WO2002033162A1 - Composition adoucissante - Google Patents

Composition adoucissante Download PDF

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Publication number
WO2002033162A1
WO2002033162A1 PCT/JP2001/009109 JP0109109W WO0233162A1 WO 2002033162 A1 WO2002033162 A1 WO 2002033162A1 JP 0109109 W JP0109109 W JP 0109109W WO 0233162 A1 WO0233162 A1 WO 0233162A1
Authority
WO
WIPO (PCT)
Prior art keywords
group
carbon atoms
atom
softener composition
alkyl
Prior art date
Application number
PCT/JP2001/009109
Other languages
English (en)
Japanese (ja)
Inventor
Noriaki Ushio
Nobuyuki Ogura
Shuji Tagata
Original Assignee
Kao Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kao Corporation filed Critical Kao Corporation
Publication of WO2002033162A1 publication Critical patent/WO2002033162A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/001—Softening compositions
    • C11D3/0015—Softening compositions liquid
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/58—Heterocyclic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/65—Mixtures of anionic with cationic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/35—Heterocyclic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/46—Compounds containing quaternary nitrogen atoms
    • D06M13/47—Compounds containing quaternary nitrogen atoms derived from heterocyclic compounds

Definitions

  • the present invention relates to fabric softener compositions for textiles.
  • Most of the products marketed as household softeners are mainly composed of two long-chain alkyl groups in one molecule such as di (hardened tallow alkyl) dimethylammonium.
  • the composition is mainly composed of a quaternary ammonium salt having
  • the quaternary ammonium salt has a good softening effect on various fibers in a small amount, but it is known that the fibers can be finished with oil, and it is hoped that the texture of the finished clothes will be improved.
  • Japanese Patent Publication No. 61-373787 discloses a method in which a dialkyl quaternary ammonium compound is used in combination with an anionic surfactant.
  • a softening composition comprising a softening component having two or more cations in a molecule and an anionic surfactant is disclosed.
  • JP-A-52-34098 discloses a textile product treating agent containing an imidazoline derivative and an anionic surfactant.
  • a softener composition containing an imidazoline derivative and an alkali metal salt of a fatty acid is disclosed in Japanese Unexamined Patent Publication (Kokai) No. 2-69589 /, and a detergent composition containing a higher alkylhydroxyethylimidazoline and an anion surfactant. All of the disclosed powers increase the softness effect, reduce oiliness, It was not possible to give a fluent texture and the desired effect comprehensively.
  • the object of the present invention is to provide a soft finish composition which is excellent in softening effect and gives a garment a refreshing texture and a fluffy feeling without an oily feeling which cannot be obtained with a conventional soft finish composition. It is to provide things.
  • the present invention relates to (a) a compound having one alkyl group or alkenyl group having 8 to 36 carbon atoms which may be separated by an ether group, an ester group or an amide group, and containing a nitrogen atom as a hetero atom.
  • the number of nitrogen atoms in the heterocyclic ring is at least 1, preferably 1 to 3, particularly preferably 1 or 2. More specifically, preferred heterocyclic compounds include at least one compound of the following formula (1) and at least one compound of the formula (2).
  • A is a group which forms an aromatic ring by bonding to the N 1 atom, and may include a nitrogen atom other than N 1 .
  • R ′ has 8 to 36 carbon atoms, preferably 10 to 28, particularly preferably 14 to 24, which may be separated by an ether group, an ester group or an amide group bonded to any one of the constituent atoms of A. It is an alkyl group or an alkenyl group.
  • A is 4 to 13, preferably 4 to 9, and particularly preferably a 5- or 6-membered ring composed of 4 or 5 atoms or a 5- and 6-membered ring connected to each other. A condensed ring may be formed.
  • B is a group which forms a saturated or unsaturated heterocyclic ring by bonding to an N 2 atom, and may contain a nitrogen atom other than N 2 .
  • R 2 is a group bonded to a constituent atom of B, and R 2 or R 3 is an alkyl group or an alkenyl group having 8 to 36 carbon atoms, one of which may be separated by an ether group, an ester group or an amide group.
  • the other is a hydrogen atom or an alkyl group, a hydroxyalkyl group or an aminoalkyl group having 1 to 5 carbon atoms.
  • R 1 is particularly preferably a group represented by the following general formula (3).
  • R 4 is preferably an alkyl group or an alkenyl group having 12 to 24 carbon atoms, particularly preferably 14 to 20 carbon atoms
  • R 5 is preferably a C 1 to C 5 carbon atom, particularly preferably a C 1 to C 3 alkyl group. It is a alkylene group.
  • X is selected from one C ⁇ 0-, one OCO—, one CONH—, one NHCO— It is a group that is exposed.
  • n is a number of 0 or 1.
  • Preferred compounds of the formula (2) include the compounds of the following formulas (4) to (8).
  • R 2 and R 3 have the same meanings as in the general formula (2), and particularly, since R 2 has the structure of the general formula (3), R 3 is an alkyl group having 1 to 3 carbon atoms or a hydroxyalkyl group. Or an aminoalkyl group, preferably a hydroxyalkyl group or an aminoalkyl group, more preferably an aminoethyl group, a dimethylaminoethyl group, an aminopropyl group, a dimethylaminopropyl group, and most preferably an aminoethyl group or an aminopropyl group.
  • m is 2 or 3
  • k and j are numbers 1-3
  • k + j is 3 or Is 4.
  • i is 3 or 4.
  • a compound selected from the formulas (4), (5) and (8) is particularly preferable, and a compound of the formula (4) is most preferable.
  • a compound selected from the formulas (4), (5), (6), and (7) it is also possible to use a compound neutralized with an acid agent before blending in the soft finish composition. it can.
