WO2003089711A1 - Textile mill applications of cellulosic based polymers to provide appearance and integrity benefits to fabrics during laundering and in-wear - Google Patents
Textile mill applications of cellulosic based polymers to provide appearance and integrity benefits to fabrics during laundering and in-wear Download PDFInfo
- Publication number
- WO2003089711A1 WO2003089711A1 PCT/US2003/011529 US0311529W WO03089711A1 WO 2003089711 A1 WO2003089711 A1 WO 2003089711A1 US 0311529 W US0311529 W US 0311529W WO 03089711 A1 WO03089711 A1 WO 03089711A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- group
- alkyl
- hydroxyalkyl
- independently selected
- textile
- Prior art date
Links
- 239000004744 fabric Substances 0.000 title claims abstract description 67
- 239000004753 textile Substances 0.000 title claims abstract description 59
- 229920000642 polymer Polymers 0.000 title claims abstract description 32
- 230000008901 benefit Effects 0.000 title abstract description 13
- 238000004900 laundering Methods 0.000 title abstract description 9
- 238000000034 method Methods 0.000 claims abstract description 32
- 239000000203 mixture Substances 0.000 claims abstract description 20
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 21
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims description 21
- 238000011282 treatment Methods 0.000 claims description 20
- 238000006467 substitution reaction Methods 0.000 claims description 17
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 14
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical group C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 claims description 14
- 125000000547 substituted alkyl group Chemical group 0.000 claims description 14
- 239000000654 additive Substances 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 9
- 230000000996 additive effect Effects 0.000 claims description 8
- 125000000278 alkyl amino alkyl group Chemical group 0.000 claims description 7
- 125000004103 aminoalkyl group Chemical group 0.000 claims description 7
- 150000001450 anions Chemical class 0.000 claims description 7
- 150000001768 cations Chemical class 0.000 claims description 7
- 125000004985 dialkyl amino alkyl group Chemical group 0.000 claims description 7
- 229910052757 nitrogen Inorganic materials 0.000 claims description 7
- 125000003386 piperidinyl group Chemical group 0.000 claims description 7
- 229910052708 sodium Inorganic materials 0.000 claims description 7
- 239000002689 soil Substances 0.000 claims description 7
- NQRYJNQNLNOLGT-UHFFFAOYSA-N tetrahydropyridine hydrochloride Natural products C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 claims description 7
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims description 6
- 238000005525 durable press finishing Methods 0.000 claims description 6
- 125000003837 (C1-C20) alkyl group Chemical group 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 239000002759 woven fabric Substances 0.000 claims description 5
- 239000003242 anti bacterial agent Substances 0.000 claims description 4
- 239000000834 fixative Substances 0.000 claims description 4
- 239000004745 nonwoven fabric Substances 0.000 claims description 3
- 239000007921 spray Substances 0.000 claims description 3
- 239000000463 material Substances 0.000 abstract description 45
- 230000008569 process Effects 0.000 abstract description 16
- 238000001035 drying Methods 0.000 abstract description 6
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 21
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 21
- 239000002421 finishing Substances 0.000 description 11
- 238000004043 dyeing Methods 0.000 description 8
- 208000016253 exhaustion Diseases 0.000 description 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 238000005299 abrasion Methods 0.000 description 4
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical group OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 4
- 239000006187 pill Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000008186 active pharmaceutical agent Substances 0.000 description 3
- 230000000844 anti-bacterial effect Effects 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 3
- 229920002678 cellulose Polymers 0.000 description 3
- 239000001913 cellulose Substances 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- MLRVZFYXUZQSRU-UHFFFAOYSA-N 1-chlorohexane Chemical compound CCCCCCCl MLRVZFYXUZQSRU-UHFFFAOYSA-N 0.000 description 2
- BPIUIOXAFBGMNB-UHFFFAOYSA-N 1-hexoxyhexane Chemical compound CCCCCCOCCCCCC BPIUIOXAFBGMNB-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 description 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 238000010002 mechanical finishing Methods 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- -1 softeners Substances 0.000 description 2
- 125000001424 substituent group Chemical group 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 0 **(*)C(C(C1O*)O*)OC(CO*)C1OC(C(C1O*)O*)OC(CO*)C1O*(*)* Chemical compound **(*)C(C(C1O*)O*)OC(CO*)C1OC(C(C1O*)O*)OC(CO*)C1O*(*)* 0.000 description 1
- MJCMGKSJAXGINY-UHFFFAOYSA-N 1-chlorodecane;1-decoxydecane Chemical compound CCCCCCCCCCCl.CCCCCCCCCCOCCCCCCCCCC MJCMGKSJAXGINY-UHFFFAOYSA-N 0.000 description 1
- CLWAXFZCVYJLLM-UHFFFAOYSA-N 1-chlorohexadecane Chemical compound CCCCCCCCCCCCCCCCCl CLWAXFZCVYJLLM-UHFFFAOYSA-N 0.000 description 1
- GVJCEHYRKRNFHO-UHFFFAOYSA-N 1-chlorohexadecane;1-hexadecoxyhexadecane Chemical compound CCCCCCCCCCCCCCCCCl.CCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCC GVJCEHYRKRNFHO-UHFFFAOYSA-N 0.000 description 1
- IGRGSDKNGHIQFV-UHFFFAOYSA-N 1-chlorohexane;1-hexoxyhexane Chemical compound CCCCCCCl.CCCCCCOCCCCCC IGRGSDKNGHIQFV-UHFFFAOYSA-N 0.000 description 1
- 101100493710 Caenorhabditis elegans bath-40 gene Proteins 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000021523 carboxylation Effects 0.000 description 1
- 238000006473 carboxylation reaction Methods 0.000 description 1
- 229920003086 cellulose ether Polymers 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 150000003841 chloride salts Chemical class 0.000 description 1
- FOCAUTSVDIKZOP-UHFFFAOYSA-N chloroacetic acid Chemical compound OC(=O)CCl FOCAUTSVDIKZOP-UHFFFAOYSA-N 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000003292 diminished effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000002979 fabric softener Substances 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
- D06M15/05—Cellulose or derivatives thereof
- D06M15/07—Cellulose esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B11/00—Preparation of cellulose ethers
- C08B11/193—Mixed ethers, i.e. ethers with two or more different etherifying groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B11/00—Preparation of cellulose ethers
- C08B11/20—Post-etherification treatments of chemical or physical type, e.g. mixed etherification in two steps, including purification
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
- D06M15/05—Cellulose or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
- D06M15/05—Cellulose or derivatives thereof
- D06M15/09—Cellulose ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/12—Soft surfaces, e.g. textile
Definitions
- the present mvention relates to textile mill applications of certain cellulosic based polymer or oligomer materials which impart appearance and integrity benefits to fabrics and textiles during laundering and in-wear.
- the applications can be stand alone or incorporated into traditional textile mill processes such as dyeing and finishing.
