WO2002089608A1 - Process for preparing a storage-stable brown stock - Google Patents

Process for preparing a storage-stable brown stock Download PDF

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Publication number
WO2002089608A1
WO2002089608A1 PCT/EP2002/004939 EP0204939W WO02089608A1 WO 2002089608 A1 WO2002089608 A1 WO 2002089608A1 EP 0204939 W EP0204939 W EP 0204939W WO 02089608 A1 WO02089608 A1 WO 02089608A1
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WO
WIPO (PCT)
Prior art keywords
weight
parts
product
minutes
process according
Prior art date
Application number
PCT/EP2002/004939
Other languages
French (fr)
Inventor
Dieter Melwitz
Andrea Mueller
Herman Schmid
Original Assignee
Unilever N.V.
Unilever Plc
Hindustan Lever Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Unilever N.V., Unilever Plc, Hindustan Lever Ltd filed Critical Unilever N.V.
Priority to AU2002341151A priority Critical patent/AU2002341151B2/en
Priority to EP02742946A priority patent/EP1385395B1/en
Priority to DE60202521T priority patent/DE60202521T2/en
Priority to AT02742946T priority patent/ATE286357T1/en
Publication of WO2002089608A1 publication Critical patent/WO2002089608A1/en

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Classifications

    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L23/00Soups; Sauces; Preparation or treatment thereof
    • A23L23/10Soup concentrates, e.g. powders or cakes
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L23/00Soups; Sauces; Preparation or treatment thereof

