WO2004009259A1 - Method and plant for the hot rolling of rails - Google Patents
Method and plant for the hot rolling of rails Download PDFInfo
- Publication number
- WO2004009259A1 WO2004009259A1 PCT/EP2003/007897 EP0307897W WO2004009259A1 WO 2004009259 A1 WO2004009259 A1 WO 2004009259A1 EP 0307897 W EP0307897 W EP 0307897W WO 2004009259 A1 WO2004009259 A1 WO 2004009259A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- rolling
- stand
- rolling passage
- fact
- universal
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B1/00—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
- B21B1/08—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling structural sections, i.e. work of special cross-section, e.g. angle steel
- B21B1/085—Rail sections
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B31/00—Rolling stand structures; Mounting, adjusting, or interchanging rolls, roll mountings, or stand frames
- B21B31/02—Rolling stand frames or housings; Roll mountings ; Roll chocks
- B21B2031/026—Transverse shifting the stand
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B2265/00—Forming parameters
- B21B2265/14—Reduction rate
Definitions
- the present invention refers to a method and a plant for the production by hot rolling of objects such as metallic beams, in particular railway rails and similar reliable materials.
- Hot rolling production of railway rails in appropriate rolling stands is known.
- the rolling operation for a rail generally comprises a break down operation of the ingot or billet in one or more break down stands, optionally the passage in an intermediate working section and then a finishing operation in a finishing stage.
- the development of high speed railway lines requires tighter working tolerances on the rails than in the case of normal railway line rails.
- a problem underlying the present invention is to provide a method and a plant, for rails rolling, able to produce rails with a higher quality, in terms of dimensional and surface tolerances, while limiting the number of rolling stands.
- Such a problem is solved, according to a first aspect of the present invention, by a method for the production of rails and similar products by means of a rolling plant, said plant comprising a reversible intermediate working section able to receive a pre-rough rolled bar from an appropriate upstream rough rolling station and to supply it, after having worked it, to a downstream finishing station, where said intermediate working station comprises:
- the three above mentioned stands are placed at such a distance between each other so that said bar can be simultaneously held in all three said stands during rolling.
- the problem indicated in more detail above is solved using a rolling plant for the implementation of a method as described above, where such plant comprises a reversible intermediate working section able to receive a pre-rough rolled bar from an appropriate upstream rough rolling station and to pass it, after having worked it, to a downstream finishing station, where said intermediate working station comprises, located in succession along at least one rolling axis, a first universal stand and a high edging stand.
- the plant according to the present invention is characterised by the fact of comprising a second universal stand located, along said at least one rolling axis, such that said high edging stand is found placed between said first and second universal stand, and said three stands are located at a distance from each other such that said bar can be simultaneously held in all three said stands during rolling.
- the limited number of stands produces a lower initial investment cost and a lower cost for the transformation of the product: In fact, being able to perform the rolling with two or three stands rolling simultaneously the same bar at global temperatures higher than in stands not rolling the same bar, and it is therefore possible to reduce the number of rolling passages.
- a method for the production of rails and similar products through rolling comprising the finishing operation of a bar transformed into a semi-worked rail, characterised by the fact that said finishing operation comprises a rolling passage in a universal stand fitted with a first vertical roll able to work the base of said rail, and a second vertical roll able to work the head (T) of said rail, and said first and second vertical rolls are able to roll said head (T) and said base (B) simultaneously.
- Such a method of finishing allows the making of rails with better dimensional precision, in particular the height and shape of the head of the rail finished.
- Preferred embodiments are also provided which allow the attainment of good surface finishing and further improve the dimensional precision of the rolled rail. Finishing methods according to this further aspect of the present invention can be used both in combination with intermediate rolling methods, according to the foregoing aspects of the present invention, described more above, and in combination with rail intermediate working methods according to the known art. List of the figures
- Figure 1 shows schematically an embodiment of a rolling plant to carry out a method according to the invention
- Figure 2 shows schematically the sequence of rolling operations carried out in the plant of Figure 1 , according to an embodiment of a method according to the invention
- Figure 3 shows schematically a sectional view of a finishing stand of the plant of Figure 1 according to a first embodiment of a method according to the present invention
- Figure 4 shows schematically a sectional view of a finishing stand of the plant of Figure 1 according to a second embodiment of a method according to the present invention
- Figure 5 shows schematically a sectional view of a finishing stand of the plant of Figure 1 according to a third embodiment of a method according to the present invention
- Figure 6 shows schematically a sectional view of a finishing stand of a plant of Figure 1 according to fourth embodiment of a method according to the present invention.
