CN1646760A - Textile mill applications of cellulosic based polymers to provide appearance and integrity benefits to fabrics during laundering and in-wear - Google Patents
Textile mill applications of cellulosic based polymers to provide appearance and integrity benefits to fabrics during laundering and in-wear Download PDFInfo
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- CN1646760A CN1646760A CNA038081326A CN03808132A CN1646760A CN 1646760 A CN1646760 A CN 1646760A CN A038081326 A CNA038081326 A CN A038081326A CN 03808132 A CN03808132 A CN 03808132A CN 1646760 A CN1646760 A CN 1646760A
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- Prior art keywords
- alkyl
- hydroxy
- independently selected
- cycloalkyl
- fabric
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- 239000004744 fabric Substances 0.000 title claims abstract description 67
- 239000004753 textile Substances 0.000 title claims abstract description 57
- 229920000642 polymer Polymers 0.000 title claims abstract description 33
- 238000004900 laundering Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 claims abstract description 27
- 239000000203 mixture Substances 0.000 claims abstract description 22
- 125000000217 alkyl group Chemical group 0.000 claims description 21
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims description 21
- -1 replacement Chemical group 0.000 claims description 19
- 238000006467 substitution reaction Methods 0.000 claims description 17
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 claims description 14
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 14
- 239000003795 chemical substances by application Substances 0.000 claims description 13
- 239000000654 additive Substances 0.000 claims description 10
- 230000000996 additive effect Effects 0.000 claims description 10
- 238000009941 weaving Methods 0.000 claims description 8
- 125000000278 alkyl amino alkyl group Chemical group 0.000 claims description 7
- 125000004103 aminoalkyl group Chemical group 0.000 claims description 7
- 150000001450 anions Chemical class 0.000 claims description 7
- 150000001768 cations Chemical class 0.000 claims description 7
- 125000006310 cycloalkyl amino group Chemical group 0.000 claims description 7
- 125000004985 dialkyl amino alkyl group Chemical group 0.000 claims description 7
- 125000003386 piperidinyl group Chemical group 0.000 claims description 7
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 6
- 239000004902 Softening Agent Substances 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 230000002421 anti-septic effect Effects 0.000 claims description 4
- 239000003599 detergent Substances 0.000 claims description 4
- 239000007921 spray Substances 0.000 claims description 3
- 230000002940 repellent Effects 0.000 claims 3
- 239000005871 repellent Substances 0.000 claims 3
- 239000000463 material Substances 0.000 abstract description 37
- 238000001035 drying Methods 0.000 abstract 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 22
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 22
- 238000002360 preparation method Methods 0.000 description 12
- 230000009286 beneficial effect Effects 0.000 description 11
- 238000004043 dyeing Methods 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- 239000000975 dye Substances 0.000 description 6
- 238000005406 washing Methods 0.000 description 6
- 230000004048 modification Effects 0.000 description 5
- 238000012986 modification Methods 0.000 description 5
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Chemical compound OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 4
- MLRVZFYXUZQSRU-UHFFFAOYSA-N 1-chlorohexane Chemical compound CCCCCCCl MLRVZFYXUZQSRU-UHFFFAOYSA-N 0.000 description 3
- BPIUIOXAFBGMNB-UHFFFAOYSA-N 1-hexoxyhexane Chemical compound CCCCCCOCCCCCC BPIUIOXAFBGMNB-UHFFFAOYSA-N 0.000 description 3
- TURGQPDWYFJEDY-UHFFFAOYSA-N 1-hydroperoxypropane Chemical compound CCCOO TURGQPDWYFJEDY-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000008186 active pharmaceutical agent Substances 0.000 description 3
- 230000003115 biocidal effect Effects 0.000 description 3
- 229920003174 cellulose-based polymer Polymers 0.000 description 3
- 238000010276 construction Methods 0.000 description 3
- 239000002979 fabric softener Substances 0.000 description 3
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 239000000080 wetting agent Substances 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 description 2
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 239000002738 chelating agent Substances 0.000 description 2
- 150000003841 chloride salts Chemical class 0.000 description 2
- 238000005202 decontamination Methods 0.000 description 2
- 230000003588 decontaminative effect Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 238000010002 mechanical finishing Methods 0.000 description 2
- 238000012805 post-processing Methods 0.000 description 2
- 238000003672 processing method Methods 0.000 description 2
- 230000003252 repetitive effect Effects 0.000 description 2
- 230000002194 synthesizing effect Effects 0.000 description 2
- ZTEHOZMYMCEYRM-UHFFFAOYSA-N 1-chlorodecane Chemical compound CCCCCCCCCCCl ZTEHOZMYMCEYRM-UHFFFAOYSA-N 0.000 description 1
- FDCJDKXCCYFOCV-UHFFFAOYSA-N 1-hexadecoxyhexadecane Chemical compound CCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCC FDCJDKXCCYFOCV-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- BOXMCJRNMGUMDI-UHFFFAOYSA-N CCCCCCCCCCCCCCCC.[Cl] Chemical compound CCCCCCCCCCCCCCCC.[Cl] BOXMCJRNMGUMDI-UHFFFAOYSA-N 0.000 description 1
- 101100493710 Caenorhabditis elegans bath-40 gene Proteins 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 241001597008 Nomeidae Species 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000021523 carboxylation Effects 0.000 description 1
- 238000006473 carboxylation reaction Methods 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- FOCAUTSVDIKZOP-UHFFFAOYSA-N chloroacetic acid Chemical compound OC(=O)CCl FOCAUTSVDIKZOP-UHFFFAOYSA-N 0.000 description 1
- 229940106681 chloroacetic acid Drugs 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- HMHFERXOZSZRML-UHFFFAOYSA-M trimethyl-(3-methyloxiran-2-yl)azanium;chloride Chemical compound [Cl-].CC1OC1[N+](C)(C)C HMHFERXOZSZRML-UHFFFAOYSA-M 0.000 description 1
- 238000004078 waterproofing Methods 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
Images
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
- D06M15/05—Cellulose or derivatives thereof
- D06M15/07—Cellulose esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B11/00—Preparation of cellulose ethers
- C08B11/193—Mixed ethers, i.e. ethers with two or more different etherifying groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B11/00—Preparation of cellulose ethers
- C08B11/20—Post-etherification treatments of chemical or physical type, e.g. mixed etherification in two steps, including purification
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
- D06M15/05—Cellulose or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
- D06M15/05—Cellulose or derivatives thereof
- D06M15/09—Cellulose ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/12—Soft surfaces, e.g. textile
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Textile Engineering (AREA)
- Wood Science & Technology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Emergency Medicine (AREA)
- Molecular Biology (AREA)
- Biochemistry (AREA)
- Materials Engineering (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Cellulosic based polymer or oligomer materials for use in textile mill applications. The compositions of the present invention impart appearance and integrity benefits to fabrics and textiles during laundering and in-wear. The applications can be stand alone or incorporated into textile mill processes. The materials can be applied onto yarns/fabrics/textiles/garments via pad-dry processes or exhaustion methods.