Definitions

  • the invention relates to a process for preparing a storage- stable brown stock from meat extract and vegetable juice.
  • Preparation of a classic culinary stock requires, in particular, bones from meat, vegetables and spices.
  • the preparation process is complex: roasting the bones and vegetables, deglazing with wine or water, reducing, adding water, boiling for several hours, repeated addition of water, filtering off the solids and reducing.
  • the object of the invention is to prepare a stock industrially and to provide a process for preparing a storage-stable brown stock. Surprisingly, it has been found that it is possible to replace the individual components by standardized industrial raw materials and, by means of the inventive process, to prepare a sauce base which is comparable to a home-made one.
  • DD-PS 132634 describes a process for preparing a sauce base stock in which bones (cleared from meat) of a particle size between 6 and 10 mm with added fats or oils and spices are browned at temperatures between 190 and 210°C, after which, with addition of water, there follows a reducing operation to be carried out repeatedly at about 120 °C and then a cooking operation also proceeding at 120°C. This process, as a result of the roasting step, is difficult to standardize and does not lead to satisfactory organoleptic results.
  • WO 87/01912 describes the preparation of a meat sauce base which can only be preserved by sterilization and needs to be further processed by the consumer.
  • DE 4233762 Al describes a process for preparing a sauce base stock from bones and vegetables, with the bones first needing to be comminuted and then, with addition of fat, browned, then the browned pieces being boiled in water for more than 10 hours, the resultant broth, after filtration, being mixed with a vegetable broth and the mixture of broths being concentrated to a solids content of 15-20%. This broth concentrate must then be sterilized, homogenized and aseptically packaged.
  • a liquid mixture having a solids content of 65-85% by weight, preferably 75-80% by weight is prepared by mixing 1-40% (preferably 2-25%) meat extract, 1-30% (preferably 2-20%) gelatin and 5-70% (preferably 10-50%) vegetable juice concentrate with or without other customary additives, which mixture is allowed to react at a temperature around boiling point, preferably 90-100°C, for 3-20 minutes, preferably 5-15 minutes, then
  • a soup stock is added to the product of the prior reaction and, after dilution to a solids content of 10-45% by weight, preferably 15-35% by weight, the mixture is cooked for 40-180 minutes, preferably 50-80 minutes, at a temperature around boiling point, preferably 90-100°C, whereupon
  • the product is concentrated to a solids content of at least 60% by weight, preferably 70% by weight or above.
  • the prior reaction is expediently carried out in a tube heater. It is not impossible also to carry out the prior reaction under pressure, higher temperatures then also being able to be used.
  • the substances extracted from these that is to say meat extract and gelatin, are used, and instead of the fresh vegetables, vegetable juice concentrates are used.
  • the Maillard reaction can be standardized.
  • Addition of gelatin is important not only to achieve the appropriate mouthfeel, but is also necessary to achieve the optimum flavour profile. It has proved to be expedient to add the gelatin in an amount of 0.5 to 0.8 parts by weight per 1 part by weight of meat extract .
  • a soup stock is a product known to those skilled in the art which is obtained by boiling bones.
  • the product is then diluted, preferably with water, and subjected to a cooking step. This cooking step is an important step to achieve the desired flavour profile as exhibited by a classically prepared stock.
  • spices can be added to further round off the taste.
  • the cooking step is expediently carried out in a jacketed cooking vessel .