- Figure 1 schematically shows a preferred embodiment of a hot rolling plant for railway rails according to the present invention.
- the bars produced for example from a continuous casting plant (not shown) are firstly rough rolled in a first group of break down stands 1, and optionally in a second group of break down stands 2; then reach an intermediate section, indicated globally by numeral 3. Emerging from said intermediate working section 3, the bars are sent to a finishing station consisting of finishing stand 4 and from this to the successive working stations (plate cooling, thermal treatments etc.).
- finishing stand or “finishing station” means the stand of the rolling line which performs the last rolling passage, performing the last dimensional adjustments on the rail.
- the intermediate working section 3 comprises, in upstream - downstream direction along the bar rolling line, a first universal stand 30, a second universal stand 32, a two-high edging stand 31 placed between the first and second universal stands 30, 32.
- the first and second universal stands 30, 32 and the high edging stand 31 are reversible and located along a single rolling axis, at such distances from each other as to engage all three simultaneously the same bar during rolling (except in the case in which one stand is performing a "dummy" passage, in which the stands simultaneously enaging a bar will be at most two).
- the distances between the horizontal rolls of the first and second universal stands 30, 32, and the high edging stand 31 are as close as possible: this allows performing the various rolling passages at temperatures on average that are higher, reducing the wear of the rolls or, equivalently, allowing higher reduction ratios at each passage and/or a lower number of passages (in the particular embodiment described it has been possible to reduce the passages to just three).
- the rolling section 3 performs the rolling of the semi-worked bar according to the following method, outlined in Figure:
- the semi-worked bar is subjected to a first rolling passage U1 in the second universal stand 32 -the rolls of the first universal stand 30 are initially opened and therefore perform a first dummy passage D1;' then the direction of advancement of the bar is inverted and the bar for working. passes again in the intermediate rolling section 3 undergoing a first rolling passage E1 in a first working groove of the high edging stand 31 , and then a first passage U2 in the first universal stand 30.
- the high edging stand 31 is mobile between different positions, so as to allow the positioning, along the rolling axis of the two universal stands 30, 32, of different grooves or rolling grooves to make different high edging passages.
- the first rolling passage U1 in the second universal stand 32 is carried out with a reduction ratio ⁇ 1 greater than the reduction ratio ⁇ 2 of the first rolling passage U2 in the first universal stand 30, preferably assuming ⁇ 1 approximately equal to 20% and p2 approximately equal to 16%; however such values can be varied and adapted as a function of the specific needs (such as for example shape and dimensions of the rails to roll, temperature etc.).
- p1 is selected from between approx. 10% and approx. 30%
- p2 is selected from between approx. 3% and approx. 25%.
- the bar before undergoing the first rolling passage U1 in the universal stand 32, the bar originates from the two break down mills 1 and 2 is further broken down with a rolling passage E2 in a second rolling groove of the high edging stand 31 : if present, the intermediate section 3 at such a distance from the break down mill 1 , 2 so that the bar, when being worked in the intermediate section 3 is no longer held by the rolls of the break down mills 1 , 2,
- the operation E2 can be performed in the shadow of other operations of such break down mills 1 , 2 suppressing a working passage from them and reducing the overall rolling time.
- the bar passes again, in a downstream - upstream direction, the intermediate working section 3, following the reversal of movement of the next bar to the first rolling U1 in the second universal stand 32 and prior to the first rolling passage E1 in the high edging stand 31 , the bar is subjected to a second rolling passage U3 in the second universal stand 32 (to carry out the passage U3, following the passage U1 the rolls of the stand 32 are brought closer): as said before, the first rolling passage U2 in the first universal stand 30, the first rolling passage E1 in the high edging stand 31 and the second rolling passage U3 in the second universal stand 32 can be carried out with the.
