WO2003008401A1 - Verfahren zur herstellung von propylenoxid - Google Patents
Verfahren zur herstellung von propylenoxid Download PDFInfo
- Publication number
- WO2003008401A1 WO2003008401A1 PCT/EP2002/008022 EP0208022W WO03008401A1 WO 2003008401 A1 WO2003008401 A1 WO 2003008401A1 EP 0208022 W EP0208022 W EP 0208022W WO 03008401 A1 WO03008401 A1 WO 03008401A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- mixture
- propene
- oxygen
- hydroperoxide
- unreacted
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/12—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Definitions
- the present invention relates to a process in which propylene oxide is prepared from a hydroperoxide, preferably hydrogen peroxide, and propene, part of the unreacted propene being recovered by a suitable procedure and being recycled into a reaction of propene with hydroperoxide.
- a hydroperoxide preferably hydrogen peroxide
- propene part of the unreacted propene being recovered by a suitable procedure and being recycled into a reaction of propene with hydroperoxide.
- propylene oxide an important intermediate in the chemical industry, from propene and hydrogen peroxide.
- unreacted propene is preferably separated from the discharge of the epoxidation in this process and returned to the process as a starting material.
- the propene is often accompanied in the removal from the discharge from other low-boiling components which are also present in the discharge, including oxygen.
- the oxygen is usually enriched in a concentration that leads to an ignitable mixture of propene and oxygen. This represents a security risk that should not be underestimated for the separation process.
- EP-B 0 719 768 proposes to carry out the separation of propene from the low-boiling mixture in a so-called absorption zone.
- an inert gas preferably methane
- methane is fed up to a concentration such that the oxygen also present in the low-boiling mixture is diluted to a concentration at which the mixture is no longer in the ignitable range.
- the present invention relates to a process for producing propylene oxide, which has at least the following steps:
- the mixture (G1) is brought into contact with a fluid medium which has at least solvent to obtain the mixtures (G2) and (G3), the mixture (G3) comprising part of the unreacted propene and oxygen, the mixture (G2) has solvent and residual propene, and the separated unreacted propene and oxygen-containing mixture (G3) has a ratio of oxygen to propene by which the mixture (G3) is not ignitable and the mixture (G2) at least one reaction of propene with hydroperoxide is fed.
- the separation of an essentially liquid mixture is preferably achieved by means of at least one distillation column.
- a so-called "absorption column” is preferably used in the context of the present invention.
- the essentially gaseous mixture flowing through the column is washed with a fluid medium (absorbent), as a rule in a countercurrent process, the desired gas component being wholly or partly absorbed by the absorbent and leaving the column together with the absorbent ,
- the non-absorbed gas component (s) can leave the column by another suitable device.
- the desired gas component to be absorbed by the fluid medium is propene.
- the amount of propene which is absorbed by the fluid medium (absorbent) within the gas scrubbing process can be controlled via all parameters which appear suitable to the person skilled in the art for this purpose.
- the amount of absorbent or the pressure in the absorption column which is in a range from 0.5 to 3 bar, preferably in the normal pressure range.
- Control over the temperature prevailing in the absorption column which is in a range from 0 to 60 ° C., preferably in a range from 25 to 40 ° C., is also possible.
- the parameter preferably used to control the amount of propene which is absorbed by the fluid medium (absorbent) within the gas washing process is the amount of absorbent used.
- the so-called residual propene is absorbed by the absorbent within the at least one absorption column, so that the gaseous mixture remaining after the washing process continues to contain propene.
- the fluid medium (absorption medium) used for absorption can in principle be any liquid medium suitable for absorption of propene.
- these are, for example, all known to the person skilled in the art and solvents suitable for this purpose. Accordingly, the following solvents can, for example, be used as absorbents: water,
- Alcohols preferably lower alcohols, more preferably alcohols with less than 6 carbon atoms, such as, for example, methanol, ethanol, propanols,
- Diols or polyols preferably those with fewer than 6 carbon atoms,
- Ethers such as diethyl ether, tetrahydrofuran, dioxane, 1,2-diethoxyethane, 2-methoxyethanol, esters such as methyl acetate or butyrolactone,
- Amides such as dimethylformamide, dimethylacetamide, N-methylpyrrolidone,
- Nitriles such as acetonitrile - or mixtures of two or more of the aforementioned compounds.
