WO2003068624A1 - Insert fonctionnel pour goulot de recipient, typiquement une bouteille, et capsule de bouchage comprenant ledit insert - Google Patents
Insert fonctionnel pour goulot de recipient, typiquement une bouteille, et capsule de bouchage comprenant ledit insert Download PDFInfo
- Publication number
- WO2003068624A1 WO2003068624A1 PCT/FR2003/000383 FR0300383W WO03068624A1 WO 2003068624 A1 WO2003068624 A1 WO 2003068624A1 FR 0300383 W FR0300383 W FR 0300383W WO 03068624 A1 WO03068624 A1 WO 03068624A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- insert
- adhesive
- neck
- functional
- typically
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D53/00—Sealing or packing elements; Sealings formed by liquid or plastics material
- B65D53/06—Sealings formed by liquid or plastic material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D47/00—Closures with filling and discharging, or with discharging, devices
- B65D47/04—Closures with discharging devices other than pumps
- B65D47/043—Closures with discharging devices other than pumps with pouring baffles, e.g. for controlling the flow
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D47/00—Closures with filling and discharging, or with discharging, devices
- B65D47/04—Closures with discharging devices other than pumps
- B65D47/06—Closures with discharging devices other than pumps with pouring spouts or tubes; with discharge nozzles or passages
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D49/00—Arrangements or devices for preventing refilling of containers
- B65D49/02—One-way valves
- B65D49/04—Weighted valves
Definitions
- the invention relates to the field of functional inserts to be placed in the necks of containers in order to provide said container with a particular function, namely typically a spout function, or even a non-filling function.
- the invention further relates to closure caps comprising this type of insert.
- closure caps provided with sealing inserts, as well as these same capsules further comprising functional inserts by virtue of a reversible assembly, so that the functional insert can be placed simultaneously in the neck of the bottle, and the closure cap on the neck.
- French application No. 99 14016 in the name of the applicant discloses a stopper capsule comprising a functional insert which forms a pourer.
- French application No 00 00397 in the name of the applicant discloses a closure cap comprising a functional insert with anti-filling function.
- the functional inserts of the state of the art generally comprise circular fins ensuring, taking into account their flexibility, the watertight fixing of the inserts in the neck.
- the functional inserts can be fixed by force fitting the insert into the neck, which poses no problem when the functional insert is fixed apart, and when it is adapted to a predetermined neck, and particularly when the neck has a profile called "A", that is to say with a significant constriction in the axial direction from bottom to top, so that the insert, once placed by force in the neck can not easily come out of the neck.
- the fixing of the inserts poses problems when the neck has a so-called "V" profile, that is to say with a significant expansion in the axial direction from bottom to top, so that there is a risk to see the insert, once placed by force in the neck, come out of the neck.
- This risk is all the greater when the necks have dimensional irregularities, or when the functional insert is fixed to the neck at the same time as the closure cap. Indeed, in the latter case, it is the standard capping equipment that is used, and the capping therefore does not include a specific step of assembly by force of the functional insert in the neck.
- the invention therefore aims to obtain a good fixing of the functional insert to a neck, whatever the type of profile of the neck, whether it is "A", "V" or whether it is straight, with in addition, greater tolerances on the internal dimensions of the necks, and this even when the functional insert is associated with a closure cap, and is fixed to the neck during the capping of the neck as if the closure cap did not include d 'functional insert.
- the functional insert typically made of plastic, for a container neck, typically a glass bottle, comprises a body intended to be introduced. in said neck, said body carrying on its outer surface at least one flexible fin intended to form a tight junction with said neck when said functional insert is introduced into said neck, and a functional element, and is characterized in that: a) said functional insert comprises an adhesive typically carried by said fin on its upper surface and / or by said outer surface of said body, said adhesive being chosen to adhere to said neck, b) said adhesive is a typically permanent adhesive, chosen in consistency or viscosity so that '' it only flows under stress, stress typically corresponding to a compression of said adhesive between said fin and said body when, said functional insert being introduced into said neck, said fin folds up, and chosen in content or quantity so that said adhesive thus comes in contact with said neck, so as to secure said body to said neck by an area adhesive contact and to prevent an axial displacement upwards of said functional insert under an axial stress.
- the invention is based on the combination of several means:
- the situation changes completely in industrial production when they accumulate, sometimes unfavorably, the manufacturing tolerances both on the neck and on the functional insert, any industrial part being situated in a more or less wide dimensional range, with a relatively wide range with regard to glass necks given the technology specific to this material.
