WO2002049437A2 - Formulation for crop protection with insecticidal and acaricidal action - Google Patents

Formulation for crop protection with insecticidal and acaricidal action Download PDF

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Publication number
WO2002049437A2
WO2002049437A2 PCT/BG2001/000017 BG0100017W WO0249437A2 WO 2002049437 A2 WO2002049437 A2 WO 2002049437A2 BG 0100017 W BG0100017 W BG 0100017W WO 0249437 A2 WO0249437 A2 WO 0249437A2
Authority
WO
WIPO (PCT)
Prior art keywords
formulation
crop protection
solvents
insecticidal
group
Prior art date
Application number
PCT/BG2001/000017
Other languages
English (en)
French (fr)
Other versions
WO2002049437A3 (en
Inventor
Ginka Shtereva Atanasova
Mariana Ivanova Karanikolova
Zoia Ivanova Pamihova
Evgenia Stoianova Videnova
Ekaterina Loginova Dimitrova
Original Assignee
Biovet Jsc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Biovet Jsc filed Critical Biovet Jsc
Priority to AU2002218077A priority Critical patent/AU2002218077A1/en
Priority to PL36165701A priority patent/PL361657A1/xx
Priority to EP01271149A priority patent/EP1351572A2/en
Publication of WO2002049437A2 publication Critical patent/WO2002049437A2/en
Publication of WO2002049437A3 publication Critical patent/WO2002049437A3/en

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Classifications

    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/08Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
    • A01N25/10Macromolecular compounds
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/24Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing ingredients to enhance the sticking of the active ingredients
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/30Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N31/00Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
    • A01N31/04Oxygen or sulfur attached to an aliphatic side-chain of a carbocyclic ring system
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N63/00Biocides, pest repellants or attractants, or plant growth regulators containing microorganisms, viruses, microbial fungi, animals or substances produced by, or obtained from, microorganisms, viruses, microbial fungi or animals, e.g. enzymes or fermentates
    • A01N63/30Microbial fungi; Substances produced thereby or obtained therefrom
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/30Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change

Definitions

  • the invention concerns' a new crop protection formulation possessing insecticidal and acaricidal action, selected for use in agronomic and horticultural crops cultivated in greenhouses and in the open.
  • avermectin and its major component avermectin Bi (B Id + B lb ), with the common name abamectin [1], synthesized of the fermentation of Strepiomyces avermii ⁇ lis has been widely used against pests in agronomic and horticultural crops.
  • avermectin formulations are a new generation of insecticides with a mechanism of action differing from that of the chemical pesticides since avermectin Bi (abamectin) is effective against populations of insects and acarines which have developed resistance to organophosphoms compounds, carbamates, pyrethroids, etc.
  • avermectin Bi abamectin
  • the invention concerns a new crop protection formulation possessing insecticidal and acaricidal action, selected for use in agriculture and horticulture.
  • the novel formulation has the following composition, expressed in percent weight units:
  • 0.2 - 3.0 of the 'active component of the avermectins group (including abamectin, ivermectin, natural mycelium product) equal to the biological activity of theniectin B ⁇ 5.0 - 30.0 surfactant (emulsifier) from the polyoxyhydrogenated castor-oil group (Kremofor PH-40 or Kremofor EL-35); 40.0 - 80.0 solvents - propylene glycol or polyethylene glycol; 5.0 - 30.0 other solvents - dimethyl acetamide or dimethyl sulfoxide; 1.0 - 6.0 benzyl alcohol; 0.1 - 1.0 antioxidants - butylhydroxytoluene or butylhydroxyanisol; 1.0 - 3.0 adhesives - poly vinyl pyrolidon (Colydon).
  • Water solution of the formulation with a concentration of 0.10 - 0.12% is applied so that very good foliage covering is assured.
  • the formulation components are stable.
  • the biological studies report good efficacy against Colorado, potato beetle (Leptinotarza decemlineata), the greenhouse whitefly (Trialeurodes vaporiorum), the leafminer fly (Liriomyza huidobrensis), the two-spotted spider mite (Tetranychus urticae) and others.
  • Cremophor EL-35 30.0 g
  • the Colorado, potato beetle is an important pest in potato and aubergine cultures which is due to its consistent proliferation, the long-lasting active feeding of the larvae and the adults and its high reproductive capacity.
  • leafminer fly populations proved to be very difficult because of the secretive way of life and feeding habits of their larvae.
  • Trials were carried out on gerbera daisy and chrysanthemum sprouts and flowers and vegetable cultui'es of tomatoes and cucumbers.
  • the application rate of the formulation was 0.12%.
  • the larval kill in the mines was the main criterion to evaluate the formulation efficacy.
  • the leafminer development was completely inhibited after 2 or 3 sprayings with a 7- day interval' regardless of the density of the population.
  • the biological activity of the leafminer fly was totally suppressed after 2 - 3 sprayings with a 7-day interval in all degrees of density of the cited cultures.
  • a biologic efficacy of 80 to 99%) was provided by the novel formulation against leafminer fly (Table 2).
  • the greenhouse whitefly is an important worldwide pest which attacks greenliouse and open-air cultures. Its larvae, nymphs and adults feed on the foliage underlayer. hi laboratory and field studies the formulation at a concentration of 0.12% killed 84%> of the larvae, eggs and adults of the greenliouse whitefly in vegetable and ornamental cultures (Table 3).

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Zoology (AREA)
  • Wood Science & Technology (AREA)
  • Dentistry (AREA)
  • Plant Pathology (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Environmental Sciences (AREA)
  • Microbiology (AREA)
  • Toxicology (AREA)
  • Mycology (AREA)
  • Biotechnology (AREA)
  • Virology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Adhesives Or Adhesive Processes (AREA)
PCT/BG2001/000017 2000-12-21 2001-11-22 Formulation for crop protection with insecticidal and acaricidal action WO2002049437A2 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
AU2002218077A AU2002218077A1 (en) 2000-12-21 2001-11-22 Formulation for crop protection with insecticidal and acaricidal action
PL36165701A PL361657A1 (en) 2000-12-21 2001-11-22 Formulation for crop protection with insecticidal and acaricidal action
EP01271149A EP1351572A2 (en) 2000-12-21 2001-11-22 Formulation for crop protection with insecticidal and acaricidal action

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
BG105073 2000-12-21
BG105073A BG64140B1 (bg) 2000-12-21 2000-12-21 Състав за растителна защита с инсектицидно и акарицидно действие

Publications (2)

Publication Number Publication Date
WO2002049437A2 true WO2002049437A2 (en) 2002-06-27
WO2002049437A3 WO2002049437A3 (en) 2002-09-26

Family

ID=3928259

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/BG2001/000017 WO2002049437A2 (en) 2000-12-21 2001-11-22 Formulation for crop protection with insecticidal and acaricidal action

Country Status (5)

Country Link
EP (1) EP1351572A2 (bg)
AU (1) AU2002218077A1 (bg)
BG (1) BG64140B1 (bg)
PL (1) PL361657A1 (bg)
WO (1) WO2002049437A2 (bg)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004026033A1 (en) * 2002-09-20 2004-04-01 Artpharm Pty Ltd Plant pesticides and uses thereof
WO2004095926A2 (en) * 2003-04-28 2004-11-11 Monsanto Technology, Llc Treatment of plants and plant propagation materials with an antioxidant to improve plant health and/or yield
CN102613210A (zh) * 2012-01-05 2012-08-01 安徽迪邦药业有限公司 一种1.8%阿维菌素
CN102870790A (zh) * 2012-09-13 2013-01-16 青岛文创科技有限公司 伊维菌素和壳寡糖的增效农药组合物
JP2014043431A (ja) * 2012-08-27 2014-03-13 Maruwa Biochemical Co Ltd マクロライド系化合物を含有する土壌線虫防除用薬剤
EP4145995A4 (en) * 2020-05-08 2024-05-22 CJB Applied Technologies, LLC PESTICIDE COMPOSITIONS AND RELATED METHODS

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0045655A2 (en) * 1980-08-04 1982-02-10 Merck & Co. Inc. Solubilization of ivermectin in water
US4560677A (en) * 1984-01-31 1985-12-24 Merck & Co., Inc. Synergistic avermectin combination for treating plant pests
EP0329460A2 (en) * 1988-02-18 1989-08-23 American Cyanamid Company Stabilised macrolide compositions
EP0867186A1 (en) * 1997-03-21 1998-09-30 Biogenesis, S.A. A long acting injectable parasiticidal composition and the process for its preparation
US5965603A (en) * 1997-07-21 1999-10-12 American Cyanamid Company Nonaqueous compositions for parenteral administration

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2070799C1 (ru) * 1993-10-08 1996-12-27 Товарищество с ограниченной ответственностью Научно-производственное объединение "Фармбиомед" Препарат для борьбы с комплексом вредителей растений "фитоверм"
JPH07173017A (ja) * 1993-12-17 1995-07-11 Toshio Suzuki 松類の枯損防止用組成物及び防止方法

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0045655A2 (en) * 1980-08-04 1982-02-10 Merck & Co. Inc. Solubilization of ivermectin in water
US4560677A (en) * 1984-01-31 1985-12-24 Merck & Co., Inc. Synergistic avermectin combination for treating plant pests
EP0329460A2 (en) * 1988-02-18 1989-08-23 American Cyanamid Company Stabilised macrolide compositions
EP0867186A1 (en) * 1997-03-21 1998-09-30 Biogenesis, S.A. A long acting injectable parasiticidal composition and the process for its preparation
US5965603A (en) * 1997-07-21 1999-10-12 American Cyanamid Company Nonaqueous compositions for parenteral administration

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
DATABASE WPI Section Ch, Week 199536 Derwent Publications Ltd., London, GB; Class C02, AN 1995-272810 XP002203431 & JP 07 173017 A (SUZUKI T), 11 July 1995 (1995-07-11) *
DATABASE WPI Section Ch, Week 199733 Derwent Publications Ltd., London, GB; Class A97, AN 1997-361913 XP002203430 & RU 2 070 799 C (FARMBIOMED CO LTD), 27 December 1996 (1996-12-27) *

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004026033A1 (en) * 2002-09-20 2004-04-01 Artpharm Pty Ltd Plant pesticides and uses thereof
WO2004095926A2 (en) * 2003-04-28 2004-11-11 Monsanto Technology, Llc Treatment of plants and plant propagation materials with an antioxidant to improve plant health and/or yield
WO2004095926A3 (en) * 2003-04-28 2005-01-27 Monsanto Technology Llc Treatment of plants and plant propagation materials with an antioxidant to improve plant health and/or yield
CN102613210A (zh) * 2012-01-05 2012-08-01 安徽迪邦药业有限公司 一种1.8%阿维菌素
JP2014043431A (ja) * 2012-08-27 2014-03-13 Maruwa Biochemical Co Ltd マクロライド系化合物を含有する土壌線虫防除用薬剤
CN102870790A (zh) * 2012-09-13 2013-01-16 青岛文创科技有限公司 伊维菌素和壳寡糖的增效农药组合物
EP4145995A4 (en) * 2020-05-08 2024-05-22 CJB Applied Technologies, LLC PESTICIDE COMPOSITIONS AND RELATED METHODS

Also Published As

Publication number Publication date
BG64140B1 (bg) 2004-02-27
AU2002218077A1 (en) 2002-07-01
EP1351572A2 (en) 2003-10-15
PL361657A1 (en) 2004-10-04
BG105073A (bg) 2002-10-31
WO2002049437A3 (en) 2002-09-26

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