Description
Invention field
The present invention relates to the textile mill applications of some cellulosic based polymer or oligomer material, this material is given fabric and textile appearance and integrality beneficial effect in washing and wearing process.The operation of traditional textile mills can be carried out or be attached to described application separately as in dyeing and the arrangement.
Background of invention
Certainly, known to fabric and textiles such as clothing and clothing item use and wash this alternate cycles will be inevitably to the fabric and the textiles goods that use and wash cause adverse influence.Along with time and dress, fabric and textiles wear and tear easily.Its dirt and stain of accumulation on it that neutralize when removing daily use, it is essential that fabric and textiles are washed.Yet, cross integrality and degraded appearance that multiply periodic washing and dress can increase the weight of and impel these fabrics and textiles.
The variation of fabric and textiles integrality and outward appearance can show to several modes self.Because the mechanism in when washing and the wearing and tearing/friction when wearing are evicted staple fibre from from woven and knit goods/textile constructions.These dispossessed fibers can form the visible velveteen of fabric face, fine hair or " bead ", and reduce the brand-new degree of appearance of fabrics.In addition, the cyclic washing of fabric and textiles-wear circulation can be washed the dyestuff in fabric and the textiles off, and because the weakening of color intensity, in most of the cases, because the outward appearance that tone variations or colour-darkening have it to fade, wear and tear.
According to the above, obviously have a kind of lasting needs: determine to join the material in the textile mill applications, this application can reduce or minimize the trend of fabric/textile degraded appearance in washing and wearing process.Certainly, any application of this material should be able to be of value to appearance of fabrics and integrality, and other fabric/textile character such as textile feel or feel, drapability, flexibility, smoothness etc. are not had influence improperly.The cellulosic based polymer or the oligomer material that the present invention relates in textile mill applications to use the mode with this expectation to work.
Summary of the invention
Be suitable for textile mill applications and provide required appearance of fabrics and the cellulosic based polymer of integrality beneficial effect or oligomer material can characterize with following general formula:
Wherein each R is selected from R
2, R
CAnd
Wherein:
-each R
2Be independently selected from H and C
1-C
4Alkyl;
-each R
CFor
Wherein each Z is independently selected from M, R
2, R
CAnd R
H
-each R
HBe independently selected from C
5-C
20Alkyl, C
5-C
7Cycloalkyl, C
7-C
20Alkylaryl, C
7-C
20The alkyl of aryl alkyl, replacement, hydroxy alkyl, C
1-C
20Alkoxyl-2-hydroxy alkyl, C
7-C
20Alkyl-aryloxy-2-hydroxy alkyl, (R
4)
2N-alkyl, (R
4)
2N-2-hydroxy alkyl, (R
4)
3N-alkyl, (R
4)
3N-2-hydroxy alkyl, C
6-C
12Aryloxy group-2-hydroxy alkyl,
With
-each R
4Be independently selected from H, C
1-C
20Alkyl, C
5-C
7Cycloalkyl, C
7-C
20Alkylaryl, C
7-C
20Aryl alkyl, aminoalkyl, alkyl amino alkyl, dialkyl aminoalkyl, piperidino alkyl, morpholino alkyl, cycloalkyl amino alkyl and hydroxy alkyl;
-each R
5Be independently selected from H, C
1-C
20Alkyl, C
5-C
7Cycloalkyl, C
7-C
20Alkylaryl, C
7-C
20The alkyl of aryl alkyl, replacement, hydroxy alkyl, (R
4)
2N-alkyl and (R
4)
3The N-alkyl;
Wherein:
M is suitable CATION, and it is selected from Na, K, 1/2Ca and 1/2Mg;
Each x is 0 to about 5;
Each y is about 1 to about 5; And
Precondition is:
-radicals R
HSubstitution value between about 0.0001 and 0.1, more preferably between about 0.0005 and 0.05, most preferably between about 0.0008 and 0.01;
-wherein Z is the radicals R of H or M
CSubstitution value between about 0.2 and 2.0, more preferably between about 0.3 and 1.0, most preferably between about 0.4 and 0.7;
If-any R
HHave positive charge, it comes balance by suitable anion; And
Two R the on-same nitrogen-atoms
4Can form the ring structure that is selected from piperidines and morpholine together.