- Short fibers are dislodged from woven and knit fabric/textile structures by the mechanical action of laundering and abrasion/rubbing during in-wear. These dislodged fibers may form lint, fuzz or "pills" which are visible on the surface of fabrics and diminish the appearance of newness of the fabric. Further, repeated laundry-wear cycles of fabrics and textiles, can remove dye from fabrics and textiles and impart a faded, worn out appearance as a result of diminished color intensity, and in many cases, as a result of changes in hues or shades of color.
- each R is selected from the group consisting of R2, Re, and
- each R2 is independently selected from the group consisting of H and C1 -C4 alkyl
- each R c is -( CH 2 ) -C-OZ wherein each Z is independently selected from the group consisting of M, R2, Rc > and R H ; each RH is independently selected from the group consisting of C5 -C20 alkyl, C5-C7 cycloalkyl, C7-C20 alkylaryl, C7-C20 arylalkyl, substituted alkyl, hydroxyalkyl, C1-C20 alkoxy-2-hydroxyalkyl, C7-C20 alkylaryloxy-2-hydroxyalkyl, (R4)2N-alkyl, (R4)2N-2- hydroxyalkyl, ⁇ 4)3 N-alkyl, ⁇ 4)3 N-2-hydroxyalkyl, 3-C12 aryloxy-2-hydroxy alkyl, O R 5 O R 5 O O R 5 O
- each R4 is independently selected from the group consisting of H, C1-C20 alkyl, C5-C7 cycloalkyl, C7-C20 alkylaryl, C7-O20 arylalkyl, aminoalkyl, alkylaminoalkyl, dialkylaminoalkyl, piperidinoalkyl, morpholinoalkyl, cycloalkylaminoalkyl and hydroxyalkyl; each R5 is independently selected from the group consisting of H, CT -C20 alkyl, C5-C7 cycloalkyl, C7-C20 alkylaryl, C7-C20 arylalkyl, substituted alkyl, hydroxyalkyl,
- M is a suitable cation selected from the group consisting of Na, K, l/2Ca, and l/2Mg; each x is from 0 to about 5; each y is from about 1 to about 5; and provided that: the Degree of Substitution for group R H is between about 0.0001 and 0.1, more preferably between about 0.0005 and 0.05, and most preferably between about 0.0008 and 0.01; the Degree of Substitution for group R c wherein Z is H or M is between about 0.2 and 2.0, more preferably between about 0.3 and 1.0, and most preferably between about 0.4 and
- the cellulosic based polymer or oligomer materials defined above can be used as an additive in dyeing, dyeing aftertreatments, softener finishing, hand building finishing, durable press finishing, antibacterial finishing, soil release finishing, and even mechanical finishings, etc.
- the materials can be applied onto yarns/fabrics/textiles/garments via pad-dry processes or exhaustion methods
- the amount of the cellulosic based fabric treatment materials of the present invention needed in the textile mill applications to provide the best fabric appearance benefits depends on many factors such as yarn/fabric constructions, types of textile processes and types of textile equipment. Based on weight of fabrics, from about 0.005% to 10% of the cellulosic based materials is needed to impart fabrics with the best fabric appearance and integrity. The prefeixed amount is from about 0.01% to 3% based on weight of fabrics treated with the cellulosic based materials.
- Such benefits can include improved overall appearance, pill/fuzz reduction, antifading, improved abrasion resistance, and/or enhanced softness.
- Figure 1 is an example of the pad-dry treatment process.
- Figure 2 is an example of the exhaustion treatment method.
- the essential component of the compositions of the present invention comprises one or more cellulosic based polymer or oligomer.
- Such materials have been found to impart a number of appearance benefits to fabrics and textiles after applied onto fabrics during textile mill applications.
- Such fabric appearance benefits can include, for example, improved overall appearance of the laundered fabrics, reduction of the formation of pills and fuzz, protection against color fading, improved abrasion resistance, etc.
- the cellulosic based fabric treatment materials used in the compositions and methods herein can provide such fabric appearance benefits with acceptably little or no loss in other preferred textile properties such as fabric feel/hand, draping, softness, smoothness, etc.
- an oligomer is a molecule consisting of only a few monomer units while polymers comprise considerably more monomer units.
- oligomers are defined as molecules having an average molecular weight below about 1,000 and polymers are molecules having an average molecular weight of greater than about 1,000.
- One suitable type of cellulosic based polymer or oligomer fabric treatment material for use herein has an average molecular weight of from about 5,000 to about 2,000,000, preferably from about 50,000 to about 1,000,000.
- each R is selected from the group consisting of R2, Re, and
- each R2 is independently selected from the group consisting of H and C1-C4 alkyl
- each R c is -( CH 2 ) -C-OZ wherein each Z is independently selected from the group consisting of M, R2, Re, and R H ; each R H is independently selected from the group consisting of C5 -C20 alkyl, C5-C7 cycloalkyl, C7-C20 alkylaryl, C7-C20 arylalkyl, substituted alkyl, hydroxyalkyl, C1-C20 alkoxy-2-hydroxyalkyl, C -C20 alkylaryloxy-2-hydroxyalkyl, (R4>2N-al yl, (R4)2N-2- hydroxyalkyl, (R4)3 N-alkyl, ⁇ 4)3 N-2-hydroxyalkyl, Cg-C] ⁇ aryloxy-2-hydroxyalkyl,
- each R4 is independently selected from the group consisting of H, C1-C20 alkyl, C5-C7 cycloalkyl, C7-C20 alkylaryl, C7-C20 arylalkyl, aminoalkyl, alkylaminoalkyl, dialkylaminoalkyl, piperidinoalkyl, mo holinoalkyl, cycloalkylaminoalkyl and hydroxyalkyl; each R5 is independently selected from the group consisting of H, C ⁇ -C20 alkyl, C5-C7 cycloalkyl, C7-C20 alkylaryl, C -C20 arylalkyl, substituted alkyl, hydroxyalkyl,
- M is a suitable cation selected from the group consisting of Na, K, l/2Ca, and l/2Mg; each x is from 0 to about 5; each y is from about 1 to about 5; and provided that: the Degree of Substitution for group R H is between about 0.0001 and 0.1, more preferably between about 0.0005 and 0.05, and most preferably between about 0.0008 and 0.01; the Degree of Substitution for group Re wherein Z is H or M is between about 0.2 and 2.0, more preferably between about 0.3 and 1.0, and most preferably between about 0.4 and
- the "Degree of Substitution” for group R H which is sometimes abbreviated herein “DS RH ", means the number of moles of group R H components that are substituted per anhydrous glucose unit, wherein an anhydrous glucose unit is a six membered ring as shown in the repeating unit of the general structure above.
- the "Degree of Substitution" for group R c which is sometimes abbreviated herein "DS RC ", means the number of moles of group R c components, wherein Z is H or M, that are substituted per anhydrous glucose unit, wherem an anhydrous glucose unit is a six membered ring as shown in the repeating unit of the general structure above.
- the requirement that Z be H or M is necessary to insure that there are a sufficient number of carboxy methyl groups such that the resulting polymer is soluble. It is understood that in addition to the required number of R c components wherein Z is H or M, there can be, and most preferably are, additional R c components wherein Z is a group other than H or M.
