JP2561752B2 - Detergent composition - Google Patents

Description

Detailed Description of the Invention

[0001] relates: The present invention relates to a fiber product for the detergent composition. INDUSTRIAL APPLICABILITY The present invention makes it possible to wash wool, animal hair, textile products such as silk, fur products and the like, which have been difficult to wash with water because of shrinkage, in ordinary households with almost no shrinkage. The present invention relates to a detergent composition for textile products.

[0002] Conventionally, as a detergent for water washing of textiles such as wool, a detergent for clothes mainly containing a nonionic surfactant such as polyoxyethylene alkyl ether has been the mainstream, but in the warm water. The effect of preventing shrinkage is insufficient even if the washing with water is carried out, so that there is a persistent need for a detergent for water washing which further improves the effect of preventing shrinkage.

At present, for wool and animal hair products, a means for preventing the material from shrinking has been provided. Wool, for example
Cuticles (scales) present on the surface of animal hair and other fibers
Oxidation methods such as an enzyme treatment method and a chlorine treatment method are used to remove oxygen. The Dylan FTC method, the DCCA method, and the protein method, which are softened when wet to prevent the fibers from being entangled with each other, have the drawbacks of slipperiness and easy fraying of the fibers. Furthermore, in the resin method, the movement of fibers during washing can be prevented by adhering fibers to each other with a resin,
IWS chlorination / resin method, Chloy resin method, silolane B for coating the scale with resin to prevent entanglement of fibers
Although the AP method, the DC-109 method and the like have been performed, it has been pointed out that the fiber cloth treated with these becomes hard and the texture is deteriorated. In addition, wool, animal wool, and knitted fabrics that once contracted could not be restored to their original dimensions.

Means for Solving the Problems: An object of the present invention is to provide a detergent for textile products which effectively prevents shrinkage and rather improves the texture without deteriorating the texture when washing textile products such as wool with water. In offer.

According to the present invention, the component (A): a polyalkylene oxide polyol having 2 to 6 functionalities, the component (B): a divalent to tetravalent metal salt, the component (C): a. Aromatic or aliphatic isocyanate end-capped with a 2 to 6 functional polyalkylene oxide polyol and / or b. A compound having an epoxy group or an alkoxymethyl group and / or c. It essentially consists of an aromatic compound substituted with an amino group, a halogen or a sulfone group, and the ratio of each component is (A) component: 55-
99.4% by weight, (B) component: 0.3 to 30% by weight and (C) component: 0.3 to 15% by weight [however, the total of (A) component + (B) component + (C) component Is 100% by weight], the anionic surfactant and / or nonionic surfactant and / or amphoteric surfactant (hereinafter also simply referred to as "surfactant") 100 There is provided a solid or liquid detergent composition for textiles, which is contained in an amount of 500 to 5 parts by weight.

In a preferred embodiment of the detergent composition of the present invention, the proportions of the components (A), (B) and (C) in the shrink-proof component are the components (A), (B) and (C). When the total of the above is 100% by weight, the component (A) is 65 to 9
5% by weight, preferably 75 to 90% by weight, component (B) is 3 to 20% by weight, preferably 2 to 15% by weight, and component (C) is 2 to 15% by weight, preferably 3 to 10% by weight.
% By weight.

If the amount of component (A) is too small, less than 55% by weight, the shrink-proofing effect will be poor, and if it exceeds 99.4% by weight, there will be no particular effect, which is not preferable.

If the content of the component (B) is less than 0.3% by weight, it is not preferable because the shrinkage resistance after washing with water decreases.
If it exceeds 30% by weight and is too large, the texture is deteriorated, which is not preferable.

When the content of the component (C) is too small, less than 0.3% by weight, the shrinkage resistance after washing with water is deteriorated, which is not preferable. If the amount exceeds 15% by weight and is too large, the fibrous material such as fiber cloth or fur becomes rigid and the texture is deteriorated, which is not preferable.

In a preferred embodiment of the detergent composition of the present invention, the shrink-proof component is an anionic surfactant and / or
Alternatively, 300 to 10 parts by weight, preferably 200 to 20 parts by weight, and more preferably 150 to 30 parts by weight per 100 parts by weight of the nonionic surfactant and / or the amphoteric surfactant.
It is contained in parts by weight.