- a liquid medium resulting from a previous method step is preferably used as the absorption agent. This must be able to absorb a certain part of the unreacted propene from the gaseous mixture (Eq) with which it is brought into contact in the absorption column during the gas washing process.
- the fluid medium in question particularly preferably has at least one solvent used in the process according to the invention.
- step (c) the mixture (G1), which has unreacted propene and oxygen, with the mixtures (G2) and (G3) obtained, with a fluid medium (absorbent) which has at least solvent, in Brought in contact.
- a fluid medium which has at least solvent
- unreacted propene is removed from the mixture (Eq) by the absorption agent and then returned to the process according to the invention.
- the amount of unreacted propene removed in this step is limited by the fact that the remaining mixture (G3) must not become ignitable.
- the mixture (G3) leaving the absorption column via a suitable outlet device which contains the propene not absorbed by the absorption agent and oxygen, contains a ratio of oxygen to propene and possibly other combustible substances present in (G3) Has components by which the mixture (G3) is not ignitable.
- non-ignitable means that the composition of the mixture (G3) must be selected such that, under the process conditions present when it was separated, it has an ignition limit at which the mixture (G3) ignites without it is manageable, whereby the term “ignitable mixture” according to the definition of the professional association chemistry BGR 104 part 1 - explosion protection rules, section B, point 9 "a mixture of gases and vapors with each other or with mists or dusts, in which a reaction occurs after ignition independently reproduced ".
- the ignition limit is the lower and upper limit concentration of a combustible gas or steam mixed with air (or another gas containing oxygen), between which the gas (steam) air mixture is heated by (ignition temperature) or Spark can be brought to ignition.
- the ignition limits are dependent on pressure and temperature. They are given as the concentration of the combustible gas, steam or oxygen in vol.% Or g / m 3 for an initial state of 1013 mbar and 20 ° C.
- the ignition limit of a mixture essentially depends on the composition of its main components.
- the present invention also relates to a method as described above, the concentration of oxygen in mixture (G3) being less than 12% by volume, preferably less than 11% by volume, particularly preferably less than 10% by volume.
- propene which has up to 10% by weight of hydrocarbon which is different from propene.
- the propene used can have up to 10% by weight of propane, ethane, ethylene, butane or butenes individually or as a mixture of two or more thereof.
- the present invention also relates to a process as described above, the propene used having up to 10% by weight of other hydrocarbons.
- Step (a) of the process according to the invention listed above is generally carried out in a so-called main reactor (1), preferably a tube bundle reactor.
- step (a) of the process according to the invention it is advantageous within step (a) of the process according to the invention with a molar ratio of propene to hydroperoxide in a range from 0.85 to 5, preferably 0.9 to 2, particularly preferably 0.9 to 1.2 to work.
- a molar ratio of propene to hydroperoxide in a range from 0.85 to 5, preferably 0.9 to 2, particularly preferably 0.9 to 1.2 to work.
- all hydroperoxides known to the person skilled in the art can be used in the context of the invention. Details regarding the production of hydroperoxides and the hydroperoxides which can preferably be used can be found in DE-A 19835907.1.
- hydrogen peroxide is preferably used as the hydroperoxide in the context of the present invention.
- the conversion of hydrogen peroxide in step (a) is furthermore preferably in a range from 70 to 99%, preferably in a range from 75 to 98%, particularly preferably in a range from 80 to 95%.
- the present invention also relates to a process as described above, the hydroperoxide being hydrogen peroxide and the conversion of hydrogen peroxide in step (a) being in the range from 80 to 95%.
- Alcohols preferably lower alcohols, more preferably alcohols with less than 6 carbon atoms such as, for example, methanol, ethanol, propanols, butanols, pentanols, diols or polyols, preferably those with less than 6 carbon atoms,
- Ethers such as diethyl ether, tetrahydrofuran, dioxane, 1,2-diethoxyethane, 2-methoxyethanol,
- Esters such as methyl acetate or butyrolactone
- Amides such as dimethylformamide, dimethylacetamide, N-methylpyrrolidone, Ketones such as acetone,
- Nitriles such as acetonitrile or mixtures of two or more of the aforementioned compounds can be used.