- the production of materials according to the present invention is further defined in the Examples below.
- B) Textile Mill Applications The cellulosic based polymer or oligomer materials defined above can be used as an additive in dyeing, dyeing after treatments, softener finishing, hand building finishing, durable press finishing, soil release finishing, antibacterial finishing and even mechanical finishings, etc.
- the materials can be also used either by themselves alone or in conjunction with other textile additives such as but not limited to wetting agents, chelating agents, pH control agents, softeners, soil release agents, water repellants, dye fixatives, durable press finishing agents, antibacterial agents, etc..
- the cellulosic based polymer or oligomer materials are commonly utilized during the dyeing and/or finishing stages
- the materials can be applied onto yarns/fabrics/textiles/garments via both pad-dry processes and exhaustion methods as shown in Figures 1 and 2 respectively or via spray application (not shown).
- the materials can be applied to woven fabric, knit fabric, nonwoven fabric, or combinations thereof.
- the pad-dry process is common for the dyeing and finishing of woven fabrics. No curing is necessary to fix the materials onto fabrics although they are safe to go through high temperature curing processes. Examples of high temperature curing processes include but are not limited to finishes such as durable press finishes and antibacterial finishes.
- the exhaustion method is commonly used to treat knit fabrics in the textile mill applications although some knit fabrics may be treated in the pad-dry process.
- the amount of the cellulosic based fabric treatment materials of the present invention needed in the textile mill applications to provide the best fabric appearance benefits depends on many factors such as yarn/fabric constructions, types of textile processes and types of textile equipment. Based on the weight of the fabric, from about 0.005% to 10% of the cellulosic based materials is needed to impart fabrics with the best fabric appearance and integrity. The preferred amount is from about 0.01% to 3% based on the weight of the fabric treated with the cellulosic based materials.
- Such benefits can include improved overall appearance, pill/fuzz reduction, antifading, improved abrasion resistance, and/or enhanced softness.
- the concentration of the cellulosic based materials in the padding solution 20 should be determined by wet pick-up. For example, 1% of the aqueous solution is needed in the padding bath 40 if the wet pick-up is controlled as 100% based on the weight of the fabric 10 and 1% of the cellulosic based materials are needed to deliver the fabric 10 appearance and integrity benefits.
- the amount of the cellulosic based materials added into the exhaustion bath 60 is determined by the weight of the fabric 10.
- a non- limiting example would be, if a 1% add-on level of the cellulosic based materials to the fabric 10 is desired, this would be accomplished for example by adding 1 kg of the cellulosic based materials to the exhaustion bath 60 to treat 100 kg of fabric 10.
- the pH range for fabric treatment is preferably from about 3 to 12 and more preferably from about 4 to 10.
- the carboxylation of cellulose to produce CMC is a procedure that is well known to those skilled in the art.
- To produce the modified CMC materials of this invention one adds during the CMC making process the material, or materials, to be substituted.
- An example of such as procedure is given below.
- This same procedure can be utilized with the other substituent materials described herein by replacing the hexylchloride with the substituent material, or materials, of interest, for example, cetylchloride.
- the amount of material that should be added to the CMC making process to achieve the desired degree of substitution will be easily calculated by those skilled in the art in light of the following Examples.
- This example illustrates the preparation of a carboxymethyl hydrophobically modified carboxymethyl cellulose and is representative of preparation of all of the cellulose ether derivatives of this invention.
- Cellulose (20 g), sodium hydroxide (10 g), water (30 g), and ethanol (150 g) are charged into a 500 ml glass reactor.
- the resulting alkali cellulose is stirred 45 minutes at 25 °C.
- monochloroacetic acid (15 g) and hexylchloride (1 g) are added and the temperature raised over time to 95°C and held at 95°C for 150 minutes.
- the reaction is cooled to 70°C, and then cooled to 25°C.
- Neutralization is accomplished by the addition of a sufficient amount of nitric acid/acetic acid to achieve a slurry pH of between 8 and 9.
- the slurry is filtered to obtain a hexylether of CMC.
- **DS RH for these materials was in the range of from about 0.001 to about 0.1
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Textile Engineering (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Materials Engineering (AREA)
- Biochemistry (AREA)
- Molecular Biology (AREA)
- Emergency Medicine (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Cellulosic based polymer or oligomer materials for use in textile mill applications. The compositions of the present invention impart appearance and integrity benefits to fabrics and textiles during laundering and in-wear. The applications can be stand alone or incorporated into textile mill processes. The materials can be applied onto yarns/fabrics/textiles/garments via pad-dry processes or exhaustion methods.
Description
TEXTILE MILL APPLICATIONS OF CELLULOSIC BASED POLYMERS TO PROVIDE APPEARANCE AND INTEGRITY BENEFITS TO FABRICS DURING
LAUNDERING AND IN-WEAR
TECHNICAL FIELD
The present mvention relates to textile mill applications of certain cellulosic based polymer or oligomer materials which impart appearance and integrity benefits to fabrics and textiles during laundering and in-wear. The applications can be stand alone or incorporated into traditional textile mill processes such as dyeing and finishing.
BACKGROUND OF THE INVENTION
It is, of course, well known that alternating cycles of using and laundering fabrics and textiles, such as articles of clothing and apparel, will inevitably adversely affect the appearance and integrity of the fabric and textile items so used and laundered. Fabrics and textiles simply wear out over time and with use. Laundering of fabrics and textiles is necessary to remove soils and stains which accumulate therein and thereon during ordinary use. However, the laundering and in-wear, over many cycles, can accentuate and contribute to the deterioration of the integrity and the appearance of such fabrics and textiles.
Deterioration of fabric integrity and appearance can manifest itself in several ways. Short fibers are dislodged from woven and knit fabric/textile structures by the mechanical action of laundering and abrasion/rubbing during in-wear. These dislodged fibers may form lint, fuzz or "pills" which are visible on the surface of fabrics and diminish the appearance of newness of the fabric. Further, repeated laundry-wear cycles of fabrics and textiles, can remove dye from fabrics and textiles and impart a faded, worn out appearance as a result of diminished color intensity, and in many cases, as a result of changes in hues or shades of color.
Given the foregoing, there is clearly an ongoing need to identify materials which could be added to textile mill applications which reduce or minimize the tendency of fabric/textiles to deteriorate in appearance during laundering and in-wear. Any applications of such materials should, of course, be able to benefit fabric appearance and integrity without unduly interfering with other fabric/textile properties such as fabric feel or hand feel, draping, softness, smoothness, etc.. The present invention is directed to the use of cellulosic based polymer or oligomer materials in textile mill application which perform in this desired manner.