If the amount of the shrink-proof component is less than 5 parts by weight, the shrinkage-preventing effect cannot be obtained, which is not preferable.
If the amount exceeds 500 parts by weight, the washing effect will not be obtained, which is not preferable.

The shrink-proof component used in the detergent composition of the present invention is a polyalkylene oxide having 2 to 6 functional groups, preferably 2 to 4 functional groups, and most preferably 2 to 3 functional groups as the component (A). Contains polyol. The molecular weight of such a polyalkylene oxide polyol is preferably 600 to 10,000, more preferably 2,000 to
Examples of the raw material alkylene oxide for such a polyalkylene polyol of 6,000 include ethylene oxide, propylene oxide, 1,2- or 2,3-butylene oxide and the like, and combinations of two or more thereof. You can Further, as the raw material polyol of the polyalkylene polyol, propylene glycol, ethylene glycol, dipropylene glycol, diethylene glycol, glycerin, 1,4-butanediol, 1,6-hexanediol , Glycerin triol, hexane triol, trimethylol propane, C ₈ -C ₂₄ aliphatic triol, pentaerythritol, α-methylene glucoside, tetramethyl methane, sorbitol, xylitol. , Tetraol, C ₉ -C ₂₄ aliphatic unsaturated polyhydric alcohol and the like can be exemplified, and the raw material polyamine is ethylenediamine, γ- (methylamino) propylamine, diethylenetriamine, diaminopropane,
Examples thereof include alkyl-propanediamine, alkylpropylenediamine, hexamethylenediamine, tetramethylenediamine, bishexamethylenetriamine, triethylenetetramine, tetraethylenepentamine, pentaethylenehexamine, mono-, di- or tri-allylamine.

As the polyalkylene oxide polyol as the component (A), polypropylene oxide-trimethylol propane triol, polypropylene oxide-hexane triol triol, polypropylene oxide-glycerin triol, random or block copolymers can be used. Examples thereof include polymerized propylene oxide / ethylene oxide-glycerin triol, random or block copolymerized ethylene oxide / propylene oxide-ethylenediamine tetraol, polypropylene oxide-sorbit hexane triol and the like. These polyalkylene oxide polyols may be used in combination of two or more kinds. The most preferable polyalkylene oxide polyol as the component (A) is a random copolymerized polyethylene oxide / propylene oxide triol (preferably about 70% by weight of ethylene oxide) or polypropylene oxide triol (preferably about propylene oxide). 9
7% by weight).

The shrink-proof component used in the detergent composition of the present invention is a component (B) having a valency of 2 to 4, preferably 3 to.
It contains a tetravalent, most preferably trivalent metal salt. Here, the metal salt refers to a salt of a metal and an inorganic acid or an organic acid. Examples of such metal salts include salts of divalent metals such as zinc salts, calcium salts and magnesium salts, salts of trivalent metals such as aluminum salts, chromium salts, iron salts, lanthanum salts and cerium salts, zirconium salts and silicon salts. Examples thereof include salts of tetravalent metals such as salts. Of these, aluminum salts and zirconium salts are preferable.

Examples of the aluminum salt include aluminum sulfate, aluminum nitrate, aluminum acetate, aluminum fluoride, aluminum chloride and aluminum lactate, and examples of the zirconium salt include zirconium sulfate. Among them, aluminum sulfate is most preferable, and the combination of aluminum sulfate and other metal salt is also preferable.