More than Ding Yi cellulosic based polymer or oligomer material can be used as dyeing, dyeing post processing, softening arrangement, improve hand feel finishing, durable press finished, antibiotic finish, decontamination arrangement and even mechanical finishing etc. in additive.These materials can by roll-the baking method or to the greatest extent the method for dying be applied on yarn/fabric/textile/clothes.
In textile mill applications, provide the required cellulosic based fabric treating amount of substance of the present invention of best appearance of fabrics beneficial effect to depend on many factors, for example yarn/fabric construction, textile treatment type and Weaving device type.Based on the weight of fabric, need about 0.005% to 10% appearance of fabrics and the integrality of cellulosic based material to give fabric the best.Preferred amount is based on about 0.01% to 3% of the fabric weight of using the cellulosic based mass treatment.These beneficial effects comprise and improve overall appearance, reduce balling-up/fluff, prevent to fade, improve ABRASION RESISTANCE and/or increase flexibility.
Except as otherwise noted, all percentages of the present invention, ratio and ratio are all by weight.All documents that this paper quotes are incorporated herein by reference.
The accompanying drawing summary
Fig. 1 is the embodiment that rolls-dry by the fire processing method.
Fig. 2 is for dying the embodiment of processing method to the greatest extent.
Detailed Description Of The Invention
A)
Cellulosic based polymer or oligomer material
The solvent of the present composition comprises one or more cellulosic based polymer or oligomer. After having found to be applied to this class material on the fabric in textile mill applications, it will give fabric and the many outward appearance beneficial effects of textile. This appearance of fabrics beneficial effect can comprise, for example, improves overall appearance, the formation that reduces bobbles and fine hair of being washed fabric, prevents from fading, improving wearability etc. Used cellulosic based polymer can provide these appearance of fabrics beneficial effects in the present composition and the method, and other preferred textile character such as textile feel/feel, drapability, flexibility, smoothness reduce and the people can be accepted or do not reduce.
Should understand that such as those skilled in the art oligomer is the molecule that only is comprised of several monomeric units, polymer then comprises considerable monomeric unit. For the purpose of the present invention, oligomer is defined as mean molecule quantity and is lower than about 1,000 molecule, and polymer is mean molecule quantity greater than about 1,000 molecule. The mean molecule quantity that can be used for the suitable cellulosic based polymer of the class of this paper or oligomer fabric treating material is about 5,000 to about 2,000,000, is preferably about 50,000 to about 1,000,000.
The one group of suitable cellulosic based polymer or the oligomer material that can be used for this paper can characterize with following formula:
Wherein each R is selected from R2、R
C, and
Wherein:
-each R2Be independently selected from H and C1-C
4Alkyl;
-each RCFor
Wherein each Z is independently selected from M, R2、R
CAnd RH；
-each RHBe independently selected from C5-C
20Alkyl, C5-C
7Cycloalkyl, C7-C
20Alkylaryl, C7-C
20The alkyl of aryl alkyl, replacement, hydroxy alkyl, C1-C
20Alkoxyl-2-hydroxy alkyl, C7-C
20Alkyl-aryloxy-2-hydroxy alkyl, (R4)
2N-alkyl, (R4)
2N-2-hydroxy alkyl, (R4)
3N-alkyl, (R4)
3N-2-hydroxy alkyl, C6-C
12Aryloxy group-2-hydroxy alkyl,
With
-each R4Be independently selected from H, C1-C
20Alkyl, C5-C
7Cycloalkyl, C7-C
20Alkylaryl, C7-C
20Aryl alkyl, aminoalkyl, alkyl amino alkyl, dialkyl aminoalkyl, piperidinoalkyl, morpholino alkyl, cycloalkyl amino alkyl and hydroxy alkyl;
-each R5Be independently selected from H, C1-C
20Alkyl, C5-C
7Cycloalkyl, C7-C
20Alkylaryl, C7-C
20The alkyl of aryl alkyl, replacement, hydroxy alkyl, (R4)
2N-alkyl and (R4)
3The N-alkyl;
Wherein:
M is selected from Na, K, 1/2Ca and 1/2Mg for suitable cation;
Each x is 0 to about 5;
Each y is about 1 to about 5; And
Precondition is:
-radicals RHSubstitution value between about 0.0001 and 0.1, more preferably between about 0.0005 and 0.05, most preferably between about 0.0008 and 0.01;
-wherein Z is the radicals R of H or MCSubstitution value between about 0.2 and 2.0, more preferably between about 0.3 and 1.0, most preferably between about 0.4 and 0.7;
If-any RHWith positive charge, it comes balance by suitable anion; And
Two R of-same nitrogen-atoms4Can form together the ring structure that is selected from piperidines and morpholine.
Radicals RH" substitution value ", sometimes be also referred to as " DSRH", refer to the substituted radicals R of each anhydrous grape sugar unitHThe molal quantity of component, wherein the anhydrous grape sugar unit is the hexatomic ring shown in the repetitive of said structure formula.
Radicals R
C" substitution value ", be also referred to as " DS sometimes
RC", be meant the substituted radicals R of each anhydrous grape sugar unit
CThe molal quantity of component, Z is H or M in this group, wherein the anhydrous grape sugar unit is the hexatomic ring shown in the repetitive of said structure formula.Requiring Z is that H or M are essential, makes the polymer solubilized of gained with the carboxymethyl group of guaranteeing to have sufficient amount.Should be clear, except the wherein Z of requirement is the R of H or M
COutside the component, can also have and other R preferably
CComponent exists, and wherein Z is the group of non-H or M.