SUMMARY OF THE INVENTION
Cellulosic based polymer or oligomer materials which are suitable for textile mill applications and provide the desired fabric appearance and integrity benefits can be characterized by the following general formula:
O - each Rcis -(CH 2) -C-OZ wherein each Z is independently selected from the group consisting of M, R2, Rc> and RH; each RH is independently selected from the group consisting of C5 -C20 alkyl, C5-C7 cycloalkyl, C7-C20 alkylaryl, C7-C20 arylalkyl, substituted alkyl, hydroxyalkyl, C1-C20 alkoxy-2-hydroxyalkyl, C7-C20 alkylaryloxy-2-hydroxyalkyl, (R4)2N-alkyl, (R4)2N-2- hydroxyalkyl, ^4)3 N-alkyl, ^4)3 N-2-hydroxyalkyl, 3-C12 aryloxy-2-hydroxy alkyl, O R5 O R5 O O R5 O
II
— C- -CH- ■CH — C- -CH -CH- -C-OM , and
(R4)2N-alkyI, and (R4)3 N-alkyl; wherein:
M is a suitable cation selected from the group consisting of Na, K, l/2Ca, and l/2Mg; each x is from 0 to about 5; each y is from about 1 to about 5; and provided that: the Degree of Substitution for group RH is between about 0.0001 and 0.1, more preferably between about 0.0005 and 0.05, and most preferably between about 0.0008 and 0.01; the Degree of Substitution for group Rc wherein Z is H or M is between about 0.2 and 2.0, more preferably between about 0.3 and 1.0, and most preferably between about 0.4 and
0.7; if any RH bears a positive charge, it is balanced by a suitable anion; and two R4's on the same nitrogen can together form a ring structure selected from the group consisting of piperidine and morpholine.
The cellulosic based polymer or oligomer materials defined above can be used as an additive in dyeing, dyeing aftertreatments, softener finishing, hand building finishing, durable press finishing, antibacterial finishing, soil release finishing, and even mechanical finishings, etc. The materials can be applied onto yarns/fabrics/textiles/garments via pad-dry processes or exhaustion methods
The amount of the cellulosic based fabric treatment materials of the present invention needed in the textile mill applications to provide the best fabric appearance benefits depends on many factors such as yarn/fabric constructions, types of textile processes and types of textile equipment. Based on weight of fabrics, from about 0.005% to 10% of the cellulosic based materials is needed to impart fabrics with the best fabric appearance and integrity. The prefeixed amount is from about 0.01% to 3% based on weight of fabrics treated with the cellulosic based
materials. Such benefits can include improved overall appearance, pill/fuzz reduction, antifading, improved abrasion resistance, and/or enhanced softness.
All percentages, ratios and proportions herein are on a weight basis unless otherwise indicated. All documents cited herein are hereby incorporated by reference.
BRIEF DESCRIPTION OF THE DRAWINGS
Figure 1 is an example of the pad-dry treatment process. Figure 2 is an example of the exhaustion treatment method.
DETAILED DESCRIPTION OF THE INVENTION
A) Cellulosic Based Polymer or Oligomer Materials
The essential component of the compositions of the present invention comprises one or more cellulosic based polymer or oligomer. Such materials have been found to impart a number of appearance benefits to fabrics and textiles after applied onto fabrics during textile mill applications. Such fabric appearance benefits can include, for example, improved overall appearance of the laundered fabrics, reduction of the formation of pills and fuzz, protection against color fading, improved abrasion resistance, etc. The cellulosic based fabric treatment materials used in the compositions and methods herein can provide such fabric appearance benefits with acceptably little or no loss in other preferred textile properties such as fabric feel/hand, draping, softness, smoothness, etc.
As will be apparent to those skilled in the art, an oligomer is a molecule consisting of only a few monomer units while polymers comprise considerably more monomer units. For the present invention, oligomers are defined as molecules having an average molecular weight below about 1,000 and polymers are molecules having an average molecular weight of greater than about 1,000. One suitable type of cellulosic based polymer or oligomer fabric treatment material for use herein has an average molecular weight of from about 5,000 to about 2,000,000, preferably from about 50,000 to about 1,000,000.
One suitable group of cellulosic based polymer or oligomer materials for use herein is characterized by the following formula:
O - each Rcis -(CH 2) -C-OZ wherein each Z is independently selected from the group consisting of M, R2, Re, and RH; each RH is independently selected from the group consisting of C5 -C20 alkyl, C5-C7 cycloalkyl, C7-C20 alkylaryl, C7-C20 arylalkyl, substituted alkyl, hydroxyalkyl, C1-C20 alkoxy-2-hydroxyalkyl, C -C20 alkylaryloxy-2-hydroxyalkyl, (R4>2N-al yl, (R4)2N-2- hydroxyalkyl, (R4)3 N-alkyl, ^4)3 N-2-hydroxyalkyl, Cg-C]^ aryloxy-2-hydroxyalkyl,
O R5 O O R5 O
II I II II I II -C- -CH- -C- -CH2 — c- -CHo -CH- -C-OM , and
(R4)2N-allyl, and ^4)3 N-alkyl; wherein:
M is a suitable cation selected from the group consisting of Na, K, l/2Ca, and l/2Mg; each x is from 0 to about 5; each y is from about 1 to about 5; and provided that: the Degree of Substitution for group RH is between about 0.0001 and 0.1, more preferably between about 0.0005 and 0.05, and most preferably between about 0.0008 and 0.01; the Degree of Substitution for group Re wherein Z is H or M is between about 0.2 and 2.0, more preferably between about 0.3 and 1.0, and most preferably between about 0.4 and
0.7; if any RH bears a positive charge, it is balanced by a suitable anion; and two R4's on the same nitrogen can together form a ring structure selected from the group consisting of piperidine and morpholine.
The "Degree of Substitution" for group RH, which is sometimes abbreviated herein "DSRH", means the number of moles of group RH components that are substituted per anhydrous glucose unit, wherein an anhydrous glucose unit is a six membered ring as shown in the repeating unit of the general structure above.
The "Degree of Substitution" for group Rc, which is sometimes abbreviated herein "DSRC", means the number of moles of group Rc components, wherein Z is H or M, that are substituted per anhydrous glucose unit, wherem an anhydrous glucose unit is a six membered ring as shown in the repeating unit of the general structure above. The requirement that Z be H or M is necessary to insure that there are a sufficient number of carboxy methyl groups such that the resulting polymer is soluble. It is understood that in addition to the required number of Rc components wherein Z is H or M, there can be, and most preferably are, additional Rc components wherein Z is a group other than H or M.
Other suitable cellulosic based polymer and/or oligomer materials are described in WO 97/31950 published on September 4, 1997 and WO 98/56825 published December 17, 1998.
The production of materials according to the present invention is further defined in the Examples below. B) Textile Mill Applications
The cellulosic based polymer or oligomer materials defined above can be used as an additive in dyeing, dyeing after treatments, softener finishing, hand building finishing, durable press finishing, soil release finishing, antibacterial finishing and even mechanical finishings, etc. The materials can be also used either by themselves alone or in conjunction with other textile additives such as but not limited to wetting agents, chelating agents, pH control agents, softeners, soil release agents, water repellants, dye fixatives, durable press finishing agents, antibacterial agents, etc.. With regard to the textile processing process, the cellulosic based polymer or oligomer materials are commonly utilized during the dyeing and/or finishing stages
The materials can be applied onto yarns/fabrics/textiles/garments via both pad-dry processes and exhaustion methods as shown in Figures 1 and 2 respectively or via spray application (not shown). The materials can be applied to woven fabric, knit fabric, nonwoven fabric, or combinations thereof. The pad-dry process is common for the dyeing and finishing of woven fabrics. No curing is necessary to fix the materials onto fabrics although they are safe to go through high temperature curing processes. Examples of high temperature curing processes include but are not limited to finishes such as durable press finishes and antibacterial finishes.