- three stands 30, 31 , 32 simultaneously holding the bar rails generally have final lengths varying from 60 m to over 100 m; the crop ends used to make spares and other extra elements have shorter lengths instead).
- the rolling passage U3 is carried out with a reduction ratio p3 comprised between around 10% and around 30%, and in particular approximately equal to 16%
- the rolling passage U4 is carried out with a reduction ratio p4 comprised between around 3% and around 20%, and in particular approximately equal to 8%.
- the break down and the hardest rolling passages U1 (and optionally U3), with the largest reduction ratios, are only carried out in the second universal stand 32, whilst the passages U2 (and optionally U4) which, with smaller reduction ratios, are all carried out in the first universal stand 30: in this way the greatest wear of the break down operations and the initial deformations U1 , U3 involve only the second universal stand 32, whilst the successive rolling passages U2, U4 -which can be considered the pre- finishing passages- are exclusively carried out in the first universal stand 30, which is therefore subjected to less wear and manages to ensure tolerances -of shape and surface finishing- sufficiently precise on the bar emerging from section 3, for a longer working lifetime with respect to plants in which both break down and rough rolling passages and the final pre-finishing passages are performed in an intermediate rolling section on the same universal stand: in fact, in the working cycle of Figure 2, the first universal stand 30 compensates for the deviations in shape which the bar receives from the second universal stand 32 which
- the surface finishing of the rolled rail with the methods according to the present invention are better:
- the reduced wear during working, of the stand rolls 30 enables to reach longer periods, of time of smoother surfaces of the rolled rails, with respect to the rolling plants of known type.
- the structure of the intermediate section 3 substantially only of three stands does not require excessively complex roll speed control systems; re-equipping times can be reduced and it is simpler to administer the production of small batches.
- the working with reversible stands ensures more uniform temperature distribution over the bar, for example, with respect to a continuous rolling process.
- the finishing station 4 is at such a distance, from the intermediate section 3, that a bar is never held simultaneously in a section three stand 3 and the finishing station 4; this, in addition to allowing simultaneously carrying out, and with less dead time, the intermediate rolling and the finishing, eliminates the bar deformations which would occur if this was held both in section 3 and in the station 4: in such a case in fact, the speed of the stands 30, 31 , 32 and the finishing stands 4 even if controlled with appropriate control systems, would be however subject to relative slippages more or less important, from which there would be dilation, deformations and in general dimensional variations of the bar.
- the finishing station 4 can comprise, as is currently normal practice, a semi- universal rolling stand (i.e. with two horizontal rolls 40, 41 and one vertical roll 42, Figure 3; the vertical roll 42 rolls and finishes the lower surface of the base of resting of the rail) or also a high edging stand (Figure 4).
- the finishing station 4 can advantageously comprise a universal stand with two horizontal rolls 400, 401 and two vertical rolls 402, 403, where the vertical roll 402 works and finishes the base of the rail B, whilst the second vertical roll works and refinishes the area of the head T of the semi-worked rail; the two vertical rolls 402, 403 refinish the. base and head of the rail working simultaneously.
- the head T of a rail comprises a reliable central surface T1 , on which the wheels of the railway vehicle rest, and the two lateral flanks T2, T3 substantially rectilinearly oriented or vertically or with a slight inclination with respect to the vertical when the rail is installed; on the lateral flanks T2, T3 the wheels of the railway vehicles laterally rest.
- the central reliable surfaces T1 and the two lateral flanks T2, T3 are joined by two curved areas T4, T5.
- the vertical rolling roll 403, which deforms and refinishes the head T of the rail, comprises a rolling groove 404 able to plastically deform and refinish the head T;
- the groove 404 comprises a central area -able to plastically deform and refinish the central reliable section T1 of the head- and two lateral surfaces located to the sides of said central zone and able to retain and shape the lateral flanks T4, T5 of the head T of the rail.