- zeolite catalysts known to the person skilled in the art for such a reaction can be used as zeolite catalysts in step (a) in the context of the present invention.
- Zeolites are preferably used which contain iron, titanium, vanadium, chromium, niobium or zirconium.
- Zeolites containing pentasil-zeolite structure containing titanium, germanium, tellurium, vanadium, chromium, niobium and zirconium in particular the types with X-ray assignment to ABW, ACO, AEI, AE AEN, AET, AFG, AFI, AFN, AFO, AFR, AFS, AFT, AFX, AFY AHT, ANA, APC, APD, AST, ATN, ATO -, ATS, ATT, ATV, AWO AWW, BEA, BIK, BOG, BPH, BRE, CAN, CAS, CFI, CGF, CGS CHA, CHI, CLO -, CON, CZP, DAC, DDR, DFO, DFT, DOH, DON EAB, EDI, EMT, EPI, ERI, ESV, EUO, FAU, FER , GIS, GME GOO, HEU, IFR, ISV, ITE,
- Titanium-containing zeolites with the structure of ITQ-4, SSZ-24, TTM-1, UTD-1, CIT-1 or CIT-5. Further titanium-containing zeolites are those with the structure of ZSM-48 or ZSM-12.
- Ti zeolites with an MFI, MEL or MFI / MEL mixed structure preference is given to using Ti zeolites with an MFI, MEL or MFI / MEL mixed structure.
- the Ti-containing zeolite catalysts which are generally referred to as “TS-1”, “TS-2”, “TS-3”, and Ti zeolites with a beta-zeolite iso- to call mo ⁇ hen framework structure.
- the present invention also relates to a method as described above, the zeolite catalyst being a titanium silicalite catalyst, in particular a titanium silicalite catalyst having the structure TS-1.
- the mixture (G0) resulting from step (a) essentially has the following components: propylene oxide, as the desired process product, solvent, unreacted propene, unreacted hydroperoxide and oxygen.
- the mixture (G0) can also comprise water as further components, and, depending on the propane or hydrocarbon content of the propene used, propane or further hydrocarbons, the compounds referred to as “hydrocarbons” being of course different from propene.
- step (b) propylene oxide is separated from the mixture (G0) resulting from step (a) of the process according to the invention in such a way that a mixture (Gl) is obtained which has unreacted propene and oxygen.
- the separation of propylene oxide from the mixture (GO) and the further processing of the other components contained in (GO) is preferably carried out in the context of the present invention via the following two process variants, variant 1 and variant 2.
- a preferred procedure (variant 1, FIG. 1) for separating off the propylene oxide consists in dividing the product discharge from the main reactor (1) into a top and a bottom fraction in a column (2) directly adjoining the main reactor (1) separate.
- the bottom fraction of column (2), mixture (GO ') has solvent, unreacted hydroperoxide and water.
- the top fraction of this column (2) essentially contains propylene oxide, unreacted propene and oxygen and is transferred to a further column (5).
- the top fraction of this column (2) can also have small amounts of solvent.
- the top fraction of column (2) preferably has less than 60% by weight, particularly preferably less than 50% by weight, of solvent.
- the propylene oxide is drawn off via the bottom fraction and, if appropriate, subjected to further workup steps in which the propylene oxide is separated from the other components present in the bottom fraction, such as solvent and water, and purified.
- the top fraction of the column (5), the mixture (Eq), has essentially unreacted propene and oxygen and is transferred to the absorption column (3) for further work-up.
- the gaseous mixture (G1) is washed with part or all of the mixture (GO '), the liquid bottom fraction from the column (2).
- the amount of the mixture (G0 ') is preferably determined via suitable line systems known to the person skilled in the art, which can have, for example, at least one bypass or valve system.
- Mixture (G0 ') can be divided into two or more fractions if necessary. At least one of these fractions is preferably used in the absorption column as an absorption medium (fluid medium) for gas scrubbing of the gaseous mixture (Eq).