The exhaustion method is commonly used to treat knit fabrics in the textile mill applications although some knit fabrics may be treated in the pad-dry process.
The amount of the cellulosic based fabric treatment materials of the present invention needed in the textile mill applications to provide the best fabric appearance benefits depends on many factors such as yarn/fabric constructions, types of textile processes and types of textile equipment. Based on the weight of the fabric, from about 0.005% to 10% of the cellulosic based materials is needed to impart fabrics with the best fabric appearance and integrity. The preferred amount is from about 0.01% to 3% based on the weight of the fabric treated with the cellulosic based materials. Such benefits can include improved overall appearance, pill/fuzz reduction, antifading, improved abrasion resistance, and/or enhanced softness.
With regard to the pad-dry process, referring to Figure 1, the concentration of the cellulosic based materials in the padding solution 20 should be determined by wet pick-up. For example, 1% of the aqueous solution is needed in the padding bath 40 if the wet pick-up is controlled as 100% based on the weight of the fabric 10 and 1% of the cellulosic based materials are needed to deliver the fabric 10 appearance and integrity benefits.
Referring to Figure 2, for the exhaustion method, the amount of the cellulosic based materials added into the exhaustion bath 60 is determined by the weight of the fabric 10. A non-
limiting example would be, if a 1% add-on level of the cellulosic based materials to the fabric 10 is desired, this would be accomplished for example by adding 1 kg of the cellulosic based materials to the exhaustion bath 60 to treat 100 kg of fabric 10.
The pH range for fabric treatment is preferably from about 3 to 12 and more preferably from about 4 to 10.
EXAMPLES
The following examples illustrate the compositions and methods of the present invention, but are not necessarily meant to limit or otherwise define the scope of the invention.
EXAMPLE I
Material composition for pad-dry application with a fabric softener
EXAMPLE II
Material composition for pad-dry application with durable press
EXAMPLE III Material composition for exhaustion application after dyeing
EXAMPLE IV
Synthesis of modified CMC Materials
The carboxylation of cellulose to produce CMC is a procedure that is well known to those skilled in the art. To produce the modified CMC materials of this invention, one adds during the CMC making process the material, or materials, to be substituted. An example of such as procedure is given below. This same procedure can be utilized with the other substituent materials described herein by replacing the hexylchloride with the substituent material, or materials, of interest, for example, cetylchloride. The amount of material that should be added to the CMC making process to achieve the desired degree of substitution will be easily calculated by those skilled in the art in light of the following Examples.
Synthesis of Hexylether of CMC
This example illustrates the preparation of a carboxymethyl hydrophobically modified carboxymethyl cellulose and is representative of preparation of all of the cellulose ether derivatives of this invention.
Cellulose (20 g), sodium hydroxide (10 g), water (30 g), and ethanol (150 g) are charged into a 500 ml glass reactor. The resulting alkali cellulose is stirred 45 minutes at 25 °C. Then monochloroacetic acid (15 g) and hexylchloride (1 g) are added and the temperature raised over time to 95°C and held at 95°C for 150 minutes. The reaction is cooled to 70°C, and then cooled to 25°C. Neutralization is accomplished by the addition of a sufficient amount of nitric acid/acetic acid to achieve a slurry pH of between 8 and 9. The slurry is filtered to obtain a hexylether of CMC.
Table D
Specific Polymer Parameters
ID Polymer Type of Types of Chemistry Modification**
*A Hexyl CMC Hexyl ether Chlorohexane added to CMC making process
*B Decyl CMC Decyl ether Chlorodecane added to CMC making process
C C12-C13 alkoxy-2 C12-C13 alkoxy-2 C12-C13 alkyl glycidyl ether hydroxypropyl CMC hydroxypropyl added to CMC making ether process
*D Hexadecyl CMC Hexadecyl ether Chlorohexadecane added to CMC making process
*E Chloride salt of 3- chloride salt of 3- 2,3-epoxypropyltrimethyl trimethylammonio-2- trimethylammonio- ammonium chloride added to hydroxypropyl ether 2-hydroxypropyl the CMC making process of CMC ether
*F [-(C(O)- Cetyl Ketene Dimer added to
CH(C16H33)- CMC making process.
C(0)CH2(C16H33) ] ester of CMC or 1,3- dioxo-2- hexadecyloctadecyl ester of CMC
CMC = Carboxymethylcellulose
* Manufactured by Noviant Specialty Chemicals
**DSRH for these materials was in the range of from about 0.001 to about 0.1
While particular embodiments of the present invention have been illustrated and described, it would be obvious to those skilled in the art that various other changes and modifications can be made without departing from the spirit and scope of the invention. It is therefore intended to cover in the appended claims all such changes and modifications that are within the scope of this invention.
Claims
1. A textile mill treatment composition, said textile mill treatment composition comprising a) a cellulosic based polymer or oligomer having the general formula:
O
- each cis -(CH 2) -C-OZ wherein each Z is independently selected from the group consisting of M, R2, Rc, and RH; each RH is independently selected from the group consisting of C5 -C20 alkyl, C5-C7 cycloalkyl, C7-C20 alkylaryl, C7-C20 arylalkyl, substituted alkyl, hydroxyalkyl, C1-C20 alkoxy-2-hydroxyalkyl, C7-C20 alkylaryloxy-2-hydroxyalkyl, (R4)2N-alkyl, (R4)2N-2- hydroxyalkyl, ^4)3 N-alkyl, ( 4)3 N-2-hydroxyalkyl, Cg-C^ aryloxy-2-hydroxyalkyl,
O R5 O R5 O R5 O
II I II I II I II
— C CH C CH2 — C CH2 CH- -C-OM , and
M is a suitable cation selected from the group consisting of Na, K, l/2Ca, and l/2Mg; each x is from 0 to about 5; each y is from about 1 to about 5; and provided that: the Degree of Substitution for group RH is between about 0.0001 and 0.1, more preferably between about 0.0005 and 0.05, and most preferably between about 0.0008 and 0.01; the Degree of Substitution for group R wherein Z is H or M is between about 0.2 and 2.0, more preferably between about 0.3 and 1.0, and most preferably between about 0.4 and 0.7; if any RH bears a positive charge, it is balanced by a suitable anion; and two R4's on the same nitrogen can together form a ring structure selected from the group consisting of piperidine and morpholine.
2. The textile mill treatment composition of Claim 1 wherein said treatment composition is added to a padding bath, an exhaustion bath, or a spray applicator, preferably wherein the pH of said padding bath, exhaustion bath, or said spray application is from about 3 to 12.
3. The textile mill treatment composition of Claim 2 wherein said composition is applied to a woven fabric, a knit fabric, or a combination thereof.