The shrink-proof component used in the detergent composition of the present invention is a polyalkylene having (C) component 2 to 6 functionality, preferably 2 to 4 functionality, and most preferably 2 to 3 functionality. It can contain an aromatic or aliphatic isocyanate end-capped with oxide polyol. The component (C) is prepared by reacting an aromatic or aliphatic isocyanate with a large excess of a 2 to 6-functional polyalkylene oxide polyol to protect the terminal isocyanate group with the polyol. Can be obtained by As the above-mentioned aromatic or aliphatic isocyanate, tolylene diisocyanate (having a mixing ratio of 2,4- or 2,6-isomers of 80:20), 4,4'-diphenylmethane diamine Isocyanate (including crude, purified and modified), phenylene diisocyanate, naphthalene 1,5-diisocyanate, polymethylene polyphenyl polyisocyanate
, Xylene diisocyanate, tolylene diisocyanate adduct to trimethylol propane, hydrogenated xylylene diisocyanate, dicyclohexylmethane diisocyanate, isophorone diisocyanate, mono- or Examples thereof include poly-hexamethylene diisocyanate. Among them, polymethylene polyphenyl polyisocyanate and polyhexamethylene diisocyanate (including biuret type and isocyanate type)
Is preferred. On the other hand, as the 2- to 6-functional polyalkylene oxide polyol, the 2- to 6-functional polyalkylene oxide polyol described above for the component (A) is used. The shrink-proof component used in the detergent composition of the present invention can contain a compound having an epoxy group or an alkoxymethyl group as the component (C). Examples of such compounds include polyethylene glycol diepoxide, bisphenol A diglycidyl ether, cross-linking agent C.
R-5L (Dainippon Ink and Chemicals), hexamethoxymethyl melamine, Sanwa Chemical oil-soluble melamine resin and water-soluble melamine resin, methoxymethylurea, etc. can be mentioned. A low temperature cross-linking type water-soluble epoxy resin and a water-soluble alkylated methylol melamine resin are preferably used.

The shrink-proof component used in the detergent composition of the present invention is, as the component (C), an aromatic compound substituted with an amino group, a halogen or a sulfone group, preferably a mono-, di- or tri- or substituted group. Can be included.
Examples of such aromatic compounds include aniline, 2,
4-diaminotoluene, 2,6-diamino, toluene,
p-phenylenediamine, o-phenylenediamine, m
-Phenylenediamine, o-toluylenediamine, m-
Toluylenediamine, p-toluylenediamine, o-chloroaniline, m-chloroaniline, p-chloroaniline, o-dichlorobenzene, trichlorobenzene, monochlorobenzene, o-dibromobenzene, p-aminophenol, m-aminophenol. -O, o-aminophenol-
Examples thereof include rupara-disulfonated benzene and monosulfonated benzene. Among the above aromatic compounds, benzene substituted with an amino group or halogen is preferable, and aniline and p-dichlorobenzene are particularly preferable.

The components (C) -A, (C) -B and (C) -C may each be used in combination of two or more kinds.

Examples of the anionic surfactant used in the detergent composition of the present invention include the following: 1) higher fatty acid alkali metal salt (soap), for example, coconut containing lauric acid as a main component. Alkali metal salts of acids, alkali metal salts of palm fatty acids, alkali metal salts of beef tallow fatty acids containing oleic acid as a main component, such as saturated or unsaturated fatty acids having 8 to 20 carbon atoms.

2) Alkylbenzenesulfonate having an alkyl group having an average carbon number of 10 to 16 3) Having a linear or branched alkyl or alkenyl group having an average carbon number of 10 to 20 and having an average of 0 in one molecule. .5
Alkyl or alkenyl ether sulfate having 8 moles of ethylene oxide added 4) Alkyl or alkenyl sulfate having an alkyl group or alkenyl group having an average carbon number of 10 to 20 5) Average 10 to 20 carbon atoms in one molecule Olefin sulfonate having 6) Alkane sulfonate having an average of 10 to 20 carbon atoms in one molecule 7) Sulfosuccinate sodium salt 8) Ether carboxylate 9) Acyl-N-methyl taurate sulfonate sodium salt 10) Sarcocine sodium salt 11) N-acyl glutamate 12) Glutamate sodium salt 13) Alkyl ether sulphate 14) Alkyl sulphate 15) Alkyl polyglucoside 16) Monoalkyl phosphite 17) Fatty acid alkanolamide 18) Ethanolates of higher alcohols 19) Sulfates of higher alcohols 20) Sodium amylisethionate In addition, the following nonionic surfactants may be used in the detergent composition of the present invention. It is possible: 1) to have a polyoxyethylene alkyl or alkenyl ether having an alkyl group or an alkenyl group having an average carbon number of 10 to 20 and to which 1 to 20 mol of ethylene oxide has been added 2) to have an alkyl group having an average carbon number of 6 to 12 Polyoxyethylene alkylphenyl ether, polyoxypropylene alkyl ether, polyoxyethylene polyoxypropylene alkyl ether, higher fatty acid alkanolamide or ethylene oxide addition thereof to which 1 to 20 mol of ethylene oxide is added Products, sucrose fatty acid ester, alkyl sugar On the other hand, as the amphoteric surfactant used in the detergent composition of the present invention, the following can be exemplified: 1) Alkyl betaine type

