WO2002064105A2 - Substituts de silicone utilises en cosmetique capillaire - Google Patents

Substituts de silicone utilises en cosmetique capillaire Download PDF

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Publication number
WO2002064105A2
WO2002064105A2 PCT/EP2002/000976 EP0200976W WO02064105A2 WO 2002064105 A2 WO2002064105 A2 WO 2002064105A2 EP 0200976 W EP0200976 W EP 0200976W WO 02064105 A2 WO02064105 A2 WO 02064105A2
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WO
WIPO (PCT)
Prior art keywords
composition according
fatty
alcohols
acids
glycine
Prior art date
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PCT/EP2002/000976
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German (de)
English (en)
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WO2002064105A3 (fr
Inventor
Peter Busch
Thomas Otto Gassenmeier
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Henkel Kommanditgesellschaft Auf Aktien
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Publication of WO2002064105A2 publication Critical patent/WO2002064105A2/fr
Publication of WO2002064105A3 publication Critical patent/WO2002064105A3/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41—Amines
    • A61K8/416—Quaternary ammonium compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37—Esters of carboxylic acids
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/60—Sugars; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/64—Proteins; Peptides; Derivatives or degradation products thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/85—Polyesters
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/12—Preparations containing hair conditioners

Definitions

  • the invention relates to a composition
  • a composition comprising carbohydrates, amino acids, peptides, oil bodies, surfactants and quaternary ammonium compounds, their use as a silicone substitute in agents for influencing properties of fibrous materials such as hair and wool, in particular the properties of hair such as volume, shine, hold, fullness, Tactility, electrostatics and resistance to heat, UV and IR radiation.
  • the cleaning and care of the hair is an important part of human body care. Both cleaning the hair with shampoos and decorating the hairstyle, for example by dyeing or perming, are interventions that influence the natural structure and properties of the hair. Following such a treatment, for example, the wet and dry combability of the hair, the hold and the fullness of the hair may be unsatisfactory or the hair may have an increased split ends.
  • the hair is treated with special active ingredients, for example quaternary ammonium salts or special polymers.
  • special active ingredients for example quaternary ammonium salts or special polymers.
  • this treatment improves combability, hold and fullness of the hair and reduces the split rate.
  • these preparations additionally contain active ingredients which were formerly reserved for the hair aftertreatment agents.
  • the consumer thus saves one application step; At the same time, the packaging effort is reduced because one product is used less.
  • the active ingredients available both for separate post-treatment agents and for combination products have so far not been able to meet all of the consumers' wishes.
  • silicone compounds have become increasingly important as components of cosmetic preparations, since they improve the skin and hair feel even in small quantities, are chemically inert, compatible with practically all cosmetic ingredients and, ultimately, are harmless from a dermatological point of view.
  • silicones cannot be incorporated stably into aqueous formulations, which leads to unsightly creams or even irreversible phase separation, especially when stored for long periods or when exposed to heat. This problem occurs in particular when the emulsions also contain pearlescent waxes.
  • silicone compounds show a tendency to accumulate on the skin and hair ("build-up" effect), which leads to an undesirable blunt grip over time
  • build-up effect
  • the desired high stability of the silicones is, on the other hand, associated with reduced biodegradability and a resulting environmental impact.
  • the object on which the present invention is based is therefore to provide silicone substitutes which do not have the disadvantages described above, but nevertheless enable a comparable influencing of the properties of fibrous materials, such as hair and wool.
  • the object was achieved according to the invention by a composition comprising
  • Carbohydrates suitable for the purposes of the invention can be cyclic or open-chain.
  • Preferred carbohydrates are selected from the group consisting of aldohexoses, aldopentoses, aldofuranoses, aldopyranoses, glycosamines from aldopyranoses, glycosamines from aldofuranoses, dimeric reducing aldopyranoses and the glycosamines, dimeric reducing aldofuranoses formed therefrom and the glycosonic acids, trimers, or trimers formed from them, glycosonic acids, or trimers, glycosonic acids, trimers, or glycosonic acids, trimers, or trimers the lactones formed from it.