Cellulosic based polymer that other is suitable and/or oligomer substance description are in WO 97/31950 that is published on September 4th, 1997 and the WO98/56825 that is published on December 17th, 1998.
The preparation of material will further describe in the following embodiments as described in the present invention.
B)
Textile mill applications
The cellulosic based polymer of above-mentioned definition or oligomer material can be used as dyeing, the arrangement of dyeing post processing, softening agent, improve hand feel finishing, durable press finished, decontamination arrangement, antibiotic finish and even mechanical finishing etc. in additive.These materials also can itself use separately or use together with other weaving additive, and other additive comprises but is not limited to wetting agent, chelating agent, pH controlling agent, softening agent, detergent, waterproofing agent, dye-fixing agent, durable press finished agent, antiseptic etc.For textiles treatment, cellulosic based polymer or oligomer material are generally used in dyeing and/or the arrangement process.
Can and dye method to the greatest extent or these materials are applied on yarn/fabric/textile/clothes by rolling as illustrated in fig. 1 and 2-baking method respectively by the spray application (not shown).These materials can be applied in textiles, knitted fabric, bondedfibre fabric or their combination.Roll-the baking method is usually used in the dyeing and the arrangement of textiles.Although they can stand the hot setting process safely, there is no need these materials to be fixed on the fabric by solidifying.The embodiment of hot setting method includes but not limited to arrangement, as durable press finished and antibiotic finish.
Although some knitted fabrics can be with rolling-processing of baking method, the method for dying is generally used for handling knitted fabric to the greatest extent in textile mill applications.
In textile mill applications, provide the required cellulosic based fabric treating amount of substance of the present invention of best appearance of fabrics beneficial effect to depend on many factors, for example yarn/fabric construction, textile treatment type and Weaving device type.Based on the weight of fabric, need about 0.005% to 10% appearance of fabrics and the integrality of cellulosic based material to give fabric the best.Preferred amount is based on about 0.01% to 3% of the fabric weight of using the cellulosic based mass treatment.These beneficial effects can comprise and improve overall appearance, reduce balling-up/fluff, prevent to fade, improve ABRASION RESISTANCE and/or improve flexibility.
Referring to Fig. 1, for rolling-the baking method, the concentration of cellulosic based material should be determined by wet the absorption in the leach mill solution 20.For example, if wet the absorption is controlled at based on 100% of fabric 10 weight, and the cellulosic based material of needs 1% then needs 1% the aqueous solution so that send outward appearance and integrality beneficial effect for fabric 10 in pad bath 40.
Referring to Fig. 2, for dying method to the greatest extent, the cellulosic based amount of substance that joins in the most dye bath 60 is determined by the weight of fabric 10.Non-limiting example is if need 1% cellulosic based material addition in the fabric 10, can realize like this: for example adding 1kg cellulosic based mass treatment 100kg fabric 10 in the dye bath 60 to the greatest extent.
The pH scope of fabric treating is preferably about 3 to 12, more preferably about 4 to 10.
Embodiment
The following example illustrates the compositions and methods of the invention, but not necessarily is intended to limit or define scope of the present invention.
Example I
Be used to roll-dry by the fire the composition of matter of using that contains fabric softener
| Material | Composition |
| Cellulose-based polymer | ????0.5％ |
| Wetting agent | ????0.1％ |
| Fabric softener | ????2.0％ |
| Water | ????97.4％ |
| PH value | ????6-7 |
Example II
Be used for durable press and roll-dry by the fire the composition of matter of using
| Material | Composition |
| Cellulose-based polymer | ????10g/l |
| Crosslinking agent | ????60g/l |
| Catalyst | ????15g/l |
| Fabric softener | ????20g/l |
| Wetting agent | ????3g/l |
| Chelating agent | ????5g/l |
| PH value | ????4-5 |
EXAMPLE III
Dye the composition of matter of application after being used to dye to the greatest extent
| Material | Composition |
| Knitted fabric | ????100kg |
| Cellulose-based polymer | ????1kg |
| PH value | ????7-8 |
EXAMPLE IV
Synthesizing of modification CMC material
Cellulosic carboxylation is the known technology of those skilled in the art with preparation CMC.In order to prepare modification CMC material of the present invention, in the CMC preparation process, add substituted material or multiple material.Provide this implementation of processes example below.This identical technology is passed through with interested substituting group material or multiple material, and for example the chloro cetane replaces chlorohexane to be used for other substituting group material as herein described.In order to obtain required substitution value, the amount of substance that should join in the CMC preparation process can easily be calculated according to following examples by those skilled in the art.
Synthesizing of CMC hexyl ether
This embodiment for example understands the preparation of the carboxymethyl cellulose of carboxymethyl hydrophobically modified, and has represented the preparation of the plain ether derivant of all fibres among the present invention.
With cellulose (20g), NaOH (10g), water (30g), and ethanol (150g) adds in the glass reactor of 500ml.The alkali cellulose of gained was stirred 45 minutes in 25 ℃.Add chloroacetic acid (15g) and chlorohexane (1g) then, with temperature slowly rise to 95 ℃ and remain on 95 ℃ 150 minutes.Reaction is cooled to 70 ℃, is cooled to 25 ℃ then.Nitric acid/the acetate that adds q.s neutralizes, to obtain the slurries of pH between 8 and 9.Dope filtration is obtained the CMC hexyl ether.