  • the product from the cooking is then concentrated by means of a suitable evaporator to a concentration corresponding to a water activity of 0.65 to 0.75; this is generally the case at a solids content of 60-70% by weight. At this water activity, the product can be kept for several months without cooling or addition of additives.
  • Suitable evaporators are falling-film evaporators and thin-film evaporators .
  • the resultant pasty end product can further be converted into a pulverulent dry product, for example by vacuum drying or microwave vacuum drying. Examples
  • a mixture having a solids content of 75% by weight, of 30 parts of meat extract, 20 parts of gelatin, 40 parts of dextrose, 30 parts of carrot juice concentrate, 68 parts of leek juice concentrate, 48 parts of salt, 34 parts of celery juice concentrate, 50 parts of onion juice concentrate, 60 parts of tomato puree, 60 parts of red wine extract and 40 parts of glutamate is given a prior reaction in a tube heater for 6 min at 99°C.
  • 106 parts of soup stock, 0.7 parts of spices (cloves, bay leaf, pepper, thyme, rosemary) and 875 parts of water are added, so that a solids content of 30% by weight is obtained and this product is cooked in a cooking vessel at 100 °C for 60 minutes.
  • the product is then concentrated in a single stage in a thin-film evaporator from approximately 30% DM to 66% DM.
  • a sauce base is obtained which corresponds in flavour and consistency to a classically prepared stock.
  • a mixture having a solids content of 80% by weight of 27 parts of meat extract, 18 parts of gelatin, 36 parts of dextrose, 27 parts of carrot juice concentrate, 62 parts of leek juice concentrate, 62 parts of salt, 31 parts of celery juice concentrate, 46 parts of onion juice concentrate, 54 parts of tomato puree and 36 parts of glutamate is given a prior reaction in a tube heater for 6 min at 99°C. Then, 100 parts of soup stock, 0.6 parts of spices (cloves, bay leaf, pepper, thyme, rosemary) and 831 parts of water are added, and the mixture is cooked in a cooking vessel at 100°C for 60 minutes.
  • the product is then concentrated in a single stage in a thin- film evaporator from approximately 28% DM to 60% DM.
  • This product also corresponds, after redilution to 1 litre, in flavour and consistency to a classically prepared stock. Since it is prepared without red wine extract, it permits more versatile applications.
  • a mixture having a solids content of 78% by weight of 30 parts of meat extract, 40 parts of dextrose, 30 parts of carrot juice concentrate, 68 parts of leek juice concentrate, 48 parts of salt, 34 parts of celery juice concentrate, 50 parts of onion juice concentrate, 60 parts of tomato puree, 60 parts of red wine extract and 40 parts of glutamate is given a prior reaction in a tube heater for 6 min at 99°C. Then, 110 parts of soup stock, 0.7 parts of spices (cloves, bay leaf, pepper, thyme, rosemary) and 875 parts of water are added, and the mixture is cooked in a cooking vessel at 100°C for 60 minutes.
  • the product is then concentrated in a single stage in a thin- film evaporator from approximately 30% DM to 66% DM. After redilution, this product did not comply with the requirements with respect to flavour and consistency.
  • This example illustrates the importance that the substances extracted from the bones and the collagen raw materials have for the flavour and consistency of a good-tasting stock.
  • Example 5 30 parts of meat extract, 20 parts of gelatin, 40 parts of dextrose, 30 parts of carrot juice concentrate, 68 parts of leek juice concentrate, 48 parts of salt, 34 parts of celery juice concentrate, 50 parts of onion juice concentrate, 60 parts of tomato puree, 60 parts of red wine extract and 40 parts of glutamate are mixed with 106 parts of soup stock, 0.7 parts of spices (cloves, bay leaf, pepper, thyme, rosemary) . An attempt was made to subject this mixture, which had a solids content of 78% by weight, to a prior reaction in the tube heater at 99°C for 6 minutes. This did not succeed, the product "burns on" immediately and exhibits a corresponding flavour profile.
  • spices cloves, bay leaf, pepper, thyme, rosemary