[0021]

[Chemical 1] 2) Amidobetaine type

[0022]

[Chemical 2] 3)

[0023]

Embedded image However, R is an alkyl group having 7 to 23 carbon atoms, a hydroxyalkyl group, an aralkyl group or an alkenyl group X is a hydrogen atom, an alkali metal salt, an ammonium ion,
Secondary amide amino acid represented by triethanolammonium ion or salt thereof The above-mentioned anionic surfactant, nonionic surfactant and amphoteric surfactant may be used in combination of two or more and / or mutually. You may use 2 or more types together.

The detergent composition of the present invention enhances the detergency in addition to the anionic surfactant and / or nonionic surfactant and / or amphoteric surfactant and the shrink-proofing component, thus improving workability and marketability. A relatively large amount is added to the auxiliary component which can be added with various auxiliary components for the purpose of improvement. There are builder, extender and the like, and a small amount of additive which is 5% or less and usually 1% or less. These include bactericides, bleaches, borax, buffers, colorants, corrosion inhibitors, enzyme softeners, antistatic agents, glidants, optical brighteners, perfume hydrotropes, brighteners, perfumes, Anti-calcining agent, anti-redeposition agent, starch, antifoaming agent, anti-skin agent,
There are solubilizers, ultraviolet absorbers, antioxidants, viscosity modifiers, preservatives, pH modifiers, etc., which are added as necessary.

As the builder, the following can be exemplified. Synthetic zeolites, phosphates, silicates, and carbonates are typical inorganic materials. Further, there are compounds belonging to the organic chelating agent, which are exemplified below. Synthetic zeolite (particle size 4 μm or less), trisodium phosphate, disodium hydrogen phosphate, tetrasodium pyrophosphate, sodium tripolyphosphate, 3 potassium phosphate, 2 potassium phosphate, 4 potassium pyrophosphate, potassium hexametaphosphate, hexametaphosphoric acid As an organic builder such as sodium, sodium orthosilicate, sodium sesquisilicate, sodium metasilicate and colloidal sodium silicate containing a large amount of SiO ₂ , sodium sulfate, sodium perborate, sodium carbonate, sodium hydrogen carbonate, sodium sesquicarbonate, etc. Is a salt of citric acid, malonic acid, succinic acid, malic acid, diglycolic acid, tartaric acid, etc., and an aminopolyacetate salt such as nitro triacetate salt, ethylenediamine tetraacetate salt, carboxymethyl tartronate salt, carboxymethyl oxalate salt Oligomers of succinate, acrylate and hydroxyacrylate, and poly (meth) acrylate, polymaleate and (meth) acrylic acid-acrylic acid ester copolymer, maleic anhydride-diisobutylene copolymer And a salt of a polymer compound such as a polymer, a maleic anhydride-methyl vinyl ether copolymer, a maleic anhydride- (meth) acrylic acid ester copolymer, and the like, and particularly a soluble organic complex for Ca ⁻ , Mg ^−, etc. Compounds, especially polycarboxylate compounds, are desirable.

Examples of the anti-redeposition agent include carboxymethyl cellulose, hydroxypropyl methyl cellulose, hydroxybutyl methyl cellulose and the like.

Examples of the solubilizing agent include lower alcohol such as ethanol and isopropyl alcohol, benzene sulfonate, lower alkyl benzene sulfonate, polyethylene glycol, polypropylene glycol, polyoxyethylene. Examples thereof include glycol of polyoxypropylene, acetamides, pyridinecarboxylic acid amides, benzoate, urea and pyridinecarboxylic acid amides.

Enzymes include protease and amylase.
Examples thereof include enzymes such as zease, lipase, and cellulase, and enzyme stabilizers such as calcium chloride and hydroxyapatite.

Examples of the fluorescent whitening agent include bistriazinyl derivatives of 4,4-diaminostilbene-2,2'-disulfonic acid, aminocoumarin derivatives, diphenylpyrazoline derivatives, and bisbenzoxazoline derivatives.

As the extender, Glauber's salt etc. can be mentioned.

The detergent compositions of the present invention may be prepared in either concentrated liquid or solid form. A thick liquid form is preferred. In the case of a solid form, it is a powdery or granular preparation.