Table D
Concrete polymer parameter
| ID polymer modification type **Chemical classes |
| *A hexyl CMC hexyl ether joins the chlorohexane in the CMC preparation process |
| *B decyl CMC decyl ethers joins the chlorodecane in the CMC preparation process |
| C C12-C13 alkoxyl-2 C12-C13 alkoxyl-the join hydroxypropyl CMC 2 hydroxypropyl ether C12-C13 alkyl glycidyl ethers in the CMC preparation process |
| *D cetyl CMC cetyl ether joins the chlorine hexadecane in the CMC preparation process |
| *E CMC 3-trimethyl amido-2-3-trimethyl amido-2-joins the chloride salt 2 of the chloride salt hydroxypropyl ether of the hydroxypropyl ether in the CMC preparation process, 3-epoxypropyl trimethylammonium chloride ammonium |
| *[(C (O)-CH (C16H33)-join C (O) CH2 (C16H33) in the CMC preparation process] ester of F CMC or the cetyl ketene dimers 1 of CMC, 3-dioxo-2-cetyl octadecyl ester |
The CMC=carboxymethyl cellulose
*Produce by Noviant Specialty Chemicals
*The DS of these materials
RHAbout 0.001 to about 0.1 scope
Although illustrated among the present invention and described many specific embodiments, it will be apparent to those skilled in the art that and under the situation that does not deviate from the spirit and scope of the present invention, can make many other variation and modifications.So all such changes and modifications that in appending claims, are included in the scope of the present invention consciously.
Claims (10)
1. textile mills' treatment compositions, described textile mills treatment compositions comprises:
A) cellulosic based polymer or oligomer, it has following general formula:
Wherein each R is selected from R
2, R
CAnd
Wherein:
-each R
2Be independently selected from H and C
1-C
4Alkyl;
-each R
CFor
Wherein each Z is independently selected from M, R
2, R
CAnd R
D
-each R
HBe independently selected from C
5-C
20Alkyl, C
5-C
7Cycloalkyl, C
7-C
20Alkylaryl, C
7-C
20The alkyl of aryl alkyl, replacement, hydroxy alkyl, C
1-C
20Alkoxyl-2-hydroxy alkyl, C
7-C
20Alkyl-aryloxy-2-hydroxy alkyl, (R
4)
2N-alkyl, (R
4)
2N-2-hydroxy alkyl, (R
4)
3N-alkyl, (R
4)
3N-2-hydroxy alkyl, C
6-C
12Aryloxy group-2-hydroxy alkyl,
-each R
4Be independently selected from H, C
1-C
20Alkyl, C
5-C
7Cycloalkyl, C
7-C
20Alkylaryl, C
7-C
20Aryl alkyl, aminoalkyl, alkyl amino alkyl, dialkyl aminoalkyl, piperidino alkyl, morpholino alkyl, cycloalkyl amino alkyl and hydroxy alkyl;
-each R
5Be independently selected from H, C
1-C
20Alkyl, C
5-C
7Cycloalkyl, C
7-C
20Alkylaryl, C
7-C
20The alkyl of aryl alkyl, replacement, hydroxy alkyl, (R
4)
2N-alkyl and (R
4)
3The N-alkyl;
Wherein:
M is suitable CATION, and it is selected from Na, K, 1/2Ca and 1/2Mg;
Each x is 0 to about 5;
Each y is about 1 to about 5; And
Precondition is:
-radicals R
HSubstitution value between about 0.0001 and 0.1, more preferably between about 0.0005 and 0.05, and most preferably between about 0.0008 and 0.01;
-wherein Z is the radicals R of H or M
CSubstitution value between about 0.2 and 2.0, more preferably between about 0.3 and 1.0, and most preferably between about 0.4 and 0.7;
If-any R
HHave positive charge, it comes balance by suitable anion; And
Two R the on-same nitrogen-atoms
4Can form the ring structure that is selected from piperidines and morpholine together.
2. textile mills' treatment compositions of claim 1, wherein said treatment compositions be added to pad bath, to the greatest extent in dye bath or the spray applicator, preferably wherein said pad bath, the pH scope of dye bath or described spray application is about 3 to 12 to the greatest extent.
3. textile mills' treatment compositions of claim 2, wherein said composition is applied in textiles, knitted fabric or their combination.
4. fabric or textiles, described fabric or textiles comprise about by weight 0.005% to 10% cellulosic based polymer or oligomer, and it has following general formula:
Wherein each R is selected from R
2, R
CAnd
Wherein:
-each R
2Be independently selected from H and C
1-C
4Alkyl;
-each R
CFor
Wherein each Z is independently selected from M, R
2, R
CAnd R
H
-each R
HBe independently selected from C
5-C
20Alkyl, C
5-C
7Cycloalkyl, C
7-C
20Alkylaryl, C
7-C
20The alkyl of aryl alkyl, replacement, hydroxy alkyl, C
1-C
20Alkoxyl-2-hydroxy alkyl, C
7-C
20Alkyl-aryloxy-2-hydroxy alkyl, (R
4)
2N-alkyl, (R
4)
2N-2-hydroxy alkyl, (R
4)
3N-alkyl, (R
4)
3N-2-hydroxy alkyl, C
6-C
12Aryloxy group-2-hydroxy alkyl,
-each R
4Be independently selected from H, C
1-C
20Alkyl, C
5-C
7Cycloalkyl, C
7-C
20Alkylaryl, C
7-C
20Aryl alkyl, aminoalkyl, alkyl amino alkyl, dialkyl aminoalkyl, piperidino alkyl, morpholino alkyl, cycloalkyl amino alkyl and hydroxy alkyl;
-each R
5Be independently selected from H, C
1-C
20Alkyl, C
5-C
7Cycloalkyl, C
7-C
20Alkylaryl, C
7-C
20The alkyl of aryl alkyl, replacement, hydroxy alkyl, (R
4)
2N-alkyl and (R
4)
3The N-alkyl;
Wherein:
M is suitable CATION, and it is selected from Na, K, 1/2Ca and 1/2Mg;
Each x is 0 to about 5;
Each y is about 1 to about 5; And
Precondition is:
-radicals R
HSubstitution value between about 0.0001 to 0.1, more preferably between about 0.0005 and 0.05, and most preferably between about 0.0008 and 0.01;
-wherein Z is the radicals R of H or M
CSubstitution value between about 0.2 and 2.0, more preferably between about 0.3 and 1.0, and most preferably between about 0.4 and 0.7;
If-any R
HHave positive charge, it comes balance by suitable anion; And
Two R the on-same nitrogen-atoms
4Can form the ring structure that is selected from piperidines and morpholine together.