- the invention therefore makes it possible to obtain industrially inserts integral with the necks, despite the tolerances on the neck and on the insert, even when these tolerances are unfavorable, for example in the case of an insert with minimum dimensions and a neck with maximum dimensions.
- the invention solves the problem of the variety of profiles of the necks, typically in the shape of an "A" - a case favorable to the fixing of the functional insert, or in the shape of a "V” or slightly flared - case unfavorable for fixing the functional insert.
- the invention constitutes a solution not based on a "geometric” cooperation between parts to be joined together, but based on adhesion, with a “chemical” cooperation between these parts, which therefore makes it possible to overcome the precise shape of the neck.
- the invention is also of great interest because the problems posed are resolved essentially upstream, at the manufacturer of inserts, and not downstream, for example in cellars where the wines are packaged in bottles, bottles which are then capped. finally encapsulated, so that the capping methods and devices can remain possibly unchanged when the functional inserts according to the invention are used.
- Figures 1 to 3 show, for the sake of simplification, only the body (30) of the functional insert (3) devoid of its functional element (6,7).
- Figure 1 on the right, illustrates a half-section of a functional insert (3) comprising a single fin (31) carrying the adhesive (5), before capping. It illustrates, on the left side, after encapsulation, the cooperation of the same insert in a neck (4), of type "A" because at a closed angle ⁇ , the folding of the fin (31) causing the creep of the adhesive (5) and the formation of an adhesive ring (50) in contact with the neck according to an adhesive contact zone (40).
- Figure 2 is similar to the left part of Figure 1. It differs in that the neck is of the "V" type because it forms an open angle ⁇ .
- Figure 3 is similar to the right part of Figure 1. It differs in that the functional insert (3) comprises 3 fins (31) and in that the adhesive (5) is placed in the limited annular groove by two adjacent fins and by the external surface of the body (30) lying between these two fins.
- FIG. 4 illustrates the case of a capsule (1) provided with sealing (2) and functional (3) inserts of the irreplaceable type (7), the latter being inserted in a threaded neck (4).
- Figures 5a to 7 illustrate the case of a capsule (1) with a functional insert (3) of the pouring type (6).
- said body (30), typically cylindrical can comprise at least two fins (31), said adhesive (5) being typically placed between the two fins, or on each of them. Indeed, the presence of several fins allows simultaneously to have a better seal, and an axial centering of the body (30) relative to the neck (4).
- said adhesive (5) can form a crown, so as to form a circular or annular contact area over the entire inner circumference of the neck.
- said adhesive (5) can form one or more discontinuous deposits, so as to form a contact zone which may or may not be discontinuous depending on the number of said discontinuous deposits, typically between 1 and 4.
- said adhesive (5) can be a permanent adhesive of the "hot-melt" type.
- the adhesive (5) may optionally be an activatable or crosslinkable adhesive, typically by supplying energy, once said insert has been placed in said neck.
- This adhesive may include a hardener or activator.
- Said adhesive (5) can also typically be in the form of microbeads which release said adhesive when said functional insert (3) is placed in said neck, or is an activatable adhesive when said functional insert (3) is placed in said neck.
- said adhesive (5) is chosen so as to typically adhere to glass, or to the material of the neck, and in which said adhesive contact zone has a contact area, typically between 20 and 500 mm 2 , so that said insert remains immobilized in said neck under axial stress of at least 0.5 daN, and preferably at least 5 daN.
- the adhesive has hardened, whether it is an aging hardening or a hardening triggered after the functional insert has been fixed in the neck, it may be impossible to separate the functional insert (3) from the neck (4) without risking destroying the neck itself, so as to prevent any risk of fraud.
- said functional element can form a pourer (6).
- said functional element can form an irreplaceable device (7) or an anti-fraud device.
- said functional insert (3) may comprise a reversible assembly means (32) intended to temporarily secure said functional insert (3) to a capsule (1), typically a closure capsule , or to a sealing insert (2) of said capsule, said axial stress corresponding at least to the stress necessary to separate said capsule (1) or said sealing insert (2), from said functional insert (3) during the opening of said capsule.
- Another object of the invention consists of a capsule (1), typically a closure capsule, comprising a shell (11) provided with a skirt (1 10) and a sealing insert (2), possibly threaded, integral with said shell (1 1), and a functional insert (3) according to the invention, said sealing insert (2) or said shell (1 1), and said insert functional (3) comprising reversible securing means (20, 32), typically by reversible snap-fastening.