Abstract

The invention relates to a process for preparing a storage-stable brown stock from meat extract and vegetable juice and other customary additives. According to this processa) in a prior reaction, a liquid mixture having a solids content of 65-85% by weight, preferably 75-80% by weight, of meat extract, gelatin and vegetable juice concentrate with or without other customary additives is allowed to react at a temperature around boiling point, preferably 90-100°C, for 3-20 minutes, preferably 5-15 minutes, thenb) in a cooking step, a soup stock is added to the product of the prior reaction and, after dilution to a solids content of 10-45% by weight, preferably 15-35% by weight, the mixture is cooked for 40-180 minutes, preferably 50-80 minutes, at a temperature around boiling point, preferably 90-100°C, whereuponc) the product is concentrated to a solids content of at least 60% by weight, preferably 70% by weight or above.The end product can be dried to give a pulverulent dry product.

Description

PROCESS FOR PREPARING A STORAGE-STABLE BROWN STOCK
The invention relates to a process for preparing a storage- stable brown stock from meat extract and vegetable juice.
Culinary preparation of a classic brown stock (Fond brun, demi glace) is a very time-consuming process and also requires experience and skill on the part of the respective chef; precise attention must be paid to selection and quality of the raw materials. Such a stock can be kept for only a few days under refrigeration. From classic cuisine, it is known that a stock can be concentrated by slow reduction to the extent that it can be kept for several months without refrigeration; this product is termed "Glace (de viande)". It is not surprising that a stock is prepared only rarely in private households .
Preparation of a classic culinary stock requires, in particular, bones from meat, vegetables and spices. The preparation process is complex: roasting the bones and vegetables, deglazing with wine or water, reducing, adding water, boiling for several hours, repeated addition of water, filtering off the solids and reducing.
It appears to be virtually impossible to standardize this process for purposes of industrial manufacture, since the raw materials differ in quality and even roasting on an industrial scale is not possible.
The object of the invention is to prepare a stock industrially and to provide a process for preparing a storage-stable brown stock. Surprisingly, it has been found that it is possible to replace the individual components by standardized industrial raw materials and, by means of the inventive process, to prepare a sauce base which is comparable to a home-made one.
DD-PS 132634 describes a process for preparing a sauce base stock in which bones (cleared from meat) of a particle size between 6 and 10 mm with added fats or oils and spices are browned at temperatures between 190 and 210°C, after which, with addition of water, there follows a reducing operation to be carried out repeatedly at about 120 °C and then a cooking operation also proceeding at 120°C. This process, as a result of the roasting step, is difficult to standardize and does not lead to satisfactory organoleptic results. WO 87/01912 describes the preparation of a meat sauce base which can only be preserved by sterilization and needs to be further processed by the consumer. DE 4233762 Al describes a process for preparing a sauce base stock from bones and vegetables, with the bones first needing to be comminuted and then, with addition of fat, browned, then the browned pieces being boiled in water for more than 10 hours, the resultant broth, after filtration, being mixed with a vegetable broth and the mixture of broths being concentrated to a solids content of 15-20%. This broth concentrate must then be sterilized, homogenized and aseptically packaged.
Against standardization of such a process is the fact that meat-bearing bones can differ in quality and the roasting operation, owing to the varying raw material quality, proceeds variably and cannot be performed to lead to uniform optimum results . The inventive process makes it possible to prepare a stock which corresponds in quality to that of a classic stock, but can be kept for several months at room temperature, and does not require sterilization for long shelf life. In addition, the process is characterized by a significantly shorter processing time and the raw materials used are available on the market in sufficient amount and in standardized qualities.
The inventive process is characterized in that
a) in a prior reaction, a liquid mixture having a solids content of 65-85% by weight, preferably 75-80% by weight, is prepared by mixing 1-40% (preferably 2-25%) meat extract, 1-30% (preferably 2-20%) gelatin and 5-70% (preferably 10-50%) vegetable juice concentrate with or without other customary additives, which mixture is allowed to react at a temperature around boiling point, preferably 90-100°C, for 3-20 minutes, preferably 5-15 minutes, then
b) in a cooking step, a soup stock is added to the product of the prior reaction and, after dilution to a solids content of 10-45% by weight, preferably 15-35% by weight, the mixture is cooked for 40-180 minutes, preferably 50-80 minutes, at a temperature around boiling point, preferably 90-100°C, whereupon
c) the product is concentrated to a solids content of at least 60% by weight, preferably 70% by weight or above.
The individual process steps and their sequence are essential for the success of the inventive process. Without the prior reaction the product lacks a roast flavour, it tastes of the individual components and the typical sauce taste is absent. From the energy point of view, it appears contradictory to dilute the concentrated raw materials for the cooking step and to concentrate them again subsequently, but without this cooking step at a low solids content, the desired taste balance is lacking from the product : the product only tastes roasted and of the individual constituents, but it lacks the rounded and harmonious organoleptic profile.
The prior reaction is expediently carried out in a tube heater. It is not impossible also to carry out the prior reaction under pressure, higher temperatures then also being able to be used.