5. handle the method for fabric or textiles, said method comprising the steps of:
A) provide treatment compositions, wherein said treatment compositions is made of cellulosic based polymer or oligomer, and the mean molecule quantity of wherein said cellulosic based polymer or oligomer is about 5,000 to about 2,000,000, and wherein said cellulosic based polymer or oligomer have following general formula:
Wherein each R is selected from R
2, R
CAnd
Wherein:
-each R
2Be independently selected from H and C
1-C
4Alkyl;
-each R
CFor
Wherein each Z is independently selected from M, R
2, R
CAnd R
H
-each R
HBe independently selected from C
5-C
20Alkyl, C
5-C
7Cycloalkyl, C
7-C
20Alkylaryl, C
7-C
20The alkyl of aryl alkyl, replacement, hydroxy alkyl, C
1-C
20Alkoxyl-2-hydroxy alkyl, C
7-C
20Alkyl-aryloxy-2-hydroxy alkyl, (R
4)
2N-alkyl, (R
4)
2N-2-hydroxy alkyl, (R
4)
3N-alkyl, (R
4)
3N-2-hydroxy alkyl, C
6-C
12Aryloxy group-2-hydroxy alkyl,
-each R
4Be independently selected from H, C
1-C
20Alkyl, C
5-C
7Cycloalkyl, C
7-C
20Alkylaryl, C
7-C
20Aryl alkyl, aminoalkyl, alkyl amino alkyl, dialkyl aminoalkyl, piperidino alkyl, morpholino alkyl, cycloalkyl amino alkyl and hydroxy alkyl;
-each R
5Be independently selected from H, C
1-C
20Alkyl, C
5-C
7Cycloalkyl, C
7-C
20Alkylaryl, C
7-C
20The alkyl of aryl alkyl, replacement, hydroxy alkyl, (R
4)
2N-alkyl and (R
4)
3The N-alkyl;
Wherein:
M is suitable CATION, and it is selected from Na, K, 1/2Ca and 1/2Mg;
Each x is 0 to about 5;
Each y is about 1 to about 5; And
Precondition is:
-radicals R
HSubstitution value between about 0.0001 and 0.1, more preferably between about 0.0005 and 0.05, and most preferably between about 0.0008 and 0.01;
-wherein Z is the radicals R of H or M
CSubstitution value between about 0.2 and 2.0, more preferably between about 0.3 and 1.0, and most preferably between about 0.4 and 0.7;
If-any R
HHave positive charge, it comes balance by suitable anion; And
Two R the on-same nitrogen-atoms
4Can form the ring structure that is selected from piperidines and morpholine together; With
B) with about amount of 0.005% to 10% by weight described cellulosic based polymer or oligomer are applied on fabric or the textiles, wherein said fabric or textiles are textiles, knitted fabric, bondedfibre fabric or their combination.
6. handle the method for fabric or textiles, said method comprising the steps of:
A) provide treatment compositions, wherein said treatment compositions is made of cellulosic based polymer or oligomer, and the mean molecule quantity of wherein said cellulosic based polymer or oligomer is about 5,000 to about 2,000,000, and wherein said cellulosic based polymer or oligomer have following general formula:
Wherein each R is selected from R
2, R
CAnd
Wherein:
-each R
2Be independently selected from H and C
1-C
4Alkyl;
-each R
CFor
Wherein each Z is independently selected from M, R
2, R
CAnd R
H
-each R
HBe independently selected from C
5-C
20Alkyl, C
5-C
7Cycloalkyl, C
7-C
20Alkylaryl, C
7-C
20The alkyl of aryl alkyl, replacement, hydroxy alkyl, C
1-C
20Alkoxyl-2-hydroxy alkyl, C
7-C
20Alkyl-aryloxy-2-hydroxy alkyl, (R
4)
2N-alkyl, (R
4)
2N-2-hydroxy alkyl, (R
4)
3N-alkyl, (R
4)
3N-2-hydroxy alkyl, C
6-C
12Aryloxy group-2-hydroxy alkyl,
With
-each R
4Be independently selected from H, C
1-C
20Alkyl, C
5-C
7Cycloalkyl, C
7-C
20Alkylaryl, C
7-C
20Aryl alkyl, aminoalkyl, alkyl amino alkyl, dialkyl aminoalkyl, piperidino alkyl, morpholino alkyl, cycloalkyl amino alkyl and hydroxy alkyl;
-each R
5Be independently selected from H, C
1-C
20Alkyl, C
5-C
7Cycloalkyl, C
7-C
20Alkylaryl, C
7-C
20The alkyl of aryl alkyl, replacement, hydroxy alkyl, (R
4)
2N-alkyl and (R
4)
3The N-alkyl;
Wherein:
M is suitable CATION, and it is selected from Na, K, 1/2Ca and 1/2Mg;
Each x is 0 to about 5;
Each y is about 1 to about 5; And
Precondition is:
-radicals R
HSubstitution value between about 0.0001 and 0.1, more preferably between about 0.0005 and 0.05, and most preferably between about 0.0008 and 0.01;
-wherein Z is the radicals R of H or M
CSubstitution value between about 0.2 and 2.0, more preferably between about 0.3 and 1.0, and most preferably between about 0.4 and 0.7;
If-any R
HHave positive charge, it comes balance by suitable anion; And
-two R on same nitrogen-atoms
4Can form the ring structure that is selected from piperidines and morpholine together; With
B) described cellulosic based polymer or oligomer are joined in pad bath or the most dye bath, preferably wherein said pad bath or the described pH scope of dye bath to the greatest extent are about 3 to 12; With
C) fabric or textiles are joined in described pad bath or the described dye bath to the greatest extent, thus with about amount of 0.005% to 10% by weight with described cellulosic based polymer or oligomer is applied on described fabric or the textiles and preferably wherein said fabric or textiles are textiles, knitted fabric, bondedfibre fabric or their combination.