- the fraction of the mixture (G0 ') not supplied to the absorption column can be wholly or partly with the liquid leaving the absorption column (3)
- Mixture can be combined into a mixture (G2), whereby the absorption coefficient Lonne (3) leaving liquid mixture has the portion of propene (residual propene) absorbed by the gas washing process from mixture (Gl).
- the mixture (G2) resulting from this process step has residual propene and the components of the absorbent, solvent, water and unreacted hydrogen peroxide.
- the conditions in the absorption column (3) must be selected so that the gaseous mixture (G3) leaving the absorption column (3) has unreacted propene and oxygen in a ratio on the basis of which it is not ignitable.
- the mixture (G3) may contain small amounts of other volatile components in addition to unreacted propene and oxygen.
- the mixture (G2) is fed to at least one further reaction of propene with hydroperoxide in a so-called post-reactor (4), preferably a tube bundle reactor.
- mixture (G2) is again mixed with such an amount of propene that the unreacted hydroperoxide still present in mixture (G2) is largely reacted with propene to give propylene oxide to obtain a mixture (G4).
- the raw output of the secondary reactor (4) is in a range of less than 500 ppm.
- the mixture (G4) can then be worked up further in order to separate off the desired product propylene oxide.
- this workup can be carried out in whole or in part in a further procedure which is separate from the previously listed method.
- mixture (G4) is preferably completely transferred to column (5) and combined there with the top fraction from column (2).
- the present invention also relates to a process as described above, wherein the mixture (G2) further contains hydroperoxide and in the further steps (d) and (e) following the step (c), the mixture (G2) of a reaction of propene with hydroperoxide as follows:
- the mixture (G2) is mixed with further propene to obtain a mixture (G4), the propene being converted to propylene oxide with extensive conversion of the unreacted hydroperoxide still present in the mixture (G2) and
- a further preferred procedure (variant 2, FIG. 2) for separating propylene oxide from the product discharge from the main reactor (1) consists in the product discharge into a directly adjoining the main reactor (1) To transfer column (6) in which the mixture (GO) is separated into a top and a bottom fraction.
- the bottom fraction from column (6) which has propylene oxide, solvent and unreacted hydroperoxide and water, is fed to further work-up steps for further processing and removal of the propylene oxide.
- the top fraction from column (6), the mixture (Gl), contains essentially unreacted propene and oxygen.
- the gaseous mixture (G3) has the portion of unreacted propene from the mixture (Gl) which was not absorbed by the solvent.
- the liquid mixture (G2) therefore has, in addition to the solvent, the propene absorbed by it (residual propene).
- this process control it is thus possible in this process control to control the amount of propene which is absorbed by the absorbent from the mixture (Gl) within the gas washing process by means of the amount of solvent which is used as the absorbent in the absorption column (7) becomes.
- unreacted propene is removed from the mixture (Eq) by the absorption agent and then returned to the process according to the invention.
- the amount of unreacted propene removed in this step is limited by the fact that the remaining mixture (G3) must not become ignitable.
- the conditions in the absorption column (7) are selected such that the propene and oxygen mixture (G3) leaving the absorption column does not ignite via its own outlet device.
- Mixture (G2) is derived from the absorption column, optionally processed and then recycled in step (a) of the process.
- the mixture (G2) is optionally prepared and recycled in step (a) of the process.
- the present invention also relates to a process as described above, wherein in a further step (f) following step (c), the mixture (G2) is fed to a reaction of propene with hydroperoxide as follows:
- step (f) the mixture (G2) is optionally prepared and returned in step (a).