4. A fabric or textile, said fabric or textile comprising by weight from about 0.005% to 10% of cellulosic based polymers or oligomers of the general formula:
O
- each Rcis →CH2)y-C-OZ wherein each Z is independently selected from the group consisting of M, R2, Rc, and RH; each RH is independently selected from the group consisting of C5 -C20 alkyl, C5-C7 cycloalkyl, C7-C20 alkylaryl, C7-C20 arylalkyl, substituted alkyl, hydroxyalkyl, Ci -C20 alkoxy-2-hydroxyalkyl, C7-C20 alkylaryloxy-2-hydroxyalkyl, (R4)2N-alkyl, (R4)2N-2- hydroxyalkyl, (R4)3 N-alkyl, (R4)3 N-2-hydroxyalkyl, Cg-C^ aryloxy-2-hydroxyalkyl,
O R5 O R5 O R5 O
II I II I II I II
— C CH C CH2 — C CH2 CH C-OM mi
(R4)2N-alkyl, and (R4)3 N-alkyl; wherein:
M is a suitable cation selected from the group consisting of Na, K, l/2Ca, and l/2Mg; each x is from 0 to about 5; each y is from about 1 to about 5; and provided that: the Degree of Substitution for group RH is between about 0.0001 and 0.1, more preferably between about 0.0005 and 0.05, and most preferably between about 0.0008 and 0.01; the Degree of Substitution for group Rc wherein Z is H or M is between about 0.2 and 2.0, more preferably between about 0.3 and 1.0, and most preferably between about 0.4 and
0.7; if any RH bears a positive charge, it is balanced by a suitable anion; and two R4's on the same nitrogen can together form a ring structure selected from the group consisting of piperidine and morpholine.
5. A method for treating fabrics or textiles, said method comprising the steps of: a) providing a treatment composition wherein said treatment composition is comprised of a cellulosic based polymer or oligomer, wherein said cellulosic based polymer or oligomer preferably has an average molecular weight of from about 5,000 to about 2,000,000, and wherein said cellulosic based polymer or oligomer has the general formula:
O
- each Rcis -(CH2)y-C-OZ wherein each Z is independently selected from the group consisting of M, R2, Rc, and RH; each RH is independently selected from the group consisting of C5 -C20 alkyl, C5-C7 cycloalkyl, C -C20 alkylaryl, C7-C20 arylalkyl, substituted alkyl, hydroxyalkyl, C1-C20 alkoxy-2-hydroxyalkyl, C7-C20 alkylaryloxy-2-hydroxyalkyl, (R4)2N-alkyl, (R4)2N-2- hydroxyalkyl, (1*4)3 N-alkyl, (R4)3 N-2-hydroxyalkyl, Cg-Cj^ aryloxy-2-hydroxy alkyl,
O R5 O O R R55 O O R R55 O
I I I II I IIII I I II
— C CH- -C- -CH L, —— r C- -CτHx - PCHH- - PC--ΠOAM , and
(R )2N-alkyl, and (R4)3 N-alkyl; wherein:
M is a suitable cation selected from the group consisting of Na, K, l/2Ca, and l/2Mg; each x is from 0 to about 5; each y is from about 1 to about 5; and provided that: the Degree of Substitution for group RH is between about 0.0001 and 0.1, more preferably between about 0.0005 and 0.05, and most preferably between about 0.0008 and 0.01; the Degree of Substitution for group Rc wherein Z is H or M is between about 0.2 and 2.0, more preferably between about 0.3 and 1.0, and most preferably between about 0.4 and
0.7; if any RH bears a positive charge, it is balanced by a suitable anion; and two R4' s on the same nitrogen can together form a ring structure selected from the group consisting of piperidine and morpholine; and b) applying said cellulosic based polymer or oligomer to a fabric or textile in the amount of from about 0.005% to 10% by weight preferably wherein said fabric or textile is a woven fabric, a knit fabric, a nonwoven fabric, or a combination thereof.
6. A method for treating fabrics or textiles, said method comprising the steps of : a) providing a treatment composition wherein said treatment composition is comprised of a cellulosic based polymer or oligomer wherein said cellulosic based polymer or oligomer preferably has an average molecular weight of from about 5,000 to about 2,000,000, and wherein said cellulosic based polymer or oligomer has the general formula:
wherein: each R2 is independently selected from the group consisting of H and C1-C4 alkyl;
O
- each Rcis -(CH2)y-C-OZ wherein each Z is independently selected from the group consisting of M, R2, Rc, and RH; each RH is independently selected from the group consisting of C5 -C20 alkyl, C5-C7 cycloalkyl, C -C20 alkylaryl, C -C20 arylalkyl, substituted alkyl, hydroxyalkyl, C -C20 alkoxy-2-hydroxyalkyl, C7-C20 alkylaryIoxy-2-hydroxyalkyl, (R4)2N-alkyl, (R4)2N-2- hydroxyalkyl, (R4)3 N-alkyl, (R4)3 N-2-hydroxyalkyl, C -C12 aryloxy-2-hydroxyalkyl,
O O R5 O R5 O
II II I II I II — C- -CH- -C- ■CH2 — C- -CH7 -CH- -C-OM , and
(R4)2N-alkyl, and (R4)3 N-alkyl; wherein:
M is a suitable cation selected from the group consisting of Na, K, l/2Ca, and l/2Mg; each x is from 0 to about 5; each y is from about 1 to about 5; and provided that: the Degree of Substitution for group RH is between about 0.0001 and 0.1, more preferably between about 0.0005 and 0.05, and most preferably between about 0.0008 and 0.01; the Degree of Substitution for group Rc wherein Z is H or M is between about 0.2 and 2.0, more preferably between about 0.3 and 1.0, and most preferably between about 0.4 and 0.7; if any RH bears a positive charge, it is balanced by a suitable anion; and - two R4' s on the same nitrogen can together form a ring structure selected from the group consisting of piperidine and morpholine; and b) adding said cellulosic based polymer or oligomer to a padding bath or an exhaustion bath, preferably wherein the pH range of said padding bath or said exhaustion bath is from about 3 to 12; and c) adding a fabric or textile to said padding bath or said exhaustion bath whereby said cellulosic based polymer or oligomer is applied to said fabric or textile in the amount of from about 0.005% to 10% by weigh and preferably wherein said fabric or textile is a woven fabric, a knit fabric, a nonwoven fabric, or a combination thereof.
7. The textile mill treatment composition of Claim 1 wherein said cellulosic based polymer or oligomer has an average molecular weight of from about 5,000 to about 2,000,000.
8. The textile mill treatment composition of Claim 1 wherein said treatment composition further comprises a textile additive, preferably wherein said textile additive is a softener, soil release agent, water repellant, dye fixative, durable press finishing agent, antibacterial agent, or a combination thereof.
9. The method of Claim 6 further comprising adding a textile additive to said padding bath or said exhaustion bath, preferably wherein said textile additive is a softener, soil release agent, water repellant, dye fixative, durable press finishing agent, antibacterial agent, or a combination thereof.