The detergent composition of the present invention is suitable for washing with water.
It is preferably used in the range of 2 to 8% by weight per laundry.

The detergent composition for textiles of the present invention comprises wool,
Even when textile products such as animal hair and silk and fur products are used for washing water with a washing machine in a general household, shrinkage of these textile products and fur products (the size of the product after washing compared to before washing) (Shrinkage) can be effectively prevented, and if the texture of the product can be improved without deterioration, the excellent effect can be obtained.

The reason why the composition for textile products of the present invention exerts the above-mentioned excellent effects is not necessarily clear, but the electrolyte component in the detergent is ionized in water, and the shrinkproof component in the detergent to the natural fiber is Since it promotes adhesion, it becomes easier to permeate and adhere to the material to be washed. It is presumed that since the shrink-proof component attached to the fiber swollen and expanded in water hinders the shrinkage of the fiber in the drying step and is fixed as it is expanded, an excellent shrink-proof effect is produced. Therefore, it is desirable that the final dehydration step during washing is not completely dehydrated, and that the product is hung and dried in a water-containing state and immediately pulled and stretched for wrinkling.

Hereinafter, the present invention will be described in more detail with reference to Examples. Unless stated otherwise, quantities are by weight.

[0036]

【Example】

Example-1 and Comparative Example-1 [Preparation of Detergent] 2-A to 6-functional polyalkylene oxide polyol (Sanyo Chemicals FA-103, Sanyo Kasei Co., Ltd.) as component (A): 544 gr and (Mitsui Toatsu Chemical) (stock)
PPG-MN-3050): 306 gr mixture 850 gr
The liquid temperature was raised to 80 to 85 ° C. while stirring. Next, 30 g of an aliphatic isocyanurate (Sumitomo Bayer Eretan Co., Ltd., Sumidule N-3500): 30 gr was added to prepare a component (C). Then, 1000 g of a 12% aqueous solution of aluminum sulfate as the component (B) was added and mixed. Then sodium laurylbenzene sulfonate 6 as a surfactant
00gr and polyoxyethylene (p = 7) lauryl ether 200gr and coconut oil fatty acid sodium 100gr are added, and after stirring, pH is adjusted with ammonia water to obtain PH8.
To obtain a detergent solution. [Washing method of textiles and shrinkage rate test method of textiles, etc.] J
The washing operation was performed according to the IS-L-0217-1976-NO. 104 method, and the shrinkage rate test of JIS-L-1042-1986 was performed according to the E method.

Detergency test: The reflectance of the unfabricated original cloth and the contaminated cloth before and after cleaning were measured with a colorimeter (manufactured by Shimadzu Corporation),
The cleaning rate (%) was calculated by the following formula.

[0038]

[Equation 1] In addition, the said main detergent was used for Example-1. In Comparative Example-1, all the test methods were the same as in Example-1, except that 40 ml of liquid detergent manufactured by Kao Corporation was added to 30 l of water.

As a test cloth, a raw cloth made of 100% wool was used as a dirt-contaminated cloth (artificial-contaminated cloth) (* -1).

(* -1) Kanuma Horticulture Red sphere soil at 120 ° C ± 5 ° C
Dry for 3 hours, pulverize, and then 100 mesh (150μ
m) pass, dried at 120 ° C ± 5 ° C for 2 hours, then 1
Disperse 50 gr in 1000 ml of perclane, apply this solution to the whole width cloth, brush it, remove the dispersion solution, and remove excess adhered dirt.

[Washing Method] A standard washing capacity with a centrifugal squeezing device conforming to the JIS-C-9606 (electric washing machine) standard, a standard water amount, and a liquid temperature of 40 ° C.
Of water, and the detergent was added thereto in an amount of 5% by weight per cloth to be washed. The water flow of this washing machine is weakened, and the cloth to be washed is put in to start the operation. After treating for 10 minutes, stop the operation, dehydrate the cloth to be washed with a dehydrator, replace the washing liquid with fresh water at room temperature, rinse for 2 minutes, then stop the operation and wash the cloth to be cleaned. Dehydrate, rinse again for 2 minutes, dehydrate to a water content of about 30%, hang it, stretch wrinkles, etc., and after air-drying, dry iron finish at the proper temperature of the material fiber. Ivy.