- the other roll 402 has a normal flat rolling surface to finish the lower face of the base B of the rail.
- the shape of the groove 404 allows to retain and shape with greater precision not just the central reliable area T1 of the head T of the rail, but also the flanksT4, T5 of the head.
- the difference between the different speed of rotation of a rolling groove in the different points P1-P10 produces, on the surfaces of the rolled bar, an undesired slipping effect in some areas of the metal of the bar; for this reason the depth of the rolling grooves is not excessively big.
- Figure 6 shows a further embodiment of a universal finishing stand with two vertical rolls 422, 423 developed by the applicant: in such an example the groove 424 which shapes the head T of the rail is less deep and deprived of the lateral flanks able to shape and retain the lateral flanks T2, T3 of the head of the rail; the groove 424 rolls and finishes only the central area T1 of the head of the rail; in this way the problem of slipping due to the rotational speed gradient along the surface of the groove 404 is overcome.
- the finishing stand of Figure 6 is also itself fitted with a second roll 422 to shape and finish precisely the lower side of the base B of the rail.
- the two vertical roll finishing stands just illustrated can be used as finishing stations not just in the plants realised according to the present invention, but also in mills of a different kind, for example having intermediate sections of known type.
- the finishing passage UF in the stand 4 Independently of the type of stand used for finishing (semi-universal, universal or high edging) preferably the finishing passage UF in the stand 4 ( Figure 1 , 2) is performed with a reduction ratio pF comprised of between around 1 % and around 15%, and in particular with a reduction ratio pF equal to around 2%: such a reduction ratio, particularly small, optionally coupled with the pre-finishing action of the optional passages U2 and U4 carried out as previously described, enables to reach rather precise dimensional and surface finishing tolerances and more constant over time, with respect to the finishing methods of the known art.
- the described embodiments are susceptible to many variations without departing from the scope of the present invention: for example it is possible to change by adding or removing rolling stands to carry out the various passages. If required by the floor space of the building in which the plant is housed the number of passages of the bar through the intermediate section 3 can also be even, and not necessarily uneven as previously described, so that the rail, at the end of the rolling cycle is expelled from the section 3 from the same side as into which it was introduced, rather than crossing the section 3 and continuing downstream. Every modification and variation falling within the meaning of the field of equivalence of the claims is intended as being comprised within them.
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Metal Rolling (AREA)
- Heat Treatment Of Articles (AREA)
Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/522,437 US20060016236A1 (en) | 2002-07-19 | 2003-07-18 | Method and plant for the hot rolling of rails |
DE60314256T DE60314256T2 (en) | 2002-07-19 | 2003-07-18 | METHOD AND SYSTEM FOR HOT ROLLING OF RAILS |
AU2003250119A AU2003250119A1 (en) | 2002-07-19 | 2003-07-18 | Method and plant for the hot rolling of rails |
EP03765060A EP1534441B1 (en) | 2002-07-19 | 2003-07-18 | Method and plant for the hot rolling of rails |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ITMI2002A001594 | 2002-07-19 | ||