- a capsule (1) typically a closure capsule, comprising a shell (11) provided with a skirt (1 10) and a sealing insert (2), possibly threaded, integral with said shell (1 1), and a functional insert (3) according to the invention, said sealing insert (2) or said shell (1 1), and said insert functional (3) comprising reversible securing means (20, 32), typically by reversible snap-fastening.
- the insert is fixed to the neck during the capping of the neck itself, so that in practice, the fixing of the insert is masked by the standard capping operation. .
- Said shell (1 1) can be metallic, typically aluminum, or plastic, and in this case, it can be heat shrinkable.
- Another object of the invention is constituted by a method of manufacturing a capsule according to the invention in which: a) provision is made for said functional insert (3), said adhesive (5) and said closure cap (1) typically provided with said sealing insert (2), b) depositing or applying said adhesive (5) on said functional insert (3), c) then securing said functional insert (3) to said sealing insert (2) or to said shell (11), so that said adhesive (5) is protected from any external contact by the skirt (110) of said shell, and thus said capsule (1) can be handled without risk of damage .
- Another object of the invention consists of the use of a functional insert (3) and / or a capsule (1) comprising said functional insert according to the invention, to secure any type of functional element (6, 7) to any type of neck (4), with a profile either straight, or "A” or “V", whatever its diameter can range from 18 mm to 45 mm, and typically close to 30 mm.
- FIG. 4 illustrates the case of a functional insert (3) of the irreplaceable type (7) inserted in a neck (4) with thread (41).
- This functional insert (3) was inserted with a closure capsule (1) comprising a shell (1 1) and a sealing insert (2), the capsule being shown screwed and crimped by irreversible deformation (12) under the ring. (42) from the neck.
- This sealing insert comprises a head (21), a threaded skirt (22), and a reversible assembly means (20) cooperating with the flexible lip (60) forming the reversible assembly means (32) of the functional insert (3).
- the functional insert (3) comprises 3 fins (31), as in the case of FIG. 3, and an irreplaceable device (7) comprising a ball (70) movable between a stop grid (71) and a support ( 72) with a central opening.
- Figures 5a to 7 illustrate the case of a functional insert (3) of the pouring type (6).
- Figure 5a is a side view of the functional insert (3) comprising said adhesive (5) between two fins
- Figure 5b is a sectional view
- FIG. 5 c is a view of the sealing insert (2) provided with a reversible assembly crown (20) intended to cooperate by reversible snap-fastening with the flange (32) of the functional insert (3).
- FIG. 6 represents, in straight half-section, the assembly constituted by the reversible assembly of the closure capsule (1) consisting of a shell, typically metallic (1 1) with a skirt (110) and a head ( 1 1 1) integral with a sealing insert (2), and the functional insert (3,6).
- Figure 7 shows, but in left half-section, the assembly of Figure 6 after crimping the capsule on a threaded neck.
- aluminum shells (11) were first manufactured, by stamping, sealing inserts (2) and functional inserts (3) with 3 fins, made of PE or PP according to the tests, by molding (injection).
- a commercial hot-melt type adhesive was supplied, Plastoflex® 9092 or 91 17 from the company Paramelt. Then, using a heated nozzle gun, applied a bead of adhesive between the two upper fins by rotating the insert opposite the fixed nozzle. According to the tests, the quantities deposited varied from 0.01 to 0.5 g per insert. Finally, the functional inserts loaded with adhesive (5) were assembled in the sealing inserts (2) fixed to the shells (1 1), so as to obtain closure caps (1) according to the invention.
- the invention economically solves all of the problems posed. It also opens the way to a new family of products which can bring increased security to the consumer, in particular in the case where the adhesive used hardens and irreversibly secures the functional insert to the neck and in the case where this functional insert is irreplaceable type.