10. A system for treating textiles, said system comprising: a) a cellulosic based polymer or oligomer having the general formula:
O
- each Rcis -(CH 2)y-C-OZ wherein each Z is independently selected from the group consisting of M, R2, Rc, and RH; each RH is independently selected from the group consisting of C5 -C20 alkyl, C5-C7 cycloalkyl, C7-C20 alkylaryl, C7-C20 arylalkyl, substituted alkyl, hydroxyalkyl, Ci -C20 alkoxy-2-hydroxyalkyl, C7-C20 alkylaryloxy-2-hydroxyalkyl, (R4)2N-alkyl, (R4)2N-2- hydroxyalkyl, ^4)3 N-alkyl, (R4)3 N-2-hydroxyalkyl, Cg-C^ aryloxy-2-hydroxyalkyl, O R5 O R5 O R5 O
II I II I II I II
— C CH C CH2 — C CH2 CH C-OM and
(R4)2N-alkyl, and (R4)3 N-alkyl; wherein:
M is a suitable cation selected from the group consisting of Na, K, l/2Ca, and l/2Mg; each x is from 0 to about 5; each y is from about 1 to about 5; and provided that: the Degree of Substitution for group RH is between about 0.0001 and 0.1, more preferably between about 0.0005 and 0.05, and most preferably between about 0.0008 and 0.01; the Degree of Substitution for group Rc wherein Z is H or M is between about 0.2 and 2.0, more preferably between about 0.3 and 1.0, and most preferably between about 0.4 and
0.7; if any RH bears a positive charge, it is balanced by a suitable anion; and two R4's on the same nitrogen can together form a ring structure selected from the group consisting of piperidine and morpholine; and b) a textile additive, preferably wherein said textile additive is a softener, soil release agent, water repellant, dye fixative, durable press finishing agent, antibacterial agent, or a combination thereof.
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA002480283A CA2480283A1 (en) | 2002-04-16 | 2003-04-16 | Textile mill applications of cellulosic based polymers to provide appearance and integrity benefits to fabrics during laundering and in-wear |
| BR0309312-3A BR0309312A (en) | 2002-04-16 | 2003-04-16 | Treatment composition for the textile, fabric or textile industry, method of treatment thereof and system for treating textile products |
| JP2003586415A JP2005520951A (en) | 2002-04-16 | 2003-04-16 | Cellulosic-based polymer textile mill application that provides appearance and integrity benefits to the fabric during cleaning and wearing |
| EP03746987A EP1495181A1 (en) | 2002-04-16 | 2003-04-16 | Textile mill applications of cellulosic based polymers to provide appearance and integrity benefits to fabrics during laundering and in-wear |
| AU2003226390A AU2003226390A1 (en) | 2002-04-16 | 2003-04-16 | Textile mill applications of cellulosic based polymers to provide appearance and integrity benefits to fabrics during laundering and in-wear |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US37287702P | 2002-04-16 | 2002-04-16 | |
| US60/372,877 | 2002-04-16 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2003089711A1 true WO2003089711A1 (en) | 2003-10-30 |
Family
ID=29250924
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/US2003/011529 WO2003089711A1 (en) | 2002-04-16 | 2003-04-16 | Textile mill applications of cellulosic based polymers to provide appearance and integrity benefits to fabrics during laundering and in-wear |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US20030226212A1 (en) |
| EP (1) | EP1495181A1 (en) |
| JP (1) | JP2005520951A (en) |
| CN (1) | CN1646760A (en) |
| AU (1) | AU2003226390A1 (en) |
| BR (1) | BR0309312A (en) |
| CA (1) | CA2480283A1 (en) |
| WO (1) | WO2003089711A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005108670A2 (en) * | 2004-05-05 | 2005-11-17 | The Procter & Gamble Company | Textile benefit compositions |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060248657A1 (en) * | 2004-05-05 | 2006-11-09 | Jiping Wang | Textile benefit compositions |
| BRPI0706667A2 (en) * | 2006-01-19 | 2011-04-05 | Procter & Gamble | fabric treatment composition providing a stain-repellent coating |
| WO2008063641A1 (en) * | 2006-11-22 | 2008-05-29 | The Procter & Gamble Company | Benefit compositions and methods |
| US20090014034A1 (en) * | 2006-11-22 | 2009-01-15 | The Procter & Gamble Company | Benefit compositions and formaldehyde scavengers for same |
| WO2011121073A1 (en) * | 2010-03-31 | 2011-10-06 | Henkel Ag & Co. Kgaa | Washing composition for sensitive textiles |
| CN110291181A (en) * | 2017-02-13 | 2019-09-27 | 荷兰联合利华有限公司 | Clothes clothes washing system |
| EP3580317B1 (en) | 2017-02-13 | 2021-10-13 | Unilever IP Holdings B.V. | Laundry composition additive |
| BR112019016823B1 (en) | 2017-02-13 | 2024-01-02 | Unilever Ip Holdings B.V. | AUXILIARY COMPOSITION FOR FABRIC WASHING, FABRIC WASHING METHOD AND USE OF THE AUXILIARY COMPOSITION FOR FABRIC WASHING |
| BR112019016821B1 (en) | 2017-02-13 | 2023-03-28 | Unilever Ip Holdings B.V | METHOD OF APPLICATION OF A SERUM COMPOSITION FOR WASHING FABRIC IN THE WASHING OR RINSE CYCLE |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1998029528A2 (en) * | 1996-12-26 | 1998-07-09 | The Procter & Gamble Company | Laundry detergent compositions with cellulosic polymers |
| WO1999014295A1 (en) * | 1997-09-15 | 1999-03-25 | The Procter & Gamble Company | Laundry detergent compositions with cellulosic based polymers to provide appearance and integrity benefits to fabrics laundered therewith |
| WO1999014245A1 (en) * | 1997-09-15 | 1999-03-25 | The Procter & Gamble Company | Laundry detergent compositions with cellulosic based polymers to provide appearance and integrity benefits to fabrics laundered therewith |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3950276A (en) * | 1971-09-01 | 1976-04-13 | Colgate-Palmolive Company | Sulfonate detergent compositions |
| US4199464A (en) * | 1977-12-23 | 1980-04-22 | The Procter & Gamble Company | Laundry detergent substrate articles |
| US4205063A (en) * | 1979-04-12 | 1980-05-27 | Johnson Products Co., Inc. | Low irritant conditioning shampoo composition |
| US4329237A (en) * | 1979-11-21 | 1982-05-11 | Colgate-Palmolive Company | Detergent softener compositions |
| GB8519047D0 (en) * | 1985-07-29 | 1985-09-04 | Unilever Plc | Detergent composition |
| US5308513A (en) * | 1990-07-20 | 1994-05-03 | Colgate-Palmolive Company | Wash cycle or rinse cycle fabric conditioning compositions |
| SK100593A3 (en) * | 1991-03-19 | 1994-07-06 | Procter & Gamble | Hair care compositions having styling/conditioning agent and plastificator |
| US5837666A (en) * | 1994-06-30 | 1998-11-17 | The Procter & Gamble Company | Detergent compositions comprising methyl cellulose ether |
| GB2297978A (en) * | 1995-02-15 | 1996-08-21 | Procter & Gamble | Detergent compositions containing amylase |