IT2002MI001594A ITMI20021594A1 (en) | 2002-07-19 | 2002-07-19 | METHOD AND SYSTEM FOR HOT ROLLING OF RAILS |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2004009259A1 true WO2004009259A1 (en) | 2004-01-29 |
WO2004009259A8 WO2004009259A8 (en) | 2004-05-06 |
Family
ID=30130898
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2003/007897 WO2004009259A1 (en) | 2002-07-19 | 2003-07-18 | Method and plant for the hot rolling of rails |
Country Status (9)
Country | Link |
---|---|
US (1) | US20060016236A1 (en) |
EP (1) | EP1534441B1 (en) |
CN (1) | CN1299844C (en) |
AT (1) | ATE363952T1 (en) |
AU (1) | AU2003250119A1 (en) |
DE (1) | DE60314256T2 (en) |
ES (1) | ES2288623T3 (en) |
IT (1) | ITMI20021594A1 (en) |
WO (1) | WO2004009259A1 (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101844150A (en) * | 2010-05-18 | 2010-09-29 | 攀钢集团钢铁钒钛股份有限公司 | Universal rolling technology for rails |
WO2010105749A3 (en) * | 2009-03-16 | 2011-01-27 | Corus Uk Limited | A method of rolling rails, apparatus for rolling rails and rail produced according to said method |
WO2011063935A2 (en) | 2009-11-26 | 2011-06-03 | Tata Steel Uk Limited | A method of rolling rails, apparatus for rolling rails and rail produced according to said method |
CN105414172A (en) * | 2015-12-16 | 2016-03-23 | 武汉科技大学 | Method for eliminating salient points at tail end of continuous rolled steel rail |
CN105665444A (en) * | 2016-02-26 | 2016-06-15 | 攀钢集团攀枝花钢钒有限公司 | Universal hole-shaped structure used for improving rolling symmetry quality of steel rail |
RU2627140C1 (en) * | 2016-10-10 | 2017-08-03 | Акционерное общество "ЕВРАЗ Объединенный Западно-Сибирский металлургический комбинат", АО "ЕВРАЗ ЗСМК" | Method for rail rolling |
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CA2833559A1 (en) * | 2003-02-14 | 2004-09-02 | Children's Hospital & Research Center At Oakland | Treatment of conditions associated with decreased nitric oxide bioavailability, including elevated arginase conditions |
CN1753008B (en) * | 2005-10-26 | 2011-08-10 | 上海宝信软件股份有限公司 | Method of optimization hot rolling scaduled sequence |
IT1397191B1 (en) * | 2009-12-01 | 2013-01-04 | Siemens Vai Metals Tech Srl | UNIVERSAL REVERSIBLE TRAIN COMPACT FOR THE PRODUCTION OF LARGE MEDIUM PROFILES. |
CN102527714B (en) * | 2011-12-30 | 2015-01-14 | 天津市宁河县隆昌异型轧钢厂 | Rolling method for T-shaped elevator guide rail and rolling pass system |
CN106424138A (en) * | 2016-10-26 | 2017-02-22 | 攀钢集团攀枝花钢钒有限公司 | Layout structure of universal rolling mill and rolling method |
CN109158424B (en) * | 2018-09-27 | 2023-08-18 | 中重科技(天津)股份有限公司 | Axial locking device for horizontal roller system of super-huge universal rolling mill |
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US3583193A (en) * | 1967-12-16 | 1971-06-08 | Nippon Steel Corp | Rolling method and apparatus for producing h-shaped steel products having flanges of different thicknesses and similarly shaped steel products |
SU623593A1 (en) * | 1974-03-11 | 1978-08-02 | Сибирский Металлургический Институт Имени С.Орджоникидзе | Rail profile rolling method |
US4503699A (en) * | 1982-06-30 | 1985-03-12 | Nippon Steel Corporation | Method and apparatus for rolling rails |
JPH0386301A (en) * | 1989-08-29 | 1991-04-11 | Nippon Steel Corp | Rail rolling method |
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BE624447A (en) * | 1961-11-22 | |||
FR2515538B1 (en) * | 1981-11-04 | 1985-05-17 | Sacilor | |
DE3627729C2 (en) * | 1986-08-16 | 1996-03-07 | Schloemann Siemag Ag | Molded steel rolling mill |
JP2712846B2 (en) * | 1991-02-08 | 1998-02-16 | 住友金属工業株式会社 | Rolling method and rolling device for section steel |
DE19618437A1 (en) * | 1996-05-08 | 1997-11-13 | Schloemann Siemag Ag | Method for operating a roll stand system |