7. the process of claim 1 wherein that the mean molecule quantity of described cellulosic based polymer or oligomer is about 5,000 to about 2,000,000.
8. textile mills' treatment compositions of claim 1, wherein said treatment compositions also comprises the weaving additive, and preferably wherein said weaving additive is softening agent, detergent, water repellent agent, dye-fixing agent, durable press finished agent, antiseptic or their combination.
9. the method for claim 6, described method comprises also the textiles additive is joined in described pad bath or the described to the greatest extent dye bath that preferably wherein said weaving additive is softening agent, detergent, water repellent agent, dye-fixing agent, durable press finished agent, antiseptic or their combination.
10. be used to handle the system of textiles, described system comprises:
A) cellulosic based polymer or oligomer, it has following general formula:
Wherein each R is selected from R
2, R
CAnd
Wherein:
-each R
2Be independently selected from H and C
1-C
4Alkyl;
-each R
CFor
Wherein each Z is independently selected from M, R
2, R
CAnd R
H
-each R
HBe independently selected from C
5-C
20Alkyl, C
5-C
7Cycloalkyl, C
7-C
20Alkylaryl, C
7-C
20The alkyl of aryl alkyl, replacement, hydroxy alkyl, C
1-C
20Alkoxyl-2-hydroxy alkyl, C
7-C
20Alkyl-aryloxy-2-hydroxy alkyl, (R
4)
2N-alkyl, (R
4)
2N-2-hydroxy alkyl, (R
4)
3N-alkyl, (R
4)
3N-2-hydroxy alkyl, C
6-C
12Aryloxy group-2-hydroxy alkyl,
With
-each R
4Be independently selected from H, C
1-C
20Alkyl, C
5-C
7Cycloalkyl, C
7-C
20Alkylaryl, C
7-C
20Aryl alkyl, aminoalkyl, alkyl amino alkyl, dialkyl aminoalkyl, piperidino alkyl, morpholino alkyl, cycloalkyl amino alkyl and hydroxy alkyl;
-each R
5Be independently selected from H, C
1-C
20Alkyl, C
5-C
7Cycloalkyl, C
7-C
20Alkylaryl, C
7-C
20The alkyl of aryl alkyl, replacement, hydroxy alkyl, (R
4)
2N-alkyl and (R
4)
3The N-alkyl;
Wherein:
M is suitable CATION, and it is selected from Na, K, 1/2Ca and 1/2Mg;
Each x is 0 to about 5;
Each y is about 1 to about 5; And
Precondition is:
-radicals R
HSubstitution value between about 0.0001 and 0.1, more preferably between about 0.0005 and 0.05, and most preferably between about 0.0008 and 0.01;
-wherein Z is the radicals R of H or M
CSubstitution value between about 0.2 and 2.0, more preferably between about 0.3 and 1.0, and most preferably between about 0.4 and 0.7;
If-any R
HHave positive charge, it comes balance by suitable anion; With
Two R the on-same nitrogen-atoms
4Can form the ring structure that is selected from piperidines and morpholine together; With
B) weaving additive, preferably wherein said weaving additive is softening agent, detergent, water repellent agent, dye-fixing agent, durable press finished agent, antiseptic or their combination.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US37287702P | 2002-04-16 | 2002-04-16 | |
| US60/372,877 | 2002-04-16 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1646760A true CN1646760A (en) | 2005-07-27 |
Family
ID=29250924
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA038081326A Pending CN1646760A (en) | 2002-04-16 | 2003-04-16 | Textile mill applications of cellulosic based polymers to provide appearance and integrity benefits to fabrics during laundering and in-wear |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US20030226212A1 (en) |
| EP (1) | EP1495181A1 (en) |
| JP (1) | JP2005520951A (en) |
| CN (1) | CN1646760A (en) |
| AU (1) | AU2003226390A1 (en) |
| BR (1) | BR0309312A (en) |
| CA (1) | CA2480283A1 (en) |
| WO (1) | WO2003089711A1 (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110291181A (en) * | 2017-02-13 | 2019-09-27 | 荷兰联合利华有限公司 | Clothes clothes washing system |
| US11053463B2 (en) | 2017-02-13 | 2021-07-06 | Conopco, Inc. | Method of delivering a laundry composition |
| US11180721B2 (en) | 2017-02-13 | 2021-11-23 | Conopco, Inc. | Ancillary laundry composition |
| US11208617B2 (en) | 2017-02-13 | 2021-12-28 | Conopco, Inc. | Laundry composition additive |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060248657A1 (en) * | 2004-05-05 | 2006-11-09 | Jiping Wang | Textile benefit compositions |
| US20050246841A1 (en) * | 2004-05-05 | 2005-11-10 | The Procter & Gamble Company | Textile benefit compositions |
| CA2634099A1 (en) * | 2006-01-19 | 2007-07-26 | The Procter & Gamble Company | Fabric treatment composition providing stain repellant coating |