According to the invention, instead of the meat-bearing bones, the substances extracted from these, that is to say meat extract and gelatin, are used, and instead of the fresh vegetables, vegetable juice concentrates are used. Thus the Maillard reaction can be standardized.
Addition of gelatin is important not only to achieve the appropriate mouthfeel, but is also necessary to achieve the optimum flavour profile. It has proved to be expedient to add the gelatin in an amount of 0.5 to 0.8 parts by weight per 1 part by weight of meat extract .
For targeted control of the Maillard reaction, expediently, in addition, various reducing sugars, in particular dextrose, are added. It has proved to be advantageous to add, per 1 part by weight of meat extract, 1-1.5 parts by weight of reducing sugars .
To round off the taste, it is further advantageous to add cooking salt, gluta ate, tomato puree and/or wine extract. After the prior reaction, a soup stock is added to the product. A soup stock is a product known to those skilled in the art which is obtained by boiling bones. The product is then diluted, preferably with water, and subjected to a cooking step. This cooking step is an important step to achieve the desired flavour profile as exhibited by a classically prepared stock.
In this cooking step, spices can be added to further round off the taste.
The cooking step is expediently carried out in a jacketed cooking vessel .
The product from the cooking is then concentrated by means of a suitable evaporator to a concentration corresponding to a water activity of 0.65 to 0.75; this is generally the case at a solids content of 60-70% by weight. At this water activity, the product can be kept for several months without cooling or addition of additives.
Suitable evaporators are falling-film evaporators and thin-film evaporators .
The resultant pasty end product can further be converted into a pulverulent dry product, for example by vacuum drying or microwave vacuum drying. Examples
Example 1
A mixture having a solids content of 75% by weight, of 30 parts of meat extract, 20 parts of gelatin, 40 parts of dextrose, 30 parts of carrot juice concentrate, 68 parts of leek juice concentrate, 48 parts of salt, 34 parts of celery juice concentrate, 50 parts of onion juice concentrate, 60 parts of tomato puree, 60 parts of red wine extract and 40 parts of glutamate is given a prior reaction in a tube heater for 6 min at 99°C. Then, 106 parts of soup stock, 0.7 parts of spices (cloves, bay leaf, pepper, thyme, rosemary) and 875 parts of water are added, so that a solids content of 30% by weight is obtained and this product is cooked in a cooking vessel at 100 °C for 60 minutes. The product is then concentrated in a single stage in a thin-film evaporator from approximately 30% DM to 66% DM. When 80-100 grams of this concentrate are boiled with 1 litre of water, a sauce base is obtained which corresponds in flavour and consistency to a classically prepared stock.
Example 2
A mixture having a solids content of 80% by weight of 27 parts of meat extract, 18 parts of gelatin, 36 parts of dextrose, 27 parts of carrot juice concentrate, 62 parts of leek juice concentrate, 62 parts of salt, 31 parts of celery juice concentrate, 46 parts of onion juice concentrate, 54 parts of tomato puree and 36 parts of glutamate is given a prior reaction in a tube heater for 6 min at 99°C. Then, 100 parts of soup stock, 0.6 parts of spices (cloves, bay leaf, pepper, thyme, rosemary) and 831 parts of water are added, and the mixture is cooked in a cooking vessel at 100°C for 60 minutes. The product is then concentrated in a single stage in a thin- film evaporator from approximately 28% DM to 60% DM. This product also corresponds, after redilution to 1 litre, in flavour and consistency to a classically prepared stock. Since it is prepared without red wine extract, it permits more versatile applications.
Example 3
A mixture having a solids content of 78% by weight of 30 parts of meat extract, 40 parts of dextrose, 30 parts of carrot juice concentrate, 68 parts of leek juice concentrate, 48 parts of salt, 34 parts of celery juice concentrate, 50 parts of onion juice concentrate, 60 parts of tomato puree, 60 parts of red wine extract and 40 parts of glutamate is given a prior reaction in a tube heater for 6 min at 99°C. Then, 110 parts of soup stock, 0.7 parts of spices (cloves, bay leaf, pepper, thyme, rosemary) and 875 parts of water are added, and the mixture is cooked in a cooking vessel at 100°C for 60 minutes. The product is then concentrated in a single stage in a thin- film evaporator from approximately 30% DM to 66% DM. After redilution, this product did not comply with the requirements with respect to flavour and consistency. This example illustrates the importance that the substances extracted from the bones and the collagen raw materials have for the flavour and consistency of a good-tasting stock.
Example 4
30 parts of meat extract, 20 parts of gelatin, 40 parts of dextrose, 30 parts of carrot juice concentrate, 68 parts of leek juice concentrate, 48 parts of salt, 34 parts of celery juice concentrate, 50 parts of onion juice concentrate, 60 parts of tomato puree, 60 parts of red wine extract and 40 parts of glutamate are mixed to form a mixture having a solids content of 75% by weight and, without prior reaction, are cooked together with 106 parts of soup stock, 0.7 parts of spices (cloves, bay leaf, pepper, thyme, rosemary) and 875 parts by water in a cooking vessel at 100°C for 3 hours. The product is then concentrated in a single stage in a thin-film evaporator from approximately 30% DM to 66% DM. The product lacks the typical roasted flavour of a stock, it has an inharmonious and raw taste.
Example 5 30 parts of meat extract, 20 parts of gelatin, 40 parts of dextrose, 30 parts of carrot juice concentrate, 68 parts of leek juice concentrate, 48 parts of salt, 34 parts of celery juice concentrate, 50 parts of onion juice concentrate, 60 parts of tomato puree, 60 parts of red wine extract and 40 parts of glutamate are mixed with 106 parts of soup stock, 0.7 parts of spices (cloves, bay leaf, pepper, thyme, rosemary) . An attempt was made to subject this mixture, which had a solids content of 78% by weight, to a prior reaction in the tube heater at 99°C for 6 minutes. This did not succeed, the product "burns on" immediately and exhibits a corresponding flavour profile.