  • Carbohydrates selected from the group consisting of allose, old rose, galactose, glucose, glucofructose, fructose, gulose, idose, mannose, saccarose, talose, glucosamine, galactosamine, mannosamine, maltose, cellobiose, gentiobiose, lactose, lactosamine are particularly suitable , Melezitose, erythrose, threose, ribose, arabinose, xylose, lyxose, glucuronic acid and gluconic acid. Glucose is particularly preferred.
  • compositions according to the invention usually contain 1 to 10% by weight, preferably 1.5 to 8% by weight, particularly preferably 2 to 5% by weight, of one or more carbohydrates, based on the total composition.
  • amino acids which can be used in the context of the invention are all natural and unnatural ⁇ - and ⁇ -amino acids, but natural amino acids or their racemates are preferably used.
  • Amino acids selected from the group consisting of glycine, serine, cysteine, threonine, methionine, alanine and phenylalanine are particularly preferably used.
  • compositions according to the invention usually contain 1 to 10% by weight, preferably 1.5 to 8% by weight, particularly preferably 2 to 5% by weight, of one or more amino acids, based on the total composition.
  • the peptides used are selected from oligopeptides (2-9 AS), polypeptides (10-100 AS) and macropeptides (> 100 AS) as well as protein hydrolyzates.
  • Peptides which are selected from gluadine, glycine-glycine, alanine-glycine, serine-glycine, serine-serine, glycine-proline, phenylalanine-glycine and glycine-alanine-valine are particularly preferably used.
  • compositions according to the invention usually contain 1 to 10% by weight, preferably 1, 5 to 8% by weight, particularly preferably 2 to 5% by weight, of one or more peptides, based on the total composition.
  • the oil bodies which can be used according to the invention are preferably selected from i. Dialkyl carbonates of the formula (I)
  • R 1 therein represents a linear or branched alkyl or alkenyl radical having 6 to 22 carbon atoms (e.g. a 2-ethylhexyl, isotridecyl or isostearyl radical) or a radical which is a polyol having 2 to 15 carbon atoms and at least derives two and at most 10, preferably 6, particularly preferably 4, hydroxyl groups,
  • R 2 corresponds to the definition of R 1 or an alkyl radical having 1 to 5 carbon atoms and n and m are independently 0 or integers from 1 to 100; ii. Guerbet alcohols based on fatty alcohols (linear, saturated or unsaturated primary alcohols with 6 to 22 carbon atoms are generally referred to as fatty alcohols) with 6 to 18, preferably 8 to 10, carbon atoms; iii. Esters of linear C 6 -C (fatty acids are used as i A. aliphatic, linear or branched, saturated or unsaturated carboxylic acids having 1 to 30 carbon atoms.) 22 fatty acids with linear C 6 - C 22 fatty alcohols; iv. Esters of branched C 6 -C 3 carboxylic acids with linear C6-C2 2 -
  • C 6 alcohols such as propylene glycol, dimer diol or trimer triol
  • Guerbet alcohols vii.Triglycerides based on C 6 -C 10 fatty acids; viii. Esters of fatty alcohols and / or Guerbet alcohols with aromatic CQ
  • C 12 carboxylic acids ix. vegetable oils; x. branched primary alcohols; xi. substituted cyclohexanes; xii. linear C 6 -C 22 fatty alcohol carbonates and / or Guerbet carbonates, xiii. Dialkyl ethers with 8 to 32 carbon atoms, xiv. aliphatic and naphthenic hydrocarbons.
  • dialkyl carbonates mentioned are in principle known substances.
  • the substances can be prepared by transesterification of dimethyl or diethyl carbonate with the hydroxy compounds mentioned by the processes of the prior art; an overview of this can be found, for example, in Chem. Rev. 96, 951 (1996).