- Adhesive contact area 40
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Closures For Containers (AREA)
- Details Of Rigid Or Semi-Rigid Containers (AREA)
Abstract
Description
Claims
Priority Applications (9)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/501,914 US7562783B2 (en) | 2002-02-12 | 2003-02-07 | Functional insert for the neck of a recipient, especially a bottle, and closing capsule comprising said insert |
BR0307621-0A BR0307621A (pt) | 2002-02-12 | 2003-02-07 | Enxerto funcional para gargalo de recipiente, tipicamente uma garrafa, e cápsula de fechamento, compreendendo esse enxerto |
AU2003214357A AU2003214357A1 (en) | 2002-02-12 | 2003-02-07 | Functional insert for the neck of a recipient, especially a bottle, and closing capsule comprising said insert |
DE60301557T DE60301557T2 (de) | 2002-02-12 | 2003-02-07 | Funktioneller einsatz für einen behälterhals, z.b. einer flasche, und verschlusskappe mit einem solchen einsatz |
EP03709927A EP1474341B1 (fr) | 2002-02-12 | 2003-02-07 | Insert fonctionnel pour goulot de recipient, typiquement une bouteille, et capsule de bouchage comprenant ledit insert |
MXPA04007497A MXPA04007497A (es) | 2002-02-12 | 2003-02-07 | Inserto funcional para cuello de recipiente, tipicamente una botella, y capsula de taponado comprendiendo dicho inserto. |
CA002474550A CA2474550C (fr) | 2002-02-12 | 2003-02-07 | Insert fonctionnel pour goulot de recipient, typiquement une bouteille, et capsule de bouchage comprenant ledit insert |
AT03709927T ATE303956T1 (de) | 2002-02-12 | 2003-02-07 | Funktioneller einsatz für einen behälterhals, z.b. einer flasche, und verschlusskappe mit einem solchen einsatz |
NO20043329A NO20043329L (no) | 2002-02-12 | 2004-08-10 | Funksjonell innsats for halsen pa en beholder, saerlig en flaske, og lukkekapsel omfattende en slik innsats |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR02/01726 | 2002-02-12 | ||
FR0201726A FR2835811B1 (fr) | 2002-02-12 | 2002-02-12 | Insert fonctionnel pour goulot de recipient, typiquement une bouteille, et capsule de bouchage comprenant ledit insert |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2003068624A1 true WO2003068624A1 (fr) | 2003-08-21 |
Family
ID=27620132
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/FR2003/000383 WO2003068624A1 (fr) | 2002-02-12 | 2003-02-07 | Insert fonctionnel pour goulot de recipient, typiquement une bouteille, et capsule de bouchage comprenant ledit insert |
Country Status (13)
Country | Link |
---|---|
US (1) | US7562783B2 (fr) |
EP (1) | EP1474341B1 (fr) |
AR (1) | AR038488A1 (fr) |
AT (1) | ATE303956T1 (fr) |
AU (1) | AU2003214357A1 (fr) |
BR (1) | BR0307621A (fr) |
CA (1) | CA2474550C (fr) |
DE (1) | DE60301557T2 (fr) |
ES (1) | ES2249710T3 (fr) |
FR (1) | FR2835811B1 (fr) |
MX (1) | MXPA04007497A (fr) |
NO (1) | NO20043329L (fr) |
WO (1) | WO2003068624A1 (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104703892A (zh) * | 2012-09-17 | 2015-06-10 | 欧文斯-布洛克威玻璃容器有限公司 | 用于容器的防再装分配配件 |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20090084799A1 (en) * | 2007-09-27 | 2009-04-02 | Stefan Mondon | Narrow neck glass container with internal embossments and method of manufacture |
FR2927885B1 (fr) * | 2008-02-26 | 2013-04-19 | Segede | Perfectionnement aux recipients |
FR2950035B1 (fr) | 2009-09-15 | 2011-09-02 | Raymond A & Cie | Coiffe de verrouillage pour recipient a col |
FR2950865B1 (fr) | 2009-10-01 | 2011-10-28 | Raymond A & Cie | Coiffe de verrouillage pour recipient a col avec une capsule a pattes de fixation |
KR101119441B1 (ko) * | 2009-10-14 | 2012-03-16 | 씨제이제일제당 (주) | 병마개 조립체 |
FR2986782B1 (fr) | 2012-02-13 | 2014-03-07 | Raymond A & Cie | Dispositif de verrouillage de bouchon sur recipient a collerette, recipient a collerette obture par bouchon pourvu d'un tel dispositif de verrouillage |
US9145240B2 (en) | 2013-04-25 | 2015-09-29 | Owens-Brockway Glass Container Inc. | Container fitment |