- Figure 1 1 main reactor (1) 2 column (2)
- Figure 2 1 main reactor (1)
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Epoxy Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Description
Claims
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE50204792T DE50204792D1 (de) | 2001-07-19 | 2002-07-18 | Verfahren zur herstellung von propylenoxid |
CA002453988A CA2453988A1 (en) | 2001-07-19 | 2002-07-18 | Process for the preparation of propylene oxide |
MXPA04000099 MX240869B (es) | 2001-07-19 | 2002-07-18 | Proceso para la preparacion de oxido de propileno. |
AT02767229T ATE308532T1 (de) | 2001-07-19 | 2002-07-18 | Verfahren zur herstellung von propylenoxid |
US10/484,204 US6881853B2 (en) | 2001-07-19 | 2002-07-18 | Method for producing propylene oxide |
EP02767229.4A EP1412339B2 (de) | 2001-07-19 | 2002-07-18 | Verfahren zur herstellung von propylenoxid |
ZA2004/00338A ZA200400338B (en) | 2001-07-19 | 2004-01-16 | Method for producing propylene oxide |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10135296A DE10135296A1 (de) | 2001-07-19 | 2001-07-19 | Verfahren zur Herstellung von Propylenoxid |
DE10135296.4 | 2001-07-19 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2003008401A1 true WO2003008401A1 (de) | 2003-01-30 |
Family
ID=7692434
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2002/008022 WO2003008401A1 (de) | 2001-07-19 | 2002-07-18 | Verfahren zur herstellung von propylenoxid |
Country Status (9)
Country | Link |
---|---|
US (1) | US6881853B2 (de) |
EP (1) | EP1412339B2 (de) |
CN (1) | CN1261421C (de) |
AT (1) | ATE308532T1 (de) |
CA (1) | CA2453988A1 (de) |
DE (2) | DE10135296A1 (de) |
MX (1) | MX240869B (de) |
MY (1) | MY138713A (de) |
WO (1) | WO2003008401A1 (de) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8211822B2 (en) | 2003-05-08 | 2012-07-03 | Basf Aktiengesellschaft | Method for producing propylene oxide |
EP3406603A1 (de) | 2017-05-22 | 2018-11-28 | Evonik Degussa GmbH | Verfahren zur epoxidierung von propen |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10233386A1 (de) * | 2002-07-23 | 2004-02-12 | Basf Ag | Verfahren zur kontinuierlich betriebenen Reindestillation des bei der koppel-produktfreien Propylenoxidsynthese verwendeten Lösungsmittels Methanol unter gleichzeitiger Abtrennung der Methoxypropanole |
DE10233388A1 (de) * | 2002-07-23 | 2004-02-12 | Basf Ag | Verfahren zur kontinuierlich betriebenen Reindestillation des bei der koppel-produktfreien Propylenoxidsynthese verwendeten Lösungsmittels Methanol unter gleichzeitiger Abtrennung der Methoxypropanole und der Schwersieder |
DE10240129B4 (de) | 2002-08-30 | 2004-11-11 | Basf Ag | Integriertes Verfahren zur Synthese von Propylenoxid |
DE10307737A1 (de) * | 2003-02-24 | 2004-09-02 | Basf Ag | Verfahren zur Herstellung eines Epoxids |
JP2008266304A (ja) * | 2007-03-22 | 2008-11-06 | Sumitomo Chemical Co Ltd | プロピレンオキサイドの製造方法 |
CN102471299A (zh) | 2009-08-05 | 2012-05-23 | 陶氏环球技术有限责任公司 | 用于制备环氧丙烷的方法 |
TWI523689B (zh) | 2010-03-25 | 2016-03-01 | 陶氏全球科技公司 | 使用預處理環氧催化劑製備環氧丙烷之方法 |
RU2013106290A (ru) | 2010-07-14 | 2014-08-20 | ДАУ ГЛОБАЛ ТЕКНОЛОДЖИЗ, ЭлЭлСи | Способ и комплекс оборудования для производства алкиленоксидов и гликолевых простых эфиров |
CN103172486B (zh) * | 2011-12-22 | 2015-07-29 | 中国石油化工股份有限公司 | 一种从直接环氧化反应产物中回收丙烯的方法 |
CN104650008B (zh) * | 2015-02-13 | 2016-08-31 | 南京航空航天大学 | 一种由氧、氢直接氧化丙烯制备环氧丙烷的工艺及系统 |
