- 229910000838 Al alloy Inorganic materials 0.000 description 5
- 239000002131 composite material Substances 0.000 description 5
- 239000010959 steel Substances 0.000 description 4
- 229910001069 Ti alloy Inorganic materials 0.000 description 3
- 238000005229 chemical vapour deposition Methods 0.000 description 3
- 229910001092 metal group alloy Inorganic materials 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000013585 weight reducing agent Substances 0.000 description 3
- 229910000851 Alloy steel Inorganic materials 0.000 description 2
- 229920000049 Carbon (fiber) Polymers 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 239000004917 carbon fiber Substances 0.000 description 2
- 239000004918 carbon fiber reinforced polymer Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C47/00—Making alloys containing metallic or non-metallic fibres or filaments
- C22C47/02—Pretreatment of the fibres or filaments
- C22C47/04—Pretreatment of the fibres or filaments by coating, e.g. with a protective or activated covering
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C49/00—Alloys containing metallic or non-metallic fibres or filaments
- C22C49/14—Alloys containing metallic or non-metallic fibres or filaments characterised by the fibres or filaments
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02F—CYLINDERS, PISTONS OR CASINGS, FOR COMBUSTION ENGINES; ARRANGEMENTS OF SEALINGS IN COMBUSTION ENGINES
- F02F3/00—Pistons
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02F—CYLINDERS, PISTONS OR CASINGS, FOR COMBUSTION ENGINES; ARRANGEMENTS OF SEALINGS IN COMBUSTION ENGINES
- F02F7/00—Casings, e.g. crankcases or frames
- F02F7/0085—Materials for constructing engines or their parts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
- Y10T428/249924—Noninterengaged fiber-containing paper-free web or sheet which is not of specified porosity
Definitions
- the invention relates to a magnesium material (hereinafter called Mg material) according to the preamble of claim 1 and uses thereof.
- the invention is therefore based on the object of providing a Mg material of the type mentioned at the outset, the strength of which transversely to the fiber direction is considerably improved, alloy elements of the matrix which form relatively coarse chemical reaction products being avoided on the fibers.
- This object is achieved by the features of claim 1.
- Preferred embodiments of the Mg material according to the invention are characterized in claims 2 to 8.
- the long C fibers are provided with a thin layer which fulfills the following tasks:
- At least one element of the layer material forms a thin, sufficiently homogeneous chemical reaction layer with the respective long carbon fiber;
- the thin layer acts as a diffusion barrier in such a way that the local
- At least one element of the material of the thin layer forms an intermetallic or intermediate connection or mixed crystal zone with the matrix.
- the layer material is expediently formed by carbide formers.
- carbide formers can be, for example, Al, Cr, Ti, Ta, Nb, Hf, Zr or alloys, for example based on Ni, which contain carbide formers.
- the thin layer of the long C fibers can be produced by PVD (physical vapor depositon) or CVD (chemical vapor deposition).
- the PVD process is preferably sputtering.
- the CVD process can be a galvanic, wet chemical or electroless electrochemical process.
- the thin layer of the long C fibers can have a thickness in the range between a few nm and a few ⁇ m.
- the Mg material according to the invention can be made from a matrix with a C long fiber reinforcement for the production of pistons from
- Creep resistance As is known, a slight increase in strength can be achieved if such Mg alloys are reinforced with short fibers or with suitable particles. However, this slight increase in strength is still not sufficient. Adequate strength, rigidity and creep resistance are only achieved with the Mg material according to the invention from a matrix with a C-long fiber reinforcement, the C-long fibers being provided with a thin layer of the type mentioned above. In the Mg material according to the invention, the interfacial strength between the C- Long fibers and the matrix optimized. A suitable design and fiber arrangement can save up to 30% in weight when using the Mg material according to the invention in pistons of internal combustion engines.
- the composite material according to the invention consisting of the matrix and the C-long fiber reinforcement has strengths in the critical areas and directions of an internal combustion engine piston which are comparable to those of high-strength Al alloys.