  • Dialkyl carbonates of the formula (I) which are particularly suitable for solving the present task, meet one of the following conditions:
  • R 1 represents a linear alkyl radical having 8 to 18 carbon atoms or a 2-ethylhexyl radical and R 2 represents R 1 or a methyl group;
  • R 1 is a linear alkyl radical having 12 to 18 carbon atoms
  • R 2 is R 1 or methyl and n and m are each numbers from 1 to 10;
  • R 1 is a radical of a polyol which is selected from the group formed by glycerol, alkylene glycols, technical oligoglycerol mixtures, methylol compounds, lower alkyl glucosides, sugar alcohols, sugars and amino sugars
  • R 2 is R 1 , a linear or branched alkyl radical with 8 to 12 carbon atoms or methyl.
  • dialkyl carbonates of the two groups (a) and (b) are complete or partial transesterification products of dimethyl and / or diethyl carbonate with capron alcohol, caprylic alcohol, 2-ethylhexyl alcohol, capric alcohol, lauryl alcohol, isotridecyl alcohol, myristyl alcohol, cetyl alcohol, palmoleyl alcohol, stearyl alcohol , Oleyl alcohol, elaidyl alcohol, petroselinyl alcohol, linolyl alcohol, linolenyl alcohol, elaeostearyl alcohol, arachyl alcohol, gadoleyl alcohol, behenyl alcohol, erucyl alcohol and brassidyl alcohol and their technical mixtures, which are used, for example, in the high-pressure hydrogenation of technical methyl esters based on fats and oils from oils and ro ores from aldehydes and oils from aldehydes or oils from aldehydes or from oils or
  • the carbonates of group (c) are substances which are obtained by completely or partially transesterifying dimethyl and / or diethyl carbonate with polyols.
  • Polyols which are suitable for the purposes of the invention preferably have 2 to 15 carbon atoms and at least two hydroxyl groups. Typical examples are glycerin;
  • Alkylene glycols such as, for example, ethylene glycol, diethylene glycol, propylene glycol, butylene glycol, hexylene glycol and polyethylene glycols with an average molecular weight of 100 to 1000 daltons; technical oligoglycerol mixtures with a degree of self-condensation of 1.5 to 10 such as technical diglycerol mixtures with a diglycerol content of 40 to 50% by weight;
  • Methylol compounds such as in particular trimethylolethane, trimethylolpropane, trimethylolbutane, pentaerythritol and dipentaerythritol; Lower alkyl glucosides, especially those with 1 to 8 carbons in the alkyl radical, such as methyl and butyl glucoside; Sugar alcohols with 5 to 12 carbon atoms, such as
  • Sugars with 5 to 12 carbon atoms such as glucose or sucrose
  • Aminosugars such as glucamine.
  • Oil bodies which are preferably used are caprone / caprylic triglyceride, dioctyl ether and glyceryl oleate.
  • compositions according to the invention usually contain 0.2 to 5% by weight, preferably 0.3 to 4% by weight, particularly preferably 0.5 to 1.5% by weight, of one or more oil bodies, based on the total composition.
  • surfactants described in the prior art can be used within the scope of the invention, provided that they have sufficient dermatological compatibility.
  • suitable mild, i.e. Surfactants which are particularly compatible with the skin are fatty alcohol polyglycol ether sulfates, monoglyceride sulfates, mono- and / or dialkyl sulfosuccinates, fatty acid isethionates, fatty acid sarcosinates, fatty acid taurides, fatty acid glutamates, ether carboxylic acids, alkyl oligoglucosides, fatty acid glucamides and fatty alcohol / fatty acid base fatty acids, fatty alkaloids or fatty acid base fatty acids, alkali alcohol or protein sulfonate fatty acids, preferably alkali alcohol or protein sulfonate fatty acids, fatty alcohol glucamides, fatty alcohol alkoxylates or fatty acid base fatty acids, alkyl amide or s
  • compositions according to the invention usually contain 2 to 20% by weight, preferably 3 to 18% by weight, particularly preferably 5 to 15% by weight, of one or more surfactants, based on the total composition.