US20150027976A1 (en) * | 2013-07-24 | 2015-01-29 | Royal Summit Inc. | Bottle cap |
GB2531090B (en) * | 2015-03-02 | 2016-08-24 | Robert Lanagan David | A diffusing device |
FR3113896B1 (fr) * | 2020-09-04 | 2022-08-19 | Verallia Packaging | Contenant en verre creux à profil de buvant spécifique |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0185245A2 (fr) * | 1984-12-11 | 1986-06-25 | Bramlage GmbH | Fermeture pour bouteilles ou similaires |
DE3618558A1 (de) * | 1986-06-03 | 1987-12-10 | Azza Sa | Vorrichtung zur entnahme von dosierten fluessigkeitsmengen |
WO2000000390A1 (fr) * | 1998-06-29 | 2000-01-06 | Astrapak Limited | Systeme d'emballage aseptique a bouchon et joint serrant |
FR2803827A1 (fr) * | 2000-01-13 | 2001-07-20 | Pechiney Emballage Alimentaire | Capsule de bouchage pour bague de verrerie standard |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4248748A (en) * | 1980-02-04 | 1981-02-03 | Minnesota Mining And Manufacturing Company | Heat-activated adhesive |
US5045569A (en) * | 1988-11-30 | 1991-09-03 | Minnesota Mining And Manufacturing Company | Hollow acrylate polymer microspheres |
US5101993A (en) * | 1990-05-10 | 1992-04-07 | Phoenix Closures, Inc. | Closure seal |
GB2244691B (en) * | 1990-06-07 | 1994-01-12 | Montgomery Daniel & Son Ltd | Non-refillable device |
US5078288A (en) * | 1990-10-30 | 1992-01-07 | Owens-Illinois Closure Inc. | Child resistant spout package |
-
2002
- 2002-02-12 FR FR0201726A patent/FR2835811B1/fr not_active Expired - Fee Related
-
2003
- 2003-02-07 MX MXPA04007497A patent/MXPA04007497A/es active IP Right Grant
- 2003-02-07 EP EP03709927A patent/EP1474341B1/fr not_active Expired - Lifetime
- 2003-02-07 CA CA002474550A patent/CA2474550C/fr not_active Expired - Fee Related
- 2003-02-07 WO PCT/FR2003/000383 patent/WO2003068624A1/fr not_active Application Discontinuation
- 2003-02-07 ES ES03709927T patent/ES2249710T3/es not_active Expired - Lifetime
- 2003-02-07 US US10/501,914 patent/US7562783B2/en not_active Expired - Fee Related
- 2003-02-07 DE DE60301557T patent/DE60301557T2/de not_active Expired - Lifetime
- 2003-02-07 AU AU2003214357A patent/AU2003214357A1/en not_active Abandoned
- 2003-02-07 AT AT03709927T patent/ATE303956T1/de active
- 2003-02-07 BR BR0307621-0A patent/BR0307621A/pt not_active Application Discontinuation
- 2003-02-11 AR ARP030100429A patent/AR038488A1/es not_active Application Discontinuation
-
2004
- 2004-08-10 NO NO20043329A patent/NO20043329L/no not_active Application Discontinuation
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0185245A2 (fr) * | 1984-12-11 | 1986-06-25 | Bramlage GmbH | Fermeture pour bouteilles ou similaires |
DE3618558A1 (de) * | 1986-06-03 | 1987-12-10 | Azza Sa | Vorrichtung zur entnahme von dosierten fluessigkeitsmengen |
WO2000000390A1 (fr) * | 1998-06-29 | 2000-01-06 | Astrapak Limited | Systeme d'emballage aseptique a bouchon et joint serrant |
FR2803827A1 (fr) * | 2000-01-13 | 2001-07-20 | Pechiney Emballage Alimentaire | Capsule de bouchage pour bague de verrerie standard |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104703892A (zh) * | 2012-09-17 | 2015-06-10 | 欧文斯-布洛克威玻璃容器有限公司 | 用于容器的防再装分配配件 |
Also Published As
Publication number | Publication date |
---|---|
EP1474341B1 (fr) | 2005-09-07 |
AR038488A1 (es) | 2005-01-19 |
ATE303956T1 (de) | 2005-09-15 |
CA2474550A1 (fr) | 2003-08-21 |
US20050211655A1 (en) | 2005-09-29 |
CA2474550C (fr) | 2009-09-08 |
DE60301557D1 (de) | 2005-10-13 |
MXPA04007497A (es) | 2004-11-10 |
US7562783B2 (en) | 2009-07-21 |
FR2835811B1 (fr) | 2004-05-21 |
EP1474341A1 (fr) | 2004-11-10 |
BR0307621A (pt) | 2004-12-21 |
DE60301557T2 (de) | 2006-06-14 |
AU2003214357A1 (en) | 2003-09-04 |
ES2249710T3 (es) | 2006-04-01 |
NO20043329L (no) | 2004-09-13 |
FR2835811A1 (fr) | 2003-08-15 |
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