DE19628369A1 (en) * | 1996-07-13 | 1998-01-15 | Schloemann Siemag Ag | Process for rolling finished profiles from a preliminary profile |
-
2002
- 2002-07-19 IT IT2002MI001594A patent/ITMI20021594A1/en unknown
-
2003
- 2003-07-18 AT AT03765060T patent/ATE363952T1/en not_active IP Right Cessation
- 2003-07-18 DE DE60314256T patent/DE60314256T2/en not_active Revoked
- 2003-07-18 ES ES03765060T patent/ES2288623T3/en not_active Expired - Lifetime
- 2003-07-18 AU AU2003250119A patent/AU2003250119A1/en not_active Abandoned
- 2003-07-18 CN CNB038167786A patent/CN1299844C/en not_active Expired - Fee Related
- 2003-07-18 EP EP03765060A patent/EP1534441B1/en not_active Revoked
- 2003-07-18 WO PCT/EP2003/007897 patent/WO2004009259A1/en active IP Right Grant
- 2003-07-18 US US10/522,437 patent/US20060016236A1/en not_active Abandoned
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US3583193A (en) * | 1967-12-16 | 1971-06-08 | Nippon Steel Corp | Rolling method and apparatus for producing h-shaped steel products having flanges of different thicknesses and similarly shaped steel products |
SU623593A1 (en) * | 1974-03-11 | 1978-08-02 | Сибирский Металлургический Институт Имени С.Орджоникидзе | Rail profile rolling method |
US4503699A (en) * | 1982-06-30 | 1985-03-12 | Nippon Steel Corporation | Method and apparatus for rolling rails |
JPH0386301A (en) * | 1989-08-29 | 1991-04-11 | Nippon Steel Corp | Rail rolling method |
Non-Patent Citations (2)
Title |
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DATABASE WPI Section Ch Week 197927, Derwent World Patents Index; Class M21, AN 1979-50504B, XP002235552 * |
PATENT ABSTRACTS OF JAPAN vol. 015, no. 260 (M - 1131) 2 July 1991 (1991-07-02) * |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2010105749A3 (en) * | 2009-03-16 | 2011-01-27 | Corus Uk Limited | A method of rolling rails, apparatus for rolling rails and rail produced according to said method |
WO2011063935A2 (en) | 2009-11-26 | 2011-06-03 | Tata Steel Uk Limited | A method of rolling rails, apparatus for rolling rails and rail produced according to said method |
WO2011063935A3 (en) * | 2009-11-26 | 2011-11-24 | Tata Steel Uk Limited | A method of rolling rails, apparatus for rolling rails and rail produced according to said method |
CN101844150A (en) * | 2010-05-18 | 2010-09-29 | 攀钢集团钢铁钒钛股份有限公司 | Universal rolling technology for rails |
CN101844150B (en) * | 2010-05-18 | 2011-10-05 | 攀钢集团钢铁钒钛股份有限公司 | Universal rolling technology for rails |
CN105414172A (en) * | 2015-12-16 | 2016-03-23 | 武汉科技大学 | Method for eliminating salient points at tail end of continuous rolled steel rail |
CN105665444A (en) * | 2016-02-26 | 2016-06-15 | 攀钢集团攀枝花钢钒有限公司 | Universal hole-shaped structure used for improving rolling symmetry quality of steel rail |
CN105665444B (en) * | 2016-02-26 | 2018-03-06 | 攀钢集团攀枝花钢钒有限公司 | For improving the Universal Pass structure of steel rail rolling Symmetric Mass |
RU2627140C1 (en) * | 2016-10-10 | 2017-08-03 | Акционерное общество "ЕВРАЗ Объединенный Западно-Сибирский металлургический комбинат", АО "ЕВРАЗ ЗСМК" | Method for rail rolling |
Also Published As
Publication number | Publication date |
---|---|
CN1668394A (en) | 2005-09-14 |
ES2288623T3 (en) | 2008-01-16 |
WO2004009259A8 (en) | 2004-05-06 |
DE60314256T2 (en) | 2008-02-07 |
ATE363952T1 (en) | 2007-06-15 |
EP1534441A1 (en) | 2005-06-01 |
DE60314256D1 (en) | 2007-07-19 |
US20060016236A1 (en) | 2006-01-26 |
CN1299844C (en) | 2007-02-14 |
AU2003250119A8 (en) | 2004-02-09 |
AU2003250119A1 (en) | 2004-02-09 |
ITMI20021594A1 (en) | 2004-01-19 |
EP1534441B1 (en) | 2007-06-06 |
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