[Calculation of Shrinkage Ratio] The average value of the lengths of the three measurement sections in each of the warp yarn direction and the weft yarn direction is calculated, and the shrinkage ratio is calculated by the following formula, and the warp yarn direction and the weft yarn direction are tested respectively. Calculate the average of three pieces (up to one decimal place).

[0043]

[Equation 2] Here, L: Length of measuring section before washing (mm) L ': Length of measuring section after washing (mm)

[0044]

[Table 1]

Examples-2 to Example-20, Comparative Example-2 A composition was prepared by changing the composition ratios of the components (A), (B) and (C) and the kinds of the components, and Example-1. Tested in the same manner as. The washing cloth used in the test and the surfactant were the same as in Example-1. The test results are shown in Table 2.

In Comparative Example-2, the same cleaning cloth as in Comparative Example-1 was used, and the test method was the same as in Comparative Example-1. The test method for the shrinkage ratio was the same as in Example-1.

[0047]

[Table 2]

[0048]

[Table 3]

[0049]

[Table 4]

Examples-21 to Example-30, Comparative Example-3 Further, Example-1 was changed to a gear bazine greige machine with 100% wool.
Table 3 shows the results of a test conducted in the same manner as in. Comparative example-
For No. 3, the test cloth used in Examples-21 to 30 was used. Other test methods were the same as in Example-1.

[0051]

[Table 5]

[0052]

[Table 6]

[Physical Properties of Washed Fiber Cloth] The physical properties of the washed and unwashed fiber cloths of Example-30 are shown in Example-30-1.
Table 4 shows Comparative Example-4.

Test cloth: 100% wool gear bazine greige Test method: It was carried out according to the following.

JIS-L-1096-1990; General woven fabric test method 6
-12-1A JIS-L-1076-1985; Piling test method for woven fabrics and knits (A) method x 10 hours JIS-L-1042-1986; Shrinkage test method for woven fabrics Bending test; KES-FB2 pure bending tester Use SEN5 × 5, sample size (vertical × horizontal) 20cm × 20cm compression test; use KES-FB3 compression tester,
SEN5 × 5 Pressing plate descending speed 1mm / 50sec Pressing plate area 2cm ² (circular) Maximum deformation amount 5mm

[0056]

[Table 7]

[0057]

[Table 8]

[0058]

[Table 9]

(Note) In accordance with the [washing method] of Example-1, the treatment time in the detergent diluent was as follows. In the washing of Example 31- (1) and Example 31- (2), the washing was performed in an electric washing machine with a weak water flow for 3 minutes, and the washing was stopped for 12 minutes. This was repeated for 15 minutes, 30 minutes, and 60 minutes for washing. The rinse was performed by rinsing for 2 minutes in the same manner as in Example 1 and dehydration. This was repeated twice.

In addition, only the first washing process is carried out in Example-1.
I used the detergent. For the second and subsequent washings, a general-purpose synthetic detergent for clothing [a liquid detergent manufactured by Kao Corporation] was used. (Note) In Comparative Example-5- (1) and Comparative Example-5- (2), a general-purpose synthetic detergent for clothing [a liquid detergent manufactured by Kao Corporation] was added in the same manner as in Comparative Example-1. -(1), Example-3
All were tested in the same manner as 1- (2). The treated fabrics are Example 31- (1), Comparative Example-5- (1) and Example 31-.
The same material was used in (2) and Comparative Example-5- (2).

Example-39-1 to Example-39-5, Comparative example-11-1, Comparative example-11-1, Surfactant compounding ratio and effect

[0062]

[Table 10]

(Note) The components (A), (B), (C) and the surfactant were the same as in Example-1. Further, the component composition ratios of the component (A), the component (B) and the component (C) were also tested in the same manner as in Example-1 except that only the compounding ratio of the surfactant was changed. However, as the surfactant of Example-39-3, powder soap for clothing manufactured by Lion Corporation was used. As the surfactant of Comparative Example-11-2, liquid detergent of Kao Corporation: synthetic detergent for clothing was used.

The washing effect and the shrink-proofing effect were measured in Example-
Tested as in 1.

As the test cloth, a gear bagin grounding machine made of 100% wool was used as the same artificially contaminated cloth as in Example-1. (Note) Negative (-) of the shrinkage prevention effect indicates elongation.