Claims

Claims
1. Process for preparing a storage-stable brown stock from meat extract and vegetable juice and other customary additives, characterized in that a) in a prior reaction, a liquid mixture having a solids content of 65-85% by weight, preferably 75-80% by weight, is prepared by mixing 1-40% meat extract, 1-30% gelatin and 5-70% vegetable juice concentrate with or without other customary additives, which mixture is allowed to react at a temperature around boiling point, preferably 90-100°C, for 3-20 minutes, preferably 5-15 minutes, then b) in a cooking step, a soup stock is added to the product of the prior reaction and, after dilution to a solids content of 10-45% by weight, preferably 15-35% by weight, the mixture is cooked for 40-180 minutes, preferably 50-80 minutes, at a temperature around boiling point, preferably 90-100 °C, whereupon c) the product is concentrated to a solids content of at least 60% by weight, preferably 70% by weight or above.
2. Process according to Claim 1, characterized in that, in the prior reaction (a) , reducing sugars, preferably dextrose, are added.
3. Process according to one of the preceding claims, characterized in that 0.5-0.8 parts by weight of gelatin are added per 1 part by weight of meat extract .
4. Process according to one of the preceding claims, characterized in that 1-1.5 parts by weight of reducing sugars are added per 1 part by weight of meat extract .
5. Process according to one of the preceding claims, characterized in that the prior reaction is carried out in a tube heater.
6. Process according to one of the preceding claims, characterized in that the dilution for the cooking step is effected by adding water.
7. Process according to one of the preceding claims, characterized in that the product is concentrated in process stage c) by means of a falling-film evaporator or thin-film evaporator.
8. Process according to one of the preceding claims, characterized in that the end product is dried to give a pulverulent dry product .
9. Process according to Claim 8, characterized in that the drying is carried out by means of vacuum drying or microwave vacuum drying
PCT/EP2002/004939 2001-05-08 2002-05-02 Process for preparing a storage-stable brown stock WO2002089608A1 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
AU2002341151A AU2002341151B2 (en) 2001-05-08 2002-05-02 Process for preparing a storage-stable brown stock
EP02742946A EP1385395B1 (en) 2001-05-08 2002-05-02 Process for preparing a storage-stable brown stock
DE60202521T DE60202521T2 (en) 2001-05-08 2002-05-02 METHOD FOR PRODUCING STORAGE STABILIZED BROTH
AT02742946T ATE286357T1 (en) 2001-05-08 2002-05-02 METHOD FOR PRODUCING A STORAGE-Stable MEAT BROTH

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10122244.0 2001-05-08
DE10122244A DE10122244A1 (en) 2001-05-08 2001-05-08 Process for the production of a storage stable brown sauce fund

Publications (1)

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WO2002089608A1 true WO2002089608A1 (en) 2002-11-14

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PCT/EP2002/004939 WO2002089608A1 (en) 2001-05-08 2002-05-02 Process for preparing a storage-stable brown stock

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US (1) US6861085B2 (en)
EP (1) EP1385395B1 (en)
AT (1) ATE286357T1 (en)
AU (1) AU2002341151B2 (en)
DE (2) DE10122244A1 (en)
WO (1) WO2002089608A1 (en)

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WO2016050454A1 (en) 2014-09-30 2016-04-07 Unilever N.V. Food concentrate
WO2016050456A1 (en) 2014-09-30 2016-04-07 Unilever N.V. Food concentrate
WO2017055090A1 (en) 2015-09-30 2017-04-06 Unilever N.V. Food concentrate
WO2018114383A1 (en) 2016-12-20 2018-06-28 Unilever N.V. Food concentrate
WO2018114382A1 (en) 2016-12-20 2018-06-28 Unilever N.V. Food concentrate

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DE102020118275B4 (en) 2020-07-10 2022-02-24 Kevin Jeffrey Hornik Process for preparing instant curry sauce powder and its use

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016050454A1 (en) 2014-09-30 2016-04-07 Unilever N.V. Food concentrate
WO2016050456A1 (en) 2014-09-30 2016-04-07 Unilever N.V. Food concentrate
WO2017055090A1 (en) 2015-09-30 2017-04-06 Unilever N.V. Food concentrate
WO2018114383A1 (en) 2016-12-20 2018-06-28 Unilever N.V. Food concentrate
WO2018114382A1 (en) 2016-12-20 2018-06-28 Unilever N.V. Food concentrate

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DE60202521T2 (en) 2005-06-23
ATE286357T1 (en) 2005-01-15
US20020168461A1 (en) 2002-11-14
EP1385395B1 (en) 2005-01-05
US6861085B2 (en) 2005-03-01
DE60202521D1 (en) 2005-02-10
EP1385395A1 (en) 2004-02-04
AU2002341151B2 (en) 2004-03-11
DE10122244A1 (en) 2003-01-02

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