  • Quaternary ammonium compounds which can be used in the context of the invention are selected from cetyltrimethylammonium chloride / bromide (CTA), stearyltrimethylammonium chloride / bromide, distearyldimethylammonium chloride / bromide, lauryldimethylammonium chloride / bromide, lauryldimethylbenzylammididium chloride / aus-bromomidium chloride / ausbromide and / - bromide "Esterquats" (quaternized fatty acid triethanolamine ester salts), for example dimethyldistearoylhydroxyethylammonium chloride, Dehyquart ® AU-46, Dehyquart ® F-30 and Dehyquart ® F-75 and Polyquaternium-10.
  • CTA cetyltrimethylammonium chloride / bromide
  • Esterquats quaternized fatty acid triethanolamine ester salts
  • compositions according to the invention usually contain 0.2 to 5% by weight, preferably 0.4 to 4% by weight, particularly preferably 0.5 to 2% by weight, of one or more quaternary ammonium compounds, based on the total composition.
  • compositions are supplemented with water to 100% by weight, so that, unless stated otherwise, all the percentages by weight relate to the percentages by weight of the constituent in question in the aqueous composition.
  • compositions according to the invention can be used in agents for hair and body care, such as shampoos, conditioners, rinses, aerosols and gels, or else in agents for wool treatment / care in the form of detergents, fabric softeners and finishes.
  • compositions usually comprise the compositions according to the invention in amounts of 0.5 to 50% by weight, preferably 5 to 30% by weight, particularly preferably up to 20% by weight, based on the compositions.
  • the agents can additionally contain a carrier.
  • the proportion of such a carrier can be 2 to 15% by weight, preferably 3 to 12% by weight, particularly preferably 5 to 10% by weight, based on the total composition of the agent.
  • Suitable carriers are solid, liquid, gel-like or pasty and preferably consist of aqueous systems, natural or synthetic oils or oil-in-water emulsions. Such systems are known in the prior art, to which reference is hereby made.
  • the formulations can also contain conventional additives such as mild surfactants, other oil substances, superfatting agents, stabilizers, waxes, consistency enhancers, thickening agents, cationic polymers, biogenic agents, anti-dandruff agents, film formers, preservatives, hydrotropes, solubilizers, UV light protection filters, insect repellents, self-tanning agents, dyes and fragrances , Rheology aids, antioxidants, stabilizers, and the like.
  • conventional additives such as mild surfactants, other oil substances, superfatting agents, stabilizers, waxes, consistency enhancers, thickening agents, cationic polymers, biogenic agents, anti-dandruff agents, film formers, preservatives, hydrotropes, solubilizers, UV light protection filters, insect repellents, self-tanning agents, dyes and fragrances , Rheology aids, antioxidants, stabilizers, and the like.
  • Substances such as lanolin and lecithin as well as polyethoxylated or acylated lanolin and lecithin derivatives, polyol fatty acid esters, monoglycerides and fatty acid alkanolamides can be used as superfatting agents, the latter simultaneously serving as foam stabilizers.
  • Mainly fatty alcohols with 12 to 22 and preferably 16 to 18 carbon atoms and also partial glycerides come into consideration as consistency agents.
  • a combination of these substances with alkyl oligoglucosides and / or fatty acid N-methylglucamides of the same chain length and / or polyglycerol poly-12-hydroxystearates is preferred.
  • Suitable thickeners are, for example, poly sacchahde, in particular xanthan gum, guar-guar, agar-agar, alginates and tyloses, carboxymethyl cellulose and hydroxyethyl cellulose, also relatively high molecular weight polyethylene glycol mono- and di-esters of fatty acids, polyacrylates (for example Carbopol ® of Goodrich or Synthalene ® from Sigma), polyacrylamides, polyvinyl alcohol and polyvinylpyrrolidone, surfactants such as ethoxylated fatty acid glycerides, esters of fatty acids with polyols such as pentaerythritol or trimethylolpropane, fatty alcohol ethoxylates with restricted Homolog distribution or alkyl oligoglucosides as well as electrolytes such as table salt and ammonium chloride.