- the stiffness is even higher than the high-strength AI alloys.
- Force introduction areas such as the bearing eyes for piston pins, grooves for piston rings and possibly piston crowns or combustion chambers can be formed as inserts, which in turn can be made of high-strength metal alloys or composite materials and which have a positive and / or form an integral bond.
- the Mg material according to the invention made of a matrix with a C-long fiber reinforcement, the C-long fibers being provided with a thin layer, as has been described above, can also be used according to the invention for the production of connecting rods of internal combustion engines.
- the currently Connecting rods used in internal combustion engines usually consist of steel or a Ti alloy. Attempts have also been made with GRP and CFRP connecting rods. Weight reduction compared to connecting rods made of steel or Ti alloys can be achieved by using Mg alloys. However, these do not have sufficient strength and rigidity. A slight increase in strength is possible if such Mg alloys are reinforced with short fibers or with particles. However, such an increase in strength is still not sufficient.
- Adequate strength and rigidity can only be obtained by using the Mg material according to the invention made of a matrix with a C long fiber reinforcement with a thin layer, as has been described above, by means of which the interfacial strength between the matrix and the C long fibers is optimized.
- a weight saving of up to 70% can be achieved with the Mg material according to the invention for connecting rods.
- the Mg material according to the invention has strengths in the critical areas and directions of connecting rods which are comparable to those of high-strength Al alloys. The stiffness is even higher than that of Ti alloys.
- Force introduction areas such as the bearing eyes for the piston pins and for the crank pins can be designed as inserts, which in turn can be made from higher-strength metal alloys or from composite materials. These inserts can form a positive and / or a material bond with the component made of the Mg material according to the invention.
- the Mg material according to the invention can also be used according to the invention for the production of sabots for sub-caliber projectiles.
- Known sabotages usually consist of high-strength AI alloys. Weight reduction can be achieved with such sabotages by using Mg alloys.
- the known Mg alloys do not have sufficient mechanical strength. With short fiber or particle reinforcements, only small increases in strength are possible with known Mg alloys.
- the Mg material according to the invention provides a remedy here, so that a weight saving of approximately 20 to 30% can be achieved by suitable design and fiber arrangement of the Mg material according to the invention.
- the Mg composite material with C-long fiber reinforcement according to the invention with the thin coating, as described at the beginning, has strengths in critical areas and directions that the critical areas and directions strengths that are comparable to the strengths of high-strength Al alloys.
- the stiffness is even higher than the high-strength AI alloys.
- Force introduction areas such as > thread to the penetrator can be designed as inserts, which in turn can be made of high-strength metal alloys or composite materials and which can be positively and / or cohesively connected to the component, ie the sabot made of the Mg material according to the invention.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Combustion & Propulsion (AREA)
- General Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacture Of Alloys Or Alloy Compounds (AREA)
Abstract
Description
Claims
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU2003278169A AU2003278169A1 (en) | 2002-11-02 | 2003-10-31 | Magnesium material and use of the same |
EP03769481A EP1563111A1 (de) | 2002-11-02 | 2003-10-31 | Magnesiumwerkstoff und verwendungen desselben |