| US6511928B2 (en) * | 1998-09-30 | 2003-01-28 | The Procter & Gamble Company | Rayon fabric with substantial shrink-resistant properties |
| US5885303A (en) * | 1997-05-13 | 1999-03-23 | American Laundry Machinery Incorporated | Durable press/wrinkle-free process |
| US6375685B2 (en) * | 1997-05-13 | 2002-04-23 | The Procter & Gamble Company | Textile finishing process |
| US6384011B1 (en) * | 1997-09-15 | 2002-05-07 | The Procter & Gamble Company | Laundry detergent compositions with cellulosic based polymers to provide appearance and integrity benefits to fabrics laundered therewith |
| JP4275312B2 (en) * | 1997-09-15 | 2009-06-10 | ザ プロクター アンド ギャンブル カンパニー | Laundry detergent composition having a linear amine-based polymer for imparting appearance and integrity benefits to fabrics washed therewith |
| US6579840B1 (en) * | 1998-10-13 | 2003-06-17 | The Procter & Gamble Company | Detergent compositions or components comprising hydrophobically modified cellulosic polymers |
-
2003
- 2003-04-14 US US10/413,632 patent/US20030226212A1/en not_active Abandoned
- 2003-04-16 CN CNA038081326A patent/CN1646760A/en active Pending
- 2003-04-16 CA CA002480283A patent/CA2480283A1/en not_active Abandoned
- 2003-04-16 AU AU2003226390A patent/AU2003226390A1/en not_active Abandoned
- 2003-04-16 EP EP03746987A patent/EP1495181A1/en not_active Withdrawn
- 2003-04-16 WO PCT/US2003/011529 patent/WO2003089711A1/en not_active Application Discontinuation
- 2003-04-16 JP JP2003586415A patent/JP2005520951A/en not_active Withdrawn
- 2003-04-16 BR BR0309312-3A patent/BR0309312A/en not_active IP Right Cessation
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1998029528A2 (en) * | 1996-12-26 | 1998-07-09 | The Procter & Gamble Company | Laundry detergent compositions with cellulosic polymers |
| WO1999014295A1 (en) * | 1997-09-15 | 1999-03-25 | The Procter & Gamble Company | Laundry detergent compositions with cellulosic based polymers to provide appearance and integrity benefits to fabrics laundered therewith |
| WO1999014245A1 (en) * | 1997-09-15 | 1999-03-25 | The Procter & Gamble Company | Laundry detergent compositions with cellulosic based polymers to provide appearance and integrity benefits to fabrics laundered therewith |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005108670A2 (en) * | 2004-05-05 | 2005-11-17 | The Procter & Gamble Company | Textile benefit compositions |
| WO2005108670A3 (en) * | 2004-05-05 | 2006-01-05 | Procter & Gamble | Textile benefit compositions |
Also Published As
| Publication number | Publication date |
|---|---|
| AU2003226390A1 (en) | 2003-11-03 |
| JP2005520951A (en) | 2005-07-14 |
| BR0309312A (en) | 2005-02-15 |
| US20030226212A1 (en) | 2003-12-11 |
| CA2480283A1 (en) | 2003-10-30 |
| EP1495181A1 (en) | 2005-01-12 |
| CN1646760A (en) | 2005-07-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR100540323B1 (en) | A textile auxiliary agent and process for the treatment of cellulosic moulded bodies by using the same | |
| WO2003089711A1 (en) | Textile mill applications of cellulosic based polymers to provide appearance and integrity benefits to fabrics during laundering and in-wear | |
| JP4302523B2 (en) | Textile processing composition and method of using the composition | |
| AU751297B2 (en) | Crosslinkable fabric care compositions | |
| JP2005506465A (en) | Textile processing composition and method of using the composition | |
| CA2514766A1 (en) | Laundry cleansing and conditioning compositions | |
| US20030226213A1 (en) | Textile mill applications of cellulosic based polymers to provide appearance and integrity benefits to fabrics during laundering and in-wear | |
| JP2000513412A (en) | Method for treating cellulosic fibers and assemblies produced from those fibers | |
| CA2564857A1 (en) | Textile benefit compositions | |
| EP1567708B1 (en) | Fabric treatment | |
| US3952128A (en) | Durable antistatic agent, hydrophobic fibers and fibrous structures having durable antistatic property and method of making same | |
| US20220090316A1 (en) | A method of providing oil and/or grease resistant textile materials | |
| JP2003531281A (en) | Fabric care composition containing modified starch-based polymer and method using the same | |
| US6369023B1 (en) | Use of polyether hydroxycarboxylate copolymers in textile manufacturing and treating processes | |
| JP7432436B2 (en) | fiber treatment agent | |
| DE2236273A1 (en) | AMPHOTIC TOOLS FOR THE FINISHING OF NATURAL OR SYNTHETIC FIBERS CONTAINING TEXTILES, LEATHER OR PAPER | |
| JP2002294556A (en) | Hygroscopic synthetic fiber with high whiteness, and method for producing the fiber | |
| KR100330274B1 (en) | Synthesis and application of low temperature reactive antimicrobial agents for cellulosic materials | |
| AU765848B2 (en) | Polysaccharide aldehydes and acetals as permanent press agents for textiles | |
| CN115819717A (en) | Washable daily softener, and preparation method and application thereof | |
| JP2005307416A (en) | Washable processing method for giving silk fiber material with excellent fabric hand durability | |
| WO2019238590A1 (en) | Method for providing an anti-microbial and an anti-pilling effect and for improving dye uptake to textiles, novel co-polymers and textiles | |
| JP2561752B2 (en) | Detergent composition | |
| JP2007146349A (en) | Method for reserve print-processing silk fiber material | |
| JPH0434075A (en) | Antimicrobial and deodorant polyester-based fiber structure and production thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| AK | Designated states |
Kind code of ref document: A1 Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NI NO NZ OM PH PL PT RO RU SC SD SE SG SK SL TJ TM TN TR TT TZ UA UG UZ VC VN YU ZA ZM ZW |
|
| AL | Designated countries for regional patents |
Kind code of ref document: A1 Designated state(s): GH GM KE LS MW MZ SD SL SZ TZ UG ZM ZW AM AZ BY KG KZ MD RU TJ TM AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LU MC NL PT RO SE SI SK TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG |
|
| 121 | Ep: the epo has been informed by wipo that ep was designated in this application | ||
| WWE | Wipo information: entry into national phase |
Ref document number: 2003586415 Country of ref document: JP |
|
| WWE | Wipo information: entry into national phase |
Ref document number: 2003746987 Country of ref document: EP Ref document number: 2480283 Country of ref document: CA |
|
| WWE | Wipo information: entry into national phase |
Ref document number: 20038081326 Country of ref document: CN |
|
| WWP | Wipo information: published in national office |
Ref document number: 2003746987 Country of ref document: EP |
|
| WWW | Wipo information: withdrawn in national office |
Ref document number: 2003746987 Country of ref document: EP |