  • poly sacchahde in particular xanthan gum, guar-guar, agar-a
  • Suitable cationic polymers are, for example, cationic cellulose derivatives, such as a quaternized hydroxyethyl cellulose, which is available under the name Polymer JR 400 ® from Amerchol, cationic starch, copolymers of diallylammonium salts and acrylamides, quaternized vinylpyrrolidone / inylimidazole polymers such as Luviquat ® (BASF ), condensation products of polyglycols and amines, quaternized Kollagenpoly- peptide for example lauryldimonium hydroxypropyl hydrolyzed collagen (Lamequat ⁇ L / Grunau), quaternized Weizenpolypeptide, polyethyleneimine, cationic silicone polymers such as, amodimethicone, copolymers of adipic acid and dimethylaminohydroxypropyl diethylenetriamine (Cartaretine ® / Sandoz), copolymers acrylic acid with dimethyldiallyl
  • formulations comprising the compositions according to the invention are preferably silicone-free.
  • Suitable silicone compounds are, for example, dimethylpolysiloxane, methylphenylpolysiloxane, cyclic silicones and amino, fatty acid, alcohol, polyether, epoxy, fluorine and / or alkyl-modified silicone compounds, which can be both liquid and resinous at room temperature.
  • Typical examples of fats are glycerides; waxes include beeswax, carnauba wax, candelilla wax, montan wax, paraffin wax or microwaxes, optionally in combination with hydrophilic waxes, for example cetyl stearyl alcohol or partial glycerides.
  • Pearlescent waxes which can be used are, in particular, mono- and difatty acid esters of polyalkylene glycols, partial glycerides or esters of fatty alcohols with polybasic carboxylic acids or hydroxycarboxylic acids.
  • Metal salts of fatty acids such as magnesium, aluminum and / or zinc stearate can be used as stabilizers.
  • Biogenic active substances are to be understood to mean, for example, tocopherol, tocopherol acetate, tocopherol palmate, ascorbic acid, retinol, bisabolol, allantoin, phytantriol, panthenol, AHA acids, plant extracts and vitamin complexes.
  • Climbazole, octopirox and zinc pyrethione can be used as antidandruff agents.
  • Common film formers are, for example, chitosan, microcrystalline chitosan, quaternized chitosan, polyvinyl pyrrolidone, vinyl pyrrolidone / vinyl acetate copolymers, polymers of the acrylic acid series, quaternary cellulose derivatives, collagen, hyaluronic acid or its salts and similar compounds.
  • UV light protection filters are understood to mean organic substances which are able to absorb ultraviolet rays and release the absorbed energy in the form of longer-wave radiation, for example heat.
  • Typical examples are 4-aminobenzoic acid and its esters and derivatives (e.g. 2-ethylhexyl-p-dimethylaminobenzoate or p-dimethylaminobenzoic acid octyl ester), methoxy cinnamic acid and its derivatives (e.g. 4-methoxycinnamic acid 2-ethylhexyl ester), benzophenones (e.g.
  • the particles should have an average diameter of less than 100 nm, preferably between 5 and 50 nm and in particular between 15 and 30 nm. They can have a spherical shape, but they can also such particles are used that have an ellipsoidal shape or shape that differs from the spherical shape in some other way.
  • secondary light stabilizers of the antioxidant type can also be used, which interrupt the photochemical reaction chain which is triggered when UV radiation penetrates the skin. Typical examples are superoxide dismutase, tocopherols (vitamin E) and ascorbic acid (vitamin C).
  • Hydrotropes such as ethanol, isopropyl alcohol or polyols can also be used to improve the flow behavior.
  • Polyols that come into consideration here preferably have 2 to 15 carbon atoms and at least two hydroxyl groups. Typical examples are
  • Alkylene glycols such as, for example, ethylene glycol, diethylene glycol,
  • Methyl compounds such as in particular trimethylolethane, trimethylolpropane, trimethylolbutane, pentaerythritol and dipentaerythritol;
  • Lower alkyl glucosides especially those with 1 to 8 carbons in the alkyl radical, such as methyl and butyl glucoside;
  • Sugars with 5 to 12 carbon atoms such as glucose or sucrose
  • Aminosugars such as glucamine.