US10/533,487 US20060051565A1 (en) | 2002-11-02 | 2003-10-31 | Magnesium material and use of the same |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10251119.5 | 2002-11-02 | ||
DE2002151119 DE10251119A1 (de) | 2002-11-02 | 2002-11-02 | Magnesiumwerkstoff und Verwendung derselben |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2004042103A1 true WO2004042103A1 (de) | 2004-05-21 |
Family
ID=32115146
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2003/012174 WO2004042103A1 (de) | 2002-11-02 | 2003-10-31 | Magnesiumwerkstoff und verwendungen desselben |
Country Status (5)
Country | Link |
---|---|
US (1) | US20060051565A1 (de) |
EP (1) | EP1563111A1 (de) |
AU (1) | AU2003278169A1 (de) |
DE (1) | DE10251119A1 (de) |
WO (1) | WO2004042103A1 (de) |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2081237A1 (en) * | 1970-03-20 | 1971-12-03 | Onera (Off Nat Aerospatiale) | Fibre impregnated composites - by forming a eutectic alloy in situ over the fibres |
US4223075A (en) * | 1977-01-21 | 1980-09-16 | The Aerospace Corporation | Graphite fiber, metal matrix composite |
EP0587494A1 (de) * | 1992-09-10 | 1994-03-16 | AEROSPATIALE Société Nationale Industrielle | Mit Kohlen verstärkter Verbundwerkstoff bestehend aus einer Zirconium enthaltenden Magnesiumlegierung |
DE19751929A1 (de) * | 1997-11-22 | 1999-05-27 | Ks Aluminium Technologie Ag | Verfahren zum Herstellen eines Gußstücks |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4056874A (en) * | 1976-05-13 | 1977-11-08 | Celanese Corporation | Process for the production of carbon fiber reinforced magnesium composite articles |
JPS6169448A (ja) * | 1984-09-14 | 1986-04-10 | 工業技術院長 | 炭素繊維強化金属とその製造法 |
US4732779A (en) * | 1985-05-21 | 1988-03-22 | Kabushiki Kaisha Toyota Chuo Kenkyusho | Fibrous material for composite materials, fiber-reinforced metal produced therefrom, and process for producing same |
US4778722A (en) * | 1986-05-15 | 1988-10-18 | Ube Industries, Ltd. | Reinforcing fibers and composite materials reinforced with said fibers |
US4961990A (en) * | 1986-06-17 | 1990-10-09 | Kabushiki Kaisha Toyota Chuo Kenkyusho | Fibrous material for composite materials, fiber-reinforced composite materials produced therefrom, and process for producing same |
US5277973A (en) * | 1988-08-12 | 1994-01-11 | Ube Industries, Ltd. | Carbon fibers having high strength and high modulus of elasticity and polymer composition for their production |
US6245439B1 (en) * | 1994-08-09 | 2001-06-12 | Kabushiki Kaisha Toyoyta Chuo Kenkyusho | composite material and method for the manufacture |
EP1477467B1 (de) * | 2003-05-16 | 2012-05-23 | Hitachi Metals, Ltd. | Verbundwerkstoff mit hoher Wärmeleitfähigkeit und niedrigem Wärmeausdehnungskoeffizienten, und Wärmesenke. |
-
2002
- 2002-11-02 DE DE2002151119 patent/DE10251119A1/de not_active Withdrawn
-
2003
- 2003-10-31 US US10/533,487 patent/US20060051565A1/en not_active Abandoned
- 2003-10-31 AU AU2003278169A patent/AU2003278169A1/en not_active Abandoned
- 2003-10-31 EP EP03769481A patent/EP1563111A1/de not_active Withdrawn
- 2003-10-31 WO PCT/EP2003/012174 patent/WO2004042103A1/de not_active Application Discontinuation
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2081237A1 (en) * | 1970-03-20 | 1971-12-03 | Onera (Off Nat Aerospatiale) | Fibre impregnated composites - by forming a eutectic alloy in situ over the fibres |
US4223075A (en) * | 1977-01-21 | 1980-09-16 | The Aerospace Corporation | Graphite fiber, metal matrix composite |
EP0587494A1 (de) * | 1992-09-10 | 1994-03-16 | AEROSPATIALE Société Nationale Industrielle | Mit Kohlen verstärkter Verbundwerkstoff bestehend aus einer Zirconium enthaltenden Magnesiumlegierung |
DE19751929A1 (de) * | 1997-11-22 | 1999-05-27 | Ks Aluminium Technologie Ag | Verfahren zum Herstellen eines Gußstücks |
Also Published As
Publication number | Publication date |
---|---|
AU2003278169A1 (en) | 2004-06-07 |
DE10251119A1 (de) | 2004-05-19 |
EP1563111A1 (de) | 2005-08-17 |
US20060051565A1 (en) | 2006-03-09 |
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