CN111574478B (zh) * | 2020-06-12 | 2023-08-29 | 中建安装集团有限公司 | 一种过氧化氢氧化丙烯制备环氧丙烷的工艺 |
CN113912571B (zh) * | 2020-07-10 | 2023-12-05 | 中国石油化工股份有限公司 | 丙烯直接环氧化以制备环氧丙烷的方法 |
CN113968831B (zh) * | 2020-07-24 | 2024-02-09 | 中国石油化工股份有限公司 | 环氧丙烷精制方法和环氧丙烷物流的分离方法和环氧化反应产物分离方法及丙烯环氧化方法 |
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EP0719768A1 (de) * | 1994-12-28 | 1996-07-03 | ARCO Chemical Technology, L.P. | Rückgewinnung von Olefin und Sauerstoff in einer Wasserstoffperoxid-Epoxidation |
DE19623611A1 (de) * | 1996-06-13 | 1997-12-18 | Basf Ag | Verfahren zur Herstellung von Epoxiden aus Olefinen und Wasserstoffperoxid |
DE19623608A1 (de) * | 1996-06-13 | 1997-12-18 | Basf Ag | Verfahren zur Herstellung von Epoxiden aus Olefinen und Wasserstoffperoxid oder Hydroperoxiden |
WO2001057009A1 (en) | 2000-02-07 | 2001-08-09 | Degussa Ag | Process for the epoxidation of olefins |
-
2001
- 2001-07-19 DE DE10135296A patent/DE10135296A1/de not_active Withdrawn
-
2002
- 2002-07-12 MY MYPI20022656A patent/MY138713A/en unknown
- 2002-07-18 MX MXPA04000099 patent/MX240869B/es active IP Right Grant
- 2002-07-18 US US10/484,204 patent/US6881853B2/en not_active Expired - Lifetime
- 2002-07-18 WO PCT/EP2002/008022 patent/WO2003008401A1/de not_active Application Discontinuation
- 2002-07-18 AT AT02767229T patent/ATE308532T1/de not_active IP Right Cessation
- 2002-07-18 DE DE50204792T patent/DE50204792D1/de not_active Expired - Lifetime
- 2002-07-18 EP EP02767229.4A patent/EP1412339B2/de not_active Expired - Lifetime
- 2002-07-18 CN CNB028144120A patent/CN1261421C/zh not_active Expired - Lifetime
- 2002-07-18 CA CA002453988A patent/CA2453988A1/en not_active Abandoned
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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EP0719768A1 (de) * | 1994-12-28 | 1996-07-03 | ARCO Chemical Technology, L.P. | Rückgewinnung von Olefin und Sauerstoff in einer Wasserstoffperoxid-Epoxidation |
DE19623611A1 (de) * | 1996-06-13 | 1997-12-18 | Basf Ag | Verfahren zur Herstellung von Epoxiden aus Olefinen und Wasserstoffperoxid |
DE19623608A1 (de) * | 1996-06-13 | 1997-12-18 | Basf Ag | Verfahren zur Herstellung von Epoxiden aus Olefinen und Wasserstoffperoxid oder Hydroperoxiden |
WO2001057009A1 (en) | 2000-02-07 | 2001-08-09 | Degussa Ag | Process for the epoxidation of olefins |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8211822B2 (en) | 2003-05-08 | 2012-07-03 | Basf Aktiengesellschaft | Method for producing propylene oxide |
CN101607211B (zh) * | 2003-05-08 | 2013-06-12 | 巴斯夫欧洲公司 | 成型催化剂体 |
EP3406603A1 (de) | 2017-05-22 | 2018-11-28 | Evonik Degussa GmbH | Verfahren zur epoxidierung von propen |
WO2018215262A1 (en) | 2017-05-22 | 2018-11-29 | Evonik Degussa Gmbh | Process for the epoxidation of propene |
Also Published As
Publication number | Publication date |
---|---|
CN1533384A (zh) | 2004-09-29 |
MXPA04000099A (es) | 2004-05-21 |
DE50204792D1 (de) | 2005-12-08 |
DE10135296A1 (de) | 2003-01-30 |
EP1412339A1 (de) | 2004-04-28 |
EP1412339B1 (de) | 2005-11-02 |
CA2453988A1 (en) | 2003-01-30 |
US20040192945A1 (en) | 2004-09-30 |
ATE308532T1 (de) | 2005-11-15 |
EP1412339B2 (de) | 2013-10-16 |
MX240869B (es) | 2006-10-09 |
US6881853B2 (en) | 2005-04-19 |
CN1261421C (zh) | 2006-06-28 |
MY138713A (en) | 2009-07-31 |
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