  • Suitable preservatives are, for example, phenoxyethanol, formaldehyde solution, parabens, pentanediol or sorbic acid.
  • insect repellents are N, N-diethyl-m-toluamide, 1, 2-pentanediol or insect repellent 3535, dihydroxyacetone is suitable as a self-tanner.
  • the dyes which can be used are those substances which are suitable and approved for cosmetic purposes, as compiled, for example, in the publication "Cosmetic Dyes" by the Dye Commission of the German Research Foundation, Verlag Chemie, Weinheim, 1984, pp. 81-106. These dyes are usually used in concentrations of 0.001 to 0.1% by weight, based on the mixture as a whole.
  • the total proportion of auxiliaries and additives can be 1 to 50, preferably 5 to 40
  • the agents can be produced by customary cold or hot processes; preferably one works according to the
  • the agents are applied by application to those to be treated
  • the treatment can have a permanent influence on the properties of the substrates, such as wet and dry combability, hold, moisture, strength, fullness, shine, tactility and electrostatic properties, as well as resistance to UV and IR radiation and heat.
  • compositions according to the invention were applied to strands of hair made from dark, central European hair. After conditioning, the strands of hair were examined under standardized, air-conditioned conditions by an expert panel with regard to sensory properties against the same strands of hair that were treated with a composition of the prior art (benchmark) (sensory assessment).
  • the hair treated with the formulation according to the invention showed silicone-like grip properties.

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  • Life Sciences & Earth Sciences (AREA)
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Abstract

L'invention concerne une composition contenant des hydrates de carbone, des acides aminés, des peptides, des corps huileux, des tensioactifs et des composés ammonium quaternaires et leur utilisation comme substituts de silicone dans des agents servant à influer sur les propriétés de matières fibreuses, notamment les propriétés capillaires, telles que le volume, la brillance, la tenue, le toucher, la tactilité, électrostatique et la résistance à la chaleur et aux rayons U.V. et infrarouges.
PCT/EP2002/000976 2001-02-09 2002-01-31 Substituts de silicone utilises en cosmetique capillaire WO2002064105A2 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10105922.1 2001-02-09
DE2001105922 DE10105922A1 (de) 2001-02-09 2001-02-09 Haarkosmetische Siliconersatzstoffe

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WO2002064105A2 true WO2002064105A2 (fr) 2002-08-22
WO2002064105A3 WO2002064105A3 (fr) 2003-03-27

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CN104856922A (zh) * 2015-06-03 2015-08-26 铜陵县黑你养殖专业合作社 羊毛护理液
US11116220B2 (en) 2017-12-22 2021-09-14 Ecolab Usa Inc. Antimicrobial compositions with enhanced efficacy

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PL1960055T3 (pl) 2005-12-07 2011-09-30 Unilever Nv Kompozycja do prostowania włosów zawierająca disacharyd
JP5629427B2 (ja) * 2008-10-31 2014-11-19 コグニス・アイピー・マネージメント・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツングＣｏｇｎｉｓ ＩＰ Ｍａｎａｇｅｍｅｎｔ ＧｍｂＨ 毛髪処理組成物
DE102010030519A1 (de) * 2010-06-25 2011-12-29 Henkel Ag & Co. Kgaa Biomimetische Zusammensetzungen zur Pflege und Restrukturierung keratinischer Fasern
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CN104069019A (zh) * 2014-06-11 2014-10-01 滨州安华生物工程有限公司 一种含有透明质酸的洗发品
CN104856922A (zh) * 2015-06-03 2015-08-26 铜陵县黑你养殖专业合作社 羊毛护理液
US11116220B2 (en) 2017-12-22 2021-09-14 Ecolab Usa Inc. Antimicrobial compositions with enhanced efficacy
US11930819B2 (en) 2017-12-22 2024-03-19 Ecolab Usa Inc. Antimicrobial compositions with enhanced efficacy

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