Example-32 to Example-37, Comparative Example-6
-Comparative example-10 [Effect when changing the kind of test cloth] It tested by the method similar to Example-1. Comparative Examples 6 to 10 were tested in the same manner as Comparative Example-1.

The test cloths and the detergents used for cleaning are shown in Table 5.

[0068]

[Table 11]

Examples 38-1 to 18-18 (Washing test of knitted fabrics, sewn products, furs) Wool such as a sweater, cardigan, subbon, muffler, animal hair products (knitted) and o Wool places and woes such as bar coat, suit top and bottom (male) and skirt (female)
Ru, cotton, hemp, synthetic fiber and other blended products, silk ties, mutton (fur rugs), and feather products were washed with water. As a result, there was no shrinkage, and cleaning could be performed more beautifully than dry cleaning. In addition, it had a good texture, and it was found that there was even a slight elongation even if it contracted, and sufficient dimensional stability was obtained even by washing with water. In particular, the coarser the one that was shrunk by wearing, the more it stretched and the original size was restored. Some of the products showed some discoloration, but none of them were significantly inferior. If the dyeing technology for washing with water is established, the use of this detergent will be expanded.

The test results are shown in Table 6. Example-38-
1 to 18 Symbols a: Length b: Upper width (back, chest, abdomen, etc.) c: Lower width (hem, etc.) d: Sleeve length or thickness

[0071]

[Table 12]

[0072]

[Table 13]

Continuation of the front page (51) Int.Cl. ⁶ Identification code Office reference number FI technical display area C11D 3:20 3:26 3:34) (C11D 10/02 1:02 1:66 1:88 3:60 (72) Inventor Ken Tahara 360-1-519 Oeda, Kasukabe City, Saitama Prefecture (72) Inventor Yoshio Fukuda 70 Asahidai Negishi, Naka-ku, Yokohama City, Kanagawa Prefecture

Claims (10)

(57) [Claims] 1. Component (A): polyalkylene oxide polyol having 2 to 6 functionalities, component (B): divalent to tetravalent metal salt (C) component: a. Aromatic or aliphatic isocyanate end-capped with a 2 to 6 functional polyalkylene oxide polyol and / or b. A compound having an epoxy group or an alkoxymethyl group and / or c. It essentially consists of an aromatic compound substituted with an amino group, a halogen or a sulfone group, and the ratio of each component is (A) component: 55-
99.4% by weight, (B) component: 0.3 to 30% by weight and (C) component: 0.3 to 15% by weight [however, the total of (A) component + (B) component + (C) component Of 100 to 100% by weight] is contained in an amount of 500 to 5 parts by weight per 100 parts by weight of an anionic surfactant and / or a nonionic surfactant and / or an amphoteric surfactant. A solid or liquid detergent composition for textiles. 2. The proportion of each of the components (A) to (C) is (A) component: 65 to 95% by weight, (B) component: 3 to 20% by weight and (C) component: 2 to 15% by weight. The detergent composition according to claim 1, which is present. 3. The proportion of each of the components (A) to (C) is (A) component: 75 to 90% by weight, (B) component: 2 to 15% by weight and (C) component: 3 to 10% by weight. The detergent composition according to claim 1, which is present. 4. The detergent composition according to claim 1, wherein the shrink-proof component is contained in an amount of 300 to 10 parts by weight per 100 parts by weight of an anionic surfactant and / or a nonionic surfactant and / or an amphoteric surfactant. . 5. The detergent composition according to claim 1, wherein the shrink-proof component is contained in an amount of 200 to 20 parts by weight per 100 parts by weight of an anionic surfactant and / or a nonionic surfactant and / or an amphoteric surfactant. . 6. The detergent composition according to claim 1, wherein the shrink-proof component is contained in an amount of 150 to 30 parts by weight per 100 parts by weight of an anionic surfactant and / or a nonionic surfactant and / or an amphoteric surfactant. . 7. The detergent composition according to claim 1, wherein the textile product is a textile product containing wool fibers. 8. The detergent composition according to claim 1, wherein the fiber product is a fiber product containing animal hair fibers. 9. The detergent composition according to claim 1, wherein the textile product is a textile product containing silk. 10. The detergent composition according to claim 1, wherein the textile product is a fur product.