| MX2009005389A (en) * | 2006-11-22 | 2009-06-02 | Procter & Gamble | Benefit compositions and methods. |
| US20090014034A1 (en) * | 2006-11-22 | 2009-01-15 | The Procter & Gamble Company | Benefit compositions and formaldehyde scavengers for same |
| EP2553077B1 (en) * | 2010-03-31 | 2015-10-14 | Henkel AG & Co. KGaA | Washing composition for sensitive textiles |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3950276A (en) * | 1971-09-01 | 1976-04-13 | Colgate-Palmolive Company | Sulfonate detergent compositions |
| US4199464A (en) * | 1977-12-23 | 1980-04-22 | The Procter & Gamble Company | Laundry detergent substrate articles |
| US4205063A (en) * | 1979-04-12 | 1980-05-27 | Johnson Products Co., Inc. | Low irritant conditioning shampoo composition |
| US4329237A (en) * | 1979-11-21 | 1982-05-11 | Colgate-Palmolive Company | Detergent softener compositions |
| GB8519047D0 (en) * | 1985-07-29 | 1985-09-04 | Unilever Plc | Detergent composition |
| US5308513A (en) * | 1990-07-20 | 1994-05-03 | Colgate-Palmolive Company | Wash cycle or rinse cycle fabric conditioning compositions |
| EP0576598A1 (en) * | 1991-03-19 | 1994-01-05 | The Procter & Gamble Company | Hair care compositions having styling/conditioning agent and plasticizer |
| US5837666A (en) * | 1994-06-30 | 1998-11-17 | The Procter & Gamble Company | Detergent compositions comprising methyl cellulose ether |
| GB2297978A (en) * | 1995-02-15 | 1996-08-21 | Procter & Gamble | Detergent compositions containing amylase |
| CN1213137C (en) * | 1996-12-26 | 2005-08-03 | 普罗格特-甘布尔公司 | Laundry detergent compsns. with cellulosic polymers available for appearance and integrity of washing fabric |
| US6511928B2 (en) * | 1998-09-30 | 2003-01-28 | The Procter & Gamble Company | Rayon fabric with substantial shrink-resistant properties |
| US5885303A (en) * | 1997-05-13 | 1999-03-23 | American Laundry Machinery Incorporated | Durable press/wrinkle-free process |
| US6375685B2 (en) * | 1997-05-13 | 2002-04-23 | The Procter & Gamble Company | Textile finishing process |
| EP1015541B1 (en) * | 1997-09-15 | 2012-05-23 | The Procter & Gamble Company | Laundry detergent compositions with linear amine based polymers to provide appearance and integrity benefits to fabrics laundered therewith |
| US6384011B1 (en) * | 1997-09-15 | 2002-05-07 | The Procter & Gamble Company | Laundry detergent compositions with cellulosic based polymers to provide appearance and integrity benefits to fabrics laundered therewith |
| JP2001516772A (en) * | 1997-09-15 | 2001-10-02 | ザ、プロクター、エンド、ギャンブル、カンパニー | Laundry detergent composition having a polymer based on cellulosic material for providing appearance and integrity benefits to a fabric washed therewith |
| JP2001516797A (en) * | 1997-09-15 | 2001-10-02 | ザ、プロクター、エンド、ギャンブル、カンパニー | Laundry detergent composition having an anionically modified cyclic amine-based polymer |
| BR9914422A (en) * | 1998-10-13 | 2001-06-26 | Procter & Gamble | Detergent compositions or components |
-
2003
- 2003-04-14 US US10/413,632 patent/US20030226212A1/en not_active Abandoned
- 2003-04-16 AU AU2003226390A patent/AU2003226390A1/en not_active Abandoned
- 2003-04-16 WO PCT/US2003/011529 patent/WO2003089711A1/en not_active Application Discontinuation
- 2003-04-16 JP JP2003586415A patent/JP2005520951A/en not_active Withdrawn
- 2003-04-16 EP EP03746987A patent/EP1495181A1/en not_active Withdrawn
- 2003-04-16 BR BR0309312-3A patent/BR0309312A/en not_active IP Right Cessation
- 2003-04-16 CN CNA038081326A patent/CN1646760A/en active Pending
- 2003-04-16 CA CA002480283A patent/CA2480283A1/en not_active Abandoned
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110291181A (en) * | 2017-02-13 | 2019-09-27 | 荷兰联合利华有限公司 | Clothes clothes washing system |
| US11053463B2 (en) | 2017-02-13 | 2021-07-06 | Conopco, Inc. | Method of delivering a laundry composition |
| US11180721B2 (en) | 2017-02-13 | 2021-11-23 | Conopco, Inc. | Ancillary laundry composition |
| US11208617B2 (en) | 2017-02-13 | 2021-12-28 | Conopco, Inc. | Laundry composition additive |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2003089711A1 (en) | 2003-10-30 |
| CA2480283A1 (en) | 2003-10-30 |
| AU2003226390A1 (en) | 2003-11-03 |
| US20030226212A1 (en) | 2003-12-11 |
| EP1495181A1 (en) | 2005-01-12 |
| BR0309312A (en) | 2005-02-15 |
| JP2005520951A (en) | 2005-07-14 |
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