  • an acid agent hydrochloric acid, sulfuric acid, hydroxycarboxylic acid, glycolic acid, phosphoric acid, and fatty acid are preferable, and hydrochloric acid, sulfuric acid, and glycolic acid are particularly preferable.
  • Compounds composed of an anionic group selected from an ester group, a phosphate group, a carboxylic acid group, preferably a sulfonic acid group and a sulfate group are preferred.
  • anionic surfactants include alkylbenzene sulfonic acid, alkyl sulfate, polyoxyalkylene alkyl ether sulfate, olefin sulfonic acid, alkane sulfonate, polyoxyalkylene alkyl or alkenyl ether carboxylic acid, ⁇ -sulfofatty acid, ⁇ -sulfofatty acid ester, ⁇ -sulphine sulfonic acid, and salts thereof.
  • alkyl sulfates having an alkyl group having 10 to 36 carbon atoms, preferably 12 to 24 carbon atoms, and particularly preferably 14 to 24 carbon atoms.
  • 0-36 preferably having 12 to 24, particularly preferably 14 to 24 alkyl chains, and having an average number of moles of ethylene oxide of 1 to 6, preferably 1 to 4, It is preferable to mix at least one selected from polyoxyethylene alkyl ether sulfuric acid and salts thereof.
  • anionic surfactants are preferably used in the form of a salt. Examples thereof include a sodium salt, a potassium salt, an ammonium salt and an alkanolamine salt, and particularly preferred are a sodium salt and a potassium or potassium salt.
  • the softener composition of the present invention preferably contains 3 to 40% by weight, more preferably 5 to 35% by weight, particularly 8 to 3% by weight of the component (a), and 1 to 3% by weight of the component (b). It is preferably contained in an amount of 20% by weight, more preferably 2 to 20% by weight, particularly preferably 3 to 15% by weight.
  • the softener composition of the present invention can be in any form such as liquid, paste, gel, and solid.
  • the total amount of the component (a) and the component (b) is preferably 4 to 50% by weight, more preferably 8 to 40% by weight, and particularly preferably 10 to 35% by weight.
  • the amount of water is preferably 40 to 95% by weight, particularly preferably 50 to 85% by weight.
  • the composition of the present invention is 25. It is preferable that ⁇ ⁇ is 1 to 9 and more preferably 2 to 8 from the viewpoint of storage stability.
  • the softener composition of the present invention preferably contains a nonionic surfactant for the purpose of improving storage stability.
  • a nonionic surfactant a compound represented by the following formula (9) is preferable.
  • R ′ is an alkyl group or an alkenyl group having 10 to 18, preferably 12 to 18 carbon atoms
  • R ′′ is an alkylene having 2 or 3 carbon atoms, preferably ethylene S It is.
  • p represents a number of 2 to 100, preferably 5 to 80, particularly preferably 10 to 60.
  • T is ⁇ , one CON— or one N—, and when T is one, Q is Q. Is 1 and Q is 2 if T is —CO N— or 1 N—.
  • Specific examples of the compound of the formula (9) include the following compounds.
  • R ′ has the meaning described above.
  • r is a number from 8 to 100, preferably from 10 to 60.
  • R ′ has the meaning described above.
  • Each s and t are independently 2-4 0, preferably a number of 5-4 0, the sequence of ten 2 Eta 4 ⁇ Ichiki As an C 3 H 6 0- groups may be either random or block .
  • R ′ has the meaning described above.
  • u and V are numbers that add up to 10 to 80.
  • the softener composition of the present invention preferably contains 0.5 to 10% by weight, particularly 1 to 8% by weight of a nonionic surfactant from the viewpoint of stability.
  • the softening agent composition of the present invention contains 0.1 to 10% by weight, particularly preferably 0 to 10% by weight, of an ester compound of a saturated or unsaturated fatty acid having 8 to 22 carbon atoms and a polyhydric alcohol in view of storage stability. It is preferable to add 5 to 5% by weight.
  • Ester compounds include tridalicelide, diglycelide, monodalicelide, and pentaerythritol mono-, di-, triester, Rubitan esters are preferred.
  • inorganic electrolytes such as sodium chloride, potassium chloride, calcium chloride, magnesium chloride, ammonium chloride, sodium sulfate, potassium sulfate, ammonium sulfate, sodium nitrate, potassium nitrate, calcium nitrate, magnesium nitrate, and ammonium nitrate are used.
  • the content of 1 to 5% by weight is also preferable from the viewpoint of storage stability.
  • These alcohols and inorganic electrolytes also have excellent effects as phase stabilizers and viscosity modifiers.
  • the softener composition of the present invention preferably contains 0.1 to 5% by weight of a silicone compound such as an amino-modified silicone or a highly polymerized silicone having a molecular weight of 1000 or more for the purpose of improving the softening effect. You can do it.
  • a silicone compound such as an amino-modified silicone or a highly polymerized silicone having a molecular weight of 1000 or more for the purpose of improving the softening effect. You can do it.
  • azo dyes When the composition is to be colored, azo dyes, anthraquinone dyes, indigoid dyes, phthalocyanine dyes, carbonium dyes, quinonimine dyes, methine dyes, quinoline dyes, nitro dyes, nitroso dyes, benzoquinone dyes, naphthoquinones are used as coloring agents. Acid dyes, direct dyes, basic dyes, or reactive dyes selected from dyes, naphthylimide dyes, and perinone dyes, and Liquitint (registered trademark) dyes manufactured by MILLIKEN, preferably 1 ppm to 100 ppm. 0 ppm may be added. In addition, antifoaming agents, fragrances, antipropellants, etc. may be added.
  • Polio -sodium tersulfate (EO average addition moles: 3 moles) (Molecular weight; 504)
  • Soft finish compositions were prepared using the above (a-l) to (a-8), (a'-1), and (b- :! to (b-3).
  • the component (a) was added to water at 65 ° C while stirring with stirring blades.
  • the components (a-1) to (a-7) were neutralized with hydrochloric acid, and then the component (b) was added. . afterwards, The pH was adjusted to a predetermined value using hydrochloric acid or sodium hydroxide, followed by cooling to obtain a desired composition.
  • ⁇ 1 The control is slightly less oily. 1: The control is less oily.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Textile Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

La présente invention concerne une composition adoucissante qui présente un excellent effet adoucissant et qui peut laisser une sensation de propreté sans aspect gras. Cette composition adoucissante comprend (a) un composé hétérocycle portant un groupe C8-36 alkyle ou alkényle qui peut être interrompu par une liaison éther, ester ou amide et contenant de l'azote en tant qu'hétéroatome et (b) un tensioactif anionique portant un groupe C8-36 hydrocarbure selon un rapport molaire (a)/(b) spécifique.
PCT/JP2001/009109 2000-10-17 2001-10-17 Composition adoucissante WO2002033162A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2000316337A JP3847546B2 (ja) 2000-10-17 2000-10-17 柔軟仕上げ剤組成物
JP2000-316337 2000-10-17

Publications (1)

Publication Number Publication Date
WO2002033162A1 true WO2002033162A1 (fr) 2002-04-25

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PCT/JP2001/009109 WO2002033162A1 (fr) 2000-10-17 2001-10-17 Composition adoucissante

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JP (1) JP3847546B2 (fr)
WO (1) WO2002033162A1 (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3914529B2 (ja) * 2002-09-30 2007-05-16 三洋化成工業株式会社 液体柔軟剤組成物
JP6651556B2 (ja) * 2017-03-07 2020-02-19 三洋化成工業株式会社 柔軟剤用基剤及び柔軟剤

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5234098A (en) * 1975-09-04 1977-03-15 Hoechst Ag Trating agents for fiber article
US4629574A (en) * 1983-04-22 1986-12-16 Henkel Kommanditgesellschaft Auf Aktien Ready-to-use fabric softener concentrate
JPH0247362A (ja) * 1988-08-03 1990-02-16 Kao Corp 柔軟仕上剤
JPH04100974A (ja) * 1990-08-09 1992-04-02 Kao Corp 柔軟仕上剤
JPH05132865A (ja) * 1991-11-14 1993-05-28 Kao Corp 衣料用柔軟仕上げ剤

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5234098A (en) * 1975-09-04 1977-03-15 Hoechst Ag Trating agents for fiber article
US4629574A (en) * 1983-04-22 1986-12-16 Henkel Kommanditgesellschaft Auf Aktien Ready-to-use fabric softener concentrate
JPH0247362A (ja) * 1988-08-03 1990-02-16 Kao Corp 柔軟仕上剤
JPH04100974A (ja) * 1990-08-09 1992-04-02 Kao Corp 柔軟仕上剤
JPH05132865A (ja) * 1991-11-14 1993-05-28 Kao Corp 衣料用柔軟仕上げ剤

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JP2002129476A (ja) 2002-05-09
JP3847546B2 (ja